Method for manufacturing sintered ore
10995388 · 2021-05-04
Assignee
Inventors
- Masato Kuroiwa (Tokyo, JP)
- Shunsuke Nonaka (Tokyo, JP)
- Yukimasa Horikawa (Tokyo, JP)
- Shunsuke OURA (Tokyo, JP)
- Tetsuya Jinno (Tokyo, JP)
Cpc classification
International classification
Abstract
Uneven sintering is prevented in a sintering machine, and thus sintered ore having high strength and a high lump yield rate is manufactured. A method for manufacturing sintered ore comprising: charging sintering raw material comprising fine ore and carbon material on a circulatively moving pallet to form a raw material layer; igniting the carbon material on a surface of the raw material layer and sucking air from above the raw material layer down to below the palette so that the air is introduced into the raw material layer; and combusting the carbon material in the raw material layer to thereby manufacture sintered ore, wherein fuel gas is discharged from a nozzle at a flow speed of 40 m/s or more, the discharged fuel gas is combusted to generate combustion gas, and the combustion gas is used for igniting the carbon material.
Claims
1. A method for manufacturing sintered ore comprising: charging sintering raw material comprising fine ore and carbon material on a circulatively moving pallet to form a raw material layer; igniting the carbon material on a surface of the raw material layer and sucking air from above the raw material layer down to below the palette so that the air is introduced into the raw material layer; and combusting the carbon material in the raw material layer to thereby manufacture sintered ore, wherein fuel gas is discharged from a nozzle at a flow speed of 40 m/s or more, the discharged fuel gas is combusted to generate combustion gas, and the combustion gas hits against a surface of the raw material layer for igniting the carbon material.
2. The method for manufacturing sintered ore according to claim 1, wherein the combustion gas is generated using a burner comprising: a main burner part having a fuel gas nozzle configured to discharge the fuel gas and an air nozzle configured to discharge air for combustion; and a sub burner part positioned further outward than the main burner part and configured to combust the fuel gas discharged from the main burner part.
3. The method for manufacturing sintered ore according to claim 2, wherein the burner has an end towards which a flame is formed; the end has a recessed part; and the recessed part has a bottom part and a tapered part wherein the tapered part gradually widens from the bottom part towards the end of the burner.
4. The method for manufacturing sintered ore according to claim 3, wherein the bottom part and the tapered part, which form the recessed part, make an angle θ of 20° or more.
5. The method for manufacturing sintered ore according to claim 1, wherein the flow speed of the fuel gas is 50 m/s or more and 150 m/s or less.
6. The method for manufacturing sintered ore according to claim 2, wherein the flow speed of the fuel gas is 50 m/s or more and 150 m/s or less.
7. The method for manufacturing sintered ore according to claim 3, wherein the flow speed of the fuel gas is 50 m/s or more and 150 m/s or less.
8. The method for manufacturing sintered ore according to claim 4, wherein the flow speed of the fuel gas is 50 m/s or more and 150 m/s or less.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) In the accompanying drawings:
(2)
(3)
(4)
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(7)
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DETAILED DESCRIPTION
(12) Next, detailed description is given below. The following provides a description of preferred embodiments and the present disclosure is by no means limited to the description.
(13) In a method for manufacturing sintered ore in one embodiment, sintering raw material comprising fine ore and carbon material is charged on a circulatively moving pallet to form a raw material layer, the carbon material on a surface of the raw material layer is ignited and air is sucked from above the raw material layer by a wind box installed below the palette so that the air is introduced into the raw material layer, and the carbon material is combusted in the raw material layer to manufacture sintered ore.
(14) To perform the manufacturing method, any sintering machine comprising a palette, ignition means (ignition furnace), and mechanism for sucking air downwards from above a raw material layer can be used. That is, a common downward suction-type Dwight Lloyd sintering machine can be used. Further, a gas fuel feeder may be installed on the downstream side of an ignition furnace to feed gas fuel above a raw material layer.
(15) In this disclosure, the fuel gas is discharged from a nozzle at a flow speed of 40 m/s or more, the discharged fuel gas is ignited to generate combustion gas, and the combustion gas is used to ignite the carbon material. The amount of heat transfer Q from flame to a surface of an object to be heated is proportional to the heat transfer coefficient α and the heat transfer coefficient α is larger as the flame speed V.sub.0 is increased. In this disclosure, fuel gas is discharged at a high speed of 40 m/s or more and the fuel gas is ignited to thereby generate combustion gas (flame) having a high speed. By hitting the combustion gas having a high speed against a surface of a raw material layer which is an object to be heated, heat can be provided to the raw material layer with extremely high efficiency. According to this disclosure, it is possible to uniformly heat a surface of a raw material layer and uniformly ignite carbon material comprised in the raw material layer, thus manufacturing sintered ore having high strength and a high lump yield rate.
(16) The carbon material can be ignited using any device which discharges fuel gas at a flow speed satisfying the aforementioned conditions and ignites the fuel gas to generate combustion gas.
(17) In one embodiment, the combustion gas can be generated using a burner comprising: a main burner part having a fuel gas nozzle configured to discharge fuel gas and an air nozzle configured to discharge air for combustion; and a sub burner part positioned further outward than the main burner part and configured to combust the fuel gas discharged from the main burner part. The following describes a case of using the burner.
(18) The main burner part comprises a fuel gas nozzle configured to discharge fuel gas and an air nozzle configured to discharge air for combustion. Fuel gas and air which are discharged from the main burner part are combusted with each other to thereby form flame for heating an object to be heated. The sub burner part has a function of igniting fuel gas discharged from the main burner part.
(19) It is important that the sub burner part is positioned further outward than the main burner part. Such a positional relationship enables stably held flame when a discharge speed is high, compared with other positional relationships.
(20) The aforementioned positional relationship enables stably held flame when a discharge speed is high, which is assumed to be because of the following reasons. Specifically, as proposed in PTL 1, when the fuel gas and the air for combustion are disposed so as to sandwich the pilot flame burner, and a discharge direction of fuel gas is set so as to hit against a discharge direction of air for combustion, a vortex occurs, increasing kinetic energy loss due to flow turbulence. Thus a high flow speed cannot be maintained. On the other hand, our technique can prevent flow turbulence of main fuel gas and air for combustion by positioning the sub burner part further outward than the main burner part in the burner, thus maintaining a high flow speed. Further, by making discharge directions of fuel gas and air for combustion which are discharged from the main burner part parallel to one another, flow turbulence can be further prevented, thus maintaining a high flow speed.
(21) In addition, when the fuel gas nozzle is in a center part and the pilot flame burners are disposed on the outside of the center part and the air for combustion nozzles are disposed on the further outside of the pilot flame burners, fuel gas is necessary to be discharged toward the pilot flame on the both sides, thus requiring to set fuel gas nozzles on the both sides, increasing the number of the nozzles. Then, when a discharge speed is intended to be increased, the diameter of each nozzle becomes small to thereby significantly decrease the gas speed after discharge, which makes it impossible to maintain a high flow speed after discharge. On the other hand, our technique does not need to divide fuel gas to the both sides, and thus a high flow speed can be maintained.
(22) [Fuel Gas]
(23) The fuel gas is not limited and any flammable gas can be used as the fuel gas. As the fuel gas, for example, natural gas and LPG are typically available. Process gas produced as a by-product in steelworks can be also used as the fuel gas. As the process gas, in particular, M gas in which coke oven gas and blast furnace gas is mixed is preferably used.
(24) Next, a more detailed description is given below based on drawings.
(25)
(26)
(27) The example illustrated in
(28) The fuel gas is supplied as illustrated by an arrow mark G, and discharged from the fuel gas nozzle 21. The air for combustion is supplied as illustrated by an arrow mark A, and discharged from the air nozzle 22. The fuel gas is not ignited at the discharge, but as illustrated in
(29) The shapes of the fuel gas nozzle 21 and the air nozzle 22 are not limited and they have any shape. As illustrated in
(30) The diameters of the fuel gas nozzle 21 and the air nozzle 22 are desirably determined so that the nozzle discharge speed in a flow rate range in ordinary use may be 50 m/s to 80 m/s to increase the heating efficiency of the burner. The gas flow speed at maximum combustion is desirably 150 m/s or less. Hereinafter, the diameters of the fuel gas nozzle and the air nozzle are simply referred to as “nozzle diameter”.
(31) Further, when the nozzle diameter is 3 mm or more, the decrease in the speed of gas after the gas has been discharged from the nozzle can be further prevented. Therefore, the nozzle diameter is preferably 3 mm or more and more preferably 5 mm or more. On the other hand, when the nozzle diameter is 30 mm or less, the increase in the flow rate of fuel gas by discharging gas at a high speed can be prevented, reducing the heat load on the burner. Accordingly, the nozzle diameter is preferably 30 mm or less.
(32) The interval (nozzle pitch) L.sub.1 between the fuel gas nozzle and the air nozzle preferably satisfies 2 d.sub.NG≤L.sub.1≤15 d.sub.NA, where d.sub.NG is a diameter of the fuel gas nozzle 21 and d.sub.NA is a diameter of the air nozzle 22. When burners are disposed to make a line burner, the interval (nozzle pitch) L.sub.2 between the fuel gas nozzles of the burners preferably satisfies 2 d.sub.NG≤L.sub.2≤15 d.sub.NA. When the conditions are satisfied, the combustion stability can be ensured and the decrease in the gas speed can be prevented.
(33) The main burner part 20 comprises pressure equalizing chambers 23 on the upstream side of each of the fuel gas nozzle 21 and the air nozzles 22, and comprises, on the opposite side (upstream side) of the nozzles of the pressure equalizing chambers 23, perforated plates 24 having an opening through which fuel gas or air passes. With such a pressure equalizing chamber 23, gas can be discharged more uniformly, thus further stabilizing flame and further increasing the discharge speed. The pressure equalizing chamber 23 may be provided only on the upstream side of either the fuel gas nozzle 21 or the air nozzles 22, but as illustrated in
(34)
(35) As the porous plate 31, any plate member made up of a porous body can be used. The porous body can be made up of materials such as metal, alloy, and ceramic. As the porous plate 31, for example, a metal mesh (laminate of metal fibers) can be used. The surface of the porous plate 31 is preferably disposed on the same plane as that of the tapered part 42.
(36) As illustrated in
(37) The distance between the main burner part and the sub burner part is determined so that flame (sub burner flame 50) of the sub burner part can reach the discharged flow from the main burner part. When the effective length of flame of the sub burner part is F, the distance of the flame of the sub burner part reaching in the direction parallel to the bottom part 41 is F.Math.sin θ. Thus, the main burner part and the sub burner part are disposed so that the distance between the edge position of the main burner and the center position of the sub burner part may be F.Math.sin θ or less in the direction parallel to the bottom part 41. Specifically, when the effective length of flame of the sub burner part is 100 mm, the width of the main burner (distance between the outermost nozzles of the main burner part) is 50 mm, and θ=30°, the distance between the center of the main burner part and the center of the sub burner part is 75 mm or less. Considering the preferred range of θ, the distance between the center of the main burner part and the center of the sub burner part is preferably 60 mm to 110 mm. The effective length of flame can be determined, based on the measurement result of a flame temperature, as the length of a region having gas ignition temperature or more from the combustion surface or the tapered surface.
(38)
(39) [Discharge Speed]
(40) As described above, the burner can stably hold flame without flame off even when a discharge speed is high.
(41) The discharge speed, which is a gas flow speed in the straight tube parts of the fuel gas nozzle and the air nozzle of the main burner part, is determined as follows: a discharge speed=a gas flow rate per unit time in a single nozzle/a cross-sectional area of the nozzle. For a nozzle without a straight tube part, the cross-sectional area of the nozzle is the cross-sectional area of the outlet part of the nozzle. When a burner with many nozzles or openings has a conical cone part in front of the nozzles as illustrated in
(42) The discharge speed of fuel gas is preferably roughly equivalent to the discharge speed of air for combustion. Specifically, the ratio of the discharge speed of fuel gas to the discharge speed of air for combustion (discharge speed ratio) is preferably 0.8 to 1.2. In a burner with a conical cone, the discharge speed ratio in the nozzle opening part in front of the cone is preferably 0.8 to 1.2.
(43) [Flow Rate Ratio of Fuel Gas]
(44) The ratio of the flow rate of fuel gas in the main burner part and the flow rate of fuel gas in the sub burner part (hereinafter, also referred to as “flow rate ratio of fuel gas”) significantly affects the stability and the heating ability of flame. Therefore, the ignition furnace preferably comprises a flow rate adjuster capable of independently adjusting the flow rate of fuel gas in the main burner part and the flow rate of fuel gas in the sub burner part. Further, the content of air for combustion can be determined by multiplying the flow rate of fuel gas by the theoretical air content of the fuel gas and the air ratio. The ignition furnace preferably comprises a flow rate adjuster capable of independently adjusting the flow rate of air for combustion in the main burner part and the flow rate of air for combustion in the sub burner part. The flow rate adjuster includes a flow adjusting valve.
(45) When the sum of the flow rate of fuel gas in the main burner part and the flow rate of fuel gas of the sub burner part is 100%, and the flow rate of fuel gas in the sub burner part is less than 15%, a flame temperature is significantly lowered by an accompanied flow, which is likely to cause flame off in the main burner. Therefore, the flow rate of fuel gas in the sub burner part is preferably 15% or more. In other words, a ratio of a flow rate of fuel gas in the main burner part and a flow rate of fuel gas in the sub burner part is preferably 85:15 or less. On the other hand, when the flow rate of fuel gas of the sub burner part is too high, flame is stably held but flame of the main burner part becomes small, thus deteriorating heating ability. Therefore, the flow rate of fuel gas in the sub burner part is preferably 30% or less. In other words, a ratio of a flow rate of fuel gas in the main burner part and a flow rate of fuel gas in the sub burner part is preferably 70:30 or more.
(46) (Evaluation of Maximum Discharge Speed)
(47) Next, to examine the ability of the burner, the following three types of burners were used to evaluate the maximum discharge speed which could hold flame without flame off. The specification of each burner is listed in Table 1.
(48) (Burner 1) a conventional typical premixing combustion burner as illustrated in
(49) (Burner 2) a burner illustrated in FIG. 1 of PTL 1
(50) (Burner 3) a burner having a structure illustrated in
(51) The burner 1 was a conventional premixing combustion burner having a cross-sectional shape as illustrated in
(52) The burner 2 was a line burner having a length of 1 m comprising a plurality of nozzles with a cross-sectional shape illustrated in FIG. 1 of PTL 1. The line burner had 60 sets of the nozzles linearly disposed in the longitudinal direction of the burner. The burner 2 had a main burner part having a fuel gas nozzle, which had a nozzle diameter of 6 mm. Further, the main burner part of the burner 2 had an air nozzle, which had the same nozzle diameter as that of the fuel gas nozzle. The burner of PTL 1 had two fuel gas nozzles, and thus the line burner had 120 fuel gas nozzles in total. Therefore, the total cross-sectional area of the fuel gas nozzles in the main burner part of the burner 2 was 33.8 cm.sup.2. When the burner 2 had 50 sets of nozzles, flame was unstable. Therefore, 60 sets of nozzles were disposed to stabilize flame.
(53) The burner 3 was a line burner having a length of 1 m comprising a plurality of nozzles having a cross-sectional shape as illustrated in
(54) Further, Table 1 also lists the ratio of a flow rate of fuel gas in the main burner part and a flow rate of fuel gas in the sub burner part (flow rate ratio of fuel gas) in each of the burner 2 and the burner 3.
(55) TABLE-US-00001 TABLE 1 Nozzle width Total cross-sectional Flow rate Straight Cone Nozzle diameter Number of area of a discharge part ratio of part part (main burner part) nozzles (cm.sup.2) fuel gas* Burner 1 10 mm 100 mm (Slit-shaped nozzle with a length of 1 m) 100 (Straight part) — Burner 2 — — 6 mm 120 33.8 (Main burner part) 75:25 Burner 3 — — 6 mm 50 14.1 (Main burner part) 75:25 *a ratio of a flow rate of fuel gas in a main burner part and a flow rate of fuel gas in a sub burner part
(56) The evaluation was performed in a combustion furnace for experiments with a combustion space of 1.4 m×1.4 m×0.4 m. The flow rate of fuel gas and the flow rate of air for combustion were increased while the ratio of the flow rates of the fuel gas and the air for combustion was kept constant, and the maximum discharge speed at which flame could be held without flame blowoff was measured.
(57) As the fuel gas, M gas (mixed gas of coke oven gas and blast furnace gas), which was a by-product in steelworks, was used. The main components of the M gas were H.sub.2: 26.5%, CO: 17.6%, CH.sub.4: 9.1%, and N.sub.2: 30.9%.
(58) The measurement results are illustrated in
(59) From the above results, it is found that our burner can achieve stable combustion at an extremely higher discharge speed than that of conventional burners. When our heating device is actually used in industries at almost the maximum flow speed which would cause no blowoff, the blowoff risk may be enhanced by fluctuations in the operation of a supply system. Therefore, the burner is preferably used at a flow speed less than the maximum flow speed which would cause no blowoff.
EXAMPLES
Example 1
(60) Using, as a burner for an ignition furnace, the burner which can hold flame under the condition that the flow speed of fuel gas is high, and a conventional burner, the effect of the flow speed of fuel gas on quality of sintered ore was evaluated.
(61) Using a downward suction-type Dwight Lloyd sintering machine having a palette width of 4 m and an effective area of 295 m.sup.2, sintered ore was manufactured from raw material with the same grade (using iron ore of one brand, mix proportion of quicklime: 2.3%, water: 7.5%, the thickness of a raw material charged layer: 580 mm). The manufactured sintered ore was cooled by a cooler, and then separated using a sieve with a mesh size of 75 mm into lumps of sintered ore having a size of more than 75 mm and sintered ore having a size of 75 mm or less. The lumps were crushed and subsequently mixed with the sintered ore having a size of 75 mm or less. The mixed sintered ore was separated using a sieve with a mesh size of 5 mm into sintered ore products having a size of more than 5 mm and generated powder having a size of 5 mm or less. Then, the “powder generating rate” was evaluated which is defined as a mass ratio (%) of the generated powder with a size of 5 mm or less to the total production of sintered ore (total mass of the products with a size of more than 5 mm and the generated powder with a size of 5 mm or less).
(62) An ignition furnace had a line burner having burners linearly disposed in a palette width direction or had a slit burner disposed so as to cover the whole palette width. The burner had a discharge opening of fuel gas disposed 0.4 m above a raw material charged layer. The burner 1 was a conventional typical premixing combustion burner (slit burner) as illustrated in
(63) The measurement results are listed in Table 2 and illustrated in
(64) TABLE-US-00002 TABLE 2 Nozzle Number of Flow Powder Burner diameter nozzles speed generating No. type (mm) (number/m) (Nm/s) rate (%) Remarks 1 Burner 1 Slit-shaped with a nozzle width of 10 mm 8.6 33.1 Comparative Example 2 Burner 2 6 120 25.6 32.6 Comparative Example 3 Burner 3 9 40 34.1 32.8 Comparative Example 4 Burner 3 9 30 45.5 30.6 Example 5 Burner 3 6 50 55.6 30.9 Example 6 Burner 3 6 50 57.9 29.9 Example 7 Burner 3 6 50 61.3 28.6 Example 8 Burner 3 6 40 76.5 28.2 Example
(65)
Example 2
(66) Next, to investigate a reason that a high flow speed of fuel gas enables uniform ignition of a raw material layer and thus increase the strength of sintered ore, the inventors examined the heating power of a burner and temperature distribution.
(67) Using the same measurement device as that in the measurement of
(68) Further, during the measurement, the distribution of flame temperature in the burner 1 and the burner 3 was measured using a thermocouple, and according to the measurement, isotherms were created in a cross-sectional direction of the burners.
REFERENCE SIGNS LIST
(69) 1 burner 10 burner body 20 main burner part 21 fuel gas nozzle 22 air nozzle 23 pressure equalizing chamber 30 sub burner part 31 porous plate 33 space 40 recessed part 41 bottom part 42 tapered part 50 sub burner flame 60 flame 100 premixing combustion burner 101 fuel gas 102 air 103 flame