METHOD OF MANUFACTURING GLASS VESSEL, AND APPARATUS FOR MANUFACTURING GLASS VESSEL

Abstract

A method of producing a glass vessel includes holding a borosilicate glass tube with a first holding device, and holding an open end portion of the glass tube with a second holding device such that the second holding device is spaced apart from the first holding device. Heat is applied to the glass tube by a burner to separate the open end portion and form a bottom portion on the open end portion. Fire-blast treatment of an inner surface of the open end portion with a flame from a point burner is performed during at least a part of (i) applying heat to the borosilicate glass tube for separation, (ii) applying heat to the separated open end portion for bottom portion formation, and/or (iii) a period applying heat to the separated open end portion and prior to releasing the glass vessel from the second holding device.

Claims

1-9. (canceled)

10. An apparatus for producing a glass vessel, said apparatus comprising: a first holding device configured to hold a borosilicate glass tube; a second holding device configured to hold an open end portion of the borosilicate glass tube, said second holding device being spaced apart from said first holding device; a burner configured to apply heat to the borosilicate glass tube at a location between said first holding device and said second holding device so as to soften the borosilicate glass tube and separate the open end portion from a remainder of the borosilicate glass tube, and configured to apply heat to the separated open end portion to form a bottom portion on the open end portion and thereby form the glass vessel; and a point burner configured to perform fire-blast treatment of an inner surface of the open end portion with a flame while said second holding device holds the open end portion and during at least one of (i) application of heat to the borosilicate glass tube by the burner, (ii) application of heat to the separated open end portion to form the glass vessel, and (iii) after applying heat to the separated open end portion and prior to release of the glass vessel by said second holding device.

11. The apparatus for producing the glass vessel according to claim 10, wherein said point burner is configured to perform the fire-blast treatment such that a temperature of an outer surface of the open end portion opposite a deteriorated region of the open end portion is between 650° C. and 800° C.

12. The apparatus for producing the glass vessel according to claim 11, further comprising a non-contact thermometer for measuring the temperature.

13. The apparatus for producing the glass vessel according to claim 10, wherein said point burner is configured to jet an oxygen-flammable gas flame containing an oxonium ion toward the inner surface of the open end portion.

14. The apparatus for producing the glass vessel according to claim 13, wherein the oxygen-flammable gas flame containing the oxonium ion is a mixed gas flame of a flammable gas and oxygen.

15. The apparatus for producing the glass vessel according to claim 10, wherein the glass vessel is a glass vial or ampule for medical use.

16. The apparatus for producing the glass vessel according to claim 10, further comprising a gas evacuation device for performing gas evacuation of the glass vessel prior to or after said fire-blast treatment.

17. The apparatus for producing the glass vessel according to claim 10, further comprising an oven configured to anneal the glass vessel after the glass vessel is released from said second holding device.

18. The apparatus for producing the glass vessel according to claim 10, wherein said first holding device is a first chuck, and said second holding device is a second chuck.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0022] FIG. 1 is a schematic diagram illustrating a conventional fire blast treatment process.

[0023] FIG. 2 is a plan view of a vertical glass vessel producing apparatus which is schematically shown for ease of understanding.

[0024] FIG. 3 is a partial elevation view of the vertical glass vessel producing apparatus of FIG. 2.

[0025] FIG. 4 is a schematic diagram illustrating the fire-blast treatment process of the present invention.

DETAILED DESCRIPTION OF THE INVENTION

[0026] The present invention will hereinafter be explained in detail by describing an embodiment of a method of producing a glass vessel, and an embodiment of an apparatus for producing the glass vessel. However, it is to be understood that the specific features explained below are simply exemplary, and it should be clear to a person of ordinary skill in the art that the method and apparatus can be modified within the scope of the claims.

[0027] FIG. 2 illustrates an apparatus 10 for producing a glass vessel 11 (not shown in FIG. 2), and the apparatus 10 is of the vertical glass forming variety. The apparatus 10 includes a pair of turntables 12, 13, with the first (upper) turntable 12 including a plurality of first (upper) holding devices 14, and the second (lower) turntable 13 including a plurality of second (lower) holding devices 15. Each of the second holding devices 15 is associated with a point burner 16 for performing the fire-blast treatment during formation of the glass vessel 11.

[0028] In the apparatus 10 shown in FIG. 2, the turntables rotate synchronously and intermittently at a predetermined interval with the turntable 12 rotating clockwise while the turntable 13 rotates counterclockwise, such that one first holding device (the device located at the position “e” in the embodiment of FIG. 2) is located just above a second holding device (the device located at the position “A” in the embodiment shown in FIG. 2) at a certain timing as shown in FIG. 2. Thus, both devices hold a glass tube (not shown in FIG. 2) together at such timing. In the embodiment shown in FIG. 2, the turntable 12 rotates by increments of 22.5 degrees intermittently (because the sixteen holding devices of turntable 12 are evenly spaced apart) while the turntable 13 rotates by increments of 45 degrees intermittently (because the eight holding devices of turntable 13 are evenly spaced apart). The term “intermittently” means that the table repeats turning by the above mentioned increments and then stopping for a period of time for a predetermined action depending on the position, such as actions including the application of heat, the separation from the glass tube, cooling, the bottom formation and/or releasing from the turn table.

[0029] In the embodiment shown in FIG. 2, it is readily seen at the next timing that the first holding device located at the position “d” which is already holding the next glass tube will be positioned after 22.5 degree rotation so that it will be located just above the second holding device after 45 degree rotation which is located at the position “H”, which second holding device will also hold the next glass tube so that those holding devices will hold the next glass tube together.

[0030] The fire-blast treatment is carried out during at least a part of the term when the second holding device holds a glass tube, a preform for the glass vessel, and a glass vessel after the formation of the bottom portion during any period after the turn table has just stopped and just before the turn table will start to turn again.

[0031] When focusing on a certain second holding device, the fire-blast treatment is carried out during at least a part of a period when said second holding device turns by almost 360 degrees from the position “A” through the position “E” toward the position “A” before the glass vessel is released from the second holding device. That is, the fire-blast treatment may be carried out throughout such period at any one, or any combination of two or more of the positions “A” to “H”.

[0032] In one embodiment, the fire-blast treatment is carried out when the second holding device is tentatively stopped at only the position “A” or at the positions from the position “A” to the position “C”. In another embodiment, the fire-blast treatment is carried out when the second holding device is tentatively stopped at only the position “D” or at the positions from the position “D” to the position “G”.

[0033] In a further embodiment, the fire-blast treatment is carried out when the second holding device moves from the position “E” to the position “H”. In a further embodiment, the fire-blast treatment is carried out when the second holding device moves from the position “F” to the position “G” or the position “H”. It is, of course, possible that the fire-blasting is carried out only when the second holding device is located at any one, two, or more positions of “A” to “H”, for example, only at the position “F”, or at the positions of “F” and “G”.

[0034] The point burner which carries out the fire-blast treatment is correlated with the second holding device and is located such that the fire-blast treatment can be carried out when the turntable 13 is intermittently stopped, and the point burner may be (but does not need to be) located at each position where the second holding device intermittently stops. In one embodiment, it may be located at limited position(s), for example, one, any combination of two, or more positions “E”, “F”, “G” and “H”.

[0035] As shown in FIG. 3, the first holding device 14 holds a borosilicate glass tube 17 during the glass vessel formation process. While the first holding device 14 holds the glass tube 17 and the second holding device 15 holds a lower open end portion 18 of the glass tube 17 at the positions “A” and “e” as shown in FIG. 2, a burner 20 applies heat at a location between the holding devices 14 and 15 to soften the glass tube 17 and eventually separate the open end portion 18 from a remainder of the glass tube 17 (see the state at the position “A” in FIG. 4). As the burner 20 continues to apply heat to the upper edge of the separated open end portion 18, a bottom portion 21 is formed on the open end portion 18 (see the state at the positons “B” to “E” in FIG. 4) so as to form the glass vessel 11. In this regard, please note that FIGS. 3 & 4 illustrate the glass vessel 11 being formed upside-down so that the opening is towards the bottom and the bottom portion 21 is at the top. It may, of course, be possible to reverse this arrangement as necessary. FIG. 4 also shows the state at the positions “F” to “H” wherein no heat is applied by the burner 20 so that the glass vessel 11 may be cooled.

[0036] In the apparatus 10 shown in FIGS. 2-4, the first and second holding devices 14 and 15 are holding chucks. However, it is also possible for one or more of the holding devices 14, 16 to be comprised of a different component, such as rollers.

[0037] As noted above and shown in FIGS. 3 and 4, a point burner 16 is associated with the second (lower) holding device 15. As the burner 20 applies heat to the glass tube 17 and open end portion 18 for separating the open end portion 18 from the remainder of the glass tube 17 and for subsequently forming the bottom portion 21 on the open end portion 18 to form the glass vessel 11, the second holding device 15 holds the open end portion 18, as explained above. During at least a part of this same time period, the point burner 16 applies a flame to the inside of the open end portion 18 and/or glass vessel 11. The point burner 18 is oriented in such a way as to apply the flame to a region of an inside surface of the open end portion 18 and/or glass vessel 11 where alkali components are being volatilized due to the heat of formation applied by burner 20. Thus, the alkali components (alkali condensate) can be removed before or immediately after being attached to the inside surface so as to prevent formation of a deteriorated region during production of the glass vessel 11.

[0038] There is no particular manner in which the point burner 16 is to be associated with the second holding device 15. This arrangement simply requires that the point burner 16 be configured to apply the flame to the inner surface of the open end portion 18 (glass vessel 11) while the second holding device 15 holds the open end portion 18 (glass vessel 11). Thus, the point burner 16 can be directly or indirectly attached to the second holding device 15, or can be unattached to the second holding device 15 but nonetheless supported, oriented, and arranged in such a way as to apply the flame to the inner surface of the open end portion 18 (glass vessel 11) while the second holding device 15 holds the open end portion 18 (glass vessel 11).

[0039] The process described above is illustrated in the schematic diagram of FIG. 4, which shows the sequence of steps for forming the glass vessel, as described above. In the initial step shown in the image farthest to the left, the first holding device 14 holds the borosilicate glass tube 17. As indicated by the large horizontal arrows, the process proceeds to the next steps shown to the right. Firstly, the second holding device 15 holds the open end portion 18 of the glass tube 17 as the burner 20 applies heat to soften the glass tube 17 and eventually separate the open end portion 18 from the remainder of the glass tube 17 (at the position “A”). Subsequently, the burner 20 applies heat to the upper edge of the separated open end portion 18 to form the bottom portion 21 (at the positions “B” to “E”). It is, of course, also possible that the burner 20 comprises two separate burners, each for performing one of (i) the initial softening and separating of the open end portion 18 from the glass tube 17 and (ii) the formation of the bottom portion 21 (i.e., the same burner 20 does not necessarily perform both the initial softening and separating and the subsequent bottom formation steps “A” to “E”). Thereafter, the formed glass vessel 11 can be left for cooling (at the positions “F” to “H”). At the position “H”, the glass vessel 11 is released from the turntable 13.

[0040] As also indicated in the steps shown in FIG. 4, the point burner 16 applies a flame during at least a part of at least one of these formation steps during which the second holding device 15 holds the open end portion 18. In particular, the point burner 16 applies the flame inside the open end portion 18 (i.e., glass vessel 11) during at least a part of at least one of (i) separation of the open end portion 18 from the remainder of the glass tube 17, (ii) formation of the bottom portion 21 on the open end portion 18 to form the glass vessel 11, and/or (iii) a period after the formation of the bottom portion and prior to release of the open end portion 18 (i.e., glass vessel 11) from the second holding device 15.

[0041] As a result of the process described above and shown in FIG. 4, no subsequent intermediate fire-blast treatment is necessary after formation of the glass vessel 11 and release of the glass vessel 11 from the second holding device 15. Therefore, the glass vessel 11 can be transported directly to a subsequent processing station after release from the second holding device 15. Such subsequent processing station can be an oven for annealing the glass vessel 11. Consequently, the overall time requirement for producing the glass vessel 11 is made shorter, and the production process becomes more efficient.

[0042] The flame applied by the point burner 16 during the fire-blast treatment can be an oxygen-flammable gas flame containing an oxonium ion jetted toward the inner surface of the open end portion. The oxygen-flammable gas flame with the oxonium ion can be mixed gas flame of a flammable gas and oxygen. The alkali components are chipped off by ions and particles contained in the flame from the point burner 16. Therefore, it is preferable that the flame contains more of the ions and particles. It is presumed that such ions and particles are generated as a result of a combustion reaction between the flammable gas such as a low hydrocarbon and oxygen.

[0043] The temperature of a portion of the external (outer) surface of the open end portion which outer surface portion is opposite the portion of the inner surface where volatilization of alkali components occurs (a deteriorated region) due to processing is, for example, between 650° C. and 800° C. The temperature of the external (outer) surface of the open end portion can be measured by a thermometer such as a non-contact thermometer. When a measured temperature of the outer surface is within the specific range of 650° C. to 800° C., the fire-blast treatment proceeds with satisfactory results. On the other hand, a measured temperature outside the specific range means that the fire-blast treatment might not be carried out so appropriately. In that case, conditions of the fire-blast treatment (for example, operation conditions of the burner such as a flow rate of the gas, a time period for the fire-blast treatment, etc.) may be changed so that the measured temperature can be within the specific range.

[0044] The fire-blast treatment should include a region of the inner surface of the open end portion 18 (or glass vessel 11) which is located at a height of from 8% to 16%, preferably 6% to 18%, and more preferably 5% to 30% of the total length of the open end portion 18 (or glass vessel) based on the external dimension of the open end portion 18. In other words, to effectively reduce the amount of alkali elution, the inner surface of the open end portion 18 located 8% to 16%, preferably 6% to 20%, and more preferably 5% to 30%, of the total length of the preform from the bottom of the open end portion 18 (or glass vessel 11 or the preform) should be fire-blast treated. It is possible to fire-blast treat only the above mentioned region. Alternatively, however, it is possible to fire-blast treat a broader area which includes the above specific region. Fire-blast treatment of the region noted above is preferably used for production of a glass vessel having a thickness between 0.8 mm to 2.0 mm, for example between 0.9 mm and 1.5 mm, and especially between 1.0 mm and 1.2 mm.

[0045] Air evacuation by injecting a pressurized gas such as air into the mouth of the glass vessel can also be performed, either before or immediately after the fire-blast treatment. The pressurized gas is then discharged out through a discharge gap between the supply tube and the mouth of the vessel. The pressurized gas can provide support for the bottom portion 21.

[0046] After completion of the formation of the bottom portion 21 and release of the glass vessel 11 from the second holding device 15, the glass vessel 11 can be transported to a subsequent processing station. For example, the glass vessel 11 can be transported to an oven for completion of an annealing process to relieve stresses created during the formation process.

[0047] Although the above-described process and apparatus are applicable to producing a glass vessel for any use, the process and apparatus are particularly applicable to producing a glass vial for medical use.