Method for producing a multilayer element, and multilayer element

Abstract

A method for producing a multilayer body, as well as a multilayer body produced thereby. A single- or multi-layered first decorative ply is applied to a carrier ply with a first and a second side. A metal layer is applied to the side of the first decorative ply facing away from the carrier ply and structured such that the metal layer is provided with a first layer thickness in one or more first zones and is provided with a second layer thickness different from the first layer thickness in one or more second zones, wherein in particular the second layer thickness is equal to zero. A single- or multi-layered second decorative ply is applied to the side of the metal layer facing away from the first decorative ply and structured using the metal layer as mask such that the first or second decorative ply is at least partially removed in the first or second zones.

Claims

1. A method for producing a multilayer body, wherein, in the method: a) a single- or multi-layered first decorative ply is applied to a carrier ply; b) at least one metal layer is applied to the side of the first decorative ply facing away from the carrier ply; c) a single- or multi-layered second decorative ply is applied to the side of the metal layer facing away from the first decorative ply; d) the at least one metal layer is structured using the second decorative ply as a mask by application of an etchant and removal of the areas of the metal layer not protected by the mask such that the metal layer is provided with a first layer thickness in one or more first zones of the multilayer body and is provided with a second layer thickness different from the first layer thickness in one or more second zones of the multilayer body, wherein the second layer thickness is equal to zero; e) the first decorative ply is structured using the metal layer as a mask in a first area of the multilayer body by application of a solvent and removal of the areas of the first decorative ply not protected by the metal layer mask such that the first decorative ply is at least partially removed in the second zones, wherein the carrier ply comprises, on the side facing the first decorative ply, at least one detachment layer and/or a protective varnish layer, and wherein the first and/or second decorative ply comprises a replication varnish layer into which a surface relief is molded, and/or wherein a surface relief is molded into the surface of the carrier ply facing the first decorative ply.

2. A method according to claim 1, wherein the second decorative ply is applied patterned by printing, wherein the second decorative ply is provided with a third layer thickness in the first zones and is provided with a fourth layer thickness different from the third layer thickness in the second zones, wherein the fourth layer thickness is equal to zero.

3. A method according to claim 1, wherein the second decorative ply is resistant to an etchant used to structure the metal layer as well as to a solvent used to structure the first decorative ply.

4. A method according to claim 1, wherein the second decorative ply comprises one or more colored layers which are applied using a printing process.

5. A method according to claim 1, wherein the surface relief comprises a diffractive structure, a microlens array or a retroreflective structure.

6. A method according to claim 1, wherein, after the structuring of the metal layer, the first decorative ply and/or the second decorative ply, a compensation layer is applied, which lies on the areas of surface, facing away from the carrier ply, of the first decorative ply, the second decorative ply and/or the carrier ply.

7. A method according to claim 1, wherein a protective varnish is applied to the multilayer body on the side of the multilayer body facing away from the carrier ply.

8. A method according to claim 1, wherein the first and/or second decorative ply is bleached by illumination.

9. A multilayer body comprising: a carrier ply defining a whole surface of the multilayer body, a single- or multi-layered first decorative ply applied to the carrier ply; a single- or multi-layered second decorative ply; and at least one metal layer arranged between the first and second decorative plies, wherein the metal layer is structured using the second decorative ply as a mask by application of an etchant and removal of the areas of the metal layer not protected by the mask such that, in a first area of the multilayer body, the at least one metal layer is provided with a first layer thickness in one or more first zones of the multilayer body and is provided with a second layer thickness different from the first layer thickness in one or more second zones of the multilayer body, wherein the second layer thickness is equal to zero, and wherein the first decorative ply is structured using the metal layer as a mask by application of a solvent and removal of the areas of the first decorative ply not protected by the metal layer mask such that the first and second decorative plies are structured congruent with each other as well as with the metal layer such that, in the first area in the first or second zones, the first and second decorative plies are at least partially removed congruent with each other as well as with the metal layer, wherein the carrier ply comprises, on the side facing the first decorative ply, at least one detachment layer and/or a protective varnish layer, and wherein the first and/or second decorative ply comprises a replication varnish layer into which a surface relief is molded, and/or wherein a surface relief is molded into the surface of the carrier ply facing the first decorative ply.

10. A multilayer body according to claim 9, wherein the first and/or second decorative ply comprises one or more layers which are dyed with at least one opaque and/or at least one transparent colorant which is colored or color-generating at least in a wavelength range of the electromagnetic spectrum, and is multicolored or multicolor-generating, wherein a colorant is contained in one or more of the layers of the first and/or second decorative ply which can be excited outside the visible spectrum and produces a visually recognizable colored impression.

11. A multilayer body according to claim 9, wherein the first and/or second decorative ply comprises one or more layers which are dyed with at least one colorant of the color yellow, magenta, cyan or black (CMYK) or of the color red, green or blue (RGB), and/or is provided with at least one radiation-excitable pigment or colorant which fluoresces in red and/or green and/or blue and thereby generates an additive color when irradiated.

12. A multilayer body according to claim 9, wherein the at least one metal layer is arranged on the surface of the at least one relief structure.

13. A multilayer body according to claim 12, wherein the at least one relief structure is arranged at least partially in the first zones and/or in the second zones and is arranged congruent with the first or second zones.

14. A multilayer body according to claim 12, wherein recesses of the first and/or of the second decorative ply and/or of the at least one metal layer are filled with a compensation layer, and the refractive index of the compensation layer in the visible wavelength range lies in the range of from 90% to 110% of the refractive index of the replication varnish layer.

15. A multilayer body according to claim 9, wherein first and/or second decorative layer comprises one or more of the following layers: liquid crystal layer, polymer layer, thin-film layer, pigment layer.

16. A multilayer body according to claim 9, wherein the first and/or second decorative ply has a thickness in the range of from 0.5 to 5 m.

17. A multilayer body according to claim 9, wherein one or more layers of the first and/or second decorative ply has nanoscale UV absorbers based on inorganic oxides.

18. A multilayer body according to claim 9, wherein the metal layer has a thickness in the range of from 20 to 70 nm.

19. A multilayer body according to claim 9, wherein recesses of the first and/or of the second decorative ply and/or of the at least one metal layer are filled with a compensation layer.

20. A multilayer body according to claim 19, wherein the compensation layer is formed as an adhesion layer.

21. A security element for security or value documents, in the form of a transfer film or laminating film, which has a multilayer body according to claim 9.

22. A security document with a security element according to claim 21.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) The invention is explained by way of example with reference to the drawings. There are shown in:

(2) FIG. 1a a schematic section of a first manufacturing stage of the multilayer body represented in FIG. 1d;

(3) FIG. 1b a schematic section of a second manufacturing stage of the multilayer body represented in FIG. 1d;

(4) FIG. 1c a schematic section of a third manufacturing stage of the multilayer body represented in FIG. 1d;

(5) FIG. 1d a schematic section of a multilayer body according to the invention produced according to a first embodiment of the method according to the invention;

(6) FIG. 2a a schematic section of a first manufacturing stage of the multilayer body represented in FIG. 2d;

(7) FIG. 2b a schematic section of a second manufacturing stage of the multilayer body represented in FIG. 2d;

(8) FIG. 2c a schematic section of a third manufacturing stage of the multilayer body represented in FIG. 2d;

(9) FIG. 2d a schematic section of a multilayer body according to the invention produced according to a second embodiment of the method according to the invention;

(10) FIG. 3a a schematic section of a first manufacturing stage of the multilayer body represented in FIG. 3e;

(11) FIG. 3b a schematic section of a second manufacturing stage of the multilayer body represented in FIG. 3e;

(12) FIG. 3c a schematic section of a third manufacturing stage of the multilayer body represented in FIG. 3e;

(13) FIG. 3d a schematic section of a fourth manufacturing stage of the multilayer body represented in FIG. 3e;

(14) FIG. 3e a schematic section of a multilayer body according to the invention produced according to a third embodiment of the method according to the invention;

(15) FIG. 4a a schematic section of a first manufacturing stage of the multilayer body represented in FIG. 4d;

(16) FIG. 4b a schematic section of a second manufacturing stage of the multilayer body represented in FIG. 4d;

(17) FIG. 4c a schematic section of a third manufacturing stage of the multilayer body represented in FIG. 4d;

(18) FIG. 4d a schematic section of a multilayer body according to the invention produced according to a fourth embodiment of the method according to the invention.

DETAILED DESCRIPTION OF THE INVENTION

(19) FIGS. 1a to 3e are in each case drawn schematically and not to scale, in order to ensure a clear representation of the important features.

(20) FIG. 1a shows an intermediate product 100a in the production of a multilayer body 100, which is represented in the finished state in FIG. 1d.

(21) The multilayer body 100 according to FIG. 1d comprises a carrier ply with a first side 11 and a second side 12. The carrier ply comprises a carrier film 1 and a functional layer 2. A first decorative ply 3 which comprises a first varnish layer 31 formed in a first zone 8 and a replication layer 4 is arranged on the functional layer 2. A metal layer 5 is arranged on the replication layer 4 registered relative to the first varnish layer 3. A second decorative ply 7 arranged registered relative to the metal layer 5 is provided on the metal layer 5. A compensation layer 10 fills height differences between the replication layer 4, the metal layer 5 and the second decorative ply 7.

(22) The carrier film 1 is a preferably transparent plastic film with a thickness of between 8 m and 125 m, preferably in the range of from 12 to 50 m, further preferably in the range of from 16 to 23 m. The carrier film 1 can be formed as a mechanically and thermally stable film of a light-permeable material, e.g. of ABS (=acrylonitrile-butadiene-styrene), BOPP (=biaxially oriented polypropylene), but preferably of PET. The carrier film 1 here can be monoaxially or biaxially stretched. Further, it is also possible for the carrier film 1 to consist not only of one layer, but also to consist of several layers. It is thus possible for example for the carrier film 1 to have, in addition to a plastic carrier, for example a plastic film described above, a detachment layer which makes it possible to detach the layer structure consisting of the layers 2 to 6 and 10 from the plastic film, for example when the multilayer body 100 is used as a hot-stamping film.

(23) The functional layer 2 can comprise a detachment layer, e.g. made of hot-melting material, which makes it easier to detach the carrier film 1 from the layers of the multilayer body 100 which are arranged on a side of the detachment layer 2 facing away from the carrier film 1. This is advantageous in particular if the multilayer body 100 is formed as a transfer ply, such as is used e.g. in a hot-stamping process or an IMD process. Furthermore, it has proved to be worthwhile, in particular if the multilayer body 100 is used as a transfer film, if the functional layer 2, in addition to a detachment layer, has a protective layer, e.g. a protective varnish layer. After the multilayer body 100 has been joined to a substrate and the carrier film 1 has been detached from the layers of the multilayer body 100 which are arranged on a side of the detachment layer 2 facing away from the carrier film 1, the protective layer forms one of the upper layers of the layers arranged on the surface of the substrate and can protect layers arranged underneath from wear, damage, chemical attacks or the like. The multilayer body 100 can be a section of a transfer film, for example a hot-stamping film, which can be arranged on a substrate by means of an adhesive layer. The adhesive layer is preferably arranged on the side of the compensation layer 10 facing away from the carrier film 1. The adhesive layer can be a hot-melt adhesive which melts when exposed to heat and joins the multilayer body 100 to the surface of the substrate.

(24) The transparent, colored varnish layer 31 is printed on the functional layer 2 in the zone 8. Transparent means that the varnish layer 31 is at least partially radiation-permeable in the visible wavelength range. Colored means that the varnish layer 31 shows a visible color impression under sufficient natural light.

(25) The varnish layer 31 here can comprise several differently dyed partial areas, as indicated for example by different shading in FIG. 1d. A first motif can be provided hereby. Further, the decorative ply 7, as indicated by different shading in FIG. 1d, can also form differently colored areas or areas with different optical properties which in particular provide a second motif.

(26) Both the zones 8 on which the varnish layer 31 is printed and the unprinted zones 9 of the functional layer 2 are covered by a replication layer 4 which preferably equalizes possibly present relief structures of the decorative ply 3, i.e. the differing levels in the printed 8 and the unprinted 9 zones.

(27) A thin metal layer 5 is arranged on the replication layer 4 registered relative to and, when viewed perpendicular to the plane of the carrier ply 1, congruent with the varnish layer 31. A second decorative ply 7 is arranged congruent with the metal layer 5. Both the zones 8 of the replication layer 4 covered with the metal layer 5 and decorative ply 7 and the uncovered zones 9 of the replication layer 4 are covered with a compensation layer 10 which equalizes, i.e. covers and fills in, structures brought about by the relief structures and the metal layer 5 arranged in areas 8 (e.g. relief structure, different layer thicknesses, height offset), with the result that the multilayer body has a flat, substantially structureless, surface on the side of the compensation layer 10 turned away from the carrier film 1.

(28) If the compensation layer 10 has a similar refractive index to the replication layer 4, i.e. if the refractive index difference is smaller than approximately 0.15, then the zones of the relief structures in the replication layer 4 not covered with the metal layer 5 and directly adjoining the compensation layer 10 are optically erased, because there are no longer any optically recognizable layer boundaries between the replication layer 4 and the compensation layer 10 there due to the similar refractive index of the two layers.

(29) FIGS. 1a to 1c now show manufacturing stages of the multilayer body 100 represented in FIG. 1d. Elements identical to those in FIG. 1d are given identical reference numbers.

(30) FIG. 1a shows a first manufacturing stage 100a of the multilayer body 100, in which on a first side 11 the carrier film 1 comprises a functional layer 2, on which in turn a decorative ply 3 is arranged. One side of the functional layer 2 adjoins the carrier film 1, its other side adjoins the decorative ply 3. The decorative ply 3 has a first zone 8, in which a varnish layer 31 is formed, and a second zone 9, in which the varnish layer 31 is not present. The varnish layer 31 is printed onto the functional layer 2, e.g. by screen printing, gravure printing or offset printing. A patterned design of the decorative ply 3 results from the formation of the varnish layer 31 in areas (in the first zones 8). Further, it is also possible for the varnish layer to consist of several partial layers which in particular overlap in areas and which have in particular different optical properties, in particular are dyed differently. The varnish layer 31 preferably has a layer thickness of from 0.1 m to 2 m, particularly preferably of from 0.3 m to 1.5 m.

(31) A replication layer 4, which is a constituent of the first decorative ply 3, is applied to the functional layer 2 and the varnish layer 31 arranged thereon in areas (in the zones 8). This can be an organic layer which is applied in liquid form by standard coating processes, such as printing, casting or spraying. The application of the replication layer 4 here is provided over the whole surface. The layer thickness of the replication layer 4 varies, as it compensates for/equalizes the different levels of the decorative ply 3, comprising the printed first zone 8 and the unprinted second zone 9; the layer thickness of the replication layer 4 is thinner in the first zone 8 than in the second zone 9, with the result that the side of the replication layer 4 turned away from the carrier ply 1 has in a flat, substantially structureless surface before the formation of relief structures.

(32) The replication varnish layer 9 preferably has a layer thickness of from 0.1 m to 3 m, particularly preferably of from 0.1 m to 1.5 m.

(33) However, an application of the replication layer 4 only in a partial area of the multilayer body 100 can also be provided. The surface of the replication layer 4 can be structured in areas using known methods. For this, for example as replication layer 4, a thermoplastic replication varnish is applied by printing, spraying or varnishing and a relief structure is molded into the, in particular thermally curable/dryable, replication varnish 4 by means of a heated stamp or a heated replication roller. The replication layer 4 can also be a UV-curable replication varnish which is structured for example using a replication roller and at the same time and/or subsequently cured by means of UV radiation. However, the structuring can also be produced by UV radiation through an illumination mask.

(34) The metal layer 5 is applied to the replication layer 4. The metal layer 5 can for example be formed as a vapor-deposited metal layer, e.g. made of silver or aluminum. The application of the metal layer is here provided over the whole surface. However, an application only in a partial area of the multilayer body 100 can also be provided, e.g. with the aid of an evaporation mask that shields in areas.

(35) The metal layer preferably has a layer thickness of from 20 nm to 70 nm.

(36) A photoactivatable resist layer 6 is applied to the metal layer 5. In the present embodiment example the resist layer 6 is formed as a positive resist (dissolving of the activated=illuminated areas). The resist layer 6 can be an organic layer which is applied in liquid form using standard coating processes, such as printing, casting or spraying. It can also be provided that the resist layer 6 is vapor-deposited or laminated on as a dry film.

(37) The photoactivatable layer 6 can be for example a positive photoresist AZ 1512 from Clariant or MICROPOSIT S1818 from Shipley, which is applied with an area density of from 0.1 g/m.sup.2 to 10 g/m.sup.2, preferably of from 0.1 g/m.sup.2 to 1 g/m.sup.2, to the layer 5 to be structured. The layer thickness complies with the desired resolution and the process. The application is provided here over the whole surface. However, an application only in a partial area of the multilayer body 100 can also be provided.

(38) FIG. 1b shows a second manufacturing stage 100b of the multilayer body 100, in which the first manufacturing stage 100a of the multilayer body 100 was irradiated and then developed. Electromagnetic radiation with a wavelength which is suitable for activating the photoactivatable resist layer 6 is radiated through the multilayer body 100d from the second side 12 of the carrier film 1, i.e. the side of the carrier film 1 which lies opposite the side of the carrier film 1 coated with the resist layer 6. The irradiation serves to activate the photoactivatable resist layer 6 in the second zone 9, in which the decorative ply 3 shows a higher transmittance than in the first zone 8. The strength and duration of the illumination with the electromagnetic radiation is matched to the multilayer body 100a such that the radiation in the second zone 9 leads to an activation of the photoactivatable resist layer 6, while the radiation in the first zone 8 on which the varnish layer 31 is printed does not lead to an activation of the photoactivatable resist layer 6. It has proved to be worthwhile if the contrast between the first zone 8 and the second zone 9 brought about by the varnish layer 31 is greater than two. Further, it has proved to be worthwhile if the varnish layer 31 is designed such that after passing through the whole multilayer body 100a the radiation has a ratio of the transmittances, i.e. a contrast ratio, of approximately 1:2 between the first zone 8 and the second zone 9.

(39) The illumination is preferably effected with an illuminance of from 100 mW/cm.sup.2 to 500 mW/cm.sup.2, preferably of from 150 mW/cm.sup.2 to 350 mW/cm.sup.2.

(40) To develop the illuminated resist layer 6 a developer solution, e.g. solvents or bases, in particular a sodium carbonate solution or a sodium hydroxide solution, is applied to the surface of the illuminated photoactivatable resist layer 6 turned away from the carrier film 1. The illuminated resist layer 6 has thereby been removed in the second zone 9. The resist layer 6 is preserved in the first zone 8, because the amount of radiation absorbed in these zones has not led to a sufficient activation. As already mentioned, in the embodiment example represented in FIG. 1a the resist layer 6 is thus formed from a positive photoresist. In the case of such a photoresist the more strongly illuminated zones 9 are soluble in the developer solution, e.g. the solvent. In contrast, in the case of a negative photoresist the non-illuminated or less strongly illuminated zones 8 are soluble in the developer solution.

(41) The metal layer 5 is then removed in the second zone 9 using an etchant. This is possible because in the second zone 9 the metal layer 5 is not protected by the developed resist layer 6 acting as etch mask from attack by the etchant. The etchant can be for example an acid or base, for example NaOH (sodium hydroxide) or Na.sub.2CO.sub.3 (sodium carbonate) in a concentration of from 0.05% to 5%, preferably of from 0.3% to 3%. In this way the areas of the metal layer 5 shown in FIG. 1b are formed.

(42) In the next step the preserved areas of the resist layer 6 are likewise also removed (stripping).

(43) In this way the metal layer 5 can thus be structured registration-accurate relative to the first and second zones 8 and 9 defined by the varnish layer 31 without additional technological outlay. In conventional methods for producing an etch mask by means of mask illumination, wherein the mask is present either as a separate unit, e.g. as a separate film or as a separate glass plate/glass cylinder, or as a subsequently printed layer, the problem arises that linear and/or non-linear deformations in the multilayer body 100 brought about by earlier process steps, in particular with high levels of thermal and/or mechanical stress, e.g. when a replication structure is produced in the replication layer 4, cannot be compensated for completely over the whole surface of the multilayer body 100, although the mask alignment is effected using existing registration or register marks (usually arranged on the horizontal and/or vertical edges of the multilayer body). The tolerance fluctuates over the whole surface of the multilayer body 100 within a comparatively large range.

(44) The first and second zones 8 and 9 defined by the varnish layer 31 are thus used as a mask, wherein the varnish layer 31 is applied, as described above, in an early process step during the production of the multilayer body 100. In this way no additional tolerances and also no additional tolerance fluctuations can occur over the surface of the multilayer body 100, as the subsequent production of a mask and the thereby necessary, as registration-accurate as possible, subsequent positioning of this mask which is independent of the previous course of the process are avoided. The tolerances or registration accuracies in the method according to the invention are based only on the not absolutely precise course of the color edge of the first and second zones 8 and 9 defined by the varnish layer 31, the quality of which is determined by the respectively used printing method, and lie approximately in the micrometer range, and thus far below the resolving power of the eye; i.e. the naked human eye can no longer perceive any tolerances present.

(45) The next intermediate product 100c represented in FIG. 1c is obtained from the intermediate product 100b by, in particular partial, application of a further, second decorative ply 7 to the zones 8 covered by the structured layer 5 and to the zones 9 of the replication layer 4 not covered by the structured layer 5. The second decorative ply 7 comprises at least one second photoactivatable resist layer. The second decorative ply 7 preferably has two or more, in particular differently dyed, second resist layers. The second resist layers here can also be printed patterned. The second resist layers can also be constructed multi-layered. The second resist layers can also be partially colorlessly transparent or translucent, i.e. have no dyeing.

(46) As with the first resist layer 6, the second resist layer can be for example a positive photoresist AZ 1512 from Clariant or MICROPOSIT S1818 from Shipley, which is applied with an area density of from 0.1 g/m.sup.2 to 10 g/m.sup.2, preferably of from 0.5 g/m.sup.2 to 1 g/m.sup.2. The application is provided here over the whole surface. However, an application only in a partial area of the multilayer body 100 can also be provided. As the second decorative ply 7 is to be preserved at least in areas in the finished multilayer body 100, colorants, pigments, nanoparticles or the like can additionally be introduced into the varnish, in order to achieve an optical effect.

(47) The second decorative ply 7 is now also illuminated from the side 12 of the carrier ply 1, for which the parameters already described for the illumination of the first resist layer 6 can be used. During the illumination of the second decorative ply 7 the varnish layer 31 and the metal layer 5 now act together as a mask, with the result that the at least one resist layer of the second decorative ply 7 is only illuminated in the zone 9, while the zone 8 covered by varnish layer 31 and structured layer 5 remains non-illuminated. Like the first resist layer 6, the second decorative ply 7 is now treated, for the developing, with a developer solution, e.g. a base, in particular a sodium carbonate solution or a sodium hydroxide solution. The illuminated resist layer of the second decorative ply 7 is thereby removed in the second zone 9. The second resist layer is preserved in the first zone 8, because the amount of radiation absorbed in these zones has not led to a sufficient activation. When a negative resist is used, this is inverted, as already described, with the result that the second resist layer is removed in the first zone 8 and preserved in the second zone 9.

(48) The multilayer body 100 represented in FIG. 1d is formed from the manufacturing stage 100c of the multilayer body 100 represented in FIG. 1c, by application of a compensation layer 10 to the exposed second decorative ply 7 arranged in the first zone 8 as well as to the replication layer 4 arranged in the second zone 9 and exposed by removal of the metal layer 5 and the first 6 and second resist layer. The application of the compensation layer 10 here is provided over the whole surface.

(49) In particular a UV-crosslinked or a heat-crosslinked varnish is used as compensation layer.

(50) It is possible for the compensation layer 10 to be applied with a different layer thickness in the first zone 8 and the second zone 9 in each case, e.g. by doctor blade, printing or spraying, with the result that the compensation layer 10 has a flat, substantially structureless surface on its side turned away from the carrier ply 1. The layer thickness of the compensation layer 10 varies, as it compensates for/equalizes the different levels of the metal layer 5 arranged in the first zone 8 and the replication layer 4 exposed in the second zone 9. The layer thickness of the compensation layer 10 in the second zone 9 is chosen to be greater than the layer thickness of the metal layer 5 in the first zone 8, with the result that the side of the compensation layer 10 turned away from the carrier ply 1 has a flat surface. However, an application of the compensation layer 10 only in a partial area of the multilayer body 100 can also be provided. It is possible for one or more further layers, e.g. an adhesion or adhesive layer, to be applied to the flat compensation layer 10.

(51) With the described method, the first and second zones 8 and 9 defined by the varnish layer 31 as well as by the metal layer 5 are thus used as a mask for the structuring of the second decorative ply 7. In this way no additional tolerances and also no additional tolerance fluctuations can occur over the surface of the multilayer body 100, as the subsequent production of a mask and the thereby necessary, as registration-accurate as possible, subsequent positioning of this mask which is independent of the previous course of the process are avoided. A multilayer body 100 is thus obtained in which the varnish layer 31 of the decorative ply 3, the metal layer 5 and the second decorative ply 7 are arranged perfectly registered.

(52) FIG. 2d shows a further multilayer body 200 which is produced using a variant of the method. The method steps and intermediate products 200a, 200b and 200c are shown in FIGS. 2a to 2c. The further multilayer body 200 corresponds to the multilayer body 100 represented in FIG. 1d. The same reference numbers are therefore used for identical structures and functional elements.

(53) The multilayer body 200 also comprises a carrier ply with a first side 11 and a second side 12. The carrier ply comprises a carrier film 1 and a functional layer 2. A first decorative ply 3 which is formed of a replication layer 4 is arranged on the functional layer 2. Alternatively, the decorative ply 3 can also be formed multi-layered and for example can have a dyed layer and a replication layer. A metal layer 5 is arranged on the replication layer 4. A second decorative ply 7 arranged registered relative to the metal layer 5 is provided on the metal layer 5. A compensation layer 10 fills height differences between the replication layer 4, the metal layer 5 and the second decorative ply 7. The materials and application methods already described with reference to the multilayer body 100 can be used for the individual layers.

(54) The multilayer body 200 differs from the multilayer body 100 only in that the decorative ply 3 does not have separate varnish areas 31, but is formed completely from a colored replication varnish, which can contain colorants, pigments, UV-activatable substances, nanoparticles or the like, or alternatively is formed completely from a correspondingly dyed varnish layer and a transparent colorless replication varnish.

(55) During the production of the multilayer body 200 the intermediate product 200a shown in FIG. 2a is provided first. Analogously to the production of the multilayer body 100 a carrier film 1 is first provided with a functional layer 2, to which the decorative ply 3 is applied over the whole surface. As already described, reliefs, for example diffractive structures, can additionally also be introduced into the replication layer 4 of the decorative ply 3. The replication layer 4 is then metallized over the whole surface in the already described manner. A second decorative ply 7 comprising one or more, also differently dyed, resist layers is now printed onto part of the surface of the thus-obtained metallic layer 5 to be structured, with the result that the metal layer 5 is protected by the second decorative ply 7 in the zone 8, while the metal layer 5 is not covered by the second decorative ply 7 in the zone 9. To produce the desired optical effects, the second decorative ply 7 comprises layers, in particular resist layers, which can contain colorants, pigments, UV-activatable substances, nanoparticles or the like. The second decorative ply 7 can be formed for example from a PVC-based varnish.

(56) In order to obtain the intermediate product 200b shown in FIG. 2b, the intermediate product 200a of the multilayer body 200 is now treated with an etchant, in particular a sodium carbonate solution or a sodium hydroxide solution, which is applied to the surface of the intermediate product 200a turned away from the carrier film 1. While the zone 8 is protected by the second decorative ply 7 from the exposure, the base can dissolve the metal layer 5 in the zone 9, with the result that the metal layer 5 is removed in the zone 9. It can hereby be achieved that the metal layer 5 is formed perfectly registered relative to the second decorative ply 7. The second decorative ply 7 here thus acts as an etch resist.

(57) The intermediate product 200b is subsequently treated with a solvent, which should preferably have a flash point of more than 65 C. The solvent is chosen such that the second decorative ply 7 is impervious to the solvent, while the material of the replication layer 4 can dissolve in the solvent.

(58) Suitable varnishes in particular for the replication varnish 4, which have these properties, are for example polyacrylates or polyacrylates in combination with cellulose derivatives.

(59) In the zone 8, however, the replication layer is protected by the metal layer 5 and the second decorative ply 7 from attack by the solvent, with the result that the replication layer 4 only dissolves in the unprotected zone 9. The intermediate product 200c shown in FIG. 2c is obtained hereby.

(60) In order to obtain the finished multilayer body 200, a compensation layer 10 is finally also applied which compensates for possibly present relief structures in the replication layer 4, as well as the removed zones 9 of the replication layer 4 and the metal layer 5, with the result that a smooth surface of the multilayer body 200 results. As with the multilayer body 100, of course, still further functional layers or the like can also be applied.

(61) In contrast to the previously described method, no illumination is thus necessary here in order to obtain an arrangement of three layers (first decorative ply 3, metal layer 5 and second decorative ply 7) in which registration is maintained. The resolution of the produced structures is only limited by the resolution achievable when the second decorative ply 7 is printed as well as by the lateral in-diffusion of the base or of the solvent in the corresponding method steps.

(62) FIG. 3e shows a further multilayer body 300, which is produced using a variant of the method. The method steps and intermediate products 300a, 300b, 300c and 300d are shown in FIGS. 3a to 3d. The further multilayer body 300 likewise corresponds to the multilayer bodies 100 and 200 represented in FIG. 1d and FIG. 2d. The same reference numbers are therefore used for identical structures and functional elements.

(63) The multilayer body 300 also comprises a carrier ply with a first side 11 and a second side 12, which comprises a carrier film 1 and a functional layer 2. A replication layer 4 which is dyed and at the same time functions as first decorative ply 3 is arranged on this. Alternatively, the decorative ply 3 can also be formed multi-layered and for example can have a dyed layer and a replication layer. A metal layer 5 registered relative to the first decorative ply 3 and a second decorative ply 7 arranged registered relative to the metal layer 5 are provided on the replication layer 4. Height differences of the replication layer 4, the metal layer 5 and the second decorative ply 7 are filled by a compensation layer 10.

(64) The materials and application methods already described with reference to the multilayer body 100 can be used for the individual layers. As with the multilayer body 200, the multilayer body 300 also differs from the multilayer body 100 only in that the decorative ply 3 does not have separate varnish areas 31, but is formed completely from a colored replication varnish, which can contain colorants, pigments, UV-activatable substances, nanoparticles or the like, or alternatively is formed completely from a correspondingly dyed varnish layer and a transparent colorless replication varnish.

(65) FIG. 3a shows a first intermediate product 300a in the production of the multilayer body 300 according to a variant of the method. Analogously to the production of the multilayer bodies 100 and 200, a carrier film 1 is first provided with a functional layer 2, to which the decorative ply 3 is applied over the whole surface. As already described, reliefs, for example diffractive structures, can additionally also be introduced into the replication layer 4 of the decorative ply 3. The replication layer 4 is then metallized over the whole surface in the already described manner. A resist 6 is now applied to the thus-obtained metal layer 5 over the whole surface.

(66) A mask 13 is now placed on the side of the resist 6 facing away from the carrier film 1. In contrast to the method described for the production of the multilayer body 100, however, the mask 13 here is a separate part, thus is not formed by structures of the multilayer body 300 itself. The mask comprises zones 8, which are non-transparent for the electromagnetic radiation used to illuminate the photoactivatable resist 6, as well as zones 9, which are transparent for said radiation. As the mask 13 is arranged on the side of the resist 6 facing away from the carrier film 1, the illumination of the resist 6 must likewise be effected from this side, thus cannot be effected from the side of the carrier film 1, as in the production of the multilayer body 100. However, all further parameters of the illumination and subsequent developing of the resist 6 correspond to the method explained with reference to the production of the multilayer body 100. After the illumination of the resist 6 the mask 13 can be removed, and the resist 6 can be developed in the already described manner. The metal layer 5 is then structured in the likewise already described manner using an etchant.

(67) A combination of a positive resist 6 with a positive mask 13 is used in the example shown. The resist 6 is thus protected by the mask in the zone 8 and only illuminated in the zone 9. The resist 6 is thus removed in the zone 9 during the developing, with the result that the metal layer 5 is exposed in the zone 5 and is removed by the etchant in the subsequent etching step. Of course, a negative mask in combination with a negative resist can also be used.

(68) After the etching, the intermediate product 300b shown in FIG. 3b is obtained, in which the structured layer is only still present in the zones 8, while the replication layer 4 is exposed in the zones 9. In addition, the resist 6 is still present in the zones 8 on the surface of the metal layer 5 facing away from the carrier film 1.

(69) In order to obtain the intermediate product 300c shown in FIG. 3c from the intermediate product 300b, the resist 6 is removed (stripped) by solvent treatment. For this, reference is made to the statements according to FIGS. 2c and 2d. This can also be effected in the manner already described for the production of the multilayer body 100. When the resist 6 is removed, the replication layer 4 is removed at the same time in the zone 9, in which it is not protected by the metal layer 5.

(70) In the next method step, a second decorative ply 7 is now applied to the metal layer 5 or the exposed zones 9 of the functional layer 2 over the whole surface, with the result that the intermediate product 300d shown in FIG. 3d is obtained. The second decorative ply 7 comprises at least one layer made of a photoactivatable resist, preferably two or more photoactivatable, differently dyed layers, and at the same time acts as a compensation layer which compensates for the height differences due to the partial removal of the metal layer 5 and the replication layer 4. As with the multilayer body 100, the second decorative ply 7 partially remains in the finished multilayer body and undertakes an optical function there. The second decorative ply 7 therefore comprises at least one layer which is dyed with colorants, pigments, UV-active substances, nanoparticles or the like.

(71) In the intermediate product 300d, the zone 8 formed by the remaining decorative ply 3 and the metal layer 5 is non-transparent for the electromagnetic radiation used to illuminate the resist of the second decorative ply 7. Analogously to the production of the multilayer body 100, an illumination of the resist of the second decorative ply 7 can thus now be effected from the side of the carrier film and the resist can then be developed in the already described manner. As the remaining decorative ply 3 acts together with the metal layer 5 as a mask, the resist is thus only illuminated in the zone 9. When a positive resist is used, the resist is thus detached in the zone 9 during the developing, with the result that it is only preserved where it lies directly on the metal layer 5.

(72) In order to achieve the finished multilayer body 300, the zone 9 in which the resist of the second decorative ply 7 was removed is provided with a compensation layer 10, in order to compensate for the height differences. Optionally, a crosslinked, transparent seal layer 14 can also be applied to the side of the multilayer body 300 facing away from the carrier film 1, in order to protect its surface from mechanical damage.

(73) With this method too, a structure of three registration-accurate layers, namely the first decorative ply 3, the metal layer 5 and the second decorative ply 7, is thus obtained. As an external mask is only used for the structuring of the metal layer 5, which then acts as mask for the removal of the replication layer in the zone 8 or for the illumination of the resist of the second decorative ply 7 in the zone 8, the problems described at the beginning in the case of the use of masks do not occur here. The remaining zones 8 of the first decorative ply 3 and of the second decorative ply 7 inevitably form grid-accurate relative to the metal layer 5.

(74) FIG. 4d shows a further multilayer body 400, which is produced using a variant of the method. The method steps and intermediate products 400a, 400b and 400c are shown in FIGS. 4a to 4c.

(75) The multilayer body 400 differs from the multilayer body 100 shown in FIG. 1a only in that the second decorative ply 7 is formed of a photoactivatable resist layer in a first partial area and of a partially applied etch resist layer in a second partial area. In the second partial area, as in the first partial area, the decorative ply 3 can have first zones 8 and/or second zones 9.

(76) In the first partial area the structure of the multilayer body 400 corresponds to the multilayer body 100 in FIGS. 1a to 1d and the method steps described there are also carried out in order to produce a multilayer body 400, as is shown in the first partial area in FIG. 4d. Deviating from the multilayer body 100, the second partial area is now provided in which, instead of the photoactivatable resist layer 6, an etch resist layer 15 is partially applied. The motif or the outer shape of the etch resist layer 15 is to determine the motif or the outer shape of the partial metallization to be achieved. The etch resist layer 15 can consist for example of a PVC-based varnish and be dyed by means of pigments and/or colorants or be colorlessly transparent or translucent.

(77) After the developing of the photoactivatable resist layer, the metal layer 5 is removed in the second zone 9 by an etchant. This is possible because in the second zone 9 the metal layer 5 is not protected from attack by the etchant by the developed resist layer 6 acting as etch mask in the first partial area as well as the etch resist layer 15 likewise acting as etch mask in the second partial area. The etchant can be for example an acid or base, for example NaOH (sodium hydroxide) or Na.sub.2CO.sub.3 (sodium carbonate) in a concentration of from 0.05% to 5%, preferably of from 0.3% to 3%. In this way, the areas of the metal layer 5 shown in FIG. 4b are formed.

(78) In the next step the preserved areas of the resist layer 6 are likewise also removed (stripping). However, the etch resist layer 15 is preserved on the metal layer 5.

(79) In this way, the metal layer 5 can thus be structured in the first partial area registration-accurate relative to the first and second zones 8 and 9 defined by the varnish layer 31 and in the second partial area registration-accurate relative to the etch resist layer 15 without additional technological outlay.

(80) As in FIG. 1c, in FIG. 4c a further, second decorative ply 7 is now applied in the first partial area to the zones 8 covered by the structured layer 5 and to the zones 9 of the replication layer 4 not covered by the structured layer 5. The second decorative ply 7 comprises at least one second photoactivatable resist layer. The second decorative ply 7 preferably has two or more, in particular differently dyed, second resist layers. The second resist layers here can also be printed patterned. The etch resist layer 15 still present in the second partial area likewise forms a part of the decorative ply 7.

(81) Alternatively the application of the decorative ply 7 in the first partial area can also be dispensed with, with the result that the metal layer 5 is present without coating in the first partial area and with the applied etch resist layer 15 in the second partial area. For example, a dyeing of the metal layer 5 by means of dyed etch resist layer 15 can thereby be effected only in the second partial area and although the metal layer 5 is present in the first partial area registration-accurate relative to the first decorative ply, it is not dyed on the side facing away from the first decorative ply and in the case of aluminum reflects in a silvery, glossy manner.

(82) As described with respect to FIGS. 1c and 1d, the decorative ply 7 is illuminated, developed and partially removed in the first partial area.

(83) As shown in FIG. 1d, in the multilayer body 400 represented in FIG. 4d is also formed from the manufacturing stage 400c of the multilayer body 400 represented in FIG. 4c by application of a compensation layer 10 to the exposed second decorative ply 7 arranged in the first zone 8 as well as to the replication layer 4 arranged in the second zone 9 and exposed by removal of the metal layer 5 and the first 6 and second resist layers. The application of the compensation layer 10 here is provided over the whole surface. The compensation layer 10 can be designed single- or multi-layered or can also be dispensed with. It is possible for an adhesion-promoter layer (adhesive layer) (not shown here), which itself can also be formed multi-layered, to be applied to the side of the compensation layer 10 turned away from the carrier ply.

LIST OF REFERENCE NUMBERS

(84) 1 Carrier film 2 Functional layer 3 First decorative ply 4 Replication layer 5 Metal layer 6 Resist layer 7 Second decorative ply 8 First zone 9 Second zone 10 Compensation layer 11 First side 12 Second side 13 Mask 14 Seal layer 15 Etch resist layer 31 First varnish layer (of 3) 32 Second varnish layer (of 3) 100 Multilayer body 200 Multilayer body 300 Multilayer body 400 Multilayer body