THERMAL MANAGEMENT STRUCTURE WITH INTEGRATED CHANNELS
20210188128 · 2021-06-24
Inventors
Cpc classification
H01M50/24
ELECTRICITY
B60L3/0046
PERFORMING OPERATIONS; TRANSPORTING
H01M10/6556
ELECTRICITY
H01M10/659
ELECTRICITY
Y02T10/70
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y02E60/10
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
H01M50/213
ELECTRICITY
F28F3/086
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
Y02E60/14
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
H01M50/249
ELECTRICITY
H01M50/289
ELECTRICITY
H01M2220/20
ELECTRICITY
F28F2255/06
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
H01M50/204
ELECTRICITY
B60K6/28
PERFORMING OPERATIONS; TRANSPORTING
H01M10/0525
ELECTRICITY
B60L50/64
PERFORMING OPERATIONS; TRANSPORTING
H01M10/6569
ELECTRICITY
International classification
B60L50/64
PERFORMING OPERATIONS; TRANSPORTING
F28D20/02
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F28F3/08
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
Abstract
The invention relates to a structure comprising at least one thermal management element comprising : a composite body (3) containing at least one phase change material (PCM) in a structuring rigid matrix, so that the composite body is self-supporting regardless of the phase of the phase change material contained, and/or a plastic or metal bag, gas-tight and under partial internal vacuum, having a shape maintained by the internal vacuum, the composite body (3) and/or the bag being shaped so as locally to present externally at least one elongated cavity (11) which by itself defines a channel wall (13) suitable for the circulation of a fluid.
Claims
1. A structure comprising at least one thermal management element comprising a composite body containing at least one phase change material disposed in a rigid structuring matrix, such that the composite body is self-supporting regardless of the phase of the phase change material contained, the composite body being shaped to locally present externally cavities which each defines by itself a wall of a channel suitable for circulating a fluid, the composite body defining a tray which has a thickness and opposite faces on at least one of which extend the channels, and between the channels, passages are formed in the thickness of the tray to receive external elements to be placed in thermal exchange with the fluid to be circulated in the channels.
2. The structure according to claim 1, wherein the rigid structuring matrix comprises an elastomer or fibers.
3. The structure according to claim 1, wherein the rigid structuring matrix comprises a graphite felt.
4. The structure according to claim 1, which further comprises sheathes which: are arranged within said cavities, are adapted for circulating said fluid, have each an inlet and an outlet, for the fluid.
5. The structure according to claim 1, wherein said cavities are arranged parallel to the passages, so that the cavities pass through the composite body and open each on said opposite faces.
6. The structure according to claim 1, wherein the inlet and the outlet are located at a same end of the sheathes and are common on said sheathes, so that the sheaths are individually adapted so that the fluid flows back and forth in each sheath.
7. A set of structures comprising a plurality of structures, each according to claim 1, wherein said channels are arranged adjacent, back to back, on said faces of each tray opposite each other according to the thickness, the trays being stacked, successively applied one on top of the other, so that one said tray forms a cover for the adjacent tray, thus creating said channels which each have a closed section.
8. A set of structures comprising a plurality of structures, each according to claim 1, wherein the trays are stacked, successively one on top of the other.
9. The set according to claim 8, which further comprises sheathes which each: is arranged within one of said cavities, is adapted for circulating said fluid, has an inlet and an outlet for the fluid.
10. The set according to claim 9, wherein the inlet and the outlet are located at a same end of the sheathes and are common on said sheathes, so that the sheaths are individually adapted so that the fluid flows back and forth in each sheath through said common inlet and outlet.
11. The set according to claim 8, wherein said cavities are arranged parallel to the passages, so that the cavities pass through the composite body and open each on said opposite faces.
12. The set according to claim 7, which further comprises sheathes which: are adapted for circulating said fluid: each has an inlet and an outlet for the fluid, each integrates several elongated depressions wedged in several of said cavities, each is placed between two successive trays.
13. The set according to claim 7, wherein the channels extend in several directions so as to cross each other and are arranged in a staggered manner in one of the directions.
14. An assembly comprising: the structure according to claim 1, wherein the passages pass through the tray, and as said external elements, cells of a vehicle electric battery individually arranged in the passages.
15. An assembly comprising: the set according to claim 7, wherein the passages pass through the stacked trays, and as said external elements, cells of a vehicle electric battery individually arranged in the passages of the stacked trays.
16. An assembly comprising: the set according to claim 8, wherein the passages pass through the stacked trays, and as said external elements, cells of a vehicle electric battery individually arranged in the passages of the stacked trays.
17. The assembly according to claim 15, wherein the cells are arranged in thermal exchange with the trays on first sides of the cells, the channels being connected to a first supply of fluid to be circulated in said channels, and, which further comprises a cooling plate arranged in thermal exchange with the cells on second sides thereof, the cooling plate having ducts which are connected to a second supply of a fluid to be circulated in said ducts, for a thermal exchange with the cells.
18. The assembly according to claim 16, wherein the cells are arranged in thermal exchange with the trays on first sides of the cells, the channels being connected to a first supply of fluid to be circulated in said channels, and, which further comprises a cooling plate arranged in thermal exchange with the cells on second sides thereof, the cooling plate having ducts which are connected to a second supply of a fluid to be circulated in said ducts, for a thermal exchange with the cells.
19. The assembly according to claim 18: wherein the cells are cylindrical and extend through successive passages of the stacked trays from a top of each cell, where an anode and a cathode are located, up to a base of each cell, and, the cooling plate is arranged in thermal exchange with the bases of the cells.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0051] If necessary, the invention will be better understood and other details, characteristics and advantages of the invention may appear when reading the following description made as a non-exhaustive example with reference to the appended drawings.
[0052] In these drawings:
[0053]
[0054]
[0055]
[0056]
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[0065]
[0066] In
[0067] 25
DETAILED DESCRIPTION
[0068] A goal of the solution proposed here is thus the efficient realization of structures with high thermal inertia (related to the presence of PCM) and/or thermal insulation (related to the presence of PIV type thermal insulation) for environmental thermal management purposes, in particular for a battery of electric accumulators (also called “cells” in the present description). In fact, structure 1 proposed for this purpose includes, as illustrated: [0069] a composite body 3 containing at least one phase-change material 5 (PCM) dispersed in a rigid structuring matrix 7, such that the composite body is self-supporting regardless of the phase of the phase-change material contained, and/or [0070] a plastic or metallic, thermally conductive, gas-tight and under partial internal vacuum (PIV type) pouch 9, having a shape maintained by the internal vacuum. Each pouch 9 (or 90 below) may wrap (i.e. contain) PCM 5.
[0071] The composite body 3 and/or the pocket 9 are shaped to present locally at least one so-called cavity (viz.hollow) 11 which defines by itself a channel wall 13 which may be suitable, or even intended, for the circulation of a fluid 15, it being then assumed that the channel created is then connected to a supply 17 and a recovery 19 of this fluid, which may be liquid or gaseous, see below: [0072]
[0074] Fluid 15 may be either a thermal transfer medium or a refrigerant. It may be a liquid.
[0075] If, as shown in
[0078] In the figures, the elements marked as composite body 3 or pocket 9 or lid 21 may be interchanged.
[0079] Thus, in an assembly or structure 1 provided with a cover 21, at least one of the elements may be presented as a plate, without a so-called cavity, as shown in
[0080] For the connection with this cover, it is proposed that each composite body 3 or pocket 9 has lateral flanges 23 for a support of cover 21. Lid 21 may then be welded to the composite body or pocket at the location of the flanges 23. In this way, welding on the edges of the parts may be avoided, as shown in
[0081] From the above, it is clear that any shape that serves as a cover for the fluid channel 15 is suitable.
[0082] However, for the construction of the covers, it may be preferable, as shown in
[0085] As previously, this other composite body 30 and/or other pocket 90 will then be shaped to locally complete and laterally close the wall 13 of the above-mentioned canal, viz. each cavity 11.
[0086] As already mentioned, this will be an interesting answer to the current difficulties in the industrial production of a structure allowing both fluid circulation and packaging of either a vacuum or PCM.
[0087] In order to help achieve both a certain intrinsic stiffness and the definition of the desired fluid channels, it is further proposed that each composite body 3.30 or so-called pocket 9.90 should have, as illustrated: [0088] a curved shape, with angles 25 which may be rounded (see
[0090] These slots and corners will also be well exploited by providing that, in order to laterally close each channel (i.e. each cavity 11), the cover 21 and the self-supporting composite body 3 or pocket 9: [0091] have watertight welds between them, at the location of respective sections, such as 31a, 31b, of walls bordering the channels, [0092] and are in support two by two, including at the place of the said respective sections of walls, such as 31a, 31b, thus interposed between two consecutive channels, or located on either side of the laterally external channels.
[0093] In pockets 9 or 90, a so-called thermally insulating material (see above) may usefully be placed 29, which may even reinforce the intrinsic strength of the vacuum pockets.
[0094] Concerning the choice in the realization of composite bodies 3,30, the following recommendations may be followed, in particular to meet a need for temperature maintenance of cells or housings of a battery 33 of electric or hybrid vehicles; cf.
[0095] Indeed, lithium-ion cells in particular are strongly impacted by the temperature parameter. If this parameter is not taken into account, it may have serious consequences on the lifetime of the battery cells, on their performance (capacity and delivered power), on their stability and on the safety of use.
[0096] First of all, even if the liquid-gas and inverse change of state of PCMs is interesting in terms of the amount of energy involved, the preferred change of state in the targeted applications may be solid-liquid and inverse. Then, to stay with the example of lithium-ion cells, the temperature range in which they must be maintained to operate optimally is between 25 and 35° C. However, in addition to the materials used for the elements involved in the thermal management and the layering of these elements in layers that may combine PCM and thermal insulation (see for example WO2017153691), it may be necessary to provide for a fluid circulation within this architecture, typically between two layers of materials; see channel 55 in this document.
[0097] To be able to circulate a fluid 15, with channels connected for example to an external air circuit, between the inlet/supply 17 and the outlet/recovery 19, will then be required, in a structure such as that 1 presented here.
[0098] In addition to achieving this with the above solution, we also wanted to define a high-performance composite body, as mentioned above, since it is the very nature of this body that will ensure the criteria of thermal performance, self-supporting and ease of shaping or cutting expected.
[0099] Therefore, two solutions are proposed, respectively based on elastomer or fibers, each with several PCMs changing phases at different temperatures. It should be noted that the phase change materials used in the formulation will then be favorably formulated to include them in matrices with a mass quantity of PCM in the formulation typically between 30 and 95%. The formulations will preferably use microencapsulated or pure materials whose phase transitions may be included, for battery applications, between −10 and 110° C. (depending in particular on the electrochemistry, lithium-ion or not).
[0100] In the case of lithium-ion applications, microencapsulated PCMs with a mass percentage on formulated product of 35 to 45% may be used. These PCMs will be favorably included in a silicone matrix containing, in particular, flame-retardant and thermally conductive fillers.
[0101] In the first of the two above-mentioned solutions, matrix 7 includes (at least) an elastomer, which allows the body 3 to be adapted to situations that may require mechanical stressing or the monitoring of complex shapes (elastic aspect of the elastomer), with small masses.
[0102] In the second solution, the matrix 7 comprises fibers.
[0103] In terms of implementation, several structures 1 may be installed between two adjacent cells and/or on different faces and on the periphery of the battery compartment in order to wrap it.
[0104] Starting from the surface of the battery compartment, four layers of phase-change material (several PCMs) may be provided, between which fluid 15 (e.g. air) may be circulated. On the outside of the PCM cells, the vacuum insulation is installed, typically one or more pockets 9 or 90. A thermally conductive peripheral envelope will allow the mechanical strength and protection of the system as a whole.
[0105] Note that the above two solutions ensure that the PCM is not in direct contact with the fluid and that there is no leakage of PCM in the fluid state. In general, a composite body solution as above will be able to work dynamically: on an electric or hybrid vehicle, typically at a time of high demand, such as for example during a start under electric drive in winter (outside temperature of 3-4° C. for example) we will indeed be able to circulate air (coming from the outside) in the cavities which will allow this air to heat the PCM, having in passing recovered thermal energy on the cells of the battery, the air may then be redirected to the outside environment. During its journey, the air will have both warmed the PCM(s) and evacuated excess heat from the battery cells. Another hypothesis: in winter, during cell operation, air cooled by an air conditioning circuit is projected towards the cells. This blown air then passes in channels 11.
[0106] Now, concerning the fabrication of the 3.30 composite bodies, it should be noted that they may be presented as plates comprising compressed fibrous graphite as a structuring matrix in which the PCM, which may be, or comprise, kerosene (viz. paraffin), is impregnated.
[0107] Graphite felts can be obtained by exfoliation. If there is a cover, it will be thermally conductive (e.g. plastic foil). The impregnated matrix will not release PCM if it is not stressed. And to obtain a composite body with an integrated channel wall, the raw composite body may simply be molded or machined. The vacuum bag solution may be obtained by folding.
[0108]
[0109] The alternative solution in
[0110] The alternative solution in
[0113] Elongated depressions 47 may be on both large surfaces of the sheath if both panels or structures 3 or 9 and 21 are provided with cavities 11 (
[0114] The advantage of a sheath compared to a solution with independent tubes or plate 51, as shown in
[0115] The alternative solution in
[0116]
[0117] In an application such as a battery 33, where thermal management may involve both part of a whole (one cell of the battery) and the whole (all cells of the battery), cell 33.53 of the above solutions shown in conjunction with
[0118] It should also be noted that cover 21 or the other element of a panel, or structure, 1 to body 3 or pocket 9 may include a thermal insulating material that is not under partial internal vacuum (PU foam, for example), and therefore not PIV (see
[0119]
[0120] The objective is to produce an assembly allowing cooling, for example by forced air, of vehicle battery cells 64, by favouring their thermal management in their optimal operating temperature range, avoiding dead zones and non-homogeneous temperatures.
[0121] To this end, each tray 63 has a thickness (e) and on at least one of the faces 630, channels formed by the aforementioned cavities 11. These channels extend along the entire length of the face concerned and open individually on two opposite sides of the tray.
[0122] In addition, between the channels 11, passages 65 are formed in the thickness (e) of the tray 63 to receive external elements 67 (in this case the cells 64) to be placed in thermal exchange with the fluid 15 to be circulated in the channels 11. Thus, the external elements 64, 67 to be stored are stored transversely to the plane P of each tray and the flow of fluid 15 circulates in this plane, over the largest possible surface.
[0123] Each tray may thus be defined by a molded PCM element integrating passages 65 and channels 11, which makes assembly easy (left view,
[0124] Typically, if the cells 64 are presented as a kind of “cylindrical stack” as illustrated, each tubular in shape, the trays will be favorably stacked, parallel and leaning against each other between channels 11 on the same side, so that one said tray 63 forms a cover for the adjacent tray 63, thus creating said channels with a closed section.
[0125] In order to increase thermal exchange, it is recommended that tray 63 include channels 11 arranged back to back, on the two opposite sides 630, 631 according to the thickness (e) of each tray.
[0126] And for the positioning and holding of cells 64, the passages 65 pass through the entire thickness (e) of the trays 63 and the cells 64 are individually arranged in the successive passages 65 of these stacked trays 63 through which they pass. A lower support plate 69 can support the stack and the cells 64. It may be a cooling plate with other channels 71 for the circulation of coolant, in thermal exchange with each cell 64, at its base 64a; right view
[0127] In the version of
[0128] In connection with a solution shown in
[0129] If WO2017153691 raises the subject, the solution could be improved. Thus it is first proposed here as an improved solution, as
[0133] The cooling plate 69 is thermally conductive and has ducts (here internal) 71 which are connected to a second supply 73 of a fluid to be circulated in said ducts 71, for a surface thermal exchange with the cells 64′. On this subject, it should be noted that this is also provided for in the solution of
[0134] In addition, in this solution, between two first opposite sides (respectively 641a and 641b,
[0135] If
[0136] The second fluid supply 73 will usefully be that of a liquid, such as water, because the sealing and connections are simpler to ensure than for the first supply 77. In addition, this will be more effective when there is “surface thermal exchange”. This second fluid supply 73 will also be usefully connected in a closed (looped) circuit, via a pump 81;
[0137] After exiting (in 83
[0138] Even if not represented in
[0139] The second fluid supply 73 will usefully use a gaseous fluid, such as air. It is preferable that the circulation of this fluid in the assembly be forced (fan or other).
[0140] Once again, for a quality of thermal exchange and a well-considered optimization of the thermal management provided by these fluid circulations, in connection with the PCMs present, it is recommended that each composite body (3) or pocket (9) presents, in front of the cells 64′ (but this may also apply for example to the cells 64 of the previous solution), a solid, continuous surface 645 for non-discrete thermal exchanges with the cells. It will have been understood that, on the contrary, a discrete contact is like separate zones without a continuum.
[0141] Thus, in the previous solution, the surfaces 645 were formed by solid cylindrical faces. In the solution of
[0142] Crossing the flows of the first and second fluids (always without mixing them) could further improve the efficiency of thermal exchanges.
[0143] Moreover, to counter the thermal transfers of a so-called 64′ cell, it is proposed in the solution for prismatic cells (
[0144] In the solution in
[0145] The purpose of the electrical insulation sheets 91 is to avoid short circuits in the event that the PCM of the composite bodies (3) or pockets (9) is electrically conductive. It is not obligatory to install this component, depending on the characteristics of the PCM but also on the desired effect: electrical insulation desired or not.
[0146] If the electrical insulation sheets 91 are provided, it will be advantageous for the effectiveness of the electrical insulation that the contact surfaces between the elements 1, 91, 64′ are flat and continuous; hence the advice of flat surfaces on the two opposite sides of the electrical insulation sheets 91 and on the side of structure 1 (composite body 3 or pocket 9) facing the adjacent electrical insulation sheet 91; see
[0147] In the additional embodiment of
[0148] The fluid supply (called first supply) 77 may comprise a fan or a compressor or a pump, and a buffer tank.
[0149] As in the solution of
[0150] In conformity with the previous embodiments, each structure comprises at least one thermal management element 1 comprising a composite body 3 containing at least one PCM 5 disposed in a rigid structuring matrix 7, such that the composite body is self-supporting regardless of the phase of the PCM contained.
[0151] The, or each, composite body 3 is shaped to locally present externally (means in fluid connection with outside) cavities 11 which each defines by itself a wall 13 of a channel suitable for circulating a fluid.
[0152] The, or each, composite body 3 defines a tray (see for example
[0153] Between the channels, passages 65 are formed in the thickness (e) of the tray to receive external elements 64′ to be placed in thermal exchange with the fluid 15 to be circulated in the channels 11.
[0154] Thus, the composite bodies 3 are individually shaped into layers, such as 3a, 3b; five layers for example.
[0155] Each layer, such as 3a, 3b, may be defined by one of said composite bodies 3. As previously, the composite bodies individually are molded composite bodies, preferably.
[0156] The layers or trays may be stacked, successively one on top of the other. They may be so arranged, along the same direction Z as the cells 64′ from their respective bases 64a (bottoms) to their tops 64b where the anode 640a and cathode 640b are located.
[0157] Each cell 64′ may be cylindrical and elongated from bottom to top.
[0158] The layers, such as 3a, 3b: [0159] are arranged face to face, so as to form a unitary block. [0160] individually have passages 65 therethrough in which the electric cells 64′ are respectively arranged, one per passage, and, [0161] individually further have channels 11 therethrough.
[0162] Superposing the layers, such as 3a, 3b is a solution, as illustrated. Each passage 65 preferably has a closed bottom 66.
[0163] At the opposite, at the top, the anode 640a and cathode 640b are accessible from outside the corresponding composite body 3, to be electrically connected.
[0164] The channels 11 are suitable to circulate a fluid 15 therein.
[0165] The channels 11 have respective fluid inlets 110a commonly connected to the (external) fluid inlet 87 and respective fluid outlets 110b commonly connected to the (external) fluid outlet 83.
[0166] The PCM 5 is in thermal exchange with the electric cells 64′ arranged in the passages 65 and with the fluid 15 which circulates in the channels 11, in accordance with the vehicle mode of operation.
[0167] Fluid 15 may be a gas or liquid, such as air or an water-based liquid (means more than 50 wt % of water).
[0168] The layers, such as 3a, 3b, individually have a thickness e according to the Z direction.
[0169] Preferably, the passages 65 and the channels 11 are arranged in a common direction.
[0170] Preferably, said layers are arranged face to face according to the Z direction, and both the passages 65 and the channels 11 pass through the layers transverse to said Z direction (vertically in the example).
[0171] If so arranged, parallel to the passages 65, the channels, or cavities, 11 will open each on the opposite faces 330, 331.
[0172] Two by two, adjacent layers, such as 3a, 3b, are applied one against the other, or bordered by seals for preventing fluid 15 from leaking, especially if liquid.
[0173] Individually arranging a sheath 39 (
[0174] To get an electric battery pack, a plurality of composite bodies 3 are grouped, side to side (
[0175]
[0181] The cooling plate, with a series of ducts 71 passing therein, in the plane of the cooling plate, may extend under the electric battery pack and the thermal management elements 1.
[0182] In other words: [0183] with cylindrical cells 64′ extending, through the successive passages 65 of the stacked trays, from the first side 64b of each cell, where the anode and the cathode are located, up to said second side 64a (bottom or base) of each cell, [0184] the cooling plate 69 will be arranged in thermal exchange with the bases 64a of the cells 64′.
[0185] In
[0186] In other words, each cavity 11 (or sheath 39) is adapted so that the fluid 15 flows back and forth through said common fluid inlet 87 and fluid outlet 83: each cavity 11 (or sheath 39) will have an opening at one end and a closed wall at the opposite end.
[0187] The (open) end of each cavity 11 (or sheath 39), where the commonly formed fluid inlet 87 and fluid outlet 83 is located, will preferably be the bottom end, so that, if liquid, the fluid 15 circulating in the respective cavities will flow back by gravity.
[0188] Neither cavity 11 nor sheath 39 has any fluid communication with the ducts 71 in the cooling plate 69. They are physically separated.
[0189] Fluid circulating in the (ducts of the) cooling plate 69 has no communication with fluid 15 circulating in each cavity 11 (or sheath 39). Preferably, these respective fluids will have no thermal exchange therebetween.