Testing method for evaluating the effect of CO2 reaction rate of acid rock plate

Abstract

The invention discloses a testing device and method for evaluating effects of CO.sub.2 reaction rate of acid rock plate. The testing device includes an acid fluid conveying unit, a CO.sub.2 conveying unit, a mixing tank, a plate holder, a recycling fluid tank, and a vacuum pump. The mixing tank includes an acid fluid inlet, a CO.sub.2 inlet, and a miscible fluid outlet. The acid fluid inlet is connected with the acid fluid conveying unit, the CO.sub.2 inlet is connected with the CO.sub.2 conveying unit, the miscible fluid outlet is connected with the plate holder, the plate holder is connected with the recycling fluid tank, and the recycling fluid tank is connected to the vacuum pump. The CO.sub.2 conveying unit includes a CO.sub.2 cylinder and a gas booster pump which is connected to the cylinder. The outlet of the pump is connected to the gas inlet of the mixing tank.

Claims

1. A testing method for evaluating effects of CO.sub.2 reaction rate of an acid rock plate, comprising the following steps: step 1: installing a plate holder and a testing device to ensure an air tight sealing of the testing device; the testing device comprising an acid fluid conveying unit, a CO.sub.2 conveying unit, a mixing tank, the plate holder, a recycling fluid tank, and a vacuum pump; wherein the mixing tank comprises an acid fluid inlet, a CO.sub.2 inlet, and a miscible fluid outlet; the acid fluid inlet is connected with the acid fluid conveying unit, the CO.sub.2 inlet is connected with the CO.sub.2 conveying unit, the miscible fluid outlet is connected with the plate holder, the plate holder is connected with the recycling fluid tank, and the recycling fluid tank is connected to the vacuum pump; wherein the CO.sub.2 conveying unit comprises a CO.sub.2 cylinder and a gas booster pump which is connected to the cylinder; a gas flowmeter and a pressure sensor are fixed on a pipe connected from the CO.sub.2 cylinder to the gas booster pump; an outlet of the gas booster pump is connected to the CO.sub.2 inlet of the mixing tank; wherein the mixing tank is sealed in such way that an external surface of the mixing tank is wrapped with a heating jacket, and a temperature sensor and a pressure sensor are provided inside the tank; the miscible fluid outlet of the mixing tank is connected to a fluid flowmeter, a plunger pump and the plate holder in order; a fluid outlet of the plate holder is successively connected with a back pressure valve and a recycling fluid tank; a pipe connected between the mixing tank and the plate holder is externally wrapped with an insulation layer; the recycling fluid tank is internally provided with an electromagnetic level gauge and a pressure sensor; a pressure of the gas booster pump and a temperature in the mixing tank are controlled to make the pressure and temperature in the mixing tank reach to a critical pressure and a critical temperature of supercritical CO.sub.2 to obtain supercritical CO.sub.2, and the obtained miscible fluid is the mixture of supercritical CO.sub.2 and acid fluid; step 2: turning on the vacuum pump to ensure that the whole testing device is completely vacuum in operation, and turning off the vacuum pump and zeroing the pressure gauge; step 3: using the gas booster pump to inject gaseous CO.sub.2 into the mixing tank with a certain displacement, recording the readings of the pressure sensor and the gas flowmeter, using the plunger pump to inject hydrochloric acid into the mixing tank with a certain displacement, controlling the pressure and temperature in the mixing tank to reach to the supercritical pressure and temperature of CO.sub.2, and uniformly mixing the supercritical CO.sub.2 and the acid fluid to obtain the miscible fluid; step 4: after the temperature of the mixing tank is stable, setting the outlet back pressure, pumping the miscible fluid with the plunger pump into the plate holder to enable acid rock reaction, recording the volume of CO.sub.2 in the recycling fluid tank at any time, and finally calculating the reaction rate of the acid rock at any time with the following formula: $J=\frac{2Q\left(P_j{V}_j-P_a{V}_a{\omega }_j\right)}{{\mathrm{APV}}_m{V}_{\mathrm{HCl}}}.Math.{10}^{-3};$ where, J refers to a reaction rate of acid rock mol/s.Math.cm.sup.2; Q refers to acid injection rate, in cm.sup.3/s; V.sub.j refers to the volume of CO.sub.2 in the recycling fluid tank at any time, in L, j=1, 2, . . . ; P.sub.j refers to the pressure of the recycling fluid tank at any time, in Pa, j=1, 2, . . . ; P.sub.a refers to the pressure for injecting CO.sub.2 into the CO.sub.2 cylinder, in Pa; V.sub.a refers to the volume of CO.sub.2 injected in the CO.sub.2 cylinder, in L; ω.sub.j refers to the percentage of pumped miscible fluid at any time; A refers to the reaction area of acid rock, in cm.sup.2; P refers to the pressure under standard conditions, with a constant of 1.013×10.sup.5 in Pa; V.sub.m refers to the molar volume of gas under standard conditions, with a constant of 24.5, in L/mol; V.sub.HCl refers to the volume of acid participating in the reaction at any time, in L.

2. The testing method for evaluating effects of CO.sub.2 reaction rate of an acid rock plate according to claim 1, wherein a derivation of the calculation formula of the reaction rate of the acid rock is as follows: according to the Boyle-Mariotte law PV.sub.b=P.sub.aV.sub.a, under a standard condition of 25° C. and 1.013×10.sup.5Pa the volume of CO.sub.2 injected into the cylinder is: $\begin{array}{cc}{V}_b=\frac{P_a{V}_a}{P};& \left(1\right)\end{array}$ a standard volume of CO.sub.2 in the recycling fluid tank in any time is: $\begin{array}{cc}{V}_j^{\prime }=\frac{P_j{V}_j}{P};& \left(2\right)\end{array}$ a percentage of pumped miscible fluid at any time is: $\begin{array}{cc}{\omega }_j=\frac{V_c}{V_o};& \left(3\right)\end{array}$ a standard volume of co-injected CO.sub.2 participating in the reaction at any time is:
V.sub.d=V.sub.bω.sub.j   (4). a standard volume of CO2 produced by acid rock reaction at any time is:
V.sub.e=V′.sub.j−V.sub.d   (.sup.5). an amount of substance of CO2 produced by acid rock reaction at any time is: $\begin{array}{cc}{n}_{{\mathrm{CO}}_2}^j=\frac{V_e}{V_m};& \left(6\right)\end{array}$ according to the stoichiometric formula of acid rock reaction 2HCl.fwdarw.CO.sub.2↑, an amount of substance of acid participating in the reaction at any time is:
n.sub.HCl.sup.j=2n.sub.CO.sub.2.sup.j   (.sup.7). an acid concentration after reaction at any time is: $\begin{array}{cc}{C}_j=\frac{{\mathrm{CV}}_{\mathrm{HCl}}-n_{\mathrm{HCl}}^j}{V_{\mathrm{HCl}}};& \left(8\right)\end{array}$ the reaction rate of the acid rock is: $\begin{array}{cc}J=-\frac{Q}{A}.Math.\left(C_j-C\right).Math.{10}^{-3};& \left(9\right)\end{array}$ substitute Formulas (1), (2), (3), (4), (5), (6), (7) and (8) into Formula (9) gives the calculation formula of acid rock reaction rate: $J=\frac{2Q\left(P_j{V}_j-P_a{V}_a{\omega }_j\right)}{{\mathrm{APV}}_m{V}_{\mathrm{HCl}}}.Math.{10}^{-3};$ where, P refers to the pressure under standard conditions, with a constant of 1.013×10.sup.5 Pa; P.sub.a refers to refers to the pressure for injecting CO.sub.2 into the CO.sub.2 cylinder Pa; P.sub.j refers to the pressure of the recycling fluid tank at any time, in Pa, j=1, 2, . . . ; V.sub.a refers to the volume of CO.sub.2 injected in the cylinder, in L; V .sub.b refers to the standard volume of CO.sub.2 injected in the cylinder, in L; V.sub.c refers to the volume of miscible fluid injected, in L ; V.sub.d refers to the standard volume of co-injected CO.sub.2 participating in the reaction at any time, in L; V.sub.c refers to the standard volume of CO.sub.2 produced by acid rock reaction at any time, in L; refers to the volume of CO.sub.2 in the recycling fluid tank at any time, in L, j=1, 2, . . . ; V.sub.j refers to the standard volume of CO.sub.2 in the recycling fluid tank in any time, in L, j=1, 2, . . . ; V.sub.o refers to the volume of the mixing tank, in L; n.sub.CO.sub.2.sup.j refers to the amount of substance of CO.sub.2 produced by acid rock reaction at any time, in .sup.mol; V.sub.m refers to the molar volume of gas under standard conditions, with a constant of 24.5, in L/mol; n.sub.HCl.sup.j refers to the amount of substance of acid participating in the reaction at any time, in mol; C refers to the acid concentration before reaction, in mol/L; V.sub.HCl refers to the volume of acid participating in the reaction at any time, in L; C.sub.j refers to the acid concentration after reaction at any time, in mol/L; Q refers to the acid injection rate, in cm.sup.3/s; A refers to the reaction area of acid rock, in cm.sup.2; J refers to the reaction rate of the acid rock, in mol/s.Math.cm.sup.2.

3. The testing method for evaluating effects of CO.sub.2 reaction rate of an acid rock plate according to claim 1, wherein in step 1, the plate holder is installed in such a way that one rock plate is overlapped on a second rock plate, the gap between the rock plates is simulated as the fracture, the two sides of the rock plate along the direction of fluid flow are attached with anti-corrosion rubber, the outer side of the rubber is covered with steel plate and placed in the inner cavity of the plate holder, and the steel plate is fixed with fastening screws onto the side of the plate holder opposite to the steel plate.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) Aspects of the present invention are best understood from the following detailed description when read with the accompanying figures. It is noted that, in accordance with the standard practice in the industry, various features are not drawn to scale. In fact, the dimensions of the various features may be arbitrarily increased or reduced for clarity of discussion.

(2) FIG. 1 is a schematic diagram of a structure of a testing device for evaluating effects of CO.sub.2 reaction rate of acid rock plate of the present invention.

(3) FIG. 2 is a front view of the plate holder.

(4) FIG. 3 is a top view of the plate holder shown in FIG. 2 after it is cut along A-A horizontal section.

DESCRIPTION OF THE PREFERRED EMBODIMENTS

(5) In the following detailed description of the preferred embodiments of the present invention, reference is made to the accompanying drawings. It is to be understood that the preferred embodiments described herein are only used to illustrate and interpret the present invention and are not intended to limit the present invention.

(6) As shown in FIG. 1, the testing device for evaluating effects of CO.sub.2 reaction rate of acid rock plate provided by the present invention comprises an acid fluid conveying unit, a CO.sub.2 conveying unit, a mixing tank 5, a plate holder 12, a recycling fluid tank 14, and a vacuum pump 17. The mixing tank 5 is provided with an acid fluid inlet, a CO.sub.2 inlet, and a miscible fluid outlet. The acid fluid inlet is connected with the acid fluid conveying unit, the CO.sub.2 inlet is connected with the CO.sub.2 conveying unit, the miscible fluid outlet is connected with the plate holder 12, the plate holder is successively connected with a back pressure valve 13 and a recycling fluid tank 14, and the recycling fluid tank is connected to the vacuum pump 17.

(7) The CO.sub.2 conveying unit comprises a CO.sub.2 cylinder 1 and a gas booster pump 2 which is connected to the cylinder. A gas flowmeter 3 and a pressure sensor 4 are fixed on the pipe connected from the CO.sub.2 cylinder to the gas booster pump. The outlet of the gas booster pump is connected to the gas inlet of the mixing tank 5. A valve switch is provided on the pipe between the gas booster pump and the mixing tank.

(8) The acid fluid conveying unit includes an acid fluid tank 6 and a plunger pump 7 through which the acid fluid in the acid fluid tank is pumped into the mixing tank 5. A valve switch is provided on the pipe between the plunger pump and the mixing tank.

(9) The mixing tank 5 is sealed and the externally wrapped with a heating jacket (not shown). The heating jacket is preferably a thermostatic water bath heating jacket to heat the fluid in the tank. A temperature sensor 8 and a pressure sensor 9 are provided in the tank. The miscible fluid outlet of the mixing tank is connected to a fluid flowmeter 10, a plunger pump 11 and a plate holder 12 in order. A valve switch is provided on the pipe between the mixing tank 5 and the fluid flowmeter 10. The fluid outlet of the plate holder is successively connected with a back pressure valve 13 and a recycling fluid tank 14. The pipe connected between the mixing tank and the plate holder is externally wrapped with an insulation layer 25 made of polyurethane. The recycling fluid tank 14 is internally provided with an electromagnetic level gauge 15 and a pressure sensor 16. The pressure of the gas booster pump and the temperature in the mixing tank are controlled to make the pressure and temperature in the mixing tank reach to the critical pressure and temperature of supercritical CO.sub.2 to obtain supercritical CO.sub.2, and the miscible fluid obtained is the mixture of supercritical CO.sub.2 and acid fluid.

(10) As shown in FIGS. 2 and 3, the main body of the plate holder 12 is a rectangular box, the left and right ends of the box are respectively provided with a fluid inlet 18 and a fluid outlet 19, the internal flow channels 20 of the fluid inlet and fluid outlet are provided with flared guide grooves, the flared ends of the two grooves are opposite each other and facing to the interior of the plate holder, and a rock plate 21 installation cavity is arranged between the flared inlet guide groove and the flared outlet guide groove. The rock plates 21 are two identical rectangular rock plates cut from the formation rock, one plate is overlapped on the other plate, and the gap between the rock plates is simulated as the fracture. Anti-corrosion rubber 22 is attached on the opposite sides of the four sides of the plates after overlapping to seal the gap between the two plates. The gap openings of the other two opposite sides are taken as the inlet and outlet of the fluid respectively. The fluid inlet is directly connected to the flared inlet guide groove and the fluid outlet is connected to the flared outlet guide groove. The outer side of the rubber is covered with steel plate 23, the plate holder and the side opposite to the steel plate are fixed with at least four fastening screws 24, the tightness of the fastening screws can be adjusted to push the steel plate to press the rubber for sealing the sides of the rock plate. The left or the right side of the plate holder is provided with a heater hole 26 for inserting an electric heating rod.

(11) As for the testing device for evaluating effects of CO.sub.2 reaction rate of acid rock plate, its working principle for testing and calculating the reaction rate of the acid rock is as follows:

(12) According to the Boyle-Mariotte law PV.sub.b=P.sub.aV.sub.a, under the standard condition of 25° C. and 1.013×10.sup.5 Pa the volume of CO.sub.2 injected into the cylinder is:

(13) $\begin{array}{cc}{V}_b=\frac{P_a{V}_a}{P}.& \left(1\right)\end{array}$

(14) The standard volume of CO.sub.2 in the recycling fluid tank in any time is:

(15) 0$\begin{array}{cc}{V}_j^{\prime }=\frac{P_j{V}_j}{P}.& \left(2\right)\end{array}$

(16) The percentage of pumped miscible fluid at any time is:

(17) $\begin{array}{cc}{\omega }_j=\frac{V_c}{V_o}.& \left(3\right)\end{array}$

(18) The standard volume of co-injected CO.sub.2 participating in the reaction at any time is:
V.sub.d=V.sub.bω.sub.j   (4).

(19) The standard volume of CO.sub.2 produced by acid rock reaction at any time is:
V.sub.e=V′.sub.j−V.sub.d   (.sup.5).

(20) The amount of substance of CO.sub.2 produced by acid rock reaction at any time is:

(21) $\begin{array}{cc}{n}_{{\mathrm{CO}}_2}^j=\frac{V_e}{V_m}.& \left(6\right)\end{array}$

(22) According to the stoichiometric formula of acid rock reaction 2HCl.fwdarw.CO.sub.2↑, the amount of substance of acid participating in the reaction at any time is:
n.sub.HCl.sup.j=2n.sub.CO.sub.2.sup.j   (.sup.7).

(23) The acid concentration after reaction at any time is:

(24) $\begin{array}{cc}{C}_j=\frac{{\mathrm{CV}}_{\mathrm{HCl}}-n_{\mathrm{HCl}}^j}{V_{\mathrm{HCl}}}.& \left(8\right)\end{array}$

(25) The reaction rate of the acid rock is:

(26) $\begin{array}{cc}J=-\frac{Q}{A}.Math.\left(C_j-C\right).Math.{10}^{-3}.& \left(9\right)\end{array}$

(27) Substitute Formulas (1), (2), (3), (4), (5), (6), (7) and (8) into Formula (9) gives the calculation formula of acid rock reaction rate:

(28) $J=\frac{2Q\left(P_j{V}_j-P_a{V}_a{\omega }_j\right)}{{\mathrm{APV}}_m{V}_{\mathrm{HCl}}}.Math.{10}^{-3}.$

(29) Where, P refers to the pressure under standard conditions, with a constant of 1.013×10.sup.5 Pa; P.sub.a refers to refers to the pressure for injecting CO.sub.2 into the CO.sub.2 cylinder Pa; P.sub.j refers to the pressure of the recycling fluid tank at any time, in Pa, j=1, 2, . . . ; V.sub.a refers to the volume of CO.sub.2 injected in the cylinder, in L; V.sub.b refers to the standard volume of CO.sub.2 injected in the cylinder, in L; V.sub.c refers to the volume of miscible fluid injected, in L; V.sub.d refers to the standard volume of co-injected CO.sub.2 participating in the reaction at any time, in L; V.sub.e refers to the standard volume of CO.sub.2 produced by acid rock reaction at any time, in L; V.sub.j refers to the volume of CO.sub.2 in the recycling fluid tank at any time, in L, j=1, 2, . . . ; V′.sub.j refers to the standard volume of CO.sub.2 in the recycling fluid tank in any time, in L, j=1, 2, . . . ; V.sub.o refers to the volume of the mixing tank, in L; n.sub.CO.sub.2.sup.j refers to the amount of substance of CO.sub.2 produced by acid rock reaction at any time, in mol; V.sub.m refers to the molar volume of gas under standard conditions, with a constant of 24.5, in L/mol; n.sub.HCl.sup.j refers to the amount of substance of acid participating in the reaction at any time, in mol; C refers to the acid concentration before reaction, in mol/L; V.sub.HCl refers to the volume of acid participating in the reaction at any time, in L; C.sub.j refers to the acid concentration after reaction at any time, in mol/L; Q refers to the acid injection rate, in cm.sup.3/s; A refers to the reaction area of acid rock, in cm.sup.2; J refers to the reaction rate of the acid rock, in mol/s.Math.cm.sup.2.

(30) The reaction rate of acid rock is calculated according to Formula (10), so that it is necessary to conduct experiments with the testing device for evaluating the effect of CO.sub.2 on the reaction rate of acid rock plate to measure the parameters required by Formula (10), and calculate the reaction rate of the acid rock.

(31) As for the testing method for using the testing device for evaluating the effect of CO.sub.2 on the reaction rate of acid rock plate, the specific steps are as follows:

(32) Step 1: installing the plate holder and the whole testing device to ensure the air tight sealing of the whole device; wherein the plate holder is installed in such a way that the rock taken from the reservoir is cut into a pair of rock plates that are slightly smaller than the inner cavity of the plate holder, with a length of 170 to 176 mm, a width of 35 to 36 mm, and a thickness of 25±5 mm; one plate is overlapped on the other plate, the gap between the rock plates is simulated as the fracture, the two sides of the rock plate along the direction of fluid flow are attached with anti-corrosion rubber, the outer side of the rubber is covered with steel plate and placed in the inner cavity of the plate holder, and the steel plate is fixed with fastening screws onto the side of the plate holder opposite to the steel plate.

(33) Step 2: after the testing device is installed, turning on the vacuum pump to ensure that the whole testing device is completely vacuum in operation, and turning off the vacuum pump and zero the pressure gauge.

(34) Step 3: starting the gas booster pump to inject gaseous CO.sub.2 into the mixing tank with a certain displacement, recording the readings of the gas flowmeter 3 and the pressure sensor 4, using the plunger pump to inject acid fluid (hydrochloric acid) into the mixing tank with a certain displacement, recording the amount of acid fluid injected, adjusting and controlling the pressure and temperature in the mixing tank to reach to the supercritical pressure and temperature of CO.sub.2, and uniformly mixing the supercritical CO.sub.2 and the acid fluid to obtain the miscible fluid.

(35) Step 4: after the temperature of the mixing tank is stable, setting the outlet back pressure, pumping the miscible fluid with the plunger pump into the plate holder to enable acid rock reaction, recording the volume of CO.sub.2 in the recycling fluid tank, and finally calculating the reaction rate of the acid rock with the Formula (10).

(36) In another embodiment, in the testing device of the present invention, a gas booster pump, a gas flowmeter, a mixing tank, all pressure sensors and temperature sensors, a plunger pump, a fluid flowmeter, a back pressure valve, an electromagnetic level gauge, and a vacuum pump all are connected to the data acquisition and control panel, and the data acquisition and control panel is connected to the computer. During the experiment, all data was transmitted to the computer through the data acquisition and control panel. The data acquisition control panel can realize intelligent device control and experimental data acquisition, and then the computer records and analyzes the data in real time.

(37) The above are only the preferred embodiments of the present invention, and are not intended to limit the present invention in any form. Although the present invention has been disclosed as above with the preferred embodiments, it is not intended to limit the present invention. Those skilled in the art, within the scope of the technical solution of the present invention, can use the disclosed technical content to make a few changes or modify the equivalent embodiment with equivalent changes. Within the scope of the technical solution of the present invention, any simple modification, equivalent change and modification made to the above embodiments according to the technical essence of the present invention, are still regarded as a part of the technical solution of the present invention.