Composition, imprinting ink and imprinting method

Abstract

Disclosed is a silane-based composition for forming an imprinting ink for imprint lithography applications in which the crosslinking of the silanes in the composition is suppressed by the inclusion of a compound of Formula 3: wherein R.sub.9 is selected from the group consisting of C.sub.1-C.sub.6 linear or branched alkyl groups and a phenyl group, and wherein n is a positive integer having a value of at least 2. An ink may be formed by adding a PAG, photoinitiator or TAG to the composition such upon their activation, the crosslinking reaction is completed. An imprinting method using 10 such an ink is also disclosed. ##STR00001##

Claims

1. A composition for forming an imprinting ink, the composition comprising: a dissolved condensation product of: at least one of a first silane compound of Formula 1 and a second silane compound of Formula 2; and a compound of Formula 3 acting as an inhibitor of polycondensation reaction of the compounds of Formula 1 or 2 at a defined pH: ##STR00009## wherein R.sub.1-R.sub.9 are individually selected from the group consisting of C.sub.1-C.sub.6 linear or branched alkyl groups and a phenyl group, and wherein n is a positive integer having a value of at least 2; the composition further comprising: a protic acid such that the composition has a pH in the range of 3-5; and an organic solvent system comprising a primary or a secondary alcohol and water wherein the compound of Formula 3 is selected from, triethylene glycol monomethyl ether, triethylene glycol monoethyl ether, tetraethylene glycol monomethyl ether and tetraethylene glycol monoethyl ether.

2. The composition of claim 1, wherein the dissolved condensation product comprises the first and second silane compounds in a molar ratio of 1:5-5:1.

3. The composition of claim 1, wherein n is 2, 3, 4 or 5.

4. The composition of claim 1, wherein: the dissolved condensation product is formed from a silane content in the composition of 1-20 wt % based on the weight of the silanes when fully condensated and a content of Formula 3 in the composition of 1-10 wt % based on the total weight of the composition prior to the formation of said condensation product; and the organic solvent system has a content in the composition of 25-98 wt % based on said total weight of the composition.

5. The composition of claim 1, wherein the first compound is methyltrimethoxysilane and the second compound is tetramethoxysilane.

6. The composition of claim 1, wherein the organic solvent system comprises at least one of 1-propanol, 2-propanol, 1-butanol, 2-butanol and 1-methoxy-2-propanol.

7. The composition of claim 6, wherein the organic solvent system further comprises 1-ethoxy-2-(2-ethoxyethoxy)ethane.

8. The composition of claim 1, wherein the composition has a water content of 5-20 mole per mole of silicon in said composition.

9. The composition of claim 1, wherein the pH of the composition is in the range of 3.5-4.5.

10. The composition of claim 1, wherein the protic acid is selected from acetic acid, formic acid and hydrochloric acid (HCl).

11. The composition of claim 1, further comprising nanoparticles.

12. The composition of claim 1, further comprising a luminescent compound.

13. An imprinting ink comprising a composition that includes: a dissolved condensation product of: at least one of a first silane compound of Formula 1 and a second silane compound of Formula 2; and a compound of Formula 3 acting as an inhibitor of polycondensation reaction of the compounds of at least one of Formula 1 and 2 at a defined pH: ##STR00010## wherein R.sub.1-R.sub.9 are individually selected from the group consisting of C.sub.1-C.sub.6 linear or branched alkyl groups and a phenyl group, and wherein n is a positive integer having a value of at least 2; the composition further comprising: a protic acid such that the composition has a pH in the range of 3-5; and an organic solvent system comprising a primary or a secondary alcohol and water, wherein the imprinting ink further comprises one of a photo-acid generator, a photo-initiator and a thermal acid generator and wherein the compound of Formula 3 is selected from, triethylene glycol monomethyl ether, triethylene glycol monoethyl ether, tetraethylene glycol monomethyl ether and tetraethylene glycol monoethyl ether.

14. The imprinting ink of claim 13, wherein the photo-acid generator is ##STR00011##

15. The imprinting ink of claim 13, further comprising a sensitizing agent for sensitizing the photo-acid generator.

16. The imprinting ink of claim 13, wherein the photo-acid generator or thermal acid generator has a content in the ink of 1-10 wt % based on the weight of the silane compounds when fully condensated.

17. A method of forming a patterned layer on a substrate, comprising: depositing an imprinting ink of claim 13 on the substrate; imprinting the deposited imprinting ink with a stamp carrying a pattern; solidifying the imprinting ink by activating one of a photo-acid generator, a photoinitiator and a thermal acid generator in said composition; and removing the stamp following the solidification.

18. The method of claim 17, wherein said activating of the photo-acid generator or the photoinitiator comprises irradiating the imprinting ink with UV radiation having a wavelength of at least 350 nm.

19. Use of an imprinting ink for an imprinting process, the imprinting ink comprising a composition that includes: a dissolved condensation product of: at least one of a first silane compound of Formula 1 and a second silane compound of Formula 2; and a compound of Formula 3 acting as an inhibitor of polycondensation reaction of the compounds of Formula 1 or 2 at a defined pH: ##STR00012## wherein R.sub.1-R.sub.9 are individually selected from the group consisting of C.sub.1-C.sub.6 linear or branched alkyl groups and a phenyl group, and wherein n is a positive integer having a value of at least 2; the composition further comprising: a protic acid such that the composition has a pH in the range of 3-5; and an organic solvent system comprising a primary or a secondary alcohol and water wherein the compound of Formula 3 is selected from, triethylene glycol monomethyl ether, triethylene glycol monoethyl ether, tetraethylene glycol monomethyl ether and tetraethylene glycol monoethyl ether.

20. The method of claim 17, comprising using a stamp carrying a pattern, wherein a pattern carrying part of the stamp comprises a rubber material.

21. The method of claim 20, wherein the rubber material is a poly-dimethylsiloxane.

22. The method of claim 21, wherein the imprinting ink is irradiated with UV irradiation having a wavelength higher than 250 nm, and wherein irradiation takes place through the stamp.

23. A substrate comprising a patterned layer that is obtainable by performing a method comprising: depositing an imprinting ink of claim 13 on the substrate; imprinting the deposited imprinting ink with a stamp carrying a pattern; solidifying the imprinting ink by activating one of a photo-acid generator, a photoinitiator and a thermal acid generator in said composition; and removing the stamp following the solidification.

24. The composition of claim 9, wherein the pH is 4.

25. The composition of claim 11, wherein the particles are silicon nanoparticles.

26. The composition of claim 12, wherein the luminescent compound is a phosphor or luminescent dye.

Description

BRIEF DESCRIPTION OF THE EMBODIMENTS

(1) The invention is described in more detail and by way of non-limiting examples with reference to the accompanying drawings, wherein:

(2) FIG. 1 schematically depicts an example of an imprinting method of the present invention;

(3) FIG. 2 schematically depicts another example of an imprinting method of the present invention;

(4) FIG. 3 schematically depicts yet another example of an imprinting method of the present invention;

(5) FIG. 4 is a SEM image of an pattern formed using an imprinting method of the present invention;

(6) FIG. 5 is a SEM image of another pattern formed using an imprinting method of the present invention;

(7) FIG. 6 is an infrared (IR) spectrum of an imprinting ink before and after activation of a PAG in the ink;

(8) FIG. 7 depicts an aspect of an infrared (IR) spectrum of an imprinting ink with and without a PAG in the ink as a function of time during a curing reaction;

(9) FIG. 8 is an infrared (IR) spectrum of an imprinting ink with and without a compound according to Formula 3 (EEOL) in the ink;

(10) FIG. 9 shows a part of an infrared (IR) spectrum of an imprinting ink according to an example of the present invention at different times during a curing process;

(11) FIG. 10 shows another part of an infrared (IR) spectrum of an imprinting ink according to an example of the present invention at different times during a curing process; and

(12) FIG. 11 shows the infrared (IR) spectrum of a compound according to Formula 3 (EEOL).

DETAILED DESCRIPTION OF THE DRAWINGS

(13) It should be understood that the Figures are merely schematic and are not drawn to scale. It should also be understood that the same reference numerals are used throughout the Figures to indicate the same or similar parts.

(14) In the context of the present application, references are made separately to a composition for forming an imprinting ink and to the imprinting ink itself. The main difference between the composition and the ink is that the ink comprises an acid generator such as a PAG or TAG and/or a photoinitiator, whereas such an acid generator and/or photoinitiator is absent from the composition, e.g. to increase the shelf-life of the composition and to relax its storage requirements as no measures have to be taken to avoid unwanted (premature) activation of the acid generator or photoinitiator.

(15) A composition may be provided as a kit of parts in which the composition is provided as a first part and the acid generator and/or photoinitiator is provided as a second part, e.g. dissolved in a suitable solvent, such as the solvent system used in the composition, such that the imprinting ink may be formed in-situ by mixing the two parts of the kit.

(16) In accordance with the present invention, a sol-gel based composition for forming an imprinting ink and an imprinting ink are provided of which the viscosity can be tuned to give the composition and ink the desired properties for facile deposition of the ink on a substrate, e.g. using spin-coating, doctor blading and so on, and in which the polycondensation of the silane compounds in the ink can be activated on demand, i.e. subsequent to the deposition, to ensure that the process window for imprinting the ink is not reduced by premature polycondensation of the silane compounds in the ink.

(17) Such premature polycondensation may for instance occur if the polycondensation reaction is initiated, e.g. the acid generator or photoinitiator is activated, prior to the deposition process to increase the viscosity of the ink such that the ink can be deposited more easily. However, this significantly reduces the period of time during which the ink can be imprinted by a stamp, as the initiated polycondensation reaction rapidly shifts the ink to a solidified (gelated) state, such that little time is available after its deposition on the substrate to perform the imprinting step before the ink becomes too rigid. This can cause stamp pattern reproducibility problems in the ink, which can negatively affect the yield of the imprinting process.

(18) The present inventors have discovered that it is possible to slow down the polycondensation rate of such a sol-gel system upon activation of the acid generator such as a PAG or TAG or photoinitiator such that premature completion of the polycondensation reaction can be avoided and the process window can be maximized. An additional advantage is that such a polycondensation reaction can be halted at an intermediate polymerization stage, i.e. by the formation of oligomers that remain dissolved in the ink or composition, to give the ink the desired deposition properties, e.g. the desired viscosity, and allows for the polycondensation reaction to be restarted on demand.

(19) To this end, the composition comprises a protic acid to catalyze the polycondensation reaction as well as a polycondensation inhibitor to halt the polycondensation reaction at an intermediate stage. An acid generator, such as a PAG or TAG or a photoinitiator such as Irgacure 369 may be added to the composition prior to the imprinting process to form an imprinting ink, which acid generator has the purpose to further decrease the pH of the ink on demand, e.g. after its deposition on the substrate and while the stamp is imprinted into the ink, to shift the equilibrium between the polycondensation reaction and the hydrolysis reaction towards polycondensation and remove the polycondensation inhibitor from the formed oligomers.

(20) A PAG is preferred as this obviates the need for strict control of the temperatures to which the ink is exposed in case a TAG is used. The ink or the composition including the oligomers can be stored for prolonged periods of time, e.g. several weeks, thus making it particularly suitable for commercial application. The ink may be stored in composition form, i.e. excluding the acid generator and/or photoinitiator, such that no measures have to be taken to avoid premature activation of the acid generator or photoinitiator.

(21) In the reaction to form a sol-gel system, alkoxysilanes may be used which undergo the reaction steps as shown in reaction scheme I in the presence of an acid or a base. Reaction scheme I shows the acid-catalyzed reaction. The alkoxysilanes undergo a hydrolysis, which is followed by a condensation reaction between two hydrolyzed alkoxysilanes (water condensation reaction) or between a hydrolyzed alkoxysilane and an unreacted alkoxysilane (alcohol condensation reaction) in which the crosslinked inorganic network is formed. The degree of crosslinking can be controlled by appropriate choice of the alkoxysilanes.

(22) ##STR00003##

(23) In the above reaction scheme, the equilibrium point between condensation and hydrolysis or alcoholysis can be controlled by the pH of the ink composition. A lower pH, i.e. a more acidic ink composition, will typically shift the equilibrium towards polycondensation. In the invention the ink composition is based on silane monomers of Formula 1, Formula 2 or a combination thereof:

(24) ##STR00004##

(25) wherein R.sub.1-R.sub.8 are individually selected from the group consisting of C.sub.1-C.sub.6 linear or branched alkyl groups and a phenyl group. Particularly suitable examples of such silane compounds are defined by the compounds of Formula 4-7:

(26) ##STR00005##

(27) In an embodiment, the imprintable ink is based on a first silane compound of Formula I and a second silane compound of Formula 2. This has the advantage that the amount of crosslinking can be controlled by varying the ratio between the first and second curable compound. Typically, an increase in the ratio towards the first curable compound reduces the crosslinking density in the network formed in the polycondensation reaction. In order to obtain the most desirable cross-linking density, the molar ratio of the first silane compound and the second silane compound is in the range of 5:1-1:5.

(28) In a particularly suitable embodiment, the first silane compound is MTMS. It has been found that when combining MTMS with a fully inorganic silane compound, i.e. a silane compound according to Formula 2, the unwanted shrinkage of the ink composition upon solidification can be largely avoided. Particularly suitable embodiments of the second silane compounds to be used in combination with MTMS are TMOS and TEOS.

(29) In order to achieve the desired degree of polymerization in the ink composition prior to its deposition, the pH of the ink composition is set in a range of 3-5, preferably 3.5-4.5. Particularly preferable is a pH of about 4. The pH may be set using any suitable protic acid, e.g. an organic acid such as acetic acid or formic acid, or an inorganic acid such as hydrochloric acid.

(30) The ink composition further comprises a polycondensation inhibitor according to Formula 3 that competes with the silane compounds in the polycondensation reaction as shown in Reaction Schedule I:

(31) ##STR00006##
wherein R.sub.9 is selected from the group consisting of C.sub.1-C.sub.6 linear or branched alkyl groups and a phenyl group, and wherein n is a positive integer having a value of at least 2. In a particular advantageous embodiment, n is 2, 3, 4 or 5.

(32) Particularly advantageous examples of the polyethylene glycol monoether of Formula 3 include diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, triethylene glycol monomethyl ether, triethylene glycol monoethyl ether, tetraethylene glycol monomethyl ether and tetraethylene glycol monoethyl ether.

(33) At a pH of 3-5, preferably a pH of 3-5-4.5 and more preferably a pH of around 4, it has been found that a compound of Formula 3 reduces the level of completion of the polycondensation reaction between the silane compounds in the ink or composition, i.e. shifts the equilibrium of the polycondensation reaction more towards the oligomer/monomer side of the equilibrium. In particular, silane oligomers are formed that include the compound of Formula 3.

(34) Although the driving force behind this behavior is not fully understood, it has been established by IR spectroscopy, and NMR spectroscopy that at the specified pH, the alcohol group of the alcohol ether of Formula 3 takes part in an alcohol condensation reaction as shown in Reaction Scheme I, with the ether functionality of the alcohol ether resisting hydrolysis at this stage, thus preventing further polymerization as the hydrolysis reaction (1) in Reaction Scheme I that creates fresh alcohol functional groups facilitating further condensation reactions does not occur. Consequently, the alcohol ether inhibits the further polycondensation of the silane oligomers.

(35) However, upon increasing the acidity of the ink composition, e.g. by the activation of the PAG or TAG, the alcohol ethers are removed from the oligomers, such that the equilibrium of the polycondensation reaction is shifted towards the polymer side of the equilibrium; i.e. the polycondensation reaction can be completed. It has been found that at least in some embodiments this process is at least partly driven by the fact that upon release of the compound of Formula 3 from the silane monomers, the compound is removed from the imprinting ink by diffusion into the stamp material, which further shifts the aforementioned equilibrium towards the polymer products.

(36) At this point, it should be understood that in addition to the oligomers of the silane compounds of Formula 1 and/or Formula 2, embodiments of the ink or composition of the present invention may further comprise the silane compounds of Formula 1 and/or Formula 2 in monomeric form as a consequence of the incomplete polycondensation reaction.

(37) The composition or the curable imprintable ink may further comprise nanoparticles, e.g. silicon nanoparticles, to reduce shrinkage of a patterned layer formed from the medium.

(38) The composition or the curable imprintable ink may further comprise a luminescent compound, e.g. a phosphor or luminescent dye, to facilitate functional modification of a semiconductor substrate carrying light-emitting elements such as light-emitting diodes by the formation of patterned layer portions on the light-emitting elements.

(39) The composition can be converted into an imprinting ink by the addition of an acid generator such as a PAG for lowering the pH to shift the polycondensation reaction equilibrium towards polymer formation as previously explained. In principle, any suitable PAG may be used for this purpose. However, some stamp materials such as PDMS can deteriorate when exposed to deep-UV irradiation, e.g. irradiation of 300 nm or less. It is therefore advantageous when using a PAG that is typically activated at wavelengths below 300 nm to use the PAG in combination with a suitable sensitizer that can be activated above 300 nm, such that degradation of the stamp material can be avoided. For instance, suitable PAGs for use in combination with such sensitizers are PAGs based on iodine salts.

(40) Alternatively, a PAG may be used that can be activated with wavelengths above 300 nm or even above 350 nm without the need for a separate sensitizer. Such sensitizers are known per se, and any suitable sensitizer may be chosen. A non-limiting example of such a PAG includes Irgacure PAG 103:

(41) ##STR00007##

(42) It has furthermore be found that a photo-initiator such as Irgacure 369 may be used instead of a PAG or TAG to accelerate the completion of the photocondensation reaction upon exposure to UV irradiation, such that an ink of the present invention may also be formed by adding such a photo-initiator to the aforementioned composition.

(43) The organic solvent system should be selected such that the formed silane oligomers do not phase separate out of the solution, i.e. remain dissolved, and should have a vapour pressure that is low enough to avoid significant evaporation of the one or more solvents in the solvent system during ink deposition on the substrate, as this can cause premature phase separation of the oligomers, which can deteriorate the quality of the structures formed by the imprinting process, e.g. because homogeneous deposition of the ink becomes problematic. A solvent system including one or more primary and/or secondary alcohols such as 1-propanol, 2-propanol, 1-butanol, 2-butanol and 1-methoxy-2-propanol for instance meets those requirements although it is emphasized that other solvents are expected to be equally suitable.

(44) In an embodiment, the organic solvent system composition has a water content of 5-20 mole per mole of silicon in said composition. It has been found that when the water content is selected within this range, particularly desirable oligomerization characteristics are obtained.

(45) The ink or composition may further comprise one or more additives that do not take part in the polycondensation reaction but may be used to improve the characteristics of the ink or composition. For instance, the ink or composition may contain additives that improve the film forming properties of the ink. A non-limiting example of such an additive is 1-ethoxy-2-(2-ethoxyethoxyl)ethane (EEE):

(46) ##STR00008##

(47) In an embodiment, the ink or composition of the present invention has a composition selected from the ranges as specified in Table I. In Table I, where reference is made to weight percentages (wt %), this is relative to the total weight of the ink or composition unless otherwise specified.

(48) TABLE-US-00001 TABLE I Compound Concentration Range Silane monomer(s) of Formula 1 and/or 1-20 wt % Formula 2 based on the weight of the silanes when fully condensated Water 5-20 mole per mole of silicon (or 2-40 wt %) Solvent system 25-98 wt % Polymerization inhibitor of Formula 3 1-10 wt % Protic acid 0.001-0.1 wt % (depending on the pKa of the acid - the amount of acid should set the pH of the composition to around 3-5, e.g. 4) PAG (absent in composition) 1-10 wt % (based on solid content in ink; i.e. the weight of the silane compounds when fully condensated) Film forming agent (e.g. EEE) 0-10 wt %

(49) An embodiment of the method of the present invention is demonstrated in FIG. 1. In step A, a substrate 10, which may be any suitable carrier such as a silicon substrate, a silicon on insulator substrate, a glass substrate and so on, is covered with a layer of a curable imprintable ink 12, i.e. a sol-gel system, of the present invention. A stamp 14, which may be made of any suitable material such as a hard stamp, e.g. from quartz or a soft stamp, e.g. from PDMS carrying a pattern 16 is imprinted into the curable imprintable ink 12, thereby transferring the pattern 16 into this layer, as shown in step B. Next, as depicted in step C, the substrate stack is irradiated with electromagnetic radiation of an appropriate wavelength, e.g. UV radiation, thereby activating a PAG in the ink 12, which removes the alcohol ether from the silane oligomers and thus induces the further polycondensation of the silane oligomers.

(50) Upon completion of this polymerization reaction, the stamp 14 is removed in step D, leaving behind the pattern portions 18 on the substrate 10, which retains its shape due to the network formed by the polycondensation reaction. Next, the remaining pattern may be densified further, e.g. by exposure to heat, thereby forming pattern portions 20 formed of the inorganic polymer resulting from the aforementioned polycondensation reaction as shown in step E.

(51) In a preferred embodiment, the stamp 14 is made of PDMS (polydimethylsiloxane) or another hydrophobic stamp material having a low Young's modulus or being porous. Such materials have the additional advantage that they largely absorb the compound of Formula 3 from the ink composition, which helps to more rapidly shift the condensation/hydrolysis equilibriums shown in Reaction Scheme I towards the polycondensation stage as previously explained. FIGS. 4 and 5 depict SEM images of example patterns that have been formed in the imprinting ink of the present invention using the patterning method of FIG. 1. As will be apparent from these images, submicron features, either raised (FIG. 4) or recessed (FIG. 5) can be formed in the imprinting ink of the present invention with high accuracy and excellent reproducibility.

(52) At this point, it is noted that due to the fact that the curable imprintable ink of the present invention can be used to achieve a cured patterned layer with a high inorganic content and high crosslinking density, the curable imprintable ink of the present invention in particularly being suitable for the formation of multi-layer structures, such as three-dimensional structures that have tuned optical properties, e.g. light emitting diodes, interferometers, photonic crystals and so on. Such structures could not be satisfactorily made with prior art curable media because of the lower inorganic content fraction in the polymers formed from these media, which impaired the structural integrity of the layers formed with these polymers, thus yielding unstable multi-layer structures.

(53) Such three-dimensional structures may be produced by filling or planarizing the patterned layer 20 by depositing a planarization material 22 over the patterned layer 20, as shown in FIG. 2, and removing excess material if necessary, e.g. by etching or polishing. The planarization material 22 may be any thermally degradable material such as a thermally degrable polymer (TDP). A non-limiting example of a TDP is polynorbornene or polystyrene. Alternatively, the planarization material 22 may be soluble in a particular solvent. In general, any planarization material 22 that can be selectively removed from a formed multi-layer structure without damaging the patterned layers formed from the curable imprintable ink of the present invention may be used.

(54) A non-limiting example of a method of manufacturing such a three-dimensional structure is shown in FIG. 3. In step A, a planarized layer 30 is formed on a substrate or carrier 10, as previously explained. The patterned portions 20 of the planarized layer 30 may be produced by UV imprint lithography (e.g. UV-assisted Substrate Conformal Imprint Lithography, UV-SCIL) using the curable imprintable ink 12 in accordance with the method shown in FIG. 1. The pattern 20 is filled, i.e. planarized with a filling material 22. In step B, a next layer of the curable imprintable ink 12 is applied over the planarized layer 30 of step A in any suitable manner, e.g. by spincoating, dispensing or doctor blading.

(55) The curable imprintable ink 12 deposited in step B is subsequently embossed by a suitably patterned stamp 14 after alignment of the stamp with respect to the substrate 10, as shown in step C. In step C, the imprint orientation of the stamp 14 with the substrate 10 has been rotated 90 with respect to the imprint orientation used to form the first patterned layer 20. It will be appreciated that other orientation rotation angles are equally feasible.

(56) The curable imprintable ink 12 is subsequently solidified (densified), e.g. as shown in FIG. 1 to form solidified portions 20 as shown in step D. Obviously, the formation of the solidified portions 20 may be completed after removal of the stamp 14, i.e. by completing the inorganic polymerization reaction as previously discussed. Removing the stamp 14 leaves the densified portions 20 on the planarized layer 30 of step A. The newly formed patterned layer may again be planarized as shown in step E, after which additional layers may be formed by repeating the steps B-E.

(57) The height of the patterned portions of the patterned layer may be reduced using an additional processing step, e.g. by means of reactive ion etching.

(58) The filling material 22 can be removed afterwards by e.g. dissolving the filling material 22 in a suitable solvent or by thermal decomposition, thus yielding a stacked structure as shown in step F. The ink 12 is very suitable for application in this method because it can withstand most solvents required to dissolve the planarization material 22, as well as withstand high temperatures up to 600 or even 1000 C., thereby making it particularly suitable for use with thermally degradable compounds such as a TDP.

(59) In any of the aforementioned embodiments may it be necessary to remove residual imprint structures from e.g. the substrate 10, for instance when a layer on the substrate 10 has been patterned using the imprint structures as a mask. The imprint structures may be removed by any suitable etching technique, e.g. reactive ion etching.

(60) FIG. 6 shows an attenuated internal reflection IR spectrum of a 200 nm layer of an imprinting ink layer comprising 2.75 wt % MTMS, 3.07 wt % TMOS, 6.18 wt % water, 0.39 wt % 1M acetic acid, 81.67 wt % 1-propanol, 0.99 wt % of a 10% PAG solution, 3.96 wt % ethylene glycol and 0.99 wt % EEOL on a silicon substrate before and after sol-gel curing, i.e. activation of the PAG 103 using UV irradiation of 350 nm (R.sub.W in FIG. 6 expresses the relative water content expressed in mole water per mole silicon present in the ink). Region 610 depicts the OH stretch vibration of the SiOH groups, which diminishes during the curing reaction, as can be expected from the fact that the OH bonds are being replaced by SiOSi bonds, which stretch vibration is shown in region 630, and which shows a distinct increase in intensity during the progress of the curing reaction. Region 620 is attributed to the SiC stretch vibration of the SiCH.sub.3 groups.

(61) The influence of the presence of the PAG103 in this ink is shown in FIG. 7, which depicts the intensity of the OH stretch vibration of the SiOH groups around 3250 cm.sup.1 as a function of time in the attenuated internal reflection IR spectrum of a 200 nm imprinting ink layer on a silicon substrate with and without the presence of the 4 wt % PAG 103 in the ink. As will be immediately apparent, the activated PAG103 significantly accelerates the formation of the polycondensation products due to the associated decrease in the pH of the ink, as signaled by the rapid decrease of the intensity of the OH stretch vibration of the SiOH groups, which indicates that these groups are being consumed in the polycondensation reaction.

(62) It is noted that even in the absence of the PAG103 the polycondensation reaction eventually progresses, as evidenced by the gradual reduction in the intensity of the OH stretch vibration of the SiOH groups in the time interval from 5-15 minutes. This can be explained by the gradual evaporation of solvents and water from the ink layer, and/or by the absorption of the solvents into the stamp, which slowly decreases the pH of the ink as the protic acid in the ink becomes more concentrated. This decrease in pH shifts the equilibrium of the polycondensation reaction towards the polymer products as previously explained. Even if the pH stays constant, e.g. because of the simultaneous slow evaporation of the acid from the ink, the consequential increase of the concentration of the reagents partaking in the polycondensation reaction in the ink will cause the equilibrium of the polycondensation reaction to shift towards the polymer products.

(63) The present invention will now be explained in more detail by way of the following non-limiting examples.

(64) All IR spectra referred to in the present application have been recorded on a Perkin Elmer Spectrum One spectrophotometer.

Preparative Example 1

(65) An imprintable ink is provided comprising 5 wt % TMOS and 5 wt % MTMS, 0.09 wt % acetic acid, 25.4 wt % water, 52 wt % 1-propanol, 2 wt % EEE, 3 wt % EEOL (diethylene glycol monoethyl ether) and 2 wt % PAG 103 with respect to the solid content in the ink by mixing the components of the ink.

Preparative Example 2

(66) An imprintable ink is provided comprising 5 wt % TMOS and 5 wt % MTMS, 0.09 wt % acetic acid, 25.4 wt % water, 39 wt % 1-propanol, 13 wt % 1-butanol, 1 wt % EEOL and 1 wt % PAG 103 with respect to the solid content in the ink by mixing the components of the ink.

Preparative Example 3

(67) An imprintable ink is provided comprising 5 wt % TMOS and 5 wt % MTMS, 0.09 wt % acetic acid, 25.4 wt % water, 16.5 wt % 1-propanol, 38 wt % 1-methoxy-2-propanol, 1 wt % EEOL and 3 wt % PAG 103 with respect to the solid content in the ink by mixing the components of the ink.

Preparative Example 4

(68) An imprintable ink is provided comprising 5 wt % TMOS and 5 wt % MTMS, 0.09 wt % acetic acid, 25.4 wt % water, 16.5 wt % 1-propanol, 38 wt % 1-methoxy-2-propanol, 4 wt % EEE, 1 wt % EEOL and 3 wt % PAG 103 with respect to the solid content in the ink by mixing the components of the ink.

Preparative Example 5

(69) An imprintable ink is provided comprising 2.5 wt % MTMS, 0.09 wt % acetic acid, 25.4 wt % water, 56 wt % 1-propanol, 2 wt % EEOL and 4 wt % PAG 103 with respect to the solid content in the ink by mixing the components of the ink.

Preparative Example 6

(70) An ink is provided as in Preparation Example 1 but for the replacement of EEOL with 1 wt % MEOL (diethylene glycol monomethyl ether).

Preparative Example 7

(71) An ink is provided as in Preparation Example 1 but for the replacement of EEOL with 1 wt % triethylene glycol monomethyl ether.

Preparative Example 8

(72) An ink is provided as in Preparation Example 1 but for the replacement of EEOL with 1 wt % tetraethylene glycol monoethyl ether.

Preparative Example 9

(73) An imprintable ink is provided comprising 5 wt % TMOS and 5 wt % MTMS, 0.09 wt % acetic acid, 25.4 wt % water, 52 wt % 1-propanol, 2 wt % EEE, 3 wt % EEOL (diethylene glycol monoethyl ether) and 4 wt % PAG 103 with respect to the solid content in the ink by mixing the components of the ink.

Comparative Preparative Example 1

(74) An ink is provided as in Preparation Example 1 with the exception that EEOL has been omitted from the ink composition.

Comparative Preparative Example 2

(75) An ink is provided as in Preparation Example 1 but for the replacement of EEOL with 1 wt % ethylene glycol.

Comparative Preparative Example 3

(76) An ink is provided as in Preparation Example 1 but for the replacement of EEOL with 1 wt % 1,2-propanediol.

Comparative Preparative Example 4

(77) An ink is provided as in Preparation Example 1 but for the replacement of EEOL with 1 wt % 2-propoxy-ethanol.

Comparative Preparative Example 5

(78) An ink is provided as in Preparation Example 1 but for the replacement of EEOL with 1 wt % 2-butoxy-ethanol.

Comparative Example 6

(79) An ink is provided as in Preparation Example 9 but for the omission of EEOL and EEE from the ink.

(80) Imprinting Experiment

(81) The ink compositions of Preparative Examples 1-8 and Comparative Preparative Examples have been spun onto a silicon substrate (with native SiO.sub.2) by spin-coating for 10 seconds at 500 rpm and 20 seconds at 300 rpm to form an ink film on the glass substrate of approximately 250 nm thickness. The spun film is subsequently imprinted with a patterned PDMS stamp and irradiated with a mercury lamp for about 5 minutes. The PDMS was made as described in international patent application with international publication nr. WO2009/147602 using composition as in any one of rows 6 to 18 of the Table 1 in the reference and using 1,1,3,3-tetramethyl-1,3-divinyl-disiloxane-Pt complex as the Pt catalyst.

(82) The results of the imprinting experiment are summarized in Table II.

(83) TABLE-US-00002 TABLE II Ink composition Imprint result (after film spinning) Preparative Example 1 Ink can be imprinted with PDMS stamp, solidification of pattern after irradiation Preparative Example 2 Ink can be imprinted with PDMS stamp, solidification of pattern after irradiation Preparative Example 3 Ink can be imprinted with PDMS stamp, solidification of pattern after irradiation Preparative Example 4 Ink can be imprinted with PDMS stamp, solidification of pattern after irradiation Preparative Example 5 Ink can be imprinted with PDMS stamp, solidification of pattern after irradiation Preparative Example 6 Ink can be imprinted with PDMS stamp, solidification of pattern after irradiation Preparative Example 7 Ink can be imprinted with PDMS stamp, solidification of pattern after irradiation Preparative Example 8 Ink can be imprinted with PDMS stamp, solidification of pattern after irradiation Preparative Example 9 Ink can be imprinted with PDMS stamp, solidification of pattern after irradiation Comparative Premature cross-linking of ink; too rigid to Preparative Example 1 imprint Comparative Premature cross-linking of ink; too rigid to Preparative Example 2 imprint Comparative Premature cross-linking of ink; too rigid to Preparative Example 3 imprint Comparative Premature cross-linking of ink; too rigid to Preparative Example 4 imprint Comparative Premature cross-linking of ink; too rigid to Preparative Example 5 imprint Comparative Premature cross-linking of ink; too rigid to Preparative Example 6 imprint

(84) From the above, it can be concluded that the ink compositions according to embodiment of the present invention can be stored for prolonged periods of time without excessive crosslinking occurring in the ink composition, whilst at the same time allowing for controlled cross-linking upon activation of the PAG, photoinitiator or TAG therein. More specifically, the inclusion of a polycondensation inhibitor of Formula 3 to the ink composition and the setting of the pH of the ink composition to an appropriate value, excessive cross-linking of the silane compounds can be suppressed during storage of the ink whilst rapid reactivation of the polycondensation, i.e. cross-linking, reaction can be achieved by the activation of the PAG, photoinitiator or TAG in the ink composition, thus providing a stable and versatile ink composition that can be cross-linked on-demand.

(85) FIG. 8 depicts the intensity of the OH stretch vibration of the SiOH groups around 3250 cm.sup.1 as a function of time in the attenuated internal reflection IR spectrum of a 200 nm imprinting ink layer according to preparation example 9 and comparative example 6 respectively. As is immediately apparent, the addition of a compound according to Formula 3 (EEOL in this example) significantly reduces the cross-linking or polycondensation speed in the ink.

(86) FIG. 9 depicts the intensity of the OH stretch vibration of the SiOH groups around 3250 cm.sup.1 and a CH stretch vibration of the EEOL around 2850 cm.sup.1 and FIG. 10 depicts the intensity of the SiOSi stretch vibration of the polycondensation product around 1100-1000 cm.sup.1 as a function of time in the attenuated internal reflection IR spectrum of a 200 nm imprinting ink layer according to preparation example 9.

(87) From the simultaneous reduction in intensity of the OH stretch vibration of the SiOH groups around 3250 cm.sup.1 and the increase in intensity of the SiOSi stretch vibration of the polycondensation product around 1100-1000 cm.sup.1 it can be concluded that the SiOH groups are converted into SiOSi groups, indicating a shift in the equilibrium towards the polycondensation product. Interestingly, the decrease in the intensity of the CH stretch vibration of the EEOL around 2850 cm.sup.1 over time not only demonstrates that the EEOL is released from the silane oligomers but furthermore demonstrates that the EEOL is removed from the imprinting ink through diffusion into the stamp material. For the avoidance of doubt, FIG. 11 shows the IR spectrum of EEOL from which it can be unambiguously derived that the stretch vibration at around 2850 cm.sup.1 and indicated by the arrows in both FIG. 9 and FIG. 11 originates from EEOL.

(88) It should be noted that the above-mentioned embodiments illustrate rather than limit the invention, and that those skilled in the art will be able to design many alternative embodiments without departing from the scope of the appended claims. In the claims, any reference signs placed between parentheses shall not be construed as limiting the claim. The word comprising does not exclude the presence of elements or steps other than those listed in a claim. The word a or an preceding an element does not exclude the presence of a plurality of such elements. The mere fact that certain measures are recited in mutually different dependent claims does not indicate that a combination of these measures cannot be used to advantage.