MOLECULAR BOTTOM-UP METHODS FOR FABRICATING PEROVSKITE SOLAR CELLS, PEROVSKITE MATERIALS FABRICATED THEREOF, AND OPTOELECTRONIC DEVICES INCLUDING SAME

Abstract

Disclosed is a building blocks method for low-cost fabrication of single crystal organometallic perovskite materials with pseudo crystallized hole transporting material layer. This method uses self-assembled molecular monolayers SAM as building blocks. This approach enables creation of defect-free perovskite crystals with desired morphology and crystallinity in a controlled way. Additionally, the crosslinked molecular layers SAM play a role of hole transporting materials HTM and encapsulation against diffusion of metal atoms and gas molecules, thus enhancing the stability of the perovskite materials. This method is cost effective and can be scaled up.

Claims

1. A method for fabricating a perovskite device, the method comprising: providing a metal substrate; forming a self-assembled molecular monolayer on top of the metal substrate; and forming the perovskite material on top of the self-assembled molecular monolayer.

2. The method of claim 1, wherein forming the self-assembled molecular monolayer comprises immersing the metal substrate in a first solution comprising self-assembly molecules.

3. The method of claim 2, wherein the self-assembly molecules are terminated with one or both of sulfur and ammonia.

4. The method of claim 2, wherein the first solution comprises n-hexane or ethanol with one or both of thiol- and amine-end groups.

5. The method of claim 1 comprising exposing the metal substrate to electron or UV radiation to crosslink the self-assembly molecules.

6. The method of claim 2, wherein forming the perovskite material comprises immersing the metal substrate with the self-assembled molecular monolayer in a second solution comprising a first metal halide to form a single metal-halide layer as a perovskite active layer on top of the self-assembled molecular monolayer, the first metal halide comprising a metal selected from the group consisting of lead (Pb), tin (Sn), bismuth (Bi), antimony (Sb), germanium (Ge), and combinations thereof, and the first metal halide further comprising a halogen selected from the group consisting of Cl, Br, I, and combinations thereof.

7. The method of claim 6, wherein the self-assembly molecules are terminated with one or both of sulfur and ammonia, and the one or both of sulfur and ammonia interact with halide ions in the second solution to form uniform single metal-halide layer.

8. The method of claim 6 further comprising immersing the substrate with the single metal-halide layer on top of the self-assembled molecular monolayer in a third solution comprising a second metal halide and methyl ammonium iodide (MAI) to grow the perovskite material on top of the self-assembled molecular monolayer, the second metal halide comprising a metal selected from the group consisting of lead (Pb), tin (Sn), bismuth (Bi), antimony (Sb), germanium (Ge), and combinations thereof, and the second metal halide further comprising a halogen selected from the group consisting of Cl, Br, I, and combinations thereof.

9. The method of claim 1, wherein the substrate comprises a material selected from the group consisting of gold, silver, copper, platinum, zinc, nickel, graphene, iron, carbon-nanotube, aluminum, and combinations thereof.

10. The method of claim 1 comprising annealing the metal substrate using a butane/propane flame or an oven with intermediate cooling under N.sub.2.

11. A perovskite device comprising: a metal substrate; a self-assembled molecular monolayer on top of the metal substrate; a perovskite material on top of the self-assembled molecular monolayer; and an electron-collector electrode deposited on top of the perovskite material.

12. The perovskite device of claim 11, wherein the self-assembled molecular monolayer comprises crosslinked self-assembly molecules terminated with one or both of sulfur and ammonia.

13. The perovskite device of claim 11, wherein the perovskite film comprises a single-crystal layer of MAPbX, where X is Cl, Br, or I.

14. The perovskite device of claim 11, wherein the substrate comprises a material selected from the group consisting of gold, silver, copper, platinum, zinc, nickel, graphene, iron, carbon-nanotube, aluminum, and combinations thereof.

15. A method of manufacturing a solar cell, the method comprising: providing a metal substrate; forming a self-assembled molecular monolayer on top of the metal substrate; forming the perovskite material on top of the self-assembled molecular monolayer; and depositing an electron-collector electrode on top of the perovskite material.

16. The method of claim 15, wherein forming the self-assembled molecular monolayer comprises immersing the metal substrate in a first solution comprising self-assembly molecules.

17. The method of claim 15, wherein the self-assembly molecules are terminated with one or both of sulfur and ammonia.

18. The method of claim 16, wherein the first solution comprises n-hexane or ethanol with one or both of thiol- and amine-end groups.

19. The method of claim 16 further comprising exposing the metal substrate with the self-assembled molecular monolayer to electron or UV radiation to crosslink the self-assembly molecules and form a stable hole transporting materials layer (HTM).

20. The method of claim 15, wherein forming the perovskite material comprises immersing the metal substrate with the self-assembled molecular monolayer in a second solution comprising a metal halide to form a single metal-halide layer as a perovskite active layer on top of the self-assembled molecular monolayer, the metal halide comprising a metal selected from the group consisting of lead (Pb), tin (Sn), bismuth (Bi), antimony (Sb), germanium (Ge), and combinations thereof, and the metal halide further comprising a halogen selected from the group consisting of Cl, Br, I, and combinations thereof.

21. The method of claim 15, wherein the electron-collector electrode includes TiO.sub.2 or Al.sub.2O.sub.3.

Description

BRIEF DESCRIPTION OF DRAWINGS

[0007] Features and advantages of the methods for fabricating perovskite materials, the perovskite materials fabricated thereof, and optoelectronic devices including same described herein may be better understood by reference to the accompanying figures in which:

[0008] FIGS. 1(a)-1(b) illustrate the process of creating a SAM of one or both of thiol- and amine-group molecules on a gold substrate. FIG. 1(a) shows a substrate immersed in a solution containing n-hexane molecules with one or both of thiol- and amine-end groups. FIG. 1(b) shows a SAM formed on the surface of the substrate through the interaction between the thiol- or amine-end groups and the surface of the substrate.

[0009] FIGS. 2(a)-2(b) illustrate the formation of a PbI layer on top of the SAM after immersing the sample in the solution with PbX.sub.2. FIG. 2(a) shows the substrate with SAM formed in FIG. 1(b) immersed in a solution of PbX.sub.2, where X is one or more of Cl, Br, and I. FIG. 2(b) shows a single layer of uniform lead-halide crystallization on top of the SAM.

[0010] FIGS. 3(a)-3(b) illustrate the formation of perovskite monocrystals. FIG. 3(a) shows the resultant sample from FIG. 2(b) immersed in a solution containing PbX.sub.2 and methyl ammonium iodide (MAI). FIG. 3(b) shows a halide perovskite material grown on the surface of the SAM.

[0011] FIGS. 4(a)-4(d) illustrate the molecular building-block fabrication process for a single-crystal metal-halide perovskite device. FIG. 4(a) shows a SAM on gold substrate as formed in FIGS. 1(a)-1(b). FIG. 4(b) shows deposition of PbX.sub.3 layer as illustrated in FIGS. 2(a)-2(b). FIG. 4(c) shows deposition of MAPbX.sub.3 as illustrated in FIGS. 3(a)-3(b). FIG. 4(d) shows deposition of a top electrode as illustrated in FIGS. 4(a)-4(d).

[0012] FIG. 5 is a cross section side view illustrating an embodiment of a semiconductor device.

[0013] The reader will appreciate the foregoing details, as well as others, upon considering the following detailed description of certain non-limiting embodiments of the present technology including methods for fabricating perovskite materials, the perovskite materials fabricated thereof, and optoelectronic devices including same according to the present disclosure.

DETAILED DESCRIPTION

[0014] The present disclosure relates to a cost-effective method of fabricating defect-free, single crystal perovskite materials for applications in photovoltaics and other optoelectronic devices, for example, light-emitting diodes. The disclosed method can be used to fabricate hole transporting materials (HTMs) made from metal-halide perovskite materials. The perovskite materials and the HTMs fabricated by the present method have high crystallinity and desired morphology. The present method uses a molecular building blocks approach. The metal-halide perovskite material fabricated by the present method can have a single crystal structure.

[0015] The crystal structure is very important for the stability of a perovskite material, as detailed in M. I. Saidaminov, A. L. Abdelhady, B. Murali, E. Alarousu, V. M. Burlakov, W. Peng, I. Dursun, L. Wang, Y. He, G. Maculan, A. Goriely, T. Wu, O. F. Mohammed, and O. M. Bakr, Nature Communications 6, 7586 (2015). However, their method of creating perovskite single crystals suffer from scalability and thus difficult for large scale applications (e.g. solar cells).

[0016] The present method is advantageous over the conventional methods of making perovskite materials. For example, the present method is low cost and scalable. Large single-crystal metal-halide perovskites can be synthesized with phase purity and macroscopic dimensions on top of a metallic substrate. A self-assembled molecular monolayer (SAM) can replace the conventional, expensive and unstable organic hole transport materials (HTM), such as spiro-OMeTAD. The SAM can also prevent the penetration of metal atoms and gas molecules to the perovskite material.

[0017] Compared to existing perovskite solar cells, the perovskite solar cells including the perovskite materials fabricated by the present method have higher mechanical and operational stability, durability, and solar conversion efficiency. Further, these solar cells are cost effective as compared to conventional perovskite solar cells and silicon-based solar cells.

[0018] In the present method, highly ordered molecular SAMs are used to trigger and immobilize a single-crystal perovskite material on a substrate. The SAMs can serve as the HTM layer for applications in solar cells. As described in the following non-limiting examples, a solution-based approaches can be used to grow the perovskite material on top of the SAM formed on the surface of the substrate. However, other approaches can also be used. For example, evaporation-based approaches can also be used to grow the perovskite materials.

[0019] The present method is illustrated in the figures and described below.

[0020] According to some non-limiting aspects of the present disclosure, SAMs can be used for immobilizing and triggering uniform growth of a perovskite material on the surface of a metallic substrate. As shown in FIG. 1(a), self-assembly of molecular monolayers can be performed on a metallic substrate 1. The substrate 1 can be made of gold, silver, zinc, copper, platinum, nickel, iron, or aluminum. The SAM 2 can play the role of HTM. The molecules used for SAM 2 can be terminated by one or both of sulfur and amine end groups, which can result in a good contact of the SAMs with the substrate 1. For example, this stage can be performed using the process described in H. Hamoudi, Z. Guo, M. Prato, C. Dablemont, W. Q. Zheng, B. Bourguignon, M. Canepad and V. A. Esaulov, On the self-assembly of short chain alkanedithiols, Phys. Chem. Chem. Phys. 10, 6836-6841 (2008), which is fully incorporated herein by reference.

[0021] The substrate 1 can be first annealed using a butane/propane flame or in oven in temperature between 300 C. and 500 C. with intermediate cooling under N.sub.2. The resulting substrate can be immersed into an organic solution from 1 h to 24 h. For example, as shown in FIG. 1(a), a solution containing n-hexane or ethanol molecules with one or both of thiol- and amine-end groups 3 can be used. As depicted in FIG. 1(b), highly ordered SAM 2 can form on the surface of the substrate 1 with the free-standing end groups that can be one or both of sulfur and ammonium. The SAM 2 can form the hole transport (HTM) layer used in solar cells. After the immobilization of the SAM 2, the sample can be exposed to electron or UV radiation to crosslink the molecules to form a stable HTM layer.

[0022] The molecules used for SAMs can serve as the HTM after the crosslinking processes, which play a crucial role in solar energy harvesting using perovskite solar cells. The HTM formed using the present method can be much cheaper and more stable than the conventional HTM materials such as Spiro-OMeTAD.

[0023] As shown in FIG. 2(a), the substrate with SAM formed as described above can be immersed into a solution of a metal halide. The metal can be lead, non-lead, or lead-free. The metal can be selected from the group consisting of lead (Pb), tin (Sn), bismuth (Bi), antimony (Sb), germanium (Ge), and combinations thereof. For example, the metal halide can be PbX.sub.2, where X is one or more of Cl, Br, and I. The metal halide can also be a low-toxicity lead-free (Pb-free) metal halide, where the metal can be selected from the group consisting of tin (Sn), bismuth (Bi), antimony (Sb), germanium (Ge), and combinations thereof. Due to the interaction of one or both of the thiol- and amine-end groups of the molecules with the halide ions, a single layer of uniformly crystallized lead-halide 5 can be obtained, as shown in FIG. 2(b). This layer can be a base for the growth of the perovskite monocrystal material as described below.

[0024] As shown in FIG. 3(a), the resultant sample from FIGS. 2(a)-2(b) can be immersed in a solution 6 containing a metal halide and methyl ammonium iodide (MAI) for the growth of the organometallic halide perovskite material 7 on top of the single layer of uniformly crystallized lead-halide 5. The immersion can last from 1 h to 5 h. In the metal halide, the metal can be lead, non-lead, or lead-free. The metal can be selected from the group consisting of lead (Pb), tin (Sn), bismuth (Bi), antimony (Sb), germanium (Ge), and combinations thereof. For example, the metal halide can be PbX.sub.2, where X is one or more of Cl, Br, and I. The metal halide can also be a low-toxicity lead-free (Pb-free) metal halide, where the metal can be selected from the group consisting of tin (Sn), bismuth (Bi), antimony (Sb), germanium (Ge), and combinations thereof. One or both of the sulfur and ammonium end groups of the SAM can assure the grafting of the PbX.sub.2 or the Pb-free and the formation of a large-scale crystal of MAPbx on top of the SAM. The resultant single crystal perovskite materials are more stable than existing polycrystalline perovskites.

[0025] To make a perovskite device 9, an electron-collector electrode 8 can be deposited by evaporation on top of the perovskite material 7, as shown in FIG. 4(d). The electron-collector electrode can include TiO.sub.2 or Al.sub.2O.sub.3. The electron-collector electrode 8 (top electrode) can include an electron conducting material, such as indium-tin oxide (ITO).

[0026] Compared to other fabrication methods, such as spin-coating approaches, the present method can be scaled up. Additionally, the resultant perovskite material does not need to be transferred as the material is grown directly on the substrate. The present method can also extend to other optoelectronic devices, such as light-emitting diodes LED.

[0027] FIG. 5 illustrates one implementation of the structure and operating principle of a semiconductor device 10. In implementations, a semiconductor device 10 can include, but are not limited to, optoelectronic devices such as solar cells, photocatalysts, photoelectrodes, light-emitting diodes, photoelectrodes, and so forth. As shown in FIG. 5, the semiconductor device 10 may include a cathode layer 101, an anode layer 103, and an active layer 102 disposed between the cathode layer 101 and the anode layer 103. The cathode layer 101 functions as a cathode electrode. The anode layer 103 can include an anode electrode.

[0028] In some specific embodiments, the cathode layer 101 can include one or both of an Al layer and a Ag layer that functions as a cathode, and the anode layer 103 can include an indium-tin oxide (ITO) layer that functions as an anode. In other specific embodiments, the cathode layer 101 can include an ITO layer that functions as a cathode. For example, the top electrode 8 as described above can function as the cathode. The anode layer 103 can include an aluminum layer that functions as an anode. Other materials may also be used to form the cathode layer 101, such as one or more of calcium, magnesium, lithium, sodium, potassium, strontium, cesium, barium, iron, cobalt, nickel, copper, silver, zinc, tin, samarium, ytterbium, chromium, gold, graphene, CNT, an alkali metal fluoride, an alkaline-earth metal fluoride, an alkali metal chloride, an alkaline-earth metal chloride, an alkali metal oxide, an alkaline-earth metal oxide, a metal carbonate, a metal acetate, and a combination of two or more of the above materials. Further, other materials may be used to form the anode layer 103 (or a transparent electrode), such as fluorine-doped tin oxide (FTO), aluminum-doped zinc oxide (AZO), antimony-tin mixed oxide (ATO), a conductive polymer, a network of metal nanowire, a network of carbon nanowire, nanotube, nanosheet, nanorod, carbon nanotube, silver nanowire, or graphene. The active layer 102 can include the perovskite material 7 as fabricated using the method described in the above examples.

[0029] It should be understood that various changes and modifications to the presently preferred embodiments described herein will be apparent to those skilled in the art. Such changes and modifications can be made without departing from the spirit and scope of the present subject matter and without diminishing its intended advantages. It is therefore intended that such changes and modifications be covered by the appended claims.