Casting method for active metal

Abstract

A casting method of an active metal includes, in an induction melting furnace using a water-cooled crucible, tapping a molten metal into a mold from a tapping hole provided at a bottom of the water-cooled copper crucible to cast an ingot of the active metal. In conducting the casting under a casting condition in which the ingot has a diameter (D) of 10 mm or more and a ratio (H/D) of an ingot height H to the ingot diameter D of 1.5 or more and a weight of the molten metal tapped in the casting is 200 kg or less, a temperature of the molten metal in the casting is set to be higher than the melting point of the active metal and a casting velocity V (mm/sec) is controlled to satisfy V≤0.1H in relation with the ingot height H by adjusting an opening diameter of the tapping hole.

Claims

1. A casting method of an active metal, the method comprising: in an induction melting furnace using a water-cooled crucible, tapping a molten metal into a mold from a tapping hole provided at a bottom of the water-cooled copper crucible, thereby casting an ingot of the active metal, wherein the casting is conducted under a casting condition in which the ingot has a diameter (D) of at least 10 mm and a ratio (H/D) of an ingot height H to the ingot diameter D of at least 1.5, and a weight of the molten metal tapped in the casting is 200 kg or less, and wherein a temperature of the molten metal in the casting is higher than a melting point of the active metal and the casting is conducted while a casting velocity V (mm/sec) that is a velocity at which the casting proceeds in the mold is controlled to satisfy V≤0.1H in relation to the ingot height H by adjusting an opening diameter of the tapping hole.

2. The method of claim 1, wherein the active metal is at least one selected from the group consisting of a titanium (Ti)-based, zirconium (Zr)-based, vanadium (V)-based, and chromium (Cr)-based alloy.

3. The method of claim 1, wherein a yield of a non-defective ingot in the bottom-tapping method is up to 80%, wherein the yield of a non-defective ingot represents a ratio h/H of a height h of a place where a shrinkage cavity C is not generated inside the ingot to a height H of the ingot.

4. The method of claim 2, wherein a yield of a non-defective ingot in the bottom-tapping method is up to 80%, wherein the yield of a non-defective ingot represents a ratio h/H of a height h of a place where a shrinkage cavity C is not generated inside the ingot to a height H of the ingot.

Description

BRIEF DESCRIPTION OF DRAWINGS

(1) FIG. 1A illustrates a casting equipment used in a melting method of active metal of this embodiment.

(2) FIG. 1B is a schematic cross-sectional view of the inside of an ingot cast by the casting apparatus of FIG. 1A.

(3) In FIG. 2, the left view is a cross-sectional view of the generation state of the defect inside an ingot cast by the conventional melting method (tilting-tapping method), and the right view is a cross-sectional view of the generation state of the defect inside an ingot cast by the melting method of this embodiment.

(4) In FIG. 3, the left view illustrates a temperature distribution inside an ingot having a weight of 5 kg and a height of 220 mm cast in a casting rate of 158.4 mm/sec and the right view illustrates a temperature distribution inside an ingot having a weight of 5 kg and a height of 220 mm cast in a casting rate of 2.2 mm/sec.

(5) FIG. 4 illustrates the influence of a casting rate on the yield of an ingot.

(6) FIG. 5A is a view of a casting equipment used in the conventional melting method (tilting-tapping method) of active metal.

(7) FIG. 5B is a schematic cross-sectional view of the inside of an ingot cast by the casting apparatus of FIG. 5A.

DESCRIPTION OF EMBODIMENTS

(8) The embodiment of the casting method of active metal according to the present invention is described in detail below by reference to the drawings.

(9) The casting method of active metal of this embodiment produces a small-diameter ingot S (ingot) by pouring a molten metal M obtained by melting an active metal having high melting point (hereinafter referred to as active metal) such as titanium (Ti)-based, zirconium (Zr)-based, vanadium (V)-based or chromium (Cr)-based alloy into a mold 4 and conducting casting.

(10) Casting equipment 1 used in the casting method of active metal of this embodiment is described below.

(11) As illustrated in FIG. 1, the casting equipment 1 of this embodiment has an induction melting furnace 3 using a water-cooled copper crucible 2 and a mold 4 into which a molten metal M tapped from the bottom of the crucible 2 is poured. The molten metal M is tapped into the mold 4 from the bottom of the crucible 2 and a small-diameter ingot S of the active metal is cast.

(12) The induction melting furnace 3 used in the casting equipment 1 of this embodiment generates induction current inside a material to be melted and utilizes its resistance heating, and is generally called Cold Crucible Induction Melting. The induction melting furnace 3 melts the active metal using the water-cooled copper crucible 2. The crucible 2 is formed of copper without using a refractory which is frequently used as a material constituting the crucible 2 of a typical melting furnace. For this reason, the induction melting furnace is difficult to receive the influence of contaminants from the refractory.

(13) The crucible 2 used in the above-described induction melting furnace 3 is formed into a bottomed cylindrical shape opened upward as illustrated in FIG. 1, and can store the molten active metal thereinside.

(14) A wall of the crucible 2 is formed of copper as described above, and is cooled with water. When the wall of the crucible 2 is formed of such a water-cooled copper, the temperature of the wall of the crucible 2 does not increase to a predetermined temperature (for example, 250° C.) or higher even when the crucible stores the molten active metal. Specifically, even when the molten active metal is placed in the water-cooled copper crucible 2, a solidified shell called skull is formed between the wall of the crucible 2 and the molten metal and plays a role as a crucible. As a result, the molten metal is not contaminated by the crucible 2.

(15) The crucible 2 of this embodiment is bottom-tapping type, and a tapping hole 5 capable of guiding the stored active metal downward is formed at the bottom of the crucible 2. The tapping hole 5 is configured so that its opening diameter is adjustable and therefore the amount of the molten metal M to be guided downward is adjustable. The tapping hole 5 may be configured so that the opening diameter is adjusted by an electromagnetic method or a mechanical method, or may be configured so that a plurality of valve members having different opening diameter is previously prepared and the opening diameter is adjusted by exchanging the valve member.

(16) The mold 4 is formed into a bottomed cylindrical shape opened upward.

(17) Inner dimension of the mold 4 preferably has a size within the following applicable range, when the diameter of the ingot S is D, the height of the ingot S is H and the weight of the molten metal M is W:

(18) Ingot diameter D (mm): 10≤D≤150

(19) Ingot height H (mm): 15≤H≤1500

(20) Molten metal weight (kg): 0.2≤W≤200

(21) Procedures of casting active metal using the above-described induction melting furnace 3, in other words, the casting method of active metal, are described below.

(22) The casting method of active metal of this embodiment a method including, in an induction melting furnace 3 using a water-cooled crucible 2, tapping a molten metal M into a mold 4 from a bottom of the water-cooled copper crucible 2 to cast a small-diameter ingot S of the active metal. In this case, the casting of the small-diameter ingot S is conducted under the casting condition in which the diameter (D) is 10 mm or more, a ratio (H/D) of the height (H) of the ingot S to the diameter (D) of the ingot S is 1.5 or more, and the weight of the molten metal M tapped in the casting is 200 kg or less. In conducting the casting, the tapping hole 5 configured so that its opening diameter is adjustable is provided at the bottom of the crucible 2. The temperature of the molten metal M in casting is set to a temperature higher than the melting point of the active metal and the casting is conducted while a casting velocity V (mm/sec) which is a velocity at which the casting proceeds in the mold 4 is controlled to satisfy V≤0.1H in relation with the ingot height H by adjusting the opening diameter of the tapping hole 5. As a result, the shrinkage cavity inside the ingot S is reduced and the casting yield is improved. In order to prevent “molten metal clogging” in which the molten metal tapped in casting is clogged and does not flow, the temperature of the molten metal M in casting is preferably higher than the melting point of the active material by 20° C. or more, more preferably by 40° C. or more.

(23) The reasons for setting the above casting conditions in the casting method of this embodiment are as follows.

(24) For example, a multicomponent Ti—Al alloy raw material (Ti-33.3Al-4.6Nb-2.55Cr) is melted in the induction melting furnace 3 of the water-cooled copper crucible 2 (size: diameter 250 mm) and maintained until reaching a completely molten state. Thereafter, current was applied to a coil arranged at the bottom, a titanium bottom plug (size: diameter 3.2 mm) arranged at the bottom was induction-melted, and the bottom plug was melted and removed to form an opening. The molten alloy raw material was tapped from the bottom of the crucible 2 in a bottom-tapping method to cast the ingot S. In comparison, an ingot was prepared by conducting a tilting type tapping as illustrated in FIG. 5A and FIG. 5B. Cross-sectional photographs of the ingot S sample of the Ti—Al alloys cast as above are illustrated in the left side of FIG. 2 regarding the tilting-tapping method (conventional technology) and in the right side of FIG. 2 regarding the bottom-tapping method (present invention).

(25) As illustrated in the left side of FIG. 2, defects by the shrinkage cavity C are apparently present over a wide range of a vertical direction inside the ingot S cast by the conventional tilting-tapping method. On the other hand, it was confirmed that the defects by the shrinkage cavity C were generated at only the upper end part of the ingot S inside the ingot S cast by the bottom-tapping as illustrated in the right side of FIG. 2. The reason for this is considered that when the molten alloy raw material was tapped by the bottom-tapping method, the casting velocity became slow as compared with the tilting-tapping method, and as a result, the finally solidified part constituted the uppermost part though a solidification process close to the directional solidification from the bottom. Although not illustrated in FIG. 1B and FIG. 5B, the defects called “medium sink mark” confined in the ingot are included in the shrinkage cavity C.

(26) The evaluating results of the generation state of the shrinkage cavity inside the ingots S by the bottom-tapping method and the tilting-tapping method and the yields are shown in Table 1.

(27) TABLE-US-00001 TABLE 1 Yield of non- Casting Shrinkage defective Art velocity cavity product Evaluation Conventional example  3.6 kg/s X 30% X (Tilting-tapping method) Present example 0.05 kg/s ◯ 80% ◯ (Bottom-tapping method)

(28) As is understood from the present example of Table 1, by slowing down the casting velocity as compared with the conventional example, the generation place of the shrinkage cavity C shifts to the upper end side of the ingot S (TOP part of ingot S), and the “yield of non-defective product” is improved up to 80% in the present example (bottom-tapping method) as compared with 30% in the conventional example (tilting-tapping method). The “yield of non-defective product” represents a ratio of a height of a place which the shrinkage cavity C is not present inside the ingot S, that is, the place at which the shrinkage cavity S is not generated in FIG. 2, to an overall height of the ingot S (specifically, h/H in FIG. 1B and h′/H in FIG. 5B).

(29) The occurrence of difference of the generation state of the shrinkage cavity C as the above is greatly affected by the position of the finally solidified part present in the ingot S. In other words, basically the shrinkage cavity C is greatly generated in the place at which the solidification is completed (finally solidified part). Therefore, when the casting velocity has been changed using numerical analysis software, if the temperature distribution inside the ingot S is obtained, the position at which the finally solidified part is present in the ingot S is also obtained, and the generation state of the shrinkage cavity C is evaluated.

(30) For example, the left side of FIG. 3 illustrates the temperature distribution inside the ingot S when the casting has been conducted by the tilting-tapping method (conventional art). Numerical values in the figure indicate the temperature inside the ingot S obtained as a result of numerical analysis. It shows that the temperature of ingot piece is high as the numerical value is large, and the finally solidified part that is not solidified until the final and remains has high temperature. In other words, it is assumed that the finally solidified part corresponds to the generation place at which the shrinkage cavity C is mainly generated.

(31) As illustrated in the left side of FIG. 3, when the tilting-tapping method is supposed, that is, when the casting velocity is high as 158.4 mm/s, the generation place of the shrinkage cavity C is present at the central part (central side in vertical direction) of the ingot S.

(32) On the other hand, as illustrated in the right side of FIG. 3, when the bottom-tapping method (the art of the present invention) is supposed, that is, when the casting velocity is slow as 2.2 mm/sec, it is confirmed that the generation place of the shrinkage cavity C has shifted to the upper end side of the ingot S. This is considered to be due to that by decreasing the casting velocity, the directional solidification in which the solidification proceeds in order upward from the bottom is realized.

(33) The relationship between the casting velocity and the position of the finally solidified part (generation place of the shrinkage cavity C) is shown in Table 2 and FIG. 4. The mold such that an ingot having a diameter (D) of 100 mm and a weight of 25 kg is obtained was used.

(34) TABLE-US-00002 TABLE 2 Casting Yield velocity V/ of non- Casting Ingot height defective velocity V H × 100 product Art (kg/s) (%/s) (%) Example CASTEM 4.80 72 50 analytical value 2.40 36 55 0.67 10 60 0.27 4 65 0.13 2 71.5 0.07 1 78 Measured value 0.15 2.26 68 of BOT tapping 0.05 0.75 76 0.066 0.0047 86 0.067 0.0059 85 Comparative Measured value 3.60 52.9 54 Example of tilting tapping

(35) FIG. 4 shows the position of the finally solidified part (in other words, yield of the ingot S) when the casting velocity to the weight of the ingot S (casting velocity [%/sec] represented by a ratio to casting length) has been changed. The casting velocity of CASTEM analytical value shown in FIG. 4 is calculated using the numerical value analysis as same as in FIG. 3. The casting velocity of the experimental value of the bottom tapping and the experimental value of the tilting tapping is obtained by the experiment. When the height of the ingot S in FIG. 1B is H (mm), in case where the casting velocity V (mm/s) is “0.1×H” or less (“casting velocity (mm/s)/ingot height (mm)×100” is 10%/s or less), the finally solidified part shifts to the upper end side (TOP part) of the ingot S and the shrinkage cavity C also shifts to the upper end side of the ingot S. As a result, in case where the casting velocity V is “0.1×H” or less, the part excluding the upper end side at which the shrinkage cavity C is generated can be used as non-defective ingot S and it is assumed that the yield of the non-defective product is improved to 60% or more. According to the Example of FIG. 4, when casting velocity V (mm/s)/ingot height (mm)×100 is 4%/s or less, the yield is improved to 65% or more; when casting velocity V (mm/s)/ingot height (mm)×100 is 2%/s or less, the yield is improved to 70% or more; when casting velocity V (mm/s)/ingot height (mm)×100 is 1%/s or less, the yield is improved to 75% or more; and when casting velocity V (mm/s)/ingot height (mm)×100 is 0.006%/s or less, the yield is improved to 85% or more.

(36) In the case of the conventional method (tilting-tapping method), the yield of the non-defective product is merely 30% in the case of Table 1 and is merely 54% in the case of Table 2.

(37) Therefore, in order that the yield of the non-defective product is 60% or more, the casting velocity V (mm/sec) is preferably “0.1×H” or less when the height of the ingot S is H (mm).

(38) The reasons for setting the above-described casting conditions in the casting method of this embodiment are described as above.

(39) That is, in the present invention, in conducting the casting under the casting condition in which the diameter (D) is 10 mm or more, the ratio (H/D) of the height H of the ingot S to the diameter D of the ingot S is 1.5 or more and the weight of the molten metal tapped in casting is 200 kg or less, the casting is conducted such that the temperature of the molten metal M in casting is set to higher than the melting point of the active metal by 40° C. or more and the casting velocity V (mm/sec) is controlled to satisfy V≤0.1H. Thus, the shrinkage cavity C inside the ingot S is reduced and the casting yield is improved.

(40) It should be considered that the embodiments disclosed herein are examples in all respects and are not limitative. In particular, items not explicitly disclosed, for example, operating conditions, various parameters, and size, weight and volume of constructs, do not deviate from the ranges in which one skilled in the art generally carries out, and values that can be easily anticipated by one skilled in the art can be used.

(41) Although the present invention has been described in detail and by reference to the specific embodiments, it is apparent to one skilled in the art that various modifications or changes can be made without departing the spirit and scope of the present invention.

(42) This application is based on Japanese Patent Application No. 2016-241248 filed on Dec. 13, 2016 and Japanese Patent Application No. 2017-206165 filed on Oct. 25, 2017, the disclosures of which are incorporated herein by reference.

INDUSTRIAL APPLICABILITY

(43) The present invention can produce high-quality ingot having less shrinkage cavity in high yield in the ingot production of active metal by an induction melting furnace.

REFERENCE SIGNS LIST

(44) 1 Casting equipment 2 Crucible 3 Induction melting furnace 4 Mold 5 Tapping hole C Shrinkage cavity M Molten metal S Ingot