Setter for firing, and method for producing honeycomb structure using setter for firing
10969175 · 2021-04-06
Assignee
Inventors
Cpc classification
C04B2235/96
CHEMISTRY; METALLURGY
B28B11/243
PERFORMING OPERATIONS; TRANSPORTING
F01N3/2828
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
C04B2235/963
CHEMISTRY; METALLURGY
B28B2003/203
PERFORMING OPERATIONS; TRANSPORTING
B28B3/20
PERFORMING OPERATIONS; TRANSPORTING
C04B2235/95
CHEMISTRY; METALLURGY
F27D5/0031
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
International classification
F27D5/00
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
C04B38/00
CHEMISTRY; METALLURGY
B28B11/24
PERFORMING OPERATIONS; TRANSPORTING
Abstract
A setter for firing in a plate which is used for firing a honeycomb formed body and interposed between the honeycomb formed body and a shelf plate, wherein the setter for firing has a setter lower surface section facing the shelf plate, the setter lower surface section including: a central region part formed by a region including a lower surface center of the setter lower surface section; and a peripheral region part formed by a peripheral region of the central region part, and the peripheral region part has at least four or more setter groove parts each having a recessed cross sectional shape and extending radially from the lower surface center respectively in a direction from a boundary with the central region part toward a setter outer circumferential section.
Claims
1. A setter for firing in a plate which is used for firing a honeycomb formed body and interposed between the honeycomb formed body and a shelf plate, wherein the setter for firing has a setter lower surface section facing the shelf plate, the setter lower surface section including: a central region part formed by a region including a lower surface center of the setter lower surface section; and a peripheral region part formed by a peripheral region of the central region part, and the peripheral region part has at least four or more setter groove parts each having a recessed cross sectional shape and extending radially from the lower surface center respectively in a direction from a boundary with the central region part toward a setter outer circumferential section without intersecting another setter groove part.
2. The setter for firing according to claim 1, wherein the setter groove parts adjacent to each other are arranged in the peripheral region part with a same radiation angle from the lower surface center, and extend linearly from the boundary toward the setter outer circumferential section.
3. The setter for firing according to claim 1, wherein the central region part is formed in a circular shape and has a diameter in a range of 10 mm to 35 mm.
4. The setter for firing according to claim 1, wherein the setter for firing is formed in an elliptical shape, and the central region part is formed in an elliptical shape similar to that of the setter for firing and has a minor axis in a range of 10 mm to 35 mm.
5. The setter for firing according to claim 1, wherein each of the setter groove parts has a groove width in a range of 0.5 mm to 2.0 mm.
6. The setter for firing according to claim 1, wherein a ratio of a groove area of the setter groove parts to a total area of the setter lower surface section is at least 1.0% or more.
7. The setter for firing according to claim 1, wherein a setter upper surface section opposing the setter lower surface section and having the honeycomb formed body placed thereon includes: a flat part in contact with at least a portion of a formed body end face of the honeycomb formed body; and a raised part in a curved surface shape raised bulgingly from the setter outer circumferential section toward the flat part.
8. A method for producing a honeycomb structure using a setter for firing, the method comprising: a molding step of extruding a honeycomb formed body from a molding material; and a firing step of firing the honeycomb formed body obtained by the molding step, the firing step including a shelf plate arrangement step of arranging a shelf plate in a firing furnace, a setter for firing installation step of installing the setter for firing on the arranged shelf plate with a setter lower surface section facing the shelf plate, the setter for firing including a central region part formed by a region including a lower surface center of the setter lower surface section and a peripheral region part formed by a peripheral region of the central region part, and the peripheral region part having at least four or more setter groove parts formed therein each having a recessed cross sectional shape and extending radially from the lower surface center respectively in a direction from a boundary with the central region part toward a setter outer circumferential section without intersecting another setter groove part, and a honeycomb formed body placement step of placing the honeycomb formed body on the setter for firing with one formed body end face directed downwardly and placing the honeycomb formed body in the firing furnace with the setter for firing interposed between the honeycomb formed body and the shelf plate.
9. The method for producing a honeycomb structure using a setter for firing according to claim 8, wherein the setter for firing installation step uses a sucking-conveying device, and further includes a sucking-conveying step of closely contacting a suction section of the sucking-conveying device to a setter upper surface section of the setter for firing positioned at an uppermost stage of a stacked body in which a plurality of the setters for firing are stacked in multiple stages and conveying the setter for firing in a decompression state between the suction section and the setter upper surface section.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
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DETAILED DESCRIPTION OF THE INVENTION
(11) Hereinafter, Embodiments of a setter for firing and a method for producing a honeycomb structure using the setter for firing of the present invention are described in detail with reference to drawings. Note that, the setter for firing and the method for producing a honeycomb structure of the present invention are not limited to the embodiments below, but can be variously changed, modified, and improved in design within a range not deviating from the scope of the present invention.
(12) A setter for firing 1 of one embodiment of the present invention is, as shown in
(13) To describe more specifically, the setter for firing 1 includes a setter lower surface section 2 that is a surface facing the shelf plate 21 and positioned on a lower side of the setter for firing 1, a setter upper surface section 3 that is opposite to the setter lower surface section 2, at least partially contacts a formed body end face 22 of the honeycomb formed body 20, and is positioned on an upper side of the setter for firing 1, and a setter outer circumferential section 4 that connects respective end parts 2a and 3a of the setter lower surface section 2 and the setter upper surface section 3 and is positioned on a side face side of the setter for firing 1.
(14) When the setter for firing 1 is seen from the bottom side (corresponding to the lower side of the paper surface in
(15) Here, in the setter for firing 1 of the present embodiment, each of the setter groove parts 7 is formed as a groove having a substantially semicircular shape in cross-section (a recessed cross-sectional shape) to a flat region surface 6a of the peripheral region part 6 (setter lower surface section 2). Here, the distance between one end 7a and the other end 7b between the setter groove part 7 having a substantially semicircular shape in cross-section and the region surface 6a corresponds to a groove width W of the setter groove part 7. Note that, the shape of the setter groove part 7 is not limited to the substantially semicircular shape in cross-section, but may be another shape, for example, such as a multangular shape or an elliptical shape.
(16) Further, in a plurality of the linear setter groove parts 7 provided radially in the setter lower surface section 2, an angle between the setter groove parts 7 adjacent to each other (radiation angle θ: refer to
(17) Furthermore, the central region part 5 provided in the setter lower surface section 2 is, in the case of the setter for firing 1 of the present embodiment, configured in the circular shape, and at this time the diameter of the central region part 5 is set in a range of 10 mm to 35 mm. That is, the lower limit and the upper limit of a region size (area) of the central region part 5 are set.
(18) Here, if the diameter of the central region part 5 is smaller than 10 mm, center side ends 7c of the plurality of setter groove parts 7 are concentrated to the lower surface center C. To avoid such a state, the diameter is prescribed to be at least 10 mm or more. On the other hand, if the diameter of the central region part 5 exceeds 35 mm, the ratio of the central region part 5 in the setter lower surface section 2 is high. Consequently, the effect of the present invention (to be described below in detail) obtained by the setter groove parts 7 of the peripheral region part 6 cannot be sufficiently expected. Therefore, the range of the diameter of the central region part 5 is prescribed as described above.
(19) Note that, in a case where the setter for firing of the present invention is, for example, configured in an elliptical shape, the central region part may also be configured in an elliptical shape similar to the shape of the setter for firing. In this case also, by the same reason as above, to avoid concentration in the center side ends 7c of the plurality of setter groove parts 7, the minor axis of the elliptical shape is set to be at least 10 mm or more. Note that, even if the setter for firing has, as described above, an elliptical shape, the shape of the central region part does not necessarily have to be elliptical, but may be circular. Further, the shape of the central region part does not necessarily have to be limited to a circular shape or an elliptical shape, but may be other multangular shape.
(20) In addition, the groove width W of the setter groove part 7 is in a range of 0.5 mm to 2.0 mm. In the case of the setter groove part 7 of the present embodiment, the height from the region surface 6a of the peripheral region part 6 to the deepest portion 7d of the setter groove part 7 is not more than ½ of the groove width W. If the groove width W is smaller than 0.5 mm, in a case of a stacked body 8 in which the setters for firing 1 are stacked in multiple stages, a gap is hard to be generated between a setter for firing 1a at an upper stage position and a setter for firing 1b at a lower stage position, and similar to the conventional setter for firing 100 (refer to
(21) Thus, the groove width W needs to be at least 0.5 mm or more. In addition, if the groove width W is not more than 2.0 mm, a sufficient gap is formed between the setters for firing 1a and 1b at the upper and lower stages, and thus further expansion of the groove width W is not necessary. Therefore, the groove width W of the setter groove part 7 is prescribed in the above-described range of 0.5 mm to 2.0 mm.
(22) Meanwhile, in the setter for firing 1 of the present embodiment, the ratio of the groove area (groove area ratio) of the setter groove part 7 in the total area of the setter lower surface section 2 is set to be at least 1.0% or more. Here, the total area of the setter lower surface section 2 indicates a total of the area of the central region part 5, the area of the peripheral region part 6 excluding the setter groove part 7, and the area of a portion opened to the exterior of the setter groove part 7.
(23) Note that, since the setter for firing 1 of the present embodiment is circular, the total area of the setter lower surface section 2 can be calculated based on the diameter of the setter for firing 1 (=(diameter/2).sup.2×π). Meanwhile, the groove area in the case of the setter for firing 1 of the present embodiment is calculated by further multiplying the area of a rectangular region, which is obtained by multiplying the groove width W by a groove length L of the setter groove part 7 extending from the boundary B to the setter outer circumferential section 4, by six that is the number of the setter groove parts 7 (refer to
(24) Note that, in a case where the above calculation method cannot be employed for the setter for firing of the present invention, for example, in a case where the setter for firing is formed by other than the above-described circular shape, the groove area ratio may be calculated by another method. For example, image analysis processing is performed on a captured image obtained by imaging the setter lower surface section 2 to discriminate the region of the setter groove part from the other regions, and the groove area ratio may be obtained.
(25) Further, the setter upper surface section 3 of the setter for firing 1 of the present embodiment, which opposes the setter lower surface section 2 and has the honeycomb formed body 20 placed thereon, includes a flat part 11 in a flat shape in contact with at least a portion of the formed body end face 22 of the honeycomb formed body 20 and a raised part 12 in a curved surface shape raised bulgingly from the upper end (corresponding to an end portion 3a of the setter upper surface section 3) of the setter outer circumferential section 4 toward a flat part edge 11a of the flat part 11. That is, when the setter for firing 1 of the present embodiment is seen from a side, the setter lower surface section 2 is formed in a flat shape so as to contact the shelf plate 21, and a portion of the setter lower surface section 2 is molded into a semicircular shape in cross-section. Meanwhile, the setter upper surface section 3 is raised upward as a whole, and only the vicinity of the center is formed by the flat part 11.
(26) Note that, not limited particularly, but for example, the central region part 5 of the setter lower surface section 2 may have the same area as the flat part 11 of the setter upper surface section 3, or the flat part 11 may be formed with a larger area than the central region part 5. Further, the shape of the flat part 11 is not limited to a circular shape, but may be a shape allowing stable placement of the honeycomb formed body 20.
(27) Since the setter upper surface section 3 includes the flat part 11, the honeycomb formed body 20 can be placed stably, and further since only a portion of the formed body end face 22 contacts the setter upper surface section 3, the possibility of constraining firing shrinkage at the time of firing becomes low. Consequently, in a case where firing is performed by using the setter for firing 1 of the present embodiment, it is possible to stabilize product quality without causing cell deformation or partition wall cutting in the honeycomb structure after firing (not shown),
(28) Further, when the setter for firing 1 is stored in the storage case or the like, the stacked body 8 in which a plurality of setters for firing 1 are stacked in multiple stages is constructed (refer to
(29) As described above, the setter for firing 1 of the present embodiment includes a plurality of setter groove parts 7 in the peripheral region part 6 of the setter lower surface section 2. Consequently, even in a case of conveying, from the stacked body 8 (refer to
(30) That is, a passage where air flows is formed between the setter for firing 1a at the upper stage side and the setter for firing 1b at the lower stage side via the setter groove part 7. As a result, the above-described suction state by the setters for firing 1a and 1b at the upper and lower stages is avoided. Note that, at a phase where the setter for firing 1a positioned at the uppermost stage is conveyed, the setter for firing 1b at the lower stage side turns into a setter for firing 1a at the uppermost stage in the stacked body 8. Conveyance of the setter for firing 1a at the uppermost stage in the stacked body 8 by the sucking-conveying device 9 is repeated, and the conveying work is continued until there is no setter for firing 1 in the stacked body 8. Note that, in a case where the setters for firing 1 placed on the shelf plate are recovered to form the stacked body 8, an inverse operation to the above processing is performed.
(31) Particularly, since the groove width W of the setter groove part 7 is set in the range of 0.5 mm to 2.0 mm, the passage where air flows is sufficiently formed, and it becomes possible to selectively lift only the setter for firing 1a at the uppermost stage by the suction section 10 of the sucking-conveying device 9. Further, to sufficiently secure the passage where air flows, the groove area ratio of the groove area of the setter groove part 7 to the total area of the setter lower surface section 2 is set to at least 1.0% or more. If the groove area ratio of the setter groove part 7 is lower than 1.0%, the passage where air flows is not sufficient, the two setters for firing 1a and 1b closely contact with each other to enter the suction state and there is a possibility that they are lifted by the suction section 10. Therefore, the groove area ratio is prescribed in the above range.
(32) The setter for firing 1 of the present embodiment is, as described above, formed of a ceramic material. The material is not particularly limited, and, for example, may use various materials that have been conventionally used as basis materials of the setter for firing. For example, it is possible to use materials that are converted into mullite, cordierite, silicon carbide, alumina, or the like by being fired at high temperatures.
(33) In addition, the method for forming the setter for firing 1 is not particularly limited. For example, after forming a general disk-shaped setter for firing, it is possible to grind the setter upper surface section 3 so as to have the flat part 11 and the raised part 12 and to further provide a plurality of the setter groove parts 7 in the setter lower surface sections 2, respectively, by grinding work. However, since a large number of setters for firing are used in the firing step, performing the cutting work on each of the setters for firing may lead to complication of production process and rising of production cost of the setter for firing.
(34) Thus, for example, the method may use a molding die for press work formed according to a shape of the setter for firing, fill the molding die with ceramic materials serving as raw materials, and form the setter formed body by applying desired press pressure thereto. The setter for firing can be produced by applying the press pressure and then firing the setter formed body taken out from the molding die. This makes it possible to manufacture press setters made of ceramics in large amount and to use the press setters as the setters for firing of the present invention.
(35) The setter for firing and the method for producing a honeycomb structure of the present invention will be described below based on examples described below, but the setter for firing and the method for producing a honeycomb structure of the present invention are not limited to the examples.
EXAMPLES
(36) (1) Production of a Setter for Firing
(37) Setters for firing in which shapes of the setters for firing, the numbers of the setter grooves, radiation angles θ, diameters (center diameters) of the central region parts, and groove area ratios are different from each other were produced (Examples 1 to 9). In addition, setters for firing the conditions of which are deviated from those prescribed for the setter for firing of the present invention were further produced (Comparative Examples 1 to 6). The other characteristics of the setters for firing other than the above parameters are the same, and each of the setters for firing is composed of mullite having a bulk specific gravity of about 2.1 g/cm.sup.3, a porosity of about 27%, a bend strength of 5 MPa or more, and a surface roughness Ra of 10 μm or less, has a diameter of 115 mm (in the case of an elliptical shape, a minor axis of 115 mm, a major axis of 135 mm), and has a flat part and a raised part in the setter upper surface section. In addition, the setter for firing is a press-molded porous press setter and fired at a firing temperature of 1400 to 1500° C.
(38) (2) Setters for Firing of Examples and Comparative Examples
(39) In the setters for firing of Examples 1 to 9, based on the setter for firing of Example 3 which has six grooves, the radiation angle θ of 60°, the center diameter of 25 mm, and the groove width of 2 mm, that of Example 1 has four grooves and the radiation angle θ of 90°, that of Example 2 has five grooves and the radiation angle θ of 72°, and that of Example 4 has eight grooves and the radiation angle θ of 45°. That is, in Examples 1 and 2 and Example 4, the numbers of grooves and the radiation angles θ were respectively changed from Example 3.
(40) Meanwhile, each of the setters for firing of Examples 5 and 8 has an elliptical shape, that of Example 5 has the elliptical central region part with the minor axis of 25 mm, and that of Example 8 has the circular central region part with the center diameter of 25 mm. In addition, based on the setter for firing of Example 3, in Example 6, the diameter (center diameter) of the central region part was changed to 10 mm, and in Example 7, the center diameter was changed to 35 mm, respectively from Example 3. Further, in Example 9, the groove width W was set to 0.5 mm.
(41) In contrast to this, in a setter for firing of Comparative Example 1, one setter groove part having a groove width W of 2 mm was arranged in a diameter direction, in Comparative Example 2, similar one pair of setter groove parts was arranged in parallel, and in Comparative Example 3, four setter groove parts were arranged in a lattice shape. That is, they are deviated from the conditions of the setter for firing of the present invention that the setter groove parts are arranged radially.
(42) Further, in Comparative Example 4, six setter groove parts were arranged radially, but they crossed one another at the lower surface center of the setter lower surface section. That is, the central region part does not exist (center diameter=0 mm) In addition, in Comparative Example 5, the groove width W of the setter groove part is 0.3 mm, and in Comparative Example 6, the groove width W of the setter groove part is 5 mm Summaries of detail specifications, such as shapes of the setters for firing, of Examples 1 to 9 and Comparative Examples 1 to 5 are shown in
(43) (3) Evaluation of Setters for Firing
(44) By use of the above-described setters for firing, there were evaluated product qualities, such as whether or not suction of the setters for firing at the upper stage side and the lower stage side has occurred by the suction section of the sucking-conveying device, shape change of the setter for firing after actual firing of the honeycomb formed body, and whether or not there were cell deformation and partition wall cutting in the fired honeycomb structure.
(45) (4) Evaluation Criteria (Suction)
(46) Note that, about evaluation of suction of the setters for firing, a case where suction between the setters for firing at the upper stage side and the lower stage side did not occur was evaluated as “A”, a case where the setter for firing at the lower stage side was lifted slightly was evaluated as “B”, and a case of suction state where the setters for firing at the upper and lower stage sides were overlappingly lifted was evaluated as “C”. At this time, a suction pressure of the sucking-conveying device was set to 19 kPa.
(47) (5) Evaluation Criteria (Shape Change after Firing)
(48) The firing step of firing the honeycomb formed body, which is one step in the method for producing the honeycomb structure, by actually using the setter for firing was performed and the shape change of the setter for firing was checked. Note that, the honeycomb formed body to be fired used the one obtained by extruding molding materials (kneaded materials) adjusted to a predetermined compounding ratio by using a well-known extruder (molding step). The firing step includes a shelf arrangement step of arranging the shelf plate in a firing furnace, a setter for firing installation step of installing the setter for firing produced as described above on the shelf plate, and a honeycomb formed body placement step of placing the honeycomb formed body further on the setter for firing with one formed body end face directed downwardly. Thus, a state was set where the setter for firing was interposed between the honeycomb formed body and the shelf plate. In such a state, the honeycomb formed body was thrown into the firing furnace and fired. Thus, production of the honeycomb structure was completed (the method for producing a honeycomb structure of the present invention). Here, the firing step under the same condition was repeatedly performed on one setter for firing, and the setter for firing that was fired 10 times and had warpage of 0.5 mm or less was evaluated as “A”, the one that was fired 6 to 9 times and had warpage of 0.5 mm or less was evaluated as “B”, and the one that was fired 5 times or less and had warpage of 0.6 mm or more was evaluated as “C”.
(49) (6) Evaluation Criteria (Product Quality)
(50) The fired honeycomb structure having no cell deformations or partition wall cuttings and having good product quality was evaluated as “A”, the one having not more than four cell deformations and partition wall cuttings was evaluated as “B”, and the one having more than five cell deformations and partition wall cuttings was evaluated as “C”.
(51) (7) Evaluation Results
(52) The evaluation results on respective evaluation criteria of above (4) to (6) are shown in
(53) Further, even in a case where four or more setter groove parts were arranged radially, when the setter lower surface section did not include the central region part (Comparative Example 4), the shape change of the setter for firing after firing and the product quality of the honeycomb structure were evaluated as “C”. That is, in the setter for firing of the present invention, it was shown that the central region part having no setter groove part formed in the setter lower surface section was an indispensable configuration.
(54) Further, in a case where the groove width W of the setter groove part was as small as 0.3 mm and the groove area ratio was 0.8% (Comparative Example 5), since the passage of air was not sufficiently formed, the suction occurred between the setters for firing at the upper and lower stages, and thus it was evaluated as “C”. In contrast to this, in a case where the groove width W of the setter groove part was 0.5 mm and the groove area ratio was 1.3% (Example 9), the above suction was not confirmed at all, and thus it was evaluated as “A”. That is, it was shown that the setter groove part needs to be formed with the groove width W of 0.5 mm or more and the groove area ratio of 1.0% or more.
(55) In contrast to this, in a case where the groove width W is 5 mm (Comparative Example 6), the suction did not occur but the product quality of the honeycomb structure degraded, and it was evaluated as “C”. Therefore, the groove width W needs to be set in a proper range.
(56) In addition, the setters for firing of Examples 1 to 9 were evaluated as at least “B” or higher in any of the evaluation criteria. Note that, from the evaluation result of Example 1, the number of grooves is more preferably five or more, and from the evaluation result of Example 7, it was confirmed that the center diameter was more preferably smaller than 35 mm. Further, it was confirmed that the shape of the setter for firing was not limited to a circular shape and even an elliptical shape (Examples 5 and 8) showed the same effect. As described above, using the setter for firing of the present invention makes it possible to produce the honeycomb structure in a stable condition.
INDUSTRIAL APPLICABILITY
(57) The setter for firing of the present invention can be particularly effectively used in the firing step that is one step of the method for producing a honeycomb structure for producing a ceramic honeycomb structure to be used, for example, as catalyst carriers for purifying automobile exhaust gas. Furthermore, the method for producing the honeycomb structure using the setter for firing makes it possible to stably produce the honeycomb structure from the honeycomb formed body.
DESCRIPTION OF REFERENCE NUMERALS
(58) 1, 1a, 1b, 100, 100a, 100b: setter for firing, 2: setter lower surface section, 2a, 3a: end part, 3, 103: setter upper surface section, 4: setter outer circumferential section, 5: central region part, 6: peripheral region part, 6a: region surface, 7: setter groove part, 7a: one end, 7b: the other end, 7c: center side end, 7d: deepest portion, 8, 104: stacked body, 9, 101: sucking-conveying device, 10, 102: suction section, 11: flat part, 11a: flat part edge, 12: raised part, 20: honeycomb formed body, 21: shelf plate, 22: formed body end face, B: boundary, C: lower surface center, W: groove width, θ: radiation angle