Component for a timepiece movement

Abstract

The invention relates to a pivot arbor (1) for a timepiece movement comprising at least one pivot (3) made of a first non-magnetic metal material (4) at one of the ends thereof in order to limit the sensitivity thereof to magnetic fields. At least the outer surface of said pivot (3) is coated with a layer (5) of a second material selected from the group comprising Ni and NiP, and preferably chemical NiP. The invention concerns the field of timepiece movements.

Claims

1. A pivot arbor, comprising a pivot made of a first non-magnetic metal material at an end thereof, wherein at least the outer surface of the pivot is coated with a layer of a second material, wherein the second material is NiP, and wherein a sub-laver of gold and/or a sub-layer of electroplated nickel is disposed underneath the layer of the second material.

2. The pivot arbor according to claim 1, wherein the second material is chemical NiP.

3. The pivot arbor according to claim 1, wherein the pivot arbor is made of the first non-magnetic metal material, and wherein the outer surface thereof is coated with a layer of the second material.

4. The pivot arbor according to claim 3, wherein the second material is chemical NiP.

5. The pivot arbor according to claim 1, wherein the first non-magnetic metal material is selected from the group consisting of an austenitic steel, an austenitic cobalt alloy, an austenitic nickel alloy, a titanium alloy, an aluminium alloy, a copper and zinc-based brass, a copper-beryllium, a nickel silver, a bronze, an aluminium bronze, a copper-aluminium, a copper-nickel, a copper-nickel-tin, a copper-nickel-silicon, a copper-nickel-phosphorus, and a copper-titanium.

6. The pivot arbor according to claim 1, wherein the first non-magnetic metal material has a hardness of less than 600 HV.

7. The pivot arbor according to claim 1, wherein the layer of the second material has a thickness comprised between 0.5 μm and 10 μm.

8. The pivot arbor according to claim 7, wherein the layer of the second material has a thickness comprised between 1 μm and 5 μm.

9. The pivot arbor according to claim 8, wherein the layer of the second material has a thickness comprised between 1 μm and 2 μm.

10. The pivot arbor according to claim 1, wherein the layer of the second material has a hardness of more than 400 HV.

11. The pivot arbor according to claim 10, wherein the layer of the second material has a hardness of more than 500 HV.

12. The pivot arbor according to claim 1, wherein the first non-magnetic metal material is a copper-beryllium alloy and wherein the layer of the second material is a chemical NiP layer.

13. The pivot arbor according to claim 1, wherein the first non-magnetic metal material is a copper-nickel-tin alloy and wherein the layer of the second material is a chemical NiP layer.

14. The pivot arbor according to claim 1, wherein the first non-magnetic metal material is a stainless steel and wherein the layer of the second material is a chemical NiP layer.

15. The pivot arbor according to claim 1, wherein the layer of the second material is an outer layer.

16. A movement, comprising a pivot arbor comprising a pivot made of a first non-magnetic metal material at an end thereof, wherein at least the outer surface of the pivot is coated with a layer of a second material, wherein the second material is NiP, and wherein a sub-laver of gold and/or a sub-laver of electroplated nickel is disposed underneath the layer of the second material.

17. The movement according to claim 16, wherein the second material is chemical NiP.

18. The movement according to claim 16, wherein the layer of the second material is an outer layer.

19. A movement, comprising a balance staff, a pallet staff and/or an escape pinion comprising a pivot arbor comprising a pivot made of a first non-magnetic metal material at an end thereof, wherein at least the outer surface of the pivot is coated with a layer of a second material, wherein the second material is NiP, and wherein a sub-laver of gold and/or a sub-laver of electroplated nickel is disposed underneath the layer of the second material.

20. The movement according to claim 19, wherein the second material is chemical NiP.

21. The movement according to claim 19, wherein the layer of the second material is an outer layer.

22. A method for fabricating a pivot arbor, the method comprising: a) forming a pivot arbor comprising a pivot made of a first non-magnetic metal material at an end thereof; b) disposing a layer of cold and/or a layer of electroplated nickel on at least the outer surface of the pivot and/or a layer disposed on the outer surface of the pivot; and c) depositing a layer of a second material on at least the layer of gold, the layer of electroplated nickel and/or a layer disposed on the layer of gold and/or the layer of electroplated nickel, wherein the second material is NiP.

23. The method according to claim 22, wherein the layer of the second material has a thickness comprised between 0.5 μm and 10 μm.

24. The method according to claim 23, wherein the layer of the second material has a thickness comprised between 1 μm and 5 μm.

25. The method according to claim 24, wherein the layer of the second material has a thickness comprised between 1 μm and 2 μm.

26. The method according to claim 22, wherein c) is achieved by a method selected from the group consisting of PVD, CVD, ALD, electroplating and chemical deposition.

27. The method according to claim 26, wherein c) is achieved by a process of chemical nickel deposition from hypophosphite.

28. The method according to claim 22, wherein the method further comprises, after c), d) heat treating the layer of the second material.

29. The method according to claim 22, wherein the layer of the second material is an outer layer.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) Other features and advantages will appear clearly from the following description, given by way of non-limiting illustration, with reference to the annexed drawings, in which:

(2) FIG. 1 is a representation of a pivot arbor according to the invention.

(3) FIG. 2 is a partial cross-section of a balance staff pivot according to the invention.

(4) FIG. 3 is a photograph of an untreated high interstitial steel (HIS) pivot arbor that has been subjected to a shock programme.

(5) FIG. 4 is a photograph of an HIS pivot arbor coated with a NiP layer according to the invention that has been subjected to the same shock programme as the pivot arbor of FIG. 3.

DETAILED DESCRIPTION OF PREFERRED EMBODIMENTS

(6) In the present description, the term “non-magnetic” means a paramagnetic or diamagnetic or antiferromagnetic material, whose magnetic permeability is less than or equal to 1.01.

(7) An alloy of an element is an alloy containing at least 50 wt % of said element.

(8) The invention relates to a component for a timepiece movement and particularly to a non-magnetic pivot arbor for a mechanical timepiece movement.

(9) The invention will be described below with reference to an application to a non-magnetic balance staff 1. Of course, other types of timepiece pivot arbors may be envisaged such as, for example, timepiece wheel set arbors, typically escape pinions or pallet staffs. Components of this type have a body with a diameter preferably less than 2 mm, and pivots with a diameter preferably less than 0.2 mm, with a precision of several microns.

(10) Referring to FIG. 1, there is shown a balance staff 1 according to the invention, which comprises a plurality of sections 2 of different diameters, preferably formed by bar turning or any other chip removal machining technique, and defining, in a conventional manner, bearing surfaces 2a and shoulders 2b arranged between two end portions defining two pivots 3. These pivots are each intended to pivot in a bearing typically in an orifice in a jewel or ruby.

(11) With the magnetism induced by objects that are encountered on a daily basis, it is important to limit the sensitivity of balance staff 1 to avoid affecting the working of the timepiece in which it is incorporated.

(12) Thus, pivot 3 is made of a first a non-magnetic metal material 4 so as to advantageously limit its sensitivity to magnetic fields.

(13) Preferably, the first non-magnetic metal material 4 is selected from the group comprising an austenitic, preferably stainless steel, an austenitic cobalt alloy, an austenitic nickel alloy, a non-magnetic titanium alloy, a non-magnetic aluminium alloy, a brass (Cu—Zn) or a special brass (Cu—Zn with Al and/or Si and/or Mn), a copper-beryllium, a bronze (Cu—Sn), an aluminium bronze, a copper-aluminium (optionally comprising Ni and/or Fe), a copper-nickel, a nickel silver (Cu—Ni—Zn), a copper-nickel-tin, a copper-nickel-silicon, a copper-nickel-phosphorus, a copper-titanium, wherein the proportions of the various alloying elements are chosen to give the alloys both non-magnetic properties and good machinability.

(14) For example, the austenitic steel is a high interstitial stainless austenitic steel such as Cr—Mn—N P2000 steel from Energietechnik Essen GmbH.

(15) The austenitic cobalt alloy may contain at least 39% of cobalt, typically an alloy known under the name of “Phynox” or the reference DIN K13C20N16Fe15D7, typically having 39% of Co, 19% of Cr, 15% of Ni and 6% of Mo, 1.5% of Mn, 18% of Fe and the remainder is additives.

(16) The austenitic nickel alloy may contain at least 33% of nickel, typically an alloy known under the reference MP35N® typically having 35% of Ni, 20% of Cr, 10% of Mo, 33% of Co and the remainder is additives.

(17) The titanium alloy preferably contains at least 85% of titanium.

(18) The brasses may comprise the alloys CuZn39Pb3, CuZn37Pb2 or CuZn37.

(19) The special brasses may comprise the alloys CuZn37Mn3Al2PbSi, CuZn23Al3Co or CuZn23Al6Mn4Fe3Pb.

(20) The nickel silver may comprise the alloys CuNi25Zn11Pb1Mn, CuNi7Zn39Pb3Mn2 or CuNi18Zn19Pb1.

(21) The bronzes may comprise the alloys CuSn9 or CuSn6.

(22) The aluminium bronzes may comprise the alloys CuAl9 or CuAl9Fe5Ni5.

(23) The copper-nickel alloys may comprise the alloy CuNi30.

(24) The copper-nickel-tin alloys may comprise the alloys CuNi15Sn8, CuNi9Sn6 or CuNi7.5Sn5 (marketed, for example, under the name Declafor).

(25) The copper-titanium alloys may comprise the alloy CuTi3Fe.

(26) The copper-nickel-silicon alloys may comprise the alloy CuNi3Si.

(27) The copper-nickel-phosphorus alloys may comprise the alloy CuNi1P.

(28) The copper-beryllium alloys may comprise the alloys CuBe2Pb or CuBe2.

(29) The composition values are given in mass percent. The elements with no indication of composition value are either the remainder (majority) or elements whose percentage in the composition is less than 1 wt %.

(30) The non-magnetic copper alloy may also be an alloy having a mass percent composition of between 14.5% and 15.5% of Ni, between 7.5% and 8.5% of Sn, at most 0.02% of Pb and the remainder is Cu. Such an alloy is marketed under the trademark ToughMet® by Materion.

(31) Of course, other non-magnetic alloys may be envisaged, provided the proportion of their constituents confers both non-magnetic properties and good machinability.

(32) The first non-magnetic metal material generally has a hardness of less than 600 HV.

(33) According to the invention, at least the outer surface of said pivot 3 is coated with a layer 5 of a second material selected from the group comprising Ni and NiP, in order advantageously to offer mechanical properties in said outer surface making it possible to obtain the required shock resistance.

(34) In the second material, the phosphorus content may preferably be comprised between 0% (in which case there is pure Ni) and 15%. Preferably, the level of phosphorus in the second NiP material may be a medium level comprised between 6% and 9%, or a high level comprised between 9% and 12%. It is quite clear however that the second NiP material may have a low phosphorus content.

(35) Furthermore, when the second material is NiP with a medium or high level of phosphorus, the layer of second NiP material may be hardened by heat treatment.

(36) The layer of second material preferably has a hardness of more than 400 HV, more preferentially more than 500 HV.

(37) In a particularly advantageous manner, the layer of the second, non-hardened Ni or NiP material preferably has a hardness higher than 500 HV, but lower than 600 HV, i.e. preferably comprised between 500 HV and 550 HV. In a surprising and unexpected manner, the pivot arbor according to the invention has excellent shock resistance although the layer of second material may have a lower hardness (HV) than that of the first material.

(38) When hardened by heat treatment, the layer of second NiP material may have a hardness comprised between 900 HV and 1000 HV.

(39) Advantageously, the layer of second material may have a thickness comprised between 0.5 μm and 10 μm, preferably between 1 μm and 5 μm, and more preferentially between 1 μm and 2 μm.

(40) Preferably, the layer of second material is a NiP layer, and more particularly a layer of chemical NiP, i.e. deposited by chemical deposition.

(41) Combinations associating the following are particularly preferred:

(42) a copper-beryllium alloy, and more particularly CuBe2Pb, as the first non-magnetic metal material and a chemical NiP layer as second material layer 5.

(43) a copper-nickel-tin alloy, and more particularly Declafor or ToughMet®, as the first non-magnetic metal material and a chemical NiP layer as second material layer 5

(44) a stainless steel, and more particularly a high interstitial stainless steel, as the first non-magnetic metal material and a chemical NIP layer as second material layer 5.

(45) Consequently, at least the outer surface area of the pivot is hardened, i.e. the rest of the arbor may remain little modified or unmodified without any significant change in the mechanical properties of balance staff 1. This selective hardening of pivots 3 of balance staff 1 makes it possible to combine advantages like low sensitivity to magnetic fields and mechanical properties allowing a very good shock resistance to be obtained, in the main stress areas.

(46) In order to improve the resistance of the layer of second material, the pivot arbor may comprise at least one adhesion sub-layer deposited between the first material and the layer of second material. For example, particularly in the case of a pivot arbor made of high interstitial stainless steel, a sub-layer of gold and/or a sub-layer of electroplated nickel may be provided underneath the layer of second material.

(47) The invention also relates to the method of manufacturing a balance staff as explained above. The method of the invention advantageously comprises the following steps:

(48) a) forming, preferably by bar turning or any other chip removal machining technique, a balance staff 1 comprising at least one pivot 3 made of a first non-magnetic metal material at each of its ends, to limit its sensitivity to magnetic fields; and

(49) b) depositing a layer 5 of a second material on at least the outer surface of said pivot 3, said second material being selected from the group comprising Ni and NiP in order to improve the mechanical properties of the pivots to obtain a suitable shock resistance at least in the main stress areas.

(50) Preferably, layer 5 of second material is deposited in step b) to exhibit a thickness comprised between 0.5 μm and 10 μm, preferably between 1 μm and 5 μm, and more preferentially between 1 μm and 2 μm.

(51) Advantageously, step b) of depositing layer 5 of second material may be achieved by a method selected from the group comprising PVD, CVD, ALD, electroplating and chemical deposition, and preferably chemical deposition.

(52) According to a particularly preferred embodiment, the second material is NiP and the step of depositing NiP layer 5 is produced by a process of chemical nickel deposition from hypophosphite.

(53) The various parameters to be taken into account for chemical nickel deposition from hypophosphite, such as the level of phosphorus in the deposition, the pH, the temperature, or the nickel bath composition, are known to those skilled in the art. Reference will be made, for example, to the publication of Y. Ben Amor et al., Dépôt chimique de nickel, synthèse bibliographique, Matériaux & Techniques 102, 101 (2014). However, it will be specified that commercial baths with a medium (6-9%) or high (9-12%) phosphorus level are preferably used. It is quite clear however that low phosphorus content or pure nickel baths can also be used.

(54) When the second material is NiP, preferably with a medium or high phosphorus content, the method according to the invention may also comprise, after deposition step b), a heat treatment step c) on layer 5 of second material. Such a heat treatment makes it possible to obtain a layer 5 of second material having a hardness preferably comprised between 900 HV and 1000 HV.

(55) The chemical nickel deposition method is particularly advantageous in that it makes it possible to obtain a suitable deposition without a peak effect. It is therefore possible to anticipate the dimension of the bar turned pivot arbor to obtain the desired geometry after coating with the layer of second material.

(56) The chemical nickel deposition method also has the advantage of being capable of being applied in bulk.

(57) In order to improve the resistance of the layer of second material, the method according to the invention may also comprise, before deposition step b), a step d) of applying at least one adhesion sub-layer on the first material. For example, particularly in the case of a pivot arbor made of high interstitial stainless steel, it is possible to apply a gold sub-layer and/or an electroplated nickel sub-layer before the chemical nickel deposition.

(58) The pivot arbor according to the invention may comprise pivots treated in accordance with the invention by applying step b) only to the pivots or be made entirely of a first non-magnetic metal material, its outer surface may be entirely coated with a layer of second material by applying step b) over all the surfaces of the pivot arbor,

(59) In a known manner, pivots 3 may be rolled or polished before or after deposition step b), to attain the dimensions and final surface finish required for pivots 3.

(60) The pivot arbor according to the invention combines the advantages of low sensitivity to magnetic fields, and at least in the main stress areas, excellent resistance to shocks. Hence, in the event of a shock, the pivot arbor according to the invention does not exhibit any marks or any severe damage liable to impair the chronometry of the movement.

(61) The following examples illustrate the present invention without thereby limiting its scope.

(62) Pivot arbors made of HIS are produced in a known manner. The untreated arbors have a hardness of 600 HV.

(63) A batch of these pivot arbors is treated according to the method of the invention, the pivot arbors being coated with a NiP layer of thickness equal to 1.5 μm obtained from a commercial chemical nickel plating bath from hypophosphite

(64) These pivot arbors according to the invention have a hardness of 500 HV.

(65) All the pivot arbors are subjected to the same standard shock programme for horology. The untreated arbors, without a NiP layer, are marked, as shown in FIG. 3. The arbors coated with a NiP layer according to the invention are intact, as shown in FIG. 4. The pivot arbors according to the invention combine the advantages of low sensitivity to magnetic fields and excellent resistance to shocks.