Method for Recovering Aluminum from Multilayered Packaging Utilizing Sonication and Formic Acid

Abstract

The process disclosed herein is method of recovering aluminum from multilayered packaging. The process comprises subjecting multilayered packaging to a reactor with aqueous formic acid, wherein the solution is sonicated using sonic horns. This process allows the recovery of aluminum in its pure metal form. PP/PE components of the multilayered packaging are recovered utilizing density separation, while ink and PET components require further treatment in a toluene reactor which may include sonication.

Claims

1. A method of recovering aluminum from multilayered packaging comprising: shredding multilayered packaging with a mechanical shredder until the multilayered packaging is reduced to small fragments, subjecting the small fragments to an aqueous solution of formic acid, wherein the aqueous solution is maintained at a minimum temperature of 25 degrees Celsius and a maximum temperature of 75 degrees Celsius, subjecting the aqueous solution of formic acid containing the small fragments to sonication until aluminum separates from the small fragments as pure aluminum metal, and filtering the pure aluminum metal from the aqueous solution of formic acid utilizing density separation.

2. The method of claim 1 wherein a sonic horn producing sonic waves at 250 watts provides the sonication.

3. The method of claim 1 wherein the small fragments have a maximum width of 1 cm and a maximum length of 2 cm.

4. A method of recovering polypropylene or polyethylene from multilayered packaging comprising: shredding multilayered packaging with a mechanical shredder until the multilayered packaging is reduced to small fragments, subjecting the small fragments to an aqueous solution of formic acid, wherein the aqueous solution is maintained at a minimum temperature of 25 degrees Celsius and a maximum temperature of 75 degrees Celsius, subjecting the aqueous solution of formic acid containing the small fragments to sonication until aluminum separates from the small fragments as pure aluminum metal, and filtering the polypropylene or polyethylene from the aqueous solution of formic acid utilizing density separation.

5. The method of claim 4 wherein aluminum is filtered from the aqueous solution of formic acid utilizing density separation before the polypropylene or polyethylene is filtered from the aqueous solution of formic acid.

6. The method of claim 4 wherein the small fragments have a maximum width of 1 cm and a maximum length of 2 cm.

7. The method of claim 4 wherein pure aluminum metal is separated from the aqueous solution of formic acid by filtering the pure aluminum metal from the aqueous solution of formic acid utilizing density separation.

8. A method of recovering polyethylene terephthalate from multilayered packaging comprising: shredding multilayered packaging with a mechanical shredder until the multilayered packaging is reduced to small fragments, subjecting the small fragments to an aqueous solution of formic acid, wherein the aqueous solution is maintained at a minimum temperature of 25 degrees Celsius and a maximum temperature of 75 degrees Celsius, subjecting the aqueous solution of formic acid containing the small fragments to sonication until aluminum separates from the small fragments as pure aluminum metal, subjecting a polyethylene terephthalate layer of the small fragments to toluene, wherein the toluene is maintained at a minimum temperature of 25 degrees Celsius and a maximum temperature of 75 degrees Celsius, subjecting the toluene to sonication until the polypropylene terephthalate layer separates from the small fragments, and filtering the polyethylene terephthalate layer from the toluene utilizing density separation.

9. The method of claim 8 wherein the small fragments have a maximum width of 1 cm and a maximum length of 2 cm.

10. The method of claim 8 wherein ink is recovered from the toluene.

11. The method of claim 8 wherein pure aluminum metal is separated from the aqueous solution of formic acid by filtering the pure aluminum metal from the aqueous solution of formic acid utilizing density separation.

12. The method of claim 8 wherein polypropylene or polyethylene is separated from the aqueous solution of formic acid by filtering the polypropylene or polyethylene from the aqueous solution of formic acid utilizing density separation.

13. The method of claim 8 wherein pure aluminum metal is separated from the aqueous solution of formic acid by filtering the pure aluminum metal from the aqueous solution of formic acid utilizing density separation, and wherein polypropylene or polyethylene is separated from the aqueous solution of formic acid by filtering the polypropylene or polyethylene from the aqueous solution of formic acid utilizing density separation.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0013] While this invention is susceptible of embodiment in many different forms, there are shown in the drawings and will herein be described in detail, several embodiments with the understanding that the present disclosure should be considered as an exemplification of the principles of the invention and is not intended to limit the invention to the embodiments so illustrated. Further, to the extent that any numerical values or other specifics of materials, etc., are provided herein, they are to be construed as exemplifications of the inventions herein, and the inventions are not to be considered as limited thereto.

[0014] The following description and drawings are illustrative and are not to be construed as limiting. Numerous specific details are described to provide a thorough understanding of the disclosure. However, in certain instances, well-known or conventional details are not described in order to avoid obscuring the description. References to one, or an embodiment in the present disclosure, can be, but not necessarily, references to the same embodiment; and, such references mean at least one of the embodiments.

[0015] Reference in this specification to “one embodiment’ or “an embodiment” means that a particular feature, structure, or characteristic described in connection with the embodiment is included in at least one embodiment of the disclosure. The appearances of the phrase “in one embodiment” in various places in the specification are not necessarily all referring to the same embodiment, nor are separate or alternative embodiments mutually exclusive of other embodiments. Moreover, various features are described which may be exhibited by some embodiments and not by others. Similarly, various requirements are described which may be requirements for some embodiments, but not other embodiments.

[0016] The terms used in this specification generally have their ordinary meanings in the art, within the context of the disclosure, and in the specific context where each term is used. Certain terms that are used to describe the disclosure are discussed below, or elsewhere in the specification, to provide additional guidance to the practitioner regarding the description of the disclosure. For convenience, certain terms may be highlighted, for example using italics and/or quotation marks. The use of highlighting has no influence on the scope and meaning of a term; the scope and meaning of a term is the same, in the same context, whether or not it is highlighted. It will be appreciated that the same term can be said in more than one way.

[0017] Consequently, alternative language and synonyms may be used for any one or more of the terms discussed herein, or is any special significance to be placed upon whether or not a term is elaborated or discussed herein. Synonyms for certain terms are provided. A recital of one or more synonyms does not exclude the use of other synonyms. The use of examples anywhere in this specification, including examples of any terms discussed herein, is illustrative only, and in no way limits the scope and meaning of the disclosure or of any exemplified term. Likewise, the disclosure is not limited to various embodiments given in this specification.

[0018] Unless otherwise defined, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this disclosure pertains. In the case of conflict, the present document, including definitions will control.

[0019] Today's plastic packaging films are most often multilayered films that combine the properties of two or more materials. The combination of different polymer layers lowers the gas and vapor permeability, reduces cost, and improves the mechanical properties of the packaging film, such as puncture and tear resistance. However, often dissimilar materials, when coextruded to a multilayer film, do not adhere well to each other. To improve adhesion between poorly adhering layers, special adhesive polymers or tie resins, also called tie layers, have been developed. These resins are typically polyethylene copolymers of polar and non-polar repeat units and with or without functional reactive groups.

[0020] FIG. 1 depicts a mid-sectional view of an exemplary multilayered package. Inner layer 2 is the innermost plastic layer and may be composed of polypropylene (PP) or polyethylene (PE), or a similar material. Metal layer 4 may be vacuum deposited onto inner layer 2. Metal layer 4 may be aluminum. Metal layer 4 may be adhered to outer layer 8 via tie layer 6. Outer layer 8 may be composed of plastic such as polyethylene terephthalate (PET) or similar material. Outer layer 8 may be printed with advertising or content material. Tie layer 6 may be composed of a resin that serves as an adhesive to attach outer layer 8 to metal layer 4. Tie layer 6 may include ethylene vinyl acetate (EVA) and ethylene methyl acrylate (EMA), acid modified olefin copolymers like ethylene acrylic acid (EAA) and ethylene methacrylic acid (EMAA). Tie layers are typically considered non-reactive because none or only a small portion of the acid groups undergo chemical reactions. Tie layer resins provide adhesion to many polar polymers because they form strong hydrogen and polar bonds with many polar polymers utilized in multilayered food packaging.

[0021] A bottom, angled view of FIG. 1 with the layers separated from each other is shown in FIG. 2. Inner layer 2 is placed next to metal layer 4, which is shown layered next to tie layer 6, which is coupled to outer layer 8. Tie layer 6 is a chemical layer, wherein inner layer 2, metal layer 4, and outer layer 8 are structural layers.

[0022] This process significantly reduces the processing time from hours to minutes and increases the efficiency of processing allowing recycling to be conducted as a flow process rather than a batch process, which is the current method employed. FIG. 3 is a flow chart depicting the process disclosed herein.

[0023] Waste food multilayered packaging enters shredder 20 where it is mechanically shredded into small pieces (e.g. 1 cm×2 cm). Shredder 20 may be a conventional shredder. Once waste food multilayer packaging is shredded, it is pumped via pump 22 through a tube into formic acid reactor 24. Pump 22 may be a peristaltic pump or similar means that forces the shredded pieces of packaging through a tube into formic acid reactor 24. Formic acid reactor 24 may contain an aqueous solution of formic acid diluted to a final concentration of 5% to 100% formic acid in solution. The temperature of formic acid reactor 24 may be maintained from 25° C. to 75° C. Generally, an increase in the temperature maintained within formic acid reactor 24 causes an increase in the rate at which metal layer 4 is separated from inner layer 2 and tie layer 6. And, an increase in the reactor temperature causes an increase in the efficiency of separation achieved. The increases in rate of reaction and efficiency of reaction can be exponential.

[0024] Formic acid reactor 24 may include one or more ultrasonic horns or other sources of ultrasonic waves. Ultrasonic energy may be utilized within the reactor to catalyze the separation of metal layer 4 from outer layer 8 and inner layer 2 via cavitation. The size of the ultrasonic horn employed to maximize the cavitation zone within formic acid reactor 24 may vary based on the size of the reactor used. Generally, an increase in wattage in the ultrasonic horn creates an increase in effectiveness of formic acid reactor 24.

[0025] The ultrasound waves causes an increase in the rate of reaction within formic acid reactor 24. Also, ultrasonic waves provide mechanical vibration that physically masticates the shredded food multilayered packaging causing metal layer 4 to flake into pieces separating bits of metal layer 4 from the other layers. Metal layer 4 flakes may tend to precipitate onto the bottom of formic acid reactor 24, while bits of inner layer 2 and outer layer 8 may rise and float. At density separator 40, flakes of metal layer 4 may be separated from the aqueous solution and recycled. Density separator 40 may include vacuum filtration. Aqueous solution containing formic acid may be returned to pump 22 via return pump 42, and pumped from pump 22 to formic acid reactor 24. Formic acid solution may be cycled through formic acid reactor 24 multiple times. Some embodiments may allow for recycling of formic acid solution through formic reactor 24 up to five times.

[0026] Generally, an increase in wattage in the ultrasound horn creates an increase in effectiveness for formic acid reactor 24. Ultrasound may be applied at formic acid reactor 24 to enhance the rate of reaction within the reactor. The size of the ultrasonic horn needed to maintain the cavitation zone will depend on the size of the formic acid reactor employed. A typical ultrasound power of 225 watts may be utilized in a standard reactor.

[0027] Bits of inner layer 2 and outer layer 8 may be transferred from formic acid reactor 24 to density separator 26 via transfer of aqueous solution from formic acid reactor 24. At density separator 26, the PP/PE plastic layer is separated from the PET plastic layer via density separation. PET has a significantly different density than PP/PE plastic and separates via density. The recovered PP/PE may be melted into new plastic products.

[0028] Once PP/PE is recovered at density separator 26, the remaining aqueous solution may be transferred to toluene reactor 28. At toluene reactor 28, the solution may be subjected to toluene for a sufficient amount of time, typically five to fifteen minutes, at a temperature that may be not less than 25° C. and not more than 75° C. Additionally, an increase in the temperature maintained within toluene reactor 28, increases the rate that the ink is converted into a particulate reducing the processing time necessary. The effect of temperature on the rate and efficiency of separation can be exponential, and the greatest decrease in processing time may be seen when increasing the reactor temperature from 25° C. to 35° C.

[0029] Generally, an increase in wattage in the ultrasonic horn creates an increase in effectiveness of toluene reactor 28. Ultrasound may be applied at toluene reactor 28 to enhance the rate of reaction within the reactor. The size of the ultrasonic horn needed to maintain the cavitation zone will depend on the size of the reactor employed. A typical ultrasound power of 225 watts may be utilized in a standard toluene reactor. Any ink utilized on outer layer 8 will be converted to particulate form at toluene reactor 28. Ink particulate may be removed via gravity filtration and recycled. PET may be removed from toluene reactor 28 after processing, and recycled.