Separator, and fuel cell stack comprising the same

Abstract

The present invention relates to a separator and a fuel cell stack comprising the same, and according to one aspect of the present invention, there is provided a separator comprising a plurality of channels including a bottom forming a flow space for a reaction gas to flow and a pair of sidewalls connected to the bottom, and a plurality of ribs provided so as to connect the sidewalls of two adjacent channels, wherein the sidewall of the channel is provided with a water storage part which is recessed inward and has a first inclined surface and a second inclined surface connected by a first angle.

Claims

1. A separator comprising a plurality of channels configured to receive a flow of reaction gas, the separator comprising: a plurality of bottoms; a plurality of pairs of sidewalls, each of the plurality of pairs of sidewalls being connected to a respective one of the plurality of bottoms, and the plurality of channels being defined by the plurality of bottoms and the plurality of pairs of sidewalls; and a plurality of ribs, each of the plurality of ribs connecting two adjacent sidewalls of the plurality of pairs of sidewalls, wherein each of the plurality of pairs of sidewalls comprises a water storage part that comprises a recess defined by a first inclined surface and a second inclined surface that are connected to each other and form a first angle.

2. The separator according to claim 1, wherein the water storage part has a wedge shape.

3. The separator according to claim 1, wherein the first inclined surface and the second inclined surface form a V shape.

4. The separator according to claim 3, wherein the first inclined surface and the second inclined surface are flat surfaces.

5. The separator according to claim 1, wherein both sidewalls of one of the plurality of pairs of sidewalls comprise a plurality of water storage parts that are spaced apart from each other by a predetermined interval, and the plurality of water storage parts are arranged to be symmetrical with respect to a direction of the flow of the reaction gas.

6. The separator according to claim 1, wherein both sidewalls of one of the plurality of pairs of sidewalls comprise a plurality of water storage parts that are spaced apart from each other by a predetermined interval, and the plurality of water storage parts are arranged to be asymmetric with respect to a direction of the flow of the reaction gas.

7. The separator according to claim 1, wherein the first angle is an acute angle.

8. The separator according to claim 7, wherein a sum of half of the first angle and a contact angle of the first inclined surface or the second inclined surface is 90 or less.

9. The separator according to claim 1, wherein a first inclined angle of the first inclined surface and a second inclined angle of the second inclined surface with respect to a corresponding sidewall of the plurality of pairs of sidewalls are equal.

10. The separator according to claim 1, wherein a first inclined angle of the first inclined surface and a second inclined angle of the second inclined surface with respect to a corresponding sidewall of the plurality of pairs of sidewalls are different from each other.

11. A fuel cell stack comprising: a membrane-electrode assembly; a gas diffusion layer on the membrane-electrode assembly; and a separator at least partially contacting the gas diffusion layer, wherein the separator comprises a plurality of channels for a flow of reaction gas and comprises: a plurality of bottoms; a plurality of pair of sidewalls, each of the plurality of pairs of sidewalls being connected to a respective one of the plurality of bottoms, and the plurality of channels being defined by the plurality of bottoms and the plurality of pairs of sidewalls; and a plurality of ribs, each of the plurality of ribs connecting two adjacent sidewalls of the plurality of pair of sidewalls and contacting the gas diffusion layer, and wherein each of the plurality of pairs of sidewalls comprises a water storage part that is configured to store for storing water and comprises a recess defined by a first inclined surface and a second inclined surface that are connected to each other and form a first angle.

12. The fuel cell stack according to claim 11, wherein the water storage part has a wedge shape.

13. The fuel cell stack according to claim 11, wherein the first inclined surface and the second inclined surface form a V shape.

14. The fuel cell stack according to claim 13, wherein the first inclined surface and the second inclined surface are flat surfaces.

15. The fuel cell stack according to claim 11, wherein movement of the water in the water storage part toward the gas diffusion layer and the membrane-electrode assembly is along the first and second inclined surfaces.

16. The fuel cell stack according to claim 11, wherein the first angle is an acute angle.

17. The fuel cell stack according to claim 16, wherein a sum of half of the first angle and a contact angle of the first inclined surface or a second included surface is 90 or less.

18. The fuel cell stack according to claim 11, wherein the gas diffusion layer extends between the membrane-electrode assembly and the separator.

Description

BRIEF DESCRIPTION OF DRAWINGS

(1) FIG. 1 is a schematic diagram of a fuel cell stack related to one embodiment of the present invention.

(2) FIG. 2 is a plan view of a separator related to one embodiment of the present invention.

(3) FIGS. 3 and 4 are perspective views of the water storage part shown in FIG. 2.

(4) FIG. 5 is a conceptual diagram for explaining one operating state of a fuel cell stack.

(5) FIG. 6 is a plan view for explaining a reaction gas flow path and a cooling water flow path.

(6) FIG. 7 is schematic diagrams illustrating various forms of channels.

(7) FIGS. 8 and 9 are schematic diagrams for explaining arrangement of a water storage part.

(8) FIGS. 10 and 11 are conceptual diagrams for explaining the principle of rising water in a water storage part.

MODE FOR INVENTION

(9) Hereinafter, a separator according to one embodiment of the present invention, a method for manufacturing the same, and a fuel cell stack comprising the same will be described in detail with reference to the accompanying drawings.

(10) In addition, the same or similar reference numerals are given to the same or corresponding components regardless of reference numerals, of which redundant explanations will be omitted, and for convenience of explanation, the size and shape of each constituent member as shown may be exaggerated or reduced.

(11) FIG. 1 is a schematic diagram of a fuel cell stack (1) related to one embodiment of the present invention, and

(12) FIG. 2 is a plan view of a separator (100) related to one embodiment of the present invention.

(13) FIGS. 3 and 4 are perspective views of the water storage part (200) shown in FIG. 2, and FIG. 5 is a conceptual diagram for explaining one operating state of a fuel cell stack (1).

(14) FIG. 6 is a plan view for explaining a reaction gas flow path (A) and a cooling water flow path (B),

(15) FIG. 7 is schematic diagrams showing various forms of channels (110-1, 110-2, 110-3), and

(16) FIGS. 8 and 9 are schematic diagrams for explaining arrangement of a water storage part.

(17) FIGS. 10 and 11 are conceptual diagrams for explaining the principle of raising water (generated water) in a water storage part (200).

(18) The fuel cell stack (1) related to one embodiment of the present invention comprises a membrane-electrode assembly (10) and a gas diffusion layer (20) provided on one side of the membrane-electrode assembly (10), and a separator (100). The separator (100) is disposed to contact the gas diffusion layer (20) in at least a part of the region.

(19) Referring to FIGS. 1 and 2, the separator (100) related to one embodiment of the present invention comprises a plurality of channels (110) including a bottom (111) forming a flow space for a reaction gas to flow and a pair of sidewalls (112) connected to the bottom (111), and a plurality of ribs (120) provided so as to connect the sidewalls (112) of two adjacent channels (110). The channel (110) has a structure opened to the rib (120) side. That is, the channel (110) has a structure opened to the gas diffusion layer (20) side.

(20) The channel (110) may be provided such that the bottom (111) and each sidewall (112) are orthogonal. Also, the bottom (111) of the channel (110) and the rib (120) may be provided in parallel. In addition, each of the ribs (120) is provided so as to be in contact with the gas diffusion layer (20).

(21) The sidewall (112) of the channel (110) is provided with a water storage part (200) which is recessed inward and has a first inclined surface (210) and a second inclined surface (220) connected at a first angle (). The water storage part (200) provides a predetermined space, where the water (generated water) generated in the channel (110) is stored therein. That is, the generated water generated in the channel (110) is stored in the water storage part (200) so as not to interfere with the flow of the reaction gas.

(22) Also, referring to FIGS. 3 and 5, the generated water staying in the water storage part (200) maintains a water pillar (W) (column) shape, which contacts the gas diffusion layer (20) through the first inclined surface (210) and the second inclined surface (220) and is diffused into the gas diffusion layer (20) and the membrane-electrode assembly (10), which can be used for humidification of the polymer electrolyte membrane. That is, the water in the water storage part (200) is moved toward the gas diffusion layer (20) and the membrane-electrode assembly (10) along the first and second inclined surfaces (210, 220). An unexplained reference numeral 11 denotes a catalyst layer.

(23) Furthermore, the water storage part (200) may have a wedge shape. In addition, the first inclined surface (210) and the second inclined surface (220) may have a V shape. In addition, the first inclined surface (210) and the second inclined surface (220) may be comprised of flat surfaces. Besides, a region (boundary region) to which the first inclined surface (210) and the second inclined surface (220) are connected is provided to have a V shape, where the boundary region preferably does not comprise a curved portion. However, the region where each inclined surface (210, 220) and the sidewall (112) of the channel (110) are connected may also comprise a curved portion.

(24) Referring to FIG. 3, the first angle () may be an acute angle. Specifically, the first angle () represents, for example, an angle formed by two wall surfaces (a first inclined surface and a second inclined surface) of a gap generated in one sidewall (112) of the linear flow path. It is also preferable that the sum of the half angle of the first angle () and a contact angle () of any one inclined surface is 90 or less. In this case, it is possible to obtain a high effect.

(25) On the other hand, referring to FIGS. 3 and 4, the contact angle () represents an angle that the inclined surface (210 or 220) contacts the water surface. The contact angle () may be adjusted according to the separator (100) material and hydrophilicity (or hydrophobicity) of the gas diffusion layer (20), and design elements such as lengths a, b, c and d, and/or a ratio of a/d. For example, the width (a) and the height (d) of the rib (120), the width (b) of the rib excluding the water storage part (200), and the interval (c) between adjacent water storage parts (200), a and d are factors affecting determination of the first angle (). In addition, the water content in the water storage part (200) may be determined by the first angle () and the height (d). Also, the length b may be adjusted according to the material of the separator and the manufacturing process and the operating conditions of the fuel cell stack (1).

(26) FIG. 5 illustrates that the water is diffused from the water pillar (W) gathered in the water storage part (200) and used for humidifying the polymer electrolyte membrane (PEM) through the gas diffusion layer (20) and the catalyst layer (11).

(27) Referring to FIG. 6, A represents a flow path and flow direction of the reaction gas, and B represents a flow path and flow direction of the cooling water. That is, it can be provided so that the reaction gas flows through the first surface (the surface on which the channel is opened) of the separator (100), and the cooling water flows through the second surface in the opposite direction of the first surface. In addition, by forming the water storage part (200), the cooling water flow path can generate a long residence time and a complicated fluid flow, so that the cooling effect can be improved. Particularly, the flow (A) of the reaction gas and the flow (B) of the cooling water can be formed in the same direction or in the opposite direction, which can be variously determined according to the arrangement structure of the channels (110) in the separator and the inlet/outlet positions and directions of the reaction gas and the cooling water.

(28) Also, referring to FIG. 7, the water storage part (200) is applicable to various types of channels (110-1, 110-2, 110-3).

(29) On the other hand, referring to FIG. 3, the inclined angle of the first inclined surface (210) and the inclined angle of the second inclined surface (220) with respect to the sidewall (112) of the channel (110) may have the same size. For example, the first inclined surface (210) and the second inclined surface (220) may have symmetrical shapes such as two hypotenuses of an isosceles triangle.

(30) Alternatively, referring to FIG. 8, the inclined angle of the first inclined surface (230) and the inclined angle of the second inclined surface (240) with respect to the sidewall of the channel (110) may have sizes different from each other. That is, the water storage part (210-1) of another embodiment may have an asymmetric shape of the first inclined surface (230) and the second inclined surface (240). In addition, a plurality of water storage parts (210-1) may be each provided on both sidewalls of the channel at predetermined intervals so as to be asymmetric along the flow direction of the reaction gas.

(31) Alternatively, referring to FIG. 9, a plurality of water storage parts (210-1) may be each provided on both sidewalls of the channel at predetermined intervals so as to be symmetrical along the flow direction of the reaction gas.

(32) FIG. 10 shows how the liquid surface in contact with the solid wall surface in the form of a tube behaves according to curvature of the solid wall surface and the liquid contact surface.

(33) Referring to FIG. 10, the A side wall surface has a rounded curved surface, while the B side edge has a wedge shape bent into a V shape. At this time, the liquid surface in contact with the B side wall surface of the liquid surfaces in contact with the solid wall surfaces is raised higher than the A side by a spontaneous capillary phenomenon. If the contact angle at the B side edge decreases, the water remains in the V-shaped space in the form of a water pillar (W) having a negative surface energy, and according to this principle, the inside of the channel (110) serves as a water storage space. If the water storage part (200) has the same curved surface shape as the A side, this phenomenon does not occur.

(34) FIG. 11 is for a more analytical explanation of the explanation via FIG. 10, and when the contact angles (01, 02) of the V-shaped wedge with two wall surfaces are different from each other, they have a relationship of Equation 1 below.
+.sub.1+.sub.2<[Equation 1]

(35) At this time, when =1=2, it is derived by Equation 2 below.

(36) $\begin{array}{cc}\frac{}{2}<\frac{}{2}-& \left[\mathrm{Equation}2\right]\end{array}$

(37) Therefore, the spontaneous capillary phenomenon occurs more in the V-shaped space than in the round curved surface.

(38) The preferred embodiments of the present invention as described above are disclosed for illustrative purposes, which can be modified, changed and added within thought and scope of the present invention by those skilled in the art and it will be considered that such modification, change and addition fall within the following claims.

INDUSTRIAL APPLICABILITY

(39) According to the present invention, it is possible to efficiently distribute the gas flow and the liquid (for example, generated water) flow in the separator, and in particular, to prevent the generated water (condensed water) from flooding in the channel of the separator.