Sample holder assembly for effective thermal conductivity measurement of pebble-bed in laser flash apparatus

Abstract

The present disclosure provides a sample holder assembly for a laser flash apparatus for measuring a thermal conductivity of a pebble-bed, the assembly comprising: a tubular sample container configured to be mounted on a sample carrier tube for the laser flash apparatus, wherein the sample container has open top and bottom; a bottom disc disposed in the sample container to block the open bottom of the sample container and configured for delivering a laser from a laser flash unit of the apparatus to a pebble-bed; the pebble-bed packed on the bottom disc to a predetermined thickness; and a top disc disposed on the pebble-bed and in the sample container to block the open top of the sample container and configured for receiving heat from the pebble-bed to transfer the heat upward.

Claims

1. A sample holder assembly for a laser flash apparatus for measuring a thermal conductivity of a pebble-bed, the assembly comprising: a tubular sample container configured to be mounted on a sample carrier tube for the laser flash apparatus, wherein the sample container has open top and bottom; a bottom disc disposed in the sample container to block the open bottom of the sample container and configured for delivering a laser from a laser flash unit of the apparatus to a pebble-bed; the pebble-bed packed on the bottom disc to a predetermined thickness; and a top disc disposed on the pebble-bed and in the sample container to block the open top of the sample container and configured for receiving heat from the pebble-bed to transfer the heat upward, wherein the assembly further comprises a tubular load ring having an outer diameter smaller than an inner diameter of the sample container so as to press the top disc toward the bottom disc to pack the pebble-bed, wherein the sample container has an annular inner step extending inwardly from an inner face of the container, wherein a bottom face of the annular inner step of the sample container is mounted on the sample carrier tube such that the sample holder assembly is mounted on the sample carrier tube, wherein the assembly further includes a quartz disc disposed on a top face of the annular inner step, wherein the bottom disc, the pebble-bed and the top disc are sequentially stacked on the quartz disc, wherein the assembly further includes a side ring disposed between outer side faces of the bottom disc, the pebble-bed, the top disc, and the load ring and an inner face of the sample container, wherein the side ring is configured for blocking heat transmission from the packed pebble-bed to the inner face of the container, wherein the tubular load ring has a hat brim extending radially outwardly from a first end of the load ring opposite a second end thereof inserted in the sample container, wherein the hat brim covers the sample container.

2. The sample holder assembly of claim 1, wherein the side ring is made of quartz or concrete.

3. The sample holder assembly of claim 1, wherein each of the top and bottom discs is made of graphite.

4. The sample holder assembly of claim 1, wherein the sample container is made of graphite.

5. The sample holder assembly of claim 1, wherein each of the sample container, the top and bottom discs is made of graphite, wherein the side ring is made of quartz.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) The accompanying drawings, which are incorporated in and form a portion of this specification and in which like numerals depict like elements, illustrate embodiments of the present disclosure and, together with the description, serve to explain the principles of the disclosure:

(2) FIG. 1 shows a laser flash apparatus including a laser power unit, a chiller, a measurement unit, and a control unit.

(3) FIG. 2 shows a first sample holder assembly for electrical conductivity measurement of a pebble-bed in accordance with the present disclosure.

(4) FIG. 3 shows results of the measurement of the thermal diffusivity based on a thickness of a Li.sub.2TiO.sub.3 pebble according to the first sample holder assembly of the present disclosure.

(5) FIG. 4 shows results of the thermal diffusivity measurement based on a thickness of an alumina pebble according to the first sample holder assembly of the present disclosure.

(6) FIG. 5 shows measurement of the thermal diffusivity based on a thickness of a graphite pebble according to the first sample holder assembly of the present disclosure.

(7) FIG. 6 shows measurement of the thermal diffusivity based on a thickness of bulk SS304 according to the first sample holder assembly of the present disclosure.

(8) FIG. 7 shows a second sample holder assembly for electrical conductivity measurement of the pebble-bed in accordance with the present disclosure.

(9) FIG. 8 shows thermal diffusivities of SS304 bulk when using the second sample holder assembly, when not using the second sample holder assembly, and a thermal diffusivity based on a literature value.

(10) FIG. 9 shows thermal diffusivities of a standard sample (Poco-Graphite) when using the second sample holder assembly, when not using the second sample holder assembly, and a thermal diffusivity based on a literature value.

(11) FIG. 10 shows a thermal diffusivity based on a thickness of Al.sub.2O.sub.3 pebble using the second sample holder assembly.

(12) FIG. 11 is a diagram illustrating a 3-layer method.

(13) FIG. 12 shows a thermal diffusivity based on a thickness of SS304 bulk using a 1-layer method when using the second sample holder assembly.

(14) FIG. 13 shows a thermal diffusivity on a thickness of SS304 bulk using a 3-layer method when using the second sample holder assembly, where each of the first and third layers includes SS304.

(15) FIG. 14 shows a third sample holder assembly for electrical conductivity measurement of the pebble-bed in accordance with the present disclosure.

(16) FIG. 15 provides ANSYS results for the third sample holder assembly in accordance with the present disclosure.

(17) FIG. 16 is a graph indicating a result of measuring a thermal conductivity of Li.sub.2TiO.sub.3 pebble-bed using the third sample holder assembly.

(18) FIG. 17 illustrates a state in which a sample holder assembly in accordance with the present disclosure is mounted to a laser flash apparatus.

DETAILED DESCRIPTIONS

(19) For simplicity and clarity of illustration, elements in the figures are not necessarily drawn to scale. The same reference numbers in different figures denote the same or similar elements, and as such perform similar functionality. Also, descriptions and details of well-known steps and elements are omitted for simplicity of the description. Furthermore, in the following detailed description of the present disclosure, numerous specific details are set forth in order to provide a thorough understanding of the present disclosure. However, it will be understood that the present disclosure may be practiced without these specific details. In other instances, well-known methods, procedures, components, and circuits have not been described in detail so as not to unnecessarily obscure aspects of the present disclosure.

(20) Examples of various embodiments are illustrated and described further below. It will be understood that the description herein is not intended to limit the claims to the specific embodiments described. On the contrary, it is intended to cover alternatives, modifications, and equivalents as may be included within the spirit and scope of the present disclosure as defined by the appended claims.

(21) It will be understood that, although the terms first, second, third, and so on may be used herein to describe various elements, components, regions, layers and/or sections, these elements, components, regions, layers and/or sections should not be limited by these terms. These terms are used to distinguish one element, component, region, layer or section from another element, component, region, layer or section. Thus, a first element, component, region, layer or section described below could be termed a second element, component, region, layer or section, without departing from the spirit and scope of the present disclosure.

(22) It will be understood that when an element or layer is referred to as being connected to, or coupled to another element or layer, it can be directly on, connected to, or coupled to the other element or layer, or one or more intervening elements or layers may be present. In addition, it will also be understood that when an element or layer is referred to as being between two elements or layers, it can be the only element or layer between the two elements or layers, or one or more intervening elements or layers may also be present.

(23) Spatially relative terms, such as beneath, below, lower, under, above, upper, and the like, may be used herein for ease of explanation to describe one element or feature's relationship to another element s or feature s as illustrated in the figures. It will be understood that the spatially relative terms are intended to encompass different orientations of the device in use or in operation, in addition to the orientation depicted in the figures. For example, if the device in the figures is turned over, elements described as below or beneath or under other elements or features would then be oriented above the other elements or features. Thus, the example terms below and under can encompass both an orientation of above and below. The device may be otherwise oriented for example, rotated 90 degrees or at other orientations, and the spatially relative descriptors used herein should be interpreted accordingly.

(24) The terminology used herein is for the purpose of describing particular embodiments only and is not intended to be limiting of the present disclosure. As used herein, the singular forms a and an are intended to include the plural forms as well, unless the context clearly indicates otherwise. It will be further understood that the terms comprises, comprising, includes, and including when used in this specification, specify the presence of the stated features, integers, operations, elements, and/or components, but do not preclude the presence or addition of one or more other features, integers, operations, elements, components, and/or portions thereof. As used herein, the term and/or includes any and all combinations of one or more of the associated listed items. Expression such as at least one of when preceding a list of elements may modify the entire list of elements and may not modify the individual elements of the list.

(25) Unless otherwise defined, all terms including technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this inventive concept belongs. It will be further understood that terms, such as those defined in commonly used dictionaries, should be interpreted as having a meaning that is consistent with their meaning in the context of the relevant art and will not be interpreted in an idealized or overly formal sense unless expressly so defined herein.

(26) In the following description, numerous specific details are set forth in order to provide a thorough understanding of the present disclosure. The present disclosure may be practiced without some or all of these specific details. In other instances, well-known process structures and/or processes have not been described in detail in order not to unnecessarily obscure the present disclosure.

(27) As used herein, the term substantially, about, and similar terms are used as terms of approximation and not as terms of degree, and are intended to account for the inherent deviations in measured or calculated values that would be recognized by those of ordinary skill in the art. Further, the use of may when describing embodiments of the present disclosure refers to one or more embodiments of the present disclosure.

(28) The present disclosure provides a sample holder assembly for a laser flash apparatus to measure the thermal conductivity of the pebble-bed.

(29) The structure of the sample holder assembly according to the present disclosure will be described in detail below with reference to the drawings.

(30) FIG. 2 illustrates a first sample holder assembly according to the present disclosure.

(31) The first sample holder assembly according to the present disclosure may include: a tubular sample container 230 configured to be mounted on a sample carrier tube for the laser flash apparatus, wherein the sample container has open top and bottom; a bottom disc 220 disposed in the sample container to block the open bottom of the sample container and configured for delivering a laser from a laser flash unit to a pebble-bed; the pebble-bed 250 packed on the bottom disc to a predetermined thickness; a top disc 210 disposed on the pebble-bed and in the sample container to block the open top of the sample container and configured for receiving heat from the pebble-bed to transfer the heat upward; and a tubular load ring 240 having an outer diameter smaller than an inner diameter of the sample container so as to press the top disc toward the bottom disc to pack the pebble-bed.

(32) FIG. 7 illustrates a second sample holder assembly as a more preferred example of a sample holder assembly according to the present disclosure.

(33) The second sample holder assembly according to the present disclosure may include: a tubular sample container 230 configured to be mounted on a sample carrier tube for the laser flash apparatus, wherein the sample container has open top and bottom; a bottom disc 220 disposed in the sample container to block the open bottom of the sample container and configured for delivering a laser from a laser flash unit to a pebble-bed; the pebble-bed 250 packed on the bottom disc to a predetermined thickness; a top disc 210 disposed on the pebble-bed and in the sample container to block the open top of the sample container and configured for receiving heat from the pebble-bed to transfer the heat upward; a tubular load ring 240 having an outer diameter smaller than an inner diameter of the sample container so as to press the top disc toward the bottom disc to pack the pebble-bed; and a side ring 330 disposed between an inner face of the sample container and an outer side face of the pebble-bed and surrounding the outer side face of the pebble-bed to block transfer of heat to the inner face of the sample container. The side ring is made of quartz.

(34) FIG. 14 illustrates a third sample holder assembly as a more preferred example of a sample holder assembly according to the present disclosure.

(35) The third sample holder assembly according to the present disclosure may include: a tubular sample container 230 configured to be mounted on a sample carrier tube for the laser flash apparatus, wherein the sample container has open top and bottom; a bottom disc 220 disposed in the sample container to block the open bottom of the sample container and configured for delivering a laser from a laser flash unit to a pebble-bed; the pebble-bed 250 packed on the bottom disc to a predetermined thickness; a top disc 210 disposed on the pebble-bed and in the sample container to block the open top of the sample container and configured for receiving heat from the pebble-bed to transfer the heat upward; a tubular load ring 240 having an outer diameter smaller than an inner diameter of the sample container so as to press the top disc toward the bottom disc to pack the pebble-bed; a side ring 330 disposed between an inner face of the sample container and an outer side face of the pebble-bed and surrounding the outer side face of the pebble-bed to block transfer of the heat to the inner face of the sample container; and a light-transmission disc 410 covering bottom and side faces of the packed pebble-bed and having an insulating property. The light-transmission disc can transmit therethrough laser light to the bottom disc, and prevents light from the pebble-bed from being lost in a direction other than the upward direction. The light-transmission disc may be made of quartz.

(36) The sample container includes an annular inner step 260 extending inwardly from an inner face of the container. A bottom face of the annular inner step of the sample container is mounted on the sample carrier tube such that the sample holder assembly is mounted on the sample carrier tube. A quartz disc 410 is disposed on the top face of the annular inner step. The bottom disc 230, the pebble-bed 250 and the top disc 210 are arranged on the quartz disc in this order. Between the outer side faces of the bottom disc/the pebble-bed/top disc and the outer side faces of the load ring 240 and the inner face of the sample container 230, a side ring 330 is disposed for blocking heat transmission from the packed pebble-bed to the inner face of the container.

(37) Further, the load ring 240 may include a hat brim 270 extending radially outwardly from an end opposite an end inserted in the sample container and covering the sample container. The sample container, the top disc, and the bottom disc are each made of graphite. Further, the side ring is made of quartz.

(38) Referring to FIG. 17, the sample container includes the annular inner step 260 extending inwardly from an inner face of the container. A bottom face of the annular inner step of the sample container is mounted on the sample carrier tube 810 such that the sample holder assembly is mounted on the sample carrier tube 810. The bottom disc 230 is disposed on the top face of the annular inner step 260. The pebble-bed 250 and the top disc 210 are arranged on the bottom disc in this order.

(39) 1. Experimental Apparatus

(40) FIG. 1 is a photograph of a laser flash apparatus a LFA 427 model available from NETZSCH. The laser flash apparatus includes a laser power unit that provides a laser source, a chiller that supplies cooling water to the laser power unit, a measurement unit that measures the sample, and a control unit that controls each component of the laser flash apparatus.

(41) 2. Measurement of Thermal Diffusivity

(42) The thermal diffusivity of the graphite pebble-bed is measured based on one-dimensional transient heat transfer equation. The thermal diffusivity may be calculated using an equation of time-based temperature change, using a half-time (t, a time to a half of the maximum temperature change) and the sample thickness d. The thermal diffusivity affects the heat transfer process inside the material, and has the form of the square of the length per hour. The thermal diffusivity has a following relationship using a thermal conductivity, a specific heat Cp, and a density:

(43) $=\frac{}{C_p}$

(44) 3. Performance Evaluation of First Sample Holder Assembly

(45) 3.1 First Sample Holder Assembly

(46) FIG. 2 shows the first sample holder assembly for the electrical conductivity measurement of the pebble-bed in accordance with the present disclosure. The sample holder assembly according to the first embodiment includes a sapphire top disc 210, a sapphire bottom disc 220, a sample container 230, and a load ring 240. On each of the faces of the discs facing the bed, a graphite coating is formed to absorb and release the laser. graphite pebbles as sample particles are filled between the top and bottom discs in the sample container.

(47) 3.2. Li.sub.2TiO.sub.3 (Japan) Pebble-Bed Experiment

(48) Experimental Objective: For the performance test of the first sample holder assembly, the applicant uses Li.sub.2TiO.sub.3 (Japan) to measure effective thermal diffusivity thereof as follows:

(49) Test method: A graphite coating is applied on a top face of the 1-layer sapphire disc and then the disc is inserted into the container. The pebbles are filled, with the desired thickness, into the sample container. After forming a graphite coating on the bottom face of the 3-layer sapphire disc, the disc covers the top face of the pebble-bed. After fitting the load ring into the container, the inside of the pebble-bed is vacuumed using a vacuum pump. Then, He gas is injected in the sample container in a vacuum state to bring the inside in the container to an atmospheric pressure. The thermal diffusivity is measured based on the sample thickness at a room temperature.

(50) The experimental conditions are shown in Table 1 below.

(51) TABLE-US-00001 TABLE 1 Parameter Value Material Li.sub.2TiO.sub.3 Pebble-bed Thickness (mm) 1.1 to 8 Diameter (mm) 22 Specific Heat (J/g/K) 0.709 Density (kg/m.sup.3) 1780 Thermal diffusivity (mm.sup.2/s) ? Temperature ( C.) RT Pressure Atmosphere He

(52) The experimental results are presented in FIG. 3. The pebble-bed measurements represent the average value of 10 measurements. The measured value is expressed with a percentage of an error bar of the corresponding value being 5%. As the thickness of the pebble-bed increases, the measured value thereof increases. The expected result is that the measured values converge when the thickness is larger than or equal to a certain thickness. It may be confirmed that the roundness of Li.sub.2TiO.sub.3 pebbles is not good and, thus, the contact between the pebbles is not good. As a result, a further experiment is planned using alumina pebbles with good roundness.

(53) 3.3 Alumina Pebble-Bed Experiment

(54) Experimental Objective: Thermal diffusivity measurements of Li.sub.2TiO.sub.3 purchased from Japan do not converge. Therefore, it is found that the roundness of Li.sub.2TiO.sub.3 pebbles is not uniform. Thus, the applicant uses the alumina pebble-bed with a relatively uniform roundness to verify whether thermal diffusivity measurements thereof converge.

(55) The experimental method is the same as the experimental method for the above Li.sub.2TiO.sub.3.

(56) The experimental results are presented in FIG. 4. As in the Li.sub.2TiO.sub.3 purchased from Japan, as the thickness of the alumina pebble-bed increases, the measured value thereof increases. Therefore, the thermal diffusivity measurement experiment is performed based on the thickness using graphite pebbles.

(57) 3.4 Graphite Pebble-Bed Experiment

(58) The experimental method is the same as the experimental method for the above Li.sub.2TiO.sub.3.

(59) Experimental Results: Unlike predicted, as the thickness of the pebble-bed increases, the thermal diffusivity values increase as in Li.sub.2TiO.sub.3 and Al.sub.2O.sub.3. Subsequent experiments are carried out based on thickness using SS304 bulk rather than the graphite pebble. To this end, the pebble sample holder assembly is used for the test of the SS304 bulk.

(60) 3.5 Thickness-Based Testing Using SS304 in a Form of Bulk Rather than Pebble-Bed

(61) Experimental Objective: Thickness-based testing is performed using SS304 in a form of a bulk other than the pebble-bed. The measurement performance of the pebble sample holder assembly is evaluated by using the bulk form rather than the pebble-bed.

(62) Test method: A SS304 disc with a graphite coating formed therein is placed on the 1-layer sapphire disc. Then, the 3-layer sapphire disc is placed on the SS304 disc. After fitting the load ring into the container, the inside of the container is vacuumed using a vacuum pump. Then, He gas is injected in the sample container in a vacuum state to bring the inside in the container to an atmospheric pressure. The thermal diffusivity is measured based on the sample thickness at a room temperature.

(63) Experimental conditions: SS304 thermal diffusivity and specific heat refer to material properties of ITER MPH.

(64) The experimental results are shown in FIG. 6. As described above, the thermal diffusivity values of Li.sub.2TiO.sub.3, Al.sub.2O.sub.3, and graphite pebble-beds increased without convergence. Therefore, the applicant measured the thermal diffusivity value based on the thickness of the sample SS304 bulk using the sample holder assembly. Experimental results show that for SS304, as the sample thickness increases, the thermal diffusivity value increases. Compared with the literature value, when the sample thickness of the SS04 bulk is 2 mm to 5 mm, the thermal diffusivity value has around 5% difference from the literature value.

(65) When the sample thickness of the SS04 bulk is 8 mm, the thermal diffusivity value has 10% or larger difference from the literature value. It may be seen that an error range is larger than in the thermal diffusivity measurement experiment based on the thickness using the existing standard sample holder assembly.

(66) 4. Performance Evaluation of Second Sample Holder Assembly

(67) 4.1 Second Sample Holder Assembly

(68) FIG. 7 illustrates a second sample holder assembly as an improved version of the first sample holder assembly for measuring the thermal conductivity of the particle bed. The improved second sample holder assembly includes a side ring 330 to suppress heat loss in a radial direction. The side ring is made of graphite (1000 W/m.Math.k) or the side ring is made of concrete (1.63 W/m.Math.k). Further, to avoid detection of noise signals from the top surfaces of the sample container and side ring, the load ring has a hat brim 240. In addition, instead of the sapphire disc, each of the top and bottom discs 330 and 340 is made of 0.5 mm thick stainless steel as a heat transfer media. A graphite coating is formed on each of top and bottom discs 330 and 340. Remaining components of the assembly are made of graphite. The second sample holder assembly uses the existing sample container. The side ring mounted on the wall of the sample container prevents the contact between the sample and the sample container to suppress the radial heat loss. The load ring has a hat brim, which blocks temperature signals from gaps around the side ring.

(69) 4.2 SS304 Bulk Experiment Using Second Pebble Sample Holder Assembly

(70) Experimental objective: The measurement of sample SS304 using the second sample holder assembly and the measurement of sample SS304 without the new second sample holder assembly are compared with each other.

(71) Test method: The thermal diffusivity measured using the second sample holder assembly and the thermal diffusivity measured without using the second sample holder assembly are compared with each other. Thus, the performance of the new second sample holder assembly is grasped.

(72) Experimental result: The measurement of sample SS304 using the second sample holder assembly and the measurement of sample SS304 without the new second sample holder assembly are compared with each other. To this end, the thermal diffusivity measured using the second sample holder assembly and the thermal diffusivity measured without using the second sample holder assembly are compared with each other. Thus, the performance of the new second sample holder assembly is grasped. As shown in FIG. 8, the thermal diffusivity measured using the second sample holder assembly and the thermal diffusivity measured without using the second sample holder assembly are substantially equal to each other. Further, each of the thermal diffusivity measured using the second sample holder assembly and the thermal diffusivity measured without using the second sample holder assembly has around 5% difference from the literature value.

(73) 4.3 Standard Sample (Poco-Graphite) Experiment Using Second Pebble Sample Holder Assembly

(74) Experimental objective: The measurement of standard sample (Poco-graphite) using the second sample holder assembly and the measurement of standard sample (Poco-graphite) without the new second sample holder assembly are compared with each other.

(75) Test method: The thermal diffusivity measured using the second sample holder assembly and the thermal diffusivity measured without using the second sample holder assembly are compared with each other. Thus, the performance of the new second sample holder assembly is grasped.

(76) Experimental result: The measurement of standard sample (Poco-graphite) using the second sample holder assembly and the measurement of standard sample (Poco-graphite) without the new second sample holder assembly are compared with each other. To this end, the thermal diffusivity measured using the second sample holder assembly and the thermal diffusivity measured without using the second sample holder assembly are compared with each other. Thus, the performance of the new second sample holder assembly is grasped. As shown in FIG. 9, the thermal diffusivity measured using the second sample holder assembly has 5% or smaller difference from the literature value. As shown in FIG. 9, the thermal diffusivity measured without using the second sample holder assembly has around 1% difference from the literature value. In this connection, the standard sample thermal diffusivity measurement error provided by the manufacturer, NETZSCH is about 5%. Thus, the pebble-bed measurement is performed using the second sample holder assembly.

(77) 4.4 Thickness-Based Experiment for Al.sub.2O.sub.3Pebble-Bed

(78) Experimental Objective: The new second sample holder assembly is used to measure the effective thermal diffusivity of sample Al.sub.2O.sub.3 with uniform pebble size. This confirms the performance of the new sample holder assembly.

(79) Test method: A graphite coating is applied on a top face of the 1-layer sapphire disc and then the disc is inserted into the container. The Al.sub.2O.sub.3 pebbles are filled, with the desired thickness, into the sample container. After forming a graphite coating on the bottom face of the 3-layer sapphire disc, the disc covers the top face of the pebble-bed. After fitting the load ring into the container, the inside of the pebble-bed is vacuumed using a vacuum pump. Then, He gas is injected in the sample container in a vacuum state to bring the inside in the container to an atmospheric pressure. The thermal diffusivity is measured based on the sample thickness at a room temperature.

(80) Experimental Results: As shown in FIG. 10, the thermal diffusivity measured using the second sample holder assembly is higher than the thermal diffusivity measured using the conventional sample holder assembly. However, even with the second sample holder assembly, the thermal diffusivity measurements increased as the thickness of the pebble-bed increased.

(81) 4.5 Measurement of Pebble-Bed Thermal Diffusivity Using 3-Layer Method

(82) The applicant measures the pebble-bed thermal diffusivity using a 3-layer method. In the 3-layer method as shown in FIG. 11, the 1-layer receives a laser power and then transmits heat to the bed and then, the heat passes through the 2-layer sample. Then, measurement is executed at the 3-layer. Graphite may be employed for 1-layer and 3-layer materials. The fabrication and basic thermal properties of the 1-layer and 3-layer materials are shown in Table 2 below:

(83) TABLE-US-00002 TABLE 2 Parameter Value Material SS304 Thickness (mm) 0.5 Diameter (mm) 22 Specific Heat (J/g/K) 0.470 Density (kg/m.sup.3) 7905 Thermal diffusivity (mm.sup.2/s) 3.901

(84) Test method: the graphite 1-layer disc is inserted into the container. The pebbles are filled, with the desired thickness, into the sample container. The 3-layer graphite disc covers the top face of the pebble-bed. After fitting the load ring into the container, the inside of the pebble-bed is vacuumed using a vacuum pump. Then, He gas is injected in the sample container in a vacuum state to bring the inside in the container to an atmospheric pressure. The thermal diffusivity is measured based on the sample thickness at a room temperature. The experimental conditions are as shown in Table 3 below.

(85) TABLE-US-00003 TABLE 3 Layer 1 Layer 2 Layer 3 Material SS304 Graphite SS304 Pebble-bed Thickness (mm) 0.5 1.1 to 7.52 0.5 Diameter (mm) 22 18 18 Specific Heat 0.470 0.709 0.470 (J/g/K) Density (kg/m.sup.3) 7905 1780 7905 Thermal diffusivity 3.901 ? 3.901 (mm.sup.2/s) Temperature ( C.) RT RT RT Pressure Atmosphere He

(86) As shown in FIGS. 12 and 13, the measured values using the 1-layer method using the second sample holder assembly increase. The values measured with the 3-layer method using the second sample holder assembly tend to increase when the thickness of the pebble is 6 mm or below 6 mm. The values measured with the 3-layer method using the second sample holder assembly tend to converge when the thickness of the pebble above 6 mm. The thermal diffusivity values measured by this method and the pebble sample holder assembly are similar to the preliminary experimental results. Test for other pebble-beds is performed additionally.

(87) 5. Performance Evaluation of Third Sample Holder Assembly

(88) 5.1 Third Sample Holder Assembly

(89) FIG. 14 illustrates the third sample holder assembly, an improved version of the first and second third sample holder assembles. The third sample holder assembly further comprises a tubular load ring 240 having an outer diameter smaller than an inner diameter of the sample container so as to press the top disc 210 toward the bottom disc to pack the pebble-bed. The sample container has an annular inner step 260 extending inwardly from an inner face of the container. A bottom face of the annular inner step of the sample container is mounted on the sample carrier tube 810 such that the sample holder assembly is mounted on the sample carrier tube. The assembly further includes a quartz disc 410 disposed on a top face of the annular inner step. The bottom disc, the pebble-bed and the top disc are sequentially stacked on the quartz disc. The assembly further includes a side ring 330 disposed between outer side faces of the bottom disc, the pebble-bed, the top disc, and the load ring and an inner face of the sample container, wherein the side ring is configured for blocking heat transmission from the packed pebble-bed to the inner face of the container. The tubular load ring 240 has a hat brim 270 extending radially outwardly from a first end of the load ring opposite a second end thereof inserted in the sample container, wherein the hat brim covers the sample container.

(90) 5.2 ANSYS Evaluation for Third Sample Holder Assembly

(91) FIG. 15 provides ANSYS results for the third sample holder assembly. When the side ring and the bottom disc surrounding the sample container are made of quartz, the temperatures in the edge and the center of the top face of the sample vary in a substantially uniform manner. From this result, it may be concluded that there is no heat transfer out of the sample, and the heat transfers only to the sample. This configuration is most advantageous for measuring the thermal conductivity of the pebble-bed. FIG. 16 is a graph indicating a result of measuring a thermal conductivity of Li.sub.2TiO.sub.3 pebble-bed using the third sample holder assembly.