Polyolefin catalyst and use thereof

Abstract

Disclosed is a new polyolefin catalyst and preparation therefor. Specifically, disclosed is a catalytic system comprising a new complex of iron, cobalt, nickel, palladium, and platinum. In the presence of the catalytic system, oily polyethylene can be efficiently obtained from simple olefins such as ethylene under mild conditions, highly branched oily alkane mixture is then obtained after hydrogenation. The alkane mixture can be used as a processing aid and a high-performance lubricant base oil. The present invention also provides a method for preparing the catalyst, a method for preparing the highly branched oily alkane mixture and a method for preparing functional polyolefin oil.

Claims

1. A complex, wherein said complex is formed by a compound of formula I and a divalent or trivalent metal salt, and the complex of the structure represented by following formula II: ##STR00157## wherein, Y.sup.1 is C1-C8 alkyl, C1-C8 haloalkyl, or unsubstituted or substituted phenyl; Y.sup.2 is CR.sub.4R.sub.5, O or S, R.sub.4 and R.sub.5 are independently C1-C4 alkyl or haloalkyl; or Y.sup.1 and Y.sup.2, and the CC bond attached to both of them together forms unsubstituted or substituted 5-12 member ring; ##STR00158## together with Y.sup.3, is substituted 5-7 member monocyclic, or bicyclic or tricyclic group containing said 5-7 member monocyclic ring, wherein the 5-7 member monocyclic ring contains 1-3 N, O or S atoms, and contains at least one N; Y.sup.3 is one or more substituents on the 5-7 member monocyclic ring, or bicyclic or tricyclic group containing said 5-7 member monocyclic ring, at least one Y.sup.3 is halogen, C1-C8 alkyl, C1-C8 haloalkyl, unsubstituted or substituted phenyl, unsubstituted or substituted benzyl, OR.sub.7, CH.sub.2OR.sub.8, SR.sub.9, or CH.sub.2SR.sub.10, wherein R.sub.7, R.sub.8, R.sub.9 and R.sub.10 are independently C1-C8 alkyl, or unsubstituted or substituted phenyl; Z is C1-C8 alkyl, C1-C8 haloalkyl, unsubstituted or substituted phenyl, or unsubstituted or substituted naphthyl, provided that Y.sup.1 and Z, and the CN bond attached to both of them together do not form unsubstituted or substituted 5-12 member ring; wherein, the substituted in the above definitions means that the group possesses 1-5 substituents selected from the group consisting of C1-C4 alkyl, C1-C4 haloalkyl, halogen, nitro, cyano, CF.sub.3, OR.sub.1, N(R.sub.2).sub.2, Si(R.sub.3).sub.3, CH.sub.2OR.sub.8, SR.sub.9, CH.sub.2SR.sub.10, CH(R.sub.10).sub.2, and phenyl which is unsubstituted or substituted by 1-5 substituents selected from the group consisting of C1-C4 alkyl and C1-C4 haloalkyl, wherein R.sub.1, R.sub.2 and R.sub.3 are independently C1-C4 alkyl or haloalkyl; while R.sub.8, R.sub.9 and R.sub.10 are independently C1-C8 alkyl or phenyl; M is nickel or palladium; X is independently halogen, C1-C4 alkyl, C2-C6 alkenyl, allyl (), .sup.OAc, .sup.OTf, or benzyl.

2. The complex of claim 1, wherein ##STR00159## is selected from the following group: ##STR00160## Y.sup.4 is halogen, C1-C8 alkyl, C1-C8 haloalkyl, unsubstituted or substituted phenyl, unsubstituted or substituted benzyl, OR.sub.7, CH.sub.2OR.sub.8, SR.sub.9, or CH.sub.2SR.sub.10, wherein R.sub.7, R.sub.8, R.sub.9 and R.sub.10 are independently C1-C8 alkyl, or unsubstituted or substituted phenyl; Y.sup.5, Y.sup.6, Y.sup.7, Y.sup.8, Y.sup.9, Y.sup.10 and Y.sup.11 are independently H, halogen, C1-C8 alkyl, C1-C8 haloalkyl, unsubstituted or substituted phenyl, unsubstituted or substituted benzyl, OR.sub.7, CH.sub.2OR.sub.8, SR.sub.9 or CH.sub.2SR.sub.10, wherein R.sub.7, R.sub.8, R.sub.9 and R.sub.10 are independently C1-C8 alkyl, or unsubstituted or substituted phenyl.

3. The complex of claim 1, wherein the compound I is of the following structure: ##STR00161## wherein, Y.sup.3 or Z are defined as in claim 1; n is 0, 1, 2, or 3; ##STR00162## is unsubstituted or substituted 5-7 member monocyclic, or bicyclic or tricyclic group containing said 5-7 member monocyclic ring; G.sup.1, G.sup.2, G.sup.3 and G.sup.4 are independently H, halogen, C1-C8 alkyl, C1-C8 haloalkyl, silicon group, unsubstituted or substituted phenyl, unsubstituted or substituted benzyl, OR.sub.7, CH.sub.2OR.sub.8, SR.sub.9 or CH.sub.2SR.sub.10, wherein R.sub.7, R.sub.8, R.sub.9 and R.sub.10 are independently C1-C8 alkyl, unsubstituted or substituted phenyl; wherein the substituted is defined as above.

4. The complex of claim 1, wherein the bicyclic ring containing the 5- to 7-membered monocyclic ring is a spiro or fused ring, and the compound has any of the following structures: ##STR00163## wherein each n is independently 1, 2, 3, or 4; Y.sup.1, Y.sup.2 and Z are defined as in claim 1; Y.sup.4 and Y.sup.5 are independently H, halogen, C1-C8 alkyl, C1-C8 haloalkyl, unsubstituted or substituted phenyl, unsubstituted or substituted benzyl, OR.sub.7, CH.sub.2OR.sub.8, SR.sub.9 or CH.sub.2SR.sub.10, wherein R.sub.7, R.sub.8, R.sub.9 and R.sub.10 are independently C1-C8 alkyl, unsubstituted or substituted phenyl; provided that Y.sup.4 and Y.sup.5 cannot be halogen, OR.sub.7 or SR.sub.9 simultaneously, and Z is unsubstituted or substituted phenyl, or unsubstituted or substituted naphthyl, wherein substituted in the above definitions means that the group possesses 1-5 substitutents selected from the following groups: C1-C4 alkyl and C1-C4 haloalkyl, halogen, nitro, cyano, CF.sub.3, OR.sub.1, N(R.sub.2).sub.2, Si(R.sub.3).sub.3, CH.sub.2OR.sub.8, SR.sub.9, CH.sub.2SR.sub.10, CH(R.sub.10).sub.2, or phenyl which is unsubstituted or substituted by 1-5 substituents selected from the following group: C1-C4 alkyl, and C1-C4 haloalkyl, wherein R.sub.1, R.sub.2, R.sub.3 are independently C1-C4 alkyl or haloalkyl; while R.sub.8, R.sub.9 and R.sub.10 are independently C1-C8 alkyl or phenyl; the substituted phenyl group has at most one nitro or cyano group; and Z is one of the following group: ##STR00164##

5. The complex of claim 1, wherein the Y.sup.1 and Y.sup.2 form unsubstituted or substituted C6-C8 ring together with the CC bond attached with both of them.

6. A complex, wherein said complex is formed by a compound of formula I and a divalent or trivalent metal salt, and the complex of the structure represented by following formula II: ##STR00165## wherein, Y.sup.1 is unsubstituted or substituted phenyl; Y.sup.2 is O; or Y.sup.1 and Y.sup.2, and the CC bond attached to both of them together form unsubstituted or substituted 5-12 member ring; ##STR00166## together with Y.sup.3, is substituted 5-7 member monocyclic, or bicyclic or tricyclic group containing said 5-7 member monocyclic ring, wherein the 5-7 member monocyclic ring contains 1-3 N, O or S atoms, and contains at least one N; Y.sup.3 is one or more substituents on the 5-7 member monocyclic ring, or bicyclic or tricyclic group containing said 5-7 member monocyclic ring, at least one Y.sup.3 is C1-C8 alkyl or C1-C8 haloalkyl; Z is unsubstituted or substituted phenyl, provided that Y.sup.1 and Z, and the CN bond attached to both of them together do not form unsubstituted or substituted 5-12 member ring; wherein, the substituted in the above definitions means that the group possesses 1-5 substituents selected from the group consisting of C1-C4 alkyl, C1-C4 haloalkyl, halogen, nitro, cyano, CF.sub.3, OR.sub.1, N(R.sub.2).sub.2, Si(R.sub.3).sub.3, CH.sub.2OR.sub.8, SR.sub.9, CH.sub.2SR.sub.10, CH(R.sub.10).sub.2, and phenyl which is unsubstituted or substituted by 1-5 substituents selected from the group consisting of C1-C4 alkyl and C1-C4 haloalkyl, wherein R.sub.1, R.sub.2 and R.sub.3 are independently C1-C4 alkyl or haloalkyl; while R.sub.8, R.sub.9 and R.sub.10 are independently C1-C8 alkyl or phenyl; M is iron, cobalt, nickel, palladium, or combinations thereof; and X is independently halogen, C1-C4 alkyl, C2-C6 alkenyl, allyl (), OAc, OTf, or benzyl.

7. A complex, wherein said complex is formed by a compound of formula I and a divalent or trivalent metal salt, and the complex of the structure represented by following formula II: ##STR00167## wherein the complex of formula II is selected from the group consisting of: ##STR00168## ##STR00169## ##STR00170## ##STR00171## ##STR00172## ##STR00173## ##STR00174## ##STR00175## ##STR00176## ##STR00177##

8. A method for preparing the complex of claim 1, the method comprising the following steps: in an inert solvent, treating the compound I with a divalent or trivalent metal salt to provide the complex of claim 1 wherein the divalent or trivalent metal salt is selected from the group consisting of NiCl.sub.2, NiBr.sub.2, NiI.sub.2, (DME)NiBr.sub.2, PdCl.sub.2, PdBr.sub.2, Pd(OTf).sub.2, Pd(OAc).sub.2, (COD)PdMeCl, and combinations thereof.

9. A method for preparing an oily polyolefin, the method comprising the following steps: (a) catalyzing olefins polymerization by the complex according to claim 1, in the presence of alkylaluminum compound as cocatalyst to form an oily polyolefin; wherein the olefin is ethylene, propylene or C4-C20 -olefins, inner olefins, dienes, or the mixtures thereof.

10. The method of claim 9, wherein further comprises the following steps: (b) hydrogenating the oily polyolefin obtained in step (a) to obtain a hydrogenated oily alkane mixture.

Description

DESCRIPTION OF THE DRAWINGS

(1) FIG. 1 shows the .sup.13C NMR spectrum of the polymer prepared in Example 125 of the present invention.

(2) FIG. 2 shows the molecular structure of the complexes 2-9 of Example 57 of the present invention.

(3) FIG. 3 shows the .sup.13C NMR spectrum of the polymer prepared in Example 198 of the present invention.

(4) FIG. 4 shows the change of inner temperature of the polymerization system and ethylene flow versus time during the reaction of Example 201 of the present invention.

(5) FIG. 5 shows the .sup.13C NMR spectrum of the polymer prepared in Example 201 of the present invention.

(6) FIG. 6 shows the .sup.13C NMR spectrum of the polymer prepared in Example 208 of the present invention.

(7) FIG. 7 shows the .sup.13C NMR spectrum of the polymer prepared in Example 245 of the present invention.

(8) FIG. 8 shows the change of shear viscosity with shear rate at different temperatures of samples P1-hydrogenation, P2-hydrogenation and P3-hydrogenation (alkane mixture).

(9) FIG. 9 shows photo of the polymer prepared in Example 248 of the present invention.

EMBODIMENTS FOR CARRYING OUT THE INVENTION

(10) After extensive and deeply studies, the present inventors have prepared a novel ligand compound, a complex and a catalytic system, thus directly polymerizing non-polar and/or polar olefin monomer comprising functional group to obtain highly branched oily polymer. The catalyst technology of the present invention enables the preparation of a series of clean oily olefin polymers with different viscosities, including polar functional group-containing polyolefin oils, which can significantly reduces the cost of high quality lubricating oils. The inventor has completed the present invention on this basis.

Terms

(11) Unless otherwise indicated, all the chiral centers in each compound of the present invention can be any structure, such as R configuration, S configuration, or racemism.

(12) Alkyl means saturated aliphatic hydrocarbon group, including straight chain and branched chain groups containing 1 to 10 carbon atoms, preferably median size alkyl groups having 1 to 6 carbon atoms, such as methyl, ethyl, propyl, 2-propyl, n-butyl, i-butyl, t-butyl, pentyl, and the like, more preferably lower alkyl groups having 1 to 4 carbon atoms, such as methyl, ethyl, propyl, 2-propyl, n-butyl, i-butyl, t-butyl, and the like.

(13) Alkenyl means unsaturated aliphatic hydrocarbon group having carbon-carbon double bond (CC), including straight chain and branched chain groups containing 2-10 (preferably 2-6) carbon atoms.

(14) Alkynyl means unsaturated aliphatic hydrocarbon group having carbon-carbon triple bond, including straight chain and branched chain groups containing 2-10 (preferably 2-6) carbon atoms.

(15) Cycloalkyl refers to a 3-8 member percarbon monocyclic ring, percarbon 5 member/6 member or 6 member/6 member fused ring or fused ring group in which one or more rings may contain one or multiple double bonds, but none of the rings have fully conjugated n-electron system. Examples of cycloalkyl groups are cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cyclohexadienyl, adamantyl, cycloheptyl, cycloheptatrienyl and the like.

(16) Carbocycle means saturated or unsaturated rings of which the ring skeleton are all carbon atoms, wherein one or more rings may contain one or more double bonds.

(17) Heterocycle means saturated or unsaturated rings which comprises at least one hetero atom selected from the following group: N, S, O or P, wherein one or more rings may contain one or more double bonds.

(18) 5-7 member monocyclic refers to a 5-membered to 7-membered monocyclic (only one ring structure) ring which may be a saturated or unsaturated ring, such as cycloalkyl, cycloalkenyl, aromatic ring.

(19) Bicyclic or tricyclic group means groups containing two or three ring structures, such as fused, spiro, or bridged ring structures, such as indolyl, quinolyl, and the like. In the present invention, preferred bicyclic or tricyclic groups are 8 to 20 member rings. Bicyclic or tricyclic group comprising monocycle A means that one or more rings in bicyclic or tricyclic group is (are) monocyclic ring A.

(20) Aromatic ring means aromatic rings having a conjugated n-electron system, including carbocyclic aryl group and heteroaryl group.

(21) Heteroaryl means aryl group which comprises one hetero atom as ring atom, and the remaining ring atoms are carbon, wherein the hetero atom comprises the following: oxygen, sulfur, nitrogen. The ring may be 5, 6 or 7 member rings. Examples of heteroaryl groups include, but are not limited to, furyl, thienyl, benzofuranyl, benzothienyl, pyridyl, pyrrolyl, N-alkylpyrrolyl.

(22) Alkoxy refers to O (alkyl). Representative examples include methoxy, ethoxy, propoxy, butoxy, and the like.

(23) The term halogen refers to F, Cl, Br and I.

(24) The ligand compounds of the present invention may contain one or more chiral centers and thus appear in the form of racemates, racemic mixtures, single enantiomers, diastereomeric compounds and single diastereomers. The existence of chiral centers depends on the nature of the various substituents on the molecule. Each chiral center will independently produce two optical isomers, and all possible optical isomers and diastereomeric mixtures and pure or partially pure compounds are included within the scope of the present invention. The present invention encompasses all such isomeric forms of ligand compounds. Some of the ligand compounds of the present invention may exist in tautomeric form with different hydrogen linkages accompanied with one or more double bond shifts.

(25) As used herein, the term inert solvent means solvents that do not chemically react with other components with which are to be mixed.

(26) Specifically, in the present invention, structures such as

(27) ##STR00020##
means that Y.sup.3 is optional substituent (s) (of which the position and number are not limited), and the position and number of the substituent (s) can be any that conforms to the definition of the present invention and the rule of substitution in the common knowledge in the field.

(28) In the present invention, the DME is glycol dimethyl ether; the .sup.OTf is trifluoromethanesulfonate negative ion; the .sup.OAc is acetate anion; the COD is cyclooctadiene.

(29) Unless otherwise indicated, a hydrogen atom on a substituted group is substituted by a substitutent selected from the following groups: C1-C4 alkyl and C1-C4 haloalkyl, halogen, nitro, cyano, CF.sub.3, OR.sub.1, N(R.sub.2).sub.2, Si(R.sub.3).sub.3, CH.sub.2OR.sub.8, SR.sub.9 or CH.sub.2SR.sub.10, wherein R.sub.1, R.sub.2 and R.sub.3 are independently C1-C4 alkyl or haloalkyl; while R.sub.8, R.sub.9 and R.sub.10 are independently C1-C8 alkyl or phenyl.

(30) As used herein, the term alkane with multiple ends means alkyl groups possessing one or more methyl groups, such as t-butyl, i-propyl, and the like.

(31) Ligand Compound

(32) The present invention has provided a ligand compound of formula I.

(33) ##STR00021##

(34) wherein the remaining groups are defined as above.

(35) Preferably, Y.sup.1 is selected from the following group: hydrogen, methyl, trifluoromethyl, n-butyl, n-hexyl, phenyl, C1-C4 alkyl-phenyl; wherein the phenyl may be substituted by alkyl, halogen, alkoxy, C1-C4 amino, nitro, cyano, trimethylsilyl substituted phenyl; aforesaid halogen comprises fluorine, chlorine, bromine and iodine; the alkoxy is preferably methoxy, ethoxy, isopropyl; the alkyl group is preferably C1-C6 alkyl group, more preferably C1-C4 alkyl group, most preferably methyl, ethyl, isopropyl and butyl, and the substituent may on any position of the phenyl which can be replaced.

(36) Preferably, Z is selected from the following group: i-propyl, t-butyl, phenyl, C1-C4 alkyl-phenyl; wherein the phenyl may be substituted by alkyl, halogen, alkoxy, or alkoxy-alkyl substituted phenyl; aforesaid halogen comprises fluorine, chlorine, bromine and iodine; the alkoxy is preferably methoxy, ethoxy, isopropyl; the alkyl group is preferably C1-C6 alkyl group, more preferably C1-C4 alkyl group, most preferably methyl, ethyl, isopropyl and butyl, and the substituent may be on any probable position of the phenyl.

(37) Preferably,

(38) ##STR00022##
wherein Y.sup.4, Y.sup.5, Y.sup.6, Y.sup.7 the substituent is C1-C4 alkyl, C1-C4 alkoxy-alkyl, phenyl, C1-C4 alkyl-phenyl, or phenyl substituted by C1-C6 alkyl, halogen, alkoxy; the halogen comprises fluorine, chlorine, bromine and iodine; the alkoxy is preferably methoxy, ethoxy, isopropyl; the alkyl group is preferably C1-C6 alkyl group, more preferably C1-C4 alkyl group, most preferably methyl, ethyl, isopropyl and butyl, and the substituent may be on any probable position of the phenyl.

(39) Or one of Y.sup.4, Y.sup.5 forms substituted or unsubstituted phenyl with one of Y.sup.6 and Y.sup.7.

(40) Preferably, Y.sup.4 and Y.sup.5 together with the adjacent carbon atom can form unsubstituted or substituted C5-C8 saturated carbon ring.

(41) Preferably, Y.sup.6 and Y.sup.7 together with the adjacent carbon atom can form unsubstituted or substituted C5-C8 saturated carbon ring.

(42) Preferably,

(43) ##STR00023##
wherein Y.sup.4, Y.sup.5, Y.sup.6, Y.sup.7 the substituent is isopropyl, tertbutyl, phenyl, or phenyl substituted by C1-C6 alkyl, halogen, alkoxy; the halogen comprises fluorine, chlorine, bromine and iodine; the alkoxy is preferably methoxy, ethoxy, isopropyl; the alkyl group is preferably C1-C6 alkyl group, more preferably C1-C4 alkyl group, most preferably methyl, ethyl, isopropyl and butyl, and the substituent may on any probable position of the phenyl; Y.sup.12 is H, C1-C8 alkyl, C1-C8 haloalkyl, unsubstituted or substituted phenyl, unsubstituted or substituted benzyl. Or one of Y.sup.4, Y.sup.5 forms substituted or unsubstituted phenyl with one of Y.sup.6 and Y.sup.7.

(44) Preferably, Y.sup.4 and Y.sup.5 together with the adjacent carbon atom can form unsubstituted or substituted C5-C8 saturated carbon ring.

(45) Preferably, Y.sup.6 and Y.sup.7 together with the adjacent carbon atom can form unsubstituted or substituted C5-C8 saturated carbon ring.

(46) In another preferred embodiment, the compound of formula I has the following structure:

(47) ##STR00024##

(48) wherein:

(49) Y.sup.3, Z, G.sup.1, G.sup.2, G.sup.3 and G.sup.4 are defined as above;

(50) n is 0, 1, 2, or 3.

(51) The alkyl group may be substituted alkyl group, and preferred substituents are halogen, alkoxy, phenoxy; the halogen includes fluorine, chlorine, bromine or iodine; aforesaid alkoxy is preferably methoxy, ethoxy, isopropoxy, more preferably methoxy.

(52) A particularly preferred ligand includes ligand L1-1 to L1-48 shown in Examples 1 to 48.

(53) In the present invention, the most preferred ligand structure comprises:

(54) ##STR00025## ##STR00026## ##STR00027##

(55) Complex

(56) In the present invention, compounds of formula I could react with divalent nickel or palladium salts to form the corresponding nickel or palladium complex.

(57) In the present invention, the complex of formula II is preferred:

(58) ##STR00028##

(59) wherein each group is defined as above.

(60) X may be halogen, C1-C4 alkyl, C2-C6 alkenyl, allyl (), benzyl; wherein the C1-C4 alkyl is preferably methyl; the halogen is preferably bromine, chlorine or iodine.

(61) In another preferred embodiment, X is chlorine, bromine, iodine, methyl, allyl () or benzyl.

(62) In another preferred embodiment, X is chlorine, bromine or iodine.

(63) In the present invention, the ligand compound of the present invention could react with a divalent metal precursor, thereby forming the corresponding complex.

(64) In the present invention, the divalent metal precursor include: NiCl.sub.2, NiBr.sub.2, NiI.sub.2, (DME)NiBr.sub.2, (DME)NiCl.sub.2, (DME)NiI.sub.2, PdCl.sub.2, PdBr.sub.2, Pd(OTf).sub.2 and Pd(OAc).sub.2.

(65) The metal catalyst of the present invention can catalyze the polymerization of ethylene, propylene, butylene, and C4-C20 -olefins, inner olefins, diolefins or mixtures thereof under the action of co-catalyst to obtain oily polymer; it can also catalyze the co-polymerization of the above olefins such as monoolefins, dienes and the like with polar monomers comprising polar functional group so as to obtain functional polyolefin oil.

(66) Preparation of Ligand Compound and Complex

(67) The present invention also provides the synthesis of the ligand compounds of formula I, comprising the following steps:

(68) (a) oxidization of heterocyclic compound A to give compound B.

(69) (b) treating compound B with amine compound C to give ligand I.

(70) The compound A, B, and C are shown as below:

(71) ##STR00029##

(72) In particular, abstract hydrogen of the heterocyclic compound A by a base in an inert organic solvent, and then oxidization of the resulting anion to form compound B by oxygen, air, or other oxidizing agents. In an inert solvent, compound B condensed with compound C in the presence of a catalyst that promotes the condensation reaction. The inert solvent comprises alcohol, aromatic hydrocarbon, aliphatic hydrocarbon, halogenated hydrocarbon, ether, and ester, preferably aromatic hydrocarbon such as toluene, xylene, trimethylbenzene, and the like. The catalyst for promoting condensation reaction comprises formic acid, acetic acid, p-toluenesulfonic acid, TiCl.sub.4, orthosilicate.

(73) Step (a) is preferably carried out in an inert solvent for 3 to 48 hours, respectively.

(74) Preferably, in step (b), 0.001-100% corresponding catalyst (the molar ratio to the reactant) for promoting condensation reaction is added, preferably acetic acid, p-toluenesulfonic acid, TiCl.sub.4, or orthosilicate.

(75) In step (b), the ratio of compound B to C is preferably (0.7-1.2):1.

(76) The preferred inert solvent in step (a) is diethyl ether or tetrahydrofuran.

(77) The preferred inert solvent in step (b) is alcohols, aromatic hydrocarbons, aliphatic hydrocarbons, halogenated hydrocarbons, ethers and ester.

(78) Step (b) is directly carried out after the resulting B is separated with or without purification.

(79) The invention also provides a method for preparing complexes. For example, nickel complexes could be synthesized by compound I and metal salts, comprising NiCl.sub.2, NiBr.sub.2, NiI.sub.2 (DME)NiBr.sub.2, (DME)NiCl.sub.2, or (DME)NiI.sub.2 under an anhydrous and anaerobic condition and in inert solvent. The inert solvent used may be any conventional solvent which does not affect the reaction, including alcohols, aromatic hydrocarbons, aliphatic hydrocarbons, halogenated hydrocarbons, ethers, esters, and nitriles, preferably halogenated hydrocarbons. Better results could be obtained in solvent of halogenated hydrocarbon and esters, and preferred examples are methylene chloride, 1,2-dichloroethane, ethyl acetate, tetrahydrofuran.

(80) Wherein, Y.sup.1-Y.sup.12, Z, X are defined as abovementioned. DME refers to ethylene glycol dimethyl ether; when X is a hydrocarbon group, for example methyl or benzyl, the complex usually could be prepared from the corresponding chloride or bromide II with methyl Grignard reagent or benzyl Grignard reagent under the conventional conditions of the similar reaction. No matter what is X (X is halogen, hydrocarbon group or any other group that can coordination with nickel, such as nitrogen-containing compound, oxygen-containing compound), as long as NiC bond or NiH bond could be formed in the presence of alkyl aluminum, that is, namely the catalysis can be achieved. These compounds have the same active site in catalyzing ethylene polymerization, and thus exhibit the same or similar properties.

(81) Catalytic Systems and Applications

(82) The present invention provides a catalytic system for olefin polymerization to obtain highly branched alkane mixture, and the catalytic system comprises 1) the complexes formed by nickel or palladium metal salt with ligand of formula I; 2) hydrogenation system.

(83) ##STR00030##

(84) wherein each group is defined as above.

(85) Highly branched alkanes could be prepared directly from ethylene in the presence of both the above polymerization catalytic system and hydrogenation catalyst. The highly branched alkanes mean aliphatic hydrocarbons having the following characteristic: there is 100-500 methyl per 1000 methylene in the polymer chain, and the bromine number is less than 0.5 g/100 g. Typically, the method includes the following two steps:

(86) 1) in the presence of the above-mentioned metal complexes and cocatalyst, preparing highly branched oily polyolefin directly from olefin.

(87) 2) Hydrogenating the oily polyolefin obtained in step (1) to obtain the hydrogenated oily alkane mixture.

(88) The metal complex is a complex formed by the reaction of compounds of formula I and divalent nickel or palladium, preferably, the metal complex is nickel complexes of formula II.

(89) The co-catalyst is reagents that can promote the polymerization, and may be alkyl aluminum compounds or organic boron reagents.

(90) The alkyl aluminum compound comprises any carbon-aluminum bond-containing compounds, including methylaluminoxane (MAO), modified methylaluminoxane (MMAO), triethylaluminum, triisobutylaluminum, diethylaluminum chloride, ethylaluminum dichloride and so on. Wherein the ratio of aluminum in co-catalyst to nickel or palladium in catalyst is 10 to 5000; methyl aluminoxane or alkyl aluminum reagents herein is co-catalyst to help nickel or palladium complex in catalyzing olefin polymerization to obtain oily polyolefin, and the structure of methyl aluminoxane or alkyl aluminum reagents would not affect the co-catalysis effect, except that the branching degree and the molecular weight of the obtained polymer would be influenced, wherein methyaluminoxane, diethylaluminum chloride, and ethylaluminum dichloride could obtain the best results. In another case, desired results could be obtained with the co-catalysis by AlCl.sub.3 alone or together with alkyl aluminum compounds.

(91) In step (1), the metal complex can be preprepared previously, or prepared in situ. That is to say, the metal complex is used in the polymerization system, or the ligand and metal precursor for the preparation of metal complex are used directly so as to form the metal complex in situ during the reaction procedure.

(92) The highly branched polyethylene of the present invention can be hydrogenated to form highly branched alkanes.

(93) The structure of the highly branched polyolefin (such as polyethylene) is determined by .sup.13C NMR and comparison of molecular weight measured by HT-GPC and the actual molecular weight measured by laser light scattering. The highly branched alkane is clear and transparent oil with molecular weight of 500-500,000 g/mol.

(94) Depending on the specific requirements, in step (1), the contacting time of ethylene and nickel or palladium complexes and alkyl aluminum compounds in inert solvent can be 0.5 to 72 hours, the reacting temperature range is 0-100 C., and the pressure (gauge pressure) range is 0.1-3 MPa (1-30 atm).

(95) In step (2), the highly branched oily polyethylene obtained in step (1) is treated with reductant, or the oily polyolefin was contacted with hydrogen in the presence of one or more reduction catalyst, to obtain highly branched oily alkane mixture with the bromine number less than 0.5 g/100 g. The reduction catalyst can be any catalyst for promoting the hydrogenation process, preferably, hydrogenation catalysts selected from Pd/C, Pd(OH).sub.2, PtO.sub.2, rhodium, nickel, ruthenium and so on. The reduction reagents can be any agent that can reduce a double bond, mainly are borane compound, triethyl silane and so on.

(96) In another preferred embodiment, between step (1) and step (2) further comprised is a step of separating oily polyethylene.

(97) In another preferred embodiment, in step (1), hydrogenation reaction is simultaneously conducted.

(98) In another preferred embodiment, the step (2) may be carried out in an inert solvent or directly be carried out in the oily olefin polymer; the step (1) may be carried out in inert solvent or be carried out in oily olefin polymers (such as oily polyethylene).

(99) Particularly, step (2) can also be completed by the following ways of: a) in step (1), hydrogen is introduced simultaneously to obtain highly branched oily alkane; b) after step (1), the polymerizing system, without processing, is purged with hydrogen, thereby obtaining highly branched oily alkane; c) after step (1), the polymerizing system, without processing, is added with one or more reducing catalyst for hydrogenation, thereby giving highly branched oily alkane; d) after step (1), separating the oily polyethylene and conducting the hydrogenation reaction.

(100) The above reaction can be conducted in an inert solvent, preferably alcohols, alkanes, aromatic hydrocarbons and halogenated hydrocarbons. Of them, in step (1), saturated C5-C12 hydrocarbon is preferred, such as hexane, heptane; halogenated hydrocarbons such as dichloromethane, 1,2-dichloroethane, 1,1,2,2-tetrachloroethane; aromatic hydrocarbons such as toluene, xylene. In step (2), saturated C5-C12 hydrocarbon is preferred, such as hexane, heptane; halogenated hydrocarbons such as dichloromethane, 1,2-dichloroethane, 1,1,2,2-tetrachloroethane; aromatic hydrocarbons such as toluene, xylene.

(101) In addition to non-polar monomer, by modifying the structure of catalysts' substituents, the catalytic system can efficiently catalyze polymerization of polar monomer, or catalyze any combination of polar monomer or non-polar monomer so as to obtain functional oily polymer.

(102) The olefin polymer of the present invention has high branching degree, preferably being dendrimer, or spherical, spherical-like polymer, and the polymer can also be used to obtain highly branched alkane by hydrogenation step (2).

(103) In another preferred embodiment, step (1) further comprises hydrogenation simultaneously; In another preferred embodiment, step (2) may be carried out in an inert solvent or directly be carried out in the oily polyolefin as a solvent; step (1) may be carried out in inert solvent or be carried out in oily polyolefin as a solvent.

(104) In addition to ethylene, the other olefin used in the present invention may be -olefins or inner olefins, which would not affect the catalytic effect. The inner olefins mean the double bond is at any position other than the end. In the application, the inner olefin can be a mixture of various isomers or a single inner olefin. For example, as for butene, it can be 1-C4, 2-C4, and 2-C4 can be cis-isomer and trans-isomer. When used, it is not limited to 1-C4 or cis-2-C4 or trans-2-C4, and it also can be a mixture of one or more isomer(s), which would not affect the polymerization process.

(105) Oily Polyolefin and Oily Alkane Mixture

(106) Catalysts disclosed in the present invention can be applied to the industrially current-used ethylene, propylene and butane polymerization process, and common reduction process equipment. Both of homogeneous conditions and heterogeneous conditions wherein catalyst loaded on organic or inorganic carriers can be used.

(107) The present invention also provided an oily olefin polymer and the preparation method thereof. The oily polyethylene of the present invention is highly branched; while the highly branched means that the number of methyl in the polyethylene is 100-500 per 1000 methylene.

(108) In the present invention, representative preparation method comprises the following steps (taking ethylene as an example):

(109) (a) under 0-100 C., 0.1 to 3 Mpa (1 to 30 atm), using the complex provided in the present invention to catalyze ethylene polymerization so as to form oily polyethylene.

(110) Preferably, there is cocatalyst in the step; more preferably, the cocatalyst is selected from the following group: alkyl aluminum reagents (such as alkyl aluminoxanes, diethylaluminum chloride and ethylaluminum dichloride); wherein the molar ratio of aluminum in the cocatalyst to nickel in the catalyst is 10-5000.

(111) In another preferred embodiment, step (a) is carried out in the following polymerization solvents: toluene, n-hexane, dichloromethane, 1,2-dichloroethane, chlorobenzene, tetrahydrofuran, or combinations thereof.

(112) In a preferred embodiment, the cocatalyst may be MAO or MMAO, alkyl aluminum or organoboron reagent, wherein the molar ratio of cocatalyst to nickel or palladium in the catalyst is from 10 to 5000.

(113) Since nickel, palladium complex II has the following characteristics in the polymerization process: 1) -H elimination can be rapidly performed to form polyolefin containing double bond and active species containing Ni (Pd)H; 2) -olefin re-coordinate and insertion into Ni (Pd)H so as to form Ni (Pd)C bond; (3) the resulted Ni(Pd)C bond could catalyze ethylene polymerization once more; and (4) finally the catalytic cycle is terminated through P3-H elimination. Therefore, the resulting polymer contains a large number of branches, and the total number of branches can be quantitatively analyzed through .sup.13C NMR by estimating the signal of CH.sub.2 and CH.sub.3 (integral area). And because the termination way of the catalytic cycle is -H elimination, the polymer contains double bonds.

(114) In the present invention, in step (a) in the representative method, at 0-100 C., at 0.1 to 3 MPa (1 to 30 atm), the complex provided in the present invention can catalyze the polymerization of propylene, butene, or any combination of ethylene, propylene, butene, C4-C20 -olefin, inner olefin, diene or a mixture thereof, and polar monomer so as to form oily polyolefin with or without functional groups, suitable monomer and catalyst are used to prepare different structures products according to the usage of the oil. The polar group is selected from the following group: carbonyl, hydroxyl, COOH, ester group COOR.sub.11, alkoxy OR.sub.12, amido NR.sub.13R.sub.14, acylamino CONR.sub.15R.sub.16, thioether SR.sub.17, selenide SeR.sub.18, PR.sub.19R.sub.20, P(O)R.sub.19R.sub.20 or combinations thereof; wherein R.sub.11 and R.sub.12 are independently C1-C10 alkyl or C6-C20 aryl; R.sub.13, R.sub.14, R.sub.15, R.sub.16, R.sub.17 or R.sub.18 are independently hydrogen, C1-C10 alkyl, or C6-C20 aryl; R.sub.19 or R.sub.20 are independently C1-C10 alkyl or C6-C20 aryl.

(115) In another preferred embodiment, the polar monomer is selected from the following group:

(116) ##STR00031## ##STR00032##

(117) Moreover, the method further comprises the following step before step (a): mixing the polar olefin monomer comprising functional group and cocatalyst and using the resulting mixture in step (a);

(118) Or reacting the polar olefin monomer with functional group protecting reagent to form a polar monomer with protected functional groups and then use it in step (a).

(119) In another preferred embodiment, the functional group protecting reagent is selected from the group consisting of: TBS, TES, TBDPS, TMS, AlEt.sub.3, Al.sup.iBu.sub.3, methylaluminoxane, ethylaluminoxane, butylalumoinxane, MMAO, and combinations thereof.

(120) In another preferred embodiment, the cocatalyst is selected from the group consisting of: alkyl aluminum reagent, alkyl aluminoxane reagent, weakly coordinating anion, and combinations thereof.

(121) In another preferred embodiment, the alkyl aluminum reagent is selected from the group consisting of: AlMe.sub.3, AlEt.sub.3, Al.sup.iBu.sub.3, or AlEt.sub.2Cl.

(122) In another preferred embodiment, the alkyl aluminoxane reagent is selected from the following group: MMAO or MAO.

(123) In another preferred embodiment, the weakly coordinating anion is selected from the following group: [B(3,5-(CF.sub.3).sub.2C.sub.6H.sub.3).sub.4].sup. or .sup.OSO.sub.2CF.sub.3.

(124) In another preferred embodiment, the MMAO refers to modified methyl aluminoxane (from Akzo Chemical Company).

(125) In another preferred embodiment, the olefin is polar olefin monomers which comprise functional groups, non-polar monomers, or combinations thereof.

(126) In another preferred embodiment, the non-polar monomer comprises: ethylene, propylene, butene, or combinations thereof.

(127) In another preferred embodiment, the olefins are any combination of ethylene, propylene and/or butene with other C5-C20 olefins.

(128) In another preferred embodiment, the oily olefin polymer is highly branched; more preferably, the highly branched means that the number of methyl in the polymer corresponding to 1000 CH.sub.2 is 100-500.

(129) In another preferred embodiment, the cocatalyst is used in step (a).

(130) More preferably, the cocatalyst is selected from the following group or combinations thereof: alkyl aluminum compound: alkyl aluminum reagents (such as alkyl aluminoxanes, diethylaluminum chloride and ethylaluminum dichloride).

(131) In another preferred embodiment, the reaction temperature of step (a) is 0-100 C.

(132) In another preferred embodiment, the reaction conditions of step (a) are: pressure (gauge pressure) 0.1-3 MPa, the cocatalyst is alkyl aluminoxane or diethylaluminum chloride, wherein the molar ratio of aluminum of cocatalyst to catalyst is 10-5000.

(133) In another preferred embodiment, step (a) is carried in the following solvents: toluene, n-hexane, dichloromethane, 1,2-dichloroethane, chlorobenzene, tetrahydrofuran, or combinations thereof.

(134) In another preferred embodiment, step (a) may be carried out in oily polyethylene or oily alkane mixture.

(135) In another preferred embodiment, the method further comprises the following steps:

(136) (b) hydrogenating the oily polyolefin obtained in step (a) to obtain a hydrogenated oily alkane mixture.

(137) In another preferred embodiment, the bromine value of the oily alkane mixture is less than 0.5 g/100 g.

(138) In another preferred embodiment, between step (a) and step (b) further comprised is a step of separating oily polyolefin.

(139) In another preferred embodiment, in step (a), hydrogenation reaction is simultaneously conducted.

(140) In another preferred embodiment, the step (b) may be carried out in an inert solvent or directly be carried out in the oily polyolefin.

(141) In another preferred embodiment, the oily alkane mixture is the hydrogenation product of the oily polyolefin of the invention.

(142) In another preferred embodiment, the oily alkane mixture is the hydrogenation product of the oily polyethylene of the invention.

(143) In another preferred embodiment, the oily olefin polymer or a hydrogenated product thereof possesses one or more of the following characteristics:

(144) (i) the number of polar group in the polymer chain: 0.1-1000 polar groups per 1000 carbon, preferably 5-200, more preferably 5-50;

(145) (ii) the number of methyl in the polymer is 100-500 methyl per 1000 methylene;

(146) (iii) the molecular weight is 300-500,000 g/mol;

(147) (iv) the density is 0.75-0.91 g/mol.

(148) In another preferred embodiment, the oily means that the olefin polymer is a colorless transparent oil with good mobility within all or part of the temperature range 50 C. to 70 C. (preferably over 40 C. to 50 C., more preferably 40 C. to 35 C.).

(149) The present invention also provides a class of highly branched oily alkane mixtures which are hydrogenated products of the oily polyolefins of the present invention, wherein the oily polyolefin comprises oily polyethylene, oily polypropylene, oily polybutene or oily copolymer obtained by the reaction of the olefins mixture of the above in the presence of a catalyst. The molecular weight of the oily alkane mixture is 500-500,000 g/mol, and the number of methyl (CH.sub.3) per 1000 methylene (CH.sub.2) is 100-500. In another preferred embodiment, the molecular weight of the oily alkane mixture is 500-50,000 g/mol, more preferably, the molecular weight of the oily alkane mixture is 500-10,000 g/mol, and the number of methyl (CH.sub.3) per 1000 methylene (CH.sub.2) is 100-300, and the pour point is below 20 C.

(150) In another preferred embodiment, the oily olefin polymer or a hydrogenated product thereof possesses one or more of the following characteristics:

(151) (i) the number of the methyl in the polymer is 100-500 methyl per 1000 methylene;

(152) (ii) the molecular weight is 300-500,000 g/mol;

(153) (iii) the density is 0.75-0.91 g/mol.

(154) In another preferred embodiment, the number of methyl in the oily olefin polymer or a hydrogenated product thereof per 1000 methylene is 100-300, and preferably 150-300.

(155) In another preferred embodiment, the number of branched chain in the oily olefin polymer or a hydrogenated product thereof per 1000 methylene is 100-300, and preferably 150-300. Wherein the branched chain comprises methyl, ethyl, n-propyl, n-butyl, sec-butyl and other branched chain with four or more (preferably 4-8) carbons.

(156) In another preferred embodiment, there are 40-70 branched alkyl chains with multiple ends per 1000 carbons.

(157) In another preferred embodiment, the polymer has a branch of the following structure: straight or branched C3-C8 alkyl.

(158) In another preferred embodiment, the branched alkyl chains with multiple ends of the polymer is sec-butyl, and the number of sec-butyl corresponding to 1000 carbon is 15-30.

(159) In another preferred embodiment, oily means that the olefin polymer is oily within all or part of the temperature range over 50 C. (preferably 40 C. to 50 C., more preferably 40 C. to 35 C.).

(160) In another preferred embodiment, the 100 C. kinematic viscosity of the oily olefin polymer or hydrogenated products thereof obtained in the present invention is 4-50 mm.sup.2/s, viscosity index (VI) is 160-300, and the surface tension is over 20 mM/m. The test method of the kinematic viscosity is as GB/T 265-1988 (2004), and the test method of viscosity index (VI value) is as GB/T 1995-1998 (2004).

(161) In another preferred embodiment, the hydrogenated product of the oily olefin polymer obtained by the present invention possesses excellent oxidative stability (over 50 min). Oxidation stability is tested according to SH/T 0193-2008 (rotating bomb method).

(162) In preferred embodiments of the present invention, the resulting oily olefin mixture is a colorless and transparent liquid at temperatures over pour point. In an inert atmosphere, it may be stable at high temperature, preferably higher than 300 C. (no oxidation reactions or the like may occur).

(163) In order to improve corresponding physical properties of highly branched saturated alkanes, such highly branched saturated alkanes may be mixed with various additives or reinforcing agents during use, such as antifreeze, alkylnaphthalene, and the like. In addition, such highly branched saturated alkanes can also be used as additives to improve the process ability of the resin, for example as a plasticizer in the process of polymer processing. In another preferred embodiment, the lubricating oil contains 0.1 to 100 wt % (preferably 1 to 90 wt %) of oily alkane mixture.

(164) During the polymerization, the metal complex can be prepared in situ. That is, (i) the desired ligand and metal salt are added into the organic solvent successively; (ii) after the reaction solution is stirred for 0-72 h, all or part of the solution is contacted with the olefin alone or together with the cocatalyst to catalyze the polymerization of the olefin to obtain oily polymer; or when the partial or total olefin monomer contains polar functional groups, the method further comprises the following before the step (i): Mixing aforesaid polar olefin monomer and cocatalyst to form a mixture, and then applying aforesaid mixture to step (i); or aforesaid polar olefin monomer to react with a functional group protecting agent to form functional group protected polar olefin monomer, and then using the protected polar olefin monomer in step (i).

(165) Whether the metal complex is prepared in situ or the metal complex is prepared and separated before the polymerization, the polymerization effect will not be affected. The same product can be obtained under the same polymerization process and polymerization conditions.

(166) Main Advantages of the Present Invention are:

(167) (a) New catalyst system can be used to achieve the direct preparation of oily alkane of high branching degree from simple olefin monomer, such as ethylene, and the cost is significantly reduced.

(168) (b) The catalyst system of the present invention can catalyze the polymerization of the polar olefin monomer containing functional groups, thus the obtained olefin polymer comprising various polar groups, which can be used in different applications.

(169) (c) The highly branched alkane mixture disclosed in the present invention has low bromine value and high viscosity index, which can be used as base oil or a processing aid for use in advanced lubricating oils.

(170) The present invention will be further illustrated below with reference to the specific examples. It should be understood that these examples are only to illustrate the invention but not to limit the scope of the invention. The experimental methods with no specific conditions described in the following examples are generally performed under the conventional conditions, or according to the manufacturer's instructions. Unless indicated otherwise, parts and percentage are weight parts and weight percentage.

(171) The kinetic test showed that the catalyst is stable and the activity almost kept unattenuated at least 3 hours.

(172) It can be seen from the .sup.13C spectrum that there are various types of branches, and the analysis of specific branches can refer to reference: Galland, G. B.; de Souza, R. F.; Mauler, R. S.; Nunes, F. F. Macromolecules 1999, 32, 1620. and Wiedemann, T.; Voit, G.; Tchernook, A.; Roesle, P.; Gottker-Schnetmann, I.; Mecking, S. J. Am. Chem. Soc. 2014, 136, 2078.

(173) Preparation of Ligand

Example 1

(174) Synthesis of Ligand L1-1

(175) ##STR00033##

(176) (1) phenylacetic acid (2.72 g, 20 mmol), ethanolamine (1.22 g, 20 mmol), xylenes (50 mL) were added into a 100 mL egg-shaped flask, and refluxed to remove water at 170 C. The reaction was tracked by NMR-monitoring, then concentrated by rotary evaporation and distilled under reduced pressure to obtain 2-benzyl-4,5-dihydrooxazole as a pale yellow liquid, yield 63%. .sup.1H NMR (300 MHz, CDCl.sub.3): =7.31-7.24 (5H, m), 4.22 (2H, t), 3.82 (2H, t), 3.60 (2H, s).

(177) (2) 100 mL dried reaction flask was added with dried tetrahydrofuran (50 mL) and diisopropylamine (1.70 mL, 12 mmol), and 2.4 M of n-butyllithium (5 mL, 12 mmol) was added dropwise in an ice-bath, and reacted at room temperature for 2 hours after completion of the addition. Then 2-benzyl-4,5-dihydro-oxazole (1.61 g, 10.0 mmol) in tetrahydrofuran was added dropwise by syringe pump into a prepared LDA solution in a dry ice-acetone bath, and reacted in dry ice-acetone bath for 3 hours after the addition was finished, finally replenished with oxygen in the dry ice-acetone bath for 3 hours, and TLC tracked until the reaction was completed. The reaction was quenched by adding saturated sodium thiosulfate solution, extracted with ether, dried over anhydrous sodium sulfate, filtered and concentrated by rotary evaporation. The reaction mixture was purified by silica gel column chromatography (triethylamine embellished, ethyl acetate/petroleum ether=1/20) to give 2-benzoyl-4,5-dihydrooxazole, and the product was a yellow liquid, yield 71%. .sup.1H NMR (400 MHz, CDCl.sub.3): =8.31 (2H, dd), 7.63 (1H, m), 7.49 (2H, m), 4.49 (1H, dd), 4.20 (1H, dd), 3.74 (2H, m).

(178) (3) 2-benzoyl-4,5-dihydrooxazole (0.88 g, 5.0 mmol), dichloromethane (25 mL), titanium tetrachloride (0.6 mL, 5.5 mmol) and 2,6-diisopropyl aniline (0.94 mL, 5.0 mmol) were added into 50 mL of the reaction tube, and triethylamine (1.05 mL, 7.5 mmol) was added, TLC tracked until the reaction was completed. The reaction was quenched by adding saturated sodium bicarbonate solution, filtered through diatomaceous earth, extracted with dichloromethane, dried over anhydrous sodium sulfate, suction filtered, concentrated by rotation, and purified through neutral alumina column chromatography (ethyl acetate/petroleum ether=1/30) to give the crude product, and ligand L1-1 was obtained by recrystallization with methanol, which is a yellow solid, yield 38%. .sup.1H NMR (400 MHz, CDCl.sub.3): =8.01 (2H, dd), 7.50 (3H, m), 7.05 (3H, m), 4.56 (0.5H, t), 4.18 (0.5H, t), 4.01 (1.5H, t), 3.82 (1.5H, t), 2.86 (2H, m), 1.19 (4.5H, d), 1.14 (1.5H, d), 1.11 (4.5H, d), 0.86 (1.5H, d).

(179) In examples 2-48, different racemic or optically pure raw materials were used to replace the corresponding raw material in example 1 so as to prepare ligand L1-2 to L1-48, and the results are shown in table 1.

(180) TABLE-US-00001 TABLE 1 The structure of the Structural characterization (H NMR spectroscopy or Example No. ligand: elemental analysis) 2 L1-2 .sup.1H NMR (400 MHz, CDCl.sub.3): = 8.00 (2 H, d), 7.50(3 H, m), 7.05 (3 H, m), 3.68 (2 H, s), 2.89 (2 H, m), 1.21 (6 H, d), 1.09 (12 H, d). 3 L1-3 .sup.1H NMR (400 MHz, CDCl.sub.3): = 7.98 (2 H, d), 7.52(3 H, m), 7.05 (3 H, m), 3.83 (2 H, s), 2.87 (2 H, m), 1.34 (4 H, q), 1.21 (6 H, d), 1.09 (6 H, d), 0.90 (6 H, t). 4 L1-4 .sup.1H NMR (400 MHz, CDCl.sub.3): = 8.00 (2 H, d), 7.50(3 H, m), 7.05 (3 H, m), 3.68 (2 H, s), 2.89 (2 H, m), 1.21 (6 H, d), 1.09 (12 H, d). 5 L1-5 .sup.1H NMR (400 MHz, CDCl.sub.3): = 8.00 (2 H, d), 7.49(3 H, m), 7.05 (3 H, m), 3.71 (2 H, s), 2.89 (2 H, m), 1.64-1.08 (22 H, m). 6 L1-6 .sup.1H NMR (400 MHz, CDCl.sub.3): = 7.91 (2 H, d), 7.50(1 H, t), 7.43(2 H, t), 7.20 (6 H, m), 7.10 (3 H, m), 6.95 (4 H, dd), 4.60 (2 H, s), 2.93 (2 H, dt), 1.10 (12 H, dd). 7 L1-7 .sup.1H NMR (400 MHz, CDCl.sub.3): = 8.01 (2 H, dd), 7.51(3 H, m), 7.05 (3 H, m), 4.15(2 H, ddd), 3.51 (2 H, dd), 2.89 (2 H, m), 1.21 (6H, dd), 1.10 (6 H, dd), 0.97. (3H, d). 8 L1-8 0 .sup.1H NMR (400 MHz, CDCl.sub.3): = 7.99 (2 H, dd), 7.48(3 H, m), 7.03 (3 H, m), 4.13(1 H, t), 3.90 (1 H, dd), 3.71 (1 H, t), 2.89 (2 H, m), 1.42 (1H, m), 1.15 (12 H, ddd), 0.67 (6H, m). 9 L1-9 .sup.1H NMR (400 MHz, CDCl.sub.3): = 7.97 (2 H, d), 7.49(3 H, m), 7.02 (3 H, m), 4.13 (1 H, dd), 3.87 (2 H, dt), 2.89 (2 H, m), 1.15 (12 H, ddd), 0.60 (9 H, s). 10 L1-10 .sup.1H NMR (400 MHz, CDCl.sub.3): = 8.05 (2 H, d), 7.52(3 H, m), 7.15(6 H, m), 6.59 (2 H, d), 5.21 (1 H, t), 4.54 (1 H, t), 3.85 (1 H, t), 2.92 (2 H, dq), 1.12 (12 H, m). 11 L1-11 .sup.1H NMR (400 MHz, CDCl.sub.3): = 7.96 (2 H, dd), 7.48(3 H, m), 7.12 (3 H, m), 7.06 (6 H, m), 4.34(1 H, dd), 3.99 (1 H, t), 3.72 (1 H, t), 2.85 (3 H, m), 2.10 (1 H, dd), 1.21 (6 H, dd), 1.11 (6 H, dd). 12 L1-12 Anal. Calcd. For C.sub.20H.sub.30N.sub.2O: C, 76.39; H, 9.62; N, 8.91. Found: C, 76.02; H, 9.60; N, 8.64. 13 L1-13 Anal. Calcd. For C.sub.21H.sub.32N.sub.2O: C, 76.78; H, 9.82; N, 8.53. Found: C, 76.37; H, 9.59; N, 8.38. 14 L1-14 Anal. Calcd. For C.sub.24H.sub.38N.sub.2O: C, 77.79; H, 9.62; N, 7.56. Found: C, 77.82; H, 10.60; N, 7.64. 15 L1-15 Anal. Calcd. For C.sub.27H.sub.36N.sub.2O: C, 80.15; H, 8.97; N, 6.92. Found: C, 79.89; H, 9.10; N, 6.75. 16 L1-16 Anal. Calcd. For C.sub.27H.sub.36N.sub.2O.sub.2: C, 77.10; H, 8.63; N, 6.66. Found: C, 77.01; H, 8.42; N, 6.49. 17 L1-17 Anal. Calcd. For C.sub.28H.sub.39N.sub.3O: C, 77.55; H, 9.07; N, 9.69. Found: C, 77.23; H, 8.94; N, 9.47. 18 L1-18 0 Anal. Calcd. For C.sub.26H.sub.33ClN.sub.2O: C, 73.48; H, 7.83; N, 6.59. Found: C, 73.09; H, 7.60; N, 6.57. 19 L1-19 Anal. Calcd. For C.sub.26H.sub.33N.sub.3O.sub.3: C, 71.70; H, 7.64; N, 9.65. Found: C, 71.51; H, 7.42; N, 9.45. 20 L1-20 Anal. Calcd. For C.sub.27H.sub.33F.sub.3N.sub.2O: C, 70.72; H, 7.25; N, 6.11. Found: C, 70.54; H, 7.02; N, 6.05. 21 L1-21 Anal. Calcd. For C.sub.27H.sub.33N.sub.3O: C, 78.03; H, 8.00; N, 10.11. Found: C, 77.93; H, 8.04; N, 9.97. 22 L1-22 Anal. Calcd. For C.sub.29H.sub.42N.sub.2OSi: C, 75.27; H, 9.07; N, 6.05. Found: C, 75.23; H, 8.87; N, 5.95. 23 L1-23 Anal. Calcd. For C.sub.20H.sub.22N.sub.2O: C, 78.40; H, 7.24; N, 9.14. Found: C, 78.21; H, 6.98; N, 9.03. 24 L1-24 Anal. Calcd. For C.sub.22H.sub.26N.sub.2O: C, 79.00; H, 7.84; N, 8.38. Found: C, 78.76; H, 7.91; N, 8.28. 25 L1-25 Anal. Calcd. For C.sub.20H.sub.20F.sub.2N.sub.2O: C, 70.16; H, 5.89; N, 8.18. Found: C, 70.21; H, 6.04; N, 8.15. 26 L1-26 Anal. Calcd. For C.sub.20H.sub.20Cl.sub.2N.sub.2O: C, 64.01; H, 5.37; N, 7.46. Found: C, 63.91; H, 5.04; N, 7.21. 27 L1-27 Anal. Calcd. For C.sub.20H.sub.20Br.sub.2N.sub.2O: C, 51.75; H, 4.34; N, 6.03. Found: C, 51.21; H, 4.15; N, 6.00. 28 L1-28 0 Anal. Calcd. For C.sub.27H.sub.36N.sub.2O: C, 80.15; H, 8.97; N, 6.92. Found: C, 79.92; H, 8.78; N, 6.40. 29 L1-29 Anal. Calcd. For C.sub.18H.sub.26N.sub.2O: C, 75.48; H, 9.15; N, 9.78. Found: C, 75.21; H, 8.98; N, 9.32. 30 L1-30 Anal. Calcd. For C.sub.26H.sub.26N.sub.2O: C, 81.64; H, 6.85; N, 7.32. Found: C, 81.21; H, 6.57; N, 7.08. 31 L1-31 Anal. Calcd. For C.sub.28H.sub.28N.sub.2O: C, 82.32; H, 6.91; N, 6.86. Found: C, 82.15; H, 6.59; N, 6.35. 32 L1-32 Anal. Calcd. For C.sub.29H.sub.32N.sub.2: C, 85.25; H, 7.89; N, 6.86. Found: C, 84.89; H, 7.42; N, 6.43. 33 L1-33 Anal. Calcd. For C.sub.24H.sub.31N.sub.3: C, 79.73; H, 8.64; N, 11.62. Found: C, 79.38; H, 8.28; N, 11.53. 34 L1-34 Anal. Calcd. For C.sub.27H.sub.29N.sub.3: C, 81.99; H, 7.39; N, 10.62. Found: C, 81.86; H, 7.17; N, 10.30. 35 L1-35 Anal. Calcd. For C.sub.34H.sub.33N.sub.3: C, 84.43; H, 6.88; N, 8.69. Found: C, 84.14; H, 6.56; N, 8.14. 36 L1-36 Anal. Calcd. For C.sub.26H.sub.34N.sub.2S: C, 76.80; H, 8.43; N, 6.89. Found: C, 76.42; H, 8.35; N, 6.51. 37 L1-37 Anal.Calcd. For C.sub.26H.sub.26N.sub.2S: C, 78.35; H, 6.88; N, 7.03. Found: C, 78.04; H, 6.27; N, 6.96. 38 L1-38 0 Anal. Calcd. For C.sub.24H.sub.28N.sub.2S: C, 76.55; H, 7.49; N, 7.44. Found: C, 76.42; H, 7.37; N, 7.25. 39 L1-39 Anal. Calcd. For C.sub.27H.sub.37N.sub.3: C, 80.35; H, 9.24; N, 10.41. Found: C, 80.14; H, 9.05; N, 10.12. 40 L1-40 Anal. Calcd. For C.sub.27H.sub.36N.sub.2O: C, 80.15; H, 8.97; N, 6.92. Found: C, 79.91; H, 8.56; N, 6.64. 41 L1-41 Anal. Calcd. For C.sub.27H.sub.36N.sub.2S: C, 77.09; H, 8.63; N, 6.66. Found: C, 76.87; H, 8.56; N, 6.37. 42 L1-42 Anal. Calcd. For C.sub.28H.sub.39N.sub.3: C, 80.53; H, 9.41; N, 10.06. Found: C, 80.24; H, 9.09; N, 10.01. 43 L1-43 Anal. Calcd. For C.sub.28H.sub.38N.sub.2O: C, 80.34; H, 9.15; N, 6.69. Found: C, 79.95; H, 8.86; N, 6.54. 44 L1-44 Anal. Calcd. For C.sub.28H.sub.38N.sub.2S: C, 77.37; H, 8.81; N, 6.44. Found: C, 76.93; H, 8.56; N, 6.02. 45 L1-45 Anal. Calcd. For C.sub.23H.sub.35N.sub.3: C, 78.14; H, 9.98; N, 11.89. Found: C, 77.94; H, 9.69; N, 11.56. 46 L1-46 Anal. Calcd. For C.sub.23H.sub.33N.sub.3: C, 78.58; H, 9.46; N, 11.95. Found: C, 78.31; H, 9.08; N, 11.50. 47 L1-47 Anal. Calcd. For C.sub.22H.sub.26N.sub.2O.sub.2: C, 75.40; H, 7.48; N, 7.99. Found: C, 75.05; H, 7.12; N, 7.54. 48 L1-48 0 Anal. Calcd. For C.sub.24H.sub.30N.sub.2O.sub.2: C, 76.16; H, 7.99; N, 7.40. Found: C, 75.83; H, 7.48; N, 7.03.

(181) Preparation of Complex

Example 49

(182) Synthesis of Complex 2-1

(183) ##STR00081##

(184) NiBr.sub.2 (DME) 1 mmol and 1.05 mmol L1-1 were mixed and the reaction system was replaced by nitrogen for three times, and 20 mL of anhydrous dichloromethane was added and stirred overnight. The reaction solution was filtered, the solvent of filtrate was removed under reduced pressure, and the solid was washed for 2-3 times with solvent mixture of dichloromethane/n-hexane (2 mL/20 mL). After filtration, the remaining solid was dried under vacuum. The product is a red solid, yield 87%. Anal. Calcd. For C.sub.22H.sub.26Br.sub.2N.sub.2NiO: C, 47.79; H, 4.74; N, 5.07. Found: C, 48.04; H, 4.65; N, 4.95.

(185) In examples 50-103, different ligand or metal precursor were used to replace the corresponding ligand or metal precursor in example 49 so as to prepare complex 2-2 to 2-55, and the results are shown in table 2.

(186) TABLE-US-00002 TABLE 2 Example No. Structure elemental analysis 50 2-2 Anal. Calcd. For C.sub.24H.sub.30Br.sub.2N.sub.2NiO: C, 49.61; H, 5.20; N, 4.82. Found: C, 50.01; H, 5.60; N, 4.64. 51 2-3 Anal. Calcd. For C.sub.26H.sub.34Br.sub.2N.sub.2NiO: C, 51.27; H, 5.63; N, 4.60. Found: C, 51.06; H, 5.32; N, 4.45. 52 2-4 Anal. Calcd. For C.sub.26H.sub.32Br.sub.2N.sub.2NiO: C, 51.44; H, 5.31; N, 4.61. Found: C, 51.13; H, 5.07; N, 4.35. 53 2-5 Anal. Calcd. For C.sub.27H.sub.34Br.sub.2N.sub.2NiO: C, 52.21; H, 5.52; N, 4.51. Found: C, 51.95; H, 5.22; N, 4.28. 54 2-6 Anal. Calcd. For C.sub.34H.sub.34Br.sub.2N.sub.2NiO: C, 57.91; H, 4.86; N, 3.97. Found: C, 57.49; H, 4.32; N, 3.45. 55 2-7 Anal. Calcd. For C.sub.23H.sub.28Br.sub.2N.sub.2NiO: C, 48.72; H, 4.98; N, 4.94. Found: C, 48.36; H, 4.62; N, 4.58. 56 2-8 Anal. Calcd. For C.sub.25H.sub.32Br.sub.2N.sub.2NiO: C, 50.46; H, 5.42; N, 4.71. Found: C, 50.23; H, 5.22; N, 4.32. 57 2-9 Anal. Calcd. For C.sub.26H.sub.34Br.sub.2N.sub.2NiO: C, 51.27; H, 5.63; N, 4.60. Found: C, 50.86; H, 5.37; N, 4.40. 58 2-10 0 Anal. Calcd. For C.sub.28H.sub.30Br.sub.2N.sub.2NiO: C, 53.46; H, 4.81; N, 4.45. Found: C, 53.02; H, 4.42; N, 4.13. 59 2-11 Anal. Calcd. For C.sub.29H.sub.32Br.sub.2N.sub.2NiO: C, 54.16; H, 5.02; N, 4.36. Found: C, 53.85; H, 4.62; N, 4.10. 60 2-12 Anal. Calcd. For C.sub.20H.sub.30Br.sub.2N.sub.2NiO: C, 45.07; H, 5.67; N, 5.26. Found: C, 43.79; H, 5.42; N, 5.06. 61 2-13 Anal. Calcd. For C.sub.21H.sub.32Br.sub.2N.sub.2NiO: C, 46.11; H, 5.90; N, 5.12. Found: C, 45.83; H, 5.48; N, 4.96. 62 2-14 Anal. Calcd. For C.sub.24H.sub.38Br.sub.2N.sub.2NiO: C, 48.93; H, 6.50; N, 4.76. Found: C, 48.47; H, 6.62; N, 5.00. 63 2-15 Anal. Calcd. For C.sub.27H.sub.36Br.sub.2N.sub.2NiO: C, 52.05; H, 5.82; N, 4.50. Found: C, 51.78; H, 5.45; N, 4.76. 64 2-16 Anal. Calcd. For C.sub.27H.sub.36Br.sub.2N.sub.2NiO.sub.2: C, 50.74; H, 5.68; N, 4.38. Found: C, 51.01; H, 5.59; N, 4.31. 65 2-17 Anal. Calcd. For C.sub.28H.sub.39Br.sub.2N.sub.3NiO: C, 51.57; H, 6.03; N, 6.44. Found: C, 51.23; H, 5.75; N, 6.36. 66 2-18 Anal. Calcd. For C.sub.26H.sub.33Br.sub.2ClN.sub.2NiO: C, 48.53; H, 5.17; N, 4.35. Found: C, 48.20; H, 5.03; N, 4.19. 67 2-19 Anal. Calcd. For C.sub.26H.sub.33Br.sub.2N.sub.3NiO.sub.3: C, 47.74; H, 5.09; N, 6.42. Found: C, 47.39; H, 5.02; N, 6.31. 68 2-20 00 Anal. Calcd. For C.sub.27H.sub.33Br.sub.2F.sub.3N.sub.2NiO: C, 47.90; H, 4.91; N, 4.14. Found: C, 47.81; H, 4.59; N, 3.94. 69 2-21 01 Anal. Calcd. For C.sub.27H.sub.33Br.sub.2N.sub.3NiO: C, 51.14; H, 5.25; N, 6.63. Found: C, 51.21; H, 5.08; N, 6.43. 70 2-22 02 Anal. Calcd. For C.sub.29H.sub.42Br.sub.2N.sub.2NiOSi: C, 51.13; H, 6.21; N, 4.11. Found: C, 50.86; H, 6.79; N, 3.85. 71 2-23 03 Anal. Calcd. For C.sub.20H.sub.22Br.sub.2N.sub.2NiO: C, 45.76; H, 4.22; N, 5.34. Found: C, 45.42; H, 4.21; N, 5.29. 72 2-24 04 Anal. Calcd. For C.sub.22H.sub.26Br.sub.2N.sub.2NiO: C, 47.79; H, 4.74; N, 5.07. Found: C, 47.45; H, 4.38; N, 5.01. 73 2-25 05 Anal. Calcd. For C.sub.20H.sub.20Br.sub.2F.sub.2N.sub.2NiO: C, 42.83; H, 3.59; N, 4.99. Found: C, 42.45; H, 3.38; N, 4.76. 74 2-26 06 Anal. Calcd. For C.sub.20H.sub.20Br.sub.2Cl.sub.2N.sub.2NiO: C, 40.45; H, 3.39; N, 4.72. Found: C, 40.21; H, 3.28; N, 4.49. 75 2-27 07 Anal. Calcd. For C.sub.20H.sub.20Br.sub.4N.sub.2NiO: C, 35.19; H, 2.95; N, 4.10. Found: C, 35.03; H, 3.02; N, 3.95. 76 2-28 08 Anal. Calcd. For C.sub.27H.sub.36Br.sub.2N.sub.2NiO: C, 52.05; H, 5.82; N, 4.50. Found: C, 51.87; H, 5.38; N, 4.28. 77 2-29 09 Anal. Calcd. For C.sub.18H.sub.26Br.sub.2N.sub.2NiO: C, 42.82; H, 5.19; N, 5.55. Found: C, 42.48; H, 5.28; N, 5.37. 78 2-30 0 Anal. Calcd. For C.sub.26H.sub.26Br.sub.2N.sub.2NiO: C, 51.96; H, 4.36; N, 4.66. Found: C, 51.78; H, 4.27; N, 4.41. 79 2-31 Anal. Calcd. For C.sub.28H.sub.28Br.sub.2N.sub.2NiO: C, 53.63; H, 4.50; N, 4.47. Found: C, 53.46; H, 4.39; N, 4.38. 80 2-32 Anal. Calcd. For C.sub.29H.sub.32Br.sub.2N.sub.2Ni: C, 55.54; H, 5.14; N, 4.47. Found: C, 55.37; H, 5.02; N, 4.32. 81 2-33 Anal. Calcd. For C.sub.24H.sub.31Br.sub.2N.sub.3Ni: C, 49.70; H, 5.39; N, 7.24. Found: C, 50.03; H, 5.26; N, 7.29. 82 2-34 Anal. Calcd. For C.sub.27H.sub.29Br.sub.2N.sub.3Ni: C, 52.81; H, 4.76; N, 6.84. Found: C, 52.75; H, 4.58; N, 6.72. 83 2-35 Anal. Calcd. For C.sub.34H.sub.33Br.sub.2N.sub.3Ni: C, 58.16; H, 4.74; N, 5.98. Found: C, 58.04; H, 4.36; N, 5.37. 84 2-36 Anal. Calcd. For C.sub.26H.sub.34Br.sub.2N.sub.2NiS: C, 49.95; H, 5.48; N, 4.48. Found: C, 49.65; H, 5.27; N, 4.32. 85 2-37 Anal. Calcd. For C.sub.26H.sub.26Br.sub.2N.sub.2NiS: C, 50.61; H, 4.25; N, 4.54. Found: C, 50.32; H, 4.22; N, 4.39. 86 2-38 Anal. Calcd. For C.sub.24H.sub.28Br.sub.2N.sub.2NiS: C, 48.44; H, 4.74; N, 4.71. Found: C, 48.03; H, 4.21; N, 4.39. 87 2-39 Anal. Calcd. For C.sub.27H.sub.37Br.sub.2N.sub.3Ni: C, 52.13; H, 5.99; N, 6.75. Found: C, 52.01; H, 5.60; N, 6.62. 88 2-40 0 Anal. Calcd. For C.sub.27H.sub.36Br.sub.2N.sub.2NiO: C, 52.05; H, 5.82; N, 4.50. Found: C, 51.76; H, 5.64; N, 4.32. 89 2-41 Anal. Calcd. For C.sub.27H.sub.36Br.sub.2N.sub.2NiS: C, 50.74; H, 5.68; N, 4.38. Found: C, 50.38; H, 5.22; N, 4.15. 90 2-42 Anal. Calcd. For C.sub.28H.sub.39Br.sub.2N.sub.3Ni: C, 52.87; H, 6.18; N, 6.61. Found: C, 52.52; H, 6.60; N, 6.45. 91 2-43 Anal. Calcd. For C.sub.28H.sub.38Br.sub.2N.sub.2NiO: C, 52.78; H, 6.01; N, 4.40. Found: C, 52.41; H, 5.83; N, 4.29. 92 2-44 Anal. Calcd. For C.sub.28H.sub.38Br.sub.2N.sub.2NiS: C, 51.49; H, 5.86; N, 4.29. Found: C, 51.35; H, 5.32; N, 4.15. 93 2-45 Anal. Calcd. For C.sub.23H.sub.35Br.sub.2N.sub.3Ni: C, 48.29; H, 6.17; N, 7.35. Found: C, 48.01; H, 5.95; N, 7.24. 94 2-46 Anal. Calcd. For C.sub.23H.sub.33Br.sub.2N.sub.3Ni: C, 48.46; H, 5.84; N, 7.37. Found: C, 48.15; H, 5.47; N, 7.08. 95 2-47 Anal. Calcd. For C.sub.22H.sub.26Br.sub.2N.sub.2NiO.sub.2: C, 46.44; H, 4.61; N, 4.92. Found: C, 46.06; H, 4.60; N, 4.59. 96 2-48 Anal. Calcd. For C.sub.24H.sub.30Br.sub.2N.sub.2NiO.sub.2: C, 48.28; H, 5.06; N, 4.69. Found: C, 48.03; H, 4.97; N, 4.64. 97 2-49 Anal. Calcd. For C.sub.28H.sub.40N.sub.2NiO: C, 70.16; H, 8.41; N, 5.84. Found: C, 70.01; H, 8.35; N, 5.62. 98 2-50 0 Anal. Calcd. For C.sub.26H.sub.34Cl.sub.2N.sub.2NiO: C, 60.03; H, 6.59; N, 5.39. Found: C, 59.85; H, 6.60; N, 5.58. 99 2-51 Anal. Calcd. For C.sub.26H.sub.34I.sub.2N.sub.2NiO: C, 44.42; H, 4.87; N, 3.98. Found: C, 44.08; H, 4.60; N, 3.67. 100 2-52 Anal. Calcd. For C.sub.40H.sub.48N.sub.2NiO: C, 76.08; H, 7.66; N, 4.44. Found: C, 75.84; H, 7.59; N, 4.32. 101 2-53 Anal. Calcd. For C.sub.28H.sub.40N.sub.2OPd: C, 63.81; H, 7.65; N, 5.32. Found: C, 63.55; H, 7.43; N, 5.20. 102 2-54 Anal. Calcd. For C.sub.26H.sub.34Cl.sub.2N.sub.2OPd: C, 54.99; H, 6.03; N, 4.93. Found: C, 54.64; H, 5.90; N, 4.69. 103 2-55 Anal. Calcd. For C.sub.26H.sub.34Br.sub.2N.sub.2OPd: C, 47.55; H, 5.22; N, 4.27. Found: C, 47.09; H, 5.03; N, 4.14.

(187) Preparation of Highly Branched Oily Polyolefins

Example 104

(188) 250 mL of the polymerization flask was replaced by nitrogen for three times, and then replaced by ethylene. 40 mL of toluene was added under ethylene atmosphere, and 1.10 mL (0.9 mol/L) diethylaluminum chloride in toluene was added. Under 30 C., and 1 atm of ethylene, complex 2-9 (2.0 umol) was added to promote the polymerization for 30 min, then the ethylene was cut off and 1.0 mL of methanol was added to quench the reaction. The solvent was removed to obtain oily polyethylene, the activity was 6.610.sup.6 g/mol.Math.h.Math.atm, and the methyl number per 1000 methylene of the oily polyethylene was 120.

Example 105

(189) The complex was prepared in situ, 60 mol of ligand L1-9 and (DME)NiBr.sub.2 weighed in glovebox, were dissolved in 30 mL dichloromethane, and reacted at under room temperature for 2 h, and then the solution was diluted into 2 mol/mL solution for further use.

(190) 250 mL of the polymerization flask was replaced by nitrogen for three times, and then replaced by ethylene. 40 mL of toluene was added under ethylene atmosphere, and 1.10 mL (0.9 mol/L) diethylaluminum chloride in toluene was added. At 30 C. and, 1 atm of ethylene, the above in-situ prepared complex (2.0 umol) was added to promote the polymerizatione for 30 min, then the ethylene was cut off and 1.0 mL of methanol was added to quench the reaction. The solvent of reaction solution was removed to obtain oily polyethylene, the activity was 6.710.sup.6 g/mol.Math.h.Math.atm, and the methyl number per 1000 methylene of the oily polyethylene was 126.

Example 106

(191) The example 104 was repeated except that the propylene was used instead of ethylene.

(192) Results: oily polymer 8.7 g was obtained. The activity was 8.710.sup.6 g/mol.Math.h.Math.atm, and the methyl number per 1000 methylene of the oily polyethylene was 276.

Example 107

(193) The example 104 was repeated except that the mixture of cis/trans-2-butene was used to instead of ethylene.

(194) Results: oily polymer 10.8 g was obtained. The activity was 10.810.sup.6 g/mol.Math.h.Math.atm, and the methyl number per 1000 methylene of the oily polyethylene was 279.

Example 108

(195) The example 104 was repeated except that the 1-hexene was used instead of ethylene.

(196) Results: oily polymer 8.3 g was obtained. The activity was 8.310.sup.6 g/mol.Math.h.Math.atm, and the methyl number per 1000 methylene of the oily polyethylene was 235.

Example 109

(197) The example 104 was repeated except that the 1-decene was used to instead of ethylene.

(198) Results: oily polymer 9.1 g was obtained. The activity was 9.110.sup.6 g/mol.Math.h.Math.atm, and the methyl number per 1000 methylene of the oily polyethylene was 208.

Example 110

(199) The example 104 was repeated except that the cyclohexene was used to instead of ethylene.

(200) Results: oily polymer 3.5 g was obtained. The activity was 3.510.sup.6 g/mol.Math.h.Math.atm.

Example 111

(201) The example 104 was repeated except that the n-hexane was used instead of toluene.

(202) Results: oily polyethylene 5.3 g was obtained. The activity was 5.310.sup.6 g/mol.Math.h.Math.atm, and the methyl number per 1000 methylene of the oily polyethylene was 134.

Example 112

(203) The example 104 was repeated except that the DCE was used instead of toluene.

(204) Results: oily polyethylene 5.8 g was obtained. The activity was 5.810.sup.6 g/mol.Math.h.Math.atm, and the methyl number per 1000 methylene of the oily polyethylene was 140.

Example 113

(205) The example 104 was repeated except that the MMAO was used instead of diethylaluminum chloride.

(206) Results: oily polyethylene 6.0 g was obtained. The activity was 6.010.sup.6 g/mol.Math.h.Math.atm, and the methyl number per 1000 methylene of the oily polyethylene was 132.

Example 114

(207) The example 104 was repeated except that the MAO was used instead of diethylaluminum chloride.

(208) Results: oily polyethylene 5.5 g was obtained. The activity was 5.510.sup.6 g/mol.Math.h.Math.atm, and the methyl number per 1000 methylene of the oily polyethylene was 138.

Example 115

(209) The example 104 was repeated except that polymerization temperature 40 C.

(210) Results: oily polyethylene 5.2 g was obtained. The activity was 5.210.sup.6 g/mol.Math.h.Math.atm, and the methyl number per 1000 methylene of the oily polyethylene was 156.

Example 116

(211) The example 104 was repeated except that polymerization temperature 50 C.

(212) Results: oily polyethylene 4.6 g was obtained. The activity was 4.610.sup.6 g/mol.Math.h.Math.atm, and the methyl number per 1000 methylene of the oily polyethylene was 175.

Example 117

(213) The example 104 was repeated except that polymerization temperature 70 C.

(214) Results: oily polyethylene 2.3 g was obtained. The activity was 2.310.sup.6 g/mol.Math.h.Math.atm, and the methyl number per 1000 methylene of the oily polyethylene was 214.

Example 118

(215) 300 mL autoclave was dried under vacuum at 120 C. overnight in advance, and the autoclave was rechanged with nitrogen under 30 C. for 3 times, 100 mL of toluene was added, and cocatalyst diethylaluminium chloride 1.10 mL (0.9 mol/L) was added, and stirred for 10 min., after complex 2-9 (5 umol) was added, the ethylene pressure was improved up to 3 atm and the polymerization was proceeded for 1 h, and then the ethylene was cut off. Oily polyethylene was obtained after removing the solvent. The activity was 7.010.sup.6 g/mol.Math.h.Math.atm, and the methyl number per 1000 methylene of the oily polyethylene was 94.

Example 119

(216) The example 118 was repeated while the pressure of ethylene was changed to 5 atm.

(217) Results: The activity was 4.310.sup.6 g/mol.Math.h.Math.atm, and the methyl number per 1000 methylene of the oily polyethylene was 85.

(218) In examples 120-149, different complexes were used to replace the corresponding complex 2-9 in example 104 so as to obtain different oily polymers in examples 120-149, and the polymerization results are shown in table 3.

(219) TABLE-US-00003 TABLE 3 Polymerization activity The methyl number Example Complex (10.sup.6 g/mol .Math. h .Math. atm) per 1000 methylene 120 2-2 4.2 167 121 2-3 4.8 156 122 2-5 3.2 145 123 2-6 3.8 133 124 2-8 6.5 127 125 2-10 7.3 102 126 2-12 8.1 94 127 2-13 7.8 123 128 2-14 7.4 164 129 2-16 3.6 109 130 2-18 6.8 123 131 2-20 8.6 142 132 2-22 4.2 133 133 2-24 3.5 203 134 2-27 6.2 154 135 2-29 2.1 219 136 2-31 5.5 156 137 2-32 1.9 134 138 2-35 4.3 147 139 2-36 3.7 126 140 2-40 5.7 118 141 2-43 6.0 173 142 2-45 6.9 148 143 2-47 3.2 109 144 2-48 6.8 174 145 2-49 9.0 122 146 2-50 4.1 165 147 2-52 2.5 120 148 2-53 0.5 212 149 2-55 1.2 229

(220) The Copolymerization of Ethylene and Polar Monomer

(221) (Note: All the numbers of the following polar monomer refer to the numbering of polar monomers in the embodiments for carrying out the invention section)

Example 150

(222) 250 mL of the polymerization flask was replaced by nitrogen for three times, and then replaced by ethylene. 40 mL of solvent toluene was added under ethylene atmosphere, and 4.40 mL (0.9 mol/L) of diethylaluminum chloride in toluene was added. At 30 C., and 1 atm ethylene, 2 mmol of polar monomer M3 was added, and complex 2-9 (2.0 umol) was added after 5 minutes, polymerized for 30 min, then the ethylene stream was cut off and 1.0 mL of methanol was added to quench the reaction. The solvent was removed to obtain oily polyethylene, the activity was 3.810.sup.5 g/mol.Math.h.Math.atm, and the polar group number per 1000 methylene of the oily polymer was 59.

Example 151

(223) Al.sup.iBu.sub.3 (60 mmol) and 20 mL toluene were added into reaction flask which was dried in vacuo at high temperature and replaced with nitrogen, and the polar monomer M3 (50 mmol) in toluene was added dropwise into the above solution at 78 C. After 2 h, the reaction was warmed to room temperature and stirred for 12 h, and certain amount of toluene was added so as to prepare polar monomer solution in toluene (1.0 mol/L) for further use.

(224) 250 mL of the polymerization flask was replaced by nitrogen for three times, and then replaced by ethylene. 40 mL of toluene was added under ethylene atmosphere, and 1.10 mL (0.9 mol/L) of diethylaluminum chloride in toluene was added. At 30 C., 1 atm ethylene, 5 mmol of polar monomer M3 was added, and complex 2-9 (2.0 umol) was added after 5 minutes, the polymerization proceed for 30 min, then the ethylene stream was cut off and 1.0 mL of methanol was added to quench the reaction. The solvent was removed to obtain oily polyethylene, the activity was 4.610.sup.5 g/mol.Math.h.Math.atm, and the polar group number per 1000 methylene of the oily polymer was 64.

(225) In examples 152-166, different polar monomers were used instead of the corresponding polar monomer M3 in example 150 so as to obtain different oily polymers in examples 152-166, and the polymerization results are shown in table 4.

(226) TABLE-US-00004 TABLE 4 Polar monomer insertion rate the (the number amount of polar of the polymerization group per AlEt.sub.2Cl/ polar monomer activity 1000 Example Complex Ni monomer (mmol) (10.sup.5 g/mol .Math. h .Math. atm) methylene) 152 2-9 500 M3 2 1.7 13 153 2-9 1000 M3 5 4.4 26 154 2-9 3000 M3 10 7.1 31 155 2-9 3000 M2 5 4.0 63 156 2-9 3000 M4 5 7.4 29 157 2-9 3000 M5 5 1.0 23 158 2-9 3000 M7 5 3.1 17 159 2-9 3000 M9 5 4.6 46 160 2-9 3000 M11 5 5.8 38 161 2-47 3000 M7 5 8.3 29 162 2-47 3000 M8 5 5.7 77 163 2-47 3000 M11 5 4.0 35 164 2-47 3000 M13 5 3.7 65 165 2-48 3000 M3 5 2.0 24 166 2-48 3000 M11 5 6.4 43

(227) In examples 167-177, different polar monomers were used instead of the corresponding polar monomer M3 in example 151 so as to obtain different oily polymers in examples 167-177, and the polymerization results are shown in table 5.

(228) TABLE-US-00005 TABLE 5 Polar monomer insertion rate the (the number amount of polar of the polymerization group per AlEt.sub.2Cl/ polar monomer activity 1000 Example Complex Ni monomer (mmol) (10.sup.5 g/mol .Math. h .Math. atm) methylene) 167 2-9 500 M3 2 5.3 52 168 2-9 1000 M3 5 6.9 49 169 2-9 3000 M3 10 9.1 98 170 2-9 3000 M2 5 6.0 123 171 2-9 3000 M4 5 8.2 75 172 2-9 3000 M7 5 5.8 35 173 2-9 3000 M11 5 8.5 117 174 2-47 3000 M7 5 9.8 57 175 2-47 3000 M11 5 5.1 35 176 2-47 3000 M13 5 4.5 105 177 2-48 3000 M3 5 2.8 34

Example 178

(229) 2.5 g of highly branched oily polyethylene obtained in example 104, Pd/C (50 mg), n-hexane (10 mL) were added into 50 mL egg-shaped flask. After exchanged nitrogen for three times, the reaction was carried out at room temperature, under 1 atm hydrogen atmosphere overnight. The reaction was monitored by .sup.1H NMR until the reactant has been hydrogenated completely. Then the hydrogenation was stopped, the reaction mixture was filtered and the solvent was removed to obtain oily highly branched alkanes, of which bromine value was 0.31 g/100 g, methyl number per 1000 methylene was 140, and viscosity index VI was 241, the kinematic viscosity at 100 C. was 7.9 cSt.

Example 179

(230) 2.5 g of highly branched oily polyethylene obtained in example 104 and Pd/C (50 mg) were added into 50 mL egg-shaped flask. After exchanged nitrogen for three times, the reaction was carried out at room temperature, under 1 atm hydrogen atmosphere overnight. The reaction was monitored by .sup.1H NMR until the reactant has been hydrogenated completely. Then the hydrogenation was stopped, the reaction mixture was filtered and the solvent was removed to obtain oily highly branched alkane, of which bromine value was 0.33 g/100 g, methyl number per 1000 methylene was 146.

Example 180

(231) The example 178 was repeated except that the Pd/C was replaced by Pd(OH).sub.2.

(232) Result: bromine value was 0.30 g/100 g.

Example 181

(233) The example 178 was repeated except that the hydrogenation substrate was replaced by the oily polyethylene obtained in example 115.

(234) Result: the bromine value of the oily highly branched alkane was 0.35 g/100 g, methyl number per 1000 methylene was 170, and viscosity index VI was 290.

Example 182

(235) The example 178 was repeated except that the hydrogenation substrate was replaced by the oily polyethylene obtained in example 118.

(236) Result: the bromine value of the oily highly branched alkane was 0.32 g/100 g.

Example 183

(237) The example 104 was repeated, and hydrogen was pumped in simultaneously when the olefin polymerization catalyst contacted the ethylene. After the hydrogenation was completed, it was filtered and the solvent of filtrate was removed so as to obtain oily highly branched alkane, of which bromine value was 0.46 g/100 g, methyl number per 1000 methylene was 230, and viscosity index was 196.

Example 184

(238) The example 104 was repeated, the olefin polymerization catalyst contacted to the ethylene for 30 min, Pd/C 50 mg was added without treatment, and then hydrogen was pumped. After the hydrogenation was completed, it was filtered and the solvent of filtrate was removed so as to obtain oily highly branched alkane, of which methyl number per 1000 methylene was 207.

Example 185

(239) The example 104 was repeated, treatment was omitted after the olefin polymerization catalyst contacted to the ethylene for 30 min, and the atmosphere was replaced by hydrogen. The reaction was conducted under hydrogen atmosphere until the hydrogenation was completed. It was filtered and the solvent of filtrate was removed so as to obtain oily highly branched alkane, the bromine value of which was 0.33 g/100 g.

Example 186

(240) 300 mL autoclave was dried under vacuum in 120 C. oil bath overnight, and replaced by nitrogen for three times. On 50 C. oil bath, 50 mL of toluene and 1.10 mL (0.9 mol/L) of diethylaluminum chloride in toluene was added, and 5 umol of complex 2-9 was added under 0.5 atm hydrogen atmosphere, and ethylene was pumped in to carry out the polymerization reaction for 30 min, then the reaction was stopped. The reaction solution was filtered and the solvent of filtrate was removed so as to obtain 4.0 g of oily highly branched alkane, of which the bromine value was 0.45 g/100 g, and the methyl number per 1000 methylene was 235.

Example 187

(241) The example 118 was repeated while the pressure of ethylene was changed to 10 atm.

(242) Results: The activity was 9.310.sup.6 g/mol.Math.h.Math.atm, and the methyl number per 1000 methylene of the oily polyethylene was 85.

Example 188

(243) The example 118 was repeated while the pressure of ethylene was changed to 20 atm.

(244) Results: The activity was 2.110.sup.7 g/mol.Math.h.Math.atm, and the methyl number per 1000 methylene of the oily polyethylene was 79.

Example 189

(245) The example 118 was repeated except that polymerization temperature was 50 C.

(246) Results: The activity was 6.910.sup.6 g/mol.Math.h.Math.atm, and the methyl number per 1000 methylene of the oily polyethylene was 103.

Example 190

(247) The example 118 was repeated except that polymerization temperature was 70 C.

(248) Results: The activity was 4.410.sup.6 g/mol.Math.h.Math.atm, and the methyl number per 1000 methylene of the oily polyethylene was 128.

Example 191

(249) The example 118 was repeated except that toluene was replaced by n-hexane.

(250) Results: The activity was 5.710.sup.6 g/mol.Math.h.Math.atm, and the methyl number per 1000 methylene of the oily polyethylene was 89.

Example 192

(251) The example 118 was repeated except that toluene was replaced by dichloromethane (DCM) and the polymerization time was 4 hours.

(252) Results: The activity was 6.610.sup.6 g/mol.Math.h.Math.atm, and the methyl number per 1000 methylene of the oily polyethylene was 157.

Example 193

(253) The example 118 was repeated except that toluene was replaced by 1, 2-dichloroethane (DCE).

(254) Results: The activity was 4.710.sup.6 g/mol.Math.h.Math.atm, and the methyl number per 1000 methylene of the oily polyethylene was 165.

Example 194

(255) The example 118 was repeated except that toluene was replaced by dichloromethane (DCM) and the ethylene pressure was changed to 10 atm.

(256) Results: The activity was 7.810.sup.6 g/mol.Math.h.Math.atm, and the methyl number per 1000 methylene of the oily polyethylene was 175.

Example 195

(257) The example 118 was repeated except that toluene was replaced by dichloromethane (DCM) and the ethylene pressure was changed to 20 atm.

(258) Results: The activity was 5.510.sup.7 g/mol.Math.h.Math.atm, and the methyl number per 1000 methylene of the oily polyethylene was 184.

Example 196

(259) The example 118 was repeated except that toluene was replaced by 1, 2-dichloroethane (DCE) and the ethylene pressure was changed to 20 atm.

(260) Results: The activity was 6.110.sup.7 g/mol.Math.h.Math.atm, and the methyl number per 1000 methylene of the oily polyethylene was 178.

Example 197

(261) The example 118 was repeated except that toluene was replaced by dichloromethane (DCM) and the ethylene pressure was changed to 5 atm, and the complex 2-9 was replaced by complex 2-2.

(262) Results: The activity was 9.010.sup.6 g/mol.Math.h.Math.atm, and the methyl number per 1000 methylene carbon of the oily polyethylene was 267.

Example 198

(263) The example 118 was repeated except that toluene was replaced by dichloromethane (DCM) and the ethylene pressure was changed to 10 atm, and the complex 2-9 was replaced by complex 2-2.

(264) Results: The activity was 2.310.sup.7 g/mol.Math.h.Math.atm, and the methyl number per 1000 methylene of the oily polyethylene was 283, the bromine value was 23.41 g/100 g, and the oxidation stability was 56 minutes. The .sup.13C spectrum was shown in FIG. 3. The .sup.13C spectrum has shown that the branch type of the polymer comprises methyl, ethyl, n-propyl, n-butyl, sec-butyl and other branches with more than four carbons, wherein sec-butyl number comprised in 1000 carbons was 24.

Example 199

(265) The example 118 was repeated except that toluene was replaced by 1, 2-dichloroethane (DCE) and the ethylene pressure was changed to 5 atm, and the complex 2-9 was replaced by complex 2-2.

(266) Results: The activity was 1.910.sup.7 g/mol.Math.h.Math.atm, and the methyl number per 1000 methylene of the oily polyethylene was 271.

Example 200

(267) The example 118 was repeated except that toluene was replaced by 1, 2-dichloroethane (DCE) and the ethylene pressure was changed to 10 atm, and the complex 2-9 was replaced by complex 2-2.

(268) Results: The activity was 4.810.sup.6 g/mol.Math.h.Math.atm, and the methyl number per 1000 methylene of the oily polyethylene was 246.

Example 201

(269) 1 L autoclave was dried under vacuum at 120 C. for 3 hours in advance. After cooled to 30 C., dichloromethane (DCM) 400 mL was added, and cocatalyst diethylaluminium chloride 2.50 mL (2.0 mol/L) was added, stirred for 10 min, and complex 2-2 (10 umol) was added, tracked under 5 atm ethylene pressure for 2 hours, and then the ethylene stream was cut off. Oily polyethylene was obtained after removing the solvent from the reaction solution. The activity was 3.910.sup.7 g/mol.Math.h.Math.atm, and the methyl number per 1000 methylene of the oily polyethylene was 282. The polymer was measured by GPC: Mn=349, Mw=673, PDI=1.69.

(270) The change of inner temperature of the kettle and ethylene flow over time during the reaction was shown in FIG. 4.

(271) The .sup.13C spectrum was shown in FIG. 5, it can be seen from the .sup.13C spectrum that there are abundant types of branches in the polymer.

Example 202

(272) The example 201 was repeated while the pressure of ethylene was changed to 10 atm.

(273) Results: The activity was 5.310.sup.7 g/mol.Math.h.Math.atm, and the methyl number per 1000 methylene of the oily polyethylene was 264.

Example 203

(274) The example 201 was repeated except that the reaction temperature was reduced to 20 C.

(275) Results: The activity was 8.010.sup.7 g/mol.Math.h.Math.atm, and the methyl number per 1000 methylene of the oily polyethylene was 257.

Example 204

(276) The example 201 was repeated except that the reaction temperature was raised to 50 C.

(277) Results: The activity was 5.010.sup.7 g/mol.Math.h.Math.atm, and the methyl number per 1000 methylene of the oily polyethylene was 278.

Example 205

(278) The example 201 was repeated except that the solution was replaced by 1, 2-dichloroethane (DCE) and the ethylene pressure was changed to 10 atm.

(279) Results: The activity was 6.310.sup.7 g/mol.Math.h.Math.atm, and the methyl number per 1000 methylene of the oily polyethylene was 264.

Example 206

(280) The example 201 was repeated except that the solution was replaced by toluene.

(281) Results: The activity was 8.710.sup.7 g/mol.Math.h.Math.atm, and the methyl number per 1000 methylene of the oily polyethylene was 231.

Example 207

(282) The example 201 was repeated except that the complex 2-2 was replaced by complex 2-4.

(283) Results: The activity was 8.410.sup.7 g/mol.Math.h.Math.atm, and the methyl number per 1000 methylene of the oily polyethylene was 278.

Example 208

(284) The example 201 was repeated except that the complex 2-2 was replaced by complex 2-5.

(285) Results: The activity was 9.110.sup.7 g/mol.Math.h.Math.atm, and the methyl number per 1000 methylene of the oily polyethylene was 261.

(286) The .sup.13C spectrum of the polymer is shown in FIG. 6.

Example 209

(287) The example 208 was repeated while the pressure of ethylene was changed to 10 atm.

(288) Results: The activity was 1.610.sup.8 g/mol.Math.h.Math.atm, and the methyl number per 1000 methylene of the oily polyethylene was 273.

Example 210 (Comparison of Example 201)

(289) The example 201 was repeated except that the complex 2-2 was replaced by complex 2-56.

(290) ##STR00136##

(291) Results: The obtained polymer was a mixture of solid and liquid product, wherein the solid product was 123.70 g and the liquid product was 37.63 g.

Example 211

(292) 20 L autoclave was dried under vacuum at 120 C. for 5 hours in advance. After cooled to 30 C., dichloromethane (DCM) 400 mL was added, and cocatalyst diethylaluminium chloride 25.0 mL (2.0 mol/L) was added, stirred for 30 min, and complex 2-2 (100 umol) was added, reacted under 5 atm ethylene pressure for 3 hours, and then the ethylene stream was cut off.

(293) Oily polyethylene was obtained after removing the solvent from the reaction solution. The activity was 3.510.sup.7 g/mol.Math.h.Math.atm, and the methyl number per 1000 methylene of the oily polyethylene was 277.

Example 212

(294) The example 211 was repeated while the pressure of ethylene was changed to 10 atm.

(295) Results: The activity was 7.610.sup.7 g/mol.Math.h.Math.atm, and the methyl number per 1000 methylene of the oily polyethylene was 239.

Example 213

(296) The example 211 was repeated except that the reaction temperature was raised to 50 C.

(297) Results: The activity was 4.810.sup.7 g/mol.Math.h.Math.atm, and the methyl number per 1000 methylene of the oily polyethylene was 286.

Example 214

(298) The example 211 was repeated except that the solution was replaced by 1, 2-dichloroethane (DCE) and the ethylene pressure was changed to 10 atm.

(299) Results: The activity was 9.210.sup.7 g/mol.Math.h.Math.atm, and the methyl number per 1000 methylene of the oily polyethylene was 272.

(300) In examples 215-225, different racemic or optical raw materials were used instead of the corresponding raw material in example 1 so as to prepare ligands L1-49 to L1-59, and the results are shown in Table 6.

(301) TABLE-US-00006 TABLE 6 structural characterization (elemental Example No. The structure of the ligand: analysis) 215 L1-49 Anal. Calcd. For C.sub.30H.sub.26N.sub.2O: C, 83.69; H, 6.09; N, 6.51; O, 3.72. Found: C, 83.89; H, 6.70; N, 6.75. 216 L1-50 Anal. Calcd. For C.sub.32H.sub.30N.sub.2O: C, 83.81; H, 6.59; N, 6.11; O, 3.49. Found: C, 83.96; H, 6.81; N, 6.97. 217 L1-51 Anal. Calcd. For C.sub.33H.sub.30N.sub.2O: C, 84.22; H, 6.43; N, 5.95; O, 3.40. Found: C, 84.39; H, 6.50; N, 5.87. 218 L1-52 0 Anal. Calcd. For C.sub.34H.sub.34N.sub.2O: C, 83.91; H, 7.04; N, 5.76; O, 3.29. Found: C, 84.05; H, 6.97; N, 5.82. 219 L1-53 Anal. Calcd. For C.sub.38H.sub.42N.sub.2O: C, 84.09; H, 7.80; N, 5.16; O, 2.95. Found: C, 84.03; H, 7.59; N, 5.01. 220 L1-54 Anal. Calcd. For C.sub.42H.sub.50N.sub.2O: C, 84.23; H, 8.42; N, 4.68; O, 2.67. Found: C, 84.70; H, 7.64; N, 4.75. 221 L1-55 Anal. Calcd. For C.sub.30H.sub.22F.sub.4N.sub.2O: C, 71.71; H, 4.41; F, 15.12; N, 5.57; O, 3.18. Found: C, 70..89; H, 4.72; N, 5.35. 222 L1-56 Anal. Calcd. For C.sub.30H.sub.22I.sub.4N.sub.2O: C, 38.57; H, 2.37; I, 54.34; N, 3.00; O, 1.71. Found: C, 38.09; H, 2.70; N, 3.45. 223 L1-57 Anal. Calcd. For C.sub.34H.sub.34N.sub.2O.sub.5: C, 74.16; H, 6.22; N, 5.09; O, 14.53. Found: C, 74.46; H, 6.50; N, 5.18. 224 L1-58 Anal. Calcd. For C.sub.29H.sub.26N.sub.2O: C, 83.22; H, 6.26; N, 6.69; O, 3.82. Found: C, 83.38; H, 6.53; N, 6.75. 225 L1-59 Anal. Calcd. For C.sub.44H.sub.38N.sub.2O: C, 86.52; H, 6.27; N, 4.59; O, 2.62. Found: C, 86.84; H, 6.52; N, 4.76.

(302) In examples 226-234, different ligand or metal precursor were used instead of the corresponding ligand or metal precursor in example 49 so as to prepare complexes 2-57 to 2-64, and the results are shown in table 7.

(303) TABLE-US-00007 TABLE 7 Example No. Structure elemental analysis 226 2-57 Anal. Calcd. For C.sub.30H.sub.26Br.sub.2N.sub.2NiO: C, 55.52; H, 4.04; N, 4.32. Found: C, 55.17; H, 4.60; N, 4.15. 227 2-58 Anal. Calcd. For C.sub.33H.sub.30Br.sub.2N.sub.2NiO: C, 57.52; H, 4.39; N, 4.07. Found: C, 57.26; H, 4.32; N, 4.40. 22 2-59 0 Anal. Calcd. For C.sub.34H.sub.34Br.sub.2N.sub.2NiO: C, 57.91; H, 4.86; N, 3.97. Found: C, 57.63; H, 5.07; N, 4.05. 229 2-60 Anal. Calcd. For C.sub.30H.sub.22Br.sub.2F.sub.4N.sub.2NiO: C, 49.98; H, 3.08; N, 3.89. Found: C, 49.95; H, 3.22; N, 4.18. 230 2-61 Anal. Calcd. For C.sub.30H.sub.22Br.sub.2I.sub.4N.sub.2NiO: C, 31.26; H, 1.92; N, 2.43. Found: C, 31.43; H, 1.69; N, 2.45. 231 2-62 Anal. Calcd. For C.sub.34H.sub.34Br.sub.2N.sub.2NiO.sub.5: C, 53.09; H, 4.46; N, 3.64. Found: C, 53.67; H, 4.62; N, 3.58. 232 2-63 Anal. Calcd. For C.sub.29H.sub.26Br.sub.2N.sub.2NiO: C, 54.68; H, 4.11; N, 4.40. Found: C, 54.23; H, 4.22; N, 4.32. 234 2-64 Anal. Calcd. For C.sub.44H.sub.38Br.sub.2N.sub.2NiO: C, 63.73; H, 4.62; N, 3.38. Found: C, 63.52; H, 4.37; N, 3.40.

Example 235

(304) The example 118 was repeated except that toluene was replaced by dichloromethane (DCM) and the ethylene pressure was changed to 10 atm, and the complex 2-9 was replaced by complex 2-57.

(305) Results: The activity was 2.310.sup.7 g/mol.Math.h.Math.atm, and the methyl number per 1000 methylene of the oily polyethylene was 201.

Example 236

(306) The example 118 was repeated except that toluene was replaced by dichloromethane (DCM) and the ethylene pressure was changed to 10 atm, and the complex 2-9 was replaced by complex 2-59.

(307) Results: The activity was 2.810.sup.7 g/mol.Math.h.Math.atm, and the methyl number per 1000 methylene of the oily polyethylene was 214.

Example 237

(308) The example 118 was repeated except that toluene was replaced by dichloromethane (DCM) and the ethylene pressure was changed to 10 atm, and the complex 2-9 was replaced by complex 2-61.

(309) Results: The activity was 2.010.sup.7 g/mol.Math.h.Math.atm, and the methyl number per 1000 methylene of the oily polyethylene was 254.

Example 238

(310) The example 118 was repeated except that toluene was replaced by dichloromethane (DCM) and the ethylene pressure was changed to 10 atm, and the complex 2-9 was replaced by complex 2-63.

(311) Results: The activity was 3.310.sup.7 g/mol.Math.h.Math.atm, and the methyl number per 1000 methylene of the oily polyethylene was 243.

Example 239

(312) The example 118 was repeated except that toluene was replaced by dichloromethane (DCM) and the ethylene pressure was changed to 10 atm, and the complex 2-9 was replaced by complex 2-64.

(313) Results: The activity was 8.110.sup.7 g/mol.Math.h.Math.atm, and the methyl number per 1000 methylene of the oily polyethylene was 182.

Example 240

(314) The example 201 was repeated except that the complex 2-2 was replaced by complex 2-57.

(315) Results: The activity was 3.410.sup.7 g/mol.Math.h.Math.atm, and the methyl number per 1000 methylene of the oily polyethylene was 212.

Example 241

(316) The example 201 was repeated except that the complex 2-2 was replaced by complex 2-59.

(317) Results: The activity was 3.810.sup.7 g/mol.Math.h.Math.atm, and the methyl number per 1000 methylene of the oily polyethylene was 225.

Example 242

(318) The example 201 was repeated except that the complex 2-2 was replaced by complex 2-61.

(319) Results: The activity was 2.410.sup.7 g/mol.Math.h.Math.atm, and the methyl number per 1000 methylene of the oily polyethylene was 262.

Example 243

(320) The example 201 was repeated except that the complex 2-2 was replaced by complex 2-63.

(321) Results: The activity was 5.410.sup.7 g/mol.Math.h.Math.atm, and the methyl number per 1000 methylene of the oily polyethylene was 282.

Example 244

(322) 2.0 g of highly branched oily polyethylene obtained in example 198, Pd/C 150 mg, 15 mL of n-hexane and 5 mL ethyl acetate were added into a 100 mL egg-shaped flask. After recharged the nitrogen for three times, the reaction was conducted at 1 atm hydrogen atmosphere and at room temperature overnight. It was monitored by .sup.1H-NMR until found that the raw material has been hydrogenated completely. Then the hydrogenation was stopped, the reaction mixture was filtered and the solvent was removed to obtain oily highly branched alkane, bromine value of which was 0.31 g/100 g, methyl number per 1000 methylene was 265, the bromine value was 0.43 g/100 g, and the oxidation stability was 107 minutes.

Example 245

(323) 2.0 g of highly branched oily polyethylene obtained in example 198, Pd/C 150 mg, 15 mL n-hexane and 5 mL ethyl acetate were added into 50 mL egg-shaped flask. After recharged nitrogen for three times, the reaction was conducted under 1 atm hydrogen atmosphere and at 40 C. for 6 hours before the hydrogenation was stopped.

(324) ##STR00156##

(325) The following table lists the hydrogenation conversion rates for several oily polyethylene under the same conditions. P1 was the oily polyethylene obtained in Example 198, P2 was the oily polyethylene obtained in Example 211, P3 was the oily polyethylene prepared through polymerization by using the palladium catalysts (complex 2-65) according to the conditions disclosed in patent (Guan, WO1999047572) example 6.

(326) TABLE-US-00008 Polyethylene Hydrogenation conversion (%) P1 100 P2 100 P3 63

(327) Under the above conditions, the hydrogenation conversion rate of P1 and P2 were 100%, while the hydrogenation conversion rate of P3 was 63%. The analysis of the branched chain type of the alkane mixture after P1 hydrogenation is shown in FIG. 7.

Example 246

(328) The rheological properties of the hydrogenated polymers in Example 244 and the hydrogenated products P1-hydrogenation and P2-hydrogenation of the oily sample in 245 were tested by Auton Parr Rotary Rheometer (MCR 302, concentric drum rotor CC27). The results were shown in FIG. 8. The results show that the viscosity of the sample does not change with the shear rate and possesses the properties of the Newtonian fluid within the range of 40-120 C., which also shows that the polymer has hyperbranched structure.

Example 247

(329) 10.0 g of highly branched oily polyethylene obtained in example 201, Pd/C 150 mg, n-hexane 100 mL and ethylacetate 30 mL were added into 250 mL egg-shaped flask. After recharged nitrogen for three times, the reaction was conducted under 1 atm hydrogen atmosphere and at room temperature overnight. The reaction was monitored by .sup.1H-NMR until that the reactant has been hydrogenated completely. Then the hydrogenation was stopped, the reaction mixture was filtered and the solvent was removed to obtain oily highly branched alkanes, bromine value of which was 0.33 g/100 g, methyl number per 1000 methylene was 274, and viscosity index VI was 253, the kinematic viscosity under 100 C. was 8.4 cSt, and the surface tension was 24.6 mM/m.

Example 248

(330) 500 g of highly branched oily polyethylene obtained in example 201, Pd/C 1.5 g, n-hexane 1 L and ethyl acetate 300 mL were added into 2 L reaction flask. After recharged nitrogen for three times, the reaction was conducted at 1 atm hydrogen atmosphere and at 50 C. overnight. The reaction was monitored by .sup.1H-NMR until that the raw material has been hydrogenated completely. Then the hydrogenation was stopped, the reaction mixture was filtered and the solvent was removed to obtain oily highly branched alkanes, bromine value of which was 0.38 g/100 g, methyl number per 1000 methylene was 269, and viscosity index VI was 259, the kinematic viscosity at 100 C. was 8.6 cSt, and the surface tension was 24.0 mM/m.

(331) The picture of the oily highly branched alkane is shown in FIG. 9, which is a colorless, clear oily substance.

Example 249

(332) 500 g of highly branched oily polyethylene obtained in example 201, Pd/C 1.5 g, n-hexane 1 L and ethyl acetate 300 mL were added into a 2 L autoclave. After recharged nitrogen for three times, the reaction was conducted at 20 bar pressure hydrogen atmosphere and at 50 C. for 6 hours. The reaction was monitored by .sup.1H-NMR until that the raw material has been hydrogenated completely. Then the hydrogenation was stopped, the reaction mixture was filtered and the solvent was removed to obtain oily highly branched alkanes, of which bromine value was 0.40 g/100 g, methyl number per 1000 methylene was 273, and viscosity index VI was 261, the kinematic viscosity under 100 C. was 8.2 cSt, and the surface tension was 24.7 mM/m.

Example 250

(333) 500 g of highly branched oily polyethylene obtained in example 208, Pd/C 1.5 g, n-hexane 1 L and ethyl acetate 300 mL were added into 2 L autoclave. After recharged nitrogen for three times, the reaction was conducted under 20 bar pressure hydrogen atmosphere and at for 6 hours. The reaction was monitored by .sup.1H-NMR until that the raw material has been hydrogenated completely. Then the hydrogenation was stopped, the reaction mixture was filtered and the solvent was removed to obtain oily highly branched alkanes, of which bromine value was 0.50 g/100 g, methyl number per 1000 methylene was 287, and viscosity index VI was 272, the kinematic viscosity at 100 C. was 4.2 cSt, and the surface tension was 22.0 mM/m.

(334) All literatures mentioned in the present application are incorporated herein by reference, as though each one is individually incorporated by reference. Additionally, it should be understood that after reading the above teachings, those skilled in the art can make various changes and modifications to the present invention. These equivalents also fall within the scope defined by the appended claims.