METHOD FOR MANUFACTURING SEMICONDUCTOR LASER DEVICE, AND SEMICONDUCTOR LASER DEVICE
20210273414 · 2021-09-02
Assignee
Inventors
- Ayumi FUCHIDA (Tokyo, JP)
- Tadashi TAKASE (Tokyo, JP)
- Naoki Nakamura (Tokyo, JP)
- Ryoko SUZUKI (Tokyo, JP)
Cpc classification
H01S5/2077
ELECTRICITY
H01S5/3211
ELECTRICITY
H01S5/3235
ELECTRICITY
H01S5/305
ELECTRICITY
International classification
H01L33/00
ELECTRICITY
Abstract
The present application is provided with: a ridge laminated with a first conductivity type cladding layer, an active layer, and a second conductivity type first cladding layer in order and having a top portion formed to be flat; a first buried layer buried on both side areas of the ridge; a second buried layer covering the first buried layer and protruding toward the center of the ridge and toward a top portion of the ridge to form an opening formed by protruding portions facing each other; and a second conductivity type second cladding layer buried on the second buried layer and in the opening, wherein a surface of the second buried layer on a side to the top portion of the ridge is formed so as to fit within a surface of the second conductivity type first cladding layer.
Claims
1.-3. (canceled)
4. A method for manufacturing a semiconductor laser device comprising the steps of: a ridge forming step in which a laminated structure is formed by laminating a first conductivity type cladding layer of a first conductivity type, an active layer, a second conductivity type first cladding layer of a second conductivity type opposite to the first conductivity type, and a cap layer made of a semiconductor material different from the second conductivity type first cladding layer in order on a surface of a first conductivity type substrate of the first conductivity type, and both side areas of the laminated structure are etched to a position closer to the first conductivity type substrate than the active layer to form a ridge; a ridge burying step in which a first buried layer of a conductivity type different from the first conductivity type is buried in both side areas of the ridge to a position higher than the second conductivity type first cladding layer; a second buried layer forming step in which a second buried layer of the first conductivity type is grown so as to cover the ridge and the first buried layer; a cap layer exposing step in which the second buried layer at a position corresponding to a center of the ridge is etched to expose the cap layer at the center of the ridge; a first cladding layer exposing step in which the cap layer exposed at the center of the ridge is etched to expose the second conductivity type first cladding layer; and a second cladding layer forming step in which a second conductivity type second cladding layer of the second conductivity type is grown so as to be buried on the second buried layer, the second conductivity type first cladding layer exposed at the center of the ridge and an exposed side face of the cap layer located between the second buried layer and the second conductivity type first cladding layer.
5. The method for manufacturing a semiconductor laser device according to claim 4, wherein the cap layer is the second conductivity type.
6. (canceled)
7. A semiconductor laser device comprising: a ridge that is laminated with a first conductivity type cladding layer of a first conductivity type, an active layer, and a second conductivity type first cladding layer of a second conductivity type opposite to the first conductivity type in order on a surface of a first conductivity type substrate of the first conductivity type, and has a flat top portion formed so as to protrude from a position closer to the first conductivity type substrate than the active layer; a first buried layer that is buried on both side areas of the ridge to a position higher than the second conductivity type first cladding layer; a second buried layer that covers the first buried layer, and protrudes toward a center of the ridge to form an opening as a current constricting window formed by protruding portions facing each other; a second conductivity type second cladding layer of the second conductivity type that is buried on the second buried layer and in the current constricting window; and a cap layer of the second conductivity type that is sandwiched between the second buried layer and the second conductivity type first cladding layer and located on both sides of the top portion of the ridge, wherein the second conductivity type second cladding layer is contact with the second conductivity type first cladding layer at the center of the top portion of the ridge.
8. The semiconductor laser device according to claim 7, wherein a width of the opening on a side to the second conductivity type first cladding layer of the current constricting window is narrower than the width of the opening on an opposite side to the second conductivity type first cladding layer.
9. The semiconductor laser device according to claim 7, wherein the second conductivity type second cladding layer is constituted by a high carrier concentration layer that is buried in the current constricting window and a low carrier concentration layer having a carrier concentration lower than that of the high carrier concentration layer.
10. The semiconductor laser device according to claim 7, wherein the first conductivity type substrate is an InP substrate, and the first buried layer is an Fe-doped InP layer or a Ru-doped InP layer.
11. The semiconductor laser device according to claim 8, wherein the second conductivity type second cladding layer is constituted by a high carrier concentration layer that is buried in the current constricting window and a low carrier concentration layer having a carrier concentration lower than that of the high carrier concentration layer.
12. The semiconductor laser device according to claim 8, wherein the first conductivity type substrate is an InP substrate, and the first buried layer is an Fe-doped InP layer or a Ru-doped InP layer.
13. The semiconductor laser device according to claim 9, wherein the first conductivity type substrate is an InP substrate, and the first buried layer is an Fe-doped InP layer or a Ru-doped InP layer.
14. The semiconductor laser device according to claim 11, wherein the first conductivity type substrate is an InP substrate, and the first buried layer is an Fe-doped InP layer or a Ru-doped InP layer.
Description
BRIEF DESCRIPTION OF DRAWINGS
[0033]
[0034]
[0035]
[0036]
[0037]
[0038]
[0039]
[0040]
[0041]
[0042]
[0043]
[0044]
DESCRIPTION OF EMBODIMENTS
Embodiment 1
[0045]
[0046] The n-type InP substrate 10 is a substrate S-doped with an impurity concentration of 4.0×10.sup.18 cm.sup.−3 and has a (001) plane as the major surface. The n-type InP cladding layer 11 is made of InP on the n-type InP substrate 10, has a thickness of 0.3 μm, and is S-doped with the concentration of 4.0×10.sup.18 cm.sup.−3. The active layer 20 is made of an AlGaInAs-based or an InGaAsP-based material containing multiple quantum wells. The p-type InP first cladding layer 30 is made of InP, has a thickness of 0.02 μm in thickness, and is Zn-doped with the concentration of 1.0×10.sup.18 cm.sup.−3. The ridge 41 is typically about 0.8 to 1.4 μm in width. Note that, the values of the concentration of the doping, thickness, width, and the like are typical examples, and are not limited to the values and ranges that are exemplified.
[0047] The first buried layer 50 is made of p-type InP that is Zn-doped with the concentration of 5.0×10.sup.17 cm.sup.−3 or is a semi-insulating material made of InP that is Fe-doped with the concentration of 5.0×10.sup.16 cm.sup.−3. The n-type InP second buried layer 60 is made of InP on the first buried layer 50, has a thickness of 0.4 μm, and is S-doped with the concentration of 7.0×10.sup.18 cm.sup.−3. Note that, the first buried layer 50 may be a semi-insulating material made of InP doped with a material such as Ti, Co, and Ru except for Zn or Fe. Further, the first buried layer 50 may be constituted with multi-laminated layers with p-type semiconductor layers or semi-insulating material layers. As described above, the conductivity type of the first buried layer 50 needs to be p-type or semi-insulating type, and the conductivity type of the first buried layer 50 is to be referred to that different from the n-type. Thus, the first buried layer 50 may be constituted with a combination of other semiconductor layers that are different in the impurity concentration or the conductivity type.
[0048] As shown in
[0049] The p-type InP second cladding layer 70 that is made of InP, has a thickness of 2.0 μm, and is Zn-doped with the concentration of 1.0×10.sup.18 cm.sup.−3 is buried on the p-type InP first cladding layer 30 exposed at the center of the ridge 41 and the n-type InP second cladding layer 60, and at the center of the ridge 41, the p-type InP first cladding layer 30 is in contact with the p-type InP second cladding layer 70. The electrodes 80 are provided each under the n-type InP substrate 10 and on the p-type InP second cladding layer 70. The electrodes 80 are made of a metal such as Au, Ge, Zn, Pt, or Ti.
[0050] A front end face and a rear end face of the semiconductor laser device 101, which are end faces in a direction perpendicular to the paper surface, that is, in the optical axis direction of the laser, form a resonator by (110) planes formed by cleavage. The light emission obtained in the active layer by current injection is amplified in the resonator, leading to laser oscillation. A length of the resonator is often set to 150 μm to 300 μm, but is not limited to this range.
[0051] In the semiconductor laser device 101 having the structure described above, when current is injected using the upper and lower electrodes 80, electrons are supplied from the n-type InP substrate 10 through the n-type InP cladding layer 11, and holes are supplied from the p-type InP second cladding layer 70 through the p-type InP first cladding layer 30. The holes supplied from the p-type InP second cladding layer 70 flow toward the n-type InP substrate 10. The hole current is indicated by an arrow in
[0052] Next, a method of manufacturing the semiconductor laser device 101 according to Embodiment 1 will be described on the basis of
[0053] Next, as shown in
[0054] Next, as shown in
[0055] Subsequently, as shown in
[0056] Next, as shown in
[0057] Then as shown in
[0058] Lastly, the electrodes 80 are formed on outer sides of the n-type InP substrate 10 and the p-type InP second cladding layer 70, thereby completing the semiconductor laser device 101 shown in
[0059] Note that, in Embodiment 1, although the semiconductor laser device using the n-type InP substrate and the method of manufacturing the same have been described, the structure may be made by reversing the conductivity type of each of the semiconductor layers using a p-type InP substrate. In the present application, one of the p-type and n-type conductivity types may be referred to as a first conductivity type and the other as a second conductivity type. That is, the second conductivity type is the conductivity type opposite to the first conductivity type, and if the first conductivity type is p-type, the second conductivity type is n-type, and if the first conductivity type is n-type, the second conductivity type is p-type. In addition, as the semiconductor material, an example mainly using the InP-based material is described, but other semiconductor materials may be used. Therefore, in the present application, without specification of the conductivity type and the material, for example, the member described as the n-type InP substrate may be referred to as a first conductivity type substrate, the member described as the n-type InP cladding layer may be referred to as a first conductivity type cladding layer, the member described as the p-type InP first cladding layer may be referred to as a second conductivity type first cladding layer, and the member described as the p-type InP second cladding layer may be referred to as a second conductivity type second cladding layer.
[0060]
[0061] In contrast, in Embodiment 1, since selective etching is performed using an etchant having an etching rate of the InGaAsP cap layer 31 different from that of the p-type InP first cladding layer 30, etching can be stopped with good controllability. Therefore, as shown in
[0062] In the semiconductor laser device 200 having the structure of the comparative example shown in
[0063]
Embodiment 2
[0064] In Embodiment 1, a manufacturing method using the degeneration of the SiO.sub.2 mask is shown, and then in Embodiment 2, a method of manufacturing a semiconductor laser device 101 similar to that shown in
[0065] First, the n-type InP cladding layer 11, the active layer 20, the p-type InP first cladding layer 30, and the InGaAsP cap layer 31 are sequentially laminated on the n-type InP substrate 10. After that, a first mask 43 is formed with the width of the current constricting window 61, and a second mask 44 is formed with the width of the ridge 41 so as to cover the first mask. The first mask 43 is made of a material having a low etching rate, and the second mask 44 is made of a material having an etching rate higher than that of the first mask 43. In addition, preferably, the width of the first mask 43 is narrower than the width of the second mask 44, and the first mask 43 is centered with respect to the second mask 44. As shown in
[0066] Next, as shown in
[0067] Next, as shown in
[0068] Next, as shown in
[0069] Using the double mask constituted by two materials having different etching rates, it is also possible to manufacture the semiconductor laser device 101 shown in
Embodiment 3
[0070]
[0071] The semiconductor laser device 103 of Embodiment 3 is manufactured, for example, as follows. The steps up to the step of forming the second buried layer for forming the n-type InP second buried layer 60 are the same as those in Embodiment 1 or 2. Then, before the p-type InP second cladding layer 70 is grown, the shape of the n-type InP second buried layer 60 is altered by mass transport by high-temperature annealing. As a result, in the current constricting window 61, the width B of the uppermost side becomes wider than the width A of the lowermost side. Others in the manufacturing method are the same as those of Embodiment 1, and the description thereof is omitted.
[0072] If the width of the current constricting layer 61 sandwiched between the layers of the n-type InP second buried layer 60 is narrow, the cross-sectional area through which the current flows becomes narrow, causing the element resistance to increase. In the case where the thickness in the direction of the current flow in the current constricting window 61 is the same, and when the semiconductor laser device 101 of Embodiment 1 is compared with the semiconductor laser device 103 of Embodiment 3, a region in which the cross-sectional area through which the current flows is wider is increased in the semiconductor laser device 103 of Embodiment 3. Thus, the element resistance in the semiconductor laser device 103 of Embodiment 3 can be reduced more than the semiconductor laser device 101 of Embodiment 1.
Embodiment 4
[0073]
[0074] The current constricting window 61 sandwiched between the layers of the n-type InP second buried layer 60 has a smaller cross-sectional area through which the current flows than in other regions, causing the element resistance to increase. In the semiconductor laser device 104 of Embodiment 4, the resistance in the current constricting window 61 can be reduced by burying in the current constricting window 61, the high carrier concentration layer 701 having a carrier concentration higher than that of the low carrier concentration layer 700 located on the electrode side. However, since the light absorption increases when the carrier concentration is high, the light conversion efficiency decreases, if the entire second cladding layer is a layer having the high carrier concentration. Therefore, it is necessary to select the ratio of the high carrier concentration layer 701 to the low carrier concentration layer 700 in the P-type InP second cladding layer 70.
[0075] According to the semiconductor laser device 104 of Embodiment 4, in comparison with the case where, in the semiconductor laser device 101 of Embodiment 1 shown in
Embodiment 5
[0076]
[0077] Next, as shown in
[0078] Next, an SiO.sub.2 mask 42 for selective etching is then formed on the n-type InP second buried layer 60 in preparation for forming the current confinement window 61. After that, when the n-type InP second buried layer 60 is etched using, for example, hydrochloric acid, since the etching rate of InP with respect to hydrochloric acid is higher than that of InGaAsP, etching can be stopped on the InGaAsP cap layer 31 with good controllability as shown in
[0079] Next, the InGaAsP cap layer 31 exposed at the upper face in the center of the ridge 41 is removed using tartaric acid, and the SiO.sub.2 mask 42 is removed using hydrofluoric acid.
[0080] Next, as shown in
[0081] As shown in
[0082] Although various exemplary embodiments and examples are described in the present application, various features, aspects, and functions described in one or more embodiments are not inherent in a particular embodiment, and can be applicable alone or in their various combinations to each embodiment. Accordingly, countless variations that are not illustrated are envisaged within the scope of the art disclosed herein. For example, the case where at least one component is modified, added or omitted, and the case where at least one component is extracted and combined with a component in another embodiment are included.
REFERENCE SIGNS LIST
[0083] 10 n-type InP substrate (first conductivity type substrate), 11 n-type InP cladding layer (first conductivity type cladding layer), 20 active layer, 30 p-type InP first cladding layer (second conductivity type first cladding layer), 31 cap layer, 40 mask, 41 ridge, 43 first mask, 44 second mask, 45 double mask, 50 first buried layer, 60 second buried layer, 61 current constricting window, 70 p-type InP second cladding layer (second conductivity type second cladding layer)