Fluorescent glue for LED lighting bar and LED bulb lamp using the LED lighting bar
10989402 · 2021-04-27
Assignee
Inventors
Cpc classification
H01L2933/0091
ELECTRICITY
F21K9/232
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F21V29/00
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F21Y2115/10
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F21K9/66
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F21V29/70
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
International classification
F21V29/70
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
H01L25/075
ELECTRICITY
F21K9/66
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F21K9/232
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
C09K11/02
CHEMISTRY; METALLURGY
Abstract
Disclosed is a fluorescent glue for an LED lighting bar, and an LED bulb lamp, the fluorescent glue comprises a phosphor, a heat radiation material having a refractive index larger than 1.4 and a heat emissivity larger than 0.8, and a colloid, the heat radiation material accounts for 0.5% to 10% by weight of the fluorescent glue, the phosphor accounts for 25% to 45% by weight of the fluorescent glue, and the colloid accounts for 45% to 74.5% by weight of the fluorescent glue. The fluorescent glue combined with the heat radiation material can directly convert heat generated by an LED chip and the fluorescent glue into infrared waves that are radiated into the surrounding environment, without additionally providing a heat dissipating device or spraying a heat dissipating coating.
Claims
1. A fluorescent glue for an LED lighting bar, the fluorescent glue is used to coat on light-emitting surface of LED lighting bar, comprising: a phosphor; a heat radiation material having a refractive index larger than 1.4 and a heat emissivity larger than 0.8; and a colloid; the heat radiation material accounts for 0.5% to 10% by weight of the fluorescent glue, the phosphor accounts for 25% to 45% by weight of the fluorescent glue, and the colloid accounts for 45% to 74.5% by weight of the fluorescent glue; the heat radiation material having a refractive index larger than 1.4 and a heat emissivity larger than 0.8 is formed by covalently bonding mica powder with one or more of boron nitride, aluminum oxide, silicon oxide or calcium fluoride.
2. The fluorescent glue for an LED lighting bar according to claim 1, wherein the phosphor is any combination of YAG-series yellow powder, YAG-series yellow green powder, or silicate-series yellow powder, silicate-series yellow green powder, silicate-series orange powder, or nitride-series red powder, nitrogen oxide-series red powder, or YAG-series phosphors, silicate-series phosphors, nitride-series phosphors, and oxynitride-series phosphors, and the phosphor has a particle size of 5 to 20 μm.
3. The fluorescent glue for an LED lighting bar according to claim 1, wherein the colloid is selected from one or more of an organic silica gel, an epoxy resin, a modified epoxy resin, a plastic, a transparent glue, a transparent paint and a polymer.
4. The fluorescent glue for an LED lighting bar according to claim 1, wherein the colloid is a methyl-based organic silica gel or a phenyl-based organic silica gel.
5. The fluorescent glue for an LED lighting bar according to claim 1, further comprising at least one additive of a dispersing agent, an assistant dispersing agent, a coupling agent, and an anti-sludging agent.
6. An LED bulb lamp, comprising: a sealed light-transmissive bulb shell; an LED lighting bar located in the light-transmissive bulb shell; a high thermal-conductive gaseous medium located inside the light-transmissive bulb shell; a light-emitting surface of the LED lighting bar is provided with a fluorescent glue for an LED lighting bar according to claim 1, and the high thermal-conductive gaseous medium is helium gas, or hydrogen gas, or a mixed gas of helium gas and hydrogen gas.
7. The LED bulb lamp according to claim 6, wherein the light-transmissive bulb shell is a silicate-based glass bulb shell having an infrared transmittance larger than 0.8.
8. The LED bulb lamp according to claim 7, wherein the LED bulb lamp is an A-type bulb lamp, a G-type bulb lamp, a PAR-type bulb lamp, a T-type bulb lamp, a C-type bulb lamp, a P-type bulb lamp, a PS-type bulb lamp, a BR-type bulb lamp, an ER-type bulb lamp, a BRL-type bulb lamp or a street lamp.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
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DESCRIPTION OF THE DRAWING REFERENCE SIGNS
(20) 1, first LED lighting bar; 2, second LED lighting bar; 3, third LED lighting bar; 4, fourth LED lighting bar; 5, fifth LED lighting bar; 6, sixth LED lighting bar; 7, seventh LED lighting bar; 8, eighth LED lighting bar; 101, metal substrate; 102, LED chip; 103, first fluorescent glue; 203, second fluorescent glue; 303, third fluorescent glue; 403, fourth fluorescent glue; 301, transparent substrate; 901, light-transmissive bulb shell; 10, core column; 11, metal wire; 12, electrical connection wire; 13, exhaust pipe; 14, vacuum sealed cavity; 15, lamp cap; 16, drive power supply; 17, transparent ceramic tube; 18, LED flip chip.
DETAILED DESCRIPTION OF THE INVENTION
(21) Implementations of the present invention are described in detail below, and the examples of the implementations are illustrated in the drawings, where the same or similar reference numerals throughout indicate the same or similar elements or elements having the same or similar functions. The implementations described below with reference to the drawings are exemplary, only intended to be illustrative of the present invention and not to be construed as limiting to the present invention.
(22) In the description of the present invention, it should be understood that orientation or position relationships indicated by the terms such as “center”, “longitudinal”, “transverse”, “length”, “width”, “thickness”, “up”, “down”, “front”, “rear”, “left”, “right”, “vertical”, “horizontal”, “top”, “bottom”, “inside”, and “outside” are based on orientation or position relationships shown in the accompanying drawings, and are used only for ease and brevity of illustration and description of the present invention, rather than indicating or implying that the mentioned device or component must have a particular orientation or must be constructed and operated in a particular orientation. Therefore, such terms should not be construed as limiting to the present invention. In the description of the present invention, it should be noted that unless otherwise explicitly specified or defined, the terms such as “mount”, “connect”, and “connection” should be understood in a broad sense. For example, the connection may be a fixed connection, a detachable connection, or an integral connection; or the connection may be a mechanical connection or an electrical connection; or the connection may be a direct connection, an indirect connection through an intermediary, or internal communication between two components. A person of ordinary skill in the art may understand the specific meanings of the foregoing terms in the present invention according to specific situations.
(23) In the present invention, unless otherwise explicitly specified or defined, the expression that a first feature is “on” or “beneath” a second feature may include that the first and second features are in direct contact, and may also include that the first and second features are not in direct contact but contact through additional features therebetween. Moreover, the expression that the first feature is “above” and “over” the second feature includes that the first feature is right above and diagonally above the second feature, or merely indicates that the first feature level is higher than the second feature. Moreover, the expression that the first feature is “below” and “under” the second feature includes that the first feature is right below and diagonally below the second feature, or merely indicates that the first feature level is lower than the second feature.
(24) The following disclosure provides many different implementations or examples for implementing different structures of the present invention. In order to simplify the disclosure of the present invention, the components and arrangements of specific examples are described below. Of course, they are merely examples and are not intended to limit the present invention. In addition, the present invention may repeat reference numbers and/or reference letters in various examples, which are for the purpose of simplicity and clarity, and do not indicate a relationship between various implementations and/or arrangements discussed. In addition, the present invention provides examples of various specific processes and materials, but a person of ordinary skill in the art will recognize the application of other processes and/or the use of other materials.
(25) The present invention provides a fluorescent glue for an LED lighting bar. The fluorescent glue comprises a phosphor, a heat radiation material having a refractive index larger than 1.4 and a heat emissivity larger than 0.8, and a colloid. The heat radiation material accounts for 0.5% to 10% by weight of the fluorescent glue, the phosphor accounts for 25% to 45% by weight of the fluorescent glue, and the colloid accounts for 45% to 74.5% by weight of the fluorescent glue. The fluorescent glue combined with the heat radiation material can directly convert heat generated by an LED chip and the fluorescent glue into infrared waves of 2 to 20 μm, which are radiated into the surrounding environment, without additionally providing a heat dissipating device or spraying a heat dissipating coating. Further, after the light-emitting surface of the LED lighting bar is coated with the fluorescent glue provided by the present invention, heat is directly dissipated by the fluorescent glue. It is unnecessary to provide a heat dissipation layer on the back of a substrate and 4π light emitting is realized, and the heat dissipation performance is good, which not only solves the problem of poor heat dissipation performance of the existing 4π light-emitting LED lighting bar, but also solves the problem that the existing 2π light-emitting LED lighting bar can only emit light at 180 degrees.
(26) In the process of using existing LEDs, the loss of photons generated during outward emission mainly includes three aspects: (1), defects of an internal structure of a chip and absorption of materials; (2), reflection losses caused by photons at an exit interface due to a refractive index difference; (3), total reflection losses caused by the fact that an angle of incidence is larger than a critical angle of total reflection. Therefore, a lot of light cannot be emitted from the chip to the outside. The prior art generally coats the surface of a chip with a silica gel having a relatively high refractive index between the chip and air, so as to effectively reduce the loss of photons at the interface, and improve the light extraction efficiency. This layer of silica gel is usually combined with a phosphor layer. The heat radiation material provided by the present invention has a refractive index larger than 1.4, and can also play the same role as the silica gel, effectively reducing the loss of photons at the interface, thereby improving the light extraction efficiency. Besides, a scattering particle layer can also be formed, so as to enhance the heat dissipation intensity of light, so that the light is re-reflected as much as possible and excites complementary color particles of the light to emit light, thereby increasing the luminous efficiency.
(27) The present invention selects a heat radiation material having a refractive index larger than 1.4 and a heat emissivity larger than 0.8, which not only can achieve the effect of radiation heat dissipation, but also has a higher refractive index, thereby avoiding the influence on the luminous effect of the LED lighting bar. Preferably, the heat radiation material may be selected from a heat radiation material known to exhibit excellent heat radiation properties, light transmission properties, etc., such as one or more of mica powder, boron nitride, aluminum oxide, silicon oxide or calcium fluoride.
(28) Further, the heat radiation material may be formed by covalently bonding mica powder with one or more of boron nitride, aluminum oxide, silicon oxide or calcium fluoride. The mica powder bonded with other heat radiation materials has a more stable structure, and the mica powder can also be used as a good dispersing agent and coupling agent to uniformly disperse the heat radiation material and the phosphor into the colloid.
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(30) Preferably, the mica powder is any one of white mica powder (muscovite), sericite powder, Nano-mica powder or modified mica powder.
(31) Further, in order to avoid interference with the light-emitting surface of the LED lighting bar, the heat radiation material may have a particle size of 200 nm to 100 μm.
(32) Preferably, the phosphor may be any combination of YAG-series yellow powder, YAG-series yellow green powder, or silicate-series yellow powder, silicate-series yellow green powder, silicate-series orange powder, or nitride-series red powder, nitrogen oxide-series red powder, or YAG-series phosphors, silicate-series phosphors, nitride-series phosphors, and oxynitride-series phosphors, and the phosphor has a particle size of 5 to 20 μm.
(33) In practical applications, the colloid is selected from one or more of an organic silica gel, an epoxy resin, a modified epoxy resin, a plastic, a transparent glue, a transparent paint and a polymer.
(34) Preferably, the colloid is a methyl-based organic silica gel or a phenyl-based organic silica gel. An ambient temperature of about 250° C. is applicable when the methyl-based organic silica gel is selected, and an ambient temperature of about 200° C. is applicable when the phenyl-based organic silica gel is selected.
(35) The fluorescent glue for an LED lighting bar further comprises at least one additive of a dispersing agent, an assistant dispersing agent, a coupling agent, and an anti-sludging agent, which may be an additive known in the prior art or sold for a fluorescent glue for an LED lighting bar.
(36) As the dispersing agent in the additive, any dispersing agent suitable for the fluorescent glue for an LED lighting bar can be used, which is not particularly limited. The dispersing agent may be, for example, an acrylic dispersing agent, a styrene-based dispersing agent, a polyolefin-based dispersing agent, an acrylate-ester-based dispersing agent, a polyacetal-based dispersing agent, a polycarbonate-ester-based dispersing agent, a polyacrylate-ester-based dispersing agent, a polyamide-based dispersing agent, a polyamideimide-based dispersing agent, a polyarylsulfone-based dispersing agent, a polyetherketone-based dispersing agent, a polytriazole-based dispersing agent, a polysulfone-based dispersing agent, a polyurethane-based dispersing agent, a polyethersulfone-based dispersing agent, or the like.
(37) Several examples are provided below to aid in the understanding of the present invention.
Embodiment 1
(38) Raw materials: in terms of mass percentage, 5 g of sericite powder, 25 g of yellow YAG phosphor, and 70 g of methyl-based organic silica gel. The sericite powder and the yellow YAG phosphor are pulverized separately until the mica powder has a particle size of 5 μm and the yellow YAG phosphor has a particle size of 5 μm. The above components are thoroughly mixed with the methyl-based organic silica gel, and stirred under vacuum for 1 hour to obtain a target fluorescent glue.
(39) As shown in
Embodiment 2
(40) Raw materials: in terms of mass percentage, 6 g of aluminum oxide powder, 25 g of yellow green YAG phosphor, and 69 g of methyl-based organic silica gel. The aluminum oxide powder and the yellow YAG phosphor are pulverized separately until the aluminum oxide powder has a particle size of 1 μm and the yellow YAG phosphor has a particle size of 1 μm. The above components are thoroughly mixed with the methyl-based organic silica gel, and stirred under vacuum for 1.5 hours to obtain a target fluorescent glue.
(41) As shown in
Embodiment 3
(42) Raw materials: in terms of mass percentage, 3 g of sericite powder, 3 g of aluminum oxide powder, 35 g of yellow YAG phosphor, and 59 g of methyl-based organic silica gel. The sericite powder, the aluminum oxide powder and the yellow YAG phosphor are pulverized separately until the sericite powder has a particle size of 300 nm, the aluminum oxide powder has a particle size of 300 nm and the yellow YAG phosphor has a particle size of 5 μm. The sericite powder and the aluminum oxide powder are mixed and sintered at a sintering temperature of 600° C., and the sintered mixed powder was thoroughly mixed with the yellow YAG phosphor and the organic silica gel, and stirred under vacuum for 2 hours to obtain a target fluorescent glue.
(43) As shown in
Embodiment 4
(44) Raw materials: in terms of mass percentage, 5 g of modified mica powder, 4 g of boron nitride powder, 30 g of silicate-series phosphor, 1 g of acrylic dispersing agent, and 60 g of modified epoxy resin. The modified mica powder, the boron nitride powder and a yellow YAG phosphor are pulverized separately until the modified mica powder has a particle size of 400 nm, the boron nitride powder has a particle size of 400 nm and the silicate-series phosphor has a particle size of 10 μm. The modified mica powder and the boron nitride powder are mixed and sintered at a sintering temperature of 500° C., and the sintered mixed powder was thoroughly mixed with the silicate-series phosphor, the modified epoxy resin gel and the acrylic dispersing agent, and stirred under vacuum for 2 hours to obtain a target fluorescent glue.
(45) As shown in
(46) The present invention also provides an LED bulb lamp. As shown in
(47) Preferably, the light-transmissive bulb shell (901) is a silicate-based glass bulb shell having an infrared transmittance larger than 0.8, so that the converted infrared wave can be directly spread through the light-transmissive bulb shell (901).
(48) Further, the present invention does not limit the type of the LED bulb lamp. The LED bulb lamp may be an A-type bulb lamp, a G-type bulb lamp, a PAR-type bulb lamp, a T-type bulb lamp, a C-type bulb lamp, a P-type bulb lamp, a PS-type bulb lamp, a BR-type bulb lamp, an ER-type bulb lamp, a BRL-type bulb lamp or a street lamp. As shown in
(49) As shown in
(50) Referring to
(51) Advantageous effects of the present invention include:
(52) The disclosure of the present invention is good in heat dissipation effect. The present invention provides a fluorescent glue for an LED lighting bar and the LED bulb lamp, wherein the fluorescent glue combined with the heat radiation material can directly convert heat generated by an LED chip and the fluorescent glue into infrared waves of 2 to 20 μm, which are radiated into the surrounding environment, without additionally providing a heat dissipating device or spraying a heat dissipating coating. Further, after the light-emitting surface of the LED lighting bar is coated with the fluorescent glue provided by the present invention, heat is directly dissipated by the fluorescent glue without providing a heat dissipation layer on the back of a substrate for realizing 4π light emitting. And the LED lighting bar coated with the fluorescent glue provided by the present invention has good heat dissipation performance, which not only solves the problem of poor heat dissipation performance of the existing 4π light-emitting LED lighting bar, but also solves the problem that the existing 2π light-emitting LED lighting bar can only emit light at 180 degrees.
(53) Furthermore, the LED bulb lamp provided by the present invention is provided with a fluorescent glue for an LED lighting bar as described above on the light-emitting surface of the built-in LED lighting bar. On the one hand, heat can be converted into an infrared wave of 2 to 20 μm first, and then transmitted to the surrounding environment through a silicate-based glass bulb shell having an infrared transmittance larger than 0.8. On the other hand, the heat can also be conducted to the glass bulb shell by gas convection through a high thermal-conductive gas medium in the bulb shell, so as to be conducted into the surrounding environment, thereby achieving all-round heat dissipation.
(54) The disclosure of the present invention has high luminous efficiency. The heat radiation material in the fluorescent glue described in the present invention has a high refractive index and a small particle size, and does not affect the light emission of LEDs. Further, the heat radiation material can form a scattering particle layer, so as to enhance the heat dissipation intensity of blue light, so that the blue light is re-reflected as much as possible, and complementary color particles of the blue light are excited to emit light, thereby increasing the luminous efficiency.
(55) It is to be understood that the application of the present invention is not limited to the above examples, and a person of ordinary skill in the art can make modifications or changes in accordance with the above description, all of which are within the scope of protection of the appended claims of the present invention.