Metal halide crystals having a nanotube structure and methods

Abstract

Provided are organic metal halide crystals having a 1D nanotube structure. The metal halide crystals may have a unit cell that includes two or more face-sharing metal halide dimers. The metal halide crystals also may include organic cations. Methods of forming metal halide crystals having a 1D nanotube structure also are provided.

Claims

1. A metal halide crystal comprising: a 1D nanotube structure, and a unit cell according to formula (I)
R.sup.d.sub.aM.sup.c.sub.2X.sub.b(I); wherein R is an organic cation comprising at least one positively charged moiety, a is 2 to 8, M is a metal atom selected from the group consisting of Sn, Pb, Sb, Bi, Ag, Au, Pd, Pt, Mn, Fe, Co, Ni, Cu, and Zn, c is the charge of the metal atom, d is the charge of the organic cation, X is a halide ion selected from the group consisting of Cl, Br, and I, b is 5 to 12, and
2(c)+a(d)=b.

2. The metal halide crystal of claim 1, wherein R comprises protonated hexamethylenetetramine (HMTA).

3. The metal halide crystal of claim 2, wherein d is 1.

4. The metal halide crystal of claim 1, wherein M is Pb.

5. The metal halide crystal of claim 1, wherein X is Br.

6. The metal halide crystal of claim 1, wherein R comprises protonated hexamethylenetetramine (HMTA), d is 1, a is 3, M is Pb, c is 2, X is Br, b is 7, and the unit cell of the metal halide crystal has the following formula:
(C.sub.6H.sub.13N.sub.4).sub.3Pb.sub.2Br.sub.7.

7. The metal halide crystal of claim 6, wherein the metal halide crystal comprises six face-sharing lead bromide dimers of the formula Pb.sub.2Br.sub.7.sup.3.

8. The metal halide crystal of claim 1, wherein R is selected from the group consisting of ##STR00005## ##STR00006## and a combination thereof.

9. The metal halide crystal of claim 1, wherein the metal halide crystal emits light in response to photo-excitation.

10. The metal halide crystal of claim 9, wherein the light emitted by the metal halide crystal is white light.

11. The metal halide crystal of claim 1, wherein the metal halide crystal has a photoluminescence quantum efficiency (PLQE) of about 7%.

12. The metal halide crystal of claim 1, wherein the 1D nanotube structure comprises a single-wall structure, a multiple-wall structure, or a combination thereof.

13. The metal halide crystal of claim 1, wherein the 1D nanotube structure comprises a metal halide tube having an inner portion and an outer portion, and the organic cations are located at (i) the inner portion of the metal halide tube, and (ii) the outer portion of the metal halide tube.

14. The metal halide crystal of claim 13, wherein a ratio of the number of organic cations located at the inner portion of the metal halide tube to the outer portion of the metal halide tube is about 1:2.

15. A method of making the metal halide crystal of claim 1 having a 1D nanotube structure, the method comprising: providing a liquid comprising a metal halide and an organic halide salt; and contacting the liquid with a crystallizing agent to form the metal halide crystal having a 1D nanotube structure; wherein the metal halide comprises a compound according to formula (II)
MX.sub.e(II); wherein M is a metal atom selected from the group consisting of Sn, Pb, Sb, Bi, Ag, Au, Pd, Pt, Mn, Fe, Co, Ni, Cu, and Zn; X is a halide ion selected from the group consisting of Cl, Br, and I; and e is 1, 2, or 3.

16. The method of claim 15, wherein the liquid comprises dimethylformamide (DMF).

17. The method of claim 15, wherein M is Pb, X is Br, e is 2, and the metal halide has the following formula:
PbBr.sub.2.

18. The method of claim 15, wherein the organic halide salt comprises hexamethylenetetramine hydrobromide.

19. The method of claim 15, wherein the crystallizing agent comprises dichloromethane.

20. A metal halide crystal comprising: a 1D nanotube structure, and a unit cell according to the following formula
(C.sub.6H.sub.13N.sub.4).sub.3Pb.sub.2Br.sub.7.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) FIG. 1 depicts a schematic of an embodiment of a 1D nanotube crystal.

(2) FIG. 2A depicts a ball-and-stick model of an individual face-sharing lead bromide dimer Pb.sub.2Br.sub.9.

(3) FIG. 2B depicts a rugged ring formed by six lead bromide dimers.

(4) FIG. 2C depicts a ball-and-stick model of an individual hexamethylenetetramine (HMTA) (C.sub.6H.sub.13N.sub.4.sup.+)(hydrogen atoms are omitted for clarity).

(5) FIG. 2D depicts a view along a longitudinal axis of a nanotube, which shows HMTA cations inside and outside the nanotube.

(6) FIG. 3 depicts powder X-ray diffraction data of an embodiment of a bulk quantum material, as well as its simulated results.

(7) FIG. 4 depicts the photo-stability of an embodiment of a metal halide crystal having a 1D nanotube structure.

(8) FIG. 5 depicts excitation (dash lines) and emission (solid lines, excited at 380 nm) spectra collected for an embodiment of a metal halide crystal having a 1D nanotube structure at room temperature.

(9) FIG. 6 depicts the emission decay of an embodiment of a metal halide crystal having a 1D nanotube structure (measured at 580 nm).

(10) FIG. 7 depicts an emission spectrum of an embodiment of a metal halide crystal having a 1D nanotube structure (excited at 380 nm) at 77 K.

(11) FIG. 8 depicts emission decays of the different emission peaks of FIG. 7 at 77 K.

(12) FIG. 9 depicts a proposed energy diagram and excited state dynamics of an embodiment of a metal halide crystal having a 1D nanotube structure (the straight and curved arrows represent optical and energy relaxation/transfer transitions, respectively).

(13) FIG. 10 depicts a calculated band structure of an embodiment of a metal halide crystal having a 1D nanotube structure.

(14) FIG. 11 depicts the projected density states of an embodiment of a metal halide crystal having a 1D nanotube structure.

DETAILED DESCRIPTION

(15) The unique nanotubular structure of embodiments of the metal halide crystals described herein may be advantageous in a number of potential applications, including, but not limited to, gas storage, ion selection, etc. Not wishing to be bound by any particular theory, it is believed that the use of an organic cation, such as protonated hexamethylenetetramine (HMTA) (C.sub.6H.sub.13N.sub.4.sup.+), can dictate the assembly of metal halides, thereby resulting, in some embodiments, in a bulk assembly of 1D metal halide nanotubes, such as those having a chemical formula of (C.sub.6H.sub.13N.sub.4).sub.3Pb.sub.2Br.sub.7.

(16) It is believed that due to the complete isolation and/or strong quantum confinement of individual metal halide nanotubes by wide band gap organic moieties in some embodiments, the nanotube-assembled materials having a 1D structure provided herein can exhibit one or more intrinsic properties of the individual metal halide nanotubes. In some embodiments, strongly Stokes shifted broadband yellowish white emission peaks at about 580 nm with a large full width at half maximum (FWHM) of about 158 nm. In some embodiments, the metal halide crystals have a photoluminescence quantum efficiency of about 7%, likely due to exciton self-trapping in the metal halide frameworks.

(17) Metal Halide Crystals

(18) Metal halide crystals are provided herein. In some embodiments, the metal halide crystals have a 1D nanotube structure, and a unit cell according to formula (I)
R.sup.d.sub.aM.sup.c.sub.2X.sub.b(I);
wherein R is an organic cation including at least one positively charged moiety; a is 2 to 8; M is a metal atom selected from the group consisting of Sn, Pb, Sb, Bi, Ag, Au, Pd, Pt, Mn, Fe, Co, Ni, Cu, and Zn; c is the charge of the metal atom; d is the charge of the organic cation; X is a halide ion selected from the group consisting of Cl, Br, and I; b is 5 to 12; and the selections for a, b, c, and d satisfy the following equation: 2(c)+a(d)=b. This equation ensures that the charges of formula (I) are balanced.

(19) In some embodiments, the metal halide crystals provided herein have a 1D nanotube structure. As used herein, the phrases 1D nanotube structure, 1D tubular structure, nanotube structure, and the like refer to crystals in which a number (e.g., three to eight) metal halides (e.g., face-sharing metal halide dimers, such as Pb.sub.2Br.sub.7.sup.3) form a ring, and a plurality of these rings substantially align and extend in one dimension, thereby forming a metal halide tube having an outer portion and an inner portion defined by the rings. The 1D nanotube structures may include one or more metal halide nanotubes formed in this manner. Organic cations, such as protonated hexamethylenetetramine (HMTA) cations (C.sub.6H.sub.13N.sub.4.sup.+), may be located at the inner portion and/or the outer portion of the metal halide tube(s). The rings formed by the metal halides may define a space that is substantially circular, but other shapes (e.g., oval, polygonal (e.g., hexagonal, octagonal, etc.), rectangular, star-shaped, etc.) are possible. The metal halides of the rings may be connected at one or more positions (e.g., at corners of the rings like the face-sharing metal halide dimers of formula Pb.sub.2Br.sub.7.sup.3).

(20) In some embodiments, the 1D nanotube structure includes a single-wall structure (e.g., as depicted at FIG. 1), a multiple-wall structure, or a combination thereof. A multiple-wall structure may include two or more concentric rings of metal halides that form two or more concentric metal halide tubes.

(21) In some embodiments, the rings of the 1D nanotube structures include three or more metal halide units. In some embodiments, the rings of the 1D nanotube structures include three to eight metal halide units. In some embodiments, the rings of the 1D nanotube structures include four to eight metal halide units. In some embodiments, the rings of the 1D nanotube structures include six metal halide units.

(22) An embodiment of a 1D nanotube structure is depicted at FIG. 1. FIG. 1 is a schematic depicting a cross-sectional view of an embodiment of a metal halide crystal having a 1D nanotube structure in which six, face-sharing metal halides form rings, which can extend in one dimension to form tubes. The rings define an inner portion and an outer portion at which the organic cations are located. The metal halides of FIG. 1 are represented by the rectangles, and the organic cations are represented by the circles. The ratio of the number of organic cations located at the inner portion of the tube to the outer portion of the tube is about 1:2 in FIG. 1. The dashes of FIG. 1 may represent at least one force, such as an attractive force, between an organic cation and a metal halide. The force represented by each dash may result from the one or more positively charged moieties of an organic cation. The 1D nanotube structure of FIG. 1 includes an array of nanotube structures in a hexagonal close-packed pattern, but other packing patterns are possible.

(23) The metal halide crystals provided herein generally may emit any color of light. The metal halide crystals may emit light in response to photo-excitation. In some embodiments, the metal halide crystals emit yellowish-white light. In some embodiments, the metal halide crystals emit white light. In some embodiments, the metal halide crystals have a photoluminescence quantum efficiency (PLQE) of about 3%, about 4%, about 5%, about 5%, about 7%, about 8%, about 9%, or about 10%. In some embodiments, the metal halide crystals have a PLQE of about 3% to about 10%.

(24) Organic Cations

(25) Any organic cation that includes at least one positively charged moiety may be included the metal halide crystals provided herein, or used in the methods provided herein. In some embodiments, the organic cation includes one positively charged moiety. In some embodiments, the organic cation includes two positively charged moieties. In some embodiments, the organic cation includes three positively charged moieties.

(26) In some embodiments, the organic cation is a C.sub.1-C.sub.24 hydrocarbyl that includes at least one positively charged moiety, such as a positively charged amine. In some embodiments, the organic cation is a C.sub.1-C.sub.24 hydrocarbyl that includes two to four positively charged moieties, such as two to four positively charged amines.

(27) In some embodiments, the organic cation is a C.sub.1-C.sub.24 hydrocarbyl that includes at least one of a protonated primary amine, a protonated secondary amine, a protonated tertiary amine, a quaternary amine, or a combination thereof. In a further embodiment, the organic cation is a C.sub.1-C.sub.24 hydrocarbyl that includes one to four protonated tertiary amines.

(28) In some embodiments, R of formula (I) is hexamethylenetetramine, and d of formula (I) is 1, 2, 3, or 4, as shown, respectively, in the following structures:

(29) ##STR00001##
The positive charges are assigned arbitrarily to the nitrogen atoms in the foregoing structures, and other assignments are envisioned.

(30) In some embodiments, the organic cation (R of formula (I)) is selected from the group consisting of N,N,N-trimethyloctan-1-aminium; tetraethylammonium; tetrabutylammonium; N,N-dimethylhexan-1-aminium; bis(2-ethylhexyl)ammonium; N.sup.1-methylethane-1,2-diaminium; N.sup.1,N.sup.2-dimethylethane-1,2-diaminium; N.sup.1,N.sup.1,N.sup.2,N.sup.2-tetramethylethane-1,2-diaminium; N.sup.1,N.sup.1-dimethylethane-1,2-diaminium; N.sup.1,N.sup.1,N.sup.2-trimethylethane-1,2-diaminium; 2,6-dimethylpyridin-1-ium; 2-amino-4-methylpyridin-1-ium; [4,4-bipyridine]-1,1-diium; [4,4-bipyridin]-1-ium; 4-(di(pyridin-4-yl)amino)pyridin-1-ium; 1-butyl-1-methylpyrrolidin-1-ium; 3-butyl-1-methyl-1H-imidazol-3-ium; 3-(pyrrolidin-1-yl)propan-1-aminium; 2-(pyrrolidin-2-yl)ethanaminium; 1,1-dibutylpiperidin-1-ium; 5-azaspiro[4.4]nonan-5-ium; (1r,3r,5s,7s)-1,3,5,7-tetraazaadamantane-1,3-diium; 6-azaspiro[5.5]undecan-6-ium; 1,4-diazabicyclo[2.2.2]octan-1-ium; (3s,5s,7s)-1-azaadamantan-1-ium; (3r,5r,7r)-1,3,5,7-tetraazaadamantan-1-ium (i.e., protonated hexamethylenetetramine); tetraphenylphosphonium; and a combination thereof.

(31) The foregoing compounds may be represented by the following structures:

(32) ##STR00002## ##STR00003##
and

(33) ##STR00004##

(34) The organic cations may be located at any position in the metal halide crystals provided herein. In some embodiments, the 1D nanotube structure includes a metal halide tube, as described herein, that has an inner portion and an outer portion, and the organic cations are located at the inner portion of the tube, the outer portion of the tube, or both the inner portion and the outer portion of the tube.

(35) In some embodiments, the organic cations are located at the inner portion of the metal halide tube and the outer portion of the metal halide tube, and a ratio of the number of organic cations located at the inner portion of the tube to the outer portion of the tube is about 1:1 to about 1:5. In some embodiments, the organic cations are located at the inner portion of the metal halide tube and the outer portion of the metal halide tube, and a ratio of the number of organic cations located at the inner portion of the tube to the outer portion of the tube is about 1:1 to about 1:4. In some embodiments, the organic cations are located at the inner portion of the metal halide tube and the outer portion of the metal halide tube, and a ratio of the number of organic cations located at the inner portion of the tube to the outer portion of the tube is about 1:1 to about 1:3. In some embodiments, the organic cations are located at the inner portion of the metal halide tube and the outer portion of the metal halide tube, and a ratio of the number of organic cations located at the inner portion of the tube to the outer portion of the tube is about 1:2. The ratio may be determined by X-ray diffraction as described herein.

(36) Metal Halides

(37) Any metal halide capable of forming a metal halide crystal having a 1D nanotube structure may be included in the metal halide crystals provided herein, or used in the methods provided herein.

(38) In some embodiments, the metal halide includes a dimer of formula M.sub.2X.sub.9, which may be a face-sharing dimer in the 1D nanotube structures provided herein. In some embodiments, the metal halide crystal includes two or more face-sharing lead bromide dimers of the formula Pb.sub.2Br.sub.7.sup.3. In some embodiments, the metal halide crystal includes three to eight face-sharing lead bromide dimers of the formula Pb.sub.2Br.sub.7.sup.3. In some embodiments, the metal halide crystal includes six face-sharing lead bromide dimers of the formula Pb.sub.2Br.sub.7.sup.3.

(39) In some embodiments, the metal halide crystals have a 1D nanotube structure, and a unit cell according to formula (I)
R.sup.d.sub.aM.sup.c.sub.2X.sub.b(I);
wherein d is 1. In some embodiments, M is Pb, and c is 2. In some embodiments, X is Br. In some embodiments, d is 1, M is Pb, and c is 2. In some embodiments, d is 1, M is Pb, c is 2, and X is Br. In some embodiments, d is 1, a is 3, M is Pb, c is 2, X is Br, b is 7, and the unit cell of the metal halide crystal has the following formula:
(R).sub.3Pb.sub.2Br.sub.7.
In some embodiments, d is 1, a is 3, M is Pb, c is 2, X is Br, b is 7, R is protonated hexamethylenetetramine, and the unit cell of the metal halide crystal has the following formula:
(C.sub.6H.sub.13N.sub.4).sub.3Pb.sub.2Br.sub.7.
Methods

(40) Methods of making metal halide crystals having a 1D nanotube structure are provided. In some embodiments, the methods include providing a liquid that includes a metal halide and an organic halide salt; and contacting the liquid with a crystallization agent. In some embodiments, the liquid includes dimethylformamide (DMF).

(41) In some embodiments, the metal halide includes a compound according to formula (II):
MX.sub.e(II);
wherein M is a metal atom selected from the group consisting of Sn, Pb, Sb, Bi, Ag, Au, Pd, Pt, Mn, Fe, Co, Ni, Cu, and Zn, X is a halide ion selected from the group consisting of Cl, Br, and I, and e is 1, 2, or 3. In some embodiments, M is Pb, X is Br, e is 2, and the metal halide of formula (II) is PbBr.sub.2. In some embodiments, the organic cation is hexamethylenetetramine hydrobromide. In some embodiments, the crystallizing agent includes dichloromethane.

(42) The phrase C.sub.1-C.sub.24 hydrocarbyl, and the like, as used herein, generally refers to aliphatic, aryl, or arylalkyl groups containing 1 to 24 carbon atoms. Examples of aliphatic groups, in each instance, include, but are not limited to, an alkyl group, a cycloalkyl group, an alkenyl group, a cycloalkenyl group, an alkynyl group, an alkadienyl group, a cyclic group, and the like, and includes all substituted, unsubstituted, branched, and linear analogs or derivatives thereof, in each instance having 1 to 24 carbon atoms. Examples of alkyl groups include, but are not limited to, methyl, ethyl, propyl, isopropyl, n-butyl, t-butyl, isobutyl, pentyl, hexyl, isohexyl, heptyl, 4,4-dimethylpentyl, octyl, 2,2,4-trimethylpentyl, nonyl, decyl, undecyl and dodecyl. Cycloalkyl moieties may be monocyclic or multicyclic, and examples include cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, and adamantyl. Additional examples of alkyl moieties have linear, branched and/or cyclic portions (e.g., 1-ethyl-4-methyl-cyclohexyl). Representative alkenyl moieties include vinyl, allyl, 1-butenyl, 2-butenyl, isobutylenyl, 1-pentenyl, 2-pentenyl, 3-methyl-1-butenyl, 2-methyl-2-butenyl, 2,3-dimethyl-2-butenyl, 1-hexenyl, 2-hexenyl, 3-hexenyl, 1-heptenyl, 2-heptenyl, 3-heptenyl, 1-octenyl, 2-octenyl, 3-octenyl, 1-nonenyl, 2-nonenyl, 3-nonenyl, 1-decenyl, 2-decenyl and 3-decenyl. Representative alkynyl moieties include acetylenyl, propynyl, 1-butynyl, 2-butynyl, 1-pentynyl, 2-pentynyl, 3-methyl-1-butynyl, 4-pentynyl, 1-hexynyl, 2-hexynyl, 5-hexynyl, 1-heptynyl, 2-heptynyl, 6-heptynyl, 1-octynyl, 2-octynyl, 7-octynyl, 1-nonynyl, 2-nonynyl, 8-nonynyl, 1-decynyl, 2-decynyl and 9-decynyl. Examples of aryl or arylalkyl moieties include, but are not limited to, anthracenyl, azulenyl, biphenyl, fluorenyl, indan, indenyl, naphthyl, phenanthrenyl, phenyl, 1,2,3,4-tetrahydro-naphthalene, tolyl, xylyl, mesityl, benzyl, and the like, including any heteroatom substituted derivative thereof. Two or more C.sub.1-C.sub.24 hydrocarbyl groups may be covalently bonded together.

(43) Unless otherwise indicated, the term substituted, when used to describe a chemical structure or moiety, refers to a derivative of that structure or moiety wherein one or more of its hydrogen atoms is substituted with a chemical moiety or functional group such as alcohol, alkoxy, alkanoyloxy, alkoxycarbonyl, alkenyl, alkyl (e.g., methyl, ethyl, propyl, t-butyl), alkynyl, alkylcarbonyloxy (OC(O)alkyl), amide (C(O)NH-alkyl- or -alkylNHC(O)alkyl), tertiary amine (such as alkylamino, arylamino, arylalkylamino), aryl, aryloxy, azo, carbamoyl (NHC(O)O alkyl- or OC(O)NH-alkyl), carbamyl (e.g., CONH.sub.2, as well as CONH-alkyl, CONH-aryl, and CONH-arylalkyl), carboxyl, carboxylic acid, cyano, ester, ether (e.g., methoxy, ethoxy), halo, haloalkyl (e.g., CCl.sub.3, CF.sub.3, C(CF.sub.3).sub.3), heteroalkyl, isocyanate, isothiocyanate, nitrile, nitro, phosphodiester, sulfide, sulfonamido (e.g., SO.sub.2NH.sub.2, SO.sub.2NRR), sulfone, sulfonyl (including alkylsulfonyl, arylsulfonyl and arylalkylsulfonyl), sulfoxide, thiol (e.g., sulfhydryl, thioether) or urea (NHCONH-alkyl-).

(44) While certain aspects of conventional technologies have been discussed to facilitate disclosure of various embodiments, applicants in no way disclaim these technical aspects, and it is contemplated that the present disclosure may encompass one or more of the conventional technical aspects discussed herein.

(45) In the descriptions provided herein, the terms includes, is, containing, having, and comprises are used in an open-ended fashion, and thus should be interpreted to mean including, but not limited to. When methods and metal halide crystals are claimed or described in terms of comprising various components or steps, the metal halide crystals and methods can also consist essentially of or consist of the various components or steps, unless stated otherwise.

(46) The terms a, an, and the are intended to include plural alternatives, e.g., at least one. For instance, the disclosure of a metal halide, an organic cation, a metal atom, and the like, is meant to encompass one, or mixtures or combinations of more than one metal halide, organic cation, metal atom, and the like, unless otherwise specified.

(47) The present invention is further illustrated by the following examples, which are not to be construed in any way as imposing limitations upon the scope thereof. On the contrary, it is to be clearly understood that resort may be had to various other aspects, embodiments, modifications, and equivalents thereof which, after reading the description herein, may suggest themselves to one of ordinary skill in the art without departing from the spirit of the present invention or the scope of the appended claims. Thus, other aspects of this invention will be apparent to those skilled in the art from consideration of the specification and practice of the invention disclosed herein.

EXAMPLES

(48) Unless stated otherwise, the following materials were used in the examples. Lead (II) bromide, hexamethylenetetramine and hydrobromic acid (48 wt. % in H.sub.2O) were purchased from Sigma-Aldrich. Dichloromethane (DCM, 99.9%) and dimethylformamide (DMF, 99.8%) were purchased from VWR. All reagents and solvents were used without further purification unless otherwise stated.

Example 1Preparation of Hexamethylenetetramine (HMTA) Hydrobromide

(49) Hexamethylenetetramine hydrobromide was prepared by adding a hydrobromic acid solution (0.81 mL, 7.1 mmol) into hexamethylenetetramine (1.00 g, 7.1 mmol) in 150 mL ethanol at 0 C.

(50) The white cotton-like organic salts were obtained (1.1 g, 70% yield) after removal of the solvents under vacuum, followed by washing with a suitable amount of ethanol. The salts were dried and kept in a desiccator.

Example 2Crystal Growth of (C.SUB.6.H.SUB.13.N.SUB.4.).SUB.3.Pb.SUB.2.Br.SUB.7 .Nanotube Material

(51) Single crystalline (HMTA).sub.3Pb.sub.2Br.sub.7 was prepared by slow solution diffusion of dichloromethane (DCM) into dimethylformamide (DMF) precursor solutions containing lead (II) bromide (PbBr.sub.2) and hexamethylenetetramine hydrobromide (C.sub.6H.sub.13N.sub.4Br).

(52) Lead (II) bromide (100 mg, 0.272 mmol) and hexamethylenetetramine hydrobromide (90.0 mg, 0.409 mmol) were mixed at 2:3 molar ratio and dissolved in dimethylformamide (DMF) (5 mL) to form a clear precursor solution.

(53) Bulk crystals were prepared by diffusing DCM (2 mL) into the prepared DMF solution (1 mL) at room temperature overnight.

(54) The large colorless crystals were washed with DCM and dried under reduced pressure. The yield was calculated as about 53%. (C.sub.6H.sub.13N.sub.4).sub.3Pb.sub.2Br.sub.7: Anal, Calc. C, 15.47; H, 2.81; N, 12.03. Found: C, 15.95; H, 2.92; N, 11.42.

Example 3Analysis of Hexamethylenetetramine Hydrobromide

(55) The products of Example 2 were characterized using the following techniques.

(56) 1. Single Crystal X-Ray Diffraction (SCXRD)

(57) Single crystal X-Ray Diffraction (SCXRD) was used to characterize the structure (see Tables below). Large arrays of metal halide nanotubes were observed, which included an individual nanotube surrounded by organic cations. FIG. 2A depicts a ball-and-stick model of an individual face-sharing lead bromide dimer Pb.sub.2Br.sub.9. FIG. 2B depicts a rugged ring formed by six lead bromide dimers. FIG. 2C depicts a ball-and-stick model of an individual HMTA (hydrogen atoms are omitted for clarity). FIG. 2D depicts a view along a longitudinal axis of a nanotube, which shows HMTA cations inside and outside the nanotube.

(58) In an individual nanotube, six face-sharing lead bromide dimers (Pb.sub.2Br.sub.7.sup.3) (FIG. 2A) connected at corners to form rugged rings (FIG. 2B) with an inner radius of around 5.5 that extended one dimensionally.

(59) In each window formed by four connected dimers on an individual hollow nanotube, three protonated HMTA cations C.sub.6H.sub.13N.sub.4.sup.+ (FIG. 2C) were anchored by columbic interaction and hydrogen bonding, with one positioned inside the tube and the other two outside (FIG. 2D). In other words, individual negatively charged metal halide nanotubes were coated by positive organic cations on both the inside and the outside at a 1/2 ratio, which resulted in an inorganic-organic core-shell nanotubular structure with an inner radius of around 3 taking the organic cations into account. These organic coated metal halide nanotubes further assembled into a hexagonal close packed array in a macroscopic crystal, such as the array depicted at FIG. 1.

(60) Single crystal X-ray diffraction data of hexamethylenetetramine lead bromide (C.sub.6H.sub.13N.sub.4).sub.3Pb.sub.2Br.sub.7 was collected using an Oxford-Diffraction Xcalibur-2 CCD diffractometer with graphite-monochromated Mo K radiation. The crystal was mounted in a cryoloop under Paratone-N oil and cooled to 100 K with an Oxford-Diffraction Cryojet.

(61) A complete sphere of data was collected using co scans with 1 frame widths to a resolution of approximately 0.68 , equivalent to 2640. Reflections were recorded, indexed and corrected for absorption using the Oxford-Diffraction CrysAlisPro software, and subsequent structure determination and refinement was carried out using the single crystal x-ray structure refinement and analysis software package CRYSTALS, employing Superflip, a program for solution of crystal structures by charge flipping, to solve the crystal structure. All hydrogens were restrained to the connecting carbons. The refinement was performed against F2, with anisotropic thermal displacement parameters for all non-hydrogen atoms and with isotropic thermal displacement parameters for the hydrogens in the structure. A CIF was deposited with CCDC (No. 1550500).

(62) Single Crystal x-Ray Diffraction Data and Collection Parameters.

(63) The collection was performed at a temperature of 100 K.

(64) TABLE-US-00001 Compound [(CH.sub.2).sub.6N.sub.4].sub.3Pb.sub.2Br.sub.7 Formula C.sub.18H.sub.36N.sub.12Pb.sub.2Br.sub.7 Molecular weight 1394.29 g/mol Space group P6.sub.3/m (#176) a 24.5206 (4) c 9.7661 (2) V 5085.3 (2) .sup.3 Z 6 .sub.calc. 2.732 g/cm.sup.3 18.201 mm.sup.1 Data collection range 2.666 < < 32.095 Reflections collected 112162 Independent reflections 5272 Parameters refined 280 Restraints 108 R.sub.1, wR.sub.2 0.0853.sup.a, 0.0737.sup.b Goodness-of-fit on F.sup.2 1.1060 .sup.aR.sub.1 = F.sub.o | | F.sub.c / | F.sub.o . .sup.bwR.sub.2 = [ w(F.sub.o.sup.2 F.sub.c.sup.2).sup.2/ w(F.sub.o.sup.2).sup.2].sup.1/2.
Atomic Positions of [(CH.sub.2).sub.6N.sub.4].sub.3Pb.sub.2Br.sub.7.

(65) All non-hydrogens were refined with anisotropic displacement parameters, while the hydrogens were refined with isotropic displacement parameters.

(66) TABLE-US-00002 Atom Site x y z U.sub.eq , U.sub.iso (.sup.2) Pb1 6h 0.93868(3) 0.65702(3) 0.25 0.0242(3) Pb2 6h 1.13162(3) 0.78579(4) 0.25 0.0531(7) Br1 6h 0.90529(7) 0.52701(6) 0.25 0.0241(7) Br2 12i 0.86617(5) 0.65139(5) 0.01916(11) 0.0329(6) Br3 12i 1.04247(5) 0.68509(5) 0.44732(9) 0.0293(6) Br4 6h 1.01457(10) 0.80536(8) 0.25 0.044(12) Br5 6h 1.21604(9) 0.73395(9) 0.25 0.0463(10) N11 12i 0.6747(4) 0.4578(4) 0.1244(8) 0.0281(5) N12 6h 0.6621(5) 0.5361(6) 0.25 0.0282(7) N13 6h 0.7657(6) 0.5428(6) 0.25 0.0322(8) C14 12i 0.6441(4) 0.4949(5) 0.1242(10) 0.028(5) C15 12i 0.7439(4) 0.5001(5) 0.1286(10) 0.028(5) C16 6h 0.6571(7) 0.4204(7) 0.25 0.0331(9) C17 6h 0.7355(6) 0.5814(6) 0.25 0.0276(8) N21 12i 0.9155(3) 0.4749(3) 0.6242(8) 0.0217(4) N22 6h 0.8762(5) 0.5338(6) 0.75 0.0255(7) N23 6h 0.9884(5) 0.5692(5) 0.75 0.0232(6) C24 12i 0.8693(5) 0.4947(5) 0.6238(10) 0.0299(6) C25 12i 0.9780(4) 0.5296(4) 0.6273(9) 0.0213(5) C26 6h 0.9073(7) 0.4364(7) 0.75 0.0354(9) C27 6h 0.9416(7) 0.5909(7) 0.75 0.0316(9) N31 12i 1.1513(4) 1.0250(5) 0.1253(10) 0.0465(6) N32 6h 1.2489(6) 1.0591(7) 0.25 0.0424(10) N33 6h 1.1681(7) 0.9472(7) 0.25 0.0427(9) C34 12i 1.2200(5) 1.0692(5) 0.1281(11) 0.0352(6) C35 12i 1.1411(6) 0.9616(6) 0.1288(12) 0.0462(8) C36 6h 1.1227(9) 1.0350(11) 0.25 0.0774(20) C37 6h 1.2354(8) 0.9957(9) 0.25 0.0512(13) H141 12i 0.6576(17) 0.5220(14) 0.045(3) 0.033(2) H142 12i 0.5987(10) 0.4673(13) 0.124(4) 0.033(2) H151 12i 0.7563(14) 0.5257(14) 0.048(2) 0.033(2) H152 12i 0.7638(14) 0.4745(14) 0.131(4) 0.033(2) H161 6h 0.678(2) 0.3955(18) 0.25 0.040(2) H162 6h 0.6120(12) 0.3929(17) 0.25 0.040(2) H171 12i 0.7483(11) 0.6079(9) 0.3313(15) 0.0330(14) H241 12i 0.8753(17) 0.5202(15) 0.544(3) 0.036(2) H242 12i 0.8273(11) 0.4583(12) 0.624(4) 0.036(2) H251 12i 1.0087(12) 0.5155(14) 0.629(4) 0.025(2) H252 12i 0.9847(15) 0.5549(12) 0.548(2) 0.025(2) H261 6h 0.9376(19) 0.4222(19) 0.75 0.043(2) H262 6h 0.8651(14) 0.4007(14) 0.75 0.043(2) H271 12i 0.9474(12) 0.6162(10) 0.8314(15) 0.0379(14) H341 12i 1.2274(15) 1.1120(11) 0.130(4) 0.042(2) H342 12i 1.2387(13) 1.0623(18) 0.048(3) 0.042(2) H351 12i 1.1602(19) 0.9557(17) 0.049(3) 0.055(2) H352 12i 1.0961(12) 0.9324(13) 0.128(4) 0.055(2) H361 6h 1.130(3) 1.0777(18) 0.25 0.094(2) H362 6h 1.0779(13) 1.005(2) 0.25 0.094(2) H371 12i 1.2544(12) 0.9893(13) 0.3313(15) 0.0620(14)
PbBr Bonds in [(CH.sub.2).sub.6N.sub.4].sub.3Pb.sub.2Br.sub.7

(67) TABLE-US-00003 Bond Distance () Pb1Br1 2.868 Pb1Br2 3.138 Pb1Br3 2.985 Pb1Br4 3.150 Pb2Br2 3.018 Pb2Br3 3.032 Pb2Br4 3.138 Pb2Br5 2.921

(68) 2. Powder X-Ray Diffraction (PXRD)

(69) The PXRD analysis was performed on Panalytical X'PERT Pro Powder X-Ray Diffractometer using Copper X-ray tube (standard) radiation at a voltage of 40 kV and 40 mA, and X'Celerator RTMS detector. The diffraction pattern was scanned over the angular range of 5-50 degree (2) with a step size of 0.02, at room temperature. Simulated powder patterns were calculated by Mercury software using the crystallographic information file (CIF) from single-crystal x-ray experiment.

(70) FIG. 3 depicts PXRD data of the (HTMA).sub.3Pb.sub.2Br.sub.7 bulk quantum material of this example, as well as its simulated results. The powder X-ray diffraction (PXRD) pattern of the ball-milled sample was identical with the simulated PXRD pattern from the single crystal structure, which confirmed the SCXRD results.

(71) 3. Absorption Spectrum Measurements

(72) Absorption spectra of bulk quantum materials were measured at room temperature through synchronous scan in an integrating sphere incorporated into the spectrofluorometer (FLS980, Edinburgh Instruments) while maintaining a 1 nm interval between the excitation and emission monochromators.

(73) 4. Excitation Spectrum Measurements

(74) Excitation spectra of bulk quantum materials were measured at room temperature on a FLS980 spectrofluorometer (Edinburgh Instruments) monitored at maximum of emission spectra.

(75) 5. Photoluminescence Steady State Studies

(76) Steady-state photoluminescence spectra of bulk quantum materials were obtained at room temperature and 77 K (liquid nitrogen was used to cool the samples) on a FLS980 spectrofluorometer.

(77) 6. Photoluminescence Quantum Efficiencies (PLQEs)

(78) For photoluminescence quantum efficiency measurements, the samples were excited using light output from a housed 450 W Xe lamp passed through a single grating (1800 l/mm, 250 nm blaze) Czerny-Turner monochromator and finally a 5 nm bandwidth slit. Emission from the sample was passed through a single grating (1800 l/mm, 500 nm blaze) Czerny-Turner monochromator (5 nm bandwidth) and detected by a Peltier-cooled Hamamatsu R928 photomultiplier tube. The absolute quantum efficiencies were acquired using an integrating sphere incorporated into the FLS980 spectrofluorometer.

(79) The PLQE was calculated by the equation: .sub.QE=I.sub.S/(E.sub.RE.sub.S), in which I.sub.S represents the luminescence emission spectrum of the sample, E.sub.R is the spectrum of the excitation light from the empty integrated sphere (without the sample), and E.sub.S is the excitation spectrum for exciting the sample. Control samples, rhodamine 101 and blue phosphor BaMgAl.sub.10O.sub.17:Eu.sup.2+, were measured using this method to give PLQEs of 98% and 93%, which were near the literature reported values. The PLQEs were double confirmed by a Hamamatsu C9920 system equipped with a xenon lamp, calibrated integrating sphere and model C10027 photonic multi-channel analyzer (PMA). The measurements took account of indirect PL provided the same results within the error bars.

(80) 7. Time-Resolved Photoluminescence

(81) Time-Resolved Emission data were collected at room temperature and 77 K (liquid nitrogen was used to cool the samples) using time-correlated single photon counting on a Horiba JY Fluoromax-4 Fluorometer. Samples were excited with 365 nm pulsed diode lasers. Emission counts were monitored at 580 nm at room temperature and at 420, 480, 625 nm separately at 77K. The average lifetime was obtained by multiexponential fitting.

(82) 8. Materials Photostability Study

(83) To test the photostability, a 100 W 20 V mercury short arc lamp was used as a continuous irradiation light source. The intensity of the irradiation was calibrated to 150 mW/cm.sup.2. The emission was measured perodically on a HORIBA iHR320 spectrofluorimeter, equipped with a HORIBA Synapse CCD detection system. The results are depicted at FIG. 4.

(84) The (HMTA).sub.3Pb.sub.2Br.sub.7 single crystals were observed and photographed under ambient light and UV light (365 nm). The colorless crystals emitted yellowish-white light or warm white under UV excitation with a reasonably good photostability, which suggested below-gap broadband emission with large Stokes shift.

(85) FIG. 5 depicts excitation (dash lines) and emission (solid lines, excited at 380 nm) spectra collected for the (HMTA).sub.3Pb.sub.2Br.sub.7 crystals at room temperature. As shown at FIG. 5, (HMTA).sub.3Pb.sub.2Br.sub.7 was excited by UV light from 250 to 400 nm, and produced a broad emission peaked at 580 nm that covered a wide range of the spectrum from 450 to 750 nm, with a large FWHM of 158 nm.

(86) The Comission Internationale de l'Eclairage (CIE) chromaticity coordinates for this yellowish-white emission were calculated to be (0.42, 0.45), which represented a significant red-shift, as compared to the bluish-white emission from the bulk assembly of 1D lead bromide nanowires (C.sub.4N.sub.2H.sub.14PbBr.sub.4) (Z. Yuan, et al., Nat. Commun. 2017, 8, 14051).

(87) FIG. 6 depicts the emission decay of the (HMTA).sub.3Pb.sub.2Br.sub.7 crystals (measured at 580 nm) and fitting at room temperature. The emission decay was characterized by time-resolved photoluminescence spectroscopy. As depicted at FIG. 6, a multiple-exponential fitting of the intensity-time curve gave an average lifetime of approximately 127 ns. Such a strongly Stokes shifted broadband emission with relatively long lifetime was similar to what has been observed in corrugated-2D and 1D metal halide perovskites (see, e.g., Z. Yuan, et al., Nat. Commun. 2017, 8, 14051).

(88) It was therefore reasonable to attribute this non-Gaussian shaped broadband emission to the self-trapped excited states with multiple energy minimums, which were in thermally activated equilibrium at room temperature. Unlike emissions from both free exciton and self-trapped excited states in bulk assembly of metal halide nanowires (C.sub.4N.sub.2H.sub.14PbBr.sub.4), only self-trapped emissions were recorded in (HMTA).sub.3Pb.sub.2Br.sub.7, which suggested the absence of delocalized excitonic states due to the ultrafast exciton self-trapping in (HMTA).sub.3Pb.sub.2Br.sub.7 at room temperature.

(89) The electron coupling and molecular orbital interaction between the metal halide dimers via corner-sharing in 1D nanotubes likely were much weaker than those between 1D edge sharing metal halide octahedral nanowires. Therefore, the reduced conjugation in metal halide nanotubes likely produced more localized electronic states with stronger electron-phonon coupling, which favored the formation of self-trapped excitons.

(90) To further confirm the origin of broadband emission from self-trapped excited states, the photophysical properties of the (HMTA).sub.3Pb.sub.2Br.sub.7 crystals at 77 K were characterized, where thermally activated equilibrium was likely suspended. FIG. 7 depicts the emission spectra with three bands peaked at 420 nm, 480 nm and 625 nm.

(91) FIG. 8 depicts the emission decays of the different emission peaks at 77 K and fittings for each curve. As depicted at FIG. 8, these emissions had different decay lifetimes, which were estimated to be 6.5 s, 3.9 s and 1.9 s from short wavelength to long wavelength, respectively. Such distinct emission bands with different lifetimes at 77 K likely indicated multiple excited states generated upon photoexcitation, and were consistent with the inherent properties of exciton self-trapping in metal halide perovskites.

(92) Therefore, the photoluminescence mechanism for this bulk assembly of metal halide nanotubes can be depicted by the configuration coordinate diagram of FIG. 9. Upon UV excitation, the lead bromide nanotubes are excited to the high energy excited states, which undergo ultrafast exciton self-trapping with the formation of multiple excited states that give strongly Stokes shifted broadband photoluminescence at room temperature due to thermally activated equilibrium, and multiple emission bands at 77 K without thermally activated equilibrium. The observation of multiple exciton emission with strong temperature dependence resembles the emission of ns.sup.2 ions in alkali halides (P. W. M. Jacobs, J. Phys. Chem. Solids 1991, 52, 35-67).

(93) 9. Thermogravimetry Analysis (TGA)

(94) TGA was carried out using a TA instruments SDT: simultaneous DSC & TGA system of Q600 model. The samples were heated from room temperature (around 22 C.) to 800 C. at a rate of 10 C..Math.min.sup.1, under an argon flux of 100 mL.Math.min.sup.1.

(95) The hybrid material exhibited moderate thermal stability without decomposition up to around 155 C. in the TGA analysis.

(96) 10. Calculations

(97) Density functional theory (DFT) calculations were performed.

(98) The calculated band structure of (HTMA).sub.3Pb.sub.2Br.sub.7 (FIG. 10) showed a direct band gap at the point.

(99) The calculated band gap was 2.37 eV at the Perdew-Burke-Ernzerh (PBE) level, which was expected to be underestimated due to the well-known band gap error of DFT. The conduction and the valence bands were flat on the plane perpendicular to the axis of the Pb.sub.2Br.sub.7 tube, indicating negligible inter-tubular interaction. Along the axis of the tube, the band dispersion was still small, reflecting the weakened PbBr hybridization, likely due to the distortion of the PbBr.sub.6 octahedral structure.

(100) The narrow bands near band edges and the soft lattice of (HTMA).sub.3Pb.sub.2Br.sub.7 should favor the charge localization and the formation of self-trapped excitons, consistent with the absence of free exciton emission at room temperature. The top of the valence band had significant Pb-6s character while the bottom of the conduction band was dominated by Pb-6p states, as shown by the projected DOS in FIG. 11. Thus, excitons should be localized on Pb.sup.2+ ions and the emission was likely due to the Pb 6p-6s transition.

(101) The calculations were based on density functional theory (DFT) implemented in the plane-wave basis VASP code (G. Kresse, J. Furthmller, Comput. Mater. Sci., 1996, 6, 15-50). The projector augmented wave method was used to describe the interaction between ions and electrons (G. Kresse, D. Joubert, Phys. Rev. B 1999, 59, 1758). Experimental lattice constants of hexagonal (HTMA).sub.3Pb.sub.2Br.sub.7 were used: a=24.5206 and c=9.7661 . Since the positions of the protons bonded to the HTMA molecules were not resolved experimentally, the organic cations were replaced by a uniform positive charge background such that the simulation cell was charge neutral.

(102) This approximation did not affect the electronic structure near the valence and the conduction band edges because the electronic states derived from the organic molecules were far from the band gap (M. H. Du, J. Mater. Chem. A 2014, 2, 9091-9098; and T. Umebayashi, K. Asai, T. Kondo, A. Nakao, Phys. Rev. B 2003, 67, 155405). The kinetic energy cutoff of 216 eV and the 112 reciprocal space k-point mesh were used. The atomic positions were fully relaxed until the residual forces were less than 0.02 eV/. The band structure and the density of states (DOS) were calculated using the Perdew-Burke-Ernzerh (PBE) exchange-correlation functional (J. P. Perdew, K. Burke, M. Ernzerhof, Phys. Rev. Lett. 1996, 77, 3865). The spin-orbit coupling (SOC) was included in the calculations.