SYSTEM AND METHOD FOR TREATING MEDICAL SEWAGE CONTAINING SARS-CoV-2 BASED ON NANO GRAPHENE

Abstract

A system for treating medical sewage containing SARS-CoV-2 based on nano graphene, including a medical sewage collection and transportation device, primary and secondary sedimentation tanks, a filtering device, primary, secondary and tertiary graphene sterilization devices, a multiple purification tank, a photocatalytic degradation device, a SARS-CoV-2 deep purification device and a graphene water purification device including at least three stages of graphene water purification units. The disclosure also provides a method for treating the medical sewage containing the SARS-CoV-2 using the above system.

Claims

1. A system for treating a medical sewage containing SARS-CoV-2 based on nanographene, comprising: a medical sewage collection and transportation device; a primary sedimentation tank, equipped with a sodium hypochlorite generator; a secondary sedimentation tank; afiltering device; a primary graphene sterilization device; a secondary graphene sterilization device; a tertiarygraphene sterilization device; a multiple purification tank; a photocatalytic degradation device; a SARS-CoV-2 deep purification device; and a graphene water-purification device comprising at least three stages of graphene water-purification units; wherein the filtering device is provided with at least three stages of filter screens; the primary graphene sterilization device, the secondary graphene sterilization device and the tertiarygraphene sterilization device each are independently filled with a superparamagnetic nanoparticle-graphene oxide nanocomposite, a first graphene sterilant or a combination of a grapheme composite material and a sterilant; the multiple purification tank is provided with an ozone generator, a first ultraviolet generating device, a graphene based chemical oxygen demand (COD) treatment agent and a second graphene sterilant; the multiple purification tank is connected with a spray liquid storage container and an ultrasonic micro-nano bubble generator; a nozzle of the ultrasonic micro-nano bubble generator is placed in the multiple purification tank; the photocatalytic degradation device is filled with a grapheme-based photocatalytic degradation agent; the SARS-CoV-2 deep purification device is provided with a transparent casing; a second ultraviolet generating device and an irradiation device are arranged outside the transparent casing; and the graphene water-purification device is filled with a heavy metal-adsorption graphene nanocomposite, a large-specific surface area graphene nanomaterial or a graphene porous ceramic material.

2. The system of claim 1, wherein a peristaltic pump is provided at a water inlet of the SARS-CoV-2 deep purification device; at least three stages of deceleration screens are provided inside the SARS-CoV-2 deep purification device; the irradiation device is a .sup.60Co-γ irradiation device; and a dosimeter is provided outside the SARS-CoV-2 deep purification device for measuring irradiation.

3. The system of claim 2, wherein the at least three stages of filter screens consist of a primary filter screen, a secondary filter screen and a tertiary filter screen; the primary filter screen, the secondary filter screen and the tertiary filter screen increase in sequence in mesh number, and are respectively arranged at a front section, a middle section and a rear section of the filtering device along a direction of water flow.

4. The system of claim 1, wherein in the superparamagnetic nanoparticle-graphene oxide nanocomposite, a superparamagnetic nanoparticle is selected from the group consisting of γ-Fe.sub.2O.sub.3, Fe.sub.3O.sub.4, Y.sub.2O.sub.3, MnZn, CoFe.sub.2O.sub.4 and a combination thereof, and has a particle size of less than 10 nm; the first graphene sterilant and the second graphene sterilant are independently selected from the group consisting of silver/graphene oxide, silver/cobalt ferrite/graphene, ferroferric oxide/graphene oxide, yttrium oxide/graphene, bismuth oxychloride/graphene, bismuth oxybromide/oxide, titanium dioxide/graphene oxide, titanium dioxide/silver/graphene oxide, zinc oxide/graphene oxide and a combination thereof; the combination of the graphene composite material and the sterilant is selected from the group consisting of a chloromethylated molecular ball-graphene nanocomposite, a chloromethylated molecular ball grafted quaternary ammonium quaternary phosphonium salt solid sterilant-graphene nanocomposite, 1-bromo-3-chloro-5,5-dimethylhydantoin-graphene nanocomposite, 2,2-dibromo-3-nitrilopropionamide-graphene nanocomposite, 1,3-dibromo-5,5-dimethylhydantoin-graphite Ene nanocomposite, 2-bromo-2-nitro-styrene-graphene nanocomposite, benzyl dibromoacetate-graphene nanocomposite, dodecyldimethylbenzylammonium bromide-graphene nanocomposite, bronopol-graphene nanocomposite, tribromophenol-graphene nanocomposite, 4-bromo-2,5-dichlorophenol-graphene nanocomposite, 1,2-dibromo-2,4-dicyanobutane-graphene nanocomposite, α-bromocinnamaldehyde-graphene nanocomposite, 2-butene-1,4-diol bis(bromoacetate) ester-graphene nanocomposite, 2,2-dibromo-2-nitroethanol-graphene nanocomposite, N-(4-bromo-2-methylphenyl) chloroacetamide-graphene nanocomposite, 2,2-dibromo-3-cyanopropionamide-graphene nanocomposite, ternary solid stable chlorine dioxide-graphene nanocomposite, ferrate-graphene nanocomposite, azoxystrobin-graphene nanocomposite, ethylphospho aluminum-graphene nanocomposite, polyiodine-graphene nanocomposite and a combination thereof; and A the graphene composite material is selected from the group consisting of graphene, graphene oxide, boron-doped graphene, nitrogen-doped graphene nanosheet, graphene nanoribbon, graphene nanotube, graphene nanocluster, graphene nanofiber, graphene three-dimensional framework, graphene quantum dot and a combination thereof.

5. The system of claim 1, wherein a spray liquid contained in the spray liquid storage tank is selected from the group consisting of nano-ionized water, alkaline ionized water, alkaline reduced water, electrolyzed water, negative ion water and fluorinated water.

6. The system of claim 5, wherein the graphene chemical oxygen demand degrading agent is selected from the group consisting of large-specific surface area graphene, boron-doped graphene, CoFe.sub.2O.sub.4/graphene oxide nanocomposite, ferrous sulfate/graphene nanocomposite, bentonite/graphene nanocomposite, vermiculite/graphene nanocomposite, serpentine/graphene nanocomposite, titanium dioxide/graphene nanocomposite, graphene oxide/titanium dioxide nanoparticle, graphene oxide/titanium dioxide nanoribbon, graphene oxide/titanium dioxide nanotube, graphene/titanium dioxide nanorod, phosphotungstic acid/graphene oxide, tungsten trioxide/graphene oxide, zinc oxide/graphene oxide composite material and a combination thereof.

7. The system of claim 1, wherein the grapheme-based photocatalytic degradation agent is selected from the group consisting of graphene oxide/titanium dioxide nanoparticle, graphene/titanium dioxide nanoparticle, graphene oxide/titanium dioxide nanoribbon, graphene/titanium dioxide nanoribbon, graphene oxide/titanium dioxide nanotube, graphene/titanium dioxide nanotube, graphene oxide/titanium dioxide nanorod, graphene/titanium dioxide nanorod, phosphotungstic acid/graphene oxide, phosphotungstic acid/graphene, tungsten trioxide/graphene oxide, tungsten trioxide/graphene, zinc oxide/graphene oxide, zinc oxide/graphene, cuprous oxide/graphene, cuprous oxide/graphene oxide, bismuth tungstate/graphene, silver phosphate/graphene, molybdenum disulfide/graphene, trimanganese tetraoxide/graphene oxide and a combination thereof.

8. The system of claim 1, wherein the heavy metal-adsorption graphene nanocomposite is selected from the group consisting of graphene oxide, hydroxylated graphene, carboxylated graphene, chitosan modified graphene oxide, glutaraldehyde-coupled graphene oxide, chitosan modified hydroxylated graphene, acid salt nanotube-graphene oxide, hydroxyapatite-graphene oxide, N-(trimethoxysilylpropane) ethylenediamine triacyl graphene oxide, hydroxylated carbon nanotube-graphene oxide, Ti-pillared montmorillonite-graphene oxide, aluminum oxide-graphene oxide, polyaluminum chloride-graphene oxide, polyhydroxyaluminum pillared vermiculite, polyhydroxyaluminum pillared vermiculite-graphene oxide, 13X molecular sieve, sodium alginate-graphene oxide, EDTA-graphene oxide, polyamide-amine dendrimer porous silica gel, polyamide-amine dendrimer-graphene oxide and N-(2,3-epoxypropyl)iminodiacetic acid modified graphene oxide; the large-specific surface area graphene nanomaterial is selected from the group consisting of a single-layer graphene nanosheet, a three-dimensional mesoporous graphene nanomaterial, a three-dimensional macroporous graphene nanomaterial, a graphene aerogel, a graphene nanofiber and a graphene organic framework composite nanomaterial.

9. The system of claim 8, wherein the graphene porous ceramic material is prepared through steps of: (S101) selecting silicon carbide or boron carbide porous ceramic material as a substrate; (S102) subjecting the substrate to ultrasonic treatment, gradient immersion in a copper chloride solution or a cobalt dichloride solution and vacuum drying and programmed heating in an inert gas to obtain a metal film-coated silicon carbide or boron carbide porous ceramic raw material; (103) sealing the metal film-coated silicon carbide or boron carbide porous ceramic raw material obtained in step (S102) in a chemical vapor deposition reaction chamber; elevating a temperature in the chemical vapor deposition reaction chamber; introducing methane or acetylene to the chemical vapor deposition reaction chamber; and subjecting the sealed metal film-coated silicon carbide or boron carbide porous ceramic raw material to reaction in argon under adjustment of hydrogen flow to obtain a reaction product; and (S104) stopping feeding methane or acetylene after the reaction is completed; keep flows of hydrogen and argon unchanged; and cooling the reaction product to obtain the graphene porous ceramic material.

10. A method for treating a medical sewage containing SARS-CoV-2 using the system of claim 1, comprising: (S201) settling solid wastes and suspended solids in the medical sewage in the primary sedimentation tank; (S202) subjecting a sewage flowing out of the primary sedimentation tank to filtration by the filtering device; (S203) subjecting a sewage flowing out of the filtering device to primary sterilization in the primary graphene sterilization device; (S204) subjecting a sewage flowing out of the primary graphene sterilization device to multiple sterilization in the multiple purification tank to preliminarily kill the SARS-CoV-2 and reduce chemical oxygen demand; (S205) subjecting a sewage flowing out of the multiple purification tank to photocatalytic degradation by the photocatalytic degradation device to remove various pollutants; (S206) allowing a sewage flowing out of the photocatalytic degradation device to enter the secondary sedimentation tank to settle suspended solids and separate the remains of parasites or pathogenic bacteria that have been killed; (S207) allowing a sewage flowing out of the secondary sedimentation tank to successively pass through the secondary graphene sterilization device and the tertiary graphene sterilization device for further sterilization; (S208) allowing a sewage flowing out of the tertiary graphene sterilization device to enter a primary graphene water-purification unit of the at least three stages of graphene water-purification unit store move heavy metals; (S209) allowing a sewage flowing out of the primary graphene water-purification unit to enter the SARS-CoV-2 deep purification device for further killing the SARS-CoV-2; and (S210) allowing a sewage flowing out of the SARS-CoV-2 deep purification device to sequentially pass through a secondary graphene water-purification unit and a tertiary graphene water-purification unit of the at least three stages of graphene water-purification units to remove peculiar smell substances and heavy metals to complete treatment of the medical sewage containing SARS-CoV-2.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0007] The FIGURE is a structural diagram of the graphene nano-purification system for treating medical sewage containing SARS-CoV-2 according to the present invention. Among them: 1. Collection and conveying device; 2. Primary sedimentation tank; 3. Filter device; 4. Primary graphene sterilization device; 5. Spray liquid storage tank; 6. Ultrasonic micro-nano bubble generator; 7. Multiple Purification tank; 8. Ozone generator; 9. First ultraviolet generating device; 10. Graphene chemical oxygen demand degrading agent; 11. Graphene sterilizing agent; 12. Photocatalytic degradation device; 13. Secondary sedimentation tank; 14. Two-stage graphene sterilization device; 15. Three-stage graphene sterilization device; 16. One-stage graphene water purification device; 17, SARS-CoV-2 deep purification device; 18. Two-stage graphene water purification device; 19. Three-stage graphene water purification device; 20. Sodium hypochlorite generator; 21. Second ultraviolet generating device; 22. Irradiation device.

DETAILED DESCRIPTION OF EMBODIMENTS

[0008] In the following description, many specific details are explained in order to fully understand the present invention. However, the present invention can be implemented in many other ways different from the description herein, and those skilled in the art can make similar popularizations without violating the connotation of the present invention. Therefore, the present invention is not limited by the specific embodiments disclosed below.

EXAMPLE 1

[0009] As shown in FIG. 1, a graphene nano-purification system for treating medical sewage containing SARS-CoV-2 includes a medical sewage collection and transportation device 1, a first-stage sedimentation tank 2, a filter device 3, and a first-stage graphene sterilization device 4 connected in sequence The spray liquid storage tank 5 is connected to the ultrasonic micro-nano bubble generator 6; the output end of the first-level graphene sterilization device 4 and the nozzle of the ultrasonic micro-nano bubble generator 6 are placed in the multiple purification tank 7. The multiple purification tank 7 is provided with an ozone generator 8 and a first ultraviolet generating device 9, and a graphene chemical oxygen demand degrading agent 10 and a graphene sterilizing agent 11 are cast. The multiple purification tank 7 is also connected to the photocatalytic degradation device 12, the second-stage sedimentation tank 13, the second-stage graphene sterilization device 14, the third-stage graphene sterilization device 15, the first-stage graphene water purification device 16, and the new crown virus deep purification device. Device 17, two-stage graphene water purification device 18, and three-stage graphene water purification device 19. Among them, the secondary sedimentation tank 13 is also provided with a sodium hypochlorite generator 20; the new crown virus deep purification device 17 is provided with a transparent casing, and a second ultraviolet generating device 21 and an irradiation device 22 are provided outside the transparent casing. The specific structure and treatment process of the graphene nano-purification system for treating medical sewage containing the SARS-CoV-2 of this embodiment are as follows:

[0010] 1. Medical sewage pretreatment process The medical sewage from the infectious disease hospital or the infectious department of a general hospital enters the first-level sedimentation tank 2 through the collection and conveying device 1 to settle solid waste and suspended solids. The first-stage sedimentation tank 2 is a cylindrical tank with a depth of 2.0 m and a diameter of 3.0 m. The bottom of the tank is provided with a sewage valve, which can periodically remove the settled solid waste and suspended matter. After the medical sewage settles, it is transported to the filtering device 3 for filtering, so as to further remove the residual solid waste in the sewage. The filtering device 3 is a columnar structure with a diameter of 20 cm and a length of 15 cm. A 10-mesh primary graphene filter, a 30-mesh secondary graphene filter, and an 80-mesh three-stage graphene filter are respectively arranged at the front, middle, and rear ends along the water flow direction. Grade graphene filter. The bottom of the middle section of the filter device 3 is also provided with a sedimentation tank, and a discharge valve is provided in the sedimentation tank to remove the settled residual solid waste and prevent the filter device 3 from clogging.

[0011] The medical sewage enters the columnar first-level graphene sterilization device 4 after being filtered. The first-level graphene sterilization device 4 is filled with superparamagnetic nanoparticles-graphene oxide composite nanomaterials, which can produce superimposed sterilization effects to remove some residual parasites and pathogenic bacteria in the medical sewage of infectious disease hospitals (Such as Pseudomonas aeruginosa, Escherichia coli, conjugate bacillus, SARS-CoV-2, cholera, Shigella dysentery, Salmonella, Klebsiella, Schistosomiasis pathogens and other possible pathogens in water). The superparamagnetic nanoparticle-graphene oxide composite nanomaterial is wrapped with 50 mesh regenerated fiber cloth, wherein the material of the superparamagnetic nanoparticle is γ-Fe.sub.2O.sub.3, and its average particle size is less than 10 nm. The medical sewage sterilized by the first-level graphene sterilization device 4 is discharged into the multiple purification tank 7 for the next purification treatment.

[0012] 2. The SARS-CoV-2 and other pathogenic bacteria further killing process The spray liquid storage tank 5 stores fluorinated water. The fluorinated water is input into the ultrasonic micro-nano bubble generator 6 through the traction pump and the delivery pipe. The ultrasonic micro-nano bubble generator 6 works to generate ultrasonic micro-nano bubbles. The power source high-pressure gas-water delivery pump is used for transportation, and the ultrasonic micro-nano bubbles enter the medical sewage in the multiple purification tank 7 through the atomization nozzle for deep purification. Ultrasonic micro-nano bubble generator 6 can generate air flow through accessory parts, and then through the intermittent pulse pneumatic or hydraulic components inside the ultrasonic micro-nano bubble generator to impact the mechanical vibration spring titanium manganese phosphor steel sheet water in the frequency-adjustable seismic cavity The high-frequency resonance of 10000-150000 times per second can be generated through the fine-toothed frequency adjustment screw at the tail of the shock cavity. The resonance frequency of the mechanical shock spring titanium manganese phosphor steel sheet can be adjusted (thereby controlling the particle size, fineness, density, and high frequency of the air bubbles). Resonance), and then pulverize the ozone airflow to produce a large number of ultrasonic micro-nano ozone bubbles in the range of 0.01 microns to 20 microns. These ultrasonic micro-nano ozone bubbles have the characteristics of high interface zeta potential, high mass transfer efficiency, and pressurized dissolved gas to precipitate bubbles. The water body stored in the spray liquid storage tank 6 can promote the efficient formation of ultrasonic micro-nano bubbles.

[0013] The principle of the killing process in this part is: Ultrasonic micro-nano bubbles float and separate at high speed in water droplets. With their physical properties of gas and water, the micro-nano bubbles shrink sharply from “μ m” micron size to “nm” nano size, and are finally compressed. When the bubbles are broken, high energy is released; at the same time, the surface of the ultrasonic ozone micro-nano bubbles is negatively charged, which is easy to adsorb positively charged organic matter and suspended matter in the water; when the bubbles are crushed, an instant high temperature and high pressure environment is generated, releasing a lot of energy, And produce .OH free radicals at the air-liquid interface, which are effective against SARS-CoV-2, Pseudomonas aeruginosa, Escherichia coli, conjugate bacilli, cholera, Shigella dysenteriae, Salmonella, Klebsiella, and Schistosomiasis remaining in medical sewage Pathogens and other possible pathogens (parasites) in water are deeply killed and inactivated.

[0014] 3. Other multiple sterilization and degradation chemical oxygen demand purification processes in multiple purification tanks.

[0015] The multiple sterilization process in this part is ozone sterilization by the ozone generator 8, ultraviolet sterilization by the first ultraviolet generator 9, and graphene sterilization agent 11 for sterilization; the graphene sterilization agent 11 is silver/Cobalt Ferrite/Graphene. The chemical oxygen demand is degraded by adding graphene chemical oxygen demand degrading agent 10, which is a ferrous sulfate/graphene nanocomposite material, which degrades residual organic matter and chemical oxygen demand in water through direct action or photocatalysis. The multiple purification tank 7 is a square tank with a length of 10 m and a depth of 3.0 m. The bottom has a drain valve and an adjustable speed agitator. The non-sedimentation time is disturbed by stirring to make the sterilization and COD degradation more thorough.

[0016] 4. Deep purification process of medical sewage The medical sewage purified by the multiple purification tanks 7 enters the photocatalytic degradation device 12 to further degrade some residual drugs, residual azo dyes and other organic pollutants in the medical sewage. The photocatalytic degradation device 12 is a columnar body made of transparent glass, and is filled with a graphene photocatalytic degradation agent wrapped in a 50-mesh recycled fiber cloth. The graphene photocatalytic degradation agent is graphene oxide/titanium dioxide nanoparticles, which can catalytically degrade azo dyes such as residual drugs in medical sewage, residual reactive red 195, methyl orange, rhodamine B, and phenol under light conditions. Oxalic acid, organic halides and other residual organic pollutants. The medical sewage after photocatalytic degradation enters the secondary sedimentation tank 13 to further settle the suspended solids, and the sodium hypochlorite generator 20 is turned on during the non-sedimentation time to further kill the remaining pathogenic bacteria and parasites

[0017] A waste discharge valve is arranged under the secondary sedimentation tank 13 to facilitate the regular removal of the solid waste after the settlement. The medical sewage after re-sedimentation enters the secondary graphene sterilization device 14 for secondary sterilization. The secondary graphene sterilization device 14 is a stainless steel cylinder filled with a graphene sterilant. The graphene sterilizing agent is titanium dioxide/silver/graphene oxide, and the size is between 10-100 nm. The medical sewage after the secondary sterilization enters the tertiary graphene sterilization device 15 for tertiary sterilization. The three-stage graphene sterilization device 15 is filled with a chlorine ball grafted quaternary ammonium quaternary phosphonium salt solid bactericide. The medical sewage after the tertiary sterilization enters the first-level graphene water purification device 16, and the first-level graphene water purification device 16 is filled with heavy metal adsorption graphene nanocomposite materials. The heavy metal adsorption graphene nanocomposite material is wrapped with 10-325 mesh recycled fiber cloth or glass fiber cloth. The heavy metal adsorption graphene nanocomposite material is graphene oxide modified by chitosan to remove heavy metals such as copper, nickel, lead, cadmium, mercury, arsenic, total chromium, and hexavalent chromium remaining in the water. The medical sewage purified by the first-level graphene water purification device 16 enters the SARS-CoV-2 deep purification device 17. The novel coronavirus deep purification device 17 is a cylinder made of transparent glass, the second ultraviolet generating device 21 is a 30 W ultraviolet lamp, which is arranged above the cylinder, and the irradiation device 22 is a .sup.60Co-γ irradiation device, which is arranged below the cylinder. Through the effect of ultraviolet radiation and .sup.60Co-γ radiation, the remaining SARS-CoV-2 and other pathogenic bacteria are further killed. The representative radiation dose of .sup.60Co-γ irradiation is 10 kGY, and it is measured by a pre-installed dosimeter. The new crown virus deep purification device 17 is equipped with a peristaltic pump at the water inlet to control the sterilization process by adjusting the flow rate; there is a 5-level decelerating screen made of polytetrafluoroethylene with an aperture between 10 and 100 to delay the water body Flow, so that the water body can fully obtain the effect of ultraviolet radiation, so as to completely kill the residual pathogenic bacteria such as new crown virus, Pseudomonas aeruginosa and E. coli. The medical water body that has been deeply purified by the SARS-CoV-2 deep purification device 17 flows into the secondary graphene water purification device 18. The secondary graphene water purification device 18 is filled with a large surface area graphene nano material, and the large surface area graphene nanocomposite material is graphene aerogel, which can effectively adsorb odorous substances such as residual chlorine in sewage and polycyclic aromatic hydrocarbons, Residual antibiotics and other drugs, volatile phenols, biological agents, chemical solvents, oil stains and other residual pollutants, as well as residual lead, chromium, mercury and other heavy metal pollutants. The large surface area graphene nano material is wrapped with 80 mesh recycled fiber cloth. After being purified by the secondary graphene water purifier 18, the water flows into the tertiary graphene water purifier 19. The three-stage graphene water purification device 19 is filled with graphene porous ceramic material wrapped with 100 mesh recycled fiber cloth or glass fiber cloth to further remove trace pollutants remaining in the water. The preparation process of the graphene porous ceramic material is as follows:

[0018] In the first step, a commercially available silicon carbide porous ceramic material is selected as the substrate. In the second step, the substrate is subjected to ultrasonic treatment, gradient immersion in a copper dichloride solution, and vacuum-dried after being pulled, and then the temperature is programmed through an inert gas atmosphere to obtain a raw material of silicon carbide porous ceramic material with a metal film on the surface. In the third step, the raw materials obtained in the second step are put into the chemical vapor deposition reaction chamber for sealing, the air tightness of the high-temperature reaction chamber is checked, the residual gas in the high-temperature reaction chamber is discharged under a protective atmosphere, and then the temperature is programmed. Heat to 900° C., 950° C., 1000° C., 1050° C. at a temperature increase rate of 10° C./min. The constant temperature time lasts for 10 minutes, 30 minutes, and 60 minutes respectively, and then enter 1, 5, 10, 15 ml/min units For methane, adjust the hydrogen flow rate to 30 ml/min, and the reaction time is 30 minutes, 60 minutes, 150 minutes, 180 minutes, 210 minutes, 240 minutes, and 300 minutes. After the reaction, stop feeding methane, keep the flow of hydrogen and argon unchanged, control the cooling rate from 10° C./min to 400° C., and then naturally cool to room temperature to obtain the graphene porous ceramic material. The primary, secondary, and tertiary graphene sterilization devices are all cylindrical, and the primary, secondary, and tertiary graphene water purification devices are also cylindrical, and their materials are all stainless steel, ceramic or polycarbonate Any kind of. The water body that has been deeply purified by the above process is sampled and tested in accordance with the “Water Pollutant Discharge Standard for Medical Institutions” (GB 18466-2005) to test various indicators to obtain qualified discharge of medical purified water. The following table is a list of indicators after purification of medical sewage from an infectious disease hospital in Guangdong that applies the process of the present invention. All indicators meet the requirements of GB 18466-2005 (the SARS-CoV-2 had not specific in this standard, and this process has not been detected after purification).

TABLE-US-00001 TABLE 1 The technical index table after the process of this embodiment purifies the sewage of each medical unit of an infectious disease hospital in Guangdong. Requirement of GB 18466-2005 The official unit of Index after Individual Items value measurement purification judgment Suspended ≤20 mg/L 9 qualified matter (SS) pH 6-9 / 8.1 qualified COD.sub.Cr ≤60 mg/L 47 qualified BOD.sub.S ≤20 mg/L 15 qualified NH.sub.3—N ≤15 mg/L 10.3 qualified Total residual ≤0.5 mg/L 0.13 qualified chlorine Fecal coliforms ≤500 MPN/L 117 qualified Enteric Must not be mg/L Not detected qualified pathogens checked out Enterovirus Must not be mg/L Not detected qualified checked out Mycobacterium Must not be mg/L Not detected qualified tuberculosis checked out Hexavalent ≤0.5 mg/L 0.39 qualified chromium Total chromium ≤1.5 mg/L 1.26 qualified Total cadmium ≤0.1 mg/L 0.07 qualified Total mercury ≤0.05 mg/L 0.04 qualified Total arsenic ≤0.5 mg/L 0.19 qualified Total lead ≤1.0 mg/L 0.41 qualified Volatile Phenol ≤0.5 mg/L 0.27 qualified Total cyanide ≤0.5 mg/L 0.34 qualified Anionic ≤5 mg/L 3.17 qualified Surfactant Animal and ≤5 mg/L 1.42 qualified vegetable oils SARS-CoV-2 No No Not detected / standard standard (Virus titer before purification was 9.17 × 10.sup.5 PFU/ml)

Example 2

[0019] Compared with Example 1, this embodiment differs in the following:

[0020] 1. Medical sewage pretreatment process 1. The first-stage sedimentation tank is a rectangular tank with a length of 2 m, a width of 1.5 m and a depth of 1.6 m, and the sewage valve is installed on the side wall of the tank. 2. The filter device 3 is a columnar structure with a diameter of 20 cm and a length of 10 cm. The number of first-level graphene filter meshes is 15, the number of second-level graphene filter meshes is 40, and the number of third-level graphene filter meshes is 90.3. The superparamagnetic nanoparticle-graphene oxide composite nanomaterial is wrapped with 120 mesh glass fiber cloth. The material of the superparamagnetic nanoparticle is CoFe.sub.2O.sub.4, and its average particle size is less than 10 nm.

[0021] 2. The SARS-CoV-2 and other pathogenic bacteria are in the process of further killing 1. Alkaline ionized water is stored in the spray liquid storage tank 5.

[0022] 3. In other multiple sterilization and degradation chemical oxygen demand purification processes in multiple purification tanks 1. Graphene sterilizing agent 11 is zinc oxide/graphene oxide; graphene reducing chemical oxygen demand degradation agent 10 is phosphotungstic acid/graphene oxide nanocomposite material 2. The multiple purification tank 7 is a rectangular tank with a length of 5 m, a width of 3.5 m, and a depth of 3.0 m. There are drain valves at the bottom and side walls of the tank. 4. In the deep purification process of medical sewage 1. The photocatalytic degradation device 12 is a cylindrical body made of transparent ceramic material, filled with a graphene photocatalytic degradation agent wrapped with 80 mesh glass fiber cloth; the graphene photocatalytic degradation agent is tungsten trioxide/graphene oxide. 2. The graphene sterilizing agent in the secondary graphene sterilization device 14 is bismuth oxybromide/graphene oxide, and the size is between 5-150 nm.

[0023] 4. The filler of the tertiary graphene sterilization device 15 is 2,2-dibromo-3-nitrilopropionamide (DBNPA)-graphene nanocomposite material. 4. The heavy metal adsorption graphene nanocomposite material in the first-level graphene water purification device 16 is a graphene oxide nanocomposite material coupled with glutaraldehyde.

[0024] 5. The new crown virus deep purification device 17 is a transparent ceramic cylinder, and the representative radiation amount of .sup.60Co-γ irradiation is 9kGY; the deceleration screen has 6 levels, made of stainless steel, and the aperture is between 20-60.

[0025] 6. The large specific surface graphene nanocomposite material in the secondary graphene water purification device 18 is a three-dimensional macroporous graphene nanomaterial, which is wrapped with a 200-mesh recycled fiber cloth.

[0026] 7. In the preparation process of the graphene porous ceramic material, the substrate in the first step is the boron carbide porous ceramic material, and the gas introduced in the third step is changed from methane to acetylene. 8. The material of the primary, secondary, and tertiary graphene sterilization devices and the primary, secondary, and tertiary graphene water purification devices is polypropylene. The water body that has been deeply purified by the above process is sampled and tested in accordance with the “Water Pollutant Discharge Standard for Medical Institutions” (GB 18466-2005) to test various indicators to obtain qualified discharge of medical purified water. The following table is a list of various indicators after purification of medical sewage from an infectious disease hospital in Hubei applying the process of the present invention. All indicators meet the requirements of GB 18466-2005 (the new crown virus is not specific in the country, and this process has not been detected after purification).

TABLE-US-00002 TABLE 2 Technical index table after purification of sewage from various medical units of an infectious disease hospital in Hubei by the process of this embodiment Requirement of GB 18466-2005 The official unit of Index after Individual Items value measurement purification judgment Suspended ≤20 mg/L 7.5 qualified matter (SS) pH 6-9 / 7.3 qualified COD.sub.Cr ≤60 mg/L 55 qualified BOD.sub.S ≤20 mg/L 17 qualified NH.sub.3—N ≤15 mg/L 9.6 qualified Total residual ≤0.5 mg/L 0.31 qualified chlorine Fecal coliforms ≤500 MPN/L 69 qualified Enteric Must not be mg/L Not detected qualified pathogens checked out Enterovirus Must not be mg/L Not detected qualified checked out Mycobacterium Must not be mg/L Not detected qualified tuberculosis checked out Hexavalent ≤0.5 mg/L 0.23 qualified chromium Total chromium ≤1.5 mg/L 1.12 qualified Total cadmium ≤0.1 mg/L 0.03 qualified Total mercury ≤0.05 mg/L 0.02 qualified Total arsenic ≤0.5 mg/L 0.14 qualified Total lead ≤1.0 mg/L 0.39 qualified Volatile Phenol ≤0.5 mg/L 0.22 qualified Total cyanide ≤0.5 mg/L 0.28 qualified Anionic ≤5 mg/L 2.36 qualified Surfactant Animal and ≤5 mg/L 2.11 qualified vegetable oils SARS-CoV-2 No No Not detected / standard standard (Virus titer before purification was 9.17 × 10.sup.5 PFU/ml)

[0027] The above are only the preferred embodiments of the present invention and are not intended to limit the present invention. Although the present invention has been described in detail with reference to the embodiments, for those skilled in the art, it is still possible for those skilled in the art to compare what has been described in the foregoing embodiments. Modifications to the technical solutions, or equivalent replacements of some of the technical features, but any modifications, equivalent replacements, improvements, etc. made within the spirit and principle of the present invention should be included in the protection scope of the present invention.