Method and apparatus for the production of microscale bubbles by depressurization cavitation

Abstract

A method and apparatus that enables the production of micron-scale free-standing bubbles made of liquids containing surfactants are provided. The method and apparatus of the invention overcomes the limitations of conventional bubble forming techniques by using a controlled cavitation process in a liquid media.

Claims

1. A method of producing free-standing micro-scale bubbles by using a controlled cavitation process comprising: providing an aqueous solution have a solution density (p) and containing a concentration of at least one surfactant such that the aqueous solution has a surface tension lower than that of pure water; disposing the solution within a pressurizing vessel defining an inner volume and having at least one gas conduit and at least one fluid outlet in fluid communication with the inner volume, wherein the at least one fluid outlet has an atomizing misting nozzle disposed at an outlet thereof disposed external to the pressurizing vessel; introducing a gas into the pressurizing vessel through the at least one gas inlet; pressurizing the pressurizing vessel to an internal pressure (p) such that a concentration of the gas is dissolved within the solution to form a pressurized solution having a solution vapor pressure (p.sub.v) of the gas disposed therein; wherein the internal pressure is at least 2000 pound-force per square inch, psi; opening the outlet to a low pressure gaseous region having a local pressure, wherein the force imparted on the pressurized solution by the pressure differential between the internal pressure and local pressure causes the pressurized solution to flow from the inner volume of the pressurized vessel through the atomizing misting nozzle of the at least one fluid outlet to the low pressure region at a flow velocity (V) sufficient to form an atomized mist of droplets of the solution in the low pressure gaseous region; wherein the at least one surfactant is selected from the group consisting of soap, detergent and sodium lauryl sulfate; wherein the pressurized gas has a concentration (c) and the concentration and the solution vapor pressure satisfy Henry's law:
p.sub.v=k.sub.Hc and k.sub.H is Henry's law constant; wherein the solution density, the pressure differential between the solution vapor pressure of the atomized mist and the local pressure of the low pressure region, and the velocity of the atomized mist at the atomizing mist nozzle of the outlet are configured to produce a cavitation number (Ca) in the droplets of less than 1 as given by the equation: $C=\frac{p-p_v}{1\text{/}2V^2}$ such that the cavitation occurs within the droplets of the atomized mist to produce a plurality of free-standing solution bubbles in the gaseous atmosphere of the low pressure region; and wherein the bubbles have a lifetime of at least 10 minutes.

2. The method of claim 1, wherein the local pressure is 1 atm.

3. The method of claim 1, wherein the internal pressure is at least 2200 psi, the local pressure is 1 atm, the atomizing misting nozzle has an orifice opening size of 1 mm or less, and the bubbles are on the order of about 10 microns in size.

4. The method of claim 1, wherein the step of pressurizing is accomplished via one of either an air compressor or a reciprocating piston.

5. The method of claim 1, wherein the atomizing misting nozzle has an orifice opening size of 1 mm or less.

6. The method of claim 1, wherein the atomizing misting nozzle has an orifice opening size of 0.25 mm or less.

7. The method of claim 1, wherein the solution has a ratio of surfactant to water of at least 1:2.

8. A method of producing free-standing bubbles comprising: providing an aqueous solution have a solution density () and containing a concentration of at least one surfactant in a ratio of surfactant to water of at least 1:2, such that the aqueous solution has a surface tension lower than that of pure water; disposing the solution within a pressurizing vessel defining an inner volume and having at least one gas conduit and at least one fluid outlet in fluid communication with the inner volume, wherein the at least one fluid outlet has an atomizing misting nozzle having an orifice opening of no greater than 1 mm, disposed at an outlet thereof disposed external to the pressurizing vessel; introducing a gas into the pressurizing vessel through the at least one gas inlet; pressurizing the pressurizing vessel to an internal pressure (p) of at least 2200 psi such that a concentration of the gas is dissolved within the solution to form a pressurized solution having a solution vapor pressure (p.sub.v) of the gas disposed therein; opening the outlet to a low pressure gaseous region having a local pressure of around 1 atm, wherein the force imparted on the pressurized solution by the pressure differential between the internal pressure and local pressure causes the pressurized solution to flow from the inner volume of the pressurized vessel through the atomizing misting nozzle of the at least one fluid outlet to the low pressure region at a flow velocity (V) sufficient to form an atomized mist of droplets of the solution in the low pressure gaseous region; wherein the at least one surfactant is selected from the group consisting of soap, detergent and sodium lauryl sulfate; wherein the pressurized gas has a concentration (c) and the concentration and the solution vapor pressure satisfy Henry's law:
p.sub.v=k.sub.Hc and k.sub.H is Henry's law constant; wherein the solution density, the pressure differential between the solution vapor pressure of the atomized mist and the local pressure of the low pressure region, and the velocity of the atomized mist at the atomizing mist nozzle of the outlet are configured to produce a cavitation number (Ca) in the droplets of less than 1 as given by the equation: $C=\frac{p-p_v}{1\text{/}2V^2}$ such that the cavitation occurs within the droplets of the atomized mist to produce a plurality of free-standing solution bubbles in the gaseous atmosphere of the low pressure region; and wherein the bubbles thus formed are on the order of about 10 microns in size and have a lifetime of at least 10 minutes.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) These and other features and advantages of the present invention will be better understood by reference to the following detailed description when considered in conjunction with the accompanying data and figures, wherein:

(2) FIG. 1 provides a flow-chart of a method for producing micron-scale bubbles in accordance with an embodiment of the instant invention;

(3) FIG. 2 provides a schematic diagram of an apparatus for producing micron scale bubbles in accordance with an embodiment of the instant invention; and

(4) FIG. 3 provides a schematic diagram of an apparatus for producing micron scale bubbles in accordance with another embodiment of the instant invention.

DETAILED DESCRIPTION OF THE INVENTION

(5) The current invention is directed to a method and apparatus that enables the production of micron-scale free-standing bubbles made of liquids containing surfactants. The method and apparatus of the invention overcomes the limitations of conventional bubble forming techniques by using a controlled cavitation process in a liquid media. Although many aspects of the discussion will focus on soap bubbles, it will be understood that the surfactants used with the method and in the apparatus of the invention may include surfactants beyond soaps, and may include, for example, detergents and medical grade materials containing surfactants such as SDL.

(6) As shown in the flow-chart provided in FIG. 1, the inventive method has several steps: In a first step, a bubble generating liquid is prepared. As described earlier, the liquid may contain a desired amount of any suitable surfactant such as, for example, a soap, detergent or other liquid with a surface tension less than that of pure water. In a second step, this surfactant containing liquid is put under pressure to form a pressurized surfactant mixture. In a third and final step, the pressurized surfactant mixture is rapidly depressurized such that the pressure of the liquid falls below its vapor or dissolved gas partial pressure, resulting in cavitation of the pressurized liquid and the formation of bubbles.

(7) In short, the basic concept of the invention relies on the rapid depressurization of an already pressurized mixture of liquid containing a desired amount of surfactants (or any liquid with surface tension less than that of pure water). This rapid depressurization will cause either air or other gases to leave the liquid media through gas or vapor cavitation. For the purposes of this invention, cavitation is defined as the formation of liquid or dissolved gas vapor bubbles of a flowing liquid in a region where the pressure of the liquid falls below its vapor or dissolved gas partial pressure. Cavitation occurs when a liquid is subjected to rapid changes of pressure causing the formation of gas or vapor bubbles in the lower pressure regions of the liquid. Whether a particular liquid will or will not cavitate, and therefore the conditions (i.e., initial and final pressure) under which any particular liquid must be placed to ensure bubble formation by cavitation, may be modeled in accordance with the equation:

(8) $\begin{array}{cc}\mathrm{Ca}=\frac{p-p_v}{\frac{1}{2}{V}^2}& \mathrm{EQ}.1\end{array}$
where, is the density of the fluid, p is the local pressure, p.sub.v is the vapor pressure of the fluid, and V is a characteristic velocity of the flow. The result of this equation, the Cavitation number (Ca) is a dimensionless number used in flow calculations. It expresses the relationship between the difference of a local absolute pressure from the vapor pressure and the kinetic energy per volume, and is used to characterize the potential of the flow to cavitate.

(9) Accordingly, it will be understood that it is possible, using this equation, for one skilled in the art to determine the initial and final conditions under which any surfactant solution will cavitate to produce bubbles in accordance with the method and apparatus of the instant invention.

Exemplary Embodiment

(10) In this section, an example of a micron-scale bubble-generating device in accordance with the current invention is provided. The person skilled in the art will recognize that additional embodiments according to the invention are contemplated as being within the scope of the foregoing generic disclosure, and no disclaimer is in any way intended by the foregoing, non-limiting examples.

Example 1: Air Compressor Device

(11) FIG. 2 shows a schematic of a spray nozzle bubble generation system in accordance with the current invention. As discussed above, while this example provides an embodiment of the invention, it should be understood that other apparatuses that incorporate the pressurizing and depressurizing system described above would be incorporated into this invention, and that this specific embodiment is provided only to demonstrate the feasibility of the inventive system in producing neutrally buoyant bubbles in the 10 micron size range.

(12) As shown in the diagram of FIG. 2, in this embodiment the bubble generation device (10) of the instant invention comprises a reservoir (12) for containing a surfactant solution (14) that can be pressurized to a desired level. By pressurizing the solution air is forced into the solution in accordance with Henry's Law:
p=k.sub.HcEQ. 2
where p is the partial pressure of the solute in the gas above the solution, c is the concentration of the solute and k.sub.H is a constant with the dimensions of pressure divided by concentration. The constant, known as the Henry's law constant, depends on the solute, the solvent and the temperature. Accordingly, it will be understood that a significant amount of air can be dissolved into the surfactant solution during the pressurization process.

(13) Although any pressure suitable for dissolving the desired amount of air into the surfactant containing fluid may be used, in this exemplary device, the solution at the chamber before the nozzle exit is preferably pressurized to 2000 psi. It will be understood that depending on the scale of the device and the level of gas saturation, this number may vary.

(14) In this embodiment, an air compressor (16) is used for pressing the solution into the nozzle and supplying air for dissolution. However, it will be understood that there are any number of ways to pressurize the solution, including, for example, the use of a reciprocating piston.

(15) The surfactant solution that is pressurized mechanically enters a nozzle (18) with an orifice (20) smaller than a millimeter, although it should be understood that the orifice may be of any suitable size to produce an atomizing mist of the surfactant solution, and, may be interchangeably interconnected with the nozzle exit. The solution is atomized as it passes through the small nozzle exit. When the atomized solution encounters the ambient pressure in air, the depressurization process follows. The dissolved air and solution rapidly expand and then collapse due to the cavitation process. The implosion process of the bubbles further fragments the initial bubble into many smaller micron size bubbles (22). Most of the bubbles created in this way are expected to have a long lifetime, that is, do not burst for a long time. Bubbles generated by the inventive bubble-generating device and method are also expected to be in the range of 10 micron size and neutrally buoyant.

Example 2: Pneumatic Piston Device

(16) Although one embodiment of the invention is provided above, it should be understood that other methods of pressurizing and depressurizing the surfactant solution may be developed. For example, FIG. 3 provides a schematic of another embodiment of the bubble-generator (30). In this embodiment, a pneumatic driven piston pump (32) (M-series, Haskel Inc.) pressurizes soap solution (34). The soap solution in a reservoir tank (36) enters the liquid inlet (38) of the piston pump, and it is pressurized by the piston pump. When the pressurized solution passes through a misting nozzle (40) having a specific orifice size, it is atomized by an atomizer inside the nozzle and depressurized by a constricting area of the nozzle.

(17) As before, the mechanism of bubble generation for this device is a cavitation process in liquid media. The basic concept is the rapid depressurization of an already pressurized liquid containing a desired amount of surfactant below its vapor or gas partial pressure through the nozzle. When the solution encounters the ambient pressure in air, the depressurization process continues. This depressurization will cause either air or other gases to leave the liquid media through vapor or gas cavitation, which results in bubble formation.

(18) In an experiment conducted using the device shown schematically in FIG. 3, the regulated pressure of compressed air entering the air inlet of the piston pump was 60 psi, and the area ratio of the air and liquid parts of the piston was 36:1. It can then be estimated that the pressure of the solution pressurized by the piston pump is about 2200 psi. The pressurized solution was then forced through an inlet having an orifice size of 0.25 mm (McMaster-Carr). Bubbles generated by the inventive bubble-generating device and method were formed in the range of 10 micron size and were neutrally buoyant since they were air-borne for more than 10 minutes after their generation. However, the surfactant has a critical role in precipitating the formation of bubbles and maintaining them in air. In the test a mixture of dish-wash detergent (Dawn Ultra dishwashing detergent) and water with a mixing ratio of 1:2 was used. When water without detergent was sprayed by the same device, most of the droplets fell down soon after injection.

(19) In an alternative embodiment, the surfactant solution may be gasified prior to depressurization, by any known technique. Gasification of the detergent solution before bubble generating operation has shown to improve the formation of micron size bubbles.

DOCTRINE OF EQUIVALENTS

(20) This description of the invention has been presented for the purposes of illustration and description. It is not intended to be exhaustive or to limit the invention to the precise form described, and many modifications and variations are possible in light of the teaching above. The embodiments were chosen and described in order to best explain the principles of the invention and its practical applications. This description will enable others skilled in the art to best utilize and practice the invention in various embodiments and with various modifications as are suited to a particular use. The scope of the invention is defined by the following claims.