Non-oriented electrical steel sheet, production method therefor, and motor core

Abstract

In the production of a non-oriented electrical stress sheet by hot rolling a slab having a chemical composition comprising, by mass %, C: not more than 0.005, Si: 1.5-6.0, Mn: 0.05-2.0 and P: 0.03-0.15, subjecting to a hot band annealing, if necessary, cold rolling, finish annealing, and forming an insulation coating, the cooling from 700 C. to 500 C. in the finish annealing is conducted in an oxidizing atmosphere with an oxygen potential P.sub.H2O/P.sub.H2 of not less than 0.001 for 1-300 seconds, whereby P is segregated into the surface of the steel sheet after the finish annealing to obtain a non-oriented electrical steel sheet enhancing a crystal grain growth properties in the stress relief annealing.

Claims

1. A non-oriented electrical steel sheet having a chemical composition comprising C: not more than 0.005 mass %, Si: 1.5-6.0 mass %, Mn: 0.05-2.0 mass %, P: 0.03-0.15 mass %, S: not more than 0.005 mass %, N: not more than 0.005 mass %, Al: not more than 0.005 mass % and the remainder being Fe and inevitable impurities, wherein a ratio (P.sub.120/Fe.sub.700) of a peak to peak height P.sub.120 of P near to an electronic energy of 120 eV to a peak to peak height Fe.sub.700 of Fe near to an electronic energy of 700 eV in an Auger differential spectrum obtained by analyzing a surface of the steel sheet after a finish annealing by an Auger electron spectroscopy is not less than 0.02.

2. The non-oriented electrical steel sheet according to claim 1, characterized by containing one or two selected from Sn: 0.005-0.2 mass % and Sb: 0.005-0.2 mass % in addition to the chemical composition.

3. The non-oriented electrical steel sheet according to claim 1, characterized in that a yield strength is not less than 400 MPa.

4. A method of producing a non-oriented electrical steel sheet according to claim 1 by hot rolling a slab having a chemical composition as claimed in claim 1, pickling without a hot band annealing or after a hot band annealing or a self-annealing, performing one cold rolling or two or more cold rollings interposing an intermediate annealing therebetween, performing a finish annealing, and forming an insulation coating, characterized in that a cooling from 700 C. to 500 C. in the finish annealing is conducted in an oxidizing atmosphere having an oxygen potential P.sub.H2O/P.sub.H2 of not less than 0.001 for 1-300 seconds, wherein P.sub.H2O and P.sub.H2 are partial pressure of H.sub.2O and H.sub.2 respectively.

5. A rotor core for a rotary machine, characterized in that the rotor core is formed by punching out rotor core materials from the non-oriented electrical steel sheet as claimed in claim 1 and laminating the rotor core materials.

6. A stator core for a rotary machine, characterized in that the stator core is formed by punching out stator core materials from the non-oriented electrical steel sheet as claimed in claim 1, laminating the stator core materials, and subjecting to a stress relief annealing.

7. The non-oriented electrical steel sheet according to claim 2, characterized in that a yield strength is not less than 400 MPa.

8. A method of producing a non-oriented electrical steel sheet according to claim 2 by hot rolling a slab having a chemical composition as claimed in claim 2, pickling without a hot band annealing or after a hot band annealing or a self-annealing, performing one cold rolling or two or more cold rollings interposing an intermediate annealing therebetween, performing a finish annealing, and forming an insulation coating, characterized in that a cooling from 700 C. to 500 C. in the finish annealing is conducted in an oxidizing atmosphere having an oxygen potential H.sub.2O, /P.sub.H2 of not less than 0.001 for 1-300 seconds, wherein P.sub.H2O and P.sub.H2 are partial pressure of H.sub.2O and H.sub.2 respectively.

9. A rotor core for a rotary machine, characterized in that the rotor core is formed by punching out rotor core materials from the non-oriented electrical steel sheet as claimed in claim 2 and laminating the rotor core materials.

10. A rotor core for a rotary machine, characterized in that the rotor core is formed by punching out rotor core materials from the non-oriented electrical steel sheet as claimed in claim 3 and laminating the rotor core materials.

11. A rotor core for a rotary machine, characterized in that the rotor core is formed by punching out rotor core materials from the non-oriented electrical steel sheet as claimed in claim 7 and laminating the rotor core materials.

12. A stator core for a rotary machine, characterized in that the stator core is formed by punching out stator core materials from the non-oriented electrical steel sheet as claimed in claim 2, laminating the stator core materials, and subjecting to a stress relief annealing.

13. A stator core for a rotary machine, characterized in that the stator core is formed by punching out stator core materials from the non-oriented electrical steel sheet as claimed in claim 3, laminating the stator core materials, and subjecting to a stress relief annealing.

14. A stator core for a rotary machine, characterized in that the stator core is formed by punching out stator core materials from the non-oriented electrical steel sheet as claimed in claim 7, laminating the stator core materials, and subjecting to a stress relief annealing.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) FIG. 1 is a graph showing a relation between an addition amount of Si and an iron loss W.sub.10/400 before and after a stress relief annealing.

(2) FIG. 2 is a graph showing a relation between an addition amount of P and an iron loss W.sub.10/400 before and after a stress relief annealing.

(3) FIG. 3 is a graph showing a relation between an addition amount of P and P.sub.120/Fe.sub.700 near to the surface of the steel sheet after the finish annealing.

DETAILED DESCRIOTION OF EMBODIMENTS OF THE INVENTION

(4) There will be described experiments building a momentum for developing aspects of the invention.

(5) <Experiment 1>

(6) Firstly, an experiment is conducted for studying an influence of Si on the crystal grain growth properties in the stress relief annealing.

(7) A steel containing C: 0.003 mass %, Mn: 0.05 mass %, P: 0.01 mass %, S: 0.002 mass %, N: 0.002 mass % and Al: 0.001 mass % and added with Si in an amount varying within a range of 0.5-4.0 mass % is melted laboratorially to provide a steel ingot, which is hot rolled to form a hot rolled sheet having a sheet thickness of 2.0 mm.

(8) Then, the hot rolled sheet is subjected to a hot band annealing at 1000 C. for 30 seconds, pickled and cold rolled to form a cold rolled sheet having a sheet thickness of 0.25 mm, which is thereafter subjected to a finish annealing at 800 C. for 10 seconds in a non-oxidizing atmosphere having an oxygen potential P.sub.H2O/P.sub.H2 of 0.0005 (10 vol % of H.sub.290 vol % of N.sub.2 and a dew point of 50 C.) to provide a non-oriented electrical steel sheet, and an iron loss W.sub.10/400 thereof is measured by a 25 cm Epstein method.

(9) Next, the steel sheet is subjected to a stress relief annealing in an N.sub.2 atmosphere at 750 C. for 2 hours, and an iron loss W.sub.10/400 thereof is again measured by a 25 cm Epstein method.

(10) FIG. 1 shows a relation between the iron loss W.sub.10/400 before and after the stress relief annealing and the addition amount of Si. As seen from this figure, when the addition amount of Si is 0.5-1.5 mass %, the ion loss W.sub.10/400 is decreased by the stress relief annealing, while when the addition amount of Si is not less than 1.5 mass %, the iron loss W.sub.10/400 is not decreased.

(11) In order to examine this cause, the structure of the steel sheet after the stress relief annealing is observed by TEM, and as a result, a large number of fine Si.sub.3N.sub.4 precipitates are found near the surface layer in a steel sheet having a Si addition amount of not less than 1.5 mass %, while the fine precipitates are not found in a steel sheet having a Si addition amount of 0.5-1.5 mass %. It is revealed from this result that in the steel sheet having a large addition amount of Si, N penetrated from the atmosphere into the steel reacts with Si in the steel to precipitate fine Si.sub.3N.sub.4, whereby the grain growth is blocked and the iron loss properties is not improved.

(12) <Experiment 2>

(13) Next, the inventors have studied an influence of an atmosphere in the stress relief annealing and an addition amount of P upon the crystal grain growth properties.

(14) A steel containing C: 0.003 mass %, Si: 3.0 mass %, Mn: 0.05 mass %, S: 0.002 mass %, N: 0.002 mass %, Al: 0.001 mass % and added with P in an amount varying within a range of 0.01-0.15 mass % is melted laboratorially to provide a steel ingot, which is hot rolled to form a hot rolled sheet having a sheet thickness of 2.0 mm.

(15) Then, the hot rolled sheet is subjected to a hot band annealing at 1000 C. for 30 seconds, pickled and cold rolled to form a cold rolled sheet having a sheet thickness of 0.25 mm, which is thereafter subjected to a finish annealing at 800 C. for 10 seconds in a non-oxidizing atmosphere having an oxygen potential P.sub.H2O/P.sub.H2 of 0.0005 (10 vol % of H.sub.290 vol % of N.sub.2 and a dew point of 50 C.) to provide a non-oriented electrical steel sheet. In this case, the cooling from 700 C. to 500 C. is conducted for 10 seconds on the following 3 conditions:

(16) Condition A: A non-oxidizing atmosphere having P.sub.H2O/P.sub.H2 of 0.0005 (10 vol % of H.sub.290 vol % of N.sub.2 and a dew point of 50 C.);

(17) Condition B: An oxidizing atmosphere having P.sub.H2O/P.sub.H2 of 0.01 (2 vol % of H.sub.298 vol % of N.sub.2 and a dew point of 40 C.); and

(18) Condition C: An oxidizing atmosphere having P.sub.H2O/P.sub.H2 of 0.5 (0.1 vol % of H.sub.299.9 vol % of N.sub.2 and a dew point of 30 C.).

(19) With respect to the thus obtained steel sheets after the finish annealing is measured an iron loss W.sub.10/400 by a 25 cm Epstein method. Moreover, the steel sheet is subjected to a stress relief annealing in a N.sub.2 atmosphere at 750 C. for 2 hours, and an iron loss W.sub.10/400 is again measured by a 25 cm Epstein method.

(20) FIG. 2 shows a relation between the iron loss W.sub.10/400 before and after the stress relief annealing and the addition amount of P. Since the iron loss W.sub.10/400 before the stress relief annealing is almost constant irrespective of P.sub.H2O/P.sub.H2 in the atmosphere during the cooling, an iron loss W.sub.10/400 at P.sub.H2O/P.sub.H2 of 0.0005 is shown in FIG. 2.

(21) As seen from FIG. 2, the iron loss properties in the steel sheet cooled at P.sub.H2O/P.sub.H2 of 0.0005 is not improved so much even in the stress relief annealing, while the iron loss in the steel sheet cooled at P.sub.H2O/P.sub.H2 of 0.01 or 0.5 is largely decreased when the addition amount of P is not less than 0.03 mass %.

(22) As the structure of the steel sheet after the stress relief annealing is observed by TEM, fine Si.sub.3N.sub.4 precipitates are found at any case of P.sub.H2O/P.sub.H2 of 0.0005, 0.01 and 0.5 in the steel sheets having a P addition amount of less than 0.03 mass %, while Si.sub.3N.sub.4 precipitates are not found in either case of P.sub.H2O/P.sub.H2 of 0.01 or 0.5 in the steel sheets having a P addition amount of not less than 0.03 mass %.

(23) In order to examine this cause, a segregation amount of P in the surface layer of the steel sheet after the finish annealing is analyzed by an Auger electron stereoscopy (AES). Moreover, the segregation amount of P is evaluated by a ratio (P.sub.120/Fe.sub.700) of a peak to peak height P.sub.120 of P near to an electronic energy of 120 eV to a peak to peak height Fe.sub.700 of Fe near to an electronic energy of 700 eV in an Auger differential spectrum. Here, the Auger differential spectrum is a spectrum obtained by differentiating an Auger spectrum.

(24) FIG. 3 shows a relation between P.sub.120/Fe.sub.700 near the surface layer of the steel sheet and the addition amount of P. As seen from this figure, in the steel sheets cooled at P.sub.H2O/P.sub.H2 of 0.01 or 0.5, P is enriched in the surface layer when the P addition amount is not less than 0.03 mass % to bring about P.sub.120/Fe.sub.700 exceeding 0.02. From this result, it is considered that the reason why the iron loss W.sub.10/400 is decreased by the stress relief annealing in the steel sheet having the P addition amount of not less than 0.03 mass % is due to the fact that penetration of N from the atmosphere into the steel is inhibited by P enriched on the surface layer through the finish annealing and hence the fine Si.sub.3N.sub.4 is not precipitated.

(25) The reason why the segregation of P into the surface layer of the steel sheet is promoted by rendering the atmosphere in the cooling during the finish annealing into an oxidizing atmosphere is not clear sufficiently, but it is considered due to the fact that decarburization is caused in the surface layer of the steel sheet in the oxidizing atmosphere to promote the segregation of P.

(26) It can be seen from the above results that the segregation of P into the surface layer of the steel sheet in the finish annealing is extremely effective for ensuring the crystal grain growth properties in the subsequent stress relief annealing.

(27) Next, the chemical composition of the non-oriented electrical steel sheet according to aspects of the invention will be explained.

(28) C: not more than 0.005 mass %

(29) C is a harmful element causing magnetic aging to deteriorate magnetic properties of a product sheet, so that it is limited to not more than 0.005 mass % in accordance with aspects of the invention. It is preferably not more than 0.003 mass %.

(30) Si: 1.5-6.0 mass %

(31) Si is an element effective for increasing a specific resistance of the steel sheet to decrease an iron loss. In accordance with aspects of the invention, Al as an element increasing an electric resistance like Si is not added, and hence Si is added in an amount of not less than 1.5 mass %. However, steel is remarkably embrittled by an addition exceeding 6.0 mass %. Therefore, Si is a range of 1.5-6.0 mass %. Preferably, it is 1.5-4.0 mass %.

(32) Mn: 0.05-2.0 mass %

(33) Mn is necessary to be added in an amount of not less than 0.05 mass % for preventing red brittleness in the hot rolling. When it exceeds 2.0 mass %, however, the magnetic flux density is decreased and embrittlement becomes prominent. Therefore, Mn is a range of 0.05-2.0 mass %. Preferably, it is a range of 0.05-1.5 mass %.

(34) P: 0.03-0.15 mass %

(35) P is an element effective for ensuring the crystal grain growth properties in the stress relief annealing as described above, and it is necessary to be added in an amount of not less than 0.03 mass %. When it exceeds 0.15 mass %, however, steel is embrittled to hinder the cold rolling. Therefore, P is a range of 0.03-0.15 mass %. Preferably, it is a range of 0.03-0.10 mass %.

(36) S: not more than 0.005 mass %

(37) S is a harmful element forming sulfides such as MnS and the like to increase the iron loss, so that an upper limit is set to 0.005 mass %. Preferably, it is not more than 0.003 mass %.

(38) N: not more than 0.005 mass %

(39) N forms nitrides and blocks the grain growth to deteriorate the iron loss properties, so that it is limited to not more than 0.005 mass %. Preferably, it is not more than 0.003 mass %.

(40) Al: not more than 0.005 mass %

(41) When a slight amount of Al exits, fine AlN is formed to block the grain growth and damage magnetic properties, so that it is limited to not more than 0.005 mass %. Preferably, it is not more than 0.003 mass %.

(42) In the non-oriented electrical steel sheet according to aspects of the invention, the remainder other than the above essential ingredients is Fe and inevitable impurities. However, one or two of Sn and Sb can be contained in the following range.

(43) Sn: 0.005-0.2 mass %, Sb: 0.005-0.2 mass %

(44) Each of Sn and Sb is an element improving the texture to increase the magnetic flux density. In order to obtain the above effect, each element is preferable to be added at least in an amount of not less than 0.005 mass %. When it exceeds 0.2 mass %, however, the above effect is saturated. Therefore, when Sn and/or Sb are added, it is preferable to be add in the above range. More preferably, Sn is a range of 0.01-0.15 mass % and Sb is a range of 0.01-0.15 mass %.

(45) The production method of the non-oriented electrical steel sheet according to aspects of the invention will be described below.

(46) The non-oriented electrical steel sheet according to aspects of the invention can be produced by a well-known method as long as a slab having P content in the above proper range is used as a raw steel material. For example, it can be produced by a method wherein molten steel adjusted to have the above chemical composition through a usual refining process of melting a steel in a converter, an electric furnace or the like and subjecting to a secondary refining in a degassing facility or the like is shaped into a slab by a continuous casting method and hot rolled to form a hot rolled sheet, which is subjected to a hot band annealing, if necessary, pickled, cold rolled to form a cold rolled sheet, and then subjected to a finish annealing.

(47) The sheet thickness of the steel sheet after the hot rolling (hot rolled sheet) is preferably a range of 1.0-5.0 mm. When it is less than 1.0 mm, rolling troubles are increased in the hot rolling, while when it exceeds 5.0 mm, the cold rolling reduction becomes extremely high to deteriorate the texture.

(48) In the case of performing the hot band annealing, it is preferable that a soaking temperature is a range of 900-1200 C. When it is lower than 900 C., the effect of the hot band annealing is small and the magnetic properties are not sufficiently improved, while when it exceeds 1200 C., it becomes disadvantageous costly, and further the surface defects are caused due to scales. More preferably, it is a range of 950-1050 C.

(49) Moreover, a self-annealing of a coil wound after the hot rolling may be utilized instead of the hot band annealing. In this case, the winding temperature of the coil is preferably not lower than 600 C. and more preferably not lower than 620 C. The upper limit of the winding temperature is preferable to be not higher than 750 C. from a viewpoint of preventing scale residue caused in the pickling of the hot rolled sheet.

(50) The cold rolling after the hot rolling or hot band annealing is preferably conducted once or two or more interposing an intermediate annealing therebetween. In particular, the final cold rolling is preferable to be a warm rolling conducted by raising the sheet temperature to about 200 C. for the purpose of improving the magnetic flux density if there is no problem in the cost on the restriction of installation or production.

(51) It is preferable that the sheet thickness of the cold rolled sheet (final sheet thickness) is a range of 0.1-1.0 mm. When it is less than 0.1 mm, the productivity is decreased, while when it exceeds 1.0 mm, the effect of decreasing the iron loss is small.

(52) As the finish annealing applied to the cold rolled sheet with the final sheet thickness, it is preferable to adopt a continuous annealing of soaking the sheet at a temperature of 700-1100 C. for 1-300 seconds. When the soaking temperature is lower than 700 C., recrystallization is not sufficiently promoted, and good magnetic properties cannot be obtained, and further an effect of correcting the shape in the continuous annealing cannot be sufficiently obtained. On the other hand, when it exceeds 1100 C., the crystal grains are coarsened to decrease the strength or lower the toughness. It is more preferable that the soaking temperature is 800-1100 C. and the soaking time is 1-100 seconds. Moreover, the temperature and the time of the finish annealing is desirable to be low and short, respectively, as long as the iron loss is accepted for ensuring the strength of the steel sheet after the finish annealing.

(53) The atmosphere during the soaking in the continuous annealing is preferable to be a non-oxidizing atmosphere having an oxygen potential P.sub.H2O/P.sub.H2 of not more than 0.001, because if it is an oxidizing atmosphere, oxides violently grown in the surface layer of the steel sheet block the grain growth and the iron loss properties is deteriorated. More preferably, it is not more than 0.0005.

(54) And also, the atmosphere in the cooling after the soaking is necessary to be an oxidizing atmosphere having an oxygen potential P.sub.H2O/P.sub.H2 of not less than 0.001 for promoting segregation of P into the surface layer of the steel sheet. Preferably, it is not less than 0.003. When P.sub.H2O/P.sub.H2 is too high, unevenness of oxidation called gas mark is caused in the surface layer of the steel sheet to damage the appearance as a product, so that the upper limit is preferably about 5.

(55) Moreover, the control of the atmosphere in the cooling is necessary to be performed between 700 C. and 500 C. The reason of setting to not lower than 500 C. is due to the fact that decarburization is necessary to be caused in the surface layer for promoting P segregation, while the reason of setting to not higher than 700 C. is due to the fact that when the atmosphere at a temperature exceeding 700 C. is an oxidizing atmosphere, oxides violently grown in the surface layer of the steel sheet block the grain growth and the iron loss properties is deteriorated. Preferably, it is a range of 650 C.-550 C.

(56) And also, the time for the cooling is necessary to be a range of 1-300 seconds. When it is less than 1 second, decarburization is not promoted, while when it exceeds 300 seconds, the productivity lowers. Moreover, it is preferable to conduct the cooling for not less than 5 seconds for sufficiently promoting the decarburization in the surface layer of the steel sheet to ensure the crystal grain growth properties. Preferably, it is a range of 5-100 seconds.

(57) In the steel sheet cooled under the above conditions after the finish annealing, a ratio (P.sub.120/Fe.sub.700) of a peak to peak height P.sub.120 of P near to an electronic energy of 120 eV to a peak to peak height Fe.sub.700 of Fe near to an electronic energy of 700 eV in an Auger differential spectrum obtained by analyzing the steel sheet surface with an Auger electron spectroscopy is not less than 0.02. Moreover, the ratio (P.sub.120/Fe.sub.700) is preferable to be not less than 0.03 for further enhancing the crystal grain growth in the stress relief annealing.

(58) The steel sheet after the finish annealing produced as above has a high strength because P is added and the crystal grains are fine. Therefore, the steel sheet after the finish annealing can be used as a rotor core material as it is. Here, the steel sheet is preferable to have a yield stress (upper yield point) of not less than 400 MPa, more preferably not less than 420 MPa in order to resist against centrifugal force due to high speed rotation of the motor. The yield stress is a value measured by subjecting a test specimen defined by JIS Z2201 (preferably JIS No. 5 test specimen) to a tensile test defined by JIS Z2241.

(59) Further, the steel sheet after the finish annealing is high in the strength and has a property that the crystal grain growth properties in the stress relief annealing are excellent because the added P is segregated into the surface layer of the steel sheet in the finish annealing. Thus, the steel sheet after the finish annealing has a low iron loss when the stress relief annealing is performed, and can be used as a stator core material.

(60) The method of producing a motor core (rotor core and stator core) from the steel sheet after the finish annealing will be described below.

(61) The non-oriented electrical steel sheet after the finish annealing is punched out to provide iron core materials for the rotor core and stator core simultaneously. A rotor core having a high strength can be obtained by laminating and assembling the punched-out rotor core materials, while a stator core having a low iron loss can be obtained by laminating and assembling the punched-out stator core materials and then subjecting to a stress relief annealing.

(62) The stress relief annealing may be conducted under conditions of a usual manner and is not particularly limited. For example, it is preferable to be conducted at a temperature of 700-900 C. for 0.1-10 hours in an inert gas atmosphere. The rotor core may be subjected to a stress relief annealing, but it is preferably not subjected thereto in order to maintain the high strength.

(63) Then, in order to decrease the iron loss in the steel sheet after the finish annealing, it is preferable to apply an insulation coating to the surface of the steel sheet. In this regard, it is preferable to apply an organic coating containing a resin for ensuring a good punchability, while a semi-organic or an inorganic coating is preferable to be applied when the weldability is considered important.

EXAMPLE

(64) A molten steel having a chemical composition shown in Table 1 is prepared through blowing in a convertor and degassing treatment and shaped into a slab by a continuous casting method. Then, the slab is reheated at 1140 C. for 1 hour and hot rolled to form a hot rolled sheet having a sheet thickness of 2.0 mm, which is subjected to a hot band annealing at 1000 C. for 30 seconds, pickled and cold rolled to obtain a cold rolled sheet having a sheet thickness of 0.25 mm. Next, the cold rolled sheet is subjected to a finish annealing by holding at a temperature of 700-900 C. for 10 seconds in a non-oxidizing atmosphere with an oxygen potential P.sub.H2O/P.sub.H2 of 0.0005 as an atmosphere of a soaking zone and then cooling from 700 C. to 500 C. for 5-250 seconds in a non-oxidizing atmosphere having an oxygen potential P.sub.H2O/P.sub.H2 of 0.0003 or in an oxidizing atmosphere having an oxygen potential P.sub.H2O/P.sub.H2 of 0.003-3.0 to thereby obtain a cold rolled annealed sheet. Moreover, the details of the above production conditions are shown in Table 2. No. 22 in Table 2 is an example of conducting a self-annealing at 650 C. for 1 hour instead of the hot band annealing, and No. 23 is an example of conducting no annealing after the hot rolling.

(65) With respect to the cold rolled annealed sheet, magnetic properties (iron loss W.sub.10/400 and magnetic flux density B.sub.50) are measured by a 25 cm Epstein test method, while a yield stress is measured by a tensile test using a JIS No. 5 specimen.

(66) Furthermore, the cold rolled annealed sheet is subjected to a stress relief annealing in a N.sub.2 atmosphere at 750 C. for 2 hours, and then W.sub.10/400 and magnetic flux density B.sub.50 are measured by a 25 cm Epstein test method.

(67) TABLE-US-00001 TABLE 1 Steel Chemical composition (mass %) No. C Si Mn P S N Al Sn Sb Remarks 1 0.0025 3.02 0.046 0.095 0.0018 0.0023 0.0008 tr. tr. Inventive steel 2 0.0029 3.00 0.046 0.022 0.0016 0.0022 0.0008 tr. tr. Comparative steel 3 0.0030 2.98 0.052 0.031 0.0021 0.0021 0.0006 tr. tr. Inventive steel 4 0.0030 2.98 0.051 0.142 0.0021 0.0019 0.0008 tr. tr. Inventive steel 5 0.0033 3.00 0.048 0.172 0.0020 0.0018 0.0007 tr. tr. Comparative steel 6 0.0027 1.56 0.046 0.094 0.0022 0.0020 0.0009 tr. tr. Inventive steel 7 0.0027 2.05 0.056 0.095 0.0022 0.0023 0.0010 tr. tr. Inventive steel 8 0.0026 4.03 0.052 0.090 0.0020 0.0016 0.0010 tr. tr. Inventive steel 9 0.0028 3.03 0.562 0.093 0.0019 0.0016 0.0009 tr. tr. Inventive steel 10 0.0033 3.00 1.975 0.094 0.0022 0.0018 0.0009 tr. tr. Inventive steel 11 0.0030 2.97 0.058 0.091 0.0055 0.0019 0.0008 tr. tr. Comparative steel 12 0.0029 2.99 0.055 0.096 0.0025 0.0059 0.0010 tr. tr. Comparative steel 13 0.0031 2.99 0.050 0.100 0.0017 0.0020 0.0042 tr. tr. Inventive steel 14 0.0030 3.05 0.046 0.099 0.0023 0.0024 0.0054 tr. tr. Comparative steel 15 0.0030 2.97 0.058 0.098 0.0016 0.0024 0.0007 0.009 tr. Inventive steel 16 0.0027 3.05 0.051 0.096 0.0017 0.0022 0.0008 0.183 tr. Inventive steel 17 0.0030 2.99 0.046 0.097 0.0021 0.0018 0.0008 tr. 0.012 Inventive steel 18 0.0031 2.97 0.057 0.092 0.0017 0.0018 0.0009 tr. 0.190 Inventive steel 19 0.0031 3.02 0.055 0.093 0.0017 0.0020 0.0009 0.036 0.031 Inventive steel 20 0.0027 2.98 0.045 0.095 0.0023 0.0020 0.0010 tr. tr. Inventive steel 21 0.0032 2.98 0.046 0.096 0.0020 0.0022 0.0009 tr. tr. Inventive steel 22 0.0033 3.03 0.052 0.092 0.0021 0.0020 0.0008 tr. tr. Inventive steel 23 0.0027 2.97 0.048 0.091 0.0020 0.0021 0.0009 tr. tr. Inventive steel 24 0.0029 3.00 0.051 0.092 0.0022 0.0017 0.0007 tr. tr. Inventive steel 25 0.0026 3.02 0.053 0.031 0.0019 0.0017 0.0009 tr. tr. Inventive steel 26 0.0033 3.02 0.051 0.059 0.0020 0.0018 0.0008 tr. tr. Inventive steel 27 0.0027 2.99 0.055 0.032 0.0021 0.0023 0.0008 tr. tr. Inventive steel 28 0.0028 3.03 0.056 0.056 0.0018 0.0023 0.0006 tr. tr. Inventive steel 29 0.0026 2.97 0.045 0.031 0.0019 0.0023 0.0006 tr. tr. Inventive steel 30 0.0025 2.96 0.049 0.058 0.0019 0.0017 0.0007 tr. tr. Inventive steel 31 0.0032 2.98 0.056 0.096 0.0016 0.0018 0.0006 tr. tr. Inventive steel 32 0.0035 3.05 0.056 0.091 0.0017 0.0021 0.0009 tr. tr. Inventive steel 33 0.0026 2.98 0.046 0.097 0.0020 0.0018 0.0007 tr. tr. Inventive steel 34 0.0030 2.97 0.054 0.096 0.0021 0.0022 0.0008 tr. tr. Inventive steel

(68) TABLE-US-00002 TABLE 2 Magnetic properties Magnetic properties before after stress relief Finish annealing condition P.sub.120/Fe.sub.700 stress relief annealing annealing Cooling P.sub.H20/P.sub.H2 in surface Mag- Mag- Annealing Temperature time during layer of netic netic after in soaking from cooling steel sheet Iron loss flux Yield Iron loss flux Steel hot zone 700 C. to from 700 C. after finish W.sub.10/400 density stress W.sub.10/400 density No. rolling* ( C.) 500 C. (s) to 500 C. annealing (W/kg) B.sub.50(T) (MPa) (W/kg) B.sub.50(T) Remarks 1 A 800 10 0.01 0.13 19.8 1.692 433 12.0 1.691 Inventive Example 2 A 800 10 0.01 0.01 20.0 1.692 434 19.0 1.692 Comparative Example 3 A 800 10 0.01 0.03 19.9 1.691 431 17.6 1.690 Inventive Example 4 A 800 10 0.01 0.22 19.8 1.691 429 11.8 1.691 Inventive Example 5 A 800 10 0.01 Cannot be measured with no rolling due to embrittlement Comparative Example 6 A 800 10 0.01 0.13 29.6 1.733 371 21.0 1.732 Inventive Example 7 A 800 10 0.01 0.13 25.2 1.720 390 16.9 1.719 Inventive Example 8 A 800 10 0.01 0.14 17.6 1.663 478 9.8 1.662 Inventive Example 9 A 800 10 0.01 0.12 19.2 1.683 448 11.3 1.682 Inventive Example 10 A 800 10 0.01 0.13 17.2 1.640 460 10.0 1.641 Inventive Example 11 A 800 10 0.01 0.12 23.8 1.653 475 19.1 1.653 Comparative Example 12 A 800 10 0.01 0.12 23.6 1.647 462 19.9 1.648 Comparative Example 13 A 800 10 0.01 0.13 21.2 1.691 431 15.6 1.690 Inventive Example 14 A 800 10 0.01 0.14 23.1 1.693 430 19.6 1.690 Comparative Example 15 A 800 10 0.01 0.13 19.9 1.701 428 12.0 1.700 Inventive Example 16 A 800 10 0.01 0.12 20.0 1.711 431 11.9 1.710 Inventive Example 17 A 800 10 0.01 0.12 19.9 1.700 430 11.8 1.700 Inventive Example 18 A 800 10 0.01 0.13 19.8 1.710 427 11.9 1.710 Inventive Example 19 A 800 10 0.01 0.12 19.3 1.706 413 11.5 1.705 Inventive Example 20 A 700 10 0.01 0.12 22.3 1.690 463 11.9 1.693 Inventive Example 21 A 900 10 0.01 0.13 17.4 1.691 377 11.9 1.691 Inventive Example 22 B 800 10 0.01 0.13 19.9 1.677 430 12.0 1.677 Inventive Example 23 not 800 10 0.01 0.12 19.8 1.665 432 11.9 1.665 Inventive Example conducted 24 A 800 10 0.0003 0.01 19.9 1.691 432 19.0 1.690 Comparative Example 25 A 800 10 0.003 0.02 19.9 1.692 427 18.5 1.690 Inventive Example 26 A 800 10 0.003 0.08 19.9 1.692 430 16.3 1.691 Inventive Example 27 A 800 10 0.30 0.04 19.9 1.693 433 17.2 1.690 Inventive Example 28 A 800 10 0.30 0.09 19.9 1.691 429 13.1 1.691 Inventive Example 29 A 800 10 3.00 0.06 19.9 1.692 431 14.2 1.693 Inventive Example 30 A 800 10 3.00 0.15 19.9 1.692 428 11.8 1.693 Inventive Example 31 A 800 5 0.01 0.11 19.8 1.693 433 12.4 1.691 Inventive Example 32 A 800 60 0.01 0.15 19.9 1.691 433 11.9 1.692 Inventive Example 33 A 800 100 0.01 0.17 19.9 1.691 434 11.9 1.692 Inventive Example 34 A 800 250 0.01 0.21 19.9 1.691 428 11.8 1.690 Inventive Example *Annealing after hot rolling: A: hot band annealing, B: self-annealing

(69) The results of the magnetic flux density and the tensile test are shown in Table 2 together with the production conditions.

(70) As seen from Table 1 and Table 2, a non-oriented electrical steel sheet having a high strength after the finish annealing and a low iron loss after the stress relief annealing can be stably produced by subjecting a steel sheet having a chemical composition adapted to aspects of the invention to the finish annealing under the conditions adapted to aspects of the invention, so that rotor core materials and stator core materials can be obtained simultaneously from the same raw material steel sheet.