PLURALITY OF HOST MATERIALS AND ORGANIC ELECTROLUMINESCENT DEVICE COMPRISING THE SAME

Abstract

The present disclosure relates to a plurality of host materials and an organic electroluminescent device comprising the same. An organic electroluminescent device with improved lifespan properties can be produced by comprising a specific combination of compounds according to the present disclosure as a plurality of host materials.

Claims

1. A plurality of host materials comprising at least one first host compound and at least one second host compound, wherein the first host compound is represented by the following formula 1, and the second host compound is represented by the following formula 2, and wherein at least one of the first host compound and the second host compound comprises deuterium: ##STR00237## in formula 1, X.sub.1 to X.sub.3, each independently, represent —N═ or —C(R)═, in which R represents hydrogen or deuterium; provided that at least two of X.sub.1 to X.sub.3 represent —N═; and Ar.sub.21 to Ar.sub.23, each independently, represent a (C6-C30)aryl unsubstituted or substituted with at least one of deuterium and a (C6-C30)aryl(s); provided that when Ar.sub.21 to Ar.sub.23, each independently, comprise fluorene, Ar.sub.21 to Ar.sub.23, each independently, are represented by the following formula 1-A, and at least one of Ar.sub.21 to Ar.sub.23 is represented by the following formula 1-A; ##STR00238## in formula 1-A, L.sub.21 represents a single bond, or a (C6-C30)arylene unsubstituted or substituted with at least one of deuterium and a (C6-C30)aryl(s); R.sub.11 and R.sub.12, each independently, represent a (C1-C30)alkyl unsubstituted or substituted with at least one of deuterium and a (C6-C30)aryl(s), or a (C6-C30)aryl unsubstuted or substituted with at least one of deuterium and a (C6-C30)aryl(s); and R.sub.21 to R.sub.28, each independently, represent hydrogen, deuterium, or a (C6-C30)aryl unsubstituted or substituted with at least one of deuterium and a (C6-C30)aryl(s), or may be linked to an adjacent substituent(s) to form a ring(s); ##STR00239## in formula 2, A.sub.1 and A.sub.2, each independently, represent a substituted or unsubstituted (C6-C30)aryl, a substituted or unsubstituted dibenzofuranyl, a substituted or unsubstituted dibenzothiophenyl, or a substituted or unsubstituted carbazolyl; any one of X.sub.15 to X.sub.18 and any one of X.sub.19 to X.sub.22 are linked to each other to form a single bond; and X.sub.11 to X.sub.14, X.sub.23 to X.sub.26, and X.sub.15 to X.sub.22 not forming a single bond, each independently, represent hydrogen, deuterium, a substituted or unsubstituted (C6-C30)aryl, or a substituted or unsubstituted (3- to 30-membered)heteroaryl; or may be linked to an adjacent substituent(s) to form a ring(s).

2. The plurality of host materials according to claim 1, wherein in formula 2, at least one of X.sub.11, X.sub.18, X.sub.19 and X.sub.26 is deuterium.

3. The plurality of host materials according to claim 1, wherein in formula 2, the deuterium substitution rate is 40% to 100%.

4. The plurality of host materials according to claim 1, wherein in formula 2, the deuterium substitution rate in X.sub.11 to X.sub.26 is 25% to 100%.

5. The plurality of host materials according to claim 1, wherein formula 2 is represented by at least one of the following formulas 2-1 to 2-8: ##STR00240## ##STR00241## in formulas 2-1 to 2-8, A.sub.1, A.sub.2, and X.sub.11 to X.sub.26 are as defined in claim 1.

6. The plurality of host materials according to claim 1, wherein A.sub.1 and A.sub.2, each independently, represents a phenyl unsubstituted or substituted with deuterium, a biphenyl unsubstituted or substituted with deuterium, a terphenyl unsubstituted or substituted with deuterium, a naphthyl unsubstituted or substituted with deuterium, a fluorenyl unsubstituted or substituted with deuterium, a benzofluorenyl unsubstituted or substituted with deuterium, a triphenylenyl unsubstituted or substituted with deuterium, a fluoranthenyl unsubstituted or substituted with deuterium, a phenanthrenyl unsubstituted or substituted with deuterium, a chrysenyl unsubstituted or substituted with deuterium, a dibenzofuranyl unsubstituted or substituted with deuterium, a carbazolyl unsubstituted or substituted with deuterium, a dibenzothiophenyl unsubstituted or substituted with deuterium, or a combination thereof.

7. The plurality of host materials according to claim 1, wherein formula 1 is represented by at least one of the following formulas 1-1 to 1-4: ##STR00242## in formulas 1-1 to 1-4, Ar.sub.21, Ar.sub.22, R.sub.11, R.sub.12, R.sub.21 to R.sub.28, L.sub.21, X.sub.1 and X.sub.2 are as defined in claim 1.

8. The plurality of host materials according to claim 1, wherein the compound represented by formula 1 is at least one selected from the following compounds: ##STR00243## ##STR00244## ##STR00245## ##STR00246## ##STR00247## ##STR00248## ##STR00249## ##STR00250## ##STR00251## ##STR00252## ##STR00253## ##STR00254## ##STR00255## ##STR00256## ##STR00257## ##STR00258## ##STR00259##

9. The plurality of host materials according to claim 1, wherein the compound represented by formula 2 is at least one selected from the following compounds: ##STR00260## ##STR00261## ##STR00262## ##STR00263## ##STR00264## ##STR00265## ##STR00266## ##STR00267## ##STR00268## ##STR00269## ##STR00270## ##STR00271## ##STR00272## ##STR00273## ##STR00274## ##STR00275## ##STR00276## ##STR00277## ##STR00278## ##STR00279## ##STR00280## ##STR00281## ##STR00282## ##STR00283## ##STR00284## ##STR00285## ##STR00286## ##STR00287## ##STR00288## ##STR00289## ##STR00290## ##STR00291## ##STR00292## ##STR00293## ##STR00294## ##STR00295## ##STR00296## ##STR00297## ##STR00298## ##STR00299## ##STR00300## ##STR00301## ##STR00302## ##STR00303## ##STR00304## ##STR00305## ##STR00306## ##STR00307## ##STR00308## ##STR00309## ##STR00310## ##STR00311## ##STR00312## ##STR00313## ##STR00314## ##STR00315## ##STR00316## ##STR00317## ##STR00318## ##STR00319## ##STR00320## ##STR00321## ##STR00322## ##STR00323## ##STR00324## ##STR00325## ##STR00326## ##STR00327## ##STR00328## ##STR00329## ##STR00330## ##STR00331## ##STR00332## ##STR00333## ##STR00334## ##STR00335## ##STR00336## ##STR00337## ##STR00338## ##STR00339## ##STR00340## ##STR00341## ##STR00342## ##STR00343## ##STR00344## ##STR00345## ##STR00346## ##STR00347## ##STR00348## ##STR00349## ##STR00350## ##STR00351## ##STR00352## ##STR00353## ##STR00354## ##STR00355## ##STR00356## ##STR00357## ##STR00358## ##STR00359## ##STR00360## ##STR00361## ##STR00362## ##STR00363## ##STR00364## ##STR00365## ##STR00366## ##STR00367## ##STR00368## ##STR00369## ##STR00370## ##STR00371## ##STR00372## ##STR00373## ##STR00374## ##STR00375## ##STR00376## ##STR00377## ##STR00378## ##STR00379## ##STR00380## ##STR00381## ##STR00382## ##STR00383## ##STR00384## ##STR00385## ##STR00386## wherein D.sub.n means that n number of hydrogens are substituted with deuterium, n is an integer of 1 or more, and the number of hydrogens in each compound is the maximum value.

10. An organic electroluminescent device comprising the plurality of host materials according to claim 1.

Description

MODE FOR THE INVENTION

[0018] Hereinafter, the present disclosure will be described in detail. However, the following description is intended to explain the present disclosure, and is not meant to restrict the scope of the present disclosure.

[0019] The term “organic electroluminescent material” in the present disclosure means a material that may be used in an organic electroluminescent device, and may comprise at least one compound. The organic electroluminescent material may be comprised in any layer constituting an organic electroluminescent device, as necessary. For example, the organic electroluminescent material may be a hole injection material, a hole transport material, a hole auxiliary material, a light-emitting auxiliary material, an electron blocking material, a light-emitting material (including a host material and a dopant material), an electron buffer material, a hole blocking material, an electron transport material, an electron injection material, etc.

[0020] The term “a plurality of host materials” in the present disclosure means a host material(s) comprising a combination of two or more compounds, which may be comprised in any light-emitting layer constituting an organic electroluminescent device. It may mean both a material before being comprised in an organic electroluminescent device (for example, before vapor deposition) and a material after being comprised in an organic electroluminescent device (for example, after vapor deposition). For example, a plurality of host materials in the present disclosure may be a combination of two or more types of host materials, and may optionally further comprise a conventional material comprised in the organic electroluminescent material. Two or more compounds comprised in the plurality of host materials of the present disclosure may be comprised together in one light-emitting layer or may be respectively comprised in different light-emitting layers. For example, the two or more host materials may be mixture-evaporated or co-evaporated, or may be individually evaporated.

[0021] Herein, the term “(C1-C30)alkyl” is meant to be a linear or branched alkyl having 1 to 30 carbon atoms constituting the chain, in which the number of carbon atoms is preferably 1 to 10, and more preferably 1 to 6. The above alkyl may include methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, tert-butyl, sec-butyl, etc. The term “(C3-C30)cycloalkyl” is meant to be a mono- or polycyclic hydrocarbon having 3 to 30 ring backbone carbon atoms, in which the number of carbon atoms is preferably 3 to 20, and more preferably 3 to 7. The above cycloalkyl may include cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cyclopentylmethyl, cyclohexylmethyl, etc. The term “(3- to 7-membered)heterocycloalkyl” in the present disclosure is meant to be a cycloalkyl having 3 to 7 ring backbone atoms, and containing at least one heteroatom(s) selected from the group consisting of B, N, O, S, Si, and P, preferably the group consisting of O, S, and N. The above heterocycloalkyl includes tetrahydrofuran, pyrrolidine, thiolane, tetrahydropyran, etc. The term “(C6-C30)aryl(ene)” in the present disclosure is meant to be a monocyclic or fused ring radical derived from an aromatic hydrocarbon having 6 to 30 ring backbone carbon atoms. The above aryl may be partially saturated, and may comprise a spiro structure. The above aryl may include phenyl, biphenyl, terphenyl, naphthyl, binaphthyl, phenylnaphthyl, naphthylphenyl, fluorenyl, phenylfluorenyl, diphenylfluorenyl, benzofluorenyl, dibenzofluorenyl, phenantrenyl, phenylphenanthrenyl, anthracenyl, indenyl, triphenylenyl, pyrenyl, tetracenyl, perylenyl, chrysenyl, naphthacenyl, fluoranthenyl, spirobifluorenyl, spiro[fluorene-benzofluorene]yl, azulenyl, tetramethyldihydrophenanthrenyl, etc. Specifically, the above aryl may include phenyl, 1-naphthyl, 2-naphthyl, 1-anthryl, 2-anthryl, 9-anthryl, benzanthryl, 1-phenanthryl, 2-phenanthryl, 3-phenanthryl, 4-phenanthryl, 9-phenanthryl, naphthacenyl, pyrenyl, 1-chrysenyl, 2-chrysenyl, 3-chrysenyl, 4-chrysenyl, 5-chrysenyl, 6-chrysenyl, benzo[c]phenanthryl, benzo[g]chrysenyl, 1-triphenylenyl, 2-triphenylenyl, 3-triphenylenyl, 4-triphenylenyl, 1-fluorenyl, 2-fluorenyl, 3-fluorenyl, 4-fluorenyl, 9-fluorenyl, benzo[a]fluorenyl, benzo[b]fluorenyl, benzo[c]fluorenyl, dibenzofluorenyl, 2-biphenylyl, 3-biphenylyl, 4-biphenylyl, o-terphenyl, m-terphenyl-4-yl, m-terphenyl-3-yl, m-terphenyl-2-yl, p-terphenyl-4-yl, p-terphenyl-3-yl, p-terphenyl-2-yl, m-quaterphenyl, 3-fluoranthenyl, 4-fluoranthenyl, 8-fluoranthenyl, 9-fluoranthenyl, benzofluoranthenyl, o-tolyl, m-tolyl, p-tolyl, 2,3-xylyl, 3,4-xylyl, 2,5-xylyl, mesityl, o-cumenyl, m-cumenyl, p-cumenyl, p-tert-butylphenyl, p-(2-phenylpropyl)phenyl, 4′-methylbiphenyl, 4″-tert-butyl-p-terphenyl-4-yl, 9,9-dimethyl-1-fluorenyl, 9,9-dimethyl-2-fluorenyl, 9,9-dimethyl-3-fluorenyl, 9,9-dimethyl-4-fluorenyl, 9,9-diphenyl-1-fluorenyl, 9,9-diphenyl-2-fluorenyl, 9,9-diphenyl-3-fluorenyl, 9,9-diphenyl-4-fluorenyl, 11,11-dimethyl-1-benzo[a]fluorenyl, 11,11-dimethyl-2-benzo[a]fluorenyl, 11,11-dimethyl-3-benzo[a]fluorenyl, 11,11-dimethyl-4-benzo[a]fluorenyl, 11,11-dimethyl-5-benzo[a]fluorenyl, 11,11-dimethyl-6-benzo[a]fluorenyl, 11,11-dimethyl-7-benzo[a]fluorenyl, 11,11-dimethyl-8-benzo[a]fluorenyl, 11,11-dimethyl-9-benzo[a]fluorenyl, 11,11-dimethyl-10-benzo[a]fluorenyl, 11,11-dimethyl-1-benzo[b]fluorenyl, 11,11-dimethyl-2-benzo[b]fluorenyl, 11,11-dimethyl-3-benzo[b]fluorenyl, 11,11-dimethyl-4-benzo[b]fluorenyl, 11,11-dimethyl-5-benzo[b]fluorenyl, 11,11-dimethyl-6-benzo[b]fluorenyl, 11,11-dimethyl-7-benzo[b]fluorenyl, 11,11-dimethyl-8-benzo[b]fluorenyl, 11,11-dimethyl-9-benzo[b]fluorenyl, 11,11-dimethyl-10-benzo[b]fluorenyl, 11,11-dimethyl-1-benzo[c]fluorenyl, 11,11-dimethyl-2-benzo[c]fluorenyl, 11,11-dimethyl-3-benzo[c]fluorenyl, 11,11-dimethyl-4-benzo[c]fluorenyl, 11,11-dimethyl-5-benzo[c]fluorenyl, 11,11-dimethyl-6-benzo[c]fluorenyl, 11,11-dimethyl-7-benzo[c]fluorenyl, 11,11-dimethyl-8-benzo[c]fluorenyl, 11,11-dimethyl-9-benzo[c]fluorenyl, 11,11-dimethyl-10-benzo[c]fluorenyl, 11,11-diphenyl-1-benzo[a]fluorenyl, 11,11-diphenyl-2-benzo[a]fluorenyl, 11,11-diphenyl-3-benzo[a]fluorenyl, 11,11-diphenyl-4-benzo[a]fluorenyl, 11,11-diphenyl-5-benzo[a]fluorenyl, 11,11-diphenyl-6-benzo[a]fluorenyl, 11,11-diphenyl-7-benzo[a]fluorenyl, 11,11-diphenyl-8-benzo[a]fluorenyl, 11,11-diphenyl-9-benzo[a]fluorenyl, 11,11-diphenyl-10-benzo[a]fluorenyl, 11,11-diphenyl-1-benzo[b]fluorenyl, 11,11-diphenyl-2-benzo[b]fluorenyl, 11,11-diphenyl-3-benzo[b]fluorenyl, 11,11-diphenyl-4-benzo[b]fluorenyl, 11,11-diphenyl-5-benzo[b]fluorenyl, 11,11-diphenyl-6-benzo[b]fluorenyl, 11,11-diphenyl-7-benzo[b]fluorenyl, 11,11-diphenyl-8-benzo[b]fluorenyl, 11,11-diphenyl-9-benzo[b]fluorenyl, 11,11-diphenyl-10-benzo[b]fluorenyl, 11,11-diphenyl-1-benzo[c]fluorenyl, 11,11-diphenyl-2-benzo[c]fluorenyl, 11,11-diphenyl-3-benzo[c]fluorenyl, 11,11-diphenyl-4-benzo[c]fluorenyl, 11,11-diphenyl-5-benzo[c]fluorenyl, 11,11-diphenyl-6-benzo[c]fluorenyl, 11,11-diphenyl-7-benzo[c]fluorenyl, 11,11-diphenyl-8-benzo[c]fluorenyl, 11,11-diphenyl-9-benzo[c]fluorenyl, 11,11-diphenyl-10-benzo[c]fluorenyl, 9,9,10,10-tetramethyl-9,10-dihydro-1-phenanthrenyl, 9,9,10,10-tetramethyl-9,10-dihydro-2-phenanthrenyl, 9,9,10,10-tetramethyl-9,10-dihydro-3-phenanthrenyl, 9,9,10,10-tetramethyl-9,10-dihydro-4-phenanthrenyl, etc.

[0022] The term “(3- to 30-membered)heteroaryl” in the present disclosure means an aryl group or an arylene group having 3 to 30 ring backbone atoms and including at least one, preferably 1 to 4 heteroatom(s) selected from the group consisting of B, N, O, S, Si, and P. It may be a monocyclic ring or a fused ring condensed with at least one benzene ring, and may be partially saturated. In addition, the above heteroaryl comprises one formed by linking at least one heteroaryl or aryl group to a heteroaryl group via a single bond(s), and may comprise a spiro structure. The above heteroaryl may include a monocyclic ring-type heteroaryl such as furyl, thiophenyl, pyrrolyl, imidazolyl, pyrazolyl, thiazolyl, thiadiazolyl, isothiazolyl, isoxazolyl, oxazolyl, oxadiazolyl, triazinyl, tetrazinyl, triazolyl, tetrazolyl, furazanyl, pyridyl, pyrazinyl, pyrimidinyl, pyridazinyl, etc., and a fused ring-type heteroaryl such as benzofuranyl, benzothiophenyl, isobenzofuranyl, dibenzofuranyl, dibenzothiophenyl, dibenzoselenophenyl, naphthobenzofuranyl, naphthobenzothiophenyl, benzofuroquinolinyl, benzofuroquinazolinyl, benzofuronaphthyridinyl, benzofuropyrimidinyl, naphthofuropyrimidinyl, benzothienoquinolinyl, benzothienoquinazolinyl, benzothienonaphthyridinyl, benzothienopyrimidinyl, naphthothienopyrimidinyl, pyrimidoindolyl, benzopyrimidoindolyl, benzofuropyrazinyl, naphthofuropyrazinyl, benzothienopyrazinyl, naphthothienopyrazinyl, pyrazinoindolyl, benzopyrazinoindolyl, benzoimidazolyl, benzothiazolyl, benzoisothiazolyl, benzoisoxazolyl, benzoxazolyl, isoindolyl, indolyl, indazolyl, benzothiadiazolyl, quinolyl, isoquinolyl, cinnolinyl, quinazolinyl, quinoxalinyl, carbazolyl, benzocarbazolyl, dibenzocarbazolyl, phenoxazinyl, phenanthridinyl, benzodioxolyl, dihydroacridinyl, benzotriazolephenazine, imidazopyridine, chromenoquinazolinyl, thiochromenoquinazolinyl, dimethylbenzoperimidinyl, indolocarbazolyl, indenocarbazolyl, etc. More specifically, the heteroaryl may include 1-pyrrolyl, 2-pyrrolyl, 3-pyrrolyl, pyrazinyl, 2-pyridinyl, 2-pyrimidinyl, 4-pyrimidinyl, 5-pyrimidinyl, 6-pyrimidinyl, 1,2,3-triazin-4-yl, 1,2,4-triazin-3-yl, 1,3,5-triazin-2-yl, 1-imidazolyl, 2-imidazolyl, 1-pyrazolyl, 1-indolidinyl, 2-indolidinyl, 3-indolidinyl, 5-indolidinyl, 6-indolidinyl, 7-indolidinyl, 8-indolidinyl, 2-imidazopyridinyl, 3-imidazopyridinyl, 5-imidazopyridinyl, 6-imidazopyridinyl, 7-imidazopyridinyl, 8-imidazopyridinyl, 3-pyridinyl, 4-pyridinyl, 1-indolyl, 2-indolyl, 3-indolyl, 4-indolyl, 5-indolyl, 6-indolyl, 7-indolyl, 1-isoindolyl, 2-isoindolyl, 3-isoindolyl, 4-isoindolyl, 5-isoindolyl, 6-isoindolyl, 7-isoindolyl, 2-furyl, 3-furyl, 2-benzofuranyl, 3-benzofuranyl, 4-benzofuranyl, 5-benzofuranyl, 6-benzofuranyl, 7-benzofuranyl, 1-isobenzofuranyl, 3-isobenzofuranyl, 4-isobenzofuranyl, 5-isobenzofuranyl, 6-isobenzofuranyl, 7-isobenzofuranyl, 2-quinolyl, 3-quinolyl, 4-quinolyl, 5-quinolyl, 6-quinolyl, 7-quinolyl, 8-quinolyl, 1-isoquinolyl, 3-isoquinolyl, 4-isoquinolyl, 5-isoquinolyl, 6-isoquinolyl, 7-isoquinolyl, 8-isoquinolyl, 2-quinoxalinyl, 5-quinoxalinyl, 6-quinoxalinyl, 1-carbazolyl, 2-carbazolyl, 3-carbazolyl, 4-carbazolyl, 9-carbazolyl, azacabazolyl-1-yl, azacabazolyl-2-yl, azacabazolyl-3-yl, azacabazolyl-4-yl, azacabazolyl-5-yl, azacabazolyl-6-yl, azacabazolyl-7-yl, azacarbazolyl-8-yl, azacarbazolyl-9-yl, 1-phenanthridinyl, 2-phenanthridinyl, 3-phenanthridinyl, 4-phenanthridinyl, 6-phenanthridinyl, 7-phenanthridinyl, 8-phenanthridinyl, 9-phenanthridinyl, 10-phenanthridinyl, 1-acridinyl, 2-acridinyl, 3-acridinyl, 4-acridinyl, 9-acridinyl, 2-oxazolyl, 4-oxazolyl, 5-oxazolyl, 2-oxadiazolyl, 5-oxadiazolyl, 3-furazanyl, 2-thienyl, 3-thienyl, 2-methylpyrrol-1-yl, 2-methylpyrrol-3-yl, 2-methylpyrrol-4-yl, 2-methylpyrrol-5-yl, 3-methylpyrrol-1-yl, 3-methylpyrrol-2-yl, 3-methylpyrrol-4-yl, 3-methylpyrrol-5-yl, 2-tert-butylpyrrol-4-yl, 3-(2-phenylpropyl)pyrrol-1-yl, 2-methyl-1-indolyl, 4-methyl-1-indolyl, 2-methyl-3-indolyl, 4-methyl-3-indolyl, 2-tert-butyl-1-indolyl, 4-tert-butyl-1-indolyl, 2-tert-butyl-3-indolyl, 4-tert-butyl-3-indolyl, 1-dibenzofuranyl, 2-dibenzofuranyl, 3-dibenzofuranyl, 4-dibenzofuranyl, 1-dibenzothiophenyl, 2-dibenzothiophenyl, 3-dibenzothiophenyl, 4-dibenzothiophenyl, 1-naphtho-[1,2-b]-benzofuranyl, 2-naphtho-[1,2-b]-benzofuranyl, 3-naphtho-[1,2-b]-benzofuranyl, 4-naphtho-[1,2-b]-benzofuranyl, 5-naphtho-[1,2-b]-benzofuranyl, 6-naphtho-[1,2-b]-benzofuranyl, 7-naphtho-[1,2-b]-benzofuranyl, 8-naphtho-[1,2-b]-benzofuranyl, 9-naphtho-[1,2-b]-benzofuranyl, 10-naphtho-[1,2-b]-benzofuranyl, 1-naphtho-[2,3-b]-benzofuranyl, 2-naphtho-[2,3-b]-benzofuranyl, 3-naphtho-[2,3-b]-benzofuranyl, 4-naphtho-[2,3-b]-benzofuranyl, 5-naphtho-[2,3-b]-benzofuranyl, 6-naphtho-[2,3-b]-benzofuranyl, 7-naphtho-[2,3-b]-benzofuranyl, 8-naphtho-[2,3-b]-benzofuranyl, 9-naphtho-[2,3-b]-benzofuranyl, 10-naphtho-[2,3-b]-benzofuranyl, 1-naphtho-[2,1-b]-benzofuranyl, 2-naphtho-[2,1-b]-benzofuranyl, 3-naphtho-[2,1-b]-benzofuranyl, 4-naphtho-[2,1-b]-benzofuranyl, 5-naphtho-[2,1-b]-benzofuranyl, 6-naphtho-[2,1-b]-benzofuranyl, 7-naphtho-[2,1-b]-benzofuranyl, 8-naphtho-[2,1-b]-benzofuranyl, 9-naphtho-[2,1-b]-benzofuranyl, 10-naphtho-[2,1-b]-benzofuranyl, 1-naphtho-[1,2-b]-benzothiophenyl, 2-naphtho-[1,2-b]-benzothiophenyl, 3-naphtho-[1,2-b]-benzothiophenyl, 4-naphtho-[1,2-b]-benzothiophenyl, 5-naphtho-[1,2-b]-benzothiophenyl, 6-naphtho-[1,2-b]-benzothiophenyl, 7-naphtho-[1,2-b]-benzothiophenyl, 8-naphtho-[1,2-b]-benzothiophenyl, 9-naphtho-[1,2-b]-benzothiophenyl, 10-naphtho-[1,2-b]-benzothiophenyl, 1-naphtho-[2,3-b]-benzothiophenyl, 2-naphtho-[2,3-b]-benzothiophenyl, 3-naphtho-[2,3-b]-benzothiophenyl, 4-naphtho-[2,3-b]-benzothiophenyl, 5-naphtho-[2,3-b]-benzothiophenyl, 1-naphtho-[2,1-b]-benzothiophenyl, 2-naphtho-[2,1-b]-benzothiophenyl, 3-naphtho-[2,1-b]-benzothiophenyl, 4-naphtho-[2,1-b]-benzothiophenyl, 5-naphtho-[2,1-b]-benzothiophenyl, 6-naphtho-[2,1-b]-benzothiophenyl, 7-naphtho-[2,1-b]-benzothiophenyl, 8-naphtho-[2,1-b]-benzothiophenyl, 9-naphtho-[2,1-b]-benzothiophenyl, 10-naphtho-[2,1-b]benzothiophenyl, 2-benzofuro[3,2-d]pyrimidinyl, 6-benzofuro[3,2-d]pyrimidinyl, 7-benzofuro[3,2-d]pyrimidinyl, 8-benzofuro[3,2-d]pyrimidinyl, 9-benzofuro[3,2-d]pyrimidinyl, 2-benzothio[3,2-d]pyrimidinyl, 6-benzothio[3,2-d]pyrimidinyl, 7-benzothio[3,2-d]pyrimidinyl, 8-benzothio[3,2-d]pyrimidinyl, 9-benzothio[3,2-d]pyrimidinyl, 2-benzofuro[3,2-d]pyrazinyl, 6-benzofuro[3,2-d]pyrazinyl, 7-benzofuro[3,2-d]pyrazinyl, 8-benzofuro[3,2-d]pyrazinyl, 9-benzofuro[3,2-d]pyrazinyl, 2-benzothio[3,2-d]pyrazinyl, 6-benzothio[3,2-d]pyrazinyl, 7-benzothio[3,2-d]pyrazinyl, 8-benzothio[3,2-d]pyrazinyl, 9-benzothio[3,2-d]pyrazinyl, 1-silafluorenyl, 2-silafluorenyl, 3-silafluorenyl, 4-silafluorenyl, 1-germafluorenyl, 2-germafluorenyl, 3-germafluorenyl, 4-germafluorenyl, 1-dibenzoselenophenyl, 2-dibenzoselenophenyl, 3-dibenzoselenophenyl, 4-dibenzoselenophenyl, etc. In the present disclosure, “halogen” includes F, Cl, Br, and I.

[0023] In addition, “ortho (o-),” “meta (m-),” and “para (p-)” are prefixes, which represent the relative positions of substituents, respectively. Ortho indicates that two substituents are adjacent to each other, and for example, when two substituents in a benzene derivative occupy positions 1 and 2, it is called an ortho position. Meta indicates that two substituents are at positions 1 and 3, and for example, when two substituents in a benzene derivative occupy positions 1 and 3, it is called a meta position. Para indicates that two substituents are at positions 1 and 4, and for example, when two substituents in a benzene derivative occupy positions 1 and 4, it is called a para position.

[0024] In addition, “substituted” in the expression “substituted or unsubstituted” means that a hydrogen atom in a certain functional group is replaced with another atom or another functional group (i.e., a substituent), and also includes that the hydrogen atom is replaced with a group formed by a linkage of two or more substituents of the above substituents. For example, the “group formed by a linkage of two or more substituents” may be pyridine-triazine. That is, pyridine-triazine may be interpreted as a heteroaryl substituent, or as substituents in which two heteroaryls are linked. In the present disclosure, the substituent(s) of the substituted aryl, the substituted heteroaryl, the substituted dibenzofuranyl, the substituted dibenzothiophenyl, and the substituted carbazolyl independently are at least one selected from the group consisting of deuterium, a halogen, a cyano, a carboxyl, a nitro, a hydroxyl, a (C1-C30)alkyl, a halo(C1-C30)alkyl, a (C2-C30)alkenyl, a (C2-C30)alkynyl, a (C1-C30)alkoxy, a (C1-C30)alkylthio, a (C3-C30)cycloalkyl, a (C3-C30)cycloalkenyl, a (3- to 7-membered)heterocycloalkyl, a (C6-C30) aryloxy, a (C6-C30)arylthio, a (3- to 30-membered)heteroaryl unsubstituted or substituted with at least one of deuterium and a (C6-C30)aryl(s), a (C6-C30)aryl unsubstituted or substituted with at least one of deuterium and a (3- to 30-membered)heteroaryl(s), a tri(C1-C30)alkylsilyl, a tri(C6-C30)arylsilyl, a di(C1-C30)alkyl(C6-C30)arylsilyl, a (C1-C30)alkyldi(C6-C30)arylsilyl, a fused ring group of a (C3-C30)aliphatic ring(s) and a (C6-C30)aromatic ring(s), an amino, a mono- or di- (C1-C30)alkylamino, a mono- or di- (C2-C30)alkenylamino, a (C1-C30)alkyl(C2-C30)alkenylamino, a substituted or unsubstituted mono- or di- (C6-C30)arylamino, a (C1-C30)alkyl(C6-C30)arylamino, a mono- or di- (3- to 30-membered)heteroarylamino, a (C1-C30)alkyl(3- to 30-membered)heteroarylamino, a (C2-C30)alkenyl(C6-C30)arylamino, a (C2-C30)alkenyl(3- to 30-membered)heteroarylamino, a (C6-C30)aryl(3- to 30-membered)heteroarylamino, a (C1-C30)alkylcarbonyl, a (C1-C30)alkoxycarbonyl, a (C6-C30)arylcarbonyl, a (C6-C30)arylphosphinyl, a di(C6-C30)arylboronyl, a di(C1-C30)alkylboronyl, a (C1-C30)alkyl(C6-C30)arylboronyl, a (C6-C30)aryl(C1-C30)alkyl, and (C1-C30)alkyl(C6-C30) aryl, which may be further substituted with deuterium. According to one embodiment of the present disclosure, the substituent(s), each independently, are at least one selected from the group consisting of deuterium, a halogen, a (C1-C20)alkyl unsubstituted or substituted with deuterium, a (5- to 25-membered)heteroaryl unsubstituted or substituted with deuterium, and a (C6-C25)aryl unsubstituted or substituted with deuterium. According to another embodiment of the present disclosure, the substituent(s), each independently, are at least one selected from the group consisting of deuterium, a halogen, a (C1-C10)alkyl unsubstituted or substituted with deuterium, a (5- to 20-membered)heteroaryl unsubstituted or substituted with deuterium, and a (C6-C18)aryl unsubstituted or substituted with deuterium. For example, the substituent(s) may be at least one selected from the group consisting of deuterium, a fluoro, a methyl, a phenyl, a naphthyl, a biphenyl, a triphenylenyl, a dibenzofuranyl and a dibenzothiophenyl, wherein the above substituents may be further substituted with deuterium.

[0025] In the present disclosure, a ring formed by a linkage of adjacent substituents means that at least two adjacent substituents are linked to or fused with each other to form a substituted or unsubstituted mono- or polycyclic (3- to 30-membered) alicyclic or aromatic ring, or the combination thereof. The ring may be preferably a substituted or unsubstituted mono- or polycyclic (3- to 25-membered) alicyclic or aromatic ring, or the combination thereof, more preferably a mono- or polycyclic (5- to 25-membered) aromatic ring unsubstituted or substituted with at least one of a (C6-C18)aryl(s) and a (5- to 25-membered)heteroaryl(s). In addition, the formed ring may contain at least one heteroatom selected from B, N, O, S, Si, and P, preferably at least one heteroatom selected from N, O, and S. For example, the ring may be a benzene ring, a cyclopentane ring, an indan ring, a fluorene ring unsubstituted or substituted with a phenyl(s), a phenanthrene ring, an indole ring, a xanthene ring, etc.

[0026] In the present disclosure, heteroaryl and heterocycloalkyl, each independently, may contain at least one heteroatom(s) selected from B, N, O, S, Si, and P. In addition, the heteroatom may be combined with at least one selected from the group consisting of hydrogen, deuterium, a halogen, a cyano, a substituted or unsubstituted (C1-C30)alkyl, a substituted or unsubstituted (C6-C30)aryl, a substituted or unsubstituted (3- to 30-membered)heteroaryl, a substituted or unsubstituted (C3-C30)cycloalkyl, a substituted or unsubstituted (C1-C30)alkoxy, a substituted or unsubstituted tri(C6-C30)arylsilyl, a substituted or unsubstituted di(C1-C30)alkyl(C6-C30)arylsilyl, a substituted or unsubstituted (C1-C30)alkyldi(C6-C30)arylsilyl, a substituted or unsubstituted tri(C6-C30)arylsilyl, a substituted or unsubstituted mono- or di- (C1-C30)alkylamino, a substituted or unsubstituted mono- or di- (C2-C30)alkenylamino, a substituted or unsubstituted mono- or di- (C6-C30)arylamino, a substituted or unsubstituted mono- or di- (3- to 30-membered)heteroarylamino, a substituted or unsubstituted (C1-C30)alkyl(C2-C30)alkenylamino, a substituted or unsubstituted (C1-C30)alkyl(C6-C30)arylamino, a substituted or unsubstituted (C1-C30)alkyl(3- to 30-membered)heteroarylamino, a substituted or unsubstituted (C2-C30)alkenyl(C6-C30)arylamino, a substituted or unsubstituted (C2-C30)alkenyl(3- to 30-membered)heteroarylamino, and a substituted or unsubstituted (C6-C30)aryl(3- to 30-membered) heteroarylamino.

[0027] A plurality of host materials according to the present disclosure comprise a first host material and a second host material, wherein the first host material comprises at least one compound represented by formula 1, and the second host material comprises at least one compound represented by formula 2. According to one embodiment of the present disclosure, the compound represented by formula 1 and the compound represented by formula 2 are different from each other.

[0028] Hereinafter, the compound represented by formula 1 will be described in more detail.

[0029] In formula 1, X.sub.1 to X.sub.3, each independently, represent —N═ or —C(R)═, in which R represents hydrogen or deuterium; provided that at least two of X.sub.1 to X.sub.3 are —N═. According to one embodiment of the present disclosure, any two of X.sub.1 to X.sub.3 are —N═ and the other is —C(R)═. According to another embodiment of the present disclosure, X.sub.1 to X.sub.3 are all —N═.

[0030] In formula 1, Ar.sub.21 to Ar.sub.23, each independently, represent a (C6-C30)aryl unsubstituted or substituted with at least one of deuterium and a (C6-C30)aryl(s). According to one embodiment of the present disclosure, Ar.sub.21 to Ar.sub.23 each independently represent a (C6-C25)aryl unsubstituted or substituted with at least one of deuterium and a (C6-C18)aryl(s). However, when Ar.sub.21 to Ar.sub.23, each independently, comprise fluorene, Ar.sub.21 to Ar.sub.23, each independently, are represented by formula 1-A. In addition, at least one of Ar.sub.21 to Ar.sub.23 is represented by formula 1-A. For example, Ar.sub.21 to Ar.sub.23 may each independently be represented by formula 1-A, or may be a phenyl, a naphthyl, a biphenyl, a terphenyl, or a quaterphenyl, which may be substituted with deuterium.

[0031] In formula 1-A, L.sub.21 represents a single bond, or a (C6-C30)arylene unsubstituted or substituted with at least one of deuterium and a (C6-C30)aryl(s). According to one embodiment of the present disclosure, L.sub.21 represents a single bond, or a (C6-C25)arylene unsubstituted or substituted with at least one of deuterium and a (C6-C25)aryl(s). According to another embodiment of the present disclosure, L.sub.21 represents a single bond; or a (C6-C25)arylene unsubstituted or substituted with at least one of deuterium and a (C6-C18)aryl(s). For example, L.sub.21 may be a single bond; a phenylene unsubstituted or substituted with a phenyl(s) or a biphenyl(s); a biphenylene; or a terphenylene, etc., which may be further substituted with deuterium.

[0032] In formula 1-A, R.sub.11 and R.sub.12 each independently represent a (C1-C30)alkyl unsubstituted or substituted with at least one of deuterium and a (C6-C30)aryl(s), or a (C6-C30)aryl unsubstuted or substituted with at least one of deuterium and a (C6-C30)aryl(s). According to one embodiment of the present disclosure, R.sub.11 and R.sub.12 each independently represent a (C1-C20)alkyl unsubstituted or substituted with deuterium, or a (C6-C25)aryl unsubstuted or substituted with deuterium. According to another embodiment of the present disclosure, R.sub.11 and R.sub.12 each independently represent a (C1-C10)alkyl unsubstituted or substituted with deuterium, or a (C6-C18)aryl unsubstuted or substituted with deuterium. According to still another embodiment of the present disclosure, R.sub.11 and R.sub.12 each independently represent a substituted or unsubstituted (C1-C30)alkyl, a substituted or unsubstituted (C6-C30)aryl, or a substituted or unsubstituted (3- to 30-membered)heteroaryl; or may be linked to each other to form a ring(s). For example, R.sub.11 and R.sub.12 each independently may be a methyl or a phenyl, etc. unsubstituted or substituted with deuterium.

[0033] In formula 1-A, R.sub.21 to R.sub.28 each independently represent hydrogen; deuterium; a halogen; or a (C6-C30)aryl unsubstituted or substituted with at least one of deuterium, a halogen(s) and a (C6-C30)aryl(s); or may be linked to an adjacent substituent(s) to form a ring(s). According to one embodiment of the present disclosure, R.sub.21 to R.sub.28 each independently represent hydrogen, deuterium, a halogen, or a (C6-C25)aryl unsubstituted or substituted with deuterium. According to another embodiment of the present disclosure, R.sub.21 to R.sub.28 each independently represent hydrogen, deuterium, a halogen, or a (C6-C18)aryl unsubstituted or substituted with deuterium. For example, R.sub.21 to R.sub.28 each independently may be hydrogen, deuterium, a halogen, a phenyl unsubstituted or substituted with deuterium, a biphenyl unsubstituted or substituted with deuterium, a terphenyl unsubstituted or substituted with deuterium, etc.

[0034] According to one embodiment of the present disclosure, formula 1 may be represented by at least one of the following formulas 1-1 to 1-4.

##STR00004##

[0035] In formulas 1-1 to 1-4, the definitions and preferred embodiments of Ar.sub.21, Ar.sub.22, R.sub.11, R.sub.12, R.sub.21 to R.sub.28, L.sub.21, X.sub.1 and X.sub.2 are as defined in formulas 1 and 1-A.

[0036] The compound represented by formula 1 may be at least one selected from the following compounds, but is not limited thereto.

##STR00005## ##STR00006## ##STR00007## ##STR00008## ##STR00009## ##STR00010## ##STR00011## ##STR00012## ##STR00013## ##STR00014## ##STR00015## ##STR00016## ##STR00017## ##STR00018## ##STR00019## ##STR00020## ##STR00021## ##STR00022## ##STR00023## ##STR00024## ##STR00025## ##STR00026## ##STR00027## ##STR00028## ##STR00029## ##STR00030## ##STR00031## ##STR00032## ##STR00033## ##STR00034## ##STR00035## ##STR00036## ##STR00037## ##STR00038## ##STR00039## ##STR00040## ##STR00041## ##STR00042## ##STR00043##

[0037] Hereinafter, the compound represented by formula 2 will be described in more detail.

[0038] In formula 2, A.sub.1 and A.sub.2, each independently, represent a substituted or unsubstituted (C6-C30)aryl, a substituted or unsubstituted dibenzofuranyl, a substituted or unsubstituted dibenzothiophenyl, or a substituted or unsubstituted carbazolyl. According to one embodiment of the present disclosure, A.sub.1 and A.sub.2, each independently, represent a substituted or unsubstituted (C6-C25)aryl, a substituted or unsubstituted dibenzofuranyl, a substituted or unsubstituted dibenzothiophenyl, or a substituted or unsubstituted carbazolyl, of which the substituent(s), each independently, may be at least one of deuterium, a halogen, a (C6-C30)aryl, and a (3- to 30-membered)heteroaryl. According to another embodiment of the present disclosure, A.sub.1 and A.sub.2, each independently, represent a (C6-C25)aryl unsubstituted or substituted with at least one of deuterium, a halogen, a (C6-C18)aryl(s), a dibenzofuranyl(s), a dibenzothiophenyl(s) and a carbazolyl(s); a dibenzofuranyl unsubstituted or substituted with at least one of deuterium, a halogen(s), and a (C6-C18)aryl(s); a dibenzothiophenyl unsubstituted or substituted with at least one of deuterium, a halogen, and a (C6-C18)aryl(s); or a carbazolyl unsubstituted or substituted with at least one of deuterium, a halogen(s), and a (C6-C18)aryl(s). Specifically, A.sub.1 and A.sub.2, each independently, may be a phenyl unsubstituted or substituted with deuterium, a biphenyl unsubstituted or substituted with deuterium, a terphenyl unsubstituted or substituted with deuterium, a naphthyl unsubstituted or substituted with deuterium, a fluorenyl unsubstituted or substituted with deuterium, a benzofluorenyl unsubstituted or substituted with deuterium, a triphenylenyl unsubstituted or substituted with deuterium, a fluoranthenyl unsubstituted or substituted with deuterium, a phenanthrenyl unsubstituted or substituted with deuterium, a chrysenyl unsubstituted or substituted with deuterium, a dibenzofuranyl unsubstituted or substituted with deuterium, a carbazolyl unsubstituted or substituted with deuterium, a dibenzothiophenyl unsubstituted or substituted with deuterium, or a combination thereof. For example, A.sub.1 and A.sub.2, each independently, may be a phenyl unsubstituted or substituted with at least one of a fluoro(s), a triphenylenyl(s), a dibenzofuranyl(s) and a dibenzothiophenyl(s); a biphenyl; a naphthyl; a naphthylphenyl; a phenylnaphthyl; a terphenyl; a triphenylenyl; a dibenzofuranyl unsubstituted or substituted with a phenyl(s); a dibenzothiophenyl unsubstituted or substituted with a phenyl(s); a carbazolyl unsubstituted or substituted with a phenyl(s), etc., which may be further substituted with deuterium.

[0039] In formula 2, any one of X.sub.15 to X.sub.18 and any one of X.sub.19 to X.sub.22 are linked to each other to form a single bond. X.sub.11 to X.sub.14, X.sub.23 to X.sub.26, and X.sub.15 to X.sub.22 not forming a single bond, each independently, represent hydrogen, deuterium, a halogen, a substituted or unsubstituted (C6-C30)aryl, or a substituted or unsubstituted (3- to 30-membered)heteroaryl; or may be linked to an adjacent substituent(s) to form a ring(s). According to one embodiment of the present disclosure, X.sub.11 to X.sub.26, each independently, represent hydrogen, deuterium, or a fluoro. According to another embodiment of the present disclosure, at least one of X.sub.11, X.sub.18, X.sub.19 and X.sub.26 represents deuterium. According to still another embodiment of the present disclosure, at least four of X.sub.11 to X.sub.26 represent deuterium, and at least one of X.sub.11, X.sub.18, X.sub.19 and X.sub.26 represent deuterium. According to much another embodiment of the present disclosure, at least eight of X.sub.11 to X.sub.26 represent deuterium, or all of X.sub.11 to X.sub.26 represent deuterium. According to one embodiment of the present disclosure, at least any two of X.sub.11, X.sub.18, X.sub.19 and X.sub.26 represent deuterium, at least any three represent deuterium, or all of X.sub.11, X.sub.18, X.sub.19 and X.sub.26 represent deuterium.

[0040] According to one embodiment of the present disclosure, in one compound represented by formula 2, the deuterium substitution rate may be about 40% to about 100%, preferably about 50% to about 100%, more preferably about 60% to about 100%, further more preferably about 70% to about 100%.

[0041] According to one embodiment of the present disclosure, in one compound represented by formula 2, the deuterium substitution rate in X.sub.11 to X.sub.26 may be about 25% to about 100%, preferably about 35% to about 100%, more preferably about 45% to about 100%, further more preferably about 55% to about 100%.

[0042] According to one embodiment of the present disclosure, formula 2 may be represented by at least one of the following formulas 2-1 to 2-8.

##STR00044## ##STR00045##

[0043] In formulas 2-1 to 2-8, the definitions and preferred embodiments of A.sub.1, A.sub.2, and X.sub.11 to X.sub.26 are as defined in formula 2.

[0044] The compound represented by formula 2 may be at least one selected from the following compounds, but is not limited thereto.

##STR00046## ##STR00047## ##STR00048## ##STR00049## ##STR00050## ##STR00051## ##STR00052## ##STR00053## ##STR00054## ##STR00055## ##STR00056## ##STR00057## ##STR00058## ##STR00059## ##STR00060## ##STR00061## ##STR00062## ##STR00063## ##STR00064## ##STR00065## ##STR00066## ##STR00067## ##STR00068## ##STR00069## ##STR00070## ##STR00071## ##STR00072## ##STR00073## ##STR00074## ##STR00075## ##STR00076## ##STR00077## ##STR00078## ##STR00079## ##STR00080## ##STR00081## ##STR00082## ##STR00083## ##STR00084## ##STR00085## ##STR00086## ##STR00087## ##STR00088## ##STR00089## ##STR00090## ##STR00091## ##STR00092## ##STR00093## ##STR00094## ##STR00095## ##STR00096## ##STR00097## ##STR00098## ##STR00099## ##STR00100## ##STR00101## ##STR00102## ##STR00103## ##STR00104## ##STR00105## ##STR00106## ##STR00107## ##STR00108## ##STR00109## ##STR00110## ##STR00111## ##STR00112## ##STR00113## ##STR00114## ##STR00115## ##STR00116## ##STR00117## ##STR00118## ##STR00119## ##STR00120## ##STR00121## ##STR00122## ##STR00123## ##STR00124##

##STR00125## ##STR00126## ##STR00127## ##STR00128## ##STR00129## ##STR00130## ##STR00131## ##STR00132## ##STR00133## ##STR00134## ##STR00135## ##STR00136## ##STR00137## ##STR00138## ##STR00139## ##STR00140## ##STR00141## ##STR00142## ##STR00143## ##STR00144## ##STR00145## ##STR00146## ##STR00147## ##STR00148## ##STR00149## ##STR00150## ##STR00151## ##STR00152## ##STR00153## ##STR00154## ##STR00155## ##STR00156## ##STR00157## ##STR00158## ##STR00159## ##STR00160## ##STR00161## ##STR00162## ##STR00163## ##STR00164## ##STR00165## ##STR00166## ##STR00167## ##STR00168## ##STR00169## ##STR00170## ##STR00171## ##STR00172## ##STR00173## ##STR00174## ##STR00175## ##STR00176## ##STR00177## ##STR00178## ##STR00179## ##STR00180## ##STR00181## ##STR00182## ##STR00183##

[0045] In compounds H2-1 to H2-145, D.sub.n means that n number of hydrogens are substituted with deuterium, n is an integer of 1 or more, and the number of hydrogens in each compound is the maximum value. According to one embodiment of the present disclosure, n is an integer of 4 or more, preferably an integer of 8 or more and more preferably an integer of 16 or more. When deuterated to a number equal to or greater than the lower limit, bond dissociation energy due to deuteration increases to increase the stability of the compound, and when the compound is used in an organic electroluminescent device, the device may exhibit improved lifespan characteristics. The upper limit of n is determined by the number of hydrogens that can be substituted in each compound.

[0046] A combination of at least one of compounds H1-1 to H1-125 and at least one of compounds H2-1 to H2-290 may be used in an organic electroluminescent device.

[0047] The compounds represented by formulas 1 and 2 according to one embodiment of the present disclosure may be produced by synthetic methods known to a person skilled in the art. For example, the compound represented by formula 1 according to the present disclosure may be produced by referring to the following Reaction Scheme 1, and the compound represented by formula 2 according to the present disclosure may be produced by referring to the following Reaction Scheme 2, but is not limited thereto.

##STR00184##

[0048] In Reaction Scheme 1, R.sub.21 to R.sub.24, R.sub.11, R.sub.12, Ar.sub.21, Ar.sub.22, L.sub.21, X.sub.1, to X.sub.3 are as defined in formulas 1 and 1-A; R′ is as defined for R.sub.25 to R.sub.28; a represents an integer of 1 to 3, where if a is 2 or more, each of R′ may be the same as or different from each other; R represents hydrogen or a (C1-C30)alkyl; and Hal represents a halogen.

##STR00185##

[0049] In Reaction Scheme 2, A.sub.1, A.sub.2, and X.sub.11 to X.sub.26 are as defined in formula 2, Dn means that n hydrogens have been replaced by deuterium.

[0050] Although illustrative synthesis examples of the compounds represented by formulas 1 and 2 are described above, one skilled in the art will be able to readily understand that all of them are based on a Buchwald-Hartwig cross coupling reaction, an N-arylation reaction, a H-mont-mediated etherification reaction, a Miyaura borylation reaction, a Suzuki cross-coupling reaction, an Intramolecular acid-induced cyclization reaction, a Pd(II)-catalyzed oxidative cyclization reaction, a Grignard reaction, a Heck reaction, a Cyclic Dehydration reaction, an SN.sub.1 substitution reaction, an SN.sub.2 substitution reaction, and a Phosphine-mediated reductive cyclization reaction, etc., and the above reactions proceed even when substituents defined in formulas 1 or 2 other than the substituents specified in the specific synthesis examples, are bonded.

[0051] In addition, the deuterated compounds herein can be prepared in a similar manner using deuterated precursor materials, or more commonly, can be prepared by treating non-deuterated compounds with a deuterated solvent, D6-benzene, in the presence of a Lewis acid H/D exchange catalyst such as aluminum trichloride or ethyl aluminum chloride. Also, the degree of deuteration can be controlled by varying reaction conditions such as reaction temperature. For example, the number of deuterium atoms in the compound can be controlled by adjusting the reaction temperature and time, the equivalent of acid, etc.

[0052] An organic electroluminescent device according to the present disclosure comprises an anode, a cathode, and at least one light-emitting layer between the anode and the cathode. At least one layer of the light-emitting layer comprises a host and a dopant, wherein the host comprises a plurality of host materials, the compound represented by formula 1 may be comprised as a first host compound of the plurality of host materials, and the compound represented by formula 2 may be comprised as a second host compound of the plurality of host materials. Herein, the weight ratio of the first host compound to the second host compound is about 1:99 to about 99:1, preferably about 10:90 to about 90:10, more preferably about 30:70 to about 70:30, still more preferably about 40:60 to about 60:40, even more preferably about 50:50.

[0053] In the present disclosure, the light-emitting layer is a layer from which light is emitted, and can be a single layer or a multi-layer in which two or more layers are stacked. In the plurality of host materials of the present disclosure, both the first and second host materials may be comprised in one layer, or the first and second host materials may be respectively comprised in different light-emitting layers. According to one embodiment of the present disclosure, the doping concentration of the dopant compound with respect to the host compound of the light-emitting layer may be less than 20 wt %.

[0054] The organic electroluminescent device of the present disclosure may further comprise at least one layer selected from a hole injection layer, a hole transport layer, a hole auxiliary layer, a light-emitting auxiliary layer, an electron transport layer, an electron injection layer, an interlayer, an electron buffer layer, a hole blocking layer, and an electron blocking layer. According to one embodiment of the present disclosure, the organic electroluminescent device of the present disclosure may further comprise an amine-based compound as at least one of a hole injection material, a hole transport material, a hole auxiliary material, a light-emitting material, a light-emitting auxiliary material, and an electron blocking material besides the plurality of host materials of the present disclosure. Also, according to one embodiment of the present disclosure, the organic electroluminescent device of the present disclosure may further comprise an azine-based compound as at least one of an electron transport material, an electron injection material, an electron buffer material and a hole blocking material besides the plurality of host materials of the present disclosure.

[0055] The dopants comprised in the organic electroluminescent device of the present disclosure may be at least one phosphorescent or fluorescent dopant, and is preferably a phosphorescent dopant. The phosphorescent dopant materials applied to the organic electroluminescent device according to the present disclosure are not particularly limited, but may be a complex compound of a metal atom selected from iridium (Ir), osmium (Os), copper (Cu), and platinum (Pt), preferably ortho-metallated complex compounds of a metal atom selected from iridium (Ir), osmium (Os), copper (Cu), and platinum (Pt), and more preferably ortho-metallated iridium complex compounds.

[0056] The dopant comprised in the organic electroluminescent device of the present disclosure may be a compound represented by the following formula 101, but is not limited thereto.

##STR00186##

[0057] In formula 101,

[0058] L is selected from the following structures 1 to 3;

##STR00187##

[0059] R.sub.100 to R.sub.103 each independently represent hydrogen, deuterium, a halogen, a (C1-C30)alkyl unsubstituted or substituted with deuterium and/or a halogen(s), a substituted or unsubstituted (C3-C30)cycloalkyl, a substituted or unsubstituted (C6-C30)aryl, a cyano, a substituted or unsubstituted (3- to 30-membered)heteroaryl, or a substituted or unsubstituted (C1-C30)alkoxy; or adjacent two or more of R.sub.100 to R.sub.103 may be linked to each other to form a ring(s), for example, a substituted or unsubstituted quinoline, a substituted or unsubstituted benzofuropyridine, a substituted or unsubstituted benzothienopyridine, a substituted or unsubstituted indenopyridine, a substituted or unsubstituted benzofuroquinoline, a substituted or unsubstituted benzothienoquinoline, or a substituted or unsubstituted indenoquinoline, together with pyridine;

[0060] R.sub.104 to R.sub.107 each independently represent hydrogen, deuterium, a halogen, a (C1-C30)alkyl unsubstituted or substituted with deuterium and/or a halogen(s), a substituted or unsubstituted (C3-C30)cycloalkyl, a substituted or unsubstituted (C6-C30)aryl, a substituted or unsubstituted (3- to 30-membered)heteroaryl, a cyano, or a substituted or unsubstituted (C1-C30)alkoxy; or adjacent two or more of R.sub.104 to R.sub.107 may be linked to each other to form a substituted or unsubstituted ring(s), for example, a substituted or unsubstituted naphthalene, a substituted or unsubstituted fluorene, a substituted or unsubstituted dibenzothiophene, a substituted or unsubstituted dibenzofuran, a substituted or unsubstituted indenopyridine, a substituted or unsubstituted benzofuropyridine, or a substituted or unsubstituted benzothienopyridine, together with benzene;

[0061] R.sub.201 to R.sub.220 each independently represent hydrogen, deuterium, a halogen, a (C1-C30)alkyl unsubstituted or substituted with deuterium and/or a halogen(s), a substituted or unsubstituted (C3-C30)cycloalkyl, or a substituted or unsubstituted (C6-C30)aryl; or adjacent two or more of R.sub.201 to R.sub.220 may be linked to each other to form a substituted or unsubstituted ring(s); and

[0062] s is an integer from 1 to 3.

[0063] The specific examples of the dopant compound are as follows, but are not limited thereto.

##STR00188## ##STR00189## ##STR00190## ##STR00191## ##STR00192## ##STR00193## ##STR00194## ##STR00195## ##STR00196## ##STR00197## ##STR00198## ##STR00199## ##STR00200## ##STR00201## ##STR00202## ##STR00203## ##STR00204## ##STR00205## ##STR00206## ##STR00207## ##STR00208## ##STR00209## ##STR00210## ##STR00211## ##STR00212## ##STR00213## ##STR00214## ##STR00215## ##STR00216## ##STR00217## ##STR00218## ##STR00219## ##STR00220## ##STR00221## ##STR00222## ##STR00223## ##STR00224##

[0064] In order to form each layer of the organic electroluminescent device of the present disclosure, dry film-forming methods such as vacuum evaporation, sputtering, plasma, ion plating methods, etc., or wet film-forming methods such as ink jet printing, nozzle printing, slot coating, spin coating, dip coating, flow coating methods, etc., can be used. When forming a film of the first host compound and the second host compound of the present disclosure, a co-evaporation process or a mixture-evaporation process is performed.

[0065] When using a wet film-forming method, a thin film may be formed by dissolving or diffusing materials forming each layer into any suitable solvent such as ethanol, chloroform, tetrahydrofuran, dioxane, etc. The solvent may be any solvent where the materials forming each layer can be dissolved or diffused, and where there are no problems in film-formation capability.

[0066] In addition, a display system, for example, a display system for smart phones, tablets, notebooks, PCs, TVs, or cars; or a lighting system, for example, an outdoor or indoor lighting system, can be produced by using the organic electroluminescent device of the present disclosure.

[0067] Hereinafter, the preparation method of the compound according to the present disclosure and the physical properties thereof, and the light-emitting properties of an organic electroluminescent device (OLED) comprising a plurality of host materials according to the present disclosure will be explained with reference to the representative compounds of the present disclosure. However, the following examples are only to describe the characteristics of the compound according to the present disclosure and the OLED comprising the same, but the present disclosure is not limited to the following examples.

Synthesis Example 1: Preparation of Compound H1-4

[0068] ##STR00225##

[0069] Compound 1-1 (11.7 g, 49.10 mmol), 2-chloro-4,6-diphenyl-1,3,5-triazine (10.9 g, 40.90 mmol), tetrakis(triphenylphosphine)palladium (1.4 g, 1.23 mmol), sodium carbonate (10.8 g, 102.10 mmol), 210 mL of toluene, 50 mL of ethanol, and 50 mL of water were added into a reaction vessel, and stirred for 4 hours at 120° C. After completion of the reaction, the mixture was washed with distilled water and the organic layer was extracted with ethyl acetate. The organic layer was dried with magnesium sulfate and the solvent was removed by rotary evaporator. The residue was separated by column chromatography to obtain compound H1-4 (11.2 g, yield: 63%).

TABLE-US-00001 MW M.P. H1-4 425.54 220° C.

Synthesis Example 2: Preparation of Compound H1-62

[0070] ##STR00226##

[0071] Compound 3-1 (11.7 g, 49.10 mmol), 2-(3′-bromo-[1,1′-biphenyl]-3-yl)-4,6-diphenyl-1,3,5-triazine (19.0 g, 40.90 mmol), tetrakis(triphenylphosphine)palladium (1.4 g, 1.23 mmol), sodium carbonate (10.8 g, 102.10 mmol), 210 mL of toluene, 50 mL of ethanol, and 50 mL of water were added into a reaction vessel, and stirred for 4 hours at 120° C. After completion of the reaction, the mixture was washed with distilled water and the organic layer was extracted with ethyl acetate. The organic layer was dried with magnesium sulfate and the solvent was removed by rotary evaporator. The residue was separated by column chromatography to obtain compound H1-62 (19.6 g, yield: 83%).

TABLE-US-00002 MW M.P. H1-62 577.73 173° C.

Device Examples 1 and 2: Producing a Green Light-Emitting OLED According to the Present Disclosure

[0072] An OLED according to the present disclosure was produced. First, a transparent electrode indium tin oxide (ITO) thin film (10 Ω/sq) on a glass substrate for an OLED (GEOMATEC CO., LTD., Japan) was subjected to an ultrasonic washing with acetone and isopropyl alcohol, sequentially, and then was stored in isopropanol. The ITO substrate was mounted on a substrate holder of a vacuum vapor deposition apparatus. Compound HI-1 was introduced into a cell of the vacuum vapor deposition apparatus, and compound HT-1 was introduced into another cell. The two materials were evaporated at different rates, and compound HI-1 was deposited in a doping amount of 3 wt % based to the total amount of compound HI-1 and compound HT-1 to form a hole injection layer with a thickness of 10 nm. Subsequently, compound HT-1 was deposited on the hole injection layer to form a first hole transport layer with a thickness of 80 nm. Next, compound HT-2 was introduced into another cell of the vacuum vapor deposition apparatus and was evaporated by applying an electric current to the cell, thereby depositing a second hole transport layer with a thickness of 30 nm on the first hole transport layer. After forming the hole injection layer and the hole transport layers, a light-emitting layer was deposited thereon as follows: The compounds shown as the first host and the second host in Table 1 below were respectively introduced into two cells of the vacuum vapor deposition apparatus as hosts, and compound D-130 was introduced into another cell as a dopant. The two host materials were evaporated at a rate of 1:2 and the dopant material was simultaneously evaporated at a different rate, and the dopant was deposited in a doping amount of 10 wt % based on the total amount of the hosts and dopant to form a light-emitting layer with a thickness of 40 nm on the second hole transport layer. Then, compound ETL-1 and compound EIL-1 were evaporated at a weight ratio of 40:60 as an electron transport material to form an electron transport layer having a thickness of 35 nm on the light-emitting layer. After depositing compound EIL-1 as an electron injection layer with a thickness of 2 nm on the electron transport layer, an Al cathode was deposited with a thickness of 80 nm on the electron injection layer by using another vacuum vapor deposition apparatus, thereby producing an OLED device. All the materials used for producing the OLED were purified by vacuum sublimation at 10.sup.−6 torr.

Comparative Examples 1 and 2: Producing an OLED Comprising a Conventional Compound

[0073] In Comparative Examples 1 and 2, OLEDs were produced in the same manner as in Device Examples 1 and 2, except that a compound H2-147 was used as the second host of a light-emitting layer.

[0074] The light-emitting color at a luminance of 1,000 nit and the time taken for reduction of luminance from 100% to 50% (lifespan: T50) at a luminance of 60,000 nit of the OLEDs produced in the Device Examples and Comparative Examples are provided in Table 1 below.

TABLE-US-00003 TABLE 1 Light- Emitting Lifespan First Host Second Host color (T50) [hr] Device Example 1 H1-4 H2-2 green 218 Comparative H1-4 H2-147 green 167 Example 1 Device Example 2 H1-62 H2-2 green 321 Comparative H1-62 H2-147 green 209 Example 2

[0075] From Table 1 above, it can be confirmed that the organic electroluminescent devices using a plurality of host materials comprising a compound represented by formula 1 of the present disclosure and a compound represented by formula 2 of the present disclosure exhibit long lifespan properties compared to the organic electroluminescent devices comprising the conventional compound.

[0076] The compounds used in the Device Examples and Comparative Examples are shown in Table 2 below.

TABLE-US-00004 TABLE 2 Hole Injection Layer/Hole Transport Layer [00227] [00228] [00229] Light-Emitting Layer [00230] [00231] [00232] [00233] [00234] Electron Transport Layer/ Electron Injection Layer [00235] [00236]