WATER CONDITIONER FOR PREVENTING OR REDUCING MINERAL PRECIPITATES

Abstract

The present invention relates to a water treatment apparatus (1), in particular for supplying water-conducting and/or water-heating household appliances or appliances for producing and preparing food and/or beverages using treated drinking water, e.g. automatic drinks machines, automatic coffee machines, ice machines, cooking and baking appliances, steam generators or high-pressure cleaners, air conditioners or the like using treated water, comprising an agent (3) present in solid form for reducing mineral precipitates.

It is characterized in that a first medium which influences the dissolution behavior of the agent for reducing mineral precipitates is provided.

Claims

1. A water treatment apparatus (1), in particular for supplying water-conducting and/or water-heating household appliances or appliances for producing and preparing food and/or beverages using treated drinking water, e.g. automatic drinks machines, automatic coffee machines, ice machines, cooking and baking appliances, steam generators or high-pressure cleaners, air conditioners or the like using treated water, comprising an agent (3) present in solid form for reducing mineral precipitates, where a first medium (4) which influences the dissolution behavior of the agent for reducing mineral precipitates is provided, characterized in that a second medium (5) which influences the dissolution behavior of the agent (3) for reducing mineral precipitates is provided.

2.-40. (canceled)

41. In a water treatment apparatus having a water inlet, water outlet and a phosphate, triphosphate or a polyphosphate complexing agent for reducing mineral precipitates wherein the improvement comprises a housing having a first chamber connected to the inlet and containing a cation ion exchanger or an acidic ion exchanger to provide a first liquid medium selected from a group consisting of an acidic aqueous liquid or water treated by the cation ion exchanger to increase solubility of the phosphate, triphosphate or the polyphosphate complexing agent and a second chamber disposed in the housing and connected to the first chamber and to a bypass to the inlet said second chamber containing the phosphate, triphosphate or the polyphosphate complexing agent and a solubility decreaser to decrease the solubility of the phosphate, triphosphate or the polyphosphate complexing agent to provide an environment or second medium less acidic than the first liquid medium to change the dissolution behavior of the phosphate, triphosphate or the polyphosphate complexing agent in the opposite direction to decrease the solubility of the phosphate, triphosphate or the polyphosphate complexing agent.

42. The water treatment apparatus of claim 41 further comprising a mixing space disposed in the second chamber.

43. The water treatment apparatus of claim 41 wherein the phosphate, triphosphate or polyphosphate complexing agent is embedded in the solubility decreaser or the solubility decreaser is embedding the phosphate, triphosphate or polyphosphate complexing agent.

44. The water treatment apparatus of claim 43 wherein the solubility decreaser is a pH increaser.

45. The water treatment apparatus of claim 44 wherein the solubility decreaser is calcium carbonate, magnesium carbonate or a mixture thereof.

46. The water treatment apparatus of claim 44 wherein the solubility decreaser is an anion exchanger and/or a weakly basic anion exchanger in a hydroxyl or partially hydroxyl form.

47. The water treatment apparatus of claim 41 further comprising a connection head and wherein the filter housing is exchangeable.

48. The water treatment apparatus of claim 41 wherein the second medium is any leftover liquid from the bypass and/or from the first liquid medium.

49. The water treatment apparatus of claim 48 wherein the leftover liquid is treated by the solubility decreaser during stagnation or when water does not flow through the water treatment apparatus.

50. The water treatment apparatus of claim 49 wherein the leftover liquid is treated by the solubility decreaser and the solubility decreaser is an anion exchanger or a weakly basic anion exchanger.

51. The water treatment apparatus of claim 50 wherein the leftover liquid treats the phosphate, triphosphate or polyphosphate complexing agent.

52. The water treatment apparatus of claim 48 further comprising a connection head and wherein the filter housing is exchangeable.

53. A filter apparatus to treat a solid agent for reducing mineral precipitates comprising: (a) a filter cartridge with an inlet opening and an outlet opening; (b) a first chamber disposed between the inlet opening and the outlet opening containing a solubility increaser for the agent to reduce mineral precipitates selected from the group consisting of a cation exchanger, an acidic ion exchanger or a combination thereof; (c) a second chamber disposed between the first chamber and the outlet opening said second chamber containing an agent to reduce mineral precipitates selected from the group consisting of a phosphate containing composition or a triphosphate composition or a polyphosphate composition or a combination thereof; and (d) a solid solubility decreaser for the agent to reduce mineral precipitates to treat the agent disposed in said second chamber to reduce mineral precipitates, where said solubility decreaser for the agent to reduce mineral precipitates is selected from the group consisting of a solubility moderator, a concentration moderator, an anion exchanger, a weakly basic ion exchanger in a hydroxyl or partially hydroxyl form or a combination thereof.

54. The filter apparatus of claim 53 wherein the first chamber and the second chamber are in axial alignment.

55. The filter apparatus of claim 54 wherein the first chamber and the second chamber are in substantial axial and radial alignment.

56. The filter apparatus of claim 55 wherein the second chamber has a mixing chamber disposed in an upper end.

57. The filter apparatus of claim 56 wherein the phosphate containing composition or the triphosphate composition or the polyphosphate composition is disposed in the mixing chamber in the upper end of the second chamber.

58. The filter apparatus of claim 57 wherein the mixing chamber communicates with the outlet and air surrounding the outlet when water does not flow through the filter.

59. The filter apparatus of claim 58 wherein air surrounding the outlet enters the mixing chamber to assist the action of the solid solubility decreaser.

60. The filter apparatus of claim 54 wherein the solubility decreaser is an anion exchanger or a weakly basic ion exchanger in the hydroxyl or partially hydroxyl form.

61. The filter apparatus of claim 60 wherein the agent to reduce mineral precipitates is embedded in the anion exchanger or weakly basic ion exchanger in the hydroxyl or partially hydroxyl form or the anion exchanger or weakly basic ion exchanger in the hydroxyl or partially hydroxyl form is embedded in the agent to reduce mineral precipitates.

62. A filter device to treat water and to treat a solid agent to reduce mineral precipitates comprising: (a) a filter cartridge having a water inlet and a water outlet; (b) a first chamber disposed between the water inlet and the water outlet; (c) a pH decreaser disposed in the first chamber to decrease a pH of a first medium when introduced into the first chamber and decrease the pH around the solid agent to reduce mineral precipitates; (d) a second chamber connected to a bypass to the water inlet and disposed between the first chamber and the outlet opening, said second chamber containing the solid agent to reduce mineral precipitates; (e) a solid pH increaser to increase a pH environment surrounding the solid agent to reduce mineral precipitates by producing a second medium from a leftover liquid when introduced from the bypass and/or the first medium to increase the pH around the solid agent to reduce mineral precipitates wherein the solid pH increaser is selected from the group consisting of a solid less acidic than the pH of the first medium to change the dissolution behavior of the solid agent to reduce mineral precipitates in the opposite direction to reduce the solubility of the solid agent to reduce mineral precipitates; and (f) wherein the pH increaser is embedded in the solid agent to reduce mineral precipitates or the solid agent to reduce precipitates is embedded in the pH increaser or the pH increaser is created when a fluid is introduced into the first chamber or second chamber or the bypass to the second chamber form the second medium.

63. The filter device of claim 62 wherein the solid agent is a phosphate, triphosphate or polyphosphate complexing agent.

64. The filter device of claim 63 wherein the pH decreaser in the first chamber is a cation exchanger in the hydrogen form.

65. The filter device of claim 63 wherein the pH increaser in the second chamber is an anion exchanger or a weakly basic anion exchanger.

66. The filter device of claim 63 wherein the pH increaser in the second chamber is calcium carbonate or magnesium carbonate.

67. The filter device of claim 63 further comprising a connection head and wherein the filter cartridge is interchangeable.

68. The filter device of claim 62 wherein the solid pH increaser treats the solid agent to reduce mineral precipitates.

Description

BRIEF DESCRIPTION OF THE SEVERAL VIEWS OF THE DRAWING(S)

[0047] The accompanying figures show, purely by way of example and schematically, possible working examples. The figures show

[0048] FIG. 1 a vessel charged with an agent for reducing mineral precipitates,

[0049] FIG. 2 a water filter element equipped with a vessel as per FIG. 1,

[0050] FIG. 3 a water treatment apparatus having a conduit connection head,

[0051] FIG. 4 a water treatment apparatus having a water tank,

[0052] FIG. 5 a water treatment apparatus having a connection element for connection to an appliance,

[0053] FIG. 6 a water filter element equipped with an agent for reducing mineral precipitates embedded in a solid or immobilized medium,

[0054] FIG. 7 a water treatment apparatus in a water filter jug,

[0055] FIG. 8 a vessel which is charged with an agent for reducing mineral precipitates and has very widely spaced feed lines for the media and has flow all around,

[0056] FIG. 9a a water treatment apparatus having a water tank when flow is occurring through the apparatus, and

[0057] FIG. 9b a water treatment apparatus having a water tank when flow is not occurring through the apparatus.

DETAILED DESCRIPTION OF THE INVENTION INCLUDING BEST MODE

[0058] Accordingly, FIGS. 1 and 2 show, as part of a water treatment apparatus 1, a second receptacle 2 disposed in a second chamber or compartment 2a. The second receptacle 2 has a porous wall 2b and contains an agent 3 for reducing mineral precipitates. Arrows symbolically show flow paths for a first medium 4 which influences the dissolution behavior of the agent for reducing mineral precipitates and for a second medium 5 which likewise influences the dissolution behavior of the agent for reducing mineral precipitates. The receptacle 2 which is formed by a preferably porous wall 6 forms a mixing space 7 for the first medium and second medium 4, 5 in its interior.

[0059] Dots symbolizing a porous material forming the receptacle 2 are shown by way of example to the left of the symbolically depicted axis 8. Depending on the configuration and arrangement of feed lines for the first medium and the second medium 4, 5, the latter can flow in over the total length of the wall 6 into the interior of the receptacle 2. Arrows 9, 10 once again symbolically show a preferred region for passage of the medium 4, 5 concerned through the wall 6. This can either be formed by a feed section opening into this region and/or optionally also be brought about by appropriate measures, e.g. targeted matching of the flow behavior of the two media or by an increased permeability of the wall 6 in these regions compared to the other wall regions and/or end faces.

[0060] As an alternative to a porous embodiment of a wall 6, such a wall can also be made impermeable and have correspondingly prepared permeable regions in appropriate regions, as shown symbolically by way of. example on the right-hand side by the arrows 11, 12. This makes targeted flow of the two media 4, 5 possible. In offtake operation, i.e. when comparatively good flow occurs, it can in this way be ensured that essentially only the first medium 4 flows around the agent 3 for reducing mineral precipitates and the second medium 5 is supplied essentially directly and without effect on the agent 3 to the discharge stream of the treated water. A retention means 14, e.g. in the form of a sieve, a mesh, a woven fabric or another liquid-permeable material, can additionally assist the separation of the two media streams 4, 5 by retaining the agent 3 in the section of the mixing space 7 remote from the outlet.

[0061] FIG. 2 shows a filter element 15 having a first chamber or first compartment or first receptacle or housing 16, a connection element 17 and the second receptacle 2 disposed in the second chamber or compartment 2a as per the depiction in FIG. 1. A first substream 18 of the water to be treated by the water treatment apparatus 1 flows via a treatment section 19 and forms the first medium 4 at the outlet thereof. The treatment section 19 can, for example, have a pH reducer, e.g. a cation exchanger, in particular an acidic cation exchanger, for example a weakly acidic cation exchanger, e.g. in the form of a resin. After flowing through the treatment section 19, this first substream forms the first medium 4. A second substream conveyed separately from the first substream, e.g. as bypass 21 to the treatment section 19, forms the second medium 5.

[0062] FIG. 3 shows, by way of example and schematically, a water treatment apparatus 1 having a conduit connection head 22, a feed line 23, a discharge line 24 and a filter element 15 connected thereto with at least one first medium 4 and an agent for reducing mineral precipitates 3 arranged therein.

[0063] FIG. 4 shows a water treatment apparatus 1 comprising a water tank 25 and once again a filter element 15 with at least a first medium 4 and an agent for reducing mineral precipitates 3.

[0064] FIG. 5 shows a further embodiment of a water treatment apparatus 1, comprising a filter element 15 with at least one first medium 4 and an agent for reducing mineral precipitates 3 and a connection element 26 for connection to an appliance 27 to be supplied by the apparatus 1.

[0065] FIG. 6 shows a filter element 15 having a housing 16, a connection element 17 and a second medium 5 which is arranged in a fixed and/or immobilized fashion and in which an agent for reducing mineral precipitates 3 is embedded. It is also possible for the agent 3 to be arranged upstream and/or downstream of the second medium 5. A first substream 18 of the water to be treated by the water treatment apparatus 1 flows via a treatment section 19 and forms the first medium 4 at the outlet thereof. The treatment section 19 can have an acidic or weakly acidic cation exchanger, e.g. in the form of a resin. The medium 4 then flows via the agent for reducing mineral precipitates 3 and the second medium 5 surrounding it. The second medium 5 can be, for example, a medium having a basic reaction, for example a basic or weakly basic anion exchanger and/or a pH increaser, for example sparingly soluble calcium carbonate and/or magnesium carbonate and/or another medium which inhibits the dissolution, moderates the dissolution or moderates the concentration in water of the agent for reducing mineral precipitates. A second substream which is conveyed separately from the first substream, e.g. as bypass 21 to the treatment section 19, mixes with the first substream downstream of the agent for reducing mineral precipitates.

[0066] As a further variant, the mixing of the two substreams can also be provided in the region of the agent for reducing mineral precipitates 3 in order to exert a further influence on the solubility behavior of the agent 3 in combination with the second medium 5.

[0067] In a further embodiment, the water to be treated can be introduced into the water treatment apparatus 1 entirely via a treatment section 19 at the outlet of which the first medium 4 is formed and this then flows through the agent for reducing mineral precipitates 3 or, in a further variant, through the agent 3 in combination with a second medium 5.

[0068] FIG. 7 shows a water treatment apparatus 1 comprising a water tank 25, a filter element 15 and a filtrate storage tank 27. The filter element 15 comprises at least one first medium 4 and an agent for reducing mineral precipitates 3.

[0069] FIG. 8, as part of a water treatment apparatus 1, shows a receptacle 2 for an agent 3 for reducing mineral precipitates. Flow paths for a first medium 4 which influences the dissolution behavior of the agent for reducing mineral precipitates and for a second medium 5 which likewise influences the dissolution behavior of the agent for reducing mineral precipitates are depicted symbolically by arrows 4. The space surrounding the receptacle 2 forms the mixing space 7 for the first and second media 4 and 5. The mixing of the two media 4 and 5 is depicted symbolically by arrows 28.

[0070] FIGS. 9a and 9b show, purely by way of example and schematically, a filter element 15 of a water treatment apparatus consisting, for example, of the filter element 15 and a water tank or an appliance, shown in section in two different operating states. FIG. 9a shows a depiction in the operating state and FIG. 9b shows a depiction in the stagnation state.

[0071] In both depictions, the filter element 15 comprises a housing 16, a conduit 32, for example in the form of a tube, arranged in the interior of the housing, an inlet opening 34 and an outlet opening 35. The inlet opening 34 is located between housing 16 and the wall of the conduit 32 and can comprise a retention means 31, for example in the form of a sieve. The outlet opening 35 is formed in the end region of the conduit 32. It can either directly be the end region thereof or else can be configured in the form of a change in the cross section, for example a reduction in the cross section. A connection piece for connection of the filter element 15, for example to a tank, can advantageously also be provided at this end region of the conduit.

[0072] A retention means 31 for filter material arranged in the intermediate space between housing 16 and conduit 32 can be provided in the inlet region of the filter element 15, i.e. the opening 34. At the end of the conduit 32 opposite the outlet, in the interior of the housing 16, there is a receptacle 2 containing agent 3 for reducing mineral precipitates. This receptacle 2 can, for example, have a depression into which the conduit 32 can be plugged, or conversely by means of which the receptacle 2 can be placed on or pushed onto the conduit 32. A further retention means 29 can optionally be provided between the receptacle 2 and the conduit 32 in order to prevent, for example, passage of particles or the receptacle itself can act as retention means for particles.

[0073] The inflow 36 of the water to be treated by the filter element is depicted symbolically by two arrows in the inlet region in FIG. 9a. The incoming water flows in the flow direction through the treatment section 19 and forms, by contact with the latter, the first medium 4. The treatment section can have, for example, a pH reducer, e.g. a cation exchanger, in particular a weakly acidic cation exchanger, e.g. in the form of a resin. The first medium 4 flows onward in the flow direction and penetrates into the receptacle 2 and can then act on the medium 3 for reducing mineral precipitates which is arranged therein in such a way that the water flowing through is treated in the desired way and optimally protects against mineral precipitates. It subsequently goes into the interior of the receptacle in the direction of the conduit 32 and flows along the interior wall thereof, for example as peripheral flow in the form of a water film, to the outlet opening 35.

[0074] In the operational depiction as per FIG. 9a, a comparatively small amount of filtrate 33 is shown in the outlet region of the conduit 32. This is due to the outflow in the direction of the appliance using the water due to offtake of water. Suction pumps are usually used for offtake of the treated water, i.e. the filtrate. Such pumps generate a reduced pressure in the piping system during operation and this can in turn draw along further water to be treated, for example from a tank in which the filter element 15 is located. The level of the water present in the filter cartridge rises during operation to such an extent that flow through the filter element occurs. A level 30 which is located in the region of the upper edge of the receptacle 2 is drawn in by way of example in FIG. 9a.

[0075] The second medium 5, which can be, for example, air or a CO.sub.2 gas mixture, is located in the interior of the conduit 32. During the operational state as shown in FIG. 9a, this second medium is drawn in the direction of the outlet by outflow of the filtrate 33 banked up therein due to the volume change in the interior of the conduit 32. In the stagnation state or in phases in which flow does not occur through the apparatus, as shown in FIG. 9b, the filtrate 33 again collects in the outlet region of the conduit 32 because it has not been taken off and thus reduces the volume available for the second medium and thus pushes this in a direction opposite the operational flow direction of the filter element in the direction of the receptacle 2 and through this in the direction of the treatment section 19 which is present between the outer wall of the conduit 32 and the housing 16.

[0076] An illustrated depiction of a level 30, in the case of flow equilibrium upstream and downstream of the receptacle 2, is drawn in by way of example below the upper edge of the receptacle 2 in FIG. 9b. In this case, the agent 3 for reducing mineral precipitates is supplied with the second medium and is correspondingly influenced by the latter. In this embodiment, in which air or a CO.sub.2 gas mixture is provided as second medium, the contact of the agent 3 with the first medium 4 is interrupted or reduced. As a consequence, the second medium 5 acts, for example, on the solubility behavior of the agent 3 and/or on the concentration of the agent in the water as a result of a corresponding reduction of the moisture content in the receptacle 2 and/or by reduction or hindering of the contact between the agent 3 and the first medium 4. As a result, an excessive concentration of the agent in the treated water during stagnation phases or phases in which flow does not occur through the filter element is prevented. The agent 3 can then briefly dissolve again in a sufficient concentration in the water when water is next taken off or when flow occurs through the filter element due to the previous conversion of the stream of the water to be treated into a first medium 4 (for example by acidification).

[0077] When during the subsequent operational phase water to be treated again flows in the operational flow direction through the filter element and the level 30 thus rises again until the water flowing through the filter material forms the first medium 4 and this again penetrates into the receptacle 2 and thus comes into contact with the agent 3 for reducing mineral precipitates, the agent 3 can again be influenced so that the water to be treated can leave the receptacle 2 in the desired quality and can accordingly be available for offtake at the outlet 35.

[0078] Further information on possible embodiments is given below.

[0079] Particularly sparingly soluble polyphosphate salts display a solubility which has a pronounced dependence on the pH of the liquid surrounding them. The following table shows, by way of example, the dissolution behavior of sparingly soluble polyphosphate salts overnight in water at different pH values of the water.

TABLE-US-00001 pH Concentration of polyphosphate 4.0 60 mg/l 5.0 10 mg/l 6.0  4 mg/l 7.0  2 mg/l

[0080] This property is utilized for increasing the amount of dissolved complexing agents, e.g. polyphosphate, in a water stream flowing continuously or semi-continuously through an apparatus containing sparingly soluble complexing agents, e.g. sparingly soluble polyphosphate salts, by carrying out targeted prior acidification of the stream of water. The prior acidification spontaneously increases the solubility of the sparingly soluble complexing agent or of the sparingly soluble polyphosphate salt.

[0081] In a particular embodiment, the stream of water is divided into at least two substreams of which at least one substream is acidified before being passed through an apparatus containing a sparingly soluble complexing agent, e.g. sparingly soluble polyphosphate salts. This substream, which preferably makes up from 5 to 50% of the total volume flow, is, after flowing through the apparatus, recombined with the other substreams. This enables a targeted influence to be exerted on the concentration of dissolved complexing agent, for example polyphosphate, even during continuous throughput in order to achieve effective protection or effective reduction of mineral precipitates, e.g. of calcium carbonate.

[0082] In a further preferred embodiment, the apparatus is configured so that when the continuous or semicontinuous volume flow is interrupted, the acidified water in contact with the complexing agent is neutralized, for example by the unacidified water combining with the acidified water, e.g. by means of diffusion, and neutralizing it in such a way that the pH of the mixture rises again and is preferably in the range from pH 5.5 and pH 7. As a result of this type of automatic control, the release of excessive amounts of complexing agents, for example of polyphosphate, and exceeding of maximum permissible values is avoided even during prolonged stagnation times, e.g. overnight or during weekends.

[0083] In a further preferred embodiment, the provision of acidified raw water can be effected by filtration of a substream through a weakly acidic cation exchanger which is predominantly in the hydrogen form. Owing to the chemistry of this exchanger, this water has a pH of 3.3-4.5 within the flow range specified for the use, virtually independently of the throughput. The acidified substream is introduced from one side, e.g. radially, through the porous wall of a perforated sheath which is completely or only partially filled with the polyphosphate (e.g. a carbon block filter). At the same time, raw water or unacidified water is introduced from the opposite side. As a result of the simultaneous introduction of the two volume streams in continuous operation, barely any mixing of the raw water, or of the unacidified water, with acidified water takes place in the entry zone of the acidified water and thus in the region of the polyphosphate bed, so that the water coming into contact with the polyphosphate bed has a sufficiently reduced pH for bringing about a targeted increase in the solubility of the polyphosphate during the contact time available. When the acidified water enriched with polyphosphate is drained from the sheath, the acidified water enriched with polyphosphate mixes with the unacidified water in the sheath and forms a mixed water having the desired polyphosphate concentration. As a result, satisfactory concentrations of dissolved polyphosphate in the mixed water are achieved in continuous operation of the apparatus even when using sparingly soluble polyphosphate.

LIST OF REFERENCE NUMERALS

[0084] 1 Water treatment apparatus

[0085] 2 Second receptacle

[0086] 2a Second chamber or second compartment

[0087] 2b Porous wall

[0088] 3 Agent for reducing mineral precipitates

[0089] 4 First medium

[0090] 5 Second medium

[0091] 6 Wall

[0092] 7 Mixing space

[0093] 8 Axis

[0094] 9 Arrow

[0095] 10 Arrow

[0096] 11 Arrow

[0097] 12 Arrow

[0098] 13 Outlet stream

[0099] 14 Retention means

[0100] 15 Filter element

[0101] 16 Housing or first chamber or first compartment or first receptacle

[0102] 17 Connection element

[0103] 18 Substream

[0104] 19 Treatment section

[0105] 20 Substream

[0106] 21 Bypass

[0107] 22 Conduit connection head

[0108] 23 Feed line

[0109] 24 Discharge line

[0110] 25 Water tank

[0111] 26 Connection element

[0112] 27 Filtrate storage tank

[0113] 28 Arrow

[0114] 29 Retention means

[0115] 30 Level

[0116] 31 Retention means

[0117] 32 Conduit

[0118] 33 Filtrate

[0119] 34 Inlet opening

[0120] 35 Outlet opening

[0121] 36 Inflow