REINFORCED AND TOUGHENED MGO SUBSTRATE, PREPARATION METHOD THEREOF AND COMPOSITE BOARD HAVING THE SUBSTRATE

Abstract

The present application discloses a reinforced and toughened MGO substrate, a preparation method thereof and a composite board having the substrate. The reinforced and toughened MGO substrate includes a middle layer and fiber layers on upper and lower surfaces of the middle layer, wherein the fiber layers are glassfiber surface mats, and the middle layer is prepared from a forming agent, a lightweight filler, a modifier and water in parts by weight as follows: 34-45 parts of light burned magnesium oxide, 23-30 parts of magnesium sulfate heptahydrate, 8-10 parts of granulated lignocellulose, 4-6 parts of xylem fiber, 0.5-2 parts of the modifier, and 18-26 parts of water; the modifier being obtained by mixing citric acid, anhydrous sodium sulfate, dihydrogen phosphate and phosphoric acid in a mass ratio of 10:3:1:6.

Claims

1. A reinforced and toughened MGO substrate, comprising a middle layer, and fiber layers on upper and lower surfaces of the middle layer, wherein the fiber layers are glassfiber surface mats, and the middle layer is prepared from a forming agent, a lightweight filler, a modifier and water in parts by weight as follows: 34-45 parts of light burned magnesium oxide, 23-30 parts of magnesium sulfate heptahydrate, 8-10 parts of granulated lignocellulose, 4-6 parts of xylem fiber, 0.5-2 parts of the modifier, and 18-26 parts of water; the modifier being obtained by mixing citric acid, anhydrous sodium sulfate, dihydrogen phosphate and phosphoric acid in a mass ratio of 10:3:1:6.

2. The reinforced and toughened MGO substrate according to claim 1, wherein the dihydrogen phosphate is any one selected from the group consisting of magnesium dihydrogen phosphate, and sodium dihydrogen phosphate.

3. The reinforced and toughened MGO substrate according to claim 1, wherein the light burned magnesium oxide has a content of magnesium oxide of >85% and a content of reactive magnesium oxide of >65%.

4. The reinforced and toughened MGO substrate according to claim 1, wherein the granulated lignocellulose has a fineness of 20-60 mesh and a moisture content of 0.5-10%, and the xylem fiber has a fiber length of 3-12 mm and a moisture content of 0.5-10%.

5. The reinforced and toughened MGO substrate according to claim 1, wherein the glassfiber surface mat is an alkali-free glassfiber surface mat which is formed by bonding randomly oriented glassfiber filaments with resin and curing, and the glassfiber filaments have a mass content of 30-100 g/m.sup.2 and a length of >50 mm.

6. A preparation method of the reinforced and toughened MGO substrate according to claim 1, comprising the following steps of: S1, uniformly stirring magnesium sulfate heptahydrate with water to obtain a magnesium sulfate heptahydrate solution; S2, uniformly blending and stirring light burned magnesium oxide with the magnesium sulfate heptahydrate solution prepared in the step S1, and then sequentially adding a modifier, granulated lignocellulose and xylem fiber, and performing stirring for mixing to obtain magnesium oxysulfate cement; S3, laying a glassfiber surface mat into a mold, spreading the magnesium oxysulfate cement prepared in the step S2 onto the glassfiber surface mat, performing flattening, laying another glassfiber surface mat on a surface of the magnesium oxysulfate cement, performing flattening until the surface of the glassfiber mat is uniformly permeated by a slurry, and putting the obtained material in a curing room with a temperature of 20-30° C. and a humidity of 40-60% for 2-6 h to obtain a primary cured semi-finished product; S4, taking out the primary cured semi-finished product prepared in the step S3 from the curing room, performing flattening and exhausting; and taking out and putting the flattened and exhausted primary cured semi-finished product in the curing room with a temperature of 25-30° C. and a humidity of 40-50% for 3-5 days to obtain a secondary cured semi-finished product; and S5, taking out the secondary cured semi-finished product prepared in the step S4 from the curing room, and performing trimming, cutting and polishing; and then putting the polished secondary cured semi-finished product in the curing room with a temperature of 25-30° C. and a humidity of 40-50% for 5-12 days to obtain a shaped substrate.

7. A reinforced and toughened MGO composite board, comprising a surface layer and a substrate, wherein the substrate adopts the reinforced and toughened MGO substrate according to claim 1, and the surface layer is any one selected from the group consisting of marble, wood veneer, and a fireproof board.

8. The reinforced and toughened MGO composite board according to claim 7, wherein the fireproof board is prepared by the following steps of: immersing a glassfiber surface mat in resin for 120-150 min, taking out the glassfiber surface mat, and performing hot-press molding on the glassfiber surface mat with melamine decorative paper under a temperature of 130-170° C. and a pressure of 10-21 MPa.

9. The reinforced and toughened MGO composite board according to claim 7, wherein the fireproof board is prepared by the following steps of: immersing a non-woven fabric in resin for 120-150 min, taking out the non-woven fabric, and performing hot-press molding on the non-woven fabric with melamine decorative paper under a temperature of 130-170° C. and a pressure of 10-21 MPa.

10. The reinforced and toughened MGO composite board according to claim 8, wherein the resin includes one or both of melamine resin and urea-formaldehyde resin.

Description

DETAINED DESCRIPTION OF THE INVENTION

[0039] The present application will now be described in further detail with reference to the embodiments.

[0040] Sources of raw materials: see Table 1 below.

TABLE-US-00001 TABLE 1 Sources and Specifications of Raw Materials of Reinforced and Toughened MGO Composite Board Raw material Source Specifications Origin Forming Light burned Content of magnesium Yingkou Xinyao agent magnesium oxide oxide 85%, Magnesium content of reactive magnesium oxide 80%. Magnesium sulfate Purity 99% Weifang Dakang heptahydrate Chemical Lightweight Poplar wood powder Fineness 20-60 mesh, Wuxi Simude filler moisture content 0.5-10%. Lignocellulose Fiber length 5 mm, Wuxi Simude moisture content 0.5-10%. Modifier Citric acid Purity 99% Shandong monohydrate Ruisheng Anhydrous sodium Sodium sulphate Zibo Huayan sulphate purity 99% Magnesium Purity 99% He'nan dihydrogen phosphate Hongkang Sodium dihydrogen Purity 99% He'nan phosphate Hongkang Phosphoric acid Industrial Nantong grade 85% Shuangxian Fine Resin Melamine resin Purity 99.8% Jining Hongming Urea-formaldehyde Molecular Kedi Chemical resin weight 90.08 Alkali-free glassfiber Gram weight per Sinoma Science surface mat square 50 g/m.sup.2 & Technology Polyurethane adhesive CR361 Jilin Zhengqi Marble 2600*2000*1600 Shiyan Tianci Yellow poplar veneer Thickness 0.6 mm Guangzhou Huayuan Non-woven fabric Gram weight per Guangzhou square 50 g/m.sup.2 Jingjin Melamine decorative Weight per square Hangzhou paper meter 30 g Lin'an Clean

[0041] A BY214*8/E series multi-ply plywood hot press was selected and purchased from Linyi Lanshan District Jianye Machinery Factory (Linyi Lanshan District Jianye Shunda Machinery Co., Ltd.); and

[0042] a PG02 series CNC slotting machine (self-digging machine) was purchased from Shanghai Eternal Co., Ltd.

EXAMPLES

[0043] The components and formulations of various Examples are shown in Table 2.

TABLE-US-00002 TABLE 2 Components and Formulations of Reinforced and Toughened MGO Substrates in Various Examples: Component Example 1 Example 2 Example 3 Example 4 Example 5 Example 6 Light burned 34 kg 40 kg 45 kg 40 kg 40 kg 40 kg magnesium oxide Magnesium 23 kg 27 kg 30 kg 27 kg 27 kg 27 kg sulfate heptahydrate Poplar wood 8 kg 9 kg 10 kg 9 kg 9 kg 9 kg powder Lignocellulose 4 kg 5 kg 6 kg 5 kg 5 kg 5 kg Citric acid 0.5 kg 1.25 kg 2 kg 1.25 kg 1.25 kg 1.25 kg monohydrate (citric acid (citric acid (citric acid (citric acid (citric acid (citric acid Anhydrous monohydrate: monohydrate: monohydrate: monohydrate: monohydrate: monohydrate: sodium anhydrous anhydrous anhydrous anhydrous anhydrous anhydrous sulphate sodium sodium sodium sodium sodium sodium Magnesium sulfate: sulfate: sulfate: sulfate: sulfate: sulfate: dihydrogen magnesium magnesium magnesium magnesium magnesium magnesium phosphate dihydrogen dihydrogen dihydrogen dihydrogen dihydrogen dihydrogen Sodium phosphate: phosphate: phosphate: phosphate: phosphate: phosphate: dihydrogen phosphoric phosphoric phosphoric phosphoric phosphoric phosphoric phosphate acid = acid = acid = acid = acid = acid = Phosphoric 10:3:1:6) 10:3:1:6) 10:3:1:6) 10:3:1:6) 10:3:1:6) 10:3:1:6) acid Water 18 kg 22.5 kg 26 kg 22.5 kg 22.5 kg 22.5 kg Moisture 6.00% 6.00% 6.00% 6.00% 6.00% 6.00% content of poplar wood powder (%) Fineness of 40 mesh 40 mesh 40 mesh 20 mesh 60 mesh 40 mesh poplar wood powder (mesh) Time, 270 min, 270 min, 270 min, 270 min, 270 min, 120 min, temperature 25° C., 50% 25° C., 50% 25° C., 50% 25° C., 50% 25° C., 50% 25° C., 50% and humidity of first curing Time, 4 days, 4 days, 4 days, 4 days, 4 days, 4 days, temperature 27° C., 45% 27° C., 45% 27° C., 45% 27° C., 45% 27° C., 45% 27° C., 45% and humidity of second curing (day) Time, 9 days, 9 days, 9 days, 9 days, 9 days, 9 days, temperature 27° C., 45% 27° C., 45% 27° C., 45% 27° C., 45% 27° C., 45% 27° C., 45% and humidity of third curing (day) Alkali-free Gram weight per square 50 g/m.sup.2 glassfiber surface mat Component Example 7 Example 8 Example 9 Example 10 Example 11 Light burned 40 kg 40 kg 40 kg 40 kg 40 kg magnesium oxide Magnesium 27 kg 27 kg 27 kg 27 kg 27 kg sulfate heptahydrate Poplar wood 9 kg 9 kg 9 kg 9 kg 9 kg powder Lignocellulose 5 kg 5 kg 5 kg 5 kg 5 kg Citric acid 1.25 kg 1.25 kg 1.25 kg 1.25 kg 1.25 kg monohydrate (citric acid (citric acid (citric acid (citric acid (citric acid Anhydrous monohydrate: monohydrate: monohydrate: monohydrate: monohydrate: sodium anhydrous anhydrous anhydrous anhydrous anhydrous sulphate sodium sodium sodium sodium sodium Magnesium sulfate: sulfate: sulfate: sulfate: sulfate: dihydrogen magnesium magnesium magnesium magnesium magnesium phosphate dihydrogen dihydrogen dihydrogen dihydrogen dihydrogen Sodium phosphate: phosphate: phosphate: phosphate: phosphate: dihydrogen phosphoric phosphoric phosphoric phosphoric phosphoric phosphate acid = acid = acid = acid = acid = Phosphoric 10:3:1:6) 10:3:1:6) 10:3:1:6) 10:3:1:6) 10:3:1:6) acid Water 22.5 kg 22.5 kg 22.5 kg 22.5 kg 22.5 kg Moisture 6.00% 6.00% 6.00% 0.5% 10% content of poplar wood powder (%) Fineness of 40 mesh 40 mesh 40 mesh 40 mesh 40 mesh poplar wood powder (mesh) Time, 360 min, 270 min, 270 min, 270 min, 270 min, temperature 25° C., 50% 20° C., 40% 30° C., 60% 25° C., 50% 25° C., 50% and humidity of first curing (min) Time, 4 days, 4 days, 4 days, 4 days, 4 days, temperature 27° C., 45% 25° C., 40% 30° C., 50% 27° C., 45% 27° C., 45% and humidity of second curing (day) Time, 9 days, 9 days, 9 days, 9 days, 9 days, temperature 27° C., 45% 25° C., 40% 30° C., 50% 27° C., 45% 27° C., 45% and humidity of third curing (day) Alkali-free Gram weight per square 50 g/m.sup.2 glassfiber surface mat

[0044] Each of the reinforced and toughened MGO substrates of Examples 1-11 above was prepared as follows:

[0045] S1, an alkali-free glassfiber surface mat according to Table 2 was laid and flattened, and the alkali-free glassfiber surface mat was cut according to a mold size of 2440*1220;

[0046] S2, a magnesium sulfate solution was prepared by firstly adding magnesium sulfate heptahydrate in parts by weight according to Table 2 into water, and performing uniform stirring to obtain the magnesium sulfate solution;

[0047] S3, magnesium oxysulfate cement was prepared by uniformly blending and stirring light burned magnesium oxide in parts by weight according to Table 2 with the magnesium sulfate solution prepared in S2, adding a modifier and performing uniform stirring to form a mixture slurry, sequentially adding poplar wood powder and xylem fiber in parts by weight according to Table 2 into the mixture slurry and performing uniform stirring, and performing exhausting with a vibration pump to obtain magnesium oxysulfate cement;

[0048] S4, a primary cured semi-finished product was prepared with a mold by laying the alkali-free glassfiber surface mat cut in S1 in the mold at normal temperature, spreading magnesium oxysulfate cement prepared in the step S3 onto the glassfiber surface mat, performing flattening with a constant-thickness roller, performing exhausting with the vibration pump during conveying, laying another glassfiber surface mat on the surface of magnesium oxysulfate cement, and performing flattening to make the surface of the alkali-free glassfiber felt uniformly permeated by the slurry; and removing the mold, and putting the obtained material in a curing room with a temperature, humidity and time according to Table 2 to obtain the preliminary cured semi-finished product;

[0049] S5, a secondary cured semi-finished product was prepared by taking out the preliminary cured semi-finished product prepared in S4 from the curing room, and performing flattening and exhausting; and then putting the flattened and exhausted primary cured semi-finished product in a curing room with a temperature, humidity and time according to Table 2 to obtain the secondary cured semi-finished product; and

[0050] S6, a substrate was obtained through final shaping by taking out the secondary cured semi-finished product prepared in S5 from the curing room, and performing trimming, cutting and polishing; and then putting the polished secondary cured semi-finished product in a curing room with a temperature, humidity and time according to Table 2 to obtain the substrate.

[0051] The properties of the reinforced and toughened MGO substrates prepared in the above Examples were tested by using the following method.

[0052] Apparent properties: including both before and after screw holding capability tests; MGO substrate or composite board standard test blocks were subjected to microscopic detection with a scanning electron microscope and observed for surface cracking.

[0053] Compressive strength and apparent density were tested according to JC688-2006 “Glass fiber & magnesium cement board”.

[0054] Impact strength: tests were carried out referring to an impact strength determination method in GB/T1043.1 “Plastics-Determination of Charpy impact properties-Part 1: Non-instrumented impact test”.

[0055] Dehalogenation resistance: referring to JC688-2006 “Glass fiber & magnesium cement board”, one piece of 200 mm*200 mm was randomly cut from each of three boards in a set of samples, and was put into a constant temperature and humidity box with a relative humidity of greater than or equal to 90% and a temperature of 30° C.-35° C., and after 24 hours, the samples were taken out and observed for the presence or absence of water drops or damping.

[0056] Determination of screw holding capability: referring to JC688-2006 “Glass fiber & magnesium cement board”, one piece of 50 mm*50 mm was randomly cut from each of three boards in a set of samples, a hole with a diameter of 3.2 mm was drilled at the intersection of diagonal lines of each sample with a bench drill in advance, and then a wood screw was screwed vertically into a depth of 10 mm±1 mm protruding from the opposite side without hammering, then the wood screw was pulled out with a loading speed of 50 N/S, and a limit load value was recorded.

[0057] Determination after slotting: referring to JC688-2006 “Glass fiber & magnesium cement board”, one piece of 300 mm*300 mm was randomly cut from each of three boards in a set of samples, side edges of diagonal corners of the samples were slotted with the CNC slotting machine, the slots were formed towards the inner depth of the samples at a speed of 50 N/S until peeling and cracking of the samples occurred, and the slotting depths at which peeling and cracking of the samples occurred were recorded.

[0058] Abrasion resistance test: evaluation was carried out according to GB/T18301-2012 “Refractory products-Determination of resistance to abrasion at ambient temperature”.

[0059] Refractory performance test: evaluation was carried out according to JC688-2006 “Glass fiber & magnesium cement board” and GB/T8624-1997 “Classification of burning behavior of building materials and products”.

TABLE-US-00003 TABLE 3 Test Results of Substrates of Reinforced and Toughened MGO Composite Boards Screw holding Detection Apparent Apparent Bending Impact capability Slotting item morphology density strength strength Dehalogenation of board depth Example 1 No cracking 1.33 t/m.sup.3 33 MPa 21 kJ/m.sup.2 No water drops, 37 N/m 160 mm no damping Example 2 No cracking 1.37 t/m.sup.3 36 MPa 25 kJ/m.sup.2 No water drops, 41 N/m 175 mm no damping Example 3 No cracking 1.35 t/m.sup.3 34 MPa 23 kJ/m.sup.2 No water drops, 39 N/m 162 mm no damping Example 4 No cracking 1.31 t/m.sup.3 33 MPa 22 kJ/m.sup.2 No water drops, 37 N/m 156 mm no damping Example 5 No cracking 1.36 t/m.sup.3 35 MPa 25 kJ/m.sup.2 No water drops, 38 N/m 168 mm no damping Example 6 No cracking 1.32 t/m.sup.3 31 MPa 20 kJ/m.sup.2 No water drops, 35 N/m 164 mm no damping Example 7 No cracking 1.34 t/m.sup.3 33 MPa 23 kJ/m.sup.2 No water drops, 37 N/m 161 mm no damping Example 8 No cracking 1.33 t/m.sup.3 36 MPa 22 kJ/m.sup.2 No water drops, 38 N/m 163 mm no damping Example 9 No cracking 1.37 t/m.sup.3 35 MPa 26 kJ/m.sup.2 No water drops, 38 N/m 167 mm no damping Example 10 No cracking 1.34 t/m.sup.3 33 MPa 27 kJ/m.sup.2 No water drops, 36 N/m 165 mm no damping Example 11 No cracking 1.32 t/m.sup.3 31 MPa 25 kJ/m.sup.2 No water drops, 35 N/m 160 mm no damping

[0060] The reinforced and toughened MGO substrates prepared according to the above formulations have no cracking on the surface with an apparent density of 1.31-1.38 t/m.sup.3, and due to the fact that the smaller the porosity of the reinforced and toughened MGO substrate is, the higher the compactness of the substrate is, the internal bonding strength of the substrates is high. Besides, the slotting depths at which peeling and cracking of the samples occurred in the above-mentioned Examples 1 to 11 is in the range of 160 to 175 mm.

COMPARATIVE EXAMPLES

[0061] The components and formulations of reinforced and toughened MGO substrates prepared in comparative examples are shown in Table 4.

TABLE-US-00004 TABLE 4 Components and Formulations of Reinforced and Toughened MGO Substrates In Comparative Examples 1-4 Comparative Comparative Comparative Comparative Components/part Example 1 Example 2 Example 3 Example 4 Light burned 40 kg 40 kg 40 kg 40 kg magnesium oxide Magnesium sulfate 27 kg 27 kg 27 kg 27 kg heptahydrate Poplar wood powder 9 kg 9 kg 9 kg 9 kg Lignocellulose 5 kg 5 kg 5 kg 5 kg Citric acid 0 kg 1.25 kg (citric 1.25 kg (citric 1.25 kg (citric monohydrate acid acid acid Anhydrous sodium monohydrate:anhydrous monohydrate:anhydrous monohydrate:anhydrous sulphate sodium sodium sodium Magnesium sulfate:magnesium sulfate:magnesium sulfate:magnesium dihydrogen dihydrogen dihydrogen dihydrogen phosphate phosphate:phosphoric phosphate:phosphoric phosphate:phosphoric Sodium dihydrogen acid = acid = acid = phosphate 8:5:1:6) 12:1:1:6) 10:3:2:5) Phosphoric acid Water 22.5 kg 22.5 kg 22.5 kg 22.5 kg Moisture content of 6.00% 6.00% 6.00% 6.00% poplar wood powder (%) Fineness of poplar 40 mesh 40 mesh 40 mesh 40 mesh wood powder (mesh) Time, temperature and 270 min, 270 min, 270 min, 270 min, humidity of first 25° C., 25° C., 25° C., 25° C., curing 50% 50% 50% 50% Time, temperature and 4 days, 4 days, 4 days, 4 days, humidity of second 27° C., 27° C., 27° C., 27° C., curing 45% 45% 45% 45% Time, temperature and 9 days, 9 days, 9 days, 9 days, humidity of third 27° C., 27° C., 27° C., 27° C., curing 45% 45% 45% 45% Alkali-free glassfiber Gram weight per square 50 g/m.sup.2 surface mat

[0062] Compared with Example 2, Comparative Example 1 was not added with a modifier; and Comparative Examples 2, 3 and 4 were added with modifiers in different mass proportions.

Comparative Example 5

[0063] An MGO board purchased from Zhangjiagang Leader Import and Export Co., Ltd. was compared with the substrate manufactured according to the present application; and the components for preparing the purchased MGO board include active magnesium oxide, high-quality magnesium chloride, alkali-resistant glassfiber fabrics, plant fiber, incombustible lightweight perlite, chemically stable lithopone, high-molecular polymers and high-performance modifiers.

Comparative Example 6

[0064] An MGO board purchased from Zhangjiagang Shitai Building Materials Co., Ltd. was compared with the substrate manufactured according to the present application; and the components for preparing the purchased MGO board include active magnesium oxide, high-quality magnesium chloride, alkali-resistant glassfiber fabrics, excellent-flexibility plant fiber, incombustible lightweight perlite, high-molecular polymers and high-performance modifiers.

[0065] The reinforced and toughened MGO substrates obtained in the above Comparative Examples 1 to 4 were prepared with the same method as in the Examples, and Comparative Examples 4 and 5 were purchased from the market. Test results of the reinforced and toughened MGO substrates prepared in the above Comparative Examples 1 to 6 are shown in Table 5.

TABLE-US-00005 TABLE 5 Test Results of Properties of Reinforced and Toughened MGO Substrates Prepared in Comparative Examples Screw holding Detection Apparent Apparent Bending Impact capability Slotting item morphology density strength strength Dehalogenation of board depth Comparative With 1.06 t/m.sup.3 14 MPa 11 kJ/m.sup.2 No water drops, 22 N/m 95 mm Example 1 cracking no damping Comparative No cracking 1.18 t/m.sup.3 25 MPa 13 kJ/m.sup.2 No water drops, 26 N/m 142 mm Example 2 no damping Comparative No cracking 1.20 t/m.sup.3 28 MPa 15 kJ/m.sup.2 With water drops 27 N/m 141 mm Example 3 and damping Comparative No cracking 1.21 t/m.sup.3 27 MPa 18 kJ/m.sup.2 No water drops, 25 N/m 144 mm Example 4 no damping Comparative No cracking 1.04 t/m.sup.3 16 MPa 12 kJ/m.sup.2 No water drops, 21 N/m 124 mm Example 5 no damping Comparative No cracking 1.06 t/m.sup.3 22 MPa 14 kJ/m.sup.2 No water drops, 24 N/m 126 mm Example 6 no damping

[0066] As can be seen from the above data, when no modifier is added or a modifier is added in an excessive amount or a small amount, small bubbles may be unstably generated during preparation of magnesium oxysulfate cement, and may easily fuse with each other to from large pores, such that the slotting depth is greatly reduced, and the phenomenon of peeling and cracking easily occurs when the substrate is mounted.

[0067] Examples of reinforced and toughened MGO composite board

Example 8

[0068] A reinforced and toughened MGO composite board included a surface layer and a substrate, and marble was used as the surface layer. The MGO substrate prepared according to Example 2 was bonded to a cut marble plane by using a polyurethane adhesive, and after 15 minutes of curing, the marble with the MGO substrate was cut off to obtain a marble surface combined with the MGO substrate, wherein the marble surface had a thickness of 0.5 mm, and the MGO substrate had a thickness of 3 mm; and the marble surface combined with the MGO composite board were taken out and subjected to polishing and UV to obtain the reinforced and toughened MGO composite board.

Example 9

[0069] A reinforced and toughened MGO composite board included a surface layer and a substrate, and yellow poplar veneer with a thickness of 0.6 mm was used as the surface layer. The MGO substrate prepared according to the second Example is bonded to a veneer plane by using a polyurethane adhesive, and after 15 minutes of curing, a semi-product was obtained; and then the semi-product was subjected to sanding and UV or coloring and UV, cutting and slotting to obtain the reinforced and toughened MGO composite board, wherein the MGO substrate is 3 mm.

Example 10

[0070] A reinforced and toughened MGO composite board included a surface layer and a substrate, and a fireproof board was used as the surface layer. The fireproof board was prepared by the following steps that: an alkali-free glassfiber surface mat was immersed in a mixed resin containing melamine resin and urea-formaldehyde resin in a mass ratio of 1:1, and soaked for 130 min, and then the glass surface mat was taken out and subjected to hot-press molding with melamine decorative paper by the multi-ply plywood hot press to obtain the fireproof board.

[0071] Then, the obtained fireproof board was bonded to two side surfaces of the substrate prepared in the Example 2 by using a polyurethane adhesive to obtain the reinforced and toughened MGO composite board.

Example 11

[0072] A reinforced and toughened MGO composite board included a surface layer and a substrate, and a fireproof board was used as the surface layer. The fireproof board was prepared by the following steps that: non-woven fabric was immersed in a mixed resin containing melamine resin and urea-formaldehyde resin in a mass ratio of 1:1, and soaked for 130 min, and then the non-woven fabric was taken out and subjected to hot-press molding with melamine decorative paper under a temperature of 150° C. and a pressure of 16 MPa to obtain the fireproof board.

[0073] Then, the obtained fireproof board was bonded to two side surfaces of the substrate prepared in the Example 2 by using a polyurethane adhesive to obtain the reinforced and toughened MGO composite board.

[0074] Test results of the reinforced and toughened MGO composite boards of Examples 8 to 11 are shown in the table below.

TABLE-US-00006 TABLE 6 Test Results of Reinforced and Toughened MGO Composite Boards Screw Static Surface holding Detection Apparent bending Bending Impact abrasion capability Slotting item morphology strength strength strength resistance of board depth Incombustibility Example 8 No cracking 34 Mpa 37 Mpa 26 kJ/m.sup.2 AC3 41 N/m 176 mm Grade A Example 9 No cracking 37 Mpa 38 Mpa 27 kJ/m.sup.2 AC3 40 N/m 180 mm Grade A Example 10 No cracking 45 Mpa 57 Mpa 41 kJ/m.sup.2 AC5 45 N/m 186 mm Grade A Example 11 No cracking 46 Mpa 58 Mpa 44 kJ/m.sup.2 AC5 46 N/m 189 mm Grade A

[0075] As can be seen from the above data, the strength of the reinforced and toughened MGO composite board prepared by the preparation method is obviously increased; meanwhile, the composite boards prepared in Examples 8 to 11 all have an abrasion resistance of up to higher than AC3 and an incombustibility of grade A.

[0076] The embodiments are merely illustrative of the application and are not intended to be limiting of the application, and modifications may be made to the embodiments by those skilled in the art, after reading the description, as required without involving any inventive contribution and are, however, to be protected by the patent law, provided they come within the scope of the appended claims.