Laminate for use in core

Abstract

Provided is a laminate having a reduced loss ratio while maintaining a high space factor. The present disclosure relates to a laminate for use in a core, comprising: a strip laminate composed of soft magnetic metal strips; and an insulating layer provided on a surface of the strip laminate, wherein each one layer of the soft magnetic metal strips has a thickness of 100 m or less, each one layer of the soft magnetic metal strips has an oxide film on their surfaces, the strip laminate is composed of at least two layers of the soft magnetic metal strip, and the strip laminate and the insulating layer are alternately disposed.

Claims

1. A laminate for use in a core, comprising: at least one strip laminate composed of soft magnetic metal strips; and at least one insulating layer provided on a surface of the strip laminate, wherein: each one layer of the soft magnetic metal strips has a thickness of 100 m or less, each one layer of the soft magnetic metal strips has an oxide film on surfaces thereof, the oxide film having a thickness in the range of from 30 nm to 100 nm, the strip laminate is composed of at least two layers of the soft magnetic metal strip, and the strip laminate and the insulating layer are alternately disposed.

2. The laminate according to claim 1, wherein each one layer of the soft magnetic metal strips has a thickness of 10 m to 100 m, and the strip laminate is composed of 2 layers to 20 layers of the soft magnetic metal strip.

3. The laminate according to claim 1, wherein each one layer of the insulating layers has a resistance value in the range of from 1000 .Math.m to 5000 .Math.m.

4. The laminate according to claim 2, wherein each one layer of the insulating layers has a resistance value in the range of from 1000 .Math.m to 5000 .Math.m.

5. A core comprising the laminate according to claim 1.

6. The laminate according to claim 1, wherein the oxide film consists of ferrite with a hematite crystal structure.

7. The laminate according to claim 1, wherein each one layer of the soft magnetic metal strips comprises Cobalt (Co) in an amount of 80 at % or more based on the total number of atoms of all elements in the soft magnetic metal strip.

8. The laminate according to claim 1, wherein each one layer of the insulating layers has a thickness of 1 m or less.

9. The laminate according to claim 3, wherein each one layer of the insulating layers has a thickness of 1 m or less.

10. A laminate for use in a core, comprising: at least one strip laminate composed of soft magnetic metal strips; and at least one insulating layer provided on a surface of the strip laminate, the insulating layer having a thickness of 1 m or less, wherein: each one layer of the soft magnetic metal strips has a thickness of 100 m or less, each one layer of the soft magnetic metal strips has an oxide film on surfaces thereof, each one layer of the insulating layers has a thickness of 1 m or less, the strip laminate is composed of at least two layers of the soft magnetic metal strip, and the strip laminate and the insulating layer are alternately disposed.

11. The laminate according to claim 10, wherein each one layer of the insulating layers has a resistance value in the range of from 1000 .Math.m to 5000 .Math.m.

12. A laminate for use in a core, comprising: at least one strip laminate composed of soft magnetic metal strips; and at least one insulating layer provided on a surface of the strip laminate, wherein: each one layer of the soft magnetic metal strips has a thickness of 100 m or less, each one layer of the soft magnetic metal strips has an oxide film on surfaces thereof, each one layer of the insulating layers has a resistance value in the range of from 1000 .Math.m to 5000 .Math.m, the strip laminate is composed of at least two layers of the soft magnetic metal strip, and the strip laminate and the insulating layer are alternately disposed.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) FIG. 1 shows one example of the laminate structure of the laminate of the present disclosure;

(2) FIG. 2 shows the loss ratios of Comparative Examples 1 to 3 and Examples 1 to 4; and

(3) FIG. 3 Shows the space factors of Comparative Examples 1 to 3 and Examples 1 to 4.

DETAILED DESCRIPTION OF THE EMBODIMENTS

(4) Below, some embodiments of the present disclosure will now be described in detail.

(5) Herein, features of the present disclosure are described in reference to the drawings as appropriate. In the drawings, emphasis is placed on the sizes and shapes of the components for clarity, and the drawings do not accurately represent the actual sizes and shapes. Accordingly, the technical scope of the present disclosure is not limited to the sizes and shapes of the components shown in the drawings. The laminate of the present disclosure is not limited to the following embodiments, and can be practiced in variously altered or modified forms as can be done by those skilled in the art without departing from the gist of the present disclosure.

(6) The present disclosure relates to a laminate for use in core, comprising:

(7) at least one strip laminate composed of soft magnetic metal strips; and

(8) at least one insulating layer provided on a surface of the strip laminate,

(9) wherein

(10) each one layer of the soft magnetic metal strips has a thickness within a specific range,

(11) each one layer of the soft magnetic metal strips has an oxide film on surfaces thereof,

(12) the strip laminate is composed of a plurality of layers of the soft magnetic metal strip, and

(13) the strip laminate and the insulating layer are alternately disposed.

(14) In the present disclosure, the soft magnetic metal strip refers to a ribbon of a metal, the magnetic polarity of which is inverted with comparative ease (generally the coercivity is 800 A/m or less).

(15) Each one layer one piece) of the soft magnetic metal strips in the present disclosure has a thickness of 100 m or less, 10 m to 100 m in some embodiments, and 20 m to 50 m in some other embodiments. A thin soft magnetic metal strip having such a thickness is also referred to as a soft magnetic foil in the specification and the like.

(16) Due to the soft magnetic metal strip being a soft magnetic foil having a thickness within the above range, the motor loss can be reduced in a laminated motor core produced with the laminate of the present disclosure.

(17) A soft magnetic foil heretofore known in the art is usable as a soft magnetic foil, and examples include soft magnetic foils composed of iron (Fe) and/or cobalt (Co) as a base metal and at least one element selected from the group consisting of boron (B), silicon (Si), phosphorus (P), copper (Cu), zirconium (Zr) and niobium (Nb), as an alloying element.

(18) In the soft magnetic foil, the amount of Fe and/or Co is usually 80 at % or more, and 80 at % to 90 at % in some embodiments, based on the total number of atoms of all elements in the soft magnetic foil.

(19) In the soft magnetic foil, the amount of alloying element is usually 20 at % or less, and 10 at % to 20 at % in some embodiments, based on the total number of atoms of all elements in the soft magnetic foil.

(20) The soft magnetic foil of the present disclosure has an oxide film on the surface.

(21) The thickness of the oxide film is usually about 1/1000 of the soft magnetic foil, i.e., about 100 nm or less, 30 nm to 80 nm in some embodiments, and 30 nm to 50 nm in other embodiments.

(22) The oxide film is ferrite and has the same crystal structure as hematite (Fe.sub.2O.sub.3). The crystal structure of the oxide film can be verified by, for example, thin-film X-ray diffraction.

(23) In the present disclosure, the soft magnetic foil has an oxide film on the surface, and thus an insulating layer does not have to be disposed between every two soft magnetic foils, and is disposed for every strip laminate composed of a plurality of layers of the soft magnetic foil, which will be described below. Accordingly, a loss ratio can be reduced while maintaining a high space factor. It is presumed that this effect is provided by the oxide film that has insulating action to prevent electrical conduction between the soft magnetic foils when the soft magnetic foils are laminated, but the present disclosure is not limited to this presumption.

(24) The soft magnetic foil of the present disclosure can be produced by a method heretofore known in the art and, for example, can be produced by a single-roll liquid quenching method. In the single-roll liquid quenching method, the soft magnetic foil can be produced, for example, with a liquid quenching-solidifying apparatus NAV-A3 manufactured by Nissin Giken Corporation by bringing the melting chamber into a high vacuum state, then purging the melting chamber with argon gas, subjecting the mother alloy in the nozzle to high-frequency melting to form a molten alloy, and after a predetermined temperature is reached, promptly discharging the alloy onto the suffice of a rapidly rotating copper roll from the nozzle opening. As for the single-roll liquid quenching method, see, for example, Keiyu Nakagawa et. al., The Effect of the Jetting Temperature on the Fabrication of Rapidly Solidified FeSiB Systems Alloys Using Single Roller Melt Spinning, J. Japan Inst. Met. Mater., Vol. 73, No. 10 (2009), pp. 764-767. The surface of a soft magnetic foil produced in this manner has the aforementioned oxide film.

(25) In the present disclosure, the strip laminate is a laminate composed of at least two layers, 2 layers to 20 layers in some embodiments, and 5 layers to 10 layers in some other embodiments, of the soft magnetic foil.

(26) Accordingly the overall thickness of the strip laminate is usually 20 to 700 m, 50 m to 500 m in some embodiments, and 100 m to 300 m in some other embodiments.

(27) In the present disclosure, the insulating layer is a layer formed of an insulator, and an insulator heretofore known in the art is usable in the insulating layer. The insulating layer contains, but is not limited to, a thermosetting epoxy resin, an alkyd resin, a polyimide resin, a polyamide-imide resin, or an imide-modified acrylic resin. The insulating layer may further contain an inorganic filler.

(28) The resistance value of the insulating layer in the present disclosure is usually 1000 .Math.m or more, and 1000 .Math.m to 5000 .Math.m in some embodiments. The thickness of the insulating layer is not limited, and is usually set such that the insulating layer has the above resistance value.

(29) In the laminate of the present disclosure, the insulating layer is disposed on the surface of the strip laminate, and the strip laminate and the insulating layer are alternately disposed. Accordingly, the insulating layer is disposed between the strip laminates.

(30) FIG. 1 shows one example of the laminate structure of the laminate of the present disclosure. In the laminate of the present disclosure shown in FIG. 1, a first strip laminate formed by laminating five layers of a soft magnetic foil 1 is laminated on a first insulating layer 2, a second insulating layer 2 is laminated on the upper surface of the first strip laminate, a second strip laminate formed by laminating five layers of the soft magnetic foil 1 is formed on the second insulating layer 2, a third insulating layer 2 is laminated on the upper surface of the second strip laminate, a third strip laminate formed by laminating five layers of the soft magnetic foil 1 is formed on the third insulating layer 2, and a fourth insulating layer 2 is laminated on the upper surface of the third strip laminate.

(31) In the laminate of the present disclosure, one insulating layer is disposed for every strip laminate that is formed of a plurality of layers of a soft magnetic and thus the volume fraction of the insulating layer in the laminate can be smaller than that of a conventional laminate having one insulating layer for every layer of a soft magnetic metal strip, and the performance, such as magnetic properties, per unit volume of the laminate can be improved.

(32) The laminate of the present disclosure can be used in a core such as a reactor core or a transformer core in addition to a motor core or a stator core.

(33) The laminate of the present disclosure can be produced by a lamination method heretofore known in the art.

(34) For example, the laminate of the present disclosure can be formed by alternately laminating the insulating layer and the strip laminate that is formed by laminating the aforementioned number of layers of a soft magnetic foil. That is to say, the laminate of the present disclosure can be produced by, first, laminating the aforementioned number of layers of a soft magnetic foil to form a first strip laminate, next forming a first insulating layer on the surface of the first strip laminate, further laminating the aforementioned number of layers of a soft magnetic foil on the surface of the first insulating layer to form a second strip laminate, then forming a second insulating layer on the surface of the second strip laminate, and further repeating the above steps until the desired laminate thickness is attained.

EXAMPLES

(35) Below, the present disclosure will now be described by way of several examples, but the examples are not intended to limit the present disclosure.

(36) Laminates were prepared in the following Comparative Examples 1 to 3 and Examples 1 to 4. The soft magnetic foil used when preparing the laminates of Comparative Examples 1 and 2 and Examples 1 to 4 was a quenched foil that was prepared by a quenching method and contained Fe in a proportion of 80 at % or more. The soft magnetic foil had a thickness of 25 m, and a thickness of an oxide film as determined from a TEM image was about 50 nm.

Comparative Example 1

(37) A laminate having a thickness of about 26 m was prepared by laminating one layer of the soft magnetic foil and one insulating layer (1 m, an insulation resistance value of 1000 .Math.m).

Comparative Example 2

(38) A laminate having a thickness of about 751 m was prepared by laminating 30 layers of the soft magnetic foil and one insulating layer (1 m, an insulation resistance value of 1000 .Math.m).

Comparative Example 3

(39) A laminate having a thickness of about 251 m was prepared by laminating one electromagnetic steel sheet (250 m, 3% silicon-Fe, provided with an oxide film, prepared by rolling) and one insulating layer (1 m, an insulation resistance value of 1000 .Math.m).

Example 1

(40) A laminate having a thickness of about 51 m was prepared by laminating two layers of the soft magnetic foil and one insulating layer (1 m, an insulation resistance value of 1000 .Math.m).

Example 2

(41) A laminate having a thickness of about 126 m was prepared by laminating five layers of the soft magnetic foil and one insulating layer (1 m, an insulation resistance value of 1000 .Math.m).

Example 3

(42) A laminate having a thickness of about 251 m was prepared by laminating ten layers of the soft magnetic foil and one insulating layer (1 m, an insulation resistance value of 1000 .Math.m).

Example 4

(43) A laminate having a thickness of about 501 m was prepared by laminating twenty layers of the soft magnetic foil and one insulating layer (1 m, an insulation resistance value of 1000 .Math.m).

(44) The loss ratios and the space factors of the laminates prepared in Comparative Examples 1 to 3 and Examples 1 to 4 were measured.

(45) The loss ratio was measured by a method involving sandwiching a laminate between excitation cores, applying compressive stress in the lamination direction of the laminate, measuring magnetic flux density B and magnetic field strength H, and calculating the area of the BH locus.

(46) The space factor was calculated according to the following formula:
Space factor=((Thickness of soft magnetic foil or electromagnetic steel sheetNumber of laminated layers)/(Thickness of laminate)100

(47) FIG. 2 shows the loss ratios of Comparative Examples 1 to 3 and Examples 1 to 4. The loss ratios in FIG. 2 are relative values with the loss ratio of Comparative Example 1 being 100%. In the bar chart of FIG. 2, Comparative Examples 1 and 2 and Examples 1 to 4 are arranged from the left according to the number of layers of the soft magnetic foil between an insulating layer and an insulating layer, i.e., so that the number of layers of the soft magnetic foil in the strip laminate is increased, and the result of Comparative Example 3 which is a conventional laminate product prepared by alternately laminating an electromagnetic steel sheet and an insulating layer is shown on the far right. From FIG. 2, it was found that the loss ratio tended to be exponentially increased as the number of layers of the soft magnetic foil in the strip laminate was increased. It was found that when the number of layers of the soft magnetic foil in the strip laminate was 20 or smaller, the loss ratio was smaller than that of Comparative Example 3 which was a conventional product.

(48) FIG. 3 shows the space factors of Comparative Examples 1 to 3 and Examples 1 to 4. In the bar chart of FIG. 3, Comparative Examples 1 and 2 and Examples 1 to 4 are arranged from the left according to the number of layers of the soft magnetic foil between an insulating layer and an insulating layer, i.e., so that the number of layers of the soft magnetic foil in the strip laminate is increased, and the result of Comparative Example 3 which is a conventional laminate product prepared by alternately laminating an electromagnetic steel sheet and an insulating layer is shown on the far right. From FIG. 3, it was found that the space factor tended to be increased as the number of layers of the soft magnetic foil in the strip laminate was increased. It was found that the space factor exceeded 95% when the number of layers of the soft magnetic foil in the strip laminate was two, in particular the space factor exceeded 98% when the number of layers of the soft magnetic foil in the strip laminate was five, and the space factor is nearly 100% when the number of layers of the soft magnetic foil in the strip laminate was five or greater.

(49) In general, a motor is required to exert a reduced loss and an increased space factor. Since the soft magnetic foil used in the present disclosure is extremely thin, the properties of the laminate greatly vary depending on how the insulating layers are disposed. According to the present disclosure, it was found that in a laminate of soft magnetic strips, the low loss and the high space factor of the laminate can be simultaneously achieved by using at least two layers, 2 to 20 layers in some embodiments, and 5 to 10 layers in some other embodiments, of the soft magnetic foil having a thickness of 25 m.

(50) All publications, patents and patent applications cited in the present description are herein incorporated by reference as they are.

DESCRIPTION OF SYMBOLS

(51) 1 Thin soft magnetic metal strip (soft magnetic foil) 2 Insulating layer