Radial flow adsorption vessel comprising flexible screen
10994238 · 2021-05-04
Assignee
Inventors
- Micah S. Kiffer (Kutztown, PA, US)
- Christopher Michael O'Neill (Allentown, PA, US)
- Stephen Clyde Tentarelli (Schnecksville, PA, US)
Cpc classification
B01J2208/00884
PERFORMING OPERATIONS; TRANSPORTING
B01D2253/204
PERFORMING OPERATIONS; TRANSPORTING
Y02C20/40
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
B01J8/0214
PERFORMING OPERATIONS; TRANSPORTING
B01J8/008
PERFORMING OPERATIONS; TRANSPORTING
International classification
Abstract
The present invention pertains to a radial flow adsorption vessel comprising a cylindrical outer shell and at least one cylindrical porous wall disposed co-axially inside the shell, wherein inside the shell one or more fluid permeable screens are rigidly connected to the at least one cylindrical porous wall, by a multitude of separate standoff elements so that the screen has a cylindrical shape co-axial to the shell, and to an adsorption process using the radial flow adsorption vessel.
Claims
1. A radial flow adsorption vessel comprising: a cylindrical outer shell and at least an inner and an outer porous cylindrical wall disposed co-axially inside the shell, wherein inside the shell one or more fluid permeable screens are rigidly connected to at least one of the porous walls by a multitude of separate standoff elements so that the one or more screens has a cylindrical shape co-axial to the shell.
2. Radial flow adsorption vessel according to claim 1 wherein the one or more screens comprises a mesh wire, woven wire cloth or an expanded metal.
3. Radial flow adsorption vessel according to claim 1 wherein the one or more screens comprises a material having a stiffness of less than 35 Nm.
4. Radial flow adsorption vessel according to claim 2 wherein the one or more screens comprises a material having a stiffness of less than 35 Nm.
5. Radial flow adsorption vessel according to claim 1 wherein the standoff elements are mounted so that they have their smallest extension in the plane perpendicular to a filling direction of the adsorbent particles.
6. Radial flow adsorption vessel according to claim 1 wherein the edges of the standoff elements pointing in a filling direction of the adsorbent particles are tapered.
7. Radial flow adsorption vessel according to claim 1 wherein the separate standoff elements are disposed in a grid along the longitudinal and circumferential directions of the cylinder formed by the screen.
8. Radial flow adsorption vessel according to claim 1 wherein the lengths of the individual standoff elements are selected so that a uniform radial distance between a first screen and at least one adjacent screen or porous wall is obtained.
9. Radial flow adsorption vessel according to claim 1 wherein the standoff elements are disposed equidistantly to each other in longitudinal direction and/or in circumferential direction.
10. Radial flow adsorption vessel according to claim 1 wherein an outermost and an innermost annular segment defined in the vessel form channels for fluid flow to and from the vessel.
11. Radial flow adsorption vessel according to claim 1 wherein at least one annular segment defined in the vessel is filled with adsorbent particles.
12. Radial flow adsorption vessel according to claim 1 wherein a support plate is provided at the bottom of the shell to which the bottom end(s) of porous wall(s) and the one or more screens are rigidly connected.
13. Radial flow adsorption vessel according to claim 1 wherein one or more of the fluid permeable screens is free-standing at the top or wherein one or more of the fluid permeable screens is fixed to the top of the vessel.
14. An adsorption process wherein a radial flow adsorption vessel according to claim 1 is used.
15. Adsorption process according to claim 14 wherein the process is a pressure and/or vacuum swing adsorption process.
16. A radial flow adsorption vessel comprising: a cylindrical outer shell and at least one cylindrical porous wall disposed co-axially inside the shell, wherein inside the shell one or more fluid permeable screens are rigidly connected to the at least one porous wall by a multitude of separate standoff elements so that the one or more screens has a cylindrical shape co-axial to the shell and wherein the one or more screens comprises a mesh wire, woven wire cloth or an expanded metal.
17. Radial flow adsorption vessel according to claim 16, wherein the one or more screens comprises a material having a stiffness of less than 35 Nm.
18. A radial flow adsorption vessel comprising: a cylindrical outer shell and at least one cylindrical porous wall disposed co-axially inside the shell, wherein inside the shell one or more fluid permeable screens are rigidly connected to the at least one porous wall by a multitude of separate standoff elements so that the one or more screens has a cylindrical shape co-axial to the shell, and wherein the one or more screens comprises a material having a stiffness of less than 35 Nm.
19. Radial flow adsorption vessel according to claim 18 wherein the standoff elements are mounted so that they have their smallest extension in the plane perpendicular to a filling direction of the adsorbent particles.
20. Radial flow adsorption vessel according to claim 18 wherein an outermost and an innermost annular segment defined in the vessel form channels for fluid flow to and from the vessel.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) The present invention will hereinafter be described in conjunction with the appended figures wherein like numerals denote like elements:
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DETAILED DESCRIPTION
(12)
(13) In all embodiments of the radial flow adsorption vessel as depicted in
(14) Furthermore, in all embodiments of the radial flow adsorption vessel as depicted in
(15) In all embodiments of the radial flow adsorption vessel as depicted in
(16) The (intermediate) screen(s) in all embodiments of the radial flow adsorption vessel as depicted in
(17) Finally, in all embodiments of the radial flow adsorption vessel as depicted in
(18) Referring to
(19) A plurality of standoff elements 29 are affixed at a first end to the outer porous wall 19 and at a second end to the intermediate screen 21. The plurality of standoff elements 29 provide the necessary strength and rigidity to intermediate screen 21 to maintain its cylindrical shape and retain a load of adsorbent within either annular segment 25 and/or 27 during filling with the adsorbent and during the adsorption process.
(20) In addition, the standoff elements all have the same length when measured from the first end to the second end creating a uniform distance between outer porous wall 19 and intermediate screen 21. Hence, annular segment 25 is controlled to have a uniform depth in fluid flow direction so that, when annular segment 25 is filled with adsorbent particles, early breakthrough of contaminants through this layer due to non-uniform bed depth is prevented and performance of the adsorption process is maintained.
(21) The intermediate screen is affixed to the vessel by a plurality of standoff elements and therefore does not need to be attached to the vessel at its upper and/or lower end. The upper end of the intermediate screen 21 may be free-standing, as shown in the figure, or may be affixed to the top of the vessel. The lower end of the intermediate screen near support plate 33 can be free or affixed to support plate 33 by a weld, adhesive, or other method.
(22) In practice, shell 13 and porous walls such as outer 19 and inner 23 may have shape imperfections such as regarding their roundness (cylindricity), straightness, and/or co-axiality with other elements of the vessel. These originate from the fabrication process of the shell and/or the porous walls/the perforated plates which may involve rolling and connecting multiple sheets of perforated plates to complete the cylindrical structural plate of a porous wall, and from the process of assembling the vessel.
(23) Vessels of the first embodiment as described above and as shown in ideal form in
(24) In this variant of the vessel in the first embodiment the length of the standoff elements may be adjusted as shown in
(25) Furthermore, in the vessel shown in
(26) As immediately apparent to the skilled person, adjustments such as made in the vessel of the above described first embodiment can be made to other embodiments of the vessel of the invention as needed.
(27) One embodiment of the standoff element design applicable to all embodiments of the radial flow adsorbtion vessel as shown in
(28) Referring to
(29) Standoff elements are installed with top face 41 perpendicular to the direction of filling with adsorbent particles, which usually coincides with the axis of the vessel 31, so that formation of voids in the adsorbent layer underneath the standoff elements during loading of the adsorbent particles is avoided as far as possible. The first end 35, second end 37 and connecting leg 39 may have constant thickness or they may be provided with tapered edges 43 at the bottom and/or top face. In the embodiment shown in
(30) As shown in
(31) When tapered edges 43 are not present, the width of first end 35, second end 37 and connecting leg 39 must be minimized to prevent the formation of voids underneath the standoff elements. In this case, there is a trade-off between the strength and stiffness of the standoff elements and the tendency to form voids.
(32) The standoff elements must have sufficient strength and stiffness to support the weight of the adsorbent bed during loading of adsorbent material without breaking or significantly deforming. The size of ends 35 and 37 are minimized to reduce shadowing effects, wherein flow is locally blocked by the ends. The shape of the standoff elements can be different from the example provided in
(33) Referring to
(34) The number and spacing of the standoff elements are chosen to provide strength and stiffness to the screen. More flexible intermediate screens will require more standoff elements, however, larger and higher numbers of standoff elements increase the overall shadowing effect on the gas flow path.
(35) Standoff elements can use any pitch layout, such as square or triangular.
(36) A second embodiment of the radial flow adsorption vessel according to the invention is illustrated in
(37) A first plurality of standoff elements 529 are affixed at a first end to the outer porous wall 19 and at a second end to first intermediate screen 21. The first plurality of standoff elements 529 provide strength and rigidity to first intermediate screen 21. In addition, the standoff elements all have the same length when measured from the first end to the second end creating a uniform distance between outer porous wall 19 and first intermediate screen 21 resulting in a uniform depth of annular segment 525 in fluid flow direction.
(38) A second plurality of standoff elements 551 are affixed at a first end to the first plurality of standoff elements 529, i.e. each element of the second plurality is affixed to an element of the first plurality with the first intermediate screen held between them, and at a second end to the second intermediate screen 547. The second plurality of standoff elements 551 provide strength and rigidity to second intermediate screen 547. In addition, the standoff elements all have the same length when measured from the first end to the second end creating a uniform distance between first intermediate screen 21 and second intermediate screen 547 which results in a uniform depth of annular segment 549 in fluid flow direction. The size, shape and number of the second plurality of standoff elements can be different from the first plurality of standoff elements.
(39) Intermediate screens 21 and 547 create three annular segments 525, 549, and 527 for filling with adsorbent particles.
(40) The upper end of the first intermediate screen 21 is not connected to the vessel. The lower end of the first intermediate screen near support plate 33 can be free or affixed to support plate 33 by a weld, adhesive, or other method. Similarly, the upper end of the second intermediate screen 547 is not connected to the vessel. The lower end of the second intermediate screen near support plate 33 can be free or affixed to support plate 33 by a weld, adhesive, or other method.
(41) A third embodiment of the radial flow adsorption vessel of the invention is illustrated in
(42) A plurality of standoff elements 629 are affixed at a first end to the outer porous wall 19 and at a second end to the first intermediate screen 21. The plurality of standoff elements 629 provide strength and rigidity to first intermediate screen 21. In addition, the standoff elements all have the same length when measured from the first end to the second end creating a uniform distance between outer porous wall 19 and first intermediate screen 21 thus controlling the annular segment 625 to have a uniform depth in fluid flow direction.
(43) A plurality of standoff elements 651 are affixed at a first end to the inner porous wall 23 and at a second end to the second intermediate screen 647. The plurality of standoff elements 651 provide strength and rigidity to second intermediate screen 647. In addition, the standoff elements all have the same length when measured from the first end to the second end creating a uniform distance between inner porous wall 23 and second intermediate screen 647 resulting in annular segment 649 to a have uniform depth in fluid flow direction. Intermediate screens 21 and 647 create three annular segments 25, 27, and 649 which are designated to be filled with adsorbent particles.
(44) The upper end of the first intermediate screen 21 is not connected to the vessel. The lower end of the first intermediate screen near support plate 33 can be free or affixed to support plate 33 by a weld, adhesive, or other method. Similarly, the upper end of the second intermediate screen 647 is not connected to the vessel. The lower end of the second intermediate screen near support plate 33 can be free or affixed to support plate 33 by a weld, adhesive, or other method.
(45) A fourth embodiment of the radial flow adsorption vessel of the invention is illustrated in
(46) A plurality of standoff elements 929 are affixed at a first end to the outer porous wall 919 and at a second end to the screen 923. The plurality of standoff elements 929 provide the necessary strength and rigidity to screen 923 to maintain its cylindrical shape and retain a load of adsorbent within annular segment 925 during filling with the adsorbent and during the adsorption process. Furthermore, screen 923 is used to create the central annulus 17. In this embodiment, the upper end of the screen 923 is closed so as to define the upper end of the central annulus 17. Alternatively, the upper end of screen 923 can be fixed to the top end of the vessel.
(47) In addition, the standoff elements all have the same length when measured from the first end to the second end creating a uniform distance between outer porous wall 919 and screen 923. Hence, annular segment 925 is controlled to have a uniform depth in fluid flow direction.
(48) The screen 923 is affixed to the vessel by a plurality of standoff elements and therefore does not need to be attached to the vessel at its upper and/or lower end. The upper end of the screen 923 is not connected to the vessel. The lower end of the screen near support plate 33 can be free or affixed to support plate 33 by a weld, adhesive, or other method.
(49) A fifth embodiment of the radial flow adsorption vessel of the invention is illustrated in
(50) A first plurality of standoff elements 1029 are affixed at a first end to the intermediate porous wall 1021 and at a second end to the screen 1019. The plurality of standoff elements 1029 provide the necessary strength and rigidity to screen 1019 to maintain its cylindrical shape and retain a load of adsorbent within annular segment 1025 during filling with the adsorbent and during the adsorption process. Furthermore, screen 1019 is used to create the outer annulus 15.
(51) A second plurality of standoff elements 1051 are affixed at a first end to the intermediate porous wall 1021 and at a second end to the screen 1023. The plurality of standoff elements 1051 provide the necessary strength and rigidity to screen 1023 to maintain its cylindrical shape and retain a load of adsorbent within annular segment 1049 during filling with the adsorbent and during the adsorption process. Furthermore, screen 1023 is used to create the central annulus 17.
(52) In addition, the standoff elements all have the same length when measured from the first end to the second end creating a uniform distance between intermediate porous wall 1021 and screens 1019 and 1023. Hence, annular segments 1029 and 1051 are controlled to have a uniform depths in fluid flow direction.
(53) The screen 1019 is attached to the shell 13 at its upper end and attached to bottom support plate 33 at its lower end. The upper end of the screen 1023 is closed so as to define the upper end of the central annulus 17.
(54) Additional embodiments of the present invention include variations of the previous embodiments as easily apparent for the skilled person. For example, in the first embodiment shown in
(55) In the second embodiment as depicted in
(56) In the embodiment shown in
(57) In any of the above embodiments, more than two pluralities of standoff elements can be incorporated into the radial vessel in order to connect screens to either screens or porous walls. For example, an additional plurality of standoff elements supporting a further screen can be used to create an annular segment that remains unfilled by adsorbent. Such an open annular segment can be used to compensate non-uniform distance between porous walls.
EXAMPLE
(58) A radial flow adsorption vessel configured like that shown in
(59) The intermediate screen consisted of a woven wire mesh material that had openings small enough to contain the smallest sieve particles.
(60) The standoff elements were made from steel channel and were welded to the outer porous wall and attached to the intermediate screen with screws.
(61) A small scale rig of screen with standoff elements was built to test strength and rigidity of the standoff concept. The test rig is 4′ (10.16 cm) high and 5′ (12.7 cm) wide, with the screen rolled to the same radius as the actual product design. The bottom and edges were blocked with aluminum and plywood pieces. A scale was embedded in the stand at the bottom of the screen. The downward pressure on the scale was measured during filling. The curvature of the intermediate screen was measured with a contour gauge before and after filling. The load on the scale reached a constant value after the bed was filled 6-12″ (15.24 cm to 30.48 cm) high. This was a very favorable result and the result was presumably improved by the presence of the standoffs and the rough texture of the wire mesh. There was no measurable deformation of the screen (within the accuracy of the gauge, which was about 1/32″ (1/12.6 cm).