Ni—Al-RE ternary eutectic alloy and preparation method thereof

Abstract

A Ni—Al-RE ternary eutectic alloy and a preparation method thereof are provided. The alloy is composed of the following elements by weight percent, aluminum (Al) of 2.50% to 19.50%, rare earth (RE) of 1.30% to 20.0%, other impurity elements being less than or equal to 0.10%, and the rest being nickel (Ni). The microstructure of the alloy is in a completely eutectic form, and the density is 6.8 to 7.1 g/cm.sup.3. Raw materials are prepared according to the ratio, and are placed into a vacuum induction smelting furnace; the smelting furnace is vacuumized to 10.sup.−5 Pa, power is increased to ensure complete melting of the raw materials, and the molten alloy melt is poured into an iron mold to obtain alloy ingots. The eutectic phase in the microstructure of the alloy in the disclosure has high hardness.

Claims

1. A method for preparing a Ni—Al-RE ternary eutectic alloy composed of following elements by weight percent: aluminum (Al) of 2.50% to 19.50%, rare earth (RE) of 1.30% to 20.0%, other impurity elements being less than or equal to 0.10%, and the rest being nickel (Ni), comprising: preparing raw materials according to a ratio, placing the raw materials in a vacuum induction smelting furnace, vacuumizing to ensure that a vacuum degree reaches 10− Pa, increasing power to ensure complete melting of the raw materials so as to form a molten alloy melt, pouring the molten alloy melt into an iron mold, and obtaining alloy ingots that are formed of the Ni—Al-RE ternary eutectic alloy in a completely eutectic form.

2. The method according to claim 1, wherein a magnesia crucible is arranged in the vacuum induction smelting furnace, and the raw materials are held in the magnesia crucible.

3. The method according to claim 1, wherein the increasing the power to ensure the complete melting of the raw materials means that increasing the power of a medium-frequency induction furnace and when the aluminum begins melting, stop increasing the power; wherein the whole alloy material is molten through a reaction between the aluminum and the other two raw materials of the RE and the Ni.

4. The method according to claim 1, wherein the pouring the molten alloy melt into the iron mold means that further increasing the power after the raw materials are all molten to ensure good fluidity of the alloy during the pouring; then pouring the alloy melt into the iron mold which is preheated to 150 to 250° C.; and taking out the cast ingots after the alloy melt is cooled, thereby obtaining the ternary alloy.

Description

DETAILED DESCRIPTION OF PREFERRED EMBODIMENTS

(1) The disclosure is further described in detail below in combination with specific embodiments. The following embodiments may help those skilled in the art to further understand the disclosure but do not limit the disclosure in any form. It should be pointed out that several modifications and improvements may be made by those ordinary skilled in the art without departing from the concept of the disclosure. These modifications and improvements belong to the protection scope of the disclosure.

(2) A Ni—Al-RE ternary eutectic alloy provided in the disclosure is composed of the following elements by weight percent, aluminum (Al) is 2.50% to 19.50%, rare earth (RE) is 1.30% to 20.0%, other impurity elements is less than or equal to 0.10%, and the rest is nickel (Ni). Microstructure of the alloy is in a completely eutectic form, and the density is 6.8 to 7.1 g/cm.sup.3. Preferably, the weight percent of the Al is 3.50% to 15.00%; the weight percent of the RE is 4.50% to 10.00%. Alternatively, the weight percent of the Al is 9.50% to 12.50%, and the weight percent of the RE is 4.50% to 8.50%. As long as the components are selected in the above proportion range, the purpose of the disclosure can be realized.

(3) For the design of the alloy, the components of the ternary alloy of a eutectic composition may be designed by adopting OpenCalphad phase diagram calculation software and a known Ni—Al-RE ternary liquidus projection phase diagram. Since the rare-earth elements have similar physical and chemical properties, the Ni—Al-RE ternary alloy designed by the disclosure has universality, RE can be replaced by various rare-earth elements, i.e. the RE may be any one or more of the rare-earth elements.

(4) The Ni—Al-RE ternary eutectic alloy is prepared as follows. The needed raw materials are prepared according to the component ratio, the prepared raw materials are placed in a medium-frequency vacuum induction smelting furnace, and are carried in a magnesia crucible, the pressure is vacuumized to be less than 10.sup.−5 Pa by starting a Roots pump and a diffusion pump, the power of the medium-frequency induction furnace is gradually increased, special attention is paid to the melting situation of the aluminum, when the aluminum begins melting, the power is no longer increased, and the whole alloy material is melt through the reaction between the aluminum and the other two raw materials. After the alloy is all molten, the power is increased again to ensure the fluidity of the alloy during the pouring, then the molten alloy is poured into an iron mold which is preheated to 200° C., and after the alloy melt is cooled, cast ingots are taken out to obtain the ternary alloy.

(5) Alternatively, the Ni—Al-RE ternary eutectic alloy may also be made through the following preparation method. The raw materials are placed into a water cooling copper crucible of a non-consumable vacuum electric arc furnace, a mechanical pump and a molecular pump are successively started to vacuumize the furnace to be less than 10.sup.−5 Pa, then argon is introduced until the relative pressure displayed on a vacuum pressure gauge is −0.03 to −0.06 Pa, a power supply is switched on to enable a tungsten electrode arc gun to strike arc to the alloy material, the current is increased to melt the alloy material, and the alloy material is repeatedly overturned and melt for multiple times, the alloy material is placed in the non-consumable vacuum electric arc furnace to be cooled by the water cooling copper crucible, and then the ternary alloy can be obtained.

(6) The alloy of the disclosure and the preparation method thereof will be further explained below through specific embodiments.

Embodiment 1

(7) Pure aluminum of 99.99% weight percent, pure yttrium of 99.9% weight percent and pure nickel of 99.99% weight percent are selected and placed in a magnesia crucible of a medium-frequency vacuum induction smelting furnace according to the designed components, wherein Al is 5.5% by weight, Y is 4.5% by weight, and the rest is Ni.

(8) A Roots pump and a diffusion pump are successively started to vacuumize the furnace to be less than 10.sup.−5 Pa. The power of the medium-frequency induction furnace is gradually increased, while special attention should be paid to the melting situation of the aluminum, and the increase of the power should be stopped when the aluminum begins melting.

(9) After the alloy is all molten, the power can be increased again, and then the alloy melt is poured into the iron mold which is preheated to 200° C.

(10) After the alloy melt is cooled, the cast ingots can be taken out to obtain the ternary alloy.

(11) Through the observation of an optical microscope and a scanning electron microscope, the microstructure of the alloy is completely eutectic of tiny laminae, and by virtue of Vickers hardness test, the alloy hardness can reach 650 HV.

Embodiment 2

(12) Pure aluminum of 99.99% weight percent, pure yttrium of 99.9% weight percent and pure nickel of 99.99% weight percent are selected and these raw materials are placed in a water cooling copper crucible of a non-consumable vacuum electric arc furnace according to the designed components, wherein Al is 3.5% by weight, Y is 4.5% by weight, and the rest is Ni.

(13) A mechanical pump and a molecular pump are successively started to vacuumize the furnace to be less than 10.sup.−5 Pa. Then argon is introduced until the relative pressure displayed on a vacuum pressure gauge is −0.04 Pa.

(14) A power supply is switched on to enable a tungsten electrode arc gun to strike arc to the raw materials of the alloy, and the current is increased to melt the alloy materials.

(15) The alloy materials are repeatedly overturned and melt for 4 times and then placed in the water cooling copper crucible for cooling, and the ternary alloy can be obtained.

(16) Through the observation of an optical microscope and a scanning electron microscope, the microstructure of the alloy is completely eutectic of tiny laminae, and by virtue of Vickers hardness test, the alloy hardness can reach 620 HV.

Embodiment 3

(17) Pure aluminum of 99.99% weight percent, pure yttrium of 99.9% weight percent and pure nickel of 99.99% weight percent are selected and placed in a magnesia crucible of a medium-frequency vacuum induction smelting furnace according to the designed components, wherein Al is 19.5% by weight, Y is 15% by weight, and the rest is Ni.

(18) A Roots pump and a diffusion pump are successively started to vacuumize the furnace to be less than 10.sup.−5 Pa. The power of the medium-frequency induction furnace is gradually increased, while special attention should be paid to the melting situation of the aluminum, and the increase of the power should be stopped when the aluminum begins melting.

(19) After the alloy is all molten, the power can be increased again, and then the alloy melt is poured into the iron mold which is preheated to 250° C. After the alloy melt is cooled, the cast ingots can be taken out to obtain the ternary alloy.

(20) Through the observation of an optical microscope and a scanning electron microscope, the microstructure of the alloy is completely eutectic of tiny laminae, and by virtue of Vickers hardness test, the alloy hardness can reach 650 HV.

Embodiment 4

(21) Pure aluminum of 99.99% weight percent, pure yttrium of 99.9% weight percent and pure nickel of 99.99% weight percent are selected and placed in a magnesia crucible of a medium-frequency vacuum induction smelting furnace according to the designed components, wherein Al is 2.5% by weight, Y is 1.5% by weight, and the rest is Ni.

(22) A Roots pump and a diffusion pump are successively started to vacuumize the furnace to be less than 10.sup.−5 Pa. The power of the medium-frequency induction furnace is gradually increased, while special attention should be paid to the melting situation of the aluminum, and the increase of the power should be stopped when the aluminum begins melting.

(23) After the alloy is all molten, the power can be increased again, and then the alloy melt is poured into the iron mold which is preheated to 150° C. After the alloy melt is cooled, the cast ingots can be taken out to obtain the ternary alloy.

Embodiment 5

(24) Pure aluminum of 99.99% weight percent, pure cerium of 99.9% weight percent and pure nickel of 99.99% weight percent are selected and placed in a magnesia crucible of a medium-frequency vacuum induction smelting furnace according to the designed components, wherein Al is 12.5% by weight, Ce is 11.5% by weight, and the rest is Ni.

(25) A Roots pump and a diffusion pump are successively started to vacuumize the furnace to be less than 10.sup.−5 Pa. The power of the medium-frequency induction furnace is gradually increased, while special attention should be paid to the melting situation of the aluminum, and the increase of the power should be stopped when the aluminum begins melting.

(26) After the alloy is all molten, the power can be increased again, and then the alloy melt is poured into the iron mold which is preheated to 200° C. After the alloy melt is cooled, the cast ingots can be taken out to obtain the ternary alloy.

(27) Through the observation of an optical microscope and a scanning electron microscope, the microstructure of the alloy is completely eutectic of tiny laminae, and by virtue of Vickers hardness test, the alloy hardness can reach 620 HV.

Embodiment 6

(28) Pure aluminum of 99.99% weight percent, pure lanthanum of 99.9% weight percent and pure nickel of 99.99% weight percent are selected and placed in a magnesia crucible of a medium-frequency vacuum induction smelting furnace according to the designed components, wherein Al is 10.5% by weight, La is 12.5% by weight, and the rest is Ni.

(29) A Roots pump and a diffusion pump are successively started to vacuumize the furnace to be less than 10.sup.−5 Pa. The power of the medium-frequency induction furnace is gradually increased, while special attention should be paid to the melting situation of the aluminum, and the increase of the power should be stopped when the aluminum begins melting.

(30) After the alloy is all molten, the power can be increased again, and then the alloy melt is poured into the iron mold which is preheated to 150° C. After the alloy melt is cooled, the cast ingots can be taken out to obtain the ternary alloy.

Embodiment 7

(31) Pure aluminum of 99.99% weight percent, pure gadolinium of 99.9% weight percent and pure nickel of 99.99% weight percent are selected and placed in a magnesia crucible of a medium-frequency vacuum induction smelting furnace according to the designed components, wherein Al is 9.5% by weight, Gd is 8.5% by weight, and the rest is Ni.

(32) A Roots pump and a diffusion pump are successively started to vacuumize the furnace to be less than 10.sup.−5 Pa. The power of the medium-frequency induction furnace is gradually increased, while special attention should be paid to the melting situation of the aluminum, and the increase of the power should be stopped when the aluminum begins melting.

(33) After the alloy is all molten, the power can be increased again, and then the alloy melt is poured into the iron mold which is preheated to 150° C. After the alloy melt is cooled, the cast ingots can be taken out to obtain the ternary alloy.

Embodiment 8

(34) Pure aluminum of 99.99% weight percent, pure praseodymium of 99.9% weight percent and pure nickel of 99.99% weight percent are selected and placed in a magnesia crucible of a medium-frequency vacuum induction smelting furnace according to the designed components, wherein Al is 9.5% by weight, Pr is 11.5% by weight, and the rest is Ni.

(35) A Roots pump and a diffusion pump are successively started to vacuumize the furnace to be less than 10.sup.−5 Pa. The power of the medium-frequency induction furnace is gradually increased, while special attention should be paid to the melting situation of the aluminum, and the increase of the power should be stopped when the aluminum begins melting.

(36) After the alloy is all molten, the power can be increased again, and then the alloy melt is poured into the iron mold which is preheated to 150° C. After the alloy melt is cooled, the cast ingots can be taken out to obtain the ternary alloy.

(37) The Ni—Al-RE ternary alloy provided in the disclosure has a completely eutectic structure; the eutectic lamina is very tiny; the space between slices is between 0.1 to 0.9 micrometer; for example, the ternary alloy can be applied to other solidification processes; and when a directional solidification process is adopted, the directional alloy with a tiny structure can be developed, so that the mechanical performance of the alloy in a single direction can be further improved. The overall hardness of the Ni—Al-RE ternary alloy material of the disclosure is high and is twice of that of the pure binary Ni—Al alloy. The preparation method is simple and efficient; no secondary feeding is needed; the needed alloy can be obtained by one-step smelting; and the component range is wide, thereby facilitating the industrialized application.

(38) The specific embodiments of the disclosure are described above. It should be understood that the disclosure is not limited to the specific embodiments, and the purpose of the disclosure may be realized by adjusting the component ratio and preparation process of the alloy. Those skilled in the art can make various modifications or changes within the scope of the claims without influencing the substantive content of the disclosure.