Fuel cell separator

Abstract

A fuel cell separator having high electrical conductivity is provided. A fuel cell separator including, on a substrate, an antimony-doped tin oxide film, in which the antimony-doped tin oxide film contains a poly(3,4-ethylenedioxythiophene)/polyethylene glycol (PEDOT/PEG) copolymer in a content of 15% by volume or more but 25% by volume or less is provided.

Claims

1. A fuel cell separator comprising, on a substrate, an antimony-doped tin oxide film, wherein the antimony-doped tin oxide film contains a poly(3,4-ethylenedioxythiophene)/polyethylene glycol (PEDOT/PEG) copolymer in a content of 15% by volume or more but 25% by volume or less.

2. A fuel cell separator comprising, on a substrate, an antimony-doped tin oxide film, wherein the antimony-doped tin oxide film contains a poly(3,4-ethylenedioxythiophene)/polyethylene glycol (PEDOT/PEG) copolymer, and an element ratio of a total of sulfur and carbon to tin [(S+C)/Sn] in the antimony-doped tin oxide film is 0.6 or more but 1.1 or less.

Description

BRIEF DESCRIPTION OF DRAWINGS

(1) FIG. 1 is a schematic cross-sectional view showing one example of a fuel cell separator according to this embodiment;

(2) FIG. 2 is a schematic cross-sectional view showing one example of a usage state of the fuel cell separator according to this embodiment;

(3) FIG. 3 is a schematic cross-sectional view showing one example of a contact of fuel cell separators;

(4) FIG. 4 is a graph showing a relation between a content rate of (PEDOT/PEG) copolymer in an antimony-doped tin oxide film that composes the separator, and contact resistance and an elastic modulus; and

(5) FIG. 5 is a graph showing a relation between an element ratio [(S+C)/Sn] of a total of sulfur and carbon to tin in the antimony-doped tin oxide film that composes the separator, and contact resistance.

DESCRIPTION OF EMBODIMENTS

(6) Referring to FIG. 1, an outline of a fuel cell separator according to this embodiment will be explained. A fuel cell separator 10 as shown in the example of FIG. 1 includes antimony-doped tin oxide (ATO) films (2 and 3) on a substrate 1.

(7) The fuel cell separator 10 according to this embodiment includes, as shown in the example of FIG. 2, gas surfaces 4 disposed in a gas diffusion layer included in a membrane electrode assembly 20 in such a way that the gas surfaces 4 are opposed to each other, which forms a gas flow path, and has electrical conductivity to draw electric power obtained from the membrane electrode assembly 20.

(8) The fuel cell typically has a stack structure in which the membrane electrode assemblies 20 are stacked on one another in order to obtain a necessary voltage. When the membrane electrode assemblies 20 are stacked on one another as shown in the example of FIG. 3, at least some of cooling surfaces 5 come in contact with each other in the fuel cell separator 10, whereby a contact part 6 is formed.

(9) In the fuel cell separator according to this embodiment, the ATO film contains a poly(3,4-ethylenedioxythiophene)/polyethylene glycol (PEDOT/PEG) copolymer in a content of 15% by volume or more but 25% by volume or less, whereby the elastic force of an antimony-doped tin oxide film is reduced, electrical conductivity in the contact part 6 of the separators is improved, and corrosion resistance of the substrate 1 is improved.

(10) In the following description, each of the components of the fuel cell separator according to this embodiment will be explained in detail.

(11) The material of the substrate 1 that composes the separator is not particularly limited, and can be selected as appropriate from among known materials used for a fuel cell separator. Examples thereof are a plastic material, a metallic substrate or the like. A metallic substrate is preferably used from the viewpoint of high corrosion resistance, high electrical conductivity and the like. The metal used for the metallic substrate may be, for example, iron, titanium, aluminum or an alloy such as stainless, but is not limited thereto. The metal is preferably titanium or stainless in view of corrosion resistance and is preferably stainless from the viewpoint of easy availability or the like.

(12) The shape of the substrate may be a desired shape in accordance with the design of the fuel cell. The shape of the separator may be, for example, the one that includes a gas surface 4 where a gas flow path can be formed on the side of the membrane electrode assembly 20 and a cooling surface 5 where a flow path of a refrigerant or the like can be formed on the surface on the opposite side of the gas surface 4.

(13) The thickness of the substrate may be selected as appropriate to the extent that gas blocking property and electrical conductivity are secured, and may be, for example, 0.05 mm-0.2 mm, and preferably 0.1 mm.

(14) The ATO film that composes the separator according to this embodiment includes an antimony-doped tin oxide and a PEDOT/PEG copolymer, and the PEDOT/PEG copolymer is contained in a content of 15% by volume or more but 25% by volume or less relative to the whole film.

(15) By containing the PEDOT/PEG copolymer having electrical conductivity in the ATO film in the aforementioned certain ratio, it is possible to give flexibility to the ATO film and to improve the electrical conductivity in the contact part 6 between the separators. Further, since the PEDOT/PEG copolymer does not include a polar group such as a sulfo group, it is possible to prevent hydrofluoric acid-based acid generated in the membrane electrode assembly 20 or hydrochloric acid-based acid generated in the gas flow path or the like from eroding the substrate, and to improve corrosion resistance of the separator.

(16) As shown in Examples that will be explained later, when the PEDOT/PEG copolymer is contained in a content of 15% by volume or more but 25% by volume or less relative to the whole film in the ATO film, the element ratio of a total of sulfur and carbon to tin [(S+C)/Sn] in the ATO film becomes 0.6 or more but 1.1 or less.

(17) The ATO film may be formed on both surfaces of the substrate, as shown in FIG. 1, may be formed only on the side of the gas surface 4 of the substrate, or may be formed only in the contact part 6 where the separators contact each other. The ATO film is preferably formed on both surfaces of the substrate in view of easiness of manufacturing, electrical conductivity, and corrosion resistance of the substrate.

(18) The PEDOT/PEG copolymer is preferably a block copolymer including a poly(3,4-ethylenedioxythiophene) block and a polyethylene glycol block. Since the PEDOT/PEG copolymer includes a poly(3,4-ethylenedioxythiophene) block, electrical conductivity is given to copolymer. The block copolymer may be, for example, a linear tri-block having a polyethylene glycol block on both ends of the a poly(3,4-ethylenedioxythiophene) block or a linear multi-block in which a poly(3,4-ethylenedioxythiophene) block and a polyethylene glycol block are alternately repeated.

(19) The PEDOT/PEG copolymer may be synthesized, for example, by a method of polymerizing 3,4-ethylenedioxythiophene and forming the poly(3,4-ethylenedioxythiophene) block, and then introducing polyethylene glycol thereinto, thereby forming the polyethylene glycol block at the end, or a commercial product may be used. The commercial product may be, for example, the one whose product name is Aedotron C3-NM, the one whose product name is Aedotron C-NM or the like manufactured by Aldrich.

(20) The antimony-doped tin oxide is not particularly limited, and a particle-shaped one having a particle diameter of 1 nm-500 nm may be, for example, selected as appropriate.

(21) While the method of forming the ATO film on the substrate is not particularly limited in this embodiment, the ATO film can be formed by, for example, preparing a coating liquid in which an antimony-doped tin oxide and a PEDOT/PEG copolymer are contained in a solvent in a desired ratio, applying this coating liquid onto the substrate, and heating and drying this substrate as necessary.

(22) The coating method is not particularly limited and may be, for example, selected from among coating means such as a spray coating method, a dip coating method, a bar coating method, a roll coating method, and a spin coating method.

(23) While the thickness of the ATO film is not particularly limited, it is preferably about 0.1 mm from the viewpoint of electrical conductivity and corrosion resistance.

EXAMPLES

(24) While this embodiment will be explained hereinafter in detail with reference to Examples and comparative examples, this embodiment is not limited to the following Examples.

Example 1

(25) A stainless (SUS447) plate (thickness: 0.1 mm) was prepared as a substrate and an antimony-doped tin oxide (particle diameter: 10 nm, product name: T-1 manufactured by Mitsubishi Materials Corporation) and a PEDOT/PEG copolymer nitromethane solution (product name: Aedotron C3-NM manufactured by Aldrich) were prepared as materials for an antimony-doped tin oxide film.

(26) The aforementioned substrate was placed in a vacuum chamber, argon gas was introduced therein under a vacuum condition, a voltage was applied to generate argon ions, and the substrate surface was hit, whereby the oxide film on the surface was removed.

(27) Separately from the aforementioned process, a mixed solution in which an antimony-doped tin oxide powder was mixed into a PEDOT/PEG copolymer nitromethane solution was prepared as a coating liquid. The mixing amount of the antimony-doped tin oxide powder was adjusted in such a way that the volume of PEDOT/PEG copolymer after the coating film formation became 15% by volume relative to the whole film.

(28) Next, the coating liquid was applied onto a substrate from which the oxide film was removed by a spin coating method (1000 rpm). Next, this substrate was heated to 100° C., and nitromethane was applied, whereby a substrate having an ATO film was formed.

Examples 2-3 and Comparative Examples 1-3

(29) A substrate having an ATO film was formed in a way similar to that in the Example 1 except that the coating liquid was prepared in such a way that the volume of the PEDOT/PEG copolymer became 5, 10, 20, 25, and 30% by volume relative to the whole film by changing the mixing amount of the antimony-doped tin oxide powder in the preparation of the coating liquid according to the Example 1.

Comparative Example 4

(30) A substrate having an ATO film was formed in a way similar to that in the Example 1 except that nitromethane solvent was used in place of the PEDOT/PEG copolymer nitromethane solution and a coating liquid in which the volume of PEDOT/PEG copolymer was 0% by volume relative to the whole film was prepared in the preparation of the coating liquid according to the Example 1.

(31) <Measurement of Contact Resistance>

(32) Two substrates, each having the ATO film according to the Example 1, were prepared, the surfaces of the substrates where the ATO films were formed were overlapped each other, and a voltage value when a constant current was applied between the substrates while applying pressure of 0.98 MPa per unit area was measured, whereby a resistance value was calculated. A measurement similar to that stated above was performed also in the Examples 2-3 and the comparative examples 1-4, whereby resistance values were calculated. FIG. 4 shows the results.

(33) <Measurement of Elastic Modulus of Film>

(34) Regarding each of the ATO films formed in the Examples 1-3 and the comparative examples 1-4, the elastic modulus at the depth of 10-15 nm of the indenter was measured by a nanoindentation method (continuous stiffness measurement method) using an ultramicro-hardness tester (Nano Indenter DCM manufactured by MTS Systems Corporation). A trigonal pyramid diamond indenter was used as the indenter. FIG. 4 shows the results.

(35) <Measurement of Element Ratio of Film>

(36) The ATO films according to the Examples 1-3 and the comparative examples 1-4 were measured by X-ray photoelectron spectroscopy (XPS) and thus the element ratio (S+C)/Sn was calculated. FIG. 5 shows a relation between the element ratio and the contact resistance.

(37) [Summary of Results]

(38) As shown in FIG. 4, when the content rate of PEDOT/PEG copolymer in the ATO film became high, the elastic modulus of the film tended to decrease. When the elastic modulus of the film decreased, the contact resistance tended to decrease. However, when the content rate of PEDOT/PEG copolymer was too large, the contact resistance tended to increase. It can be estimated that this is because the conductive network in a film made of tin oxide particles having high electrical conductivity was broken since the ratio of PEDOT/PEG copolymer increased. It has been revealed, from the aforementioned experimental results, that an antimony-doped tin oxide contains a (PEDOT/PEG) copolymer in a content of 15% by volume or more but 25% by volume or less, whereby the elastic modulus of the film is reduced and the adhesion between separators is improved, and the conductive network of the tin oxide particles is maintained, and thus the separator according to this embodiment having high electrical conductivity between separators is obtained.

(39) Further, as shown in FIG. 5, it has been revealed that, when PEDOT/PEG copolymer is included in the ATO film, the range in which the element ratio (S+C)/Sn is 0.6-1.1 is preferable in view of high electrical conductivity between separators.

(40) From the disclosure thus described, it will be obvious that the embodiments of the disclosure may be varied in many ways. Such variations are not to be regarded as a departure from the spirit and scope of the disclosure, and all such modifications as would be obvious to one skilled in the art are intended for inclusion within the scope of the following claims.