TEMPERATURE-RESISTANT POTTING MATERIAL FOR HOLLOW FIBER MEMBRANES
20210197124 · 2021-07-01
Assignee
Inventors
Cpc classification
International classification
Abstract
The invention relates to a method for potting hollow fiber membranes in potting compounds of increased temperature resistance, wherein an isocyanate component with inorganic particles and a polyol component are processed into a potting compound and the hollow fiber membranes are tightly encased by the potting compound in at least one potting zone by the hardening of said potting compound.
Claims
1. A method for potting hollow fiber membranes comprising the steps: (i) providing a plurality of hollow fiber membranes, (ii) reacting an isocyanate component containing at least one diisocyanate compound with inorganic particles containing hydroxy groups to form a compound comprising an isocyanate group-containing adduct, wherein the isocyanate groups of the isocyanate component are present in stoichiometric excess relative to the hydroxy groups of the hydroxy group-containing inorganic particles, and wherein at least a portion of the hydroxy groups of the hydroxy group-containing inorganic particles reacts with at least a portion of the isocyanate groups of the isocyanate component into urethane bonds, (iii) mixing the obtained compound containing the isocyanate group-containing adduct with a polyol component containing at least one diol compound into a potting compound, (iv) potting the hollow fiber membranes with the potting compound in at least one potting zone, (v) hardening the potting compound in the potting zone into a polyurethane resin.
2. The method according to claim 1, characterized in that the hydroxy group-containing inorganic particles have a weight-average particle size of 200 nm or less, preferentially 150 nm or less, further preferentially 100 nm or less, further preferentially 50 nm or less, and at least 1 nm or greater, or 2 nm or greater, or 5 nm or greater.
3. The method according to claim 1, characterized in that the percentage of the hydroxy group-containing inorganic particles amount to 2.3% by weight or less, preferentially 1.3 wt % or less, further preferentially 0.75 wt % or less, further preferentially 0.6 wt % or less, and 0.01 wt % or more, preferentially 0.05 wt % or more, further preferentially 0.1 wt % or more, further preferentially 0.15 wt % or more in relation to the total weight of the potting compound.
4. The method according to claim 1, characterized in that the hydroxy group-containing inorganic particles are particles containing silicon dioxide (SiO.sub.2), titanium dioxide (TiO.sub.2), zirconium dioxide (ZrO.sub.2) or aluminum oxide (Al.sub.2O.sub.3) or mixtures of said particles.
5. The method according to claim 1, characterized in that the hydroxy group-containing inorganic particles have a hydroxy group number of 1×10.sup.−5 mol/g to 1×10.sup.−2 mol/g, preferentially 5×10.sup.−4 mol/g to 1×10.sup.−2 mol/g, relative to the mass of the hydroxy group-containing inorganic particles.
6. The method according to claim 1, characterized in that the hydroxy group-containing inorganic particles are dried to constant weight at temperatures of from 100° C. to 150° C. prior to the reaction with the isocyanate component.
7. The method according to claim 1, characterized in that the compound has a molar ratio of isocyanate component isocyanate groups to hydroxy groups of the hydroxy group-containing inorganic particles of at least 100 to 1, preferentially at least 1000:1.
8. The method according to claim 1, characterized in that a stoichiometric molar ratio of from 0.9-1.1 to 1.1-0.9, preferentially 0.99-1.01 to 1.01-0.99, further preferentially a molar ratio of 1 to 1, is set for the hydroxy groups of the polyol component and the free isocyanate groups of the compound containing the isocyanate group-containing adduct.
9. A hollow fiber membrane filter comprising a plurality of hollow fiber membranes potted in a polyurethane resin in at least one potting zone characterized in that the polyurethane resin comprises at least 0.01% to 2.3% by weight of inorganic particles bonded in the polyurethane resin via urethane bonds relative to the total weight of the polyurethane resin.
10. The hollow fiber membrane filter according to claim 9, characterized in that the inorganic particles bound in the polyurethane resin by the urethane bonds are particles of silicon dioxide (SiO.sub.2), zirconium dioxide (ZrO.sub.2), aluminum oxide (Al.sub.2O.sub.3) or titanium dioxide (TiO.sub.2) or mixtures of said particles.
11. The hollow fiber membrane filter according to claim 9, characterized in that the inorganic particles have a weight-average particle size of 200 nm or less, preferentially 150 nm or less, further preferentially 100 nm or less, further preferentially 50 nm or less, and at least 1 nm or greater, or 2 nm or greater, or 5 nm or greater.
12. The hollow fiber membrane filter according to claim 9, characterized in that the polyurethane resin amounts to 1.3% by weight or less, further preferentially 0.75 wt % or less, preferentially 0.6 wt % or less, and 0.05 wt % or more, preferentially 0.1 wt % or more, further preferentially 0.15 wt % or more of the inorganic particles relative to the total weight of the polyurethane resin.
13. The hollow fiber membrane filter according to claim 9, characterized in that the polyurethane resin has a glass transition temperature which is higher than 3° C., preferentially higher than 5° C., further preferentially higher than 7° C., or preferentially up to 12° C., further preferentially up to 14° C. higher than an equivalent polyurethane resin not comprising any urethane-bound inorganic particles but yet produced from the same isocyanate component and the same polyol component.
14. The hollow fiber membrane filter according to claim 9, characterized in that the hollow fiber membranes are potted in the polyurethane resin in accordance with claim 1.
15. An isocyanate group-containing adduct, obtained by reacting at least one isocyanate component containing at least one diisocyanate compound and hydroxy group-containing inorganic particles, wherein at least one portion of the hydroxy groups of the hydroxy group-containing inorganic particles are reacted with at least one portion of the isocyanate groups of the isocyanate component into a urethane bond, and wherein free isocyanate groups are present in the obtained adduct.
16. The isocyanate group-containing adduct according to claim 15, characterized in that the molar ratio of the urethane bonds between the inorganic particles and the free isocyanate groups of the diisocyanate compound amounts to from 1 to 100 up to 1 to 10.000, preferentially 1:1000 up to 1:10.000.
17. The isocyanate group-containing adduct according to claim 15, characterized in that the inorganic particles are particles consisting of silicon dioxide (SiO.sub.2), zirconium dioxide (ZrO.sub.2), aluminum oxide (Al.sub.2O.sub.3) or titanium dioxide (TiO.sub.2) or mixtures of said particles.
18. The isocyanate group-containing adduct according to claim 15, characterized in that the inorganic particles have a weight-average particle size of 200 nm or less, preferentially 150 nm or less, further preferentially 100 nm or less, further preferentially 50 nm or less, and at least 1 nm or greater, or 2 nm or greater, or 5 nm.
19. The isocyanate group-containing adduct according to claim 15, characterized in that the number of urethane bonds between the isocyanate component and the inorganic particles amounts to 1×10.sup.−5 mol/g to 1×10.sup.−2 mol/g, preferentially 5×10.sup.−4 mol/g to 1×10.sup.−2 mol/g, relative to the mass of the hydroxy group-containing inorganic particles.
Description
BRIEF DESCRIPTION OF THE FIGURES
[0022]
[0023]
DETAILED DESCRIPTION OF THE INVENTION
[0024] In a first aspect, the invention relates to a method for potting hollow fiber membranes which comprises the steps:
(i) Providing a plurality of hollow fiber membranes,
(ii) Reacting an isocyanate component containing at least one diisocyanate compound with inorganic particles containing hydroxy groups to form a compound comprising an isocyanate group-containing adduct, whereby the isocyanate groups of the isocyanate component are present in stoichiometric excess relative to the hydroxy groups of the hydroxy group-containing inorganic particles, and whereby at least a portion of the hydroxy groups of the hydroxy group-containing inorganic particles reacts with at least a portion of the isocyanate groups of the isocyanate component into urethane bonds,
(iii) Mixing the obtained compound containing the isocyanate group-containing adduct with a polyol component containing at least one diol compound into a potting compound,
(iv) Potting the hollow fiber membranes with the potting compound in at least one potting zone,
(v) Hardening the potting compound in the potting zone into a polyurethane resin.
[0025] According to the inventive method, it is possible to embed hollow fiber membranes in a polyurethane resin which exhibits higher thermal stability. It was found that forming the isocyanate-containing adduct from hydroxy group-containing inorganic particles and the isocyanate component effects the improved thermal stability of the potting compound hardened into the polyurethane resin. The glass transition temperature is to be deemed as a measure of the thermal stability. A higher glass transition temperature of the polyurethane resin therefore also represents higher material strength at higher temperatures. In particular, the inventive method enables polyurethane resin potting zones to be produced which have glass transition temperatures of 3° C., in particular 5° C., further particularly 8° C. higher than the glass transition temperatures of polyurethane resins not produced according to the inventive method although using the same polyol and isocyanate compound. The stability of the polyurethane resin in the potting zone between hollow fiber membranes and parts of the hollow fiber membrane filter housing is thereby improved at higher temperatures so as to yield an overall higher reliability of the tightness of the polyurethane resin.
[0026] The inventive method initially proceeds from a plurality of hollow fiber membranes, whereby the hollow fiber membranes are provided for the potting. The plurality of hollow fiber membranes is preferably a hollow fiber membrane bundle. The bundling of hollow fiber membranes into hollow fiber membrane bundles is known in the prior art and in the producing of hollow fiber membrane filter modules. Preferably, a hollow fiber membrane bundle is provided for the inventive method in part of a housing, in particular in part of a housing for a hollow fiber membrane filter module. To be understood by a “plurality” of hollow fiber membranes is a number of hollow fiber membranes as commonly used during processes of producing hollow fiber membrane filter modules. Known in this respect are hollow fiber membrane filter modules having a count of from 100 to 55,000 hollow fiber membranes. In comparison, however, experimental modules with a lesser number of hollow fiber membranes of up to 10 or less were also potted for development purposes.
[0027] The inventive method further initially proceeds from an isocyanate component. An “isocyanate component” in the sense of the present invention is to be understood as a compound of difunctional, trifunctional and multifunctional organic isocyanate compounds. What is essential is for the isocyanate component to contain diisocyanate compounds able to react to a polymer under polyaddition with a polyol component by forming a urethane bond. To a lesser extent, monoisocyanate compounds and multifunctional isocyanates can also be present in the isocyanate component. It is also possible in the sense of the present invention for the isocyanate component to rely on compounds of isocyanate-group-functionalized prepolymers. Such prepolymers can be obtained by polymerization of diisocyanate monomers. One example of a polymeric isocyanate is PMDI (polymeric diphenylmethane diisocyanate). It is further possible for the isocyanate component used according to the inventive method to comprise a mixture of isocyanate group-containing prepolymers and monomeric isocyanate group-containing compounds. Examples of suitable monomeric isocyanates are HDI (hexamethylene diisocyanate), TDI (toluylene diidocyanate), MDI (methylene diphenylene diisocyanate), NDI (naphthylene diisocyanate), IPDI (isophorone diisocyanate) and H12MDI (4,4′-methylene dicyclohexyl diisocyanate). The isocyanate component can comprise further additives which support the reaction of the isocyanate component with the polyol component or serve in the polyurethane resin's resistance to aging.
[0028] Preferably, the isocyanate component is in liquid state at room temperature. It is in particular advantageous for the isocyanate component to comprise percentages of liquid diisocyanate compounds. The isocyanate component can also contain diisocyanate compounds which in themselves are solid, ceraceous or viscous. In this case, it is advantageous for such diisocyanate compounds to be dissolved in a percentage of liquid diisocyanate compounds. In particular, a liquid isocyanate component is provided for the inventive method. The liquid isocyanate component used in accordance with the inventive method advantageously has a viscosity of 50 to 1000 mPa*s, preferentially 500 to 1000 mPa*s, measured at 25° C. with a VT550 viscometer from the Haake company, Germany, at level r.3 (30 rpm) using an “MV1 (MV-DIN)” rotor from the Haake company (shear rate 38.7/s). A low viscosity to the isocyanate component enables good processing of the potting compound during the pot life, in particular a complete embedding of the hollow fiber membranes in the potting compound.
[0029] Hydroxy group-containing inorganic particles are furthermore used in the inventive method. The hydroxy group-containing inorganic particles can be the form of a powder or initially as granulates in compacted or porous form. Comminution processes can bring the hydroxy group-containing particles into the desired particle size. Preferentially, however, the inorganic particles are obtained by precipitation in a sol-gel process or produced in a pyrogenic process since doing so can form particles of particularly small particle size. The hydroxy groups of the inorganic particles can already have been formed in the inorganic particle production process. Alternatively, the hydroxy groups can also be obtained by functionalizing the surface of the inorganic particles. Experience has shown that hydroxy groups also form in pyrogenic products shortly after being stored under ambient conditions.
[0030] The conversion of the isocyanate component with the hydroxy group-containing inorganic particles into a compound containing the isocyanate group-containing adduct preferably occurs in a container and under stirring. The hydroxy group-containing particles are thereby added to a liquid preparation of the isocyanate component and stirred, if applicable also under the additional effect of ultrasound. In the sense of the present invention, “conversion” is to be understood as a reaction leading to formation of a chemical bond. In the sense of the present invention, “chemical bond” refers to covalent bonds and coordinative bonds. The number of isocyanate groups in the produced isocyanate component is thereby present in a stoichiometric excess relative to the hydroxy bond yielded by the hydroxy group-containing inorganic particles. The conversion thereby ensues such that free isocyanate groups are present in the isocyanate group-containing adduct post-conversion. “Free isocyanate groups” are to be understood as reactive isocyanate groups which are not bound to the hydroxy groups of the hydroxy group-containing particles and thus capable of reacting with the hydroxy groups of the polyol component. In the sense of the present invention, “isocyanate group-containing adduct” is to be understood as a compound forming from the isocyanate component and the hydroxy group-containing inorganic particles by chemical reaction.
[0031] The compound obtained by the reaction of the isocyanate component with the hydroxy group-containing inorganic particles is a mixture of different compounds. Inorganic particles can thereby be bound by the reaction of the hydroxy groups to one or more isocyanate compounds of the isocyanate component by chemical reaction and formation of urethane bonds. Isocyanate compounds which are not bond to inorganic particles by chemical reaction can additionally be present in the compound. Advantageous during the reaction is for all possible reactive hydroxy groups of the hydroxy group-containing inorganic particles to be converted by chemical reaction. The continuation of the conversion of the hydroxy groups can in this respect be continuously monitored by analytical methods and an end point of the isocyanate component reaction with the hydroxy group-containing inorganic particles determined therefrom. Pursuant to the invention, the conversion to the isocyanate group-containing adduct occurs within 0.5 h or 1 h or 5 h or 1 day or 2 days at room temperature. Thereby important is for the reaction of the compound containing isocyanate group-containing adduct with the isocyanate component not to lead to a macroscopic cross-linking since the isocyanate group-containing adduct cannot otherwise adequately mix with the polyol component. In consequence, the further step of hardening and the thorough potting of the hollow fiber membranes will also be hindered. In the sense of the present invention, “macroscopic cross-linking” is to be understood as the visible formation of polymeric precipitates or gels.
[0032] Low-molecular and high-molecular polyol compounds can be used for mixing the polyol component with the compound containing the isocyanate group-containing adduct. Suitable low-molecular polyols are e.g. ethylene glycol, diethylene glycol, propylene glycol, dipropylene glycol, 1,3-butandiol or 1,4-butandiol. Polyether polyols are suitable high-molecular polyols such as e.g. polyethylene glycols, polypropylene glycols, polytetra-methylene glycol ethers alongside polyester polyols, polycaprolactone polyols and linear or branched castor oils. Mixtures of the aforesaid polyols can also be used as polyol components. Essential is for the polyol component to comprise a diol compound which is able to react with a diisocyanate compound under polyaddition to form a polyurethane. Monohydroxycompounds, trihydroxycompounds and polyhydroxycompounds can be present in the polyol component to a lesser extent. Mono-, tri- and polyhydroxycompounds are used to regulate the chain length and the degree of branching of the polyurethane resins obtained by the hardening of the potting compounds.
[0033] Preferentially, the polyol component is in the liquid state at room temperature. It is in particular advantageous for the polyol component to comprise a percentage of liquid diol compounds. The polyol component can also contain diol compounds which in themselves are solid, ceraceous or viscous. In this case, it is advantageous for such diol compounds to be dissolved in a percentage of liquid diol compounds. The polyol component used in accordance with the inventive method has a viscosity of 200-5500 mPa*s, preferentially 300-5000 mPa*s, measured at 25° C. with a VT550 viscometer from the Haake company, Germany, at level r.3 (30 rpm) using an “MV1 (MV-DIN)” rotor from the Haake company (shear rate 38.7/s). A low viscosity to the polyol component enables good processing of the potting compound during the pot life, in particular a complete embedding of the hollow fiber membranes in the potting compound.
[0034] The compound containing the isocyanate group-containing adduct is preferentially mixed with the polyol component in a container while being stirred and forms the potting compound. The mixing starts the hardening process of the potting compound into polyurethane resin. At first, the viscosity of the still-liquid potting compound decreases since the temperature increases as the reaction begins. As the reaction progresses further, however, the viscosity increases sharply to complete hardening despite the further rising temperature. Crossing the viscosity minimum ensures good processability and thereby also enables the potting to completely embed the hollow fiber membranes despite there being isocyanate-containing adduct in the potting compound. The packing density of the hollow fiber membranes is thereby to be factored in; i.e. that a potential particularly high packing density can necessitate a lower potting compound viscosity, which in this case can also limit the applicable adduct concentration in the potting compound. The hollow fiber membranes are preferably potted in a dip casting process or in a rotation process. In a “dip casting process,” a section of the provided hollow fiber membranes is dipped into the liquid potting compound and subsequently hardened. The liquid potting compound thereby spreads between the hollow fiber membranes by capillary action. In a “rotation process,” the provided hollow fiber membrane bundle is rotated. During the rotation, the potting compound is fed to a section of the hollow fiber membranes forming the potting zone. The liquid potting compound spreads between the hollow fiber membranes by capillary action and centrifugal forces. In respect of the rotation process, reference is made to the applicant's European application EP 2 024 067 A1.
[0035] Since the potting compound self-cures into a polyurethane resin by polyaddition directly after mixing, the potting compound typically hardens within 1 h at room temperature. Alternatively, temperatures of up to 80° C. or up to 70° C. or up to 60° C., in particular up to 45° C., can facilitate hardening and can result in reduced curing times of less than 20 minutes.
[0036] In one implementation of the first aspect, the inventive method is characterized by the hydroxy group-containing inorganic particles having a weight-average particle size of 200 nm or less, preferentially 150 nm or less, further preferentially 100 nm or less, further preferentially 50 nm or less, and at least 1 nm or greater, or 2 nm or greater, or 5 nm or greater. The weight-average particle size can be determined per known methods, for example by laser diffraction. It can however also be determined by means of transmission electron microscopy. A sample of the particles is to that end measured in the transmission electron microscope, whereby the diameter and the aspect ratio for elongated particles are determined for a number of particles (approx. 1000). A particle size distribution can be determined therefrom. This method is particularly preferred with small particle sizes under 50 nm.
[0037] Hydroxy group-containing inorganic particles of low weight-average particle size are preferential since they can have a higher percentage of hydroxy groups and thus enable a higher number of urethane groups in the resulting isocyanate group-containing adduct. However, hydroxy group-containing particles which are too small in particle size are difficult to work with due to the agglomeration which occurs, making the most complete possible saturation of the hydroxy groups no longer able to be sufficiently ensured such that potentially a slightly lower increase in the glass transition point is to be obtained.
[0038] In a further implementation of the first aspect of the invention, the method for potting the hollow fiber membranes is characterized by the percentage of the hydroxy group-containing inorganic particles amounting to 2.3% by weight or less, preferentially 1.3 wt % or less, further preferentially 0.75 wt % or less, further preferentially 0.6 wt % or less, and 0.01 wt % or more, preferentially 0.05 wt % or more, further preferentially 0.1 wt % or more, further preferentially 0.15 wt % or more, or 2.3 wt % or less and 0.01 wt % or more, preferentially 1.3 wt % or less and 0.05 wt % or more, further preferentially 0.75 wt % or less and 0.1 wt % or more, further preferentially 0.6 wt % or less and 0.15 wt % or more in relation to the total weight of the potting compound.
[0039] The volume of hydroxy group-containing inorganic particles used also depends on the volume of the isocyanate groups present in the isocyanate component. In particular, when the percentage of hydroxy group-containing particles is too high, there is the risk of excessive macroscopic cross-linking. Additionally, the viscosity of the potting compound can increase so sharply that hollow fiber membrane filters of particularly high packing density can no longer be reliably produced in pressure-tight manner. On the other hand, a percentage which is too low can potentially result in a lower increase in the glass temperature of the polyurethane resins obtained by way of the inventive method.
[0040] In one implementation of the first aspect of the invention, the method for potting the hollow fiber membranes is characterized by the hydroxy group-containing inorganic particles being particles containing silicon dioxide (SiO.sub.2), zirconium dioxide (ZrO.sub.2), aluminum oxide (Al.sub.2O.sub.3) or titanium dioxide (TiO.sub.2) or mixtures of these particles. Hydroxy group-containing particles made of silicon, alumina or titanium dioxide are particularly advantageous since they are stable as regards surface-bound hydroxy groups and the number of hydroxy groups can be determined with sufficient precision. Precisely knowing the number of hydroxy groups of the hydroxy group-containing inorganic particles serves in being able to adapt the necessary stoichiometric ratio of the isocyanate groups of the isocyanate component and the hydroxy groups in the polyol component to the production of the potting compound. Moreover, silicon, alumina and titanium dioxide particles are readily and economically available.
[0041] In a further implementation of the first aspect of the invention, the method for potting the hollow fiber membranes is characterized by the hydroxy group-containing inorganic particles having a hydroxy group number of 1×10.sup.−5 mol/g to 1×10.sup.−2 mol/g, preferentially 5×10.sup.−4 mol/g to 1×10.sup.−2 mol/g, relative to the mass of the hydroxy group-containing inorganic particles. At these concentration ratios to the hydroxy groups on the surface of the hydroxy group-containing particles, the adduct formation along with associated increase in glass transition temperature is particularly advantageous.
[0042] In a further implementation of the first aspect, the inventive method is characterized by the hydroxy group-containing inorganic particles being dried to constant weight at temperatures of from 100° C. to 150° C. prior to the reaction with the isocyanate component. Drying the hydroxy group-containing particles results in eliminating the water adsorbed on the surface of the particle. Water leads to side reactions with the isocyanate component and negatively affects the production of the potting compound and the hardening process. Drying the particles above 100° C. is effective in eliminating adsorbed water. An excessively high drying temperature can lead to cleavage of the surface-bound hydroxy groups and is therefore to be avoided.
[0043] In a further implementation of the first aspect of the invention, the method for potting the hollow fiber membranes is characterized by the compound having a molar ratio of isocyanate component isocyanate groups to hydroxy groups of the hydroxy group-containing inorganic particles of at least 100 to 1, preferentially at least 1000:1. Such a molar ratio has proven advantageous as it ensures sufficient saturation of the particles' hydroxy groups. Similarly, the preselected molar ratio leaves a sufficient number of free isocyanate groups, responsible for the subsequent development of the polyurethane resin. It was additionally seen that a molar ratio which is too low can lead to a diisocyanate molecule reacting with an isocyanate group to form a urethane bond with a hydroxy group and a second isocyanate group abreacting at the same time with a further hydroxy group. If the molar ratio is maintained, particularly high increases in the glass transition temperature result.
[0044] In a further implementation of the first aspect of the invention, the inventive method is characterized by the setting of an almost stoichiometric molar ratio of from 0.9-1.1 to 1.1-0.9, preferentially 0.99-1.01 to 1.01-0.99 to the hydroxy groups of the polyol component and the free isocyanate groups of the compound containing the isocyanate group-containing adduct. Particularly preferential is an exact 1 to 1 setting of the molar ratios. High conversions of the polyol component with the compound containing the isocyanate-containing adduct can be achieved by means of the molar ratio setting. This will thereby prevent the residual monomer content in the potting compound hardening into the poly-urethane resin which e.g. can be eluted by filtration of the potted hollow fiber membranes.
[0045] In a second aspect, the invention relates to a hollow fiber membrane filter comprising a plurality of hollow fiber membranes potted in a polyurethane resin in at least one potting zone characterized by the polyurethane resin comprising at least 0.01% to 2.3% by weight of inorganic particles bonded in the polyurethane resin via urethane bonds relative to the total weight of the polyurethane resin. The volume of the inorganic particles also depends on the volume of the urethane bonds able to be formed between the inorganic particles and the polyurethane resin. In particular, with too high of an inorganic particle percentage, which can occur with the hydroxy group-containing inorganic particles as per one implementation of the first aspect of the invention, there is the risk of the potting compound not being able to convert into the polyurethane resin. With too low of a percentage, the increase in the polyurethane resin's glass temperature is too low.
[0046] In one implementation of the second aspect of the invention, the hollow fiber membrane filter is characterized by inorganic particles bound in the polyurethane resin by the urethane bonds being particles of silicon dioxide (SiO.sub.2), zirconium dioxide (ZrO.sub.2), aluminum oxide (Al.sub.2O.sub.3) or titanium dioxide (TiO.sub.2) or mixtures of these particles. Silica-containing and titanium dioxide-containing particles are particularly advantageous since the particle size and the urethane bonds can be determined with sufficient precision. Knowing the number of urethane bonds by which the particles are embedded in the polyurethane resin is important in order to be able to regulate the thermal stability of the polyurethane resin.
[0047] In a further implementation of the second aspect of the invention, the hollow fiber membrane filter is characterized by the inorganic particles having a weight-average particle size of 200 nm or less, preferentially 150 nm or less, further preferentially 100 nm or less, further preferentially 50 nm or less, and at least 1 nm or greater, or 2 nm or greater, or 5 nm or greater. Smaller average particle sizes are preferential as these particles exhibit a higher number of hydroxy groups. Particle sizes which are too small can be disadvantageous due to agglomeration.
[0048] In a further implementation of the second aspect of the invention, the hollow fiber membrane filter is characterized by the polyurethane resin amounting to 1.3% by weight or less, preferentially 0.75 wt % or less, further preferentially 0.6 wt % or less, and 0.05 wt % or more, further preferentially 0.1 wt % or more, further preferentially 0.15 wt % or more, or 1.3 wt % or less and 0.05 wt % or more, further preferentially 0.75 wt % or less and 0.1 wt % or more, further preferentially 0.6 wt % or less and 0.15 wt %, whereby the weight percentages are based on the total weight of the polyurethane resin.
[0049] In a further implementation of the second aspect of the invention, the hollow fiber membrane filter is characterized by the polyurethane resin having a glass transition temperature which is 3° C. or higher, preferentially 5° C. or higher, further preferentially 7° C. or higher, or preferentially up to 12° C., further preferentially up to 14° C. higher than an equivalent polyurethane resin not comprising any urethane-bound inorganic particles but yet produced from the same isocyanate component and the same polyol component. The glass transition temperature is determined pursuant to the “DSC measuring method.” It was shown that the polyurethane resin containing urethane-bonded inorganic particles has higher temperature resistance. This is particularly important with water filters which are operated at higher temperature. The inventive hollow fiber membrane filters in this case exhibit particularly good stability, in particular hydrolytic resistance.
[0050] In a further embodiment of the second aspect of the invention, the hollow fiber membrane filter is characterized by the hollow fiber membranes being potted in the poly-urethane resin pursuant to at least one of the embodiments according to the first aspect.
[0051] In a further embodiment of the second aspect of the invention, the hollow fiber membrane filter is characterized by the space-filling packing density of the hollow fiber membranes in the housing of the hollow fiber membrane filter amounting to 50 to 70%, in particular 60 to 70%, further particularly 55 to 65%. In the case of cylindrical hollow fiber membrane filters having hollow fiber membranes of the same diameter, the packing density results from the square of the diameter of the hollow fiber membranes to the diameter of the housing:
With such high packing densities, it is particularly difficult to provide pressure-tight and watertight potting of the hollow fibers of the hollow fiber membrane filter. On the one hand, the potting compound needs to have a particularly low viscosity prior to hardening since the spaces between the fibers are particularly close; on the other hand, good resistance to heat and hot water is desired, which low-viscosity potting compounds often do not achieve. Hollow fiber membrane filters comprising the inventive polyurethane resin are potted in pressure-tight manner and exhibit a high temperature resistance.
[0055] A third aspect of the invention relates to the isocyanate group-containing adduct, obtained by reacting at least one isocyanate component containing at least one diisocyanate compound and hydroxy group-containing inorganic particles, wherein at least one portion of the hydroxy groups of the hydroxy group-containing inorganic particles are reacted with at least one portion of the isocyanate groups of the isocyanate component into a urethane bond, and wherein free isocyanate groups are present in the obtained adduct. The isocyanate group-containing adduct has the advantage of being able to be mixed together with a polyol component into a hardenable potting compound which ensures good processability over the pot life and complete embedding of the hollow fiber membranes in the potting compound. Furthermore, the isocyanate group-containing adduct offers the advantage of the potting compound hardened into the polyurethane resin having a higher glass transition temperature and the polyurethane resin thereby having improved thermal stability in filtration applications at increased temperatures.
[0056] In one embodiment of the third aspect, the isocyanate group-containing adduct is characterized by at least 70%, preferentially at least 90%, further preferentially at least 98% of all reactive hydroxy groups of the inorganic particles converting into urethane bonds. In this context, “reactive” is to be understood as the reactivity relative to isocyanate groups in terms of conversion to an urethane bond. Good saturation to the inorganic particle hydroxy groups inventively effects a high increase of the glass transition point and thus a polyurethane resin with good hydrolytic resistance.
[0057] In one embodiment of the third aspect, the isocyanate group-containing adduct is characterized by the molar ratio of the inorganic particle urethane bonds to free isocyanate groups amounting to from 1 to 100 up to 1 to 10.000, preferentially 1:1000 up to 1:10.000. These molar ratios have proven advantageous as they ensure sufficient saturation of the particles' hydroxy groups. Similarly, the preselected molar ratio leaves a sufficient number of free isocyanate groups, responsible for the subsequent development of the polyurethane resin. It was additionally seen that a molar ratio which is too low can lead to a diisocyanate molecule reacting with an isocyanate group to form a urethane bond with a hydroxy group and a second isocyanate group abreacting at the same time with a further hydroxy group. If the molar ratio is maintained, particularly high increases in the glass transition temperature result.
[0058] In a further embodiment of the third aspect of the invention, the isocyanate group-containing adduct is characterized by the inorganic particles being particles consisting of silicon dioxide (SiO.sub.2), zirconium dioxide (ZrO.sub.2), aluminum oxide (Al.sub.2O.sub.3) or titanium dioxide (TiO.sub.2) or mixtures of these particles. Hydroxy group-containing particles made of silicon, alumina or titanium dioxide are particularly advantageous since they are stable as regards surface-bound hydroxy groups and the number of hydroxy groups can be determined with sufficient precision. Precisely knowing the number of hydroxy groups of the hydroxy group-containing inorganic particles serves in being able to adapt the necessary stoichiometric ratio of the isocyanate groups of the isocyanate component and the hydroxy groups in the polyol component to the production of the potting compound. Moreover, silicon, alumina and titanium dioxide particles are readily and economically available.
[0059] In a further embodiment of the third aspect of the invention, the isocyanate group-containing adduct is characterized by the inorganic particles having a weight-average particle size of 200 nm or less, preferentially 150 nm or less, further preferentially 100 nm or less, further preferentially 50 nm or less, and at least 1 nm or greater, or 2 nm or greater, or 5 nm or greater.
[0060] In a further embodiment of the third aspect of the invention, the isocyanate group-containing adduct is characterized by the number of urethane bonds between the iso-cyanate component and the inorganic particles amounting to 1×10.sup.−5 mol/g to 1×10.sup.−2 mol/g, preferentially 5×10.sup.−4 mol/g to 1×10.sup.−2 mol/g, relative to the mass of the hydroxy group-containing inorganic particles. At these concentration ratios to the hydroxy groups on the surface of the hydroxy group-containing particles, the adduct formation along with associated increase in glass transition temperature is particularly advantageous.
[0061] In a fourth aspect, the invention relates to the use of an isocyanate-containing adduct pursuant to at least one embodiment according to the third aspect in a method for potting a plurality of hollow fiber membranes.
[0062] A further implementation of the fourth aspect relates to the use of an isocyanate-containing adduct pursuant to at least one embodiment according to the third aspect for potting a plurality of hollow fiber membranes in the production of filter modules for nano-filtration, ultrafiltration or microfiltration.
EXAMPLE EMBODIMENTS AND METHODS
[0063] Materials Used
[0064] polyol component: Arathane CW 5631 from the Huntsman company isocyanate component: Arathane HY 5610 from the Huntsman company hydroxy group-containing inorganic particles: [0065] (1) TiO.sub.2 UV100 from the Huntsman company [0066] 2.5-5 hydroxy groups per nm.sup.2 particle surface [0067] weight-average particle size 10 nm [0068] BET surface 330+/−15 m.sup.2/g [0069] (2) TiO.sub.2 P25 from the Evonik company [0070] 4-5 hydroxy groups per nm.sup.2 particle surface [0071] weight-average particle size 20-25 nm [0072] BET surface 55 m.sup.2/g [0073] (3) TiO.sub.2 AT-1 from the Crystal company [0074] 1.4 hydroxy groups per nm.sup.2 particle surface [0075] weight-average particle size 200 nm [0076] BET surface 9 m2/g [0077] (4) SiO.sub.2 Aerosil 300 from the Evonik company [0078] 1.9 hydroxy groups per nm.sup.2 particle surface [0079] weight-average particle size 7 nm [0080] BET surface 300 m2/g
[0081] Measuring Method for Determining Particle Size
[0082] Particle size distributions or weight-average particle sizes respectively of fine particles less than 50 nm are determined by means of transmission electron microscopy. A sample of the particles is thereby measured under the transmission electron microscope, whereby the diameter and aspect relationship of elongated particles is determined for a number of particles (1000). The particle size distribution and thus also the weight-average particle size can be calculated therefrom. The laser diffraction method is employed for samples of larger weight-average particle size.
[0083] Measuring Method for Determining Glass Transition Temperature—DSC
[0084] The glass temperature is determined using a DSC 200F3 instrument from the Netsch company. 5 mg samples of the potting compound hardened into the polyurethane resin are used. The collected samples are positioned in an aluminum crucible in the sample holder of the DSC unit. The area of the sample holder is continuously flushed with nitrogen. The sample was heated within a temperature range of from −5° C. to 120° C. The heating rate was 10° C./min. The sample was thereafter cooled at a cooling rate of 10° C./min. The samples were reheated within a temperature range of from −5° C. to 120° C. The second heat curve was used in the analysis. The glass transition was determined from the onset of the glass transition range of the recorded temperature curve.
[0085] Measuring Method for Determining Pressure Tightness
[0086] To determine pressure tightness, the front edge of a potting zone is visually examined. The front edge is created by cutting through the end of the potting zone. This thereby exposes the lumen-side openings of the hollow fiber membranes in the potting zone. A visual analysis checks whether the hollow fiber membranes in the potting zone are densely encased by the polyurethane resin.
Comparative Example 1
[0087] 100 g of the polyol component is mixed with 25 g of the isocyanate component into a potting compound. A hollow fiber membrane bundle comprising 10752 hollow fiber membranes consisting of polysulfone and polyvinylpyrrolidone is inserted into a cylindrical filter housing having an inside diameter of 34 mm. The same membranes are used in all the examples. The production of such membranes is described in PCT/EP2017/081955. The outer diameter of the fibers amounted to 255 μm, the wall thickness 35 μm. The packing density was 60.5%. The filter housing is provided for the potting of the hollow fiber membranes. The potting zone includes the fiber ends of the hollow fiber membranes. Polyurethane resin is added until a potting height of 22 mm could be ensured. The potting compound is introduced into the potting zone in the filter housing under rotation pursuant to the method described in EP 2 024 067 A1 and hardened to polyurethane resin at 45° C. The filter housing with the pressure-tight potted hollow fibers is extracted after 30 min. An approximate 5 mg sample of the potting compound hardened to the polyurethane resin is taken and the glass transition temperature determined by DSC analysis. The determined glass transition temperature (onset) is used as the baseline for the further tests.
Example 1
[0088] Aerosil 300 is dried to constant weight at 110° C. 23 g of the Aerosil 300 is mixed with 977 g of the isocyanate component and stirred for 24 h at room temperature. A compound containing the isocyanate-containing adduct of Aerosil 300 and the isocyanate component is obtained. 100 g of the polyol component and 25.6 g of the obtained compound containing the isocyanate-containing adduct is mixed into a potting compound. A hollow fiber membrane bundle comprising 10752 hollow fiber membranes is inserted into a cylindrical filter housing having an inside diameter of 34 mm. The outer diameter of the fibers amounted to 255 μm, the wall thickness 35 μm. The packing density was 60.5%. The filter housing is provided for the potting of the hollow fiber membranes. The potting zone includes the fiber ends of the hollow fiber membranes. Polyurethane resin is added until a potting height of 22 mm could be ensured. The potting compound is introduced into the potting zone in the filter housing under rotation pursuant to the method described in EP 2 024 067 A1 and hardened to polyurethane resin at 45° C. A potting formed in which the hollow fiber membranes were encased by the polyurethane resin in pressure-tight manner. The percentage of SiO.sub.2 particles in the potting material amounted to 0.5% by weight. An approximate 5 mg sample of the potting compound hardened to the polyurethane resin is taken and the glass transition temperature determined by DSC analysis. The increase in the polyurethane resin's glass transition temperature compared to the polyurethane resin produced according to comparative example 1 amounted to 6.3° C.
Example 2
[0089] UV100 is dried to constant weight at 110° C. 53 g of the UV100 is mixed with 947 g of the isocyanate component and stirred for 24 h at room temperature. A compound containing the isocyanate-containing adduct of UV100 and the isocyanate component is obtained. 100 g of the polyol component and 26.5 g of the obtained compound containing the isocyanate-containing adduct is mixed into a potting compound. A hollow fiber membrane bundle comprising 10752 hollow fiber membranes is inserted into a cylindrical filter housing having an inside diameter of 34 mm. The outer diameter of the fibers amounted to 255 μm, the wall thickness 35 μm. The packing density was 60.5%. The filter housing is provided for the potting of the hollow fiber membranes. The potting zone includes the fiber ends of the hollow fiber membranes. Polyurethane resin is added until a potting height of 22 mm could be ensured. The potting compound is introduced into the potting zone in the filter housing under rotation pursuant to the method described in EP 2 024 067 A1 and hardened to polyurethane resin at 45° C. A potting formed in which the hollow fiber membranes were encased by the polyurethane resin in pressure-tight manner. The percentage of inorganic particles in the potting material amounted to 1.2% by weight. An approximate 5 mg sample of the potting compound hardened to the polyurethane resin is taken and the glass transition temperature determined by DSC analysis. The increase in the polyurethane resin's glass transition temperature compared to the polyurethane resin produced according to comparative example 1 amounted to 7.1° C.
Example 3
[0090] UV100 is dried to constant weight at 110° C. 23 g of the UV100 is mixed with 977 g of the isocyanate component and stirred for 24 h at room temperature. A compound containing the isocyanate-containing adduct of UV100 and the isocyanate component is obtained. 100 g of the polyol component and 25.6 g of the obtained compound containing the isocyanate-containing adduct is mixed into a potting compound. A hollow fiber membrane bundle comprising 10752 hollow fiber membranes is inserted into a cylindrical filter housing having an inside diameter of 34 mm. The outer diameter of the fibers amounted to 255 μm, the wall thickness 35 μm. The packing density was 60.5%. The filter housing is provided for the potting of the hollow fiber membranes. The potting zone includes the fiber ends of the hollow fiber membranes. Polyurethane resin is added until a potting height of 22 mm could be ensured. The potting compound is introduced into the potting zone in the filter housing under rotation pursuant to the method described in EP 2 024 067 A1 and hardened to polyurethane resin at 45° C. A potting formed in which the hollow fiber membranes were encased by the polyurethane resin in pressure-tight manner. The percentage of inorganic particles in the potting material amounted to 0.5% by weight. An approximate 5 mg sample of the potting compound hardened to the polyurethane resin is taken and the glass transition temperature determined by DSC analysis. The increase in the polyurethane resin's glass transition temperature compared to the polyurethane resin produced according to comparative example 1 amounted to 8° C.
Example 4
[0091] UV100 is dried to constant weight at 110° C. 7.5 g of the UV100 is mixed with 992.5 g of the isocyanate component and stirred for 24 h at room temperature. A compound containing the isocyanate-containing adduct of UV100 and the isocyanate component is obtained. 100 g of the polyol component and 25.2 g of the obtained compound containing the isocyanate-containing adduct is mixed into a potting compound. A hollow fiber membrane bundle comprising 11230 hollow fiber membranes is inserted into a cylindrical filter housing having an inside diameter of 34 mm. The outer diameter of the fibers amounted to 255 μm, the wall thickness 35 μm. The packing density was 63.2%. The filter housing is provided for the potting of the hollow fiber membranes. The potting zone includes the fiber ends of the hollow fiber membranes. Polyurethane resin is added until a potting height of 22 mm could be ensured. The potting compound is introduced into the potting zone in the filter housing under rotation pursuant to the method described in EP 2 024 067 A1 and hardened to polyurethane resin at 45° C. A potting formed in which the hollow fiber membranes were encased by the polyurethane resin in pressure-tight manner. The percentage of inorganic particles in the potting material amounted to 0.2% by weight. An approximate 5 mg sample of the potting compound hardened to the polyurethane resin is taken and the glass transition temperature determined by DSC analysis. The increase in the polyurethane resin's glass transition temperature compared to the polyurethane resin produced according to comparative example 1 amounted to 4.7° C.
Example 5
[0092] P25 is dried to constant weight at 110° C. 53 g of the P25 is mixed with 980 g of the isocyanate component and stirred for 24 h at room temperature. A compound containing the isocyanate-containing adduct of P25 and the isocyanate component is obtained. 100 g of the polyol component and 26.5 g of the obtained compound containing the isocyanate-containing adduct is mixed into a potting compound. A hollow fiber membrane bundle comprising 10752 hollow fiber membranes is inserted into a cylindrical filter housing having an inside diameter of 34 mm. The outer diameter of the fibers amounted to 255 μm, the wall thickness 35 μm. The packing density was 60.5%. The filter housing is provided for the potting of the hollow fiber membranes. The potting zone includes the fiber ends of the hollow fiber membranes. Polyurethane resin is added until a potting height of 22 mm could be ensured. The potting compound is introduced into the potting zone in the filter housing under rotation pursuant to the method described in EP 2 024 067 A1 and hardened to polyurethane resin at 45° C. A potting formed in which the hollow fiber membranes were encased by the polyurethane resin in pressure-tight manner. The percentage of TiO.sub.2 particles in the potting material amounted to 1.2% by weight. An approximate 5 mg sample of the potting compound hardened to the poly-urethane resin is taken and the glass transition temperature determined by DSC analysis. The increase in the polyurethane resin's glass transition temperature compared to the polyurethane resin produced according to comparative example 1 amounted to 9.5° C.
Example 6
[0093] AT1 is dried to constant weight at 110° C. 23 g of the AT1 is mixed with 977 g of the isocyanate component and stirred for 24 h at room temperature. A compound containing the isocyanate-containing adduct of AT1 and the isocyanate component is obtained. 100 g of the polyol component and 25.6 g of the obtained compound containing the isocyanate-containing adduct is mixed into a potting compound. A hollow fiber membrane bundle comprising 10752 hollow fiber membranes is inserted into a cylindrical filter housing having an inside diameter of 34 mm. The outer diameter of the fibers amounted to 255 μm, the wall thickness 35 μm. The packing density was 60.5%. The filter housing is provided for the potting of the hollow fiber membranes. The potting zone includes the fiber ends of the hollow fiber membranes. Polyurethane resin is added until a potting height of 22 mm could be ensured. The potting compound is introduced into the potting zone in the filter housing under rotation pursuant to the method described in EP 2 024 067 A1 and hardened to polyurethane resin at 45° C. A potting formed in which the hollow fiber membranes were encased by the polyurethane resin in pressure-tight manner. The percentage of TiO.sub.2 particles in the potting material amounted to 0.5% by weight. An approximate 5 mg sample of the potting compound hardened to the polyurethane resin is taken and the glass transition temperature determined by DSC analysis. The increase in the polyurethane resin's glass transition temperature compared to the polyurethane resin produced according to comparative example 1 amounted to 7.2° C.
Example 7
[0094] UV100 is dried to constant weight at 110° C. 96 g of the UV100 is mixed with 904 g of the isocyanate component and stirred for 24 h at room temperature. A compound containing the isocyanate-containing adduct of UV100 and the isocyanate component is obtained. 100 g of the polyol component and 27.7 g of the obtained compound containing the isocyanate-containing adduct is mixed into a potting compound. A hollow fiber membrane bundle comprising 8432 hollow fiber membranes is inserted into a cylindrical filter housing having an inside diameter of 34 mm. The outer diameter of the fibers amounted to 255 μm, the wall thickness 35 μm. The packing density was 47.4%. The filter housing is provided for the potting of the hollow fiber membranes. The potting zone includes the fiber ends of the hollow fiber membranes. Polyurethane resin is added until a potting height of 22 mm could be ensured. The potting compound is introduced into the potting zone in the filter housing under rotation pursuant to the method described in EP 2 024 067 A1 and hardened to polyurethane resin at 45° C. A potting formed in which the hollow fiber membranes were encased by the polyurethane resin in pressure-tight manner. The percentage of inorganic particles in the potting material amounted to 2.0% by weight. An approximate 5 mg sample of the potting compound hardened to the polyurethane resin is taken and the glass transition temperature determined by DSC analysis. The increase in the polyurethane resin's glass transition temperature compared to the polyurethane resin produced according to comparative example 1 amounted to 10.1° C.
Comparative Example 2
[0095] UV100 is dried to constant weight at 110° C. 8 g of the UV100 is mixed with 992 g of the isocyanate component and stirred for 24 h at room temperature. A 100.2 g mixture containing the polyol component and UV100 is mixed with 25 g of the isocyanate component into a potting compound. A hollow fiber membrane bundle comprising 10752 hollow fiber membranes is inserted into a cylindrical filter housing having an inside diameter of 34 mm. The outer diameter of the fibers amounted to 255 μm, the wall thickness 35 μm. The packing density was 60.5%. The filter housing is provided for the potting of the hollow fiber membranes. The potting zone includes the fiber ends of the hollow fiber membranes. Polyurethane resin is added until a potting height of 22 mm could be ensured. The potting compound is introduced into the potting zone in the filter housing under rotation pursuant to the method described in EP 2 024 067 A1 and hardened to polyurethane resin at 45° C. A potting formed in which the hollow fiber membranes were encased by the polyurethane resin in pressure-tight manner. The percentage of TiO.sub.2 particles in the potting material amounted to 0.2% by weight. An approximate 5 mg sample of the potting compound hardened to the polyurethane resin is taken and the glass transition temperature determined by DSC analysis. The increase in the polyurethane resin's glass transition temperature compared to the polyurethane resin produced according to comparative example 1 amounted to only 0.5° C.