BURNER SYSTEM FOR A STEAM CRACKING FURNACE
20210048193 ยท 2021-02-18
Inventors
Cpc classification
F23C2202/10
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F23C9/08
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F23D14/64
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
Y02E20/34
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
International classification
F23D14/64
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F23C9/08
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
Abstract
Burner system for a radiant section of a steam cracking furnace configured to provide heat to the radiant section, the burner system including a fuel inlet and an oxidant inlet, and further comprising an ejector block arranged located within the radiant section and to receive a propellant and a propelled fluid and arranged to premix said propellant with said propelled fluid.
Claims
1. Burner system for a radiant section of a steam cracking furnace configured to provide heat to the radiant section, the burner system including a fuel inlet and an oxidant inlet, and further comprising an ejector block located within the radiant section and arranged to receive a propellant and a propelled fluid and arranged to premix said propellant with said propelled fluid, wherein the burner system comprises a single outlet into the radiant section for an outlet flow of the at least partly unconverted mixture of fuel and/or oxidant combined with a propellant/propelled fluid pre-mixture.
2. Burner system according to claim 1, wherein the ejector block comprises an ejector of the constant area mixing type, the ejector block including an ejector constant area mixing section in which propellant and propelled fluid are mixed, wherein the ejector constant area mixing section is at a distance from an entrance of the ejector block.
3. Burner system according to claim 2, wherein a ratio of a length of the ejector constant area mixing section over a throat inner diameter of the ejector constant area mixing section is in a range of about 5 to about 8.
4. Burner system according to any of the preceding claims, wherein the ejector block comprises a suction chamber arranged to suck in the propelled fluid, such as flue gas, wherein the suction chamber is arranged to increase a momentum of said propelled fluid.
5. Burner system according to any of the preceding claims, further comprising a first nozzle (71, 91) configured to inject the propellant into the ejector block, wherein the nozzle extends into the ejector block along a longitudinal axis of the ejector block, preferably a longitudinal central axis of the ejector block.
6. Burner system according to at least claims 2 and 5, wherein the first nozzle is placed at an entrance of the ejector constant-area mixing section.
7. Burner system according to at least claims 2 and 5, wherein a ratio of a throat inner diameter of the ejector constant area mixing section over a diameter of the first nozzle is higher than 5, preferably higher than 7, more preferably around 10.
8. Burner system according to any of the preceding claims, wherein the ejector block comprises an ejector diffuser configured to transfer dynamic pressure into static pressure.
9. Burner system according to claim 8, wherein a ratio of an ejector diffuser exit area over an ejector diffuser inlet area is in a range of about 1.5 to about 2.5.
10. Burner system according to any of the preceding claims, wherein the propellant is one of fuel gas, compressed air, and compressed combustion oxygen.
11. Burner system according to any of the preceding claims, further comprising an outlet bend piece, wherein a ratio of a bend inner radius over a diameter of the outlet bend piece is preferably higher than approximately 0.75 or more preferably higher than approximately 1.
12. Burner system according to any of the preceding claims, further comprising a straight extension piece, wherein a ratio of a length of the extension piece over a diameter of the extension piece is preferably higher than approximately 1, more preferably higher than approximately 1.5.
13. Burner system according to claim 12, wherein an inside of a straight extension piece exit area is tapered into a sharp edge.
14. Furnace firebox of a steam cracking furnace comprising at least one burner system according to any of the preceding claims.
15. Use of the burner system according to any of the preceding claims 1-13 in a radiant section of a steam reformer.
16. Method of operating a burner system according to any of the preceding claims 1-13, comprising the steps of injecting a primary fuel and an oxidant into the burner system until reaching an excess oxidant level below approximately 30 vol %; decreasing a supply of primary fuel once the excess oxidant level below approximately 30 vol % has been reached; injecting a propellant into the ejector block.
Description
[0023] The present invention will be further elucidated with reference to figures of exemplary embodiments. Corresponding elements are designated with corresponding reference signs.
[0024]
[0025]
[0026]
[0027]
[0028]
[0029]
[0030]
[0031]
[0032] An example of a combustion process using this first embodiment of the burner system 51 can be described as follows. An oxidant 6, such as combustion air, can enter the burner system 51 through the opening between a muffler 53 and a windbox 52. The flow rate of the oxidant can be controlled by the oxidant control damper 54 located on the windbox. The oxidant travels through the oxidant channel on the inside of the windbox through the furnace floor 41 and the inside of the burner block 55 towards the primary combustion zone 58 and the main combustion zone 74 at the outlet of the burner block.
[0033] Primary fuel gas 56 passes through the firebox side wall 42 and through the primary fuel burner nozzles 57 located in a recess in the burner block, where it enters the burner block and is ignited upon mixing with combustion air to create flue gas in the primary combustion zone 58. If only the primary burner nozzles 57 are in operation, the majority of the flue gas 75 leaves the firebox 40 through the firebox exit 43. Flue gas recirculation is very limited in this case.
[0034] A propellant, such as secondary fuel gas 70, can pass through the firebox floor 41 and through the secondary fuel burner nozzle 71 located in the entrance of the constant-area mixing section of the ejector block 61, where it enters the ejector block 65. This secondary fuel gas 70 is ignited upon mixing with recirculated flue gas 50, coming from the ejector suction chamber 60, in the pre-combustion zone 72 to create an oxygen-depleted flue gas/fuel mixture 73. The recirculated flue gas 50 is propelled into the ejector block through the ejector suction chamber 60 by the high velocity jet created at the exit of the secondary fuel gas nozzle by fuel gas, called the propellant in this context, leaving the nozzle. This recirculated flue gas 50 still contains oxygen. The remaining oxygen in this flue gas is fully converted, mostly to carbon monoxide (CO), in the pre-combustion zone 72, consuming part of the secondary fuel gas. The oxygen-depleted flue gas/fuel mixture 73 leaving the pre-combustion zone 72 is transferred through the ejector constant-area mixing section 61, the ejector diffuser 62, ejector outlet bend 63 and ejector straight extension piece 64, before leaving the ejector block 65. After leaving the extension piece, the oxygen-depleted flue gas/fuel mixture 73 is mixed with the remaining oxidant, for example combustion air 6, in the main combustion zone 74. Here all the secondary fuel is converted to flue gas 75. The produced flue gas is partly recirculated back to the suction chamber of the ejector block by the suction effect of the propellant injected into the ejector block 65, and the nett flue gas 75 is transferred to the firebox exit 43.
[0035] The primary fuel 56 and the secondary fuel 70 can both be in operation at the same time, but preferably only at start-up of the burning system, until the excess air in the firebox 40 reduces to a level of less than 30 vol %. After having reached said level, the supply of primary fuel 56 can be decreased, while the secondary fuel 70, being in operation simultaneously, may be increased. If the secondary fuel 70 were injected into the ejector block 65 at start-up of the firebox, when the oxygen content or excess oxidant level in the firebox 40 would still be above 30 vol %, without supply of primary fuel 56, then predominantly CO.sub.2 would be produced in the pre-combustion zone 72 as a result of exothermic reactions. This production of CO.sub.2 could cause the temperature to rise in the ejector block 65, which might damage the ejector block. In order to prevent this potentially dangerous rise in temperature in the ejector block 65, a primary fuel 56 is first injected into the burner system 51, in particular in a way bypassing the ejector block 65, until reaching an excess oxidant level, in particular an oxygen level, below approximately 30 vol % in the firebox 40. A supply of primary fuel 56 can then be decreased and secondary fuel 70 can be injected into the ejector block 65. As a result of the reduced oxygen content in the firebox, endothermic reactions in the pre-combustion zone 72 can predominantly produce CO, which can keep the temperature in the ejector block 65 under control or may even cause the temperature in the ejector block to decrease. As the combustion temperature in the main combustion zone 74 is considerably lower than in the primary combustion zone 58, less NOx is produced in the main combustion zone 74 than in the primary combustion zone 58. The smaller the percentage primary fuel, the lower the NOx emission.
[0036]
[0037]
[0038] In a combustion process using this third embodiment of the burning system, combustion air 6 can enter the ejector burner 51 through the opening between the muffler 53 and the windbox 52, just as in the previously described embodiments. The flow rate of the air is controlled by the oxidant control damper 54 located on the windbox. The air travels through the air channel on the inside of the windbox through the furnace floor 41 and the inside of the burner block 55 towards the primary combustion zone 58 and the main combustion zone 73 at the outlet of the burner block.
[0039] Primary fuel gas 56 passes through the firebox side wall 42 and through the primary fuel burner nozzles 57 located in a recess in the burner block, where it enters the burner block 55 and is ignited upon mixing with combustion air to create flue gas in the primary combustion zone 58. If only the primary burner nozzles 57 are in operation, the majority of the flue gas 75 leaves the firebox 40 through the firebox exit 43. Flue gas recirculation is very limited in this case.
[0040] In contrast to previous embodiments, compressed air can pass through the firebox floor 41 and through the first nozzle 91 located in the entrance of the constant-area mixing section 61 of the ejector block 65, where it enters the ejector block 65. The recirculated flue gas 50 is propelled into the ejector block 65 through the ejector suction chamber 60 by the high velocity jet created at the exit of the compressed air nozzle by the compressed air, called the propellant in this context, leaving the nozzle. The flue gas/air mixture 76 is transferred through the ejector constant-area mixing section 61, the ejector diffuser 62, the ejector outlet bend 63 towards the ejector straight extension piece 64, where it is mixed with secondary fuel in the pre-combustion zone 72.
[0041] Secondary fuel gas 70 can pass through a wall of the windbox 52, the wall of the ejector outlet bend 63 and through the secondary fuel burner nozzle 71 preferably located in the entrance of the ejector straight extension piece 64, where the secondary fuel gas 70 enters the ejector block 65. This secondary fuel gas 70 is ignited upon mixing with recirculated flue gas/air mixture 76, coming from the ejector outlet bend 63, in the pre-combustion zone 72 to create an oxygen-depleted flue gas/fuel mixture 73.
[0042] The oxygen in this flue gas/air mixture 73 is fully converted, mostly to carbon monoxide (CO), in the pre-combustion zone 72, consuming part of the secondary fuel gas. The oxygen-depleted flue gas/fuel mixture 73 leaving the pre-combustion zone 72 is transferred through the ejector straight extension piece, before leaving the ejector block 65. After leaving the extension piece, the oxygen-depleted flue gas/fuel mixture 73 is mixed with the remaining combustion air 6 in the main combustion zone 74. Here all the secondary fuel is converted to flue gas 75. The flue gas produced is partly recirculated back to the suction chamber of the ejector block and the nett flue gas 75 is transferred to the firebox exit 43.
[0043] The primary fuel 56 and the secondary fuel 70 can both be in operation at the same time, but need not. Secondary fuel gas 70 and compressed air 90 are preferably in operation simultaneously.
[0044]
[0045] A compressed oxidant 90, such as compressed combustion oxygen or compressed air, can pass through the firebox floor 41 and through the compressed oxidant nozzle 91 located in the entrance of the constant-area mixing section of the ejector block 61, where it enters the ejector block 65. The recirculated flue gas 50 is propelled into the ejector block through the ejector suction chamber 60 by the high velocity jet created at the exit of the compressed oxidant nozzle by the compressed oxidant, called the propellant in this context, leaving the nozzle. The flue gas/oxidant mixture 76 is transferred through the ejector constant-area mixing section 61, the ejector diffuser 62, the ejector outlet bend 63 towards the ejector straight extension piece 64, where it is mixed with the main fuel 97, which passes through the firebox floor 41, the wall of the ejector outlet bend 63 and through the main fuel burner nozzle 98 located in or past the entrance of the ejector straight extension piece 64, where the main fuel 97 enters the ejector block 65. This main fuel gas 97 is ignited upon mixing with the mixture 76 of compressed oxidant/recirculated flue gas, coming from the ejector outlet bend 63, near the outlet of the burner system and near the main combustion zone 74 to create flue gas 75. So, there is no pre-combustion zone 72 in the ejector block 65. The produced flue gas is partly recirculated back to the suction chamber of the ejector block and the nett flue gas 75 is transferred to the firebox exit 43. Main fuel gas 97 and compressed oxidant 90 are in operation simultaneously. Due to the high amount of premixing of flue gas and oxidant, the percentage of oxygen in the flue gas/oxidant mixture is reduced to a level that is similar or even lower to that in normal combustion air. This reduces the combustion temperature in the main combustion zone considerably. This, in combination with very low nitrogen levels in the recirculating flue gas inside the firebox, reduces the NOx to extremely low values. However, the main purpose of this case is to prevent external flue gas recirculation. The intention is to recirculate enough flue gas to bring the flame temperature to conditions that are normally achieved during combustion with air. Since there is practically no nitrogen present, the NOx emission will be very low in this case any way. An additional advantage of this embodiment is that the flue gas generated is relatively rich in CO2, making it a suitable waste stream for carbon capturing, thus reducing the emission of greenhouse gases into the atmosphere.
[0046]
[0047] Primary fuel gas 56 can pass through the firebox side wall 42 and through the primary fuel burner nozzles 57 located in a recess in the burner block 55, where it enters the burner block 55 and is ignited upon mixing with combustion oxidant to create flue gas in the primary combustion zone 58. If only the primary burner nozzles 57 are in operation, the majority of the flue gas 75 leaves the firebox 40 through the firebox exit 43. Flue gas recirculation is very limited in this case.
[0048] Compressed oxidant 90 can pass through the firebox floor 41 and through the compressed oxidant nozzle 91 located in the entrance of the constant-area mixing section 61 of the ejector block 65, where it enters the ejector block 65. The recirculated flue gas 50 is propelled into the ejector block 65 through the ejector suction chamber 60 by the high velocity jet created at the exit of the compressed oxidant nozzle 91 by the compressed oxidant 90, called the propellant in this context, leaving the nozzle. The flue gas/oxidant mixture 76 is transferred through the ejector constant-area mixing section 61, the ejector diffuser 62, the ejector outlet bend 63 towards the ejector straight extension piece 64, where it can be mixed with secondary fuel in the pre-combustion zone 72. Secondary fuel gas 70 can pass through the wall of the windbox 52, the wall of the ejector outlet bend 63 and through the secondary fuel burner nozzle 71 located in the entrance of the ejector straight extension piece 64, where it enters the ejector block 65. This secondary fuel gas 70 is ignited upon mixing with the recirculated flue gas/oxidant mixture 76 coming from the ejector outlet bend 63, in the pre-combustion zone 72 to create an oxygen-depleted flue gas/fuel mixture 73. The oxygen in this flue gas/oxidant mixture is substantially fully converted, mostly to carbon monoxide (CO), in the pre-combustion zone 72, consuming part of the secondary fuel gas. The oxygen-depleted flue gas/fuel mixture 73 leaving the pre-combustion zone 72 is transferred through the ejector straight extension piece, before leaving the ejector block 65. After leaving the extension piece, the oxygen-depleted flue gas/fuel mixture 73 is mixed with the remaining mixture 7 of combustion oxidant and externally recirculated flue gas in the main combustion zone 74. Here all the secondary fuel is converted to flue gas 75. The produced flue gas produced is partly recirculated back to the suction chamber 60 of the ejector block and the nett flue gas 75 is transferred to the firebox exit 43.
[0049] The primary fuel 56 and the secondary fuel 70 can both be in operation at the same time, but preferably only at start-up of the burning system, before reaching an excess oxidant level below around approximately 30 vol %, more preferably below 30 vol %, in the firebox 40. After having reached said condition, the supply of primary fuel 56 can be decreased, while the secondary fuel 70 and compressed oxidant 90, being in operation simultaneously, may be increased. As the combustion temperature in the main combustion zone is considerably lower than in the primary combustion zone, less NOx is produced in this zone than in the primary combustion zone. The smaller the percentage primary fuel, the lower the NOx emission.
[0050]
[0051]
[0052] For the purpose of clarity and a concise description, features are described herein as part of the same or separate embodiments, however, it will be appreciated that the scope of the invention may include embodiments having combinations of all or some of the features described. As an example, even if it is not shown, the burner systems of both the embodiments of
[0053] It may be understood that the embodiments shown have the same or similar components, apart from where they are described as being different.
[0054] In the claims, any reference signs placed between parentheses shall not be construed as limiting the claim. The word comprising does not exclude the presence of other features or steps than those listed in a claim. Furthermore, the words a and an shall not be construed as limited to only one, but instead are used to mean at least one, and do not exclude a plurality. The mere fact that certain measures are recited in mutually different claims does not indicate that a combination of these measures cannot be used to an advantage. Many variants will be apparent to the person skilled in the art. All variants are understood to be comprised within the scope of the invention defined in the following claims.
LIST OF REFERENCE SIGNS
[0055] 6. Combustion oxidant [0056] 7. Mixture of combustion oxidant and externally recirculated flue gas [0057] 40. Firebox [0058] 41. Firebox floor [0059] 42. Firebox sidewall [0060] 43. Firebox exit [0061] 44. Firebox terrace floor [0062] 50. Internally recirculating flue gas [0063] 51. Burner system [0064] 52. Windbox [0065] 53. Muffler [0066] 54. Oxidant control damper [0067] 55. Burner block [0068] 56. Primary fuel [0069] 57. Primary fuel burner nozzle [0070] 58. Primary combustion zone [0071] 60. Ejector suction chamber [0072] 61. Ejector constant area mixing section [0073] 62. Ejector diffuser [0074] 63. Ejector outlet bend piece [0075] 64. Ejector straight extension piece [0076] 65. Ejector block [0077] 66. Ejector inlet bend piece [0078] 70. Secondary fuel [0079] 71. Secondary fuel burner nozzle [0080] 72. Precombustion zone [0081] 73. Oxygen depleted flue gas/fuel mixture [0082] 74. Main combustion zone [0083] 75. Flue gas [0084] 76. Oxidant/flue gas mixture [0085] 80. Staged fuel [0086] 81. Staged fuel nozzle [0087] 90. Compressed oxidant [0088] 91. Compressed oxidant nozzle [0089] 97. Main fuel [0090] 98. Main fuel burner nozzle