Graphene-and Hexagonal Boron Nitride van der Waals Heterostructured Solar Energy Processing Unit
20210280731 · 2021-09-09
Inventors
Cpc classification
H01L31/075
ELECTRICITY
H01L31/072
ELECTRICITY
Y02P70/50
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
H01L31/036
ELECTRICITY
Y02E10/544
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
H01L31/0336
ELECTRICITY
H01L31/1852
ELECTRICITY
Y02E10/548
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
H01L31/074
ELECTRICITY
International classification
H01L31/074
ELECTRICITY
H01L31/0336
ELECTRICITY
Abstract
A solar processing unit (SPU) for the conversion of solar energy to electric power includes a heterostructure of sheets of two (2)-dimensional materials. The heterostructure is utilized to produce a crystalline structure, wherein elemental Boron (B) and elemental Nitrogen (N), contained in sheets of hexagonal Boron Nitride (hBN), are located as bookends to one or more Carbons (C)s, between at least one sheet of Graphene. Each absorbed photon produces Multi-Excitation Generation, wherein more than one electron is generated. The SPU produces a spin motion of the Boron atoms in one direction and the Nitrogen atoms in the opposite direction within hBN by placing an external fixed magnetic field perpendicular to the sheet of hBN and a second orthogonal magnetic field paired to the strength of the fixed magnetic field and tuned to the resonant magnetic frequency of Nitrogen-15 followed by Boron-11, thereby achieving the spin required for enhanced photonic absorption.
Claims
1. A solar processing unit for the conversion of solar energy to electric power comprising: a metal base; a p-type layer of hexagonal boron nitride being deposited on the metal base; a layer of graphene being deposited on the p-type layer of hexagonal boron nitride; an n-type layer of hexagonal boron nitride being deposited on the layer of graphene; the layer of graphene sandwiched between the p-type layer of hexagonal boron nitride and the n-type layer of hexagonal boron nitride forming a heterostructure; and the n-type layer of hexagonal boron nitride being configured to be closer to a surface struck by sunlight than the p-type layer of hexagonal boron nitride.
2. The solar processing unit in claim 1, wherein a first insulating layer of hexagonal boron nitride is interjected between the p-type layer of hexagonal boron nitride and the layer of graphene, and wherein a second insulating layer of hexagonal boron nitride is interjected between the n-type layer of hexagonal boron nitride and the layer of graphene.
3. The solar processing unit in claim 1, wherein the metal base is composed of nickel.
4. The solar processing unit in claim 1, wherein the p-type layer of hexagonal boron nitride is doped with boron or lithium.
5. The solar processing unit in claim 1, wherein the n-type layer of hexagonal boron nitride is doped with nitrogen or fluorine.
6. The solar processing unit in claim 1, wherein the metal base is electrically connected to a negative terminal of the solar processing unit.
7. The solar processing unit in claim 1, wherein the n-type layer of hexagonal boron nitride is implanted with a conductive layer, and wherein the conductive layer is electrically connected to a positive terminal of the solar processing unit.
8. The solar processing unit in claim 7, wherein the conductive layer is composed of gold.
9. The solar processing unit in claim 7, wherein a proximal surface of a lens is deposited on the conductive layer.
10. The solar processing unit in claim 9, wherein the metal base is configured to reflect impinging electromagnetic radiation towards the lens.
11. The solar processing unit in claim 9, wherein an anti-reflective coating is deposited on a distal surface of the lens.
12. The solar processing unit in claim 9, wherein the lens is composed of borosilicate flat float glass.
13. The solar processing unit in claim 9, wherein a thickness of the lens ranges from a minimum of 0.7 mm to a maximum of 1.1 mm.
14. The solar processing unit in claim 1, wherein the layer of graphene is a monolayer of graphene, a bilayer of graphene, or a quadlayer of graphene.
15. A solar processing unit for the conversion of solar energy to electric power comprising: a metal base; the layer of graphene being bifurcated into a first graphene portion and a second graphene portion; a p-type layer of hexagonal boron nitride being deposited on the first graphene portion; the p-type layer of hexagonal boron nitride being implanted with a first conductive layer; the first conductive layer being electrically connected to a negative terminal of the solar processing unit; an n-type layer of hexagonal boron nitride being deposited on the second graphene portion; the n-type layer of hexagonal boron nitride being implanted with a second conductive layer; the second conductive layer being electrically connected to a positive terminal of the solar processing unit; the first conductive layer and the second conductive layer being deposited on a proximal surface of a lens; the first graphene portion, the p-type layer of hexagonal boron nitride, and the first conductive layer being electrically isolated from the second graphene portion, the n-type layer of hexagonal boron nitride, and the second conductive layer; the first graphene portion, the p-type layer of hexagonal boron nitride, and the first conductive layer being positioned adjacent to the second graphene portion, the n-type layer of hexagonal boron nitride, and the second conductive layer; and the first graphene portion and the second graphene portion being electrically connected to each other by the metal base.
16. The solar processing unit in claim 15, wherein a first insulating layer of hexagonal boron nitride is interjected between the p-type layer of hexagonal boron nitride and the first graphene portion, and a second insulating layer of hexagonal boron nitride is interjected between the n-type layer of hexagonal boron nitride and the second graphene portion.
17. The solar processing unit in claim 16, wherein the solar processing unit is configured to apply a forward bias voltage ranging from a minimum of 4 volts to a maximum of 5 volts across the metal base, thereby elevating a base voltage through the first graphene portion, the p-type layer of hexagonal boron nitride, the first conductive layer, and the metal base to resonate a bandgap of the p-type layer of hexagonal boron nitride in order to collect the available UV-A portion, the available UV-B portion, and the available UV-C portion of the solar spectrum, and thereby elevating the base voltage through the second graphene portion, the n-type layer of hexagonal boron nitride, the second conductive layer, and the metal base to resonate a bandgap of the n-type layer of hexagonal boron nitride in order to collect the available UV-A portion, the available UV-B portion, and the available UV-C portion of the solar spectrum.
18. The solar processing unit in claim 15, wherein an anti-reflective coating is deposited on a distal surface of the lens.
19. The solar processing unit in claim 18, wherein the anti-reflective coating is configured to transmit 20% of the available UV-A portion of the solar spectrum, transmit 80% of the available UV-B portion of the solar spectrum, or transmit 90% of the available UV-C portion of the solar spectrum.
20. The solar processing unit in claim 15, wherein the metal base is composed of gold.
21. The solar processing unit in claim 15, wherein the metal base is configured as a conductive backgate bridge.
22. The solar processing unit in claim 15, wherein the first conductive layer and the second conductive layer are composed of gold.
23. The solar processing unit in claim 15, wherein the first conductive layer and the second conductive layer are patterned with a plurality of fingers, and wherein the plurality of fingers covers a minimum of 5% of the total surface area of the proximal surface to a maximum of 25% of the total surface area of the proximal surface.
24. The solar processing unit in claim 23, wherein the plurality of fingers covers 15% of the total surface area of the proximal surface, and wherein the plurality of fingers is 301 fingers, and wherein each of the plurality of fingers is 14 millimeters in length and 15 micrometers in width, and wherein the plurality of fingers is spaced 85 micrometers apart from each other.
25. The solar processing unit in claim 15, wherein, wherein the p-type layer of hexagonal boron nitride is doped with boron or lithium.
26. The solar processing unit in claim 15, wherein the n-type layer of hexagonal boron nitride is doped with nitrogen or fluorine.
27. The solar processing unit in claim 15, wherein the metal base is electrically connected to a negative terminal of the solar processing unit.
28. The solar processing unit in claim 15, wherein the layer of graphene is a monolayer of graphene, a bilayer of graphene, or a quadlayer of graphene.
29. The solar processing unit in claim 15, wherein the metal base is configured to reflect impinging electromagnetic radiation towards the lens.
30. The solar processing unit in claim 15, wherein the lens is composed of borosilicate flat float glass.
31. The solar processing unit in claim 15, wherein a thickness of the lens ranges from a minimum of 0.7 mm to a maximum of 1.1 mm.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
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DETAILED DESCRIPTION OF THE INVENTION
[0025] All illustrations of the drawings are for the purpose of describing selected versions of the present invention and are not intended to limit the scope of the present invention.
[0026] The pi bonds between Boron and Nitrogen in Hexagonal Boron Nitride (hBN) are at least an order of magnitude greater than the pi bonds between Carbons in the hexagonal structure of Carbon. Therefore, substitution of Boron for Carbon or Nitrogen for Carbon are possible for Graphene, but not possible for hBN. However, as shown in
[0027] The Van der Waals forces between B, C, and N that are present in the three (3) Dimensional structure substitute for the pi forces in the two (2) Dimensional structure. These forces are mass-dependent. In the present invention, the mass of B, C, and N are similar with the value of the mass of Carbon only 16.6% greater than the mass of Nitrogen and 11.7% less than the mass of Boron.
[0028] To move electrons that are produced from the absorption of photons in the simplest embodiment of the solar processing unit (SPU) monolayer of Graphene with hBN bookends above and below, the hBN layer closest to the Sun must be an n-Type semiconductor, and the hBN layer farthest from the Sun must be a p-Type semiconductor. This is accomplished by electrochemically implanting the hBN with an element that has a high electronegativity in order to lessen the electronegativity of the Boron to produce an n-Type semiconductor, and by implanting the hBN with an element that has a low electronegativity in order to decrease the electronegativity of the Nitrogen to produce a p-Type semiconductor. The electronegativity of a group of elements from which can be selected one or more dopants for electrochemical attachment to Boron and Nitrogen is shown in
[0029] The SPU will function when there is a difference in electronegativity between the n-Type bookend and the p-Type bookend. However, the performance of the SPU is enhanced in proportion to the difference in electronegativity between the hBN bookends. From the electronegativity data in
[0030] The implant of strongly electronegative and electropositive elements in hBN to create n-Type and p-Type semiconductors is depicted in
[0031] A cross-section of a heterostructure for a preferred embodiment of the present invention is shown in
[0032] There are two (2) isotopes of each of Nitrogen and Boron. The heavier isotopes of each are the preferred forms for the invention, for these forms do not have the same number of neutrons and protons in their nucleus. These imbalances result in magnetic moments for their isotopes. The isotopes of Nitrogen and Boron and their Magnet Moments are shown in
[0033] The arrangement of orthogonal magnetic fields and the Fixed Magnetic Field and Resonant Nuclear Magnetic Frequencies pairs required to spin the nucleus of several elements is shown in
[0034] A cross section of a three (3) layer side by side Heterostructure, Embodiment Seven of the present invention that is equivalent to the five (5) layer Heterostructure, Embodiment Five in
[0035] A cross section of a three (3) layer side by side heterostructure, embodiment seven of the present invention that is equivalent to the five (5) layer heterostructure, embodiment five in
[0036] A cross section of a two (2) layer side by side heterostructure, embodiment eight of the present invention, that is equivalent to the three (3) layer heterostructure, embodiment six in
[0037] An assembly drawing for
[0038] A picture of an SPU dimensions of 31.75 mm, 1.25 inches, square, with the heterostructure of
[0039] With certain details and embodiments of the present invention for Systems and Methods for the conversion of Solar Energy to Electric Power disclosed, it will be appreciated by one skilled in the art that numerous changes and additions could be made thereto without deviating from the spirit or scope of the present invention. This is particularly true when one bears in mind that the presented preferred embodiments merely exemplify the broader invention revealed herein. Accordingly, it will be clear that those with major features in mind could craft embodiments that incorporate those major features while not incorporating all the features included in the preferred embodiments.
[0040] Therefore, the claims that will ultimately be employed to protect this invention will define the scope of protection to be afforded to the inventor. Those claims shall be deemed to include equivalent constructions insofar as they do not depart from the spirit and the scope of the invention. It must be further noted that a plurality of the following claims may express certain elements as means of performing a specific function, at times without the recital of structure of material. As the law demands, any such claim shall be construed to cover not only the corresponding structure and material expressly described in this specification but also the equivalents thereof.
[0041] Supplemental Description
[0042] As can be seen from
[0043] These embodiments of the present invention may further comprise a first insulating layer of hexagonal boron nitride 110 and a second insulating layer of hexagonal boron nitride 112. The first insulating layer of hexagonal boron nitride 110 is interjected between the p-type layer of hexagonal boron nitride 104 and the layer of graphene 106, while the second insulating layer of hexagonal boron nitride 112 is interjected between the n-type layer of hexagonal boron nitride 108 and the layer of graphene 106.
[0044] These embodiments of the present invention may further comprise a positive terminal 114, a negative terminal 116, and a conductive layer 120. The metal base 102 is electrically connected to the negative terminal 116. The n-type layer of hexagonal boron nitride 108 is implanted with the conductive layer 120 so that the conductive layer 120 is able to electrically connect to the positive terminal 114. The conductive layer 120 may be composed of gold.
[0045] These embodiments of the present invention may further comprise a lens 122 and an anti-reflective coating 124. A proximal surface of a lens 122 is deposited on the conductive layer 120, while the anti-reflective coating 124 is deposited on a distal surface of the lens 122. The lens 122 may be composed of borosilicate flat float glass. In addition, a thickness of the lens 122 may range from a minimum of 0.7 mm to a maximum of 1.1 mm. Moreover, the metal base 102 may be configured to reflect any impinging electromagnetic radiation (e.g. light) towards the lens 122.
[0046] Some other embodiments of the present invention have an objective of minimizing the number of layers by creating a U-shaped path for the electrons and holes. These embodiments may comprise a metal base 202, a p-type layer of hexagonal boron nitride 204, a layer of graphene 206, an n-type layer of hexagonal boron nitride 208, a first conductive layer 210, a second conductive layer 212, a positive terminal 214, a negative terminal 216, and a lens 218. The layer of graphene 206 is bifurcated into a first graphene portion 2061 and a second graphene portion 2062. The layer of graphene 206 may be a monolayer of graphene, a bilayer of graphene, or a quadlayer of graphene. The p-type layer of hexagonal boron nitride 204 is deposited on the first graphene portion 2061 and is then implanted with the first conductive layer 210 so that the first conductive layer 210 is able to electrically connect to the negative terminal 216. The p-type layer of hexagonal boron nitride 204 may be doped with boron or lithium, and the first conductive layer 210 may be composed of gold. Similarly, the n-type layer of hexagonal boron nitride 208 is deposited on the second graphene portion 2062 is then implanted with a second conductive layer 212 so that the second conductive layer 212 is able to electrically connect to the positive terminal 214. The n-type layer of hexagonal boron nitride 208 may be doped with nitrogen or fluorine, and the second conductive layer 212 may be composed of gold. This arrangement allows the first graphene portion 2061, the p-type layer of hexagonal boron nitride 204, and the first conductive layer 210 to be electrically isolated from the second graphene portion 2062, the n-type layer of hexagonal boron nitride 208, and the second conductive layer 212, while also allowing the first graphene portion 2061 and the second graphene portion 2062 to be electrically connected to each other by the metal base 202. The metal base 202 may be composed of gold and may be configured as a conductive backgate bridge. The metal base 202 may also be electrically connected to the negative terminal 216. In addition, the first graphene portion 2061, the p-type layer of hexagonal boron nitride 204, and the first conductive layer 210 are positioned adjacent to the second graphene portion 2062, the n-type layer of hexagonal boron nitride 208, and the second conductive layer 212. Moreover, the first conductive layer 210 and the second conductive layer 212 are both deposited on a proximal surface of the lens 218.
[0047] As can be seen from
[0048] These embodiments of the present invention may further comprise an anti-reflective coating 224. The anti-reflective coating 224 is deposited on a distal surface of the lens 218. The anti-reflective coating 224 may be configured to transmit 20% of the available UV-A portion of the solar spectrum, transmit 80% of the available UV-B portion of the solar spectrum, or transmit 90% of the available UV-C portion of the solar spectrum. The lens 218 may be composed of borosilicate flat float glass. In addition, a thickness of the lens 218 may range from a minimum of 0.7 mm to a maximum of 1.1 mm. Moreover, the metal base 202 may be configured to reflect any impinging electromagnetic radiation (e.g. light) towards the lens 218.
[0049] These embodiments of the present invention may allow the first conductive layer 210 and the second conductive layer 212 to be patterned with a plurality of fingers. The plurality of fingers may cover a minimum of 5% of the total surface area of the proximal surface to a maximum of 25% of the total surface area of the proximal surface. However, the plurality of fingers preferably covers 15% of the total surface area of the proximal surface. The plurality of fingers preferably has a total of 301 fingers. Each of the plurality of fingers is preferably 14 mm in length and 15 μm in width. The plurality of fingers is preferably spaced 85 μm apart from each other.
[0050] Although the invention has been explained in relation to its preferred embodiment, it is to be understood that many other possible modifications and variations can be made without departing from the spirit and scope of the invention as hereinafter claimed.