Gas supply, conditioning, and discharge systems and methods
10923743 ยท 2021-02-16
Assignee
Inventors
Cpc classification
H01M8/04074
ELECTRICITY
F28D2021/0043
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F28D21/0015
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
H01M8/04776
ELECTRICITY
H01M8/04014
ELECTRICITY
Y02E60/50
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
International classification
H01M8/04014
ELECTRICITY
H01M8/04119
ELECTRICITY
Abstract
A gas supply and discharge system may have a fuel cell arrangement having at least one electrode, a gas-gas heat exchanger for exchanging heat between a first gas to be supplied to the electrode and a second gas discharged or dischargeable from the second electrode, and a humidifier for transferring humidity between the first gas and the second gas. The first gas to be supplied to the electrode can be introduced into the gas-gas heat exchanger before the supply of the first gas to the electrode, and such that the second gas can be introduced into the gas-gas heat exchanger from the electrode in order to transfer heat between the first gas and the second gas in the gas-gas heat exchanger. The first gas and the second gas can be introduced into the humidifier from the gas-gas heat exchanger in order to transfer humidity between the first gas and the second gas in the humidifier. The first gas can be introduced into the fuel cell arrangement from the humidifier and can be supplied to the electrode.
Claims
1. A method for leading a first gas onto at least one electrode of a fuel cell arrangement and for leading a second gas away from the at least one electrode, comprising the steps; leading the first gas which is to be fed to the electrode into a gas-gas heat exchanger and leading the second gas which is led away from the electrode into the gas-gas heat exchanger, for transferring heat between the first gas and the second gas in the gas-gas heat exchanger, wherein an outlet for the second gas in the gas-gas heat exchanger is in direct fluid connection with an inlet of a humidifier for the second gas; coming from the gas-gas heat exchanger, leading the first and second gas which are temperature adjusted in the gas-gas heat exchanger into a humidifier for transferring humidity between the first gas and the second gas in the humidifier; and coming from the humidifier, leading the first gas which is humidified or dehumidified in the humidifier onto the electrode.
2. The method according to claim 1, wherein the first gas and/or the second gas are led into a gas-liquid heat exchanger which transfers heat between the first gas and/or the second gas and a liquid coolant.
3. The method according to claim 2, wherein the first gas and/or the second gas is/are led into the gas-liquid heat exchanger before the leading into the gas-gas heat exchanger and coming from the gas-liquid heat exchanger is/are led into the gas-gas heat exchanger.
4. The method according to claim 2, wherein the first gas and/or the second gas after the heat transfer in the gas-gas heat exchanger and coming from the gas-gas heat exchanger is/are led into the gas-liquid heat exchanger and coming from the gas-liquid heat exchanger is/are led into the humidifier.
5. The method according to claim 2, wherein the first gas is compressed before leading the first gas onto the electrode or before leading the first gas into the gas-gas heat exchanger.
6. The method according to claim 5, wherein the first gas is compressed after the humidity transfer between the first gas and the second gas is effected in the humidifier.
7. The method according to claim 1, wherein the second gas after the humidity transfer between the first gas and the second gas in the humidifier and coming from the humidifier is fed to an expander or a thermoelectric generator and the thermal energy of the second gas and/or the kinetic energy of the second gas is converted at least partly into kinetic energy of the expander or into electrical energy.
8. The method according to claim 7, wherein the energy which is transferred from the second gas onto the expander or onto the thermoelectric generator is transferred at least partly from the expander or from the thermoelectric generator onto the compressor and/or onto the further compressor, for compressing the first gas.
9. The method according to claim 1, further comprising one or more of the following steps: at least partly diverting the first gas into an outlet of the humidifier before leading the first gas into the gas-gas heat exchanger; at least partly diverting the first gas into the fuel cell arrangement before leading the first gas into the gas-gas heat exchanger; at least partly diverting the first gas into an outlet of the gas-gas heat exchanger before leading the first gas into the gas-gas heat exchanger; at least partly diverting the first gas into the fuel cell arrangement after letting the first gas out of the gas-gas heat exchanger and before leading the first gas into the humidifier; at least partly diverting the first gas into a conduit which exits from the fuel cell arrangement, after letting the first gas out of the humidifier and before leading the first gas into the gas-gas heat exchanger; at least partly diverting the second gas into an outlet of the humidifier before leading the second gas into the gas-gas heat exchanger; at least partly diverting the second gas into an outlet of the gas-gas heat exchanger before leading the second gas into the gas-gas heat exchanger; at least partly diverting the second gas into an outlet of the humidifier after letting the second gas out of the gas-gas heat exchanger and before leading the second gas into the humidifier.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) Embodiment examples of the invention are represented in the figures and are explained in more detail by way of the subsequent description. There are shown in:
(2)
(3)
(4)
(5)
(6)
(7)
(8)
DETAILED DESCRIPTION OF THE INVENTION
(9)
(10) The electrode 2a is arranged at least partly within the reaction volume 2b or reaches up to the reaction volume 2b. A first gas 5 is fed to the electrode 2a via the reaction volume 2b. The arrows which represent the first gas 5 stand for conduits, in which the first gas 5 is led, wherein the arrow direction specifies the flow direction of the first gas 5 in the respective conduit. A second gas 6 is led away from the electrode 2a likewise via the reaction volume 2b. The arrows which represent the second gas 6 again stand for conduits, in which the second gas 6 is led, wherein the arrow direction specifies the flow direction of the second gas 6 in the respective conduit.
(11) Here, the electrode 2a is a cathode of the fuel cell arrangement 2. The fuel cell arrangement 2 yet comprises a multitude of further cathodes and anodes which are not represented here and hereinafter for the sake of simplicity. E.g. the first gas 5 can be simultaneously fed to a multitude of cathodes via the reaction volume 2b. The second gas 6 can likewise be simultaneously led away from a multitude of cathodes via the reaction volume 2b.
(12) In the represented embodiment example, the fuel cell arrangement 2 is a hydrogen fuel cell arrangement. The first gas 5 comprises air and/or oxygen. The oxygen which is contained in the first gas 5 absorb electrons at the cathode 2a and in the reaction volume 2b reacts with protons which diffuse from an adjacent anode through a membrane into the reaction volume 2b, into water. The second gas 6 comprises water vapour which arises with this reaction.
(13) The gas-gas heat exchanger 3 comprises a first volume 7 for leading the first gas 5 and a second volume 8 for leading the second gas 6. An inlet 7a of the first volume 7 is connected e.g. to a gas reservoir (not shown) via a conduit for leading the first gas 5, so that coming from the gas reservoir, the first gas 5 can be led or is led into the first volume 7. An inlet 8a of the second volume 8 is connected to an outlet 2c of the fuel cell arrangement 2, in particular to an outlet 2c of the reaction volume 2b via a conduit for leading the second gas 6, so that coming from the fuel cell arrangement 2 or coming from the reaction volume 2b, the second gas 6 can be led or is led directly into the second volume 8 of the gas-gas heat exchanger 3.
(14) The first volume 7 and the second volume 8 of the gas-gas heat exchanger 3 are physically separated from one another, so that no through-mixing of the first gas 5 and the second gas 6 is effected in the gas-gas heat exchanger 3. Heat is transferred between the first gas 5 which is led in the first volume 7 and the second gas 6 which is led in the second volume 8, via a thermal contact 9 of the gas-gas heat exchanger 3. Thus an at least partial balancing of the temperatures of the gases 5 and 6 is effected in the gas-gas heat exchanger 3. Here, on leading the first gas 5 into the first volume 7, the temperature of the first gas 5 is higher than the temperature of the second gas 6 on leading the second gas 6 into the second volume 8, so that heat is transferred from the first gas 5 onto the second gas 6 in the gas-gas heat exchanger 3. E.g. the first gas 5 has a temperature between 200 C. and 250 C. on leading the first gas 5 into the first volume 7, and the second gas 6 has a temperature e.g. between 60 C. and 80 C. on leading the second gas 6 into the volume 8. The thermal contact 9 between the first volume 7 and the second volume 8 is realised merely by way of solid bodies, e.g. in the form of plates and/or lamellae. A possibly existing further cooling system for cooling the fuel cell arrangement 2 can be designed smaller due to the at least partial cooling of the first gas 5 which is to be fed to the electrode 2a, with the help of the second gas which is led away from the electrode 2a, in the gas-gas heat exchanger 3.
(15) The humidifier 4 comprises a third volume 10 for leading the first gas 5 and a fourth volume 11 for leading the second gas 6. An outlet 7b of the first volume 7 of the gas-gas heat exchanger 3 is connected to an inlet 10a of the third volume 10 of the humidifier 4 via a conduit. Coming from the first volume 7 of the gas-gas heat exchanger 3, the first gas 5 is led directly into the third volume 10 of the humidifier 4 via this conduit, after the heat transfer between the first gas 5 and the second gas 6 in the gas-gas heat exchanger 3. An outlet 8b of the second volume 8 of the gas-gas heat exchanger 3 is connected via a conduit to an inlet 11a of the fourth volume 11 of the humidifier 4. Coming from the second volume 8 of the gas-gas heat exchanger 3, the second gas 6 is led directly into the fourth volume 11 of the humidifier 4 via this conduit, after the heat transfer between the first gas 5 and the second gas 6 in the gas-gas heat exchanger 3. Here and hereinafter, conduits which are represented in the figures as conduits crossing one another are not to be in fluid connection with one another at the crossing point.
(16) The humidifier 4 further comprises a water exchange membrane 12 which is arranged between the third volume 10 and the fourth volume 12 and which separates the third volume 10 from the fourth volume 12. Alternatively or additionally, the humidifier 4 can be designed as a tube humidifier or comprise capillaries for transferring humidity between the third volume 10 and the fourth volume 12. A humidity transfer between the gases which are led in the volumes 10 and 11 of the humidifier 4 can be effected via the water exchange membrane 12. In the present embodiment example, the humidity degree of the second gas 6 which is led away from the electrode 2a, on leading the second gas 6 into the fourth volume 11 of the humidifier 4 is higher than the humidity degree of the first gas 5 which is to be fed to the electrode 2a, on leading the first gas 5 into the third volume 10 of the humidifier 4. For this reason, humidity is transferred here in the humidifier 4 from the second gas 6 in the fourth volume 11 onto the first gas 5 in the third volume 10. The water exchange membrane 12 is not permeable to gases, so that no through-mixing of the first gas 5 with the second gas 6 takes place in the humidifier 4.
(17) It has been found that the humidity transfer between the gases 5 and 6 in the humidifier 4 is particularly efficient on account of the at least partial balancing of the temperatures of the gases 5 and 6 in the gas-gas heat exchanger 3 before leading the gases 5 and 6 into the humidifier 4. The water exchange membrane 12 can therefore be designed smaller for transferring the same quantity of water via this. Furthermore, the service life of the water exchange membrane 12 of the humidifier 4 can be extended by the prior cooling of the warmer of the two gases 5 and 6 on account of the heating, usually of the gas 5, in the gas-gas heat exchanger 3, said heating resulting from the compressing. Furthermore, an undesired condensation of the humidity which is contained in the colder of the gases 5 and 6, in the humidifier, can be prevented or reduced by way of the heating of the colder of the gases 5 and 6, i.e. at least the gas 6 in the gas-gas heat exchanger 3 before leading the gases 5 and 6 into the humidifier 4. This also contributes to a more efficient humidity transfer via the water exchange membrane 12 of the humidifier 4.
(18) The second gas 6 is led away out of the humidifier 4 via an outlet 11b of the volume 11 of the humidifier 4. An outlet 10b of the volume 10 of the humidifier 4 is connected via a conduit to an inlet 2d of the fuel cell arrangement 2, in particular to an inlet 2d of the reaction volume 2b. Coming from the humidifier 4, the first gas 5 is led via this conduit into the fuel cell arrangement 2 and via the reaction volume 2b is fed to the electrode 2a, after the humidity transfer between the first gas 5 and the second gas 6 in the humidifier 4. The humidification of the first gas 5 which is to be introduced into the fuel cell arrangement 2, in the humidifier 4, amongst other things serves for avoiding a drying-out of the proton exchange membrane of the fuel cell arrangement 2 which is not shown here and via which the proton exchange between the non-represented anode and the cathode 2a of the fuel cell arrangement 2 is effected.
(19)
(20) The system 100 according to
(21) The system 100 according to
(22) The system 100 according to
(23) The system 100 according to
(24) The system 100 according to
(25) The system 100 according to
(26) The system 100 according to
(27) The system 100 according to
(28) The system 100 according to
(29)
(30) The gas-liquid heat exchanger 13 comprises a volume 18 for leading the first gas. The first gas 5 e.g. coming from the previously described gas reservoir is led into the volume 18 via an inlet 13a. An outlet 13b of the volume 18 is connected via a conduit to an inlet 7a of the first volume 7 of the gas-gas heat exchanger 3. A coolant 14 can be circulated in the volume 18 or through the volume 18, so that a heat transfer between the first gas 5 which is led in the volume 18 and the cooling medium 14 is effected in the volume 18.
(31) With modified embodiments, the gas-liquid heat exchanger 13 can additionally also be designed for transferring heat between the second gas 6 and the coolant 14. For this, the gas-liquid heat exchanger 13 can comprise e.g. a further volume for leading the second gas 6, in which or through which volume the coolant 14 can be circulated. The second gas e.g. coming from the fuel cell arrangement 2 can be led into this further volume of the gas-liquid heat exchanger 13 and coming from this further volume of the gas-liquid heat exchanger 13 can be led into the second volume 8 of the gas-gas heat exchanger 3, as described in reference to the system 100.
(32) The design of the fuel cell arrangement 2, of the gas-gas heat exchanger 3 and of the humidifier 4 of the system 200 and their fluidic connection amongst one another correspond to those of the system 100 according to
(33)
(34) The design of the fuel cell arrangement 2, of the gas-gas heat exchanger 3 and of the humidifier 4 of the system 300 and their fluid connections amongst one another otherwise correspond to those of the system 100 according to
(35)
(36) An inlet 15a of the compressor can be connected e.g. to the previously described gas reservoir. An outlet 15b of the compressor is connected via a conduit to the inlet 7a of the first volume of the gas-gas heat exchanger 3. Coming from the compressor 15, the first gas 5 is led into the first volume 7 of the gas-gas heat exchanger 3. The outlet 11b of the fourth volume 11 of the humidifier 4 is connected via a conduit to an inlet 16a of the expander 16. The second gas 6 is led onto the expander 16 after the humidity transfer between the first gas 5 and the second gas 6 in the humidifier 4.
(37) The compressor 15 can be designed as a rotation compressor with a compressor wheel. The expander can comprise a turbine which is driven by the second gas 6. The energy of the second gas 6 which is absorbed by the expander 16 can be transferred at least partly onto the compressor 15 via a coupling 17 between the expander 16 and the compressor 15 and is thus used for compressing the first gas 5 in the compressor. The coupling 17 can be a mechanical coupling, e.g. in the form of a belt connection between a turbine of the expander 16 and a compressor wheel of the compressor 15. The coupling 17 can also comprise a generator for converting kinetic energy of the expander 16 into electric energy. This electrical energy can then for example drive an electric motor which for its part drives a compressor wheel of the compressor 15.
(38) Here and hereinafter, a thermoelectric generator can also be provided alternatively or additionally to the expander, said generator being configured to at least partly convert the thermal energy of the second gas 6 into electric energy.
(39) The thermoelectric generator can then be connected to the compressor 15 via an electric lead, so that the electric energy can be transferred from the thermoelectric generator onto the compressor 15. The compressing of the first gas 5 by the compressor 15 can then be carried out at least partly with the help of the electrical energy which is transferred from the thermoelectric generator onto the compressor 15.
(40) The design of the fuel cell arrangement 2, of the gas-gas heat exchanger 3 and of the humidifier 4 of the system 400 and their fluid connections amongst one another otherwise correspond to those of the system 100 according to
(41)
(42) The design of the fuel cell arrangement 2, of the gas-gas heat exchanger 3 and of the humidifier 4 of the system 500 and their fluid connections amongst one another otherwise correspond to those of the system 100 according to
(43)
(44) The design of the fuel cell arrangement 2, of the gas-gas heat exchanger 3 and of the humidifier 4 of the system 600 and their fluidic connections amongst one another otherwise correspond to those of the system 100 according to