METHOD FOR PRODUCING A SEALING ELEMENT ON A GAS DIFFUSION LAYER OF AN ELECTROCHEMICAL UNIT AND ASSEMBLY OF A GAS DIFFUSION LAYER AND A SEALING ELEMENT
20210126267 ยท 2021-04-29
Inventors
Cpc classification
C25B9/17
CHEMISTRY; METALLURGY
Y02E60/50
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
H01M8/0273
ELECTRICITY
B29C45/14836
PERFORMING OPERATIONS; TRANSPORTING
International classification
Abstract
A method for producing a sealing element on a gas diffusion layer of an electrochemical unit including the following is provided: arranging an injection molding tool on the gas diffusion layer; and introducing injection molding material into a cavity of the injection molding tool. The injection molding tool includes at least one deformation delimiting element, which delimits or prevents a deformation of the gas diffusion layer during the introduction of the injection molding material into the cavity such that damage to the gas diffusion layer is avoided and a sealing element with a mechanically stable connection region is produced.
Claims
1. A method for producing a sealing element on a gas diffusion layer of an electrochemical unit, the method comprising the following: arranging an injection molding tool on the gas diffusion layer; introducing injection molding material into a cavity of the injection molding tool; wherein the injection molding tool comprises at least one deformation delimiting element, which delimits or prevents a deformation of the gas diffusion layer during the introduction of the injection molding material into the cavity.
2. The method in accordance with claim 1, wherein the injection molding tool comprises at least one pressing tool part that has a pressing projection for pressing the gas diffusion layer.
3. The method in accordance with claim 2, wherein the deformation delimiting element is formed separate from the pressing tool part.
4. The method in accordance with claim 3, wherein the deformation delimiting element is in contact with the pressing projection of the pressing tool part during the introduction of the injection molding material into the cavity of the injection molding tool.
5. The method in accordance with claim 3, wherein the deformation delimiting element is at a distance from the pressing projection of the pressing tool part during the introduction of the injection molding material into the cavity of the injection molding tool.
6. The method in accordance with claim 1, wherein the deformation delimiting element is arranged above or below a penetration region of the gas diffusion layer in a thickness direction of the gas diffusion layer, said penetration region being penetrated by the injection molding material during the introduction of the injection molding material into the cavity.
7. The method in accordance with claim 1, wherein the deformation delimiting element contacts the gas diffusion layer before the introduction of the injection molding material into the cavity of the injection molding tool.
8. The method in accordance with claim 1, wherein the deformation delimiting element is at a distance from the gas diffusion layer before the introduction of the injection molding material into the cavity of the injection molding tool.
9. The method in accordance with claim 1, wherein a plurality of deformation delimiting elements are provided, which are spaced at a distance from each other along a peripheral direction of the gas diffusion layer.
10. The method in accordance with claim 1, wherein at least one deformation delimiting element is provided, which has a height that varies along a peripheral direction of the gas diffusion layer and/or the outer rim thereof has a distance from an outside rim of the gas diffusion layer that varies along a peripheral direction of the gas diffusion layer.
11. The method in accordance with claim 1, wherein at least one deformation delimiting element is arranged on a part of the injection molding tool so as to be moveable relative to the respective part of the injection molding tool and is moved relative to the respective part of the injection molding tool in order to release the gas diffusion layer and/or the sealing element produced by injection molding from the respective part of the injection molding tool.
12. The method in accordance with claim 1, wherein at least one deformation delimiting element projects beyond an outside rim of the gas diffusion layer.
13. An assembly of an electrochemical device, comprising a gas diffusion layer and a sealing element fixed to the gas diffusion layer that comprises a sealing region located outward from an outside rim of the gas diffusion layer and a connection region located inward from the outside rim of the gas diffusion layer, wherein the connection region is provided with at least one recess on an inside rim of the connection region and/or outward from the inside rim of the connection region.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
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[0092] The same or functionally equivalent elements are provided with the same reference numerals in all Figures.
DETAILED DESCRIPTION OF THE INVENTION
[0093] Depicted in
[0094]
[0095] The pressing tool part 106 and the supporting tool part 108 together enclose a cavity 110 into which an injection molding material in a flowable state is introduced during the injection molding operation.
[0096] The gas diffusion layer 102 projects into said cavity 110.
[0097] The pressing tool part 106 has a pressing projection 112, which is provided with a pressing edge 114.
[0098] The gas diffusion layer 102 placed in the injection molding tool 104, which is mechanically compressible in its thickness direction 117 (in the assembled state of the electrochemical device in parallel to the stacking direction of the electrochemical device), is pressed locally by means of the pressing edge 114. As a result, the capillary pressure in the pores of the porous gas diffusion layer 102 rises locally, and the penetration of the gas diffusion layer 102 with the injection molding material is delimited in the x and y directions perpendicular to the thickness direction (z direction).
[0099] Upon producing the sealing element 100 by means of an injection molding process in the injection molding tool 104, very high injection pressures arise in the cavity 110 of the injection molding tool 104.
[0100] If the injection point or the injection points through which the injection molding material is introduced into the cavity 110 are located outside of the connection regions between the sealing element 100 and the gas diffusion layer 102, the gas diffusion layer 102 may fold over, i.e., deform, in said connection regions during the filling of the cavity 110 of the injection molding tool 104 with the injection molding material.
[0101] The deformed state caused by the injection molding material introduced into the cavity 110 is depicted in
[0102] As a result of this deformation process, the gas diffusion layer 102 is locally brought out of its initial planar form and is subjected to bending stress.
[0103] The gas diffusion layer 102 may be damaged, for example by breaking, as a result of the bending of the gas diffusion layer 102 in the deformed connection region.
[0104] In addition, if the gas diffusion layer 102 is severely deformed, the connection region may be mechanically weakened by the gas diffusion layer 102 projecting into the connection region 116, which is located above the gas diffusion layer 102 in the thickness direction 117 and is also referred to as a connecting lip 118, and thus prevents the flow of (in particular elastomeric) injection molding material in this region.
[0105] It is then not ensured that the cavity 110 of the injection molding tool 104 is completely filled in the region of the connecting lip 118, thus increasing the risk of mechanical damage to the connection region 116 of the sealing element 100, in particular due to crack formation.
[0106] After the introduction of the injection molding material into the cavity 110 of the injection molding tool 104 and the injection molding material cures to form the sealing material of the sealing element 100, the production of the sealing element 100 on the gas diffusion layer 102 and thus the formation of an assembly 120, which comprises the gas diffusion layer 102 and the sealing element 100 fixed to the gas diffusion layer 102 and is also referred to as a seal-on-GDL unit 122, is complete.
[0107] After opening the injection molding tool 104, by removing the pressing tool part 106 from the supporting tool part 108, the assembly 120 can be used in assembling the membrane electrode arrangement and the mounting of the electrochemical device.
[0108] The sealing element 100 of the finished assembly 120 comprises a sealing region 124 with a sealing lip 126, a penetration region 128, in which the injection molding material has penetrated into the porous material of the gas diffusion layer 102 and which extends from an outside rim 130 of the gas diffusion layer 102 inward into the region of the pressing edge 114, and a connection region 116 in the form of a connecting lip 118, located outside of the gas diffusion layer 102, above and/or below the gas diffusion layer 102 in the thickness direction 117.
[0109] In the method in accordance with the invention for producing the sealing element 110 on the gas diffusion layer 102, which method is schematically depicted in
[0110] In the depicted embodiment, the deformation delimiting elements 132 are formed separate from the pressing tool part 106 and separate from the supporting tool part 108 of the injection molding tool 104.
[0111] The deformation delimiting elements 132 may in principle also be formed in one piece with another constituent part of the injection molding tool 104, for example with the pressing tool part 106 or with the supporting tool part 108.
[0112] In the embodiment in accordance with
[0113] Further, the deformation delimiting elements 132 already contact the gas diffusion layer 102 on its main face 136 facing toward the pressing edge 114 before the introduction of the injection molding material into the cavity 110 of the injection molding tool 104.
[0114] An outer rim 138 of each deformation delimiting element 132, which is remote from the pressing edge 114, is arranged between the outside rim 130 of the gas diffusion layer 102 on the one hand and the pressing edge 114 of the injection molding tool 104 on the other hand, such that the deformation delimiting elements 132 do not completely cover the region of the gas diffusion layer 102 the projects into the cavity 110 of the injection molding tool 104.
[0115] The deformation delimiting elements 132 arranged in the injection molding tool 104 in the connection region between the gas diffusion layer 102 and the sealing element 100 prevent the gas diffusion layer 102 from deforming during the introduction of the injection molding material into the cavity 110 of the injection molding tool 104 under the occurring internal pressure of the tool or injection pressure, as is depicted in
[0116] It is hereby achieved that the regions of the cavity 110 located outside of the deformation delimiting elements 132 are completely filled with the injection molding material. The risk of mechanical damage to the connection region 116 of the sealing element 100, in particular a crack formation, is hereby reduced.
[0117] In addition, damage to the gas diffusion layer 102 caused by a bending stress due to a deformation of the gas diffusion layer 102 is avoided.
[0118] As can be seen in
[0119] As can be seen in
[0120] Arranged between the recesses 142 in the connection region 116 of the sealing element 100 are stabilization regions 146, in which the sealing element 100 has a greater material thickness than in the region of the recesses 142, such that the stabilization regions 146 provide for a mechanical connection of the sealing element 100 to the gas diffusion layer 102.
[0121] The position of the outside rim 130 of the gas diffusion layer 102 is indicated in
[0122] The position of the rounded tip of the sealing lip 126 of the sealing element 100 is indicated in
[0123] The alternative assembly 120 of a gas diffusion layer 102 and a sealing element 100, shown in
[0124] Located between the recesses 142 are stabilization regions 146 in which the cured injection molded material of the sealing element 100 provides for a good mechanical connection of the sealing element 100 to the gas diffusion layer 102.
[0125] The outside rim of the gas diffusion layer 102 is enclosed with sealing material, i.e., with cured injection molding material, across the entire periphery of the gas diffusion layer 102.
[0126] The connection region 116 of the sealing element 100 produced in that way comprises a likewise wave-shaped inside rim 140, which is formed complementarily to the outer rim of the deformation delimiting element 132.
[0127] In addition, in this embodiment of the production method, the wave-shaped deformation delimiting element 132 extends, at least in sections, outward across the outside rim 130 of the gas diffusion layer 102, such that in the finished assembly 120, the outside rim 130 of the gas diffusion layer 102 intersects the inside rim 140 of the connection region 116 of the sealing element 100, seen along the thickness direction 117 of the gas diffusion layer 102.
[0128] Because the deformation delimiting element 132 does not extend into the plane of the gas diffusion layer 102 and the sealing region 124 of the sealing element 100 directly adjoins the penetration region 128, the sealing element 100 still does not have any through-holes in the regions in which the inside rim 140 of the connection region 116 extends outward from the outside rim 130 of the gas diffusion layer 102.
[0129] The further assembly 120, shown in
[0130] Further, in this embodiment, the outer rim 138 of the deformation delimiting element 132 is always located between the outside rim 130 of the gas diffusion layer 102 and the pressing edge 114, such that in the finished assembly 120, the outside rim 130 of the gas diffusion layer 102 does not intersect the inside rim 140 of the connection region 116 of the sealing element 100, seen along the thickness direction 117 of the gas diffusion layer 102.
[0131] In the alternative method, schematically depicted in
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[0133] The connection region 116 of the sealing element 100 of this assembly 120 is provided with recesses 142, which are arranged outward from the inside rim 140 of the connection region 116 and are spaced at a distance from each other in the peripheral direction 134 of the gas diffusion layer 102.
[0134] As can be seen in
[0135] In this embodiment, the deformation delimiting elements 132 are arranged between the outside rim 130 of the gas diffusion layer 102 and the pressing edge 114 of the injection molding tool 104, such that in the finished assembly 120, the outside rim 130 of the gas diffusion layer 102 does not intersect the recesses 124 in the connection region 116 of the sealing element 100, seen along the thickness direction 117 of the gas diffusion layer 102.
[0136] In an alternative method, schematically depicted in
[0137] In this case, the deformation delimiting element 132, in the cut plane of
[0138] The finished assembly 120 produced by means of the injection molding tool 104 from
[0139] The connection region 116 of the sealing element 100 of this assembly 120 is provided with recesses 142 following one another along the peripheral direction 134 of the gas diffusion layer 102, said recesses 142 having a height (i.e., extent along the thickness direction 117 of the gas diffusion layer 102) that varies in an undulating manner.
[0140] These recesses 142 are separated from each other by stabilization regions 146 located therebetween, which also have a height that varies in an undulating manner and follow one another in the peripheral direction 134 of the gas diffusion layer 102.
[0141] An alternative embodiment, depicted sectionally in
[0142] The cross section, taken perpendicular to the thickness direction 117 of the gas diffusion layer 102, of the deformation delimiting elements 132 may, in principle, have any shape, for example a polygonal, in particular a quadrangular, for example a rectangular, shape or a shape with a curved rim line, for example an ellipse segment shape or a circle segment shape, in particular a semicircle shape.
[0143] In
[0144] However, the maximum height of the deformation delimiting element 132 is thereby smaller than the distance between the delimiting wall 148 of the pressing tool part 106 on the one hand and the main face 136 of the gas diffusion layer 102 facing toward the delimiting wall 148 on the other hand, such that the deformation delimiting element 132 does not contact the gas diffusion layer 102 before the introduction of the injection molding material into the cavity 110 of the injection molding tool 104.
[0145] In this embodiment, an outer rim 138 of the deformation delimiting element 132 is arranged between the outside rim 130 of the gas diffusion layer 102 and the pressing edge 114, in a plan view of the gas diffusion layer 102 seen along the thickness direction 117 of the gas diffusion layer 102.
[0146] The assembly 120, produced by means of the injection molding tool 104 depicted in
[0147]
[0148] In the alternative method, schematically depicted in
[0149] The displacement direction 152, which corresponds to a movement direction 154 of the respectively associated deformation delimiting element 132, is preferably oriented substantially in parallel to the thickness direction 117 of the gas diffusion layer 102.
[0150] Each plunger 150 is coupled to a movement device (not depicted), by means of which a movement of the plunger 150 along the displacement direction 152 and thus a movement of the respectively associated deformation delimiting element 132 along the movement direction 154 is producible.
[0151] Before the introduction of the injection molding material into the cavity 110 of the injection molding tool 104, the deformation delimiting elements 132 that are moveable relative to the pushing tool part 106 are brought into the rest position depicted in
[0152] When the injection molding tool 104 is opened after completion of the injection molding operation by removing the supporting tool part 108 from the pressing tool part 106, the deformation delimiting elements 132 are moved, by actuating the movement device, relative to the pressing tool part 106 against the gas diffusion layer 102 and/or against the sealing element 100 produced by injection molding, such that the gas diffusion layer 102 and/or the sealing element 100 produced by injection molding is released from the pressing tool part 106.
[0153] In this embodiment, the deformation delimiting elements 132 thus act as ejectors 156 for ejecting the gas diffusion layer 102 and/or the sealing element 100 produced thereon by injection molding from the injection molding tool 104.
[0154] The movement tool may be configured, in particular, as a hydraulic movement device, a pneumatic movement device and/or an electromotive movement device.
[0155] The coupling between the plunger 150 and the respectively associated deformation delimiting element 132 may be produced e.g., by the plunger 150 being formed in one piece with the respectively associated deformation delimiting element 132.
[0156] The extent d of the plunger 150 in a direction oriented perpendicular to the displacement direction 152 and preferably perpendicular to the peripheral direction 134 of the gas diffusion layer 102 may be smaller than the extent D of the respectively associated deformation delimiting element 132 in the same direction, as depicted in
[0157] In all other respects, the method schematically depicted in
[0158] An alternative method, depicted schematically in
[0159] In all other respects, the method schematically depicted in