METHOD AND APPARATUS FOR DESALINATING WATER
20210039008 ยท 2021-02-11
Assignee
Inventors
- Bahman Abbasi (Bend, OR, US)
- Xiang Zhang (Bend, OR, US)
- Mohammed Abbas Elhashimi Khalifa (Corvallis, OR, US)
- Deepak Sharma (Corvallis, OR, US)
Cpc classification
B01D45/16
PERFORMING OPERATIONS; TRANSPORTING
B01D1/14
PERFORMING OPERATIONS; TRANSPORTING
F04F5/18
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
B01D5/006
PERFORMING OPERATIONS; TRANSPORTING
B01D1/30
PERFORMING OPERATIONS; TRANSPORTING
C02F1/10
CHEMISTRY; METALLURGY
Y02A20/131
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y02W10/30
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
International classification
B01D1/30
PERFORMING OPERATIONS; TRANSPORTING
B01D1/14
PERFORMING OPERATIONS; TRANSPORTING
B01D45/16
PERFORMING OPERATIONS; TRANSPORTING
B01D5/00
PERFORMING OPERATIONS; TRANSPORTING
C02F1/10
CHEMISTRY; METALLURGY
Abstract
This disclosure concerns a system and a method for removing dissolved solids from liquids. Specific implementations concern desalinating water. The system may comprise a blower, such as a thermal fan/compressor, configured to atomize a solid-bearing liquid to produce a hot, humid gas containing dissolved solids; a gas-solid separator configured to receive hot, humid gas containing entrained dissolved solids from the blower to separate the solids from the humid gas and to transmit the humid gas with solids removed through an exit port; a heater configured to heat the hot, humid gas received from the exit port of the gas-solid separator; and a condenser configured to receive heated humid gas from the heater and to condense solids-free liquid therefrom. The thermal fan/compressor may comprise a plurality of nozzles with outlets positioned adjacent atomization apertures across which a solid-bearing liquid flows and through which gas exiting the nozzles passes.
Claims
1. A desalination system, comprising: a blower configured to atomize a solid-bearing liquid to produce a hot, humid gas containing dissolved solids; a gas-solid separator configured to receive hot, humid gas containing entrained solids from the blower to separate the solids from the humid gas and to transmit the humid gas with solids removed through an exit port; a heater configured to heat the hot, humid gas received from the exit port of the gas-solid separator; and a condenser configured to receive heated humid gas from the heater and to condense solids-free liquid therefrom.
2. The system according to claim 1 wherein the gas blower is a thermal fan/compressor, comprising: an inlet face having one or more inlet ports; a plurality of nozzles for receiving a gas from the one or more inlet ports, each nozzle comprising a heat exchange wall, an inlet orifice having a first size, and an outlet orifice having a second size smaller than the inlet orifice; an outlet face having a plurality of atomization apertures across which a solid-bearing liquid can flow and through which gas exiting the nozzles is directed; and a wall separating the inlet face from the outlet face and forming a condensation and heat exchange chamber in which the plurality of nozzles is disposed.
3. The thermal fan/compressor according to claim 2 wherein the condenser and the heat exchange walls of the plurality of nozzles form a unitary structure.
4. The system according to claim 2 wherein the gas-solid separator is a cyclonic separator.
5. The system according to claim 4, wherein: substantially solids-free gas flows from the condenser to an auxiliary heating element and then to the cyclonic separator to be recycled back to the thermal fan/compressor; or substantially solids-free gas flows from the cyclonic separator to an auxiliary heating element to be recycled back to the thermal fan/compressor.
6. The system according to claim 4 further comprising a solids collector in communication with the cyclonic separator and configured to receive solids rejected from the hot, humid gas by the cyclone.
7. The system according to claim 6 wherein the solids collector functions as a heat recuperator and transmits heat from the rejected solids to a liquid flowing to the outlet face of the thermal fan/compressor.
8. The system according to claim 1 wherein the heater is a solar heater.
9. A desalination system, comprising: a blower configured to atomize a solid-bearing liquid to produce a hot, humid gas containing dissolved solids; a gas-solid separator configured to receive hot, humid gas containing entrained solids from the blower to separate the solids from the humid gas and to transmit the humid gas with solids removed through an exit port; a condenser configured to condense substantially solid-free liquid from the hot, humid gas leaving the gas-solid separator and to supply evaporation heat to the hot, humid gas from the thermal fan/compressor; a gas-liquid separator configured to receive the hot gas and to condense substantially solid-free liquid from the condenser to separate the liquid from the gas; and a heater configured to supply heat to the heat exchange chamber of the thermal fan/compressor.
10. The system according to claim 9, wherein the gas blower is a thermal fan/compressor, comprising: an inlet face having one or more inlet ports; a plurality of nozzles for receiving a gas from the one or more inlet ports, each nozzle comprising a heat exchange wall, an inlet orifice having a first size, and an outlet orifice having a second size smaller than the inlet orifice; an outlet face having a plurality of atomization apertures across which a solid-bearing liquid can flow and through which gas exiting the nozzles can pass; and a wall separating the inlet face from the outlet face and forming a condensation and heat exchange chamber in which the plurality of nozzles is disposed.
11. The system according to claim 9 wherein the gas-solid separator is a cyclonic separator.
12. The system according to claim 11, wherein: substantially solids-free gas flows from the condenser to an auxiliary heating element and then to the cyclonic separator to be recycled back to the thermal fan/compressor; or substantially solids-free gas flows from the cyclonic separator to an auxiliary heating element to be recycled back to the thermal fan/compressor.
13. The system according to claim 9 wherein the heater is a solar heater.
14. The system according to claim 9 further comprising a solids collector in communication with the gas-solid separator and configured to receive solids rejected from the hot humid gas by the separator.
15. The system according to claim 9 further comprising a heat recuperator configured to remove heat from the solids-free liquid leaving the gas-liquid separator, and to transmit that heat to an incoming flow of solids-bearing liquid.
16. The system according to claim 15 wherein the gas-liquid separator is fluidly coupled to the inlet orifices of the thermal fan/compressor nozzles.
17. The system according to claim 9, further comprising a bleed stream to heat solids-free liquid exiting the gas-liquid separator with bleed enthalpy from hot gas leaving a cyclonic separator.
18. A thermal fan/compressor, comprising: an inlet face having a plurality of inlet ports; a plurality of nozzles for receiving a gas from the inlet ports, each nozzle comprising a heat exchange wall, an inlet orifice having a first size, and an outlet orifice having a second size smaller than the inlet orifice; an outlet face having a plurality of atomization apertures across which a solid-bearing liquid can flow and through which gas exiting the nozzles can pass; and a wall separating the inlet face from the outlet face and forming a condensation and heat exchange chamber in which the plurality of nozzles is disposed.
19. A method for desalinating water, comprising: providing a system according to claim 1; and using the system to desalinate water.
20. The method according to claim 19, comprising: supplying a flow of slow-moving dry gas to a gas blower; accelerating the dry gas in the gas blower; directing the accelerated dry gas through a solid-bearing liquid, thereby atomizing the liquid and forming a hot, humid gas with entrained solids; supplying the flow of hot, humid gas to a gas-solid separator wherein the entrained solids are separated from the hot, humid gas with entrained solids; supplying the flow of hot, humid gas from the gas-solid separator to a solar heater to heat the hot, humid gas; and supplying the flow of hot, humid gas from the solar heater to a condenser wherein the substantially solid-free liquid is removed from the gas by condensation.
21. The method according to claim 20 wherein the gas is substantially dry air when it enters the gas blower.
22. The method according to claim 20 wherein the solid-bearing liquid is saline water, and the substantially solid free liquid is desalinated water.
23. The method according to claim 20 wherein the gas blower is a thermal fan/compressor, comprising: an inlet face having a plurality of inlet ports; a plurality of nozzles for receiving a gas from the inlet ports, each nozzle comprising a heat exchange wall, an inlet orifice having a first size, and an outlet orifice having a second size smaller than the inlet orifice; an outlet face having a plurality of atomization apertures across which a solid-bearing liquid can flow and through which gas exiting the nozzles can pass; and a wall separating the inlet face from the outlet face and forming a condensation and heat exchange chamber in which the plurality of nozzles is disposed.
24. A method for desalinating water, comprising: supplying a flow of air to a blower; accelerating the air in the blower; directing the accelerated air through saline water, thereby atomizing the water and forming a hot, humid gas with entrained solids; supplying the flow of hot, humid gas with entrained solids to a gas-solid separator, wherein the entrained solids are separated from the hot, humid gas to provide substantially solids-free water; supplying the flow of hot, humid gas from the gas-solid separator to a condenser to condense substantially solid-free water from the gas; and supplying the gas and substantially solid-free water mixture from the condenser to a gas-liquid separator to separate gas from the substantially solid free water.
25. The method according to claim 24 wherein slow-moving air is supplied to a thermal fan/compressor, wherein the thermal fan/compressor comprises: an inlet face having a plurality of inlet ports; a plurality of nozzles for receiving a gas from the inlet ports, each nozzle comprising a heat exchange wall, an inlet orifice having a first size, and an outlet orifice having a second size smaller than the inlet orifice; an outlet face having a plurality of atomization apertures across which a solid-bearing liquid can flow and through which gas exiting the nozzles can pass; and a wall separating the inlet face from the outlet face and forming a condensation and heat exchange chamber in which the plurality of nozzles is disposed.
26. The method according to claim 25 wherein the nozzles of the thermal fan/compressor are heated, thereby causing the dry gas to accelerate and flow out of the outlet orifices of the nozzles and through atomization apertures of the outlet face of the thermal fan/compressor, thereby atomizing the solid-bearing water and forming hot, humid gas with entrained solids.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
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DETAILED DESCRIPTION
[0040] The following detailed description is provided with reference to the drawings and embodiments described herein. The drawings are illustrative and are not intended to limit the scope of the disclosure. It should further be understood that the term desalination as used herein refers to the removal of salt and other total dissolved solids (TDS) from any fluid source, particularly a water source contaminated with such solids. TDS refers to any material that may be dissolved in a fluid, particularly water, and includes by way of example dissolved salts, ionic compounds, minerals, metals or other materials dissolved in water.
I. Definitions
[0041] The following explanations of terms and abbreviations are provided to better describe the present disclosure and to guide those of ordinary skill in the art in the practice of the present disclosure. As used herein, comprising means including and the singular forms a or an or the include plural references unless the context clearly dictates otherwise. The term or refers to a single element of stated alternative elements or a combination of two or more elements, unless the context clearly indicates otherwise.
[0042] Unless explained otherwise, all technical and scientific terms used herein have the same meaning as commonly understood to one of ordinary skill in the art to which this disclosure belongs. Although methods and materials similar or equivalent to those described herein can be used in the practice or testing of the present disclosure, suitable methods and materials are described below. The materials, methods, and examples are illustrative only and not intended to be limiting. Other features of the disclosure are apparent from the following detailed description and the claims.
[0043] The disclosure of numerical ranges refers to each discrete point within the range, inclusive of endpoints, unless otherwise noted. Unless otherwise indicated, all numbers expressing quantities of components, molecular weights, percentages, temperatures, times, and so forth, as used in the specification or claims are to be understood as being modified by the term about. Accordingly, unless otherwise implicitly or explicitly indicated, or unless the context is properly understood by a person of ordinary skill in the art to have a more definitive construction, the numerical parameters set forth are approximations that may depend on the desired properties sought and/or limits of detection under standard test conditions/methods as known to those of ordinary skill in the art. When directly and explicitly distinguishing embodiments from discussed prior art, the embodiment numbers are not approximates unless the word about is recited.
[0044] Certain disclosed embodiments concern processing fluids, particularly water, to produce a substantially solid free fluid. Substantially solid free will be understood by a person of ordinary skill in the art to depend upon the fluid, the solids content, and the purpose for which the fluid is used. Substantially solid free refers to a fluid having a reduced solids content after processing according to disclosed embodiments relative to the same fluid prior to processing, and such processing to produce a reduced solids content provides a processed fluid having an improved property or benefit relative to the fluid prior to processing. For disclosed embodiments directed to desalinating water to produce potable water, substantially solid free means water having a salt concentration after processing according to disclosed embodiments approaching 0 ppm, more typically greater than 0 ppm to 1,000 ppm, and preferably equal to or less than 500 ppm, such as 100 to 500 ppm or less.
II. Introduction
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[0046]
III. Fluid Purification System
[0047] Described herein are embodiments of a system for the energy-efficient purification of fluids, with particular embodiments concerning desalination of water. Also disclosed herein are embodiments of a method for using the disclosed system.
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[0051] Each of the exemplary systems discussed above include a thermal fan/compressor, such as thermal fan/compressors 300, 400 and 500. However, a thermal fan/compressor is not a required component, and instead can be replaced with a component that provides substantially the same function, such as desalination chamber 1100 that includes an air blower and a humidifier-dehumidifier as illustrated by
[0052]
[0053] Each of the exemplary systems discussed above includes a cyclone, such as cyclones 310, 412, 512 and 1112. However, in each such disclosed exemplary system, the cyclone could be replaced with a packed bed component. The packed bed would include a sorbent or combinations of sorbents suitable for separating solids from fluids to produce a fluid with a reduced solids content, such as a substantially solids-free fluid.
IV. Embodiments of Thermal Nozzles and Fans
[0054] Described herein are examples of thermal fan/compressors suitable for use in the fluid purification system and method embodiments disclosed herein, such as a water desalination system and process. The present disclosure also provides thermal fan/compressor nozzles for use in the thermal fan/compressors. Additional features of exemplary thermal fan/compressor embodiments are disclosed by assignee's U.S. provisional patent application No. 62/968,747, filed on Jan. 31, 2020, and entitled Thermal Fan Apparatus and Method of Use. U.S. provisional patent application No. 62/968,747 is incorporated herein by reference in its entirety.
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[0056] Thermal fan/compressor nozzles may be made of any material that is chemically and thermally compatible with fluid purification processes, such as desalination. Certain embodiments are suitable for use with 450,000 ppm TDS water, more typically 100,000 ppm TDS or less water, under the temperature and pressure conditions under which the invention is used. Exemplary materials that can be used include polymers, such as polyetheretherketone (PEEK), polysulfone (PSU), and polyvinylidene fluoride (PVDF). In some embodiments, the strength and thermal conductivity of nozzles 602 may be improved by including thermally-conductive metal powder in the thermal fan/compressor nozzle body.
[0057] Thermal fan/compressor 600 incorporates a plurality of thermal fan/compressor nozzles 602. The exemplary thermal fan/compressor 600 of
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[0059] As illustrated in
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[0061] In a generalized operational example, dry or low humidity air enters the thermal fan/compressor nozzles 602, 702 through inlet orifices, such as orifices 614, in a near-stagnant state with a velocity of v.sub.0, near 0 m/s, and a temperature of T.sub.0. Thermal energy is transferred to the heat exchange chamber 612, 712 and is conducted to the air inside the thermal fan/compressor nozzles 602, 702, accelerating the air to velocity v.sub.1 greater than v.sub.0 and heating it to a temperature of T.sub.1 greater than T.sub.0. Jets of dry air moving at velocity v.sub.1 contacts incoming dissolved solids-bearing feed water at the outlet face 608, 708. The feed water is atomized by the high-velocity hot air, and the solid particles are entrained in the resulting hot, humid air.
V. Embodiments of Other Components
[0062] Described herein are examples of various other components suitable for desalination.
[0063] In one disclosed embodiment, the gas-solid separator (e.g. the cyclone) is substantially conical in shape and has an inlet at an upper end. The inlet communicates with the passageway and is located adjacent to the upper end of the cyclone. The inlet is arranged tangentially to the side wall of the cyclone such that warm, humid air entering the cyclone is directed in a helical path around the interior of the cyclone. The cyclone further includes an outlet. The outlet provides a passageway for cleaned air leaving the cyclonic separating apparatus and passing to other parts of the desalination apparatus downstream of the cyclone, such as the condensation chamber of the thermal fan/compressor or the air-water separator. A solids collector is located at the lower end of the cyclone. The solids collector collects salt and other solids rejected from the warm and humid air in the cyclone and subsequently caused to fall towards the lower end of the cyclone.
[0064] In operation, hot, humid air from a thermal fan/compressor enters the cyclone through an inlet. The airflow may follow a helical path around the interior of the cyclone. Entrained solids, such as salts, are separated from the hot, humid air by this cyclonic motion, accumulate at the lower end of the cyclone, and are collected in the solids collector. Cleaned hot, humid air that no longer contains entrained solids exits the cyclone through outlet and proceeds to downstream elements of the desalination apparatus.
VI. EXAMPLES
[0065] The following examples are provided to illustrate certain features of exemplary embodiments of the present invention. A person of ordinary skill in the art will understand that the scope of the disclosed invention is not limited to, nor defined by, these exemplary features.
Example 1
[0066] In one example of a method for the desalination of water, dry, near-stagnant (v.sub.o=near 0 m/s) air enters a thermal fan/compressor such as illustrated in
Example 2
[0067] In another embodiment of a method for desalinating water, dry, near-stagnant (v=near 0 m/s) air enters a thermal fan/compressor at a temperature of approximately 30 C. and a pressure of 1 atmosphere. An array of thermal fan/compressor nozzles containing the near-stagnant air is externally heated by contact with hot, humid air, raising the temperature of the dry air inside the nozzles to 100 C. and accelerating it to a second velocity greater than the first velocity, such as about 2.6 m/s. The dry air exits the nozzles and contacts incoming feed water having a temperature of 90 C. The high-velocity jets of hot air atomize the feed water, entraining solids, such as salt(s) in the humidified air stream. The resulting humidified air stream with entrained solid particles exits the thermal fan/compressor at a velocity of 2 m/s, a temperature of 93 C., and a pressure of approximately 2 atmospheres. The humid air stream then enters a cyclone in which solids larger than approximately 3 m are separated from the humid air and collected in a combined salt collector and heat recuperator, where intake feed water is heated to 90 C. before being introduced to the thermal fan/compressor for atomization. The substantially solids-free humid air leaves the cyclone and is heated by a heater, such as a solar heater, before flowing to the thermal fan/compressor nozzles. This causes substantially solid-free liquid, such as salt-free water, to condense as heat transfers to the air within the thermal fan/compressor nozzles.
Example 3
[0068] In another embodiment of a method for desalinating water, dry, near-stagnant (v=near 0 m/s) air enters the thermal fan/compressor at a temperature of approximately 98 C. An array of thermal fan/compressor nozzles containing the near-stagnant air is externally heated, such as by using a solar heater, to raise the temperature of the dry air inside the nozzles to 120 C. The thermal fan/compressor nozzles accelerate the heated air to a second velocity greater than the first velocity, such as velocity greater than about 19 m/s. The dry air exits the nozzles and contacts incoming hot saline feed water having a temperature of 95 C. The high-velocity hot air jets atomize the feed water, entraining solids in the humidified air stream. The humidified air is further heated by heat of condensation that is supplied by contacting the interior surface of a condenser. The resulting humidified air stream with entrained solid particles, such as salt particles, exits the thermal fan/compressor at a velocity of about 12 m/s and a temperature of about 108 C. The humid air stream then enters a cyclone in which solids larger than approximately 3 m are separated from the humid air. Substantially particle-free humid air exits the cyclone at about 107 C. and is reintroduced to the outside surface of the condenser, where water condenses, and excess heat is transferred to the flow of atomized feed water. The hot, condensed fresh water then flows to an air-water separator. Remaining air is removed and reintroduced to the thermal fan/compressor nozzles. Fresh water then enters a heat recuperator, where heat is transferred to intake fluid, such as saline water, to heat it to a target temperature of 95 C. prior to atomization.
[0069] In view of the many possible embodiments to which the principles of the disclosed invention may be applied, it should be recognized that the illustrated embodiments are only preferred examples of the invention and should not be taken as limiting the scope of the invention. Rather, the scope of the invention is defined by the following claims. We therefore claim as our invention all that comes within the scope and spirit of these claims.