USE OF A NICKEL-CHROMIUM-IRON-ALUMINUM ALLOY

Abstract

A nickel-chromium-aluminum alloy as powder is used for additive manufacturing, wherein the powder consists of spherical particles of a size of 5 to 250 pm, and wherein this alloy consists of (in % by weight) 24 to 33% chromium, 1.8 to 4.0% aluminum, 0.10 to 7.0% iron, 0.001 to 0.50% silicon, 0.005 to 2.0% manganese, 0.00 to 0.60% titanium, 0.0 to 0.05% magnesium and/or calcium respectively, 0.005 to 0.12% carbon, 0.001 to 0.050% nitrogen, 0.00001-0.100% oxygen, 0.001 to 0.030% phosphorus, a maximum of 0.010% sulfur, a maximum of 2.0% molybdenum, a maximum of 2.0% tungsten, the remainder nickel and the usual process-related impurities, wherein, with a pore size >1 pm, the powder has total inclusions of 0.0-4% of the pore surface area.

Claims

1. A powder for additive fabrication comprising a nickel-chromium alloy, wherein the powder comprises spherical particles having a size of 5 to 250 μm, and wherein the alloy comprises (in wt %) 24 to 33% chromium, 1.8 to 4.0% aluminum, 0.10 to 7.0% iron, 0.001 to 0.50% silicon, 0.005 to 2.0% manganese, 0.00 to 0.60% titanium, respectively 0.0 to 0.05% magnesium and/or calcium, 0.005 to 0.12% carbon, 0.001 to 0.050% nitrogen, 0.00001-0.100% oxygen, 0.001 to 0.030% phosphorus, max. 0.010% sulfur, max. 2.0% molybdenum, max. 2.0% tungsten, the rest nickel and the usual process-related impurities, wherein the powder has total inclusions of 0.04% pore area for a pore size >1 μm.

2. The powder according to claim 1, wherein the powder was manufactured by means of a vacuum inert-gas atomization system (VIGA).

3. The powder according to claim 1, with a chromium content of 24 to <32%.

4. The powder according to claim 1, with an yttrium content of 0.0 to 0.20%

5. The powder according to claim 1, with a lanthanum content of 0.0 to 0.20%

6. The powder according to claim 1, with a cerium content of 0.0 to 0.20%

7. The powder according to claim 1, with a niobium content of 0.0 to 1.1%.

8. The powder according to claim 1, with a zirconium content of 0.0 to 0.20%.

9. The powder according to claim 1, with a boron content of 0.0001 to 0.008%.

10. The powder according to claim 1, further containing 0.0 to 5.0% cobalt.

11. The powder according to claim 1, further containing at most 0.5% copper.

12. The powder according to claim 1, wherein the impurities are adjusted in contents of at most 0.002% Pb, at most 0.002% Zn, at most 0.002% Sn.

13. The powder according to claim 1, wherein the particles have a size of 5-150 μm, especially 10-150 μm.

14. The powder according to claim 1, wherein the powder has a bulk density of 2 up to the density of the alloy of at most 8 g/cm.sup.3.

15. The powder according to claim 1, wherein the following relationship must be fulfilled:
Fp≤39.9 with  (3a)
Fp=Cr+0.272*Fe+2.36*Al+2.22*Si+2.48*Ti+0.374*Mo+0.538*W−11.8*C  (4a) wherein Cr, Fe, Al, Si, Ti, Mo, W and C are the concentrations of the elements in question in mass %.

16. A composition of matter generated by additive fabrication using the powder according to claim 1 comprising a component, a structural part, a layer on a component, or a layer on a structural part.

17. The composition of matter according to claim 16, wherein the component, the structural part, the layer on the component, or the layer on the structural part is configured for use in the petrochemical industry.

18. A furnace constructed using the powder according to claim 1.

Description

EXAMPLES

[0262] Manufacture:

[0263] For observation of the properties of the structural parts and components manufactured from the powder, alloys melted on the laboratory scale in a vacuum furnace are used.

[0264] Tables 3a and 3b show the analyses of the batches melted on the laboratory scale together with some batches of Alloy 602CA (N06025), Alloy 690 (N06690), Alloy 601 (N06601) melted on the industrial scale according to the prior art and used for comparison. The batches according to the prior art are identified with a T and those according to the invention with an E. The batches marked on the laboratory scale are marked with an L, the batches melted on the industrial scale with a G.

[0265] The ingots of the alloys in Table 3a and b, melted on the laboratory scale in vacuum, were annealed between 900° C. and 1270° C. for 8 hours and hot-rolled to a final thickness of 13 mm and 6 mm by means of hot rolling and further intermediate annealings between 900° C. and 1270° C. for 0.1 to 1 hours. The sheets produced in this way were solution-annealed between 900° C. and 1270° C. for 1 hour. The specimens needed for the measurements were manufactured from these sheets.

[0266] For the alloys melted on the industrial scale, a sample was taken from the industrial-scale fabrication of a commercially fabricated sheet having appropriate thickness. The specimens needed for the measurements were manufactured from these sheets.

[0267] All alloy variants typically had a grain size of 70 to 300 μm.

[0268] For the exemplary batches in Table 3a and b, the following properties were compared: [0269] Metal dusting resistance as an example of high corrosion resistance in a highly corrosive atmosphere [0270] Phase stability [0271] Formability on the basis of the tension test at room temperature [0272] The high-temperature strength/creep strength by means of hot tension tests [0273] The corrosion resistance by means of an oxidation test

[0274] For the batches 2297 to 2308 and 250060 to 250149 melted on the laboratory scale, but in particular for the batches according to the invention marked with E (2301, 250129, 250132, 250133, 250 134, 250137, 240138, 250147, 250148), formula (2a) Al+Cr 28 is fulfilled. Thus they fulfill the requirement that was imposed on the metal dusting resistance.

[0275] For the chosen alloys according to the prior art in Table 2 and for all laboratory batches (Tables 3a and 3b), the phase diagrams were therefore calculated and the temperature of formation T.sub.s BCC was entered in Tables 2 and 3a. For the compositions in Tables 2 and 3a and b, the value for Fp was also calculated according to formula 4a. Fp is all the more greater the higher the temperature of formation T.sub.s BCC is. All examples of N06693 with a higher temperature of formation T.sub.s E.sub.BCC higher than that of Alloy 10 have an Fp>39.9. The requirement Fp≤39.9 (formula 3a) is therefore a good criterion for achieving an adequate phase stability for an alloy. All laboratory batches in Tables 3a and b fulfill the criterion Fp≤39.9.

[0276] Offset yield strength R.sub.p.02, the tensile strength R.sub.m and the elongation As for room temperature (RT) and for 600° C. are entered in Table 4, as is further the tensile strength R.sub.m for 800° C. Moreover, the values for Fa and Fk are entered.

[0277] In Table 4, the exemplary batches 156817 and 160483 of the alloy according to the prior art, Alloy 602 CA, have a relatively small elongation A5 at room temperature of 36 and 42% respectively, which lie below the requirements for a good formability. Fa is greater that 60 and thus above the range that characterizes a good workability. All alloys according to the invention (E) exhibit an elongation greater than 50%. Thus they fulfill the requirements. Fa is smaller than 60 for all alloys according to the invention. Thus they lie in the range of a good formability. The elongation is particularly high when Fa is relatively small.

[0278] The exemplary batch 156658 of the alloy according to the prior art, Alloy 601 in Table 4, is an example of the minimum requirements of offset yield strength and tensile strength at 600° C. and 800° C.; in contrast, the exemplary batches 156817 and 160483 of the alloy according to the prior art, Alloy 602 CA, are examples of very good values of offset yield strength and tensile strength at 600° C. and 800° C. Alloy 601 represents a material that exhibits the minimum requirements of high-temperature strength and creep strength that are described in relationships 9a to 9d, Alloy 602 CA a material that exhibits an outstanding high-temperature strength and creep strength that are described in relationships 10a to 10d. For both alloys, the value for Fk is much larger than 45 and for Alloy 602 CA it is additionally even much higher than the value of Alloy 601, which reflects the elevated strength values of Alloy 602 CA. The alloys according to the invention (E) all exhibit an offset yield strength and tensile strength at 600° C. and 800° C. in the range of or clearly above that of Alloy 601, and therefore have fulfilled the relationships 9a to 9d. They lie in the range of the values of Alloy 602 CA and also fulfill the desirable requirements, i.e. 3 of the 4 relationships 10a to 10d. Fk also is larger than 45 for all alloys according to the invention in the examples in Table 4, in fact even larger than 54 in most cases and thus in the range that is characterized by a good high-temperature strength and creep strength. Among the laboratory batches that are not according to the invention, batches 2297 and 2300 are an example that does not fulfill relationships 9a to 9d and also has an Fk smaller than 45.

[0279] Table 5 shows the specific changes in mass after an oxidation test at 1100° C. in air after 11 cycles of 96 hours, i.e. in total 1056 hours. In Table 5, the specific gross change in mass, the specific net change in mass and specific change in mass of the spalled oxides after 1056 hours are indicated. The exemplary batches of the alloys according to the prior art, Alloy 601 and Alloy 690, exhibited a much higher gross change in mass than Alloy 602 CA, wherein that of Alloy 601 is in turn much larger than that of Alloy 690. Both form a chromium oxide layer that grows more rapidly than an aluminum oxide layer. Alloy 601 still contains approximately 1.3% Al. This content is too small in order to already form an even only partly closed aluminum oxide layer, for which reason the aluminum in the interior of the metallic material is oxidized underneath the oxide layer (internal oxidation), which results in a greater increase in mass in comparison with Alloy 690. Alloy 602 CA contains approximately 2.3% aluminum. For this alloy, therefore, an at least partly closed aluminum oxide layer is able to form underneath the chromium oxide layer. This reduces the growth of the oxide layer markedly and thus also the specific increase in mass. All alloys according to the invention (E) contain at least 2% aluminum and therefore have a similarly small or smaller gross increase in mass than Alloy 602 CA. Also, all alloys according to the invention exhibit spalling in the range of the measurement accuracy, similarly to the exemplary batches of Alloy 602 CA, whereas Alloy 601 and Alloy 690 exhibit greater spalling.

[0280] The claimed limits for the use of the alloy “E” according to the invention as powder for the additive fabrication can therefore be justified in detail as follows:

[0281] A too small particle size below 5 μm impairs the flow behavior and is therefore to be avoided; a too large particle size above 250 μm impairs the behavior during additive fabrication.

[0282] A too low bulk density of 2 g/cm.sup.2 impairs the behavior during additive fabrication. The greatest possible bulk density of approximately 8 g/cm.sup.3 is imposed by the density of the alloy.

[0283] Too low Cr contents mean that the Cr concentration during use of the alloy in a corrosive atmosphere decreases very rapidly below the critical limit, and so a closed chromium oxide can no longer be formed. Therefore 24% Cr is the lower limit for chromium. Too high Cr contents worsen the phase stability of the alloy, especially at the high aluminum contents of 1.8%. Therefore 33% Cr is to be regarded as the upper limit.

[0284] The formation of an aluminum oxide layer underneath the chromium oxide layer reduces the oxidation rate. Below 1.8% Al, the aluminum oxide layer is too incomplete to develop its effect fully. Too high Al contents impair the processability of the alloy. Therefore an Al content of 4.0% forms the upper limit.

[0285] The costs for the alloy increase with the reduction of the iron content. Below 0.1%, the costs rise disproportionally, since special primary material must be used. For cost reasons, therefore, 0.1% Fe is to be regarded as the lower limit. With increase of the iron content, the phase stability is reduced (formation of embrittling phases), especially at high chromium and aluminum contents. Therefore 7% Fe is a practical upper limit in order to ensure the phase stability of the alloy according to the invention.

[0286] Si is needed for the manufacture of the alloy. A minimum content of 0.001% is therefore necessary. Too high contents in turn impair the processability and the phase stability, especially at high aluminum and chromium contents. The Si content is therefore restricted to 0.50%.

[0287] A minimum content of 0.005% Mn is necessary for improvement of the processability. Manganese is limited to 2.0%, since this element reduces the oxidation resistance.

[0288] Titanium increases the high-temperature stability. At 0.60% and above, the oxidation behavior may be impaired, which is why 0.60% is the maximum value.

[0289] Even very low Mg contents and/or Ca contents improve the processing by the binding of sulfur, whereby the occurrence of low-melting NiS eutectics is avoided. For Mg and Ca, therefore, a minimum content of 0.0002% is necessary. At too high contents, intermetallic Ni—Mg phases or Ni—Ca phases may occur, which again greatly worsen the processability. The Mg content and/or Ca content is therefore limited to at most 0.05%.

[0290] A minimum content of 0.005% C is necessary for a good creep strength. C is limited to at most 0.12%, since above such a content this element reduces the processability by the excessive formation of primary carbides.

[0291] A minimum content of 0.001% N is necessary, whereby the processability of the material is improved. N is limited to at most 0.05%, since this element reduces the processability by the formation of coarse carbonitrides.

[0292] The oxygen content must be smaller than or equal to 0.100%, in order to ensure the manufacturability and usability of the alloy. A too low oxygen content increases the costs. The oxygen content is therefore 0.0001%.

[0293] The content of phosphorus should be smaller than or equal to 0.030%, since this surface-active element impairs the oxidation resistance. A too low P content increases the costs. The P content is therefore 0.001%.

[0294] The content of sulfur should be adjusted as low as possible, since this surface-active element impairs the oxidation resistance. Therefore at most 0.010% S is specified.

[0295] Molybdenum is limited to at most 2.0%, since this element reduces the oxidation resistance.

[0296] Tungsten is limited to at most 2.0%, since this element likewise reduces the oxidation resistance.

[0297] For highly corrosive conditions, but especially for a good metal dusting resistance, it is advantageous if the following relationship between Cr and Al is fulfilled:

Cr+Al≥28  (2a)

wherein Cr and Al are the concentrations of the elements in question in mass %. Only then is the content of oxide-forming elements high enough to ensure an adequate metal dusting resistance.

[0298] Beyond this, the following relationship must be fulfilled in order that adequate phase stability is assured:

Fp≤39.9 with  (3a)

Fp=Cr+0.272*Fe+2.36*Al+2.22*Si+2.48*Ti+0.374*Mo+0.538*W−11.8*C  (4a)

wherein Cr, Fe, Al, Si, Ti, Mo, W and C are the concentrations of the elements in question in mass %. The limits for Fp and the possible incorporation of further elements have been justified in detail in the foregoing text.

[0299] If necessary, the oxidation resistance may be further improved with additions of oxygen-affine elements. They accomplish this by being incorporated in the oxide layer, where they block the paths of diffusion of oxygen to the grain boundaries.

[0300] A minimum content of 0.01% Y is necessary to obtain the effect of the Y that increases the oxidation resistance. For cost reasons, the upper limit is set to 0.20%.

[0301] A minimum content of 0.001% La is necessary to obtain the effect of the La that increases the oxidation resistance. For cost reasons, the upper limit is set to 0.20%.

[0302] A minimum content of 0.001% Ce is necessary to obtain the effect of the Ce that increases the oxidation resistance. For cost reasons, the upper limit is set to 0.20%.

[0303] A minimum content of 0.001% Ce mixed metal is necessary to obtain the effect of the Ce mixed metal that increases the oxidation resistance. For cost reasons, the upper limit is set to 0.20%.

[0304] If necessary, Nb may be added, since niobium also increases the high-temperature strength. Higher contents very greatly increase the costs. The upper limit is therefore set at 1.10%.

[0305] If necessary, the alloy may also contain tantalum, since tantalum also increases the high-temperature strength. Higher contents very greatly increase the costs. The upper limit is therefore set at 0.60%. A minimum content of 0.001% is necessary in order to achieve an effect.

[0306] If necessary, the alloy may also contain Zr. A minimum content of 0.01% Zr is necessary to obtain the effect of Zr that increases the high-temperature strength and the oxidation resistance. For cost reasons, the upper limit is set to 0.20% Zr.

[0307] If necessary, Zr may replaced completely or partly by Hf, since this element also, just as Zr, increases the high-temperature strength and the oxidation resistance. The replacement is possible at contents of and above 0.001%. For cost reasons, the upper limit is set to 0.20% Hf.

[0308] If necessary, boron may be added to the alloy, since boron improves the creep strength. Therefore a content of at least 0.0001% should be present. At the same time, this surface-active element worsens the oxidation resistance. Therefore at most 0.008% boron is specified.

[0309] Cobalt up to 5.0% may be contained in this alloy. Higher contents markedly reduce the oxidation resistance.

[0310] Copper is limited to at most 0.5%, since this element reduces the oxidation resistance.

[0311] Vanadium is limited to at most 0.5%, since this element reduces the oxidation resistance.

[0312] Pb is limited to at most 0.002%, since this element reduces the oxidation resistance. The same is true for Zn and Sn.

[0313] Furthermore, optionally the following relationship may be fulfilled for the carbide-forming elements Cr, Ti and C, which describes a particularly good processability:

Fa≤60 with  (5a)

Fa=Cr+20.4*Ti+201*C  (6a)

wherein Cr, Ti and C are the concentrations of the elements in question in mass %. The limits for Fa and the possible incorporation of further elements have been justified in detail in the foregoing text.

[0314] Furthermore, optionally the following relationship between the elements that increase the strength may be fulfilled, which describes a particularly good high-temperature strength and creep strength:

Fk≥45 with  (7a)

Fk=Cr+19*Ti+10.2*Al+12.5*Si+98*C  (8a)

wherein Cr, Ti, Al, Si and C are the concentrations of the elements in question in mass %. The limits for Fa and the possible incorporation of further elements have been justified in detail in the foregoing text.

DESCRIPTION OF THE FIGURES

[0315] FIG. 1 Metal loss due to metal dusting as a function of the aluminum and chromium content in a strongly carburizing gas containing 37% CO, 9% H.sub.2O, 7% CO.sub.2, 46% H.sub.2, which has a.sub.c=163 and p(O.sub.2)=2.5.Math.10.sup.−27. (from (Hermse, C. G. M. and van Wortei, J. C.: Metal dusting: relationship between alloy composition and degradation rate. Corrosion Engineering, Science and Technology 44 (2009), p. 182-185)

[0316] FIG. 2 Quantitative proportions of the phases in thermodynamic equilibrium in dependence on the temperature of alloy 690 (N06690) on the example of the typical batch 111389

[0317] FIG. 3 Quantitative proportions of the phases in thermodynamic equilibrium in dependence on the temperature of alloy 693 (N06693) on the example of alloy 3 from Table 2

[0318] FIG. 4 Quantitative proportions of the phases in thermodynamic equilibrium in dependence on the temperature of alloy 693 (N06693) on the example of alloy 10 from Table 2

TABLE-US-00001 TABLE 1 Alloys according to ASTM B 168-11, all values in mass -%, [in the table below, all commas should be periods] Alloy Ni Cr Co Mo Nb Fe Mn Al C Cu Si S Ti P Zr Y B N Ce Alloy 72.0 14.0- 6.0- 1.0 0.15 0.5 0.5 0.015 600 - min 17.0 10.0 max max max max max N06600 Alloy 58.0- 21.0- Rest 1.0 1.0- 0.10 0.5 0.5 0.015 601 - 63.0 25.0 max 1.7 max max max max N06601 Alloy 44.5 20.0- 10.0- 8.0- 3.0 1.0 0.8- 0.05- 1.0 0.5 0.015 0.6 0.006 617 - min 24.0 15.0 10.0 max max 1.5 0.15 max max max max max N06617 Alloy 58.0 27.0- 7.0- 0.5 0.05 0.5 1.0 0.015 690 - min 31.0 11.0 max max max max max N06690 Alloy Rest 27.0- 0.5- 2.5- 1.0 2.5- 0.15 0.5 0.5 0.01 1.0 693 - 31.0 2.5 6.0 max 4.0 max max max max max N06693 Alloy Rest 24.0- 8.0- 0.15 1.8- 0.15- 0.1 0.5 0.010 0.1- 0.020 0.01- 0.05- 602CA - 26.0 11.0 max 2.4 0.25 max max max 0.2 max 0.10 0.12 N06025 Alloy 45 26.0- 21.0- 1.0 0.05- 0.3 2.5- 0.010 0.020 0.03- 45 - min 29.0 25.0 max 0.12 max 3.0 max max 0.09 N06045 Alloy Rest 24.0- 8.0- 0.15 2.4- 0.20- 0.50 0.5 0.010 0.01- 0.020 0.01- 0.01- 603 - 26.0 11.0 max 3.0 0.40 max max max 0.25 max 0.10 0.15 N06603 Alloy Rest 28.0- 1.0- 2.0- 1.0 0.15 1.5- 1.0- 0.010 1.0 696 - 32.0 3.0 6.0 max max 3.0 2.5 max max N06696

TABLE-US-00002 TABLE 2 Typical compositions of some alloys according to ASTM B 168-11 (prior art). All values in mass-%*). Alloy compositions from U.S. Pat. No. 4,88,125 Table 1 [in the table below, all commas should be periods] Alloy Batch C S Cr Ni Mn Si Mo Ti Nb Alloy 600 164310 0.07 0.002 15.75 73.77 0.28 0.32 0.2 N06600 Alloy 601 156656 0.053 0.0016 22.95 59.58 0.72 0.24 0.47 N06601 Alloy 690 111389 0.022 0.002 28.45 61.95 0.12 0.32 0.29 N06690 Alloy 693 Alloy 10 *) 0.015 ≤0.01 29.42 60.55 0.014 0.075 0.02 1.04 N06693 Alloy 693 Alloy 8 *) 0.007 ≤0.01 30.00 60.34 0.11 0.38 0.23 1.13 N06693 Alloy 693 Alloy 3 *) 0.009 ≤0.01 30.02 57.79 0.01 0.14 0.02 2.04 N06693 Alloy 693 Alloy 2 *) 0.006 ≤0.01 30.01 60.01 0.12 0.14 0.01 0.54 N06693 Alloy 602 163968 0.170 ≤0.01 25.39 62.12 0.07 0.07 0.13 N06025 Alloy 603  52475 0.225 0.002 25.20 61.6 0.09 0.03 0.16 0.01 N06603 Alloy 696 UNS Mitte 0.080 ≤0.01 30.00 61.20 0.1 1.5 2 0.1 N06696 T.sub.s .sub.BCC Alloy Cu Fe P Al Zr Y B in ° C. Cr + Al Fp Alloy 600 0.01 9.42 0.009 0.16 0.001 15.9 19.1 N06600 Alloy 601 0.04 14.4 0.008 1.34 0.015 0 0.001 669 24.3 31.2 N06601 Alloy 690 0.01 8.45 0.005 0.31 0 0 720 28.8 32.7 N06690 Alloy 693 0.03 5.57 3.2 0.002 939 32.6 39.9 N06693 Alloy 693 0.03 4.63 3.08 0.002 979 33.1 41.3 N06693 Alloy 693 0.03 5.57 4.3 0.002 1079 34.3 44.5 N06693 Alloy 693 0.03 5.80 3.27 0.002 948 33.3 40.3 N06693 Alloy 602 0.01 9.47 0.008 2.25 0.08 0.08 0.005 690 27.6 31.8 N06025 Alloy 603 0.01 9.6 0.007 2.78 0.07 0.08 0.003 707 28.0 32.2 N06603 Alloy 696 2 3 792 30.0 35.1 N06696

TABLE-US-00003 TABLE 3a Composition of the laboratory batches, Part 1. All values in mass % (T: alloy according to the prior art, E: alloy according to the invention, L: melted on the laboratory scale, G: melted on the industrial scale) [in the table below, all commas should be periods] Name Batch C N Cr Ni Mn Si Mo Ti T G Alloy 602 CA 156817 0.171 0.036 25.2 62.1 0.06 0.07 0.01 0.17 T G Alloy 602 CA 160483 0.172 0.025 25.7 62.0 0.06 0.05 0.02 0.14 T G Alloy 601 156656 0.053 0.018 23.0 59.6 0.72 0.24 0.04 0.47 T G Alloy 690 80116 0.010 0.025 27.8 62.8 0.18 0.15 0.01 0.31 T G Alloy 690 111389 0.022 0.024 28.5 62.0 0.12 0.32 <0.01 0.29 L Cr30Al1La 2297 0.018 0.023 29.9 68.0 0.25 0.09 <0.01 <0.01 L Cr30Al1LaT 2300 0.019 0.021 30.2 67.5 0.25 0.08 <0.01 <0.01 L Cr30Al1TiLa 2298 0.018 0.022 29.9 67.5 0.25 0.08 <0.01 0.3 L Cr30Al1TiNbLa 2308 0.017 0.028 30.1 67.1 0.25 0.08 <0.01 0.31 L Cr30Al1CLaTi 2299 0.060 0.021 30.1 67.6 0.25 0.09 <0.01 0.01 L Cr30Al1CLa 2302 0.049 0.02 30.1 67.1 0.26 0.09 <0.01 <0.01 E L Cr30Al2La 2301 0.015 0.021 30.2 66.6 0.25 0.08 <0.01 <0.01 L Cr30Al1Ti 250060 0.017 0.027 29.6 67.9 0.24 0.11 <0.01 0.31 L Cr30Al1Ti 250063 0.017 0.024 29.9 67.4 0.25 0.10 <0.01 0.31 L Cr30Al1TiNb 250066 0.016 0.022 29.9 67.1 0.24 0.09 <0.01 0.31 L Cr30Al1TiNb 250065 0.017 0.025 30.3 67.1 0.24 0.10 0.01 0.3 L Cr30Al1TiNbZr 250067 0.019 0.020 29.7 67.2 0.25 0.10 0.02 0.31 L Cr30Al1TiNb 250068 0.017 0.024 29.8 66.6 0.25 0.09 0.01 0.31 E L Cr28Al2 250129 0.018 0.025 28.2 68.3 0.25 0.10 <0.01 <0.01 E L Cr28Al2Y 250130 0.022 0.022 28.1 68.6 0.25 0.07 <0.01 <0.01 E L Cr28Al2YC1 250132 0.059 0.022 28.3 68.2 0.27 0.06 <0.01 <0.01 E L Cr28Al2Nb.5C1 250133 0.047 0.022 28.3 67.7 0.25 0.06 0.01 <0.01 E L Cr28Al2Nb.5C1 250148 0.049 0.019 27.9 67.9 0.26 0.07 <0.01 <0.01 E L Cr28Al2Nb1C1 250134 0.048 0.026 28.2 67.1 0.26 0.09 0.02 <0.01 E L Cr28Al2Nb1C1 250147 0.045 0.017 28.4 67.5 0.27 0.07 0.02 <0.01 E L Cr28Al2Nb1C1Y 250149 0.054 0.020 27.9 67.2 0.27 0.06 0.01 <0.01 E L Cr28Al2TiC1 250137 0.063 0.024 28.2 67.7 0.27 0.09 <0.01 0.15 E L Cr28Al2TiC1 250138 0.053 0.018 28.3 68.4 0.27 0.05 <0.01 0.16 T.sub.s .sub.BCC Name Nb Cu Fe Al W in ° C. Cr + Al Fp T G Alloy 602 CA <0.01 0.01 9.6 2.36 — 683 27.6 31.9 T G Alloy 602 CA 0.01 0.01 9.4 2.17 — 683 27.8 31.8 T G Alloy 601 0.01 0.04 14.4 1.34 0.01 669 24.3 31.2 T G Alloy 690 <0.01 0.01 8.5 0.14 — 683 27.9 31.4 T G Alloy 690 0.01 0.01 8.5 0.31 — 720 28.8 32.7 L Cr30Al1La <0.01 <0.01 0.56 1.04 <0.01 737 30.9 32.5 L Cr30Al1LaT <0.01 <0.01 0.54 1.3 <0.01 737 31.5 33.3 L Cr30Al1TiLa <0.01 <0.01 0.55 1.28 <0.01 759 31.2 33.8 L Cr30Al1TiNbLa 0.28 <0.01 0.53 1.25 0.01 772 31.4 34.3 L Cr30Al1CLaTi <0.01 <0.01 0.54 1.25 0.01 730 31.3 32.7 L Cr30Al1CLa <0.01 <0.01 0.57 1.65 <0.01 730 31.8 33.8 E L Cr30Al2La <0.01 <0.01 0.54 2.25 <0.01 809 32.4 35.6 L Cr30Al1Ti <0.01 <0.01 0.54 1.16 0.01 759 30.8 33.3 L Cr30Al1Ti <0.01 <0.01 0.53 1.39 <0.01 759 31.3 34.2 L Cr30Al1TiNb 0.31 <0.01 0.50 1.42 0.01 772 31.3 34.6 L Cr30Al1TiNb 0.31 <0.01 0.05 1.41 0.01 768 31.7 34.8 L Cr30Al1TiNbZr 0.31 <0.01 0.53 1.47 0.01 776 31.1 34.4 L Cr30Al1TiNb 0.88 <0.01 0.53 1.43 0.02 799 31.2 35.2 E L Cr28Al2 <0.01 0.01 0.57 2.51 <0.01 740 30.7 34.3 E L Cr28Al2Y <0.01 <0.01 0.51 2.61 <0.01 766 30.7 34.3 E L Cr28Al2YC1 0.01 0.02 0.60 2.61 0.02 762 30.9 34.1 E L Cr28Al2Nb.5C1 0.50 0.02 0.52 2.76 0.02 800 31.1 35.2 E L Cr28Al2Nb.5C1 0.56 0.03 0.48 2.62 0.01 779 30.5 34.5 E L Cr28Al2Nb1C1 1.06 0.03 0.48 2.84 0.02 830 31.1 36.1 E L Cr28Al2Nb1C1 0.90 0.02 0.43 2.15 0.02 774 30.5 34.3 E L Cr28Al2Nb1C1Y 1.04 0.03 0.45 2.64 <0.01 800 30.6 35.1 E L Cr28Al2TiC1 <0.01 0.03 0.5 2.88 <0.01 788 31.0 34.9 E L Cr28Al2TiC1 <0.01 0.03 0.45 2.62 0.01 774 30.9 34.5

TABLE-US-00004 TABLE 3b Composition of the laboratory batches, Part 2: All values in mass % (The following apply for all alloys: Pb: max. 0.002%, Zn: max. 0.002%. Sn: max. 0.002%) (For significance of T, E, G, L, see Table 3a) [in the table below, all commas should be periods] Name Batch S P Mg Ca V Zr Co T G Alloy 602 CA 156817 0.002 0.005 0.004 0.001 0.03 0.08 0.05 T G Alloy 602 CA 160483 <0.002 0.007 0.010 0.002 — 0.09 0.04 T G Alloy 601 156656 0.002 0.008 0.012 <0.01 0.03 0.015 0.04 T G Alloy 690 80116 0.002 0.006 0.030 0.0009 — <0.002 0.02 T G Alloy 690 111389 0.002 0.005 <0.001 0.0005 — — 0.01 L Cr30Al1La 2297 0.004 0.003 0.015 <0.01 <0.01 <0.002 — L Cr30Al1LaT 2300 0.003 0.002 0.014 <0.01 <0.01 <0.002 <0.001 L Cr30Al1TiLa 2298 0.004 0.002 0.016 <0.01 <0.01 <0.002 <0.001 L Cr30Al1TiNbLa 2308 0.002 0.002 0.014 <0.01 <0.01 <0.002 — L Cr30Al1CLaTi 2299 0.003 0.002 0.015 <0.01 <0.01 <0.002 <0.001 L Cr30Al1CLa 2302 0.003 0.002 0.013 <0.01 <0.01 <0.002 0.001 E L Cr30Al2La 2301 0.003 0.002 0.015 <0.01 <0.01 <0.002 <0.001 L Cr30Al1Ti 250060 0.003 0.002 0.009 <0.01 <0.01 <0.002 <0.001 L Cr30Al1Ti 250063 0.003 0.003 0.012 <0.01 <0.01 <0.002 <0.001 L Cr30Al1TiNb 250066 0.002 0.002 0.012 <0.01 <0.01 <0.002 <0.001 L Cr30Al1TiNb 250065 0.002 0.002 0.012 <0.01 <0.01 <0.002 <0.001 L Cr30Al1TiNbZr 250067 0.003 0.002 0.010 <0.01 <0.01 0.069 <0.001 L Cr30Al1TiNb 250068 0.002 <0.002 0.010 <0.01 <0.01 <0.002 <0.001 E L Cr28Al2 250129 0.004 0.003 0.011 0.0002 <0.01 <0.002 — E L Cr28Al2Y 250130 0.003 0.003 0.013 <0.0002 <0.01 <0.002 — E L Cr28Al2YC1 250132 0.003 0.004 0.009 0.0012 0.01 0.003 <0.01 E L Cr28Al2Nb.5C1 250133 0.005 0.003 0.009 0.0012 <0.01 0.004 0.01 E L Cr28Al2Nb.5C1 250148 0.004 0.004 0.010 0.0005 0.01 — <0.01 E L Cr28Al2Nb1C1 250134 0.006 0.002 0.009 0.0009 <0.01 0.006 0.01 E L Cr28Al2Nb1C1 250147 0.002 0.002 0.010 0.0005 <0.01 0.01 0.01 E L Cr28Al2Nb1C1Y 250149 0.004 0.005 0.013 <0.0005 <0.01 0.006 <0.01 E L Cr28Al2TiC1 250137 0.005 0.004 0.008 0.0002 <0.01 0.004 <0.01 E L Cr28Al2TiC1 250138 0.005 0.004 0.010 0.0002 <0.01 0.003 0.01 Name Y La.sub.— B Hf T Ce O T G Alloy 602 CA 0.060 — 0.003 — — — 0.001 T G Alloy 602 CA 0.070 — 0.003 — — — 0.001 T G Alloy 601 — — 0.001 — — — 0.0001 T G Alloy 690 — — 0.002 — — — 0.0005 T G Alloy 690 — — — — — — 0.001 L Cr30Al1La <0.001 0.062 <0.001 <0.001 <0.005 0.001 0.0001 L Cr30Al1LaT <0.001 0.051 <0.001 <0.001 <0.005 0.001 0.0001 L Cr30Al1TiLa <0.001 0.058 <0.001 <0.001 <0.005 0.001 0.002 L Cr30Al1TiNbLa <0.001 0.093 <0.001 <0.001 <0.005 0.001 0.002 L Cr30Al1CLaTi <0.001 0.064 <0.001 <0.001 <0.005 0.001 0.002 L Cr30Al1CLa <0.001 0.057 <0.001 <0.001 <0.005 0.001 0.0001 E L Cr30Al2La <0.001 0.058 <0.001 <0.001 <0.005 0.001 0.002 L Cr30Al1Ti <0.001 <0.001 <0.001 <0.001 <0.005 <0.001 0.003 L Cr30Al1Ti <0.001 <0.001 <0.001 <0.001 <0.005 <0.001 0.003 L Cr30Al1TiNb <0.001 <0.001 <0.001 <0.001 <0.005 <0.001 0.004 L Cr30Al1TiNb <0.001 <0.001 <0.001 <0.001 <0.005 <0.001 0.005 L Cr30Al1TiNbZr <0.001 <0.001 <0.001 <0.001 <0.005 <0.001 0.003 L Cr30Al1TiNb <0.001 <0.001 <0.001 <0.001 <0.005 <0.001 0.004 E L Cr28Al2 — — <0.0005 — — — 0.001 E L Cr28Al2Y 0.063 — <0.0005 — — — 0.001 E L Cr28Al2YC1 0.07 — 0.001 — — — 0.001 E L Cr28Al2Nb.5C1 0.01 — — — — — 0.001 E L Cr28Al2Nb.5C1 <0.01 — — — — — 0.003 E L Cr28Al2Nb1C1 0.01 — <0.0005 — — — 0.003 E L Cr28Al2Nb1C1 0.01 — 0.0012 — — — 0.001 E L Cr28Al2Nb1C1Y 0.08 — 0.0012 — — — 0.002 E L Cr28Al2TiC1 <0.01 — 0.0012 — — — 0.001 E L Cr28Al2TiC1 <0.01 — 0.0012 — — — 0.004

TABLE-US-00005 TABLE 4 Results of the tension tests at room temperature (RT), 600° C. and 800° C. The forming speed was 8.33.Math. 10.sup.−5 sec.sup.−1 (0.5%/min) for R.sub.p0.2 and 8.33.Math. 10.sup.−4 sec.sup.−1 (5%/min) for R.sub.m; KG = grain size. [in the table below, all commas should be periods] Grain size in R.sub.p02 in MPa R.sub.m in MPa A.sub.5 in % R.sub.p02 in MPa Name Batch μm RT RT RT 600° C. T Alloy 602 CA 156817 76 292 699 36 256 T Alloy 602 CA 160483 76 340 721 42 254 T Alloy601 156656 136 238 645 53 154 T Aloy 690 80116 92 279 641 56 195 T Alloy 690 111389 72 285 630 50 188 Cr30Al1La 2297 233 221 637 67 131 Cr30Al1LaT 2300 205 229 650 71 131 Cr30Al1TiLa 2298 94 351 704 59 228 Cr30Al1TiNbLa 2308 90 288 683 55 200 Cr30Al1CLaTi 2299 253 258 661 62 212 Cr30Al1CLa 2302 212 353 673 59 233 E Cr30Al2La 2301 155 375 716 66 298 Cr30Al1Ti 250060 114 252 662 67 183 Cr30Al1Ti 250063 118 252 659 70 178 Cr30Al1TiNb 250066 121 240 666 67 186 Cr30Al1TiNb 250065 132 285 685 61 213 Cr30Al1TiNbZr 250067 112 287 692 67 227 Cr30Al1TiNb 250068 174 261 666 69 205 E Cr28Al2 250129 269 334 674 66 E Cr28Al2Y 250130 167 322 693 63 252 E Cr28Al2YC1 250132 189 301 669 65 E Cr28Al2Nb.5C1 250133 351 399 725 57 334 E Cr28Al2Nb.5C1 250148 365 353 704 60 284 E Cr28Al2Nb1C1 250134 384 448 794 59 410 E Cr28Al2Nb1C1 250147 350 372 731 57 306 E Cr28Al2Nb1C1Y 250149 298 415 784 53 339 E Cr28Al2TiC1 250137 142 379 745 59 327 E Cr28Al2TiC1 250138 224 348 705 61 278 R.sub.m in MPa A.sub.5 in % R.sub.p02 in MPa R.sub.m in MPa Name 600° C. 600° C. 800° C. 800° C. Fa Fk T Alloy 602 CA 578 41 186 198 63.0 76.9 T Alloy 602 CA 699 69 186 197 62.2 79.6 T Alloy601 509 54 133 136 43.3 56.3 T Aloy 690 469 48 135 154 36.2 41.6 T Alloy 690 465 51 36.8 43.6 Cr30Al1La 460 61 134 167 33.5 43.4 Cr30Al1LaT 469 65 132 160 33.9 46.3 Cr30Al1TiLa 490 31 149 161 39.7 51.5 Cr30Al1TiNbLa 508 39 174 181 41.6 61.0 Cr30Al1CLaTi 475 59 181 185 42.3 50.0 Cr30Al1CLa 480 59 189 194 40.0 52.9 E Cr30Al2La 504 49 275 277 33.2 55.6 Cr30Al1Ti 509 62 143 154 39.3 50.4 Cr30Al1Ti 510 57 148 152 39.6 52.9 Cr30Al1TiNb 498 66 245 255 41.4 63.6 Cr30Al1TiNb 521 58 264 265 41.8 64.0 Cr30Al1TiNbZr 532 65 280 280 41.6 64.2 Cr30Al1TiNb 498 65 297 336 44.9 83.2 E Cr28Al2 191 224 31.8 56.8 E Cr28Al2Y 522 53 220 244 32.6 57.9 E Cr28Al2YC1 226 226 40.2 64.0 E Cr28Al2Nb.5C1 522 33 285 353 40.8 78.9 E Cr28Al2Nb.5C1 523 58 259 344 41.2 79.5 E Cr28Al2Nb1C1 579 28 343 377 44.4 99.4 E Cr28Al2Nb1C1 547 49 309 384 43.0 89.1 E Cr28Al2Nb1C1Y 528 27 340 400 45.1 99.2 E Cr28Al2TiC1 542 29 311 314 44.0 70.4 E Cr28Al2TiC1 510 46 247 296 42.2 66.5

TABLE-US-00006 TABLE 5 Results of the oxidation tests at 1000° C. in air after 1056 hours. [in the table below, all commas should be periods] m.sub.gross m.sub.net m.sub.spall Name Batch Test No. in g/m.sup.2 in g/m.sup.2 in g/m.sup.2 T Alloy 602 CA 160483 412 8.66 7.83 0.82 T Alloy 602 CA 160483 425 5.48 5.65 −0.18 T Alloy 601 156125 403 51.47 38.73 12.74 T Alloy 690 111389 412 23.61 7.02 16.59 T Alloy 690 111389 421 30.44 −5.70 36.14 T Alloy 690 111389 425 28.41 −0.68 29.09 Cr30Al1La 2297 412 36.08 −7.25 43.33 Cr30Al1LaT 2300 412 41.38 −2.48 43.86 Cr30Al1TiLa 2298 412 49.02 −30.59 79.61 Cr30Al1TiNbLa 2306 412 40.43 16.23 24.20 Cr30Al1CLaTi 2308 412 42.93 −15.54 58.47 Cr30Al1CLa 2299 412 30.51 0.08 30.44 Cr30Al2La 2302 412 27.25 9.57 17.68 E Cr30Al1Ti 2301 412 8.43 6.74 1.69 Cr30Al1Ti 250060 421 43.30 −19.88 63.17 Cr30Al1TiNb 250063 421 32.81 −22.15 54.96 Cr30Al1TiNb 250066 421 26.93 −16.35 43.28 Cr30Al1TiNbZr 250065 421 25.85 −24.27 50.12 Cr30Al1TiNb 250067 421 41.59 −15.56 57.16 Cr28Al2 250068 421 42.69 −39.26 81.95 E Cr28Al2Y 250129 425 3.72 3.55 0.16 E Cr28Al2YC1 250130 425 4.68 4.90 −0.23 E Cr28Al2Nb.5C1 250132 425 3.94 5.01 −1.07 E Cr28Al2Nb.5C1 250133 425 2.56 3.98 −1.42 E Cr28Al2Nb1C1 250148 425 3.15 3.21 −0.07 E Cr28Al2Nb1C1 250134 425 3.34 4.23 −0.89 E Cr28Al2Nb1C1Y 250147 425 2.72 2.62 0.10 E Cr28Al2TiC1 250149 425 3.44 3.84 −0.40 E Cr28Al2TiC1 250137 425 3.62 4.24 −0.62 E Cr30Al1La 250138 425 3.87 4.28 −0.41