Hair treatment process

Abstract

The present invention relates to a process for straightening and frizz reduction of hair which leaves hair in one part straight and volumeless and the remaining part may still have the curly appearance but not frizzy at all. It has been found out when treating hair at the parts where the straight appearance is preferred with a composition comprising higher concentration of hair straightening ingredient and straightening the said part with an iron at relatively higher temperature and treating the remaining parts with a composition comprising the same straightening ingredient at a lower concentration and treating the said parts with an iron at relatively lower temperature provides hair structures which appear to be straight and with low volume in one part which is the part closer to the scalp and, curly and voluminous but not frizzy at the remaining parts which is usually the lengths.

Claims

1. A process for treating hair comprising: a) applying, to 30 to 60% of a first hair length calculated to its total length from the scalp, a first aqueous composition comprising b) applying, to 40 to 70% of a second hair length calculated to its total length from the tip of the hair, a second aqueous composition comprising at a concentration of C2; c) leaving the first and second aqueous compositions on the hair for 1 to 120 min; d) optionally rinsing the first and second aqueous compositions off the hair; e) drying the hair; f) treating the first hair length of a) with an iron having a first surface temperature of 190 to 230° C.; g) treating the second hair length of b) with an iron having a second surface temperature of 150 to 190° C.; h) optionally rinsing the first and second aqueous compositions off the hair; i) optionally shampooing the hair; and j) optionally drying the hair, wherein C1 is larger than C2, and the C2 is not more than 50%, by weight of the C1, calculated to a total of the first and second aqueous compositions.

2. The process of claim 1, wherein the aqueous compositions of a) and b) have a pH of 4.0 or lower.

3. The process of claim 1, wherein the aqueous compositions of a) and b) do not comprise more than 2% by weight, calculated to the total of each aqueous composition, any sulfur based reducing agent.

4. The process of claim 1, wherein the aqueous compositions of a) and b) comprise one or more surfactants selected from cationic, anionic, nonionic, and amphoteric surfactants.

5. The process of claim 1, wherein the aqueous compositions of a) and b) comprise at least one mono alkyl quaternary ammonium surfactant selected from compounds with the general formula ##STR00003## wherein R.sub.8 is a saturated or unsaturated, branched or straight alkyl chain with 8-22 carbon atoms or
R.sub.12—CO—NH—(CH.sub.2).sub.n— wherein R.sub.12 is a saturated or unsaturated, branched or straight alkyl chain with 7-21 carbon atoms and n is an integer of 1-4, or
R.sub.12—CO—O—(CH.sub.2).sub.n— wherein R.sub.12 is a saturated or unsaturated, branched or straight alkyl chain with 7-21 carbon atoms and n is an integer of 1-4, and R.sub.9, R.sub.10 and R.sub.11 are independent from each other an alkyl group with 1 to 4 carbon atoms, hydroxyl alky chain with 1 to 4 carbon atoms, or ethoxy or propoxy group with a number of ethoxy or propoxy groups varying in the range of 1 to 4, and X is chloride, bromide, methosulfate or ethosulfate.

6. The process of claim 1, wherein the aqueous compositions of a) and b) comprise one or more surfactants selected from cationic, anionic, nonionic, and amphoteric surfactants, at a concentration in the range of 0.05 to 10% by weight calculated to the total of the aqueous composition.

7. The process of claim 1, wherein the aqueous compositions of a) and b) comprise one or more hair conditioning compound.

8. The process of claim 1, wherein the aqueous compositions of a) and b) comprise at least one hair conditioning compound selected from cationic polymers, silicones, fatty alcohols, and conditioning oils, at a total concentration in the range of 0.01 to 15% by weight calculated to the total aqueous composition.

9. The process of claim 1, wherein the aqueous compositions of a) and b) comprise one or more silicone, at a concentration in the range of 0.1 to 10% by weight, calculated to the total of the aqueous composition.

10. The process of claim 1, wherein the aqueous compositions of a) and b) comprise aminated silicone.

11. The process of claim 1, wherein the aqueous compositions of a) and b) comprise one or more fatty alcohols, at a concentration in the range of 0.1 to 10% by weight, calculated to the total of the aqueous composition.

12. The process of claim 1, wherein the first surface temperature is greater than the second surface temperature.

Description

EXAMPLE 1

(1) Composition 1

(2) TABLE-US-00001 % by weight Glyoxylic acid 10.0 Amodimethicone 1.2 Cetearyl alcohol 3.5 Cetrimonium chloride 1.0 Fragrance 1.0 Sodium hydroxide to pH 2.0 Water to 100

(3) Composition 2

(4) TABLE-US-00002 % by weight Glyoxylic acid 3.0 Amodimethicone 0.8 Cetrimonium chloride 1.0 Fragrance 0.7 Sodium hydroxide to pH 2.0 Water to 100

(5) C2 (3.0% by weight) is 30% of the C1 (10.0% by weight).

(6) With the above two compositions hair of a volunteer having a length of 35 cm was treated. The hair was washed first with a commercially available cleansing shampoo composition and towel dried. The first composition was then applied onto the 14 cm (40%) of the hair measured from the scalp and the composition 2 was applied to the remaining 21 cm (60%) of the hair and the compositions were left on the hair for 20 min and the hair was dried afterwards. Afterwards, the part treated with the composition 1, the first 14 cm, was treated with an iron having a surface temperature of 220° C. and the part treated with the composition 2, the lower 21 cm, was treated with an iron having a surface temperature of 170° C.

(7) It was observed that the upper part of the hair was well straightened and had almost no volume whereas the lower part appeared to be still curly with big curls, although less curly than prior to the treatment, and had no frizzy appearance and had volume and the hair had natural movements with the head movements.

(8) Treating whole hair either with only composition 1 or only with composition 2 did not allow to obtain the above result. Treating hair only with composition 1 delivered straight hair with no curls at all and hair had lost its complete volume. On the other hand, treating whole hair with composition 2 did not provide hair parts enough straightening which was the aim of the treatment.

EXAMPLE 2

(9) Composition 1

(10) TABLE-US-00003 % by weight Glyoxylic acid 9.0 Amodimethicone 1.0 Behentrimonium chloride 0.8 Fragrance 1.0 Sodium hydroxide to pH 2.0 Water to 100

(11) Composition 2

(12) TABLE-US-00004 % by weight Glyoxylic acid 1.8 Amodimethicone 0.8 Steartrimonium chloride 0.6 Fragrance 0.7 Sodium hydroxide to pH 2.0 Water to 100

(13) C2 (1.8.0% by weight) is 20% of the C1 (9.0% by weight).

(14) Similar results were obtained as in the Example 1.

EXAMPLE 3

(15) Composition 1

(16) TABLE-US-00005 % by weight Glyoxylic acid 10.0 Amodimethicone 1.0 Behentrimonium chloride 0.8 Hydroxyethylcellulose 1.0 Fragrance 1.0 Sodium hydroxide to pH 2.0 Water to 100

(17) Composition 2

(18) TABLE-US-00006 % by weight Glyoxylic acid 2.5 Amodimethicone 0.8 Steartrimonium chloride 0.6 Xanthan gum 0.5 Fragrance 0.7 Sodium hydroxide to pH 2.0 Water to 100

(19) C2 (2.5% by weight) is 25% of the C1 (10.0% by weight).

(20) Similar results were obtained as in the Example 1.