SMALL SIZE LIGHT EMITING DIODES FABRICATED VIA REGROWTH
20230411554 ยท 2023-12-21
Assignee
Inventors
Cpc classification
H01L33/62
ELECTRICITY
H01L2933/0066
ELECTRICITY
H01L21/7806
ELECTRICITY
H01L33/20
ELECTRICITY
International classification
H01L33/00
ELECTRICITY
Abstract
A method for fabricating and transferring high quality and manufacturable light-emitting devices, such as small sized light-emitting diodes (mLEDs), using epitaxial lateral overgrowth (ELO) and isolation methods. III-nitride ELO layers are grown on a host substrate using a growth restrict mask, and III-nitride device layers are grown on wings of the III-nitride ELO layers. The resulting devices are isolated from the host substrate while attached by a connecting link comprising an epitaxial or non-epitaxial bridge. A regrowth is performed on selected mesas of the device layers to realize improved devices with the help of the bridge. The bridge is broken, and the devices are then plucked from the host substrate and placed on a display panel.
Claims
1. A method of preparing a device, comprising: providing island-like semiconductor layers comprising: one or more epitaxial lateral overgrowth (ELO) layers and device layers on a substrate; and a connecting link between the substrate and the ELO layers; and transferring the ELO layers and device layers to a submount by breaking the connecting link.
2. The method of claim 23, further comprising performing device fabrication before breaking the connecting link.
3. The method of claim 1, wherein the connecting link is an epitaxial bridge.
4. The method of claim 1, wherein the connecting link is a non-epitaxial bridge.
5. The method of claim 1, wherein the connecting link comprises a separation length between a light emitting aperture on the wing region of the ELO layers and an open area of the ELO layers.
6. The method of claim 5, wherein the separation length at least partially stays on the wing region of the ELO layers.
7. The method of claim 1, wherein the breaking includes fracturing and/or cleaving of the connecting link.
8. (canceled)
9. The method of claim 1, wherein the connecting link holds the ELO layers and device layers on the substrate.
10. The method of claim 1, wherein the transferring integrates the ELO layers and device layers onto a larger wafer.
11. The method of claim 2, wherein the fabricating is performed after the transferring.
12. The method of claim 1, wherein the transferring is performed using a pick-and-place method.
13. The method of claim 1, wherein the transferring is performed selectively.
14. (canceled)
15. The method of claim 1, wherein the substrate is independent of crystal orientations.
16. (canceled)
17. A method of preparing a device, comprising: providing island-like semiconductor layers comprising: one or more epitaxial lateral overgrowth (ELO) layers on a substrate; and a connecting link between the substrate and the ELO layers; performing a regrowth of one or more device layers on the ELO layers; and transferring the device layers to a submount by breaking the connecting link.
18. The method of claim 17, further comprising fabricating a light emitting aperture on a wing region of the ELO layers and device layers.
19. The method of claim 18, further comprising performing device fabrication before breaking the connecting link.
20. The method of claim 18, wherein the fabricating is performed after the transferring.
21. A device, comprising: a substrate; and one or more epitaxial lateral overgrowth (ELO) layers and device layers on the substrate; and a connection link between the substrate and the ELO layers.
22. The device of claim 21, further comprising a light emitting aperture on a wing region of the ELO layers and device layers.
23. The method of claim 1, further comprising fabricating a light emitting aperture on a wing region of the ELO layers and device layers.
24. The method of claim 2, the submount has an embedded electrode track pad.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0048] Referring now to the drawings in which like reference numbers represent corresponding parts throughout:
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DETAILED DESCRIPTION OF THE INVENTION
[0059] In the following description of the preferred embodiment, reference is made to a specific embodiment in which the invention may be practiced. It is to be understood that other embodiments may be utilized, and structural changes may be made without departing from the scope of the present invention.
[0060] Overview
[0061] The present invention describes a method of fabricating semiconductor devices, such as light emitting devices, including LEDs, wherein the semiconducting layers remain on the host substrate with a very delicate contact, known as an epitaxial bridge. As ELO is relied on, this invention is easily applicable to foreign substrates, such as Si, SiC, sapphire, templates of semiconductor layers, or a host substrate containing ELO engineered layers templates. This invention covers LEDs, micro-cavity LEDs can be fabricated on good crystal quality ELO wings, which can be isolated from the host substrate, and then can be picked selectively or can be transferred onto a display back panel.
[0062]
[0063] In schematic 100A, a growth restrict mask 102 is formed on or above the III-nitride based substrate 101. Specifically, the growth restrict mask 102 is disposed directly in contact with the substrate 101, or is disposed indirectly through an intermediate layer grown by MOCVD, etc., made of III-nitride-based semiconductor layer or template deposited on the substrate 101.
[0064] The growth restrict mask 102 can be formed from an insulator film, for example, an SiO.sub.2 film deposited upon the base substrate 101, for example, by a plasma chemical vapor deposition (CVD), sputter, ion beam deposition (IBD), etc., wherein the SiO.sub.2 film is patterned by photolithography using a predetermined photo mask and then etched to include opening areas 103, as well as no-growth regions 104 (which may or may not be patterned). The present invention can use SiO.sub.2, SiN, SiON, TiN, etc., as the growth restrict mask 102. A multi-layer growth restrict mask 102 which is comprised of the above materials is preferred.
[0065] Epitaxial III-nitride layers 105, such as GaN-based layers, are grown using the ELO method on the GaN substrate 101 and the growth restrict mask 102. The growth of the III-nitride ELO layers 105 occurs first in the opening areas 103, on the III-nitride based substrate 101, and then laterally from the opening areas 103 over the growth restrict mask 102. The growth of the III-nitride ELO layers 105 may be stopped or interrupted before the III-nitride ELO layers 105 at adjacent opening areas 103 can coalesce on top of the growth restrict mask 102, wherein this interrupted growth results in the no-growth regions 104 between adjacent III-nitride ELO layers 105. Alternatively, the growth of the III-nitride ELO layers 105 may be continued and coalesce with neighboring III-nitride ELO layers 105, as shown in schematic 100B, thereby forming a coalesced region 106 of increased defects at a meeting region.
[0066] In
[0067] The III-nitride ELO layers 105 and III-nitride device layers 107 include one or more flat surface regions 108 and layer bending regions 109 at the edges thereof adjacent the no-growth regions 104, when the III-nitride ELO layers 105 stopped before coalescing as shown in 100a, or when the III-nitride ELO layers 105 continued to coalesce in a coalesced region 106 as shown in 100b. The width of the flat surface region 108 is at least 3 m, and most preferably is 10 m or more.
[0068] A light-emitting active region 107a of the devices 110 is processed at the flat surface regions 108 on either side of region 201, preferably between opening area 103 and the edge portion 109 or coalesced region 106. By doing so, a bar of a device 110 will possess an array of twin or nearly identical light emitting apertures 111 on either side of the opening area 103 along the length of the bar, as indicated in schematics 200d and 200e.
[0069] There are many methods of removing the light emitting regions from the substrate 101. For example, the present invention can utilize the ELO method for removing the light emitting devices 110. In the present invention, the bonding strength between the substrate 101 and the III-nitride ELO layers 105 is weakened by the growth restrict mask 102. In this case, the bonding area between the substrate 101 and the III-nitride ELO layers 105 is the opening area 103, wherein the width of the opening area 103 is narrower than the III-nitride ELO layers 105. Consequently, the bonding area is reduced by the growth restrict mask 102, so that this method is preferable for removing the epitaxial layers 105, 107.
[0070] This invention proposes two approaches to realize micro-LED devices. In one approach, as shown in schematics 300a and 300b in
[0071] Alternatively, as shown in the schematics 300c and 300d in
[0072] There are many methods of removing the light emitting regions from the substrate 101. For example, the present invention can utilize the ELO method for removing the light emitting devices 110. In the present invention, the bonding strength between the substrate 101 and the III-nitride ELO layers 105 is weakened by narrower design of W2 in the epitaxial bridge 301. Consequently, the bonding area is reduced, so this method is preferable for removing the epitaxial layers 105, 107.
[0073] In one embodiment, the III-nitride ELO layers 105 are allowed to coalesce to each other at region 106, as shown by schematic 100b in
[0074] As shown in
[0075] The device unit patterns 302 may comprise light emitting apertures 111 as mentioned above, that are located at a separate distance 304 in separate regions 202 placed directly on or above the growth restrict mask 102 for the sake of facilitating the removal of the devices 110. The separate distance 304 is preferably 1 m or more, which facilitates the breaking of the epitaxial bridge 301 or the non-epitaxial bridge 303 by fracturing and/or cleaving of the connecting link.
[0076] Preferably, the edge of the light emitting aperture 111, which is emitting a predetermined wavelength light by applying a current, is more than 1 m away from the edge of the region 202. When the separate region 202 is fractured to remove the device 110, it may damage the emitting aperture 111. More preferably, the emitting aperture 111 is 2 m or more away from the edge of the region 201, which reduces the number of defects in in the aperture 111 area.
[0077] By doing this, there is a greater process tolerance for the yield. As can be seen in the
[0078] Two approaches to the epitaxial bridge 301 or non-epitaxial bridge 303 follow.
[0079] (i) Epitaxial Bridge to Hold Regrowth Layer of p-Type
[0080] For clarity, this description is limited to one device 110, as described in
[0081] The typical fabrication steps for this invention are described in more detail below: [0082] Step 1: Forming a growth restrict mask 102 with a plurality of striped opening areas 103 directly or indirectly upon a substrate 101, wherein the substrate 101 is a III-nitride-based semiconductor, or the substrate is a hetero-substrate (Si, SiN, Sapphire, etc.), or the template prepared including growth restrict masks 102. [0083] Step 2: As shown in the schematic 400a in
[0094]
[0095] (ii) Epitaxial Bridge to Hold Regrowth Layers of n-Type, Active Region and p-Type
[0096] For clarity, this description is limited to one device unit, as described in
[0097] The typical fabrication steps for this invention are described in more detail below: [0098] Step 1: Forming a growth restrict mask 102 with a plurality of striped opening areas 103 directly or indirectly upon a substrate 101, wherein the substrate 101 is a III-nitride-based semiconductor, or the substrate is a hetero-substrate, or the template prepared including growth restrict masks. [0099] Step 2: As shown in the schematic 500a in
[0108]
[0109] Vertical Pad Configuration
[0110] The epitaxial bridge 301 may also be applied to derive a vertical pad configuration chip, as indicated in
[0111] In the separation process regions 201, 202 are etched at least to expose growth restrict mask 102, if necessary, and the III-nitride ELO layers 105 are divided into individual devices 110 or are kept together as a group of devices 110. The divided III-nitride ELO layers 105 still remain on the growth restrict mask 102 of the host substrate 101 for processes such as solvent cleaning, UV ozone exposer, etc. Therefore, cleaning the III-nitride ELO layers 105 after separation using a RIE or some other technique will help to remove residues and may also help to prepare the surface for a bonding process or chemical treatments for recovering etch damage. This is a big advantage for reducing the process time and cost. Alternatively, as indicated above, the protection layer 407 still serves as an assist layer to secure the III-nitride device layers to the host substrate.
[0112] Many kinds of materials can be used as the protection layer 407, such as SiOx, SiNx, AlOx, SiONx, AlONx, TaOx, ZrOx, AlNx, TiOx, NbOx and so on (where x>0). It is preferable that the protection layer 407 is a transparent layer for light from the active region 107a of the device 110, because then there is no need to remove the protection layer 407 after removing the III-nitride ELO layers 105 from the substrate 101. Alternatively, the protection layer 407 may be an insulation layer. If the protection layer 407 is not an insulation layer, the protection layer 407 connects a p-type layer 107b and a n-type layer 405 of the device 110, which eventually would result in a short current, in which case, the protection layer 407 has to be removed. Thus, the protection layer 407 should be transparent and an insulation layer.
[0113] Moreover, AlONx, AlNx, AlOx, SiOx, SiN, SiON can passivate the device 110 surface, especially an etched GaN crystal. Since the protection layer 407 covers the side walls of the device 110, choosing these materials is preferable to reduce current leakage which flows from the side walls of the device 110. Moreover, the smaller the size of the device 110, the more the current leakage. Passivating the side walls of the device 110 is very important, especially at the separate region.
[0114] Forming a Growth Restrict Mask
[0115] In one embodiment, the III-nitride layers 105 are grown by ELO on a III-nitride substrate 101, such as an m-plane GaN substrate 101 patterned with a growth restrict mask 102 comprised of SiO.sub.2, wherein the III-nitride ELO layers 105 may or may not coalesce at 106 on top of the growth restrict mask 102.
[0116] The growth restrict mask 102 is comprised of striped opening areas 103, wherein the SiO.sub.2 stripes of the growth restrict mask 102 between the opening areas 103 have a width of 1 m-20 m and an interval of 10 m-100 m. If a nonpolar substrate is used, the opening areas 103 are oriented along a <0001> axis. If semipolar (20-21) or (20-2-1) substrates are used, the opening areas 103 are oriented in a direction parallel to [1014] or [10-14], respectively. Other planes of the substrate may be use as well, with the opening areas 103 oriented in other directions.
[0117] When using a III-nitride substrate 101, the present invention can obtain high quality III-nitride semiconductor layers 105, 107. As a result, the present invention can also easily obtain devices 110 with reduced defect density, such as reduced dislocation and stacking faults.
[0118] Moreover, these techniques can be used with a hetero-substrate, such as sapphire, SiC, LiAlO.sub.2, Si, Ga.sub.2O.sub.3 etc., as long as it enables growth of the ELO GaN-based layers 105 through the growth restrict mask 102.
[0119] Growing a Plurality of Epitaxial Layers on the Substrate Using the Growth Restrict Mask
[0120] The III-nitride semiconductor device layers 107 are grown on the III-nitride ELO layers 105 in the flat region 108 by conventional methods. In one embodiment, MOCVD is used for the epitaxial growth of the island-like III-nitride semiconductor layers including the III-nitride ELO layers 105 and the III-nitride semiconductor device layers 107. The resulting island-like III-nitride semiconductor layers 105, 107 are separated from each other, because the MOCVD growth is stopped before the III-nitride ELO layers 105 coalesce at 106. In one embodiment, the III-nitride ELO layers 105 are made to coalesce and later etching is performed to remove unwanted regions.
[0121] Trimethylgallium (TMGa), trimethylindium (TMIn) and triethylaluminium (TMAl) are used as III elements sources. Ammonia (NH.sub.3) is used as the raw gas to supply nitrogen. Hydrogen (H.sub.2) and nitrogen (N.sub.2) are used as a carrier gas of the III elements sources. It is important to include hydrogen in the carrier gas to obtain a smooth surface epi-layer.
[0122] Saline and Bis(cyclopentadienyl)magnesium (Cp.sub.2Mg) are used as n-type and p-type dopants. The pressure setting typically is 50 to 760 Torr. III-nitride-based semiconductor layers are generally grown at temperature ranges from 700 to 1250 C.
[0123] For example, the growth parameters include the following: TMG is 12 sccm, NH.sub.3 is 8 slm, carrier gas is 3 slm, SiH.sub.4 is 1.0 sccm, and the V/III ratio is about 7700.
[0124] ELO of Limited Area Epitaxy (LAE) III-Nitride Layers
[0125] In the prior art, a number of pyramidal hillocks have been observed on the surface of m-plane III-nitride films following growth. See, for example, US Patent Application Publication No. 2017/0092810. Furthermore, a wavy surface and depressed portions have appeared on the growth surface, which made the surface roughness worse. This is a very severe problem. For example, according to some papers, a smooth surface can be obtained by controlling an off-angle (>1 degree) of the substrate's growth surface, as well as by using an N.sub.2 carrier gas condition. These are very limiting conditions for mass production, however, because of the high production costs. Moreover, GaN substrates have a large fluctuation of off-angles to the origin from their fabrication methods. For example, if the substrate has a large in-plane distribution of off-angles, it has a different surface morphology at these points in the wafer. In this case, the yield is reduced by the large in-plane distribution of the off-angles. Therefore, it is necessary that the technique does not depend on the off-angle in-plane distribution.
[0126] The present invention solves these problems as set forth below: [0127] 1. The growth area is limited by the area of the growth restrict mask 102 from the edges of the substrate 101. [0128] 2. The substrate 101 is a nonpolar or semipolar III-nitride substrate 101 that has off-angle orientations ranging from 16 degrees to +30 degrees from the m-plane towards the c-plane. Alternatively, a hetero-substrate with a III-nitride-based semiconductor layer deposited thereon may be used, wherein the layer has an off-angle orientation ranging from +16 degrees to 30 degrees from the m-plane towards the c-plane. [0129] 3. The island-like III-nitride semiconductor layers 105, 107 have a long side that is perpendicular to an a-axis of the III-nitride-based semiconductor crystal. [0130] 4. During MOCVD growth, a hydrogen atmosphere can be used.
[0131] In this invention, a hydrogen atmosphere can be used during non-polar and semi-polar growth. This condition is preferable because hydrogen can prevent excessive growth at the edge of the open area 103 from occurring in the initial growth phase.
[0132] Those results have been obtained by the following growth conditions.
[0133] In one embodiment, the growth pressure ranges from 60 to 760 Torr, although the growth pressure preferably ranges from 100 to 300 Torr to obtain a wide width for the island-like III-nitride semiconductor layers; the growth temperature ranges from 900 to 1200 C. degrees; the V/III ratio ranges from 10-30,000; the TMG is from 2-20 sccm; NH.sub.3 ranges from 0.1 to 10 slm; and the carrier gas is only hydrogen gas, or both hydrogen and nitrogen gases. To obtain a smooth surface, the growth conditions of each plane needs to be optimized by conventional methods.
[0134] After growing for about 2-8 hours, the III-nitride ELO layers 105 had a thickness of about 1-50 n and a bar width of about 50-150 m.
[0135] Fabricating the Device
[0136] The device 110 is fabricated at the flat surface region 108 by conventional methods, wherein various device 110 designs are possible. For example, LEDs may be fabricated, if only the front-end process is enough to realize device 110, such as p-pads and n-pads can be fabricated either along the length or width of the wing of the III-nitride ELO layers 105, as shown in
[0137] Forming a Structure for Separating Device Units
[0138] The aim of this step is to prepare for isolation from the host substrate 101 for the III-nitride ELO layers 105 and III-nitride device layers 107. By placing a selective etching mask, III-nitride device layers 107 are separated from the host substrate 101 by etching regions 201, 202, at least to expose the growth restrict mask 102.
[0139] The dividing may also be performed via scribing by a diamond tipped scriber or laser scriber, for example, tools such as RIE (Reactive Ion Etching) or ICP (Inductively Coupled Plasma); but is not limited to those methods, and other methods may also be used to isolate device units.
[0140] To keep the isolated III-nitride device layers 107 on the host substrate 101 while performing a regrowth, an epitaxial bridge 301 is proposed in this invention. It is also possible to ensure that the isolated III-nitride device layers 107 stay on the host substrate 101 by modifying the etching mask. Region 201, which connects the III-nitride ELO layers 105 directly with the host substrate 101, was modified in such a way that a non-epitaxial bridge 303 with the host substrate 101 still remains, even after exposing a growth restrict mask 102 at the region 202, as shown in
[0141] Moreover, the epitaxial bridge 301 can help position the emitting aperture 111 away from the opening area 103, which can reduce the number of defects included within the emitting aperture 111. With the aim of keeping the emitting aperture 111 away from the opening area 103, the bridge 301, 303 can be comprised of any other material such as dielectric layers, metals, semiconductors and insulators. In using a side from the epitaxial bridge 301, the devices 110 can completely separate from the III-nitride layers 105, 107. In other words, the devices 110 are placed on the growth restrict mask 102. At this time, the III-nitride layers 105, 107 on the opening area 103 still remain. In addition, the devices 110 are connected with the III-nitride layers 105, 107 on the opening area 103. By doing this, the devices 110 can be held on the growth restrict mask 102. This makes it possible to make the devices 110 far from opening area 103. This is preferred, because it uses a low defect area for the device 110.
[0142] Regrowth of Crystalline Layers with Epitaxial Bridge
[0143] This invention follows two approaches with regard to regrowth. In one approach, only a thin p-layer was grown and, in another approach, complete device structure layers were regrown on the isolated wing of the n-type III-nitride ELO layers 105.
[0144] These approaches have their own advantages. [0145] (a) Regrowth may heal the plasma damage associated in forming a light emitting structure 404, as regrowth temperatures are generally higher. [0146] (b) Damaged crystalline layers during plasma etching may be exposed to the crystalline environment, thus repairing the damage or healing the etched defects. [0147] (c) When regrowth is only for a p-type layer 107b, active region 107a formation could be uniform, leading to uniform wavelength emission throughout the wafer. [0148] (d) When regrowth is performed for re-growing of entire device layers 107, growth temperatures can be higher, thus leading to reduced crystalline defects. [0149] (e) When regrowth is performed for only the p-type layer 107b, the layer 107b must be very thin, for example, a thin Mg-doped GaN layer 107b with higher doping concentration can be grown using pulsed sputtering deposition. [0150] (f) The epitaxial bridge 301 can be stable at elevated temperatures. [0151] (g) Devices 110 can be plucked from the host substrate 101 by mechanically breaking the epitaxial bridge 301.
[0152] ELO III-Nitride Device Layers are Removed from the Substrate
[0153] The epitaxial bridge 301 is very delicate, and thus ultrasonic waves or a small impact are enough to break the bridge 301. The completed hanging devices 110 may be transferred from their host substrate 101 using the following methods. [0154] 1. Elastomer (PDMS) stamps: As shown in
[0156] Mounting the Device on a Display Panel
[0157] The divided/isolated devices 110 are lifted using the approaches described above: (1) PDMS stamp 414 or (2) vacuum chuck 701, and then mounted on a display panel 416.
[0158] Using a Vacuum Chuck to Pick ELO III-Nitride Device Layers and Local Repair Methods
[0159] This invention provides a solution to the problem of mass transferring of smaller light emitting apertures 111, alternatively called emissive inorganic pixels, when targeted sizes are below 50 m. LEDs, fabricated on the wing of the III-nitride ELO layers 105, can be removed as mentioned above. In particular, these devices 110 preferably have larger wing regions of the III-nitride ELO layers 105 and smaller open regions 201, that is, a ratio between the wing regions of the III-nitride ELO layers 105 and open regions 201 should be more than 1, more preferably 5-10, and in particular, open regions 201 should be around 1-5 m. Therefore, devices 110 can be removed from the III-nitride substrate 101 more easily and can be transferred to external carriers or processed in further steps in an easy manner.
[0160] A vacuum chuck 701 is combination of at least two plates 702a, 702b, wherein a top plate 702a has a large vacuum hole 703a and a bottom plate 702b has vacuum holes 703b with dimensions dl slightly smaller than the device 110 to be lifted from the host substrate 101, and, which can be controlled either electrically or magnetically for physically extracting isolated devices 110 out of the host substrate 101.
[0161] A vacuum chuck 701 is placed over the isolated devices 110 on the host substrate 101 and the devices 110 are extracted out of the host substrate 101 by turning on a vacuum using a valve.
[0162] Then, the device layers contained by the chuck 701 are either placed on a processed carrier plate 704, or directly attached onto a display back panel 416.
Definitions of Terms
[0163] III-Nitride-Based Substrate
[0164] The III-nitride-based substrate 101 may comprise any type of III-nitride-based substrate, as long as a III-nitride-based substrate enables growth of III-nitride-based semiconductor layers 105, 107, 108, 109, through a growth restrict mask 102, any GaN substrate 101 that is sliced on a {0001}, {11-22}, {1-100}, {20-21}, {20-2-1}, {10-11}, {10-1-1} plane, etc., or other plane, from a bulk GaN, and AlN crystal substrate.
[0165] Hetero-Substrate
[0166] Moreover, the present invention can also use a hetero-substrate. For example, a GaN template or other III-nitride-based semiconductor layer may be grown on a hetero-substrate, such as sapphire, Si, GaAs, SiC, Ga.sub.2O.sub.3, etc., prior to the growth restrict mask 102. The GaN template or other III-nitride-based semiconductor layer is typically grown on the hetero-substrate to a thickness of about 2-6 m, and then the growth restrict mask 102 is disposed on the GaN template or another III-nitride-based semiconductor layer.
[0167] Growth Restrict Mask
[0168] The growth restrict mask 102 comprises a dielectric layer, such as SiO.sub.2, SiN, SiON, Al.sub.2O.sub.3, AlN, AlON, MgF, ZrO.sub.2, TiN etc., or a refractory metal or precious metal, such as W, Mo, Ta, Nb, Rh, Ir, Ru, Os, Pt, etc. The growth restrict mask 102 may be a laminate structure selected from the above materials. It may also be a multiple-stacking layer structure chosen from the above materials.
[0169] In one embodiment, the thickness of the growth restrict mask 102 is about 0.05-3 m. The width of the growth restrict mask 102 is preferably larger than 20 m, and more preferably, the width is larger than 40 m. The growth restrict mask 102 is deposited by sputter, electron beam evaporation, plasma-enhanced chemical vaper deposition (PECVD), ion beam deposition (IBD), etc., but is not limited to those methods.
[0170] On an m-plane free standing GaN substrate 101, the growth restrict mask 102 comprises a plurality of opening areas 103, which are arranged in a first direction parallel to the 11-20 direction of the substrate 101 and a second direction parallel to the 0001 direction of the substrate 101, periodically at intervals extending in the second direction. The length of the opening area 103 is, for example, 200 to 35000 m; the width is, for example, 2 to 180 m; and the interval of the opening area 103 is, for example, 20 to 180 m. The width of the opening area 103 is typically constant in the second direction but may be changed in the second direction as necessary.
[0171] On a c-plane free standing GaN substrate 101, the opening areas 103 are arranged in a first direction parallel to the 11-20 direction of the substrate 101 and a second direction parallel to the 1-100 direction of the substrate 101.
[0172] On a semipolar (20-21) or (20-2-1) GaN substrate 101, the opening areas 103 are arranged in a direction parallel to [1014] and [10-14], respectively.
[0173] Alternatively, a hetero-substrate 101 can be used. When a c-plane GaN template is grown on a c-plane sapphire substrate 101, the opening area 103 is in the same direction as the c-plane free-standing GaN substrate 101; when an m-plane GaN template is grown on an m-plane sapphire substrate 101, the opening area 103 is same direction as the m-plane free-standing GaN substrate 101. By doing this, an m-plane cleaving plane can be used for dividing the bar of the device 110 with the c-plane GaN template, and a c-plane cleaving plane can be used for dividing the bar of the device 110 with the m-plane GaN template; which is much preferable.
[0174] III-Nitride-Based Semiconductor Layers
[0175] The III-nitride ELO layers 105 and the III-nitride device layers 107 can include In, Al and/or B, as well as other impurities, such as Mg, Si, Zn, 0, C, H, etc.
[0176] The III-nitride-based device layers 107 generally comprise more than two layers, including at least one layer among an n-type layer, an undoped layer and a p-type layer. The III-nitride-based device layers 107 may comprise a GaN layer, an AlGaN layer, an AlGaInN layer, an InGaN layer, etc. In the case where the device 110 has a plurality of III-nitride-based semiconductor layers 105, 107, the distance between the island-like III-nitride semiconductor layers 105, 107 adjacent to each other is generally 30 m or less, and preferably 10 m or less, but is not limited to these figures. In the semiconductor device 110, a number of electrodes according to the types of the semiconductor device 110 are disposed at predetermined positions.
[0177] Separation Length
[0178] The separation length L is formed using either an epitaxial bridge 301 or a non-epitaxial bridge 303. The separation length L keeps the light emitting aperture 111 away from the open region 201 of the III-nitride ELO layers 105. The length L is designed to be at least 1 m to avoid any edge damage, crystal defects near the open region 201, etc. A longer length guarantees an easy breakoff of devices 110 when pressed with a PDMS stamp 414 or vacuum chuck 701, and a better crystal quality for the light emitting aperture 111. In the case of the epitaxial bridge 301, devices 110 may use a cleavable plane in the length L to separate the devices 110 from the host substrate 101.
[0179] Merits of Epitaxial Lateral Overgrowth
[0180] The crystallinity of the island-like III-nitride semiconductor layers 105, 107 grown using the III-nitride ELO layers 105 upon the growth restrict mask 102 from a striped opening area 103 of the growth restrict mask 102 is very high.
[0181] Furthermore, two advantages may be obtained using a III-nitride-based substrate 101. One advantage is that a high-quality III-nitride semiconductor layer 107 can be obtained on the wings of the III-nitride ELO layers 105, such as with a very low defects density, as compared to using a sapphire substrate 101.
[0182] The use of a hetero-substrate 101, such as sapphire (m-plane, c-plane), LiAlO.sub.2, SiC, Si, etc., for the growth of the epilayers 105, 107 is that these substrates 101 are low-cost substrates. This is an important advantage for mass production.
[0183] When it comes to the quality of the device 110, the use of a free standing III-nitride-based substrate 101 is more preferable, due to the above reasons. On the other hand, the use of a hetero-substrate 101 makes it cheaper and scalable.
[0184] Also, as the growth restrict mask 102 and the III-nitride ELO layers 105 are not bonded chemically, the stress in the III-nitride ELO layers 105 can be relaxed by a slide caused at the interface between the growth restrict mask 102 and the III-nitride ELO layers 105.
[0185] Flat Surface Region
[0186] The flat surface region 108 is between layer bending regions 109. Furthermore, the flat surface region 108 is in the region of the growth restrict mask 102.
[0187] Fabrication of the semiconductor device 110 is mainly performed on the flat surface region 108. The width of the flat surface region 108 is preferably at least 5 m, and more preferably is 10 m or more. The flat surface region 108 has a high uniformity of thickness for each of the semiconductor layers.
[0188] Layer Bending Region
[0189]
[0190] From another point of view, an epitaxial layer of the flat surface region 108 except for the opening area 103 has a lesser defect density than an epitaxial layer of the opening area 103. Therefore, it is more preferable that the apertures 111 should be formed in the flat surface region 108 including on a wing region.
[0191] Semiconductor Device
[0192] The semiconductor device 110 is, for example, a Schottky diode, a light-emitting diode, a semiconductor laser, a photodiode, a transistor, etc., but is not limited to these devices. This invention is particularly useful for micro-LEDs. This invention is especially useful for a semiconductor laser which require smooth regions for cavity formation.
[0193] Epitaxial Bridge
[0194] An epitaxial bridge 301 grown using ELO is specially constructed to hold the III-nitride ELO and device layers 105, 107 at regrowth of crystal layer environment. Examples of such a structure are shown in
Alternative Embodiments
[0195] The following describes alternative embodiments of the present invention.
First Embodiment
[0196] A first embodiment discloses a method for manufacturing a III-nitride-based micro-display 416 containing semiconductor devices 110.
[0197] In the first embodiment, as shown in
[0198] In this embodiment, the island-like III-nitride ELO layers 105 are allowed contact neighboring layers 105 in order to form a foundation layer for the desired device 110. Thereafter, device layers 107, such as multi quantum well structures, waveguides, electron blocking layer, p-GaN, etc., were grown on the above the III-nitride ELO layers 105. Devices 110, as described in
[0199] The structure containing the epitaxial bridge 301 and the regrowth area 408 with the protection layer 407 is sent to a regrowth chamber for forming a thin highly doped p-GaN layer 409. The regrowth may help to heal the damage caused by the etching in the plasma environment.
[0200] Since the device layers 107 have already formed below the regrowth area 408, it is recommended to not use an aggressive temperature growth environment to form a p-GaN layer 409. For example, pulsed sputter deposition (PSD), pulsed laser deposition, or MBE, may be used to grow a high concentration Mg-doped p-GaN layers 409. These regrowth layers may help to obtain improved current spreading in the p-GaN layer 409 and heal the device damage that may have occurred in the plasma etching.
[0201] Once the regrowth finished, the growth restrict mask 102 and protection layer 407 are etched using BHF or HF, leaving only the epitaxial layers 105, 107, as indicated in
[0202] A TCO layer 410 is laid over a light emitting area and annular p-pads and n-pads 411 are deposited, as shown in
[0203] Then, the weakly attached III-nitride ELO layers 105 and device layers 107 are transferred onto a desired carrier, such as a display panel 416, using tools such as an elastomer stamp 414, vacuum chuck 701, etc. The display panels 416 can be used in a number of applications, such as TVs, laptops, phones, AR/VR/MR headsets, HUDs, etc.
Second Embodiment
[0204] A second embodiment discloses a III-nitride-based micro-display 416 containing semiconductor devices 110.
[0205] In the first embodiment, as shown in
[0206] In the second embodiment, the island-like III-nitride ELO layers 105 are allowed contact neighboring layers 105 in order to form foundation or base layers for the desired device 110. These base III-nitride ELO layers 105 are n-GaN layers. In this embodiment, device layers 107, such as multi quantum well structures, waveguides, electron blocking layer, p-GaN, etc., were grown on or above the base III-nitride ELO layers 105 in the regrowth process.
[0207] A regrowth area 408 is opened on the base n-GaN layers 105, and then the III-nitride ELO layers 105 and device layers 107 are divided into individual devices 110 or groups of devices 110 by etching to expose the underlying growth restrict mask 102 via removing regions 201, 202. While etching regions 201, 202, a epitaxial bridge 301 is formed near region 201, as shown in
[0208] The structure containing the epitaxial bridge 301 and regrowth area 408 with the protection layer 407 is sent to a regrowth chamber for regrowing device layers 107, such as n-GaN layers, multi quantum well structures, waveguides, electron blocking layers, p-GaN layers, etc. The regrowth may help to heal the damage caused by the etching in the plasma environment.
[0209] Since, in this process, the regrowth comprises growing an active region 107a, one may use higher temperatures than the process described in the first embodiment. Growing at higher temperatures increases the crystalline quality of the layers 107, thereby improved performance of the devices 110 can be observed.
[0210] For example, MOCVD or MBE may be used for the regrowth. These regrowth layers 107 may help to heal the device 110 damage that may have occurred in the plasma etching.
[0211] Once the regrowth is finished, the growth restrict mask 102 and protection layer 407 are etched using a BHF or HF, leaving only the epitaxial layers 105, 107, as indicated in
[0212] Then, weakly-attached III-nitride ELO layers 105 and device layers 107 are transferred onto a desired carrier, which can be a display panel 416, using tools such as an elastomer stamp 414, vacuum chuck 701, etc. The display panels 416 can be used in a number of applications, such as TVs, laptops, phones, AR/VR/MR headsets, HUDs, etc.
Third Embodiment
[0213] A third embodiment provides a structure for electrical injection. In the first and second embodiments, electrical injection is chosen as a later injection. However, the backside interface 601 of the III-nitride ELO layers 105 may be used as one of the electrical injection pads, which leads to a vertical configuration of electrical injection, as indicated in
Fourth Embodiment
[0214] A fourth embodiment describes on how to remove isolated devices 110 from their host substrate 101 using a PDMS stamp 414. As the isolated III-nitride ELO layers 105 have only the epitaxial bridge 301 as a connection with the host substrate 101, this connection can be easily broken using movement of the PDMS stamp 414. As described in
Fifth Embodiment
[0215] A fifth embodiment picks the isolated III-nitride ELO layers 105 and device layers 107 from the host substrate 101 using a vacuum chuck 701, wherein the vacuum chuck 701 is designed to contain at least two plates 702a, 702b. The plate 702b contains finite dimension holes 703b, which are smaller than the dimensions of the devices 110. The plate 702a has a larger dimension hole 703a, in order to control the holding process of the plate 702b. The vacuum hole 703a may be controlled either by a mechanical method, an electromagnetic method, or a hydraulic method.
[0216] One may also use the vacuum chuck 701 to pick up only selected devices 110 by closing undesired vacuum holes 703b on the plate 702b, as shown in
Sixth Embodiment
[0217] In a sixth embodiment, AlGaN layers are used as the island-like III-nitride ELO layers 105 and III-nitride device layers 107, which may be grown on various off angle substrates 101. The AlGaN layers can have a very smooth surface, and can be removed, as the island-like III-nitride ELO layers 105 and device layers 107, from various off-angle substrates 101.
[0218] In this case, an active laser, which emits UV-light (UV-A or UV-B or UV-C), can be grown on the AlGaN ELO layers 105. After removal, the AlGaN ELO layers 105 with an active layer 107a looks like a UV device 110 with a pseudo-AlGaN substrate 101. By doing this, one can obtain a high-quality UV-LED display panel 416. Applications of this may lead to sterilization, lighting, etc.
Seventh Embodiment
[0219] In a seventh embodiment, a III-nitride ELO layer 105 is grown on various off-angle substrates 101. The off-angle orientations range from 0 to +15 degrees and 0 to 28 degrees from the m-plane towards the c-plane. The present invention can remove the bar of the device 110 from the various off-angle substrates 101. This is a big advantage for this technique, as various off-angle orientations semiconductor plane devices 110 can be realized without changing the fabrication process.
Eighth Embodiment
[0220] In an eighth embodiment, a III-nitride ELO layer 105 is grown on c-plane substrates 101 with two different mis-cut orientations. Then, the III-nitride ELO and device layers 105, 107 are removed after processing a desired device 110 using the invention described in this application.
Ninth Embodiment
[0221] In a ninth embodiment, a sapphire substrate 101 with a buffer layer is used as the hetero-substrate. The resulting structure is almost the same as the first and second embodiments, except for using the sapphire substrate 101 and a buffer layer. In this embodiment, the buffer layer may also include an additional n-GaN layer or undoped GaN layer. The buffer layer is grown at a low temperature of about 500-700 C. degrees. The n-GaN layer or undoped GaN layer is grown at a higher temperature of about 900-1200 C. degrees. The total thickness is about 1-3 m. Then, the growth restrict mask 102 is disposed on the buffer layer and the n-GaN layer or undoped GaN layer.
[0222] On the other hand, it is not necessary to use the buffer layer. For example, the growth restrict mask 102 can be disposed on the hetero-substrate 101 directly. After that, the III-nitride ELO layer 105 and/or III-nitride device layers 107 can be grown.
Tenth Embodiment
[0223] A tenth embodiment is about a non-epitaxial bridge 303. The processes mentioned in the first and second embodiments may also be realized without using an epitaxial bridge 301. Regions 201, 202 separate the device layers 107 and isolates the devices 110 from the host substrate 101, as shown in
[0224] Like the epitaxial bridge 301 case, only a p-type layer 409 regrowth as described in the first embodiment, or a complete device layer 107 growth as described in the second embodiment, can be performed, even with the non-epitaxial bridge 303, as shown in
[0225] Process Steps
[0226]
[0227] Block 801 represents the step of forming the III-nitride ELO layers 105, which may coalesced or non-coalesced.
[0228] Block 802 represents the step of where the III-nitride ELO layers 105 comprise only n-GaN layers.
[0229] Block 803 represents the step of forming a lateral electrode structure and Block 804 represents the step of forming a vertical electrode structure.
[0230] Blocks 805 and 806 both represent the step of opening an area on the surface of the wing region of the III-nitride ELO layers 105.
[0231] Block 807 represents the step of forming the epitaxial or non-epitaxial bridge 301, 303.
[0232] Block 808 represents the step of performing a regrowth of the device layers 107.
[0233] Block 809 represents the step of forming the TCO layers 410 on the device layers 107.
[0234] Block 810 represents the step of placing electrical pads 411 on the resulting device 110.
[0235] Block 811 represents the step of plucking the devices 110 from the substrate 101, after breaking the connection with the substrate 101 comprised of the epitaxial or non-epitaxial bridge 301, 303.
[0236] Block 812 represents the step of placing the devices 110 on the display panel 416, or another carrier or submount.
[0237] Block 813 represents the step of forming the III-nitride device layers 107 on the III-nitride ELO layers 105.
[0238] Block 814 represents the step of forming a lateral electrode structure and Block 815 represents the step of forming a vertical electrode structure.
[0239] Blocks 816 and 817 both represent the step of opening an area on the surface of the device layers 107 on the wing region of the III-nitride ELO layers 105.
[0240] Block 818 represents the step of forming the epitaxial or non-epitaxial bridge 301, 303.
[0241] Block 819 represents the step of performing a regrowth of a highly-doped p-GaN layer 409.
[0242] Block 820 represents the step of forming the TCO layer 410 on the device layers 107.
[0243] Block 821 represents the step of placing electrical pads 411 on the resulting device 110.
[0244] Block 822 represents the step of plucking the devices 110 from the substrate 101, after breaking the connection with the substrate 101 comprised of the epitaxial or non-epitaxial bridge 301, 303.
[0245] Block 823 represents the step of placing the devices 110 on the display panel 416, or another carrier or submount.
CONCLUSION
[0246] This concludes the description of the preferred embodiment of the present invention. The foregoing description of one or more embodiments of the invention has been presented for the purposes of illustration and description. It is not intended to be exhaustive or to limit the invention to the precise form disclosed. Many modifications and variations are possible in light of the above teaching. It is intended that the scope of the invention be limited not by this detailed description, but rather by the claims appended hereto.