Bonding wire for semiconductor device

Abstract

The present invention provides a bonding wire for a semiconductor device suitable for cutting-edge high-density LSIs and on-vehicle LSIs by improving the formation rate of CuAl IMC in ball bonds. A bonding wire for a semiconductor device contains Pt of 0.1 mass % to 1.3 mass %, at least one dopant selected from a first dopant group consisting of In, Ga, and Ge, for a total of 0.05 mass % to 1.25 mass %, and a balance being made up of Cu and incidental impurities.

Claims

1. A bonding wire for a semiconductor device containing Pt of 0.1 mass % to 1.3 mass %, at least one dopant selected from a first dopant group consisting of In, Ga, and Ge, for a total of 0.05 mass % to 1.25 mass %, and a balance being made up of Cu and incidental impurities, wherein breaking elongation in a tensile test of the bonding wire is 8% to 15.5%, and the bonding wire has no coating layer.

2. The bonding wire for a semiconductor device according to claim 1, further containing at least one dopant selected from a second dopant group of B, P, Ca, La, and Ce, for a total of 0.0005 mass % to 0.0100 mass %.

3. The bonding wire for a semiconductor device according to claim 1, wherein a crystal orientation in a longitudinal section of the bonding wire is such that an abundance ratio of a crystal orientation <100> having an angular difference of 15 degrees or less from a longitudinal direction of the bonding wire is from 50% to 100% in area percentage.

4. The bonding wire for a semiconductor device according to claim 1, further containing at least one element selected from a third dopant group of Au, Pd, and Ni, for a total of 0.0005 mass % to 1.0 mass %.

Description

DESCRIPTION OF EMBODIMENTS

(1) A bonding wire of the present embodiment contains Pt of 0.1 mass % to 1.3 mass %, both inclusive, at least one dopant selected from a first dopant group consisting of In, Ga, and Ge, for a total of 0.05 mass % to 1.25 mass %, both inclusive, and a balance being made up of Cu and incidental impurities. The bonding wire of the present embodiment can improve the formation rate of CuAl IMC in ball bonds.

(2) (About Formation Rate of CuAl IMC in Ball Bond)

(3) The formation rate of CuAl IMC in a ball bond is defined herein as the ratio of the formation area of CuAl IMC to the bonding area of the ball bond. A method for measuring the bonding area of a ball bond and the formation area of CuAl IMC will be described. First, to prepare a specimen, ball bonds resulting from ball bonding of a bonding wire are heat-treated at 175 C. for 3 hours. This is done to facilitate the growth of CuAl IMC and thereby ease subsequent observation. Next, only the balls are dissolved by acid treatment, thereby exposing the Al electrodes and CuAl IMC. Subsequently, the Al electrodes are observed with the balls removed and the bonding area of each ball bond and the formation area of CuAl IMC are measured. The bonding area of the ball bond is the area of a region in which the Al electrode is deformed as a result of ball bonding. The formation area of CuAl IMC is the area of that region on the Al electrode in which CuAl IMC exists after the removal of the ball.

(4) (Improvement Effect on Formation Rate of CuAl IMC)

(5) The present inventors found that if 0.1 mass % to 1.3 mass % of Pt was contained and a total of 0.05 mass % to 1.25 mass % of at least one dopant selected from a first dopant group was contained, the formation rate of CuAl IMC in small-ball bonding was improved. Specifically, the use of the bonding wire according to the present embodiment was able to improve the formation rate of CuAl IMC in small-ball bonding to 80% or above. Also, no Al splashing or Si chip damage occurred. The hardness of the balls formed by the use of the bonding wire according to the present embodiment was measured with a Vickers hardness tester and microcompression tester and increases in the hardness were confirmed in the indications of both testers. A crystal structure of a ball section was revealed by etching and observed using an optical microscope and consequently, and it was confirmed that the crystal grains of the balls had been refined. It is considered that with the bonding wire of the present embodiment, by adding Pt compositely with at least one or more dopants selected from the first dopant group, a grain refinement effect was enhanced synergistically, increasing the hardness of the balls. Consequently, it is presumed that destruction of the Al oxide on the Al alloy electrodes was facilitated during ball bonding, improving the formation rate of CuAl IMC.

(6) When the concentration of Pt is 0.3 mass % to 1.0 mass %, and a total of 0.05 mass % to 1.25 mass %, of at least one dopant selected from the first dopant group is contained or when 0.1 mass % to 1.3 mass %, of Pt is contained and the concentration of at least one dopant selected from the first dopant group is 0.10 mass % to 0.75 mass %, the formation rate of CuAl IMC is improved and this is preferable.

(7) When the concentration of Pt is 0.3 mass % to 1.0 mass %, and the concentration of at least one dopant selected from the first dopant group is 0.10 mass % to 0.75 mass %, the formation rate of CuAl IMC is further improved and this is more preferable.

(8) Note that it was confirmed that when Pt was contained singly or when only at least one or more element selected from the first dopant group was contained, the formation rate of CuAl IMC was insufficient, posing a problem in practical use. When the crystal structure of the balls was observed, it was confirmed that the crystal grains of the balls were relatively coarse, meaning that the grain refinement effect was not achieved sufficiently. From this, it is considered that when Pt was added singly or when only the first dopant group was added, the grain refinement effect was not achieved sufficiently, making the improvement effect on ball hardness insufficient.

(9) Even when the bonding wire contained Pt and at least one dopant selected from the first dopant group, if the concentration of Pt was less than 0.1 mass % or if the concentration of at least one dopant selected from the first dopant group was less than 0.05 mass %, the formation rate of CuAl IMC was low. It is considered that this is because the concentrations of Pt and first dopant group were low, making the improvement effect on ball hardness insufficient.

(10) Also, when more than 1.3 mass % of Pt was contained or when a total of more than 1.25 mass % of at least one or more dopant selected from the first dopant group was contained, a good formation rate of CuAl IMC was not available. When states of plural ball bonds were observed under an optical microscope, many of the balls were found to be bonded by being displaced from the center of the wire. It is presumed that this is because the balls were displaced from the center of the wire in the stage of ball formation. It is presumed that the reason why this phenomenon occurred is that the high concentrations of Pt and at least one or more dopant selected from the first dopant group changed the resistance and the like on the wire surface, making arc discharges unstable.

(11) (Formation of Crimped Ball Shape into Perfect Circle and Effect of Inhibiting CuAl IMC Center-Unbonded During Ball Bonding)

(12) Preferably the bonding wire of the present embodiment further contains a total of 0.0005 mass % to 0.0100 mass % of at least one or more elements selected from a second dopant group of B, P, Ca, La, and Ce. This can improve roundness of a crimped ball shape in small-ball bonding and improve the formation rate of CuAl IMC right under a center portion of a ball and in its vicinity in a ball bond (hereinafter referred to as the formation rate of CuAl IMC right under the ball), where the roundness of a crimped ball shape is required for cutting-edge narrow-pitch bonding. Specifically, in small-ball bonding using a wire with a diameter of 20 m and balls approximately 1.4 times a wire diameter, the roundness of the crimped ball shape was improved and it was confirmed that the present embodiment is also applicable to narrow-pitch bonding with a pitch of 45 m or less. Also, the formation rate of CuAl IMC right under the ball was improved, confirming that the improvement effect on the formation rate of CuAl IMC was able to be further enhanced. The structure of a ball section was observed, and it was confirmed that the crystal grains had been refined more finely. It is considered that with the bonding wire of the present embodiment, excessive deformation of balls and variation within the same balls were inhibited because the grain refinement effect of Pt and the first dopant group was enhanced synergistically by the addition of the second dopant group.

(13) (Improvement Effect on Spring Performance)

(14) Furthermore, in the bonding wire of the present embodiment, preferably a crystal orientation in a longitudinal section of the bonding wire is such that an abundance ratio of a crystal orientation <100> having an angular difference of 15 degrees or less from a longitudinal direction of the bonding wire is from 50% to 100% in terms of area percentage. This also offers the effect of inhibiting a poor loop shape called a spring failure in using a bonding method called reverse bonding. The reverse bonding is a technique for reducing the thickness of chips by limiting loop height by ball-bonding electrodes for wedge bonding and wedge-bonding electrodes for ball bonding. The spring failure is a phenomenon in which when the bonding wire is cut right above the ball after ball bonding, a great impact is delivered to the bonding wire, deforming the bonding wire into the shape of a spring and thereby causing straightness of the loop to be lost. An excellent spring failure correction effect can be obtained using the effect of improving wire strength and the effect of reducing variation of strength in the longitudinal strength of the wire. It is considered that the improvement of wire strength is attributable to the effect of improving by adding Pt, the first dopant group, and the second dopant group while the reduction of variation in the longitudinal strength of the wire is attributable to the effect of improving by crystal orientation control. For similar reasons, the addition of Pt and dopants and crystal orientation control are effective in preventing a loop shape defect called a leaning failure in which a bonded bonding wire leans toward an adjacent bonding wire before sealing.

(15) (Improvement Effect on Wedge Bonding Strength)

(16) Furthermore, in the bonding wire of the present embodiment, preferably breaking elongation in a tensile test is 8% to 15.5%, and more preferably 11% to 14%. In connecting high-density LSIs, because wire diameter is small, area contributing to bonding of wedge bonds is small, making it difficult to obtain bonding strength equal to that of normal bonding. To deal with this problem, good bonding strength can be obtained in wedge bonds by the combined use of the effect of increasing the bonding area by controlling the breaking elongation and the effect of making the wire resistant to breakage in spite of increased bonding area by enhancing the strength of the wire through the addition of Pt and elements of the first dopant group. Specifically, using the bonding wire of the present embodiment with a diameter of 20 m, Ag-plated electrodes were wedge-bonded and the bonding strength was measured by a wire pull test, and as a result, it was confirmed that a good bonding strength of 4 gf or above was able to be obtained. Breaking elongation can be controlled by optimizing conditions of thermomechanical treatment and the like during manufacturing. It is considered that the bonding wire of the present embodiment has obtained excellent wedge bonding strength by combining the optimization of breaking elongation and the effect of making the wire resistant to breakage through the addition of Pt and elements of the first dopant group.

(17) (Damage Resistance Performance of Heat-Affected Zone (Neck Portion))

(18) Preferably, the bonding wire of the present embodiment further contains a total of 0.0005 mass % to 1.0 mass % of at least one or more elements selected from a third dopant group of Au, Pd, and Ni. In low loop connection used in connecting high-density LSIs, a wire portion right above the ball called a neck may get damaged by undergoing a large bending deformation. Also, as a characteristic of a neck portion, crystal grains become coarse under the influence of heat input during ball formation, creating a tendency for strength of the neck portion to degrade easily. Therefore, there has been demand for material design intended to inhibit strength degradation of the neck portion. The present inventors have found that by adding elements of the third dopant group in combination with Pt and elements of the first dopant group, it is possible to improve the strength of the neck portion and improve a damage prevention effect of the neck portion. Specifically, it was confirmed that damage to the neck portion was able to be reduced under loop formation conditions of 3 mm in loop length and 80 m in loop height.

(19) (Method for Producing Bonding Wire)

(20) A production method of a bonding wire for a semiconductor device of the present embodiment will be described.

(21) (Melting Method 1)

(22) First, using high-purity Cu with copper purity of 4N to 6N (99.99 to 99.9999 mass %), a copper alloy containing necessary concentrations of dopants is prepared by melting. An arc melting furnace, high-frequency melting furnace, or the like can be used for the melting. To prevent admixture of atmospheric gases such as O.sub.2 and H.sub.2, preferably the melting is done in a vacuum atmosphere or in an inert atmosphere of Ar, N.sub.2, or another gas. After the melting, the copper is cooled slowly in the furnace to prepare an ingot. Preferably, surfaces of the ingot produced by melting are washed with acid or alcohol, followed by drying.

(23) (Melting Method 2)

(24) Available alloying methods include a method of directly melting and alloying copper and high-purity additive components and a method of preparing a master alloy made up of copper and approximately 3 to 5 mass % of dopants in advance and melting and alloying copper and the master alloy. The technique which uses a master alloy is effective in making an element distribution uniform at a low concentration. With the additive components of the present embodiment, in adding Pt and elements of the first dopant group and third dopant group at a relatively high concentration of 0.5 mass % or above, a technique for directly adding high-purity additive components can be used. In adding Pt and elements of the first dopant group, second dopant group, and third dopant group stably at a low concentration, the technique which uses a master alloy is effective.

(25) (Description of Drawing Process and Heat Treatment)

(26) The copper alloy ingot thus produced is processed first into a large diameter by rolling and forging and then reduced in diameter by a drawing process until a final wire diameter is reached. A drawing step is carried out using a continuous wire drawing machine capable of being equipped with plural diamond-coated dies. Desirably a lubricant is used during continuous wire drawing to reduce worn-out of the dies and wire surface flaws. Because the drawing process tends to cause work hardening of the wire and increase worn-out of the dies, preferably intermediate heat treatment is carried out at an intermediate stage for the principal purpose of removing strain. Also, with the final wire diameter, final heat treatment is carried out to adjust breaking elongation by recrystallizing the bonding wire. Preferably, the intermediate heat treatment and final heat treatment are carried out while continuously running the wire. This method can reduce quality variations and provide high productivity compared to when, for example, a batch heating furnace is used. Note that desirably the heat treatment is carried out by running Ar gas or N.sub.2 gas to inhibit oxidation of the bonding wire surface during the heat treatment as much as possible. Desirably the wire feed rate during the intermediate heat treatment and final heat treatment is 20 to 200 m/min to control the crystal orientation and breaking elongation.

(27) (Method for Controlling Crystal Orientation)

(28) Furthermore, by controlling the wire feed rate and intermediate heat treatment temperature during wire drawing, the abundance ratio of the crystal orientation <100> having an angular difference of 15 degrees or less from the longitudinal direction of the bonding wire can be adjusted. Preferred conditions are as follows: the wire feed rate during wire drawing is 400 to 600 m/min, intermediate heat treatment is carried out once at a wire diameter of 110 to 300 m, the temperature of the intermediate heat treatment is 400 to 500 C., the temperature of the final heat treatment is 350 to 550 C., and the wire feed rate during the intermediate heat treatment and final heat treatment is 20 to 200 m/min. These conditions increase the abundance ratio of the crystal orientation <100> having an angular difference of 15 degrees or less from the longitudinal direction of the bonding wire to 50% or above.

(29) (Method for Controlling Breaking Elongation)

(30) Furthermore, if the wire feed rate during wire drawing is set to 470 to 770 m/min, an amount of strain on the bonding wire surface during the wire drawing process can be reduced and a recrystallized structure having equiaxial crystal grains effective in improving breaking elongation tends to be available, and consequently, the breaking elongation after the final heat treatment can be adjusted to 8 to 15%, and further to 11 to 14%.

(31) (Method for Analyzing Types and Concentrations of Dopants Contained in Bonding Wire)

(32) An ICP emission spectrophotometer or the like can be used for concentration analysis of elements contained in the bonding wire. If elements such as oxygen, carbon, and/or sulfur are adsorbed to the surface of the bonding wire, before conducting analysis, concentration measurements may be taken after shaving a region of 1 to 2 nm off the surface of the bonding wire by sputtering or the like. Other effective methods include a method which uses acid wash.

(33) (Method for Measuring Crystal Orientation)

(34) Micro area X-ray diffraction (XRD) or electron backscattered diffraction (EBSD) can be used for measurement of the crystal orientation in a cross-sectional area of the bonding wire. Dedicated software (OIM analysis or the like produced by TSL Solutions) is suitable for analysis of EBSD measurement data. As a method for exposing a section of the bonding wire, mechanical polishing, an ion etching process, or the like can be used. The crystal orientation in the section of the bonding wire can be determined using an EBSD method. The abundance ratio of the crystal orientation <100> with an angular difference of 15 degrees or less from the longitudinal direction of the bonding wire can be found by calculating the ratio of the area occupied by the region having the crystal orientation <100> to the area of the measurement region of crystal orientations determined by EBSD or the like. The measurement region is a section which contains the wire axis and is parallel to the wire axis, measuring 100 m or less in the longitudinal direction of the wire and extending the entire width of the wire (wire diameter).

(35) (Method for Measuring Breaking Elongation)

(36) A value obtained by a tensile test of the bonding wire was used as the breaking elongation.

EXAMPLES

(37) (Manufacturing Samples)

(38) A method for manufacturing samples will be described. The Cu used as a raw material had a purity of 99.99 mass % or above, with the balance being incidental impurities. The Pt and the first to third dopant groups had a purity of 99 mass % or above, with the balance being incidental impurities. To obtain the desired wire compositions, Pt, which was a dopant, as well as alloying elements of the first dopant group, second dopant group, and third dopant group were alloyed as appropriate. When the desired concentrations of Pt and the elements of the first dopant group and third dopant group were 0.5 mass % or above, separate elements were melted and alloyed. When the desired concentrations of Pt, the first dopant group, second dopant group, and third dopant group were less than 0.5 mass %, alloys were prepared using a master alloy prepared by adding dopants in desired concentrations to copper.

(39) The copper alloy was melted in an Ar atmosphere using a high frequency melting furnace. The ingot produced by melting had a columnar shape with a diameter of a few mm. To remove an oxide film from the surface of the resulting ingot, an acid wash process was performed using sulfuric acid, hydrochloric acid, or the like. Subsequently, the ingot was subjected to a drawing process using the dies to produce a wire with an intermediate wire diameter in a range of 0.3 to 1.4 mm. The wire feed rate during wire drawing was 10 to 770 m/min. A commercially available lubricant was used. In so doing, the reduction rate of area of the dies was 12 to 24%. Next, intermediate heat treatment was carried out once at a wire diameter of 110 to 300 m. The temperature of the intermediate heat treatment was 200 to 600 C. After the drawing process, final heat treatment was carried out to obtain desired final breaking elongation. The intermediate heat treatment and final heat treatment were carried out at a temperature of 350 to 550 C., while continuously running the wire at a feed rate of 20 to 200 m/min. During the heat treatment, N.sub.2 or Ar gas was run at a flow rate of 1 to 2 L/min to prevent oxidation. The configurations of the manufactured samples are shown in Tables 1-1, 1-2, 1-3, and 3.

(40) (Evaluation Method)

(41) The concentrations of the dopants contained in the wire were analyzed using an ICP spectrophotometer.

(42) The abundance ratio of the crystal orientation <100> with an angular difference of 15 degrees or less from the longitudinal direction of the bonding wire was found by calculating the ratio of the area occupied by the region having the crystal orientation <100> to the area of the measurement region of crystal orientations determined by EBSD. The measurement region is a section which contains the wire axis and is parallel to the wire axis, measuring 100 m or less in the longitudinal direction of the wire and extending a distance equal to the entire width of the wire (wire diameter).

(43) (Evaluation of Formation Rate of CuAl IMC in Small-Ball Bonding)

(44) After bonding of the bonding wire, heat treatment was carried out at 175 C. for 3 hours and the balls were removed by acid treatment, and the resulting samples were used in evaluating the formation rate of CuAl IMC in small-ball bonding. A general-purpose bonding machine and capillary were used. The electrodes to which the bonding wire was bonded were prepared by forming a film of Al-1.0 at % Si-0.5 at % Cu alloy 0.8 m in thickness on a Si substrate. The ball size was in a range of 27.5 to 28.5 m, which was approximately 1.4 times the wire diameter (20 m). The balls were formed by blowing a nitrogen-hydrogen gas mixture with a hydrogen content of 4 to 5 vol %. The gas flow rate was 0.45 to 0.50 L/min. Note that any region in which CuAl IMC was formed was determined based on a difference in contrast from the electrode material. CuAl IMC, which is lower in reflectivity than the electrode material, appears dark in images taken under an optical microscope. Using this principle, the images taken under the optical microscope were binarized using image processing software and the area of CuAl IMC was calculated by extracting only relatively dark regions. Elemental analysis was conducted on every region using EDS (Energy dispersive spectroscope) provided on SEM (Scanning electron microscope) and it was confirmed in advance that there was no error in any of the regions. As the value of the formation rate of CuAl IMC, the average value of measured values of ball bonds at 100 locations selected at random was used. In the above evaluation, when the formation rate of CuAl IMC was less than 80%, 0 points were given by judging that there was a problem in practical use; when the formation rate was 80% inclusive to 90% exclusive, 1 point was given by judging that there was no problem in practical use; when the formation rate was 90% inclusive to 95% exclusive, 2 points were given by judging that the result was excellent; and when the formation rate was 95% inclusive to 100% exclusive, 3 points were given by judging that the result was particularly excellent. The evaluation results were entered in the CuAl IMC formation rate fields of Tables 2-1, 2-2, and 4. Only 0 points were rejected and 1 point and above were accepted.

(45) (Evaluation of Roundness of Crimped Shape in Small-Ball Bonding)

(46) Regarding evaluation of the crimped shapes of ball bonds in small-ball bonding, the ball bonds resulting from bonding were observed from directly above and determinations were made based on the roundness of the ball bonds. The bonding wire was bonded to an electrode manufactured by forming a 1.0-m-thick film from an Al-0.5 at % Cu alloy on a Si substrate. The ball size was in a range of 27.5 to 28.5 m, which was approximately 1.4 times the wire diameter (20 m). The balls were formed by blowing a nitrogen-hydrogen gas mixture with a hydrogen content of 4 to 5 vol %. The gas flow rate was 0.45 to 0.50 L/min. Using an optical microscope, crimped ball shapes were observed at 150 locations selected at random. When the ball bond had an elliptical shape deviating greatly from a perfect circle or had an anisotropic deformation, the collapsed shape was judged to be defective. In the above evaluation, when 3 or more defects occurred, 0 points were given by judging that there was a problem in practical use; when 1 or 2 defects occurred, 1 point was given by judging that there was no problem; and when good roundness was obtained in all the ball bonds, 2 points were given by judging that the result was particularly excellent. These points were entered in the Roundness of crimped ball shape in small-ball bonding fields of Tables 2-1, 2-2, and 4. Only 0 points were rejected and 1 point and above were accepted.

(47) (Evaluation of Formation Rate of CuAl IMC Right Under Balls in Small-Ball Bonding)

(48) After bonding of the bonding wire, heat treatment was carried out at 175 C. for 3 hours and the balls were removed by acid treatment, and the resulting samples were used in evaluating the formation rate of CuAl IMC right under the balls in small-ball bonding. CuAl IMC forming regions were determined using a technique which involves binarizing the images taken under the optical microscope, by means of image processing software and extracting only relatively dark regions. The occurrence rate of center-unbonded was defined as the area ratio of CuAl IMC in a circular region with a diameter of 15 m near the center of the ball bond. As the value of the formation rate of CuAl IMC right under the balls, the average value of measured values of ball bonds at 100 locations selected at random was used. When the formation rate of CuAl IMC right under the balls was less than 70%, 0 points were given by judging that there was a problem in practical use; when the formation rate was 70% inclusive to 95% exclusive, 1 point was given by judging that there was no problem; when the formation rate was 95% or above, 2 points were given by judging that the result was particularly excellent. These points were entered in the CuAl IMC formation rate right under balls fields of Tables 2-1, 2-2, and 4. Only 0 points were rejected and 1 point and above were accepted.

(49) (Evaluation of Spring and Leaning)

(50) To evaluate spring failures, 500 samples resulting from bonding were observed under an optical microscope. When there were 3 or more spring failures, i.e., spring-shaped bends on loops, 0 points were given by judging that there was a problem in practical use; when there were 1 or 2 spring failures, 1 point was given by judging that there was no problem; and when there was no spring failure, 2 points were given by judging that the result was particularly excellent. These points were entered in the Spring performance fields of Tables 2-1, 2-2, and 4. To evaluate leaning failures, using 500 samples resulting from bonding, deviation (amount of leaning) of each loop from the normal to the bonding surface of the ball bond was measured under an optical microscope. When the average value of the amounts of leaning was 30 m or above, 0 points were given by judging that there was a problem in practical use; when the amount of leaning was 20 m inclusive to 30 m exclusive, 1 point was given by judging that there was no problem in practical use; and when the amount of leaning was less than 20 m, 2 points were given by judging that the result was extremely excellent. These points were entered in the Leaning performance fields of Tables 2-1, 2-2, and 4. Only 0 points were rejected and 1 point and above were accepted.

(51) (Evaluation of Wedge Bondability)

(52) Electrodes obtained by Ag-plating a typical metal lead frame were wedge-bonded and the bonding strength of 10 wedge bonds selected at random was measured by a wire pull test. A lead frame made of Fe-42 at % Ni alloy was used by being Ag-plated to a thickness of 1 to 3 m. In the present evaluation, by assuming bonding conditions more stringent than usual, stage temperature was set to 165 C., which was lower than a common set temperature zone. The average value of measurement results at 10 locations was adopted as the bonding strength of the wedge bond. In the above evaluation, when the bonding strength of the wedge bond was less than 3 gf, 0 points were given by judging that there was a problem in practical use; when the bonding strength was 3 gf or above, 1 point was given by judging that there was no problem in practical use; when the bonding strength was 3.5 gf or above, 2 points were given by judging that the result was good; and when the bonding strength was 4 gf or above, 3 points were given by judging that the result was excellent. These points were entered in the Wedge bondability fields of Tables 2-1, 2-2, and 4. Only 0 points were rejected and 1 point and above were accepted.

(53) (Evaluation of Damage Resistance Performance of Neck Portion)

(54) To evaluate the damage resistance performance of the neck portion, damage to the neck portion was observed under an SEM and a determination was made based on the occurrence frequency of the damage. In the present evaluation, as loop formation conditions for accelerated evaluation of damage to the neck portion, the loop length was set to 3 mm and the loop height was set to 80 m. One hundred (100) neck portions selected at random were observed. When there were two or more damaged neck portions, 0 points were given by judging that there was a problem in practical use; when there was one damaged neck portion, 1 point was given by judging that there was no problem in practical use; and when there was no damaged neck portion, 2 points were given by judging that the result was excellent. These points were entered in the Damage resistance performance of neck portion fields of Tables 2-1, 2-2, and 4.

(55) (Description of Evaluation Results)

(56) Because Examples No. 1 to 81 are bonding wires containing 0.1 mass % to 1.3 mass % of Pt and a total of 0.05 mass % to 1.25 mass % of at least one dopant selected from the first dopant group consisting of In, Ga, and Ge, with the balance being made up of Cu and incidental impurities, the formation rate of CuAl IMC had no problem in practical use.

(57) Because Examples No. 29 to 49, 80, and 81 are bonding wires in which the concentration of Pt is 0.3 mass % to 1.0 mass %, and a total of 0.05 mass % to 1.25 mass % of at least one dopant selected from the first dopant group is contained, or 0.1 mass % to 1.3 mass % of Pt is contained and the concentration of at least one dopant selected from the first dopant group is 0.10 mass % to 0.75 mass %, excellent formation rates of CuAl IMC were obtained.

(58) Because Examples 41 to 49 are bonding wires in which the concentration of Pt is 0.3 mass % to 1.0 mass %, and the concentration of at least one dopant selected from the first dopant group is 0.10 mass % to 0.75 mass %, particularly excellent formation rates of CuAl IMC were obtained.

(59) Because Examples 50 to 62, 80, and 81 are bonding wires further containing a total of 0.0005 mass % to 0.0100 mass % of at least one dopant selected from the second dopant group of B, P, Ca, La, and Ce, particularly excellent crimped shapes of ball bonds in small-ball bonding were obtained and particularly excellent formation rates of CuAl IMC right under balls were obtained as well.

(60) Because Examples 63 to 67, 80, and 81 are bonding wires in which the crystal orientation in a longitudinal section of the bonding wire is such that the abundance ratio of the crystal orientation <100> having an angular difference of 15 degrees or less from the longitudinal direction of the bonding wire is from 50% to 100%, in terms of area percentage, evaluation results of spring failures and leaning failures were extremely good.

(61) Because Examples 1 to 67, 71 to 76, 78, and 79 are bonding wires in which breaking elongation in a tensile test is 8% to 15.5%, good bonding strength of wedge bonds were obtained. Furthermore, because Examples 68 to 70, 80, and 81 are bonding wires in which breaking elongation in a tensile test is 11% to 14%, excellent bonding strength of wedge bonds were obtained.

(62) Because Examples 72 to 81 are bonding wires further containing a total of 0.0005 mass % to 1.0 mass % of at least one element selected from a third dopant group of Au, Pd, and Ni, an excellent damage prevention effect of the neck portions was obtained.

(63) TABLE-US-00001 TABLE 1-1 Content Contents of first dopant group Contents of second dopant group of Pt (mass %) (mass %) No. (mass %) In Ga Ge Total B P Ca La Ce Total Examples 1 0.1 0.050 0.050 0.0000 2 0.1 0.050 0.050 0.0000 3 0.1 0.050 0.050 0.0000 4 0.1 0.024 0.026 0.050 0.0000 5 0.1 0.020 0.030 0.050 0.0000 6 0.1 0.028 0.022 0.050 0.0000 7 0.1 0.010 0.020 0.020 0.050 0.0000 8 0.1 1.250 1.250 0.0000 9 0.1 1.250 1.250 0.0000 10 0.1 1.250 1.250 0.0000 11 0.1 0.500 0.750 1.250 0.0000 12 0.1 0.500 0.750 1.250 0.0000 13 0.1 0.600 0.650 1.250 0.0000 14 0.1 0.400 0.300 0.550 1.250 0.0000 15 1.3 0.050 0.050 0.0000 16 1.3 0.050 0.050 0.0000 17 1.3 0.050 0.050 0.0000 18 1.3 0.024 0.026 0.050 0.0000 19 1.3 0.020 0.030 0.050 0.0000 20 1.3 0.028 0.022 0.050 0.0000 21 1.3 0.010 0.020 0.020 0.050 0.0000 22 1.3 1.250 1.250 0.0000 23 1.3 1.250 1.250 0.0000 24 1.3 1.250 1.250 0.0000 25 1.3 0.500 0.750 1.250 0.0000 26 1.3 0.500 0.750 1.250 0.0000 27 1.3 0.600 0.650 1.250 0.0000 28 1.3 0.400 0.300 0.550 1.250 0.0000 Ratio of orientation <100> in longitudinal Contents of third dopant group direction of wire Breaking (mass %) No. in wire section elongation Au Pd Ni Total Examples 1 41 10.2 0.0000 2 44 10.3 0.0000 3 32 10.1 0.0000 4 30 10.5 0.0000 5 25 10.4 0.0000 6 45 10.0 0.0000 7 31 10.9 0.0000 8 39 10.9 0.0000 9 42 10.6 0.0000 10 15 10.8 0.0000 11 26 10.7 0.0000 12 28 10.5 0.0000 13 16 10.0 0.0000 14 43 10.1 0.0000 15 19 10.1 0.0000 16 18 10.4 0.0000 17 22 10.9 0.0000 18 41 10.7 0.0000 19 36 10.3 0.0000 20 33 10.0 0.0000 21 38 10.2 0.0000 22 49 10.1 0.0000 23 16 10.6 0.0000 24 14 10.5 0.0000 25 30 10.2 0.0000 26 18 10.3 0.0000 27 39 10.2 0.0000 28 37 10.0 0.0000

(64) TABLE-US-00002 TABLE 1-2 Content Contents of first dopant group Contents of second dopant group of Pt (mass %) (mass %) No. (mass %) In Ga Ge Total B P Ca La Ce Total Examples 29 0.3 0.800 0.800 0.0000 30 0.3 0.780 0.780 0.0000 31 0.3 0.860 0.860 0.0000 32 1.0 0.840 0.840 0.0000 33 1.0 0.800 0.800 0.0000 34 1.0 0.790 0.790 0.0000 35 1.1 0.100 0.100 0.0000 36 1.2 0.100 0.100 0.0000 37 1.1 0.100 0.100 0.0000 38 1.2 0.750 0.750 0.0000 39 1.1 0.750 0.750 0.0000 40 1.3 0.730 0.730 0.0000 41 0.3 0.100 0.100 0.0000 42 0.3 0.100 0.100 0.0000 43 0.3 0.100 0.100 0.0000 44 0.5 0.050 0.050 0.100 0.0000 45 0.7 0.500 0.500 0.0000 46 0.8 0.500 0.500 0.0000 47 1.0 0.750 0.750 0.0000 48 1.0 0.750 0.750 0.0000 49 1.0 0.750 0.750 0.0000 50 0.1 0.050 0.050 0.0005 0.0005 51 0.1 0.080 0.080 0.0005 0.0005 52 0.1 0.090 0.090 0.0005 0.0005 53 0.1 0.050 0.050 0.0005 0.0005 54 0.1 0.070 0.070 0.0005 0.0005 55 0.1 0.040 0.040 0.0100 0.0100 56 0.1 0.040 0.040 0.0100 0.0100 57 0.1 0.060 0.060 0.0100 0.0100 Ratio of orientation <100> in longitudinal Contents of third dopant group direction of wire Breaking (mass %) No. in wire section elongation Au Pd Ni Total Examples 29 19 10.1 0.0000 30 22 10.5 0.0000 31 28 10.3 0.0000 32 19 10.5 0.0000 33 38 10.8 0.0000 34 44 10.1 0.0000 35 28 10.3 0.0000 36 27 10.2 0.0000 37 29 10.5 0.0000 38 10 10.4 0.0000 39 43 10.7 0.0000 40 41 10.6 0.0000 41 22 10.8 0.0000 42 28 10.0 0.0000 43 18 10.2 0.0000 44 13 10.2 0.0000 45 28 10.3 0.0000 46 30 10.4 0.0000 47 20 10.9 0.0000 48 15 10.6 0.0000 49 24 10.5 0.0000 50 13 10.8 0.0000 51 28 10.7 0.0000 52 26 10.6 0.0000 53 25 10.3 0.0000 54 38 10.4 0.0000 55 36 10.8 0.0000 56 19 10.9 0.0000 57 24 10.4 0.0000

(65) TABLE-US-00003 TABLE 1-3 Content Contents of first dopant group Contents of second dopant group of Pt (mass %) (mass %) No. (mass %) In Ga Ge Total B P Ca La Ce Total Examples 58 0.1 0.050 0.050 0.0100 0.0100 59 0.1 0.060 0.010 0.070 0.0100 0.0100 60 0.1 0.060 0.060 0.0020 0.0010 0.0030 61 0.1 0.070 0.070 0.0010 0.0010 0.0020 62 0.1 0.090 0.090 0.0020 0.0030 0.0050 63 0.1 0.080 0.080 0.0000 64 0.1 0.070 0.070 0.0000 65 0.1 0.090 0.090 0.0000 66 0.1 0.070 0.070 0.0000 67 0.1 0.080 0.080 0.0000 68 0.1 0.050 0.050 0.0000 69 0.1 0.050 0.050 0.0000 70 0.1 0.050 0.050 0.0000 71 0.1 0.050 0.050 0.0000 72 0.1 0.060 0.060 0.0000 73 0.1 0.080 0.080 0.0000 74 0.1 0.080 0.080 0.0000 75 0.1 0.060 0.060 0.0000 76 0.1 0.080 0.080 0.0000 77 0.1 0.060 0.060 0.0000 78 0.1 0.090 0.090 0.0000 79 0.1 0.080 0.080 0.0000 80 0.5 0.050 0.050 0.0015 0.0015 81 0.5 0.050 0.050 0.0018 0.0018 Ratio of orientation <100> in longitudinal Contents of third dopant group direction of wire Breaking (mass %) No. in wire section elongation Au Pd Ni Total Examples 58 25 10.3 0.0000 59 22 10.5 0.0000 60 19 10.1 0.0000 61 28 10.0 0.0000 62 16 10.3 0.0000 63 50 10.6 0.0000 64 59 10.5 0.0000 65 64 10.4 0.0000 66 77 10.7 0.0000 67 98 10.6 0.0000 68 45 11.2 0.0000 69 48 12.5 0.0000 70 46 14.0 0.0000 71 45 10.0 0.0000 72 40 8.4 0.0005 0.0005 73 36 8.1 1.0000 1.0000 74 42 8.0 0.0005 0.0005 75 39 8.2 1.0000 1.0000 76 34 8.3 0.0005 0.0005 77 35 7.6 1.0000 1.0000 78 41 8.2 0.0002 0.0003 0.0005 79 46 8.1 0.0005 0.0005 0.0010 80 75 13.0 0.4000 0.4000 81 77 11.4 0.4000 0.4000

(66) TABLE-US-00004 TABLE 2-1 Evaluation results Roundness of CuAl IMC Damage CuAl IMC crimped ball formation resistance formation shape in small- rate right Spring Leaning Wedge performance of No. rate ball bonding under balls performance performance bondability neck portion Examples 1 1 1 1 1 1 2 1 2 1 1 1 1 1 2 1 3 1 1 1 1 1 2 1 4 1 1 1 1 1 2 1 5 1 1 1 1 1 2 1 6 1 1 1 1 1 2 1 7 1 1 1 1 1 2 1 8 1 1 1 1 1 2 1 9 1 1 1 1 1 2 1 10 1 1 1 1 1 2 1 11 1 1 1 1 1 2 1 12 1 1 1 1 1 2 1 13 1 1 1 1 1 2 1 14 1 1 1 1 1 2 1 15 1 1 1 1 1 2 1 16 1 1 1 1 1 2 1 17 1 1 1 1 1 2 1 18 1 1 1 1 1 2 1 19 1 1 1 1 1 2 1 20 1 1 1 1 1 2 1 21 1 1 1 1 1 2 1 22 1 1 1 1 1 2 1 23 1 1 1 1 1 2 1 24 1 1 1 1 1 2 1 25 1 1 1 1 1 2 1 26 1 1 1 1 1 2 1 27 1 1 1 1 1 2 1 28 1 1 1 1 1 2 1 29 2 1 1 1 1 2 1 30 2 1 1 1 1 2 1 31 2 1 1 1 1 2 1 32 2 1 1 1 1 2 1 33 2 1 1 1 1 2 1 34 2 1 1 1 1 2 1 35 2 1 1 1 1 2 1 36 2 1 1 1 1 2 1 37 2 1 1 1 1 2 1 38 2 1 1 1 1 2 1 39 2 1 1 1 1 2 1 40 2 1 1 1 1 2 1 41 3 1 1 1 1 2 1 42 3 1 1 1 1 2 1 43 3 1 1 1 1 2 1 44 3 1 1 1 1 2 1 45 3 1 1 1 1 2 1

(67) TABLE-US-00005 TABLE 2-2 Evaluation results Roundness of CuAl IMC Damage CuAl IMC crimped ball formation resistance formation shape in small- rate right Spring Leaning Wedge performance of No. rate ball bonding under balls performance performance bondability neck portion Examples 46 3 1 1 1 1 2 1 47 3 1 1 1 1 2 1 48 3 1 1 1 1 2 1 49 3 1 1 1 1 2 1 50 1 2 2 1 1 2 1 51 1 2 2 1 1 2 1 52 1 2 2 1 1 2 1 53 1 2 2 1 1 2 1 54 1 2 2 1 1 2 1 55 1 2 2 1 1 2 1 56 1 2 2 1 1 2 1 57 1 2 2 1 1 2 1 58 1 2 2 1 1 2 1 59 1 2 2 1 1 2 1 60 1 2 2 1 1 2 1 61 1 2 2 1 1 2 1 62 1 2 2 1 1 2 1 63 1 1 1 2 2 2 1 64 1 1 1 2 2 2 1 65 1 1 1 2 2 2 1 66 1 1 1 2 2 2 1 67 1 1 1 2 2 2 1 68 1 1 1 1 1 3 1 69 1 1 1 1 1 3 1 70 1 1 1 1 1 3 1 71 1 1 1 1 1 2 1 72 1 1 1 1 1 2 2 73 1 1 1 1 1 2 2 74 1 1 1 1 1 2 2 75 1 1 1 1 1 2 2 76 1 1 1 1 1 2 2 77 1 1 1 1 1 1 2 78 1 1 1 1 1 2 2 79 1 1 1 1 1 2 2 80 2 2 2 2 2 3 2 81 2 2 2 2 2 3 2

(68) TABLE-US-00006 TABLE 3 Content Contents of first dopant group Contents of second dopant group of Pt (mass %) (mass %) No. (mass %) In Ga Ge Total B P Ca La Ce Total Comparative 1 0.20 0.000 0 Examples 2 1.30 0.000 0 3 0.005 0.005 0 4 1.250 1.250 0 5 0.005 0.005 0 6 1.250 1.250 0 7 0.005 0.005 0 8 1.250 1.250 0 9 0.08 0.005 0.005 0 10 0.08 1.250 1.250 0 11 0.08 0.005 0.005 0 12 0.08 1.250 1.250 0 13 0.08 0.005 0.005 0 14 0.08 1.250 1.250 0 15 1.30 0.005 0.005 0 16 1.41 1.250 1.250 0 17 1.30 0.005 0.005 0 18 1.43 1.250 1.250 0 19 1.30 0.005 0.005 0 20 1.31 1.250 1.250 0 21 0.50 0.004 0.004 0 22 0.50 1.300 1.300 0 23 0.50 0.004 0.004 0 24 0.50 1.300 1.300 0 25 0.50 0.004 0.004 0 26 0.50 1.300 1.300 0 Ratio of orientation <100> in longitudinal Contents of third dopant group direction of wire Breaking (mass %) No. in wire section elongation Au Pd Ni Total Comparative 1 32 10.2 0.0000 Examples 2 44 10.3 0.0000 3 43 10.1 0.0000 4 42 10.0 0.0000 5 46 9.7 0.0000 6 49 9.6 0.0000 7 44 10.4 0.0000 8 45 10.6 0.0000 9 41 9.6 0.0000 10 38 10.4 0.0000 11 46 10.8 0.0000 12 38 9.4 0.0000 13 46 10.6 0.0000 14 42 9.7 0.0000 15 41 10.9 0.0000 16 40 9.4 0.0000 17 45 9.2 0.0000 18 43 10.4 0.0000 19 39 10.1 0.0000 20 34 10.0 0.0000 21 49 9.7 0.0000 22 38 9.3 0.0000 23 44 10.6 0.0000 24 46 10.1 0.0000 25 49 9.4 0.0000 26 44 9.5 0.0000

(69) TABLE-US-00007 TABLE 4 Evaluation results CuAl Roundness CuAl IMC Damage IMC of crimped ball formation resistance formation shape in small- rate right Spring Leaning Wedge performance of No. rate ball bonding under balls performance performance bondability neck portion Comparative 1 0 1 1 1 1 1 1 Examples 2 0 1 1 1 1 1 1 3 0 1 1 1 1 1 1 4 0 1 1 1 1 1 1 5 0 1 1 1 1 1 1 6 0 1 1 1 1 1 1 7 0 1 1 1 1 1 1 8 0 1 1 1 1 1 1 9 0 1 1 1 1 1 1 10 0 1 1 1 1 1 1 11 0 1 1 1 1 1 1 12 0 1 1 1 1 1 1 13 0 1 1 1 1 1 1 14 0 1 1 1 1 1 1 15 0 1 1 1 1 1 1 16 0 1 1 1 1 1 1 17 0 1 1 1 1 1 1 18 0 1 1 1 1 1 1 19 0 1 1 1 1 1 1 20 0 1 1 1 1 1 1 21 0 1 1 1 1 1 1 22 0 1 1 1 1 1 1 23 0 1 1 1 1 1 1 24 0 1 1 1 1 1 1 25 0 1 1 1 1 1 1 26 0 1 1 1 1 1 1