SLOT-DIE COATING APPARATUS AND SLOT-DIE COATING METHOD
20210086221 ยท 2021-03-25
Inventors
Cpc classification
B05C5/0275
PERFORMING OPERATIONS; TRANSPORTING
B05C5/004
PERFORMING OPERATIONS; TRANSPORTING
B05C11/1015
PERFORMING OPERATIONS; TRANSPORTING
B05C5/0208
PERFORMING OPERATIONS; TRANSPORTING
B05C5/0254
PERFORMING OPERATIONS; TRANSPORTING
B05C11/1034
PERFORMING OPERATIONS; TRANSPORTING
International classification
B05C11/10
PERFORMING OPERATIONS; TRANSPORTING
B05C5/00
PERFORMING OPERATIONS; TRANSPORTING
B05C5/02
PERFORMING OPERATIONS; TRANSPORTING
Abstract
A slot-die coating apparatus for manufacturing a patterned coating layer (3) on a substrate surface (1s) of a substrate (1) comprises a slot-die coating head (2), a controlled coating fluid supply system (7) and a substrate carrier (6) for carrying the substrate (1). The slot-die coating head (2) comprises an inlet (21) for receiving coating fluid from the coating fluid supply system and a slit-shaped outflow opening (22) that is communicatively coupled to the inlet and has a slit direction. The controlled coating fluid supply system (7) alternately operates in a first mode (M1) to provide for a flow of coating fluid out of the slit-shaped outflow opening (22) for deposition on the substrate surface and in a second mode (M2) wherein a deposition of coating fluid out of the slit-shaped outflow opening (22) on the substrate surface is interrupted (21). The coating head (2) has an internal coating fluid trajectory extending from the inlet (21) to the slit-shaped outflow opening (22). In a stream-downwards order, the coating fluid trajectory comprises a lateral distribution portion (23) to distribute a flow of fluid over said slit direction, a collection channel (24) extending transverse to the stream-downwards direction, and a flow resistive output portion (25). Upon a transition from the first mode (M1) to the second mode (M2) the coating fluid supply system (7) sucks coating fluid from at least one outlet (26) of the slot-die coating head (2) that is communicatively coupled to the collection channel (24).
Claims
1. A slot-die coating apparatus for manufacturing a patterned coating layer on a substrate surface of a substrate, the apparatus comprising: a slot-die coating head, a coating fluid supply system, a controller that controls the coating fluid supply system, and a substrate carrier for carrying the substrate, wherein the slot-die coating head comprises: an inlet for receiving a coating fluid from the coating fluid supply system, and a slit-shaped outflow opening communicatively coupled to the inlet and having a slit direction, and wherein in use the controller alternately causes the coating fluid supply system to operate in: a first mode to provide for a flow of coating fluid out of the slit-shaped outflow opening for deposition on the substrate surface, and a second mode wherein a deposition of coating fluid out of the slit-shaped outflow opening on the substrate surface is interrupted, wherein the slot-die coating head defines an internal coating fluid trajectory extending from the inlet to the slit-shaped outflow opening, wherein the internal coating fluid trajectory, in a stream-downwards order, comprises: a lateral distribution channel to distribute a flow of fluid over said slit direction, a collection channel extending transverse to a stream-downwards direction, and a flow resistive output portion, wherein the internal coating trajectory includes a distribution gap stream from a distribution gap, wherein the distribution gap stream is downstream from the lateral distribution channel and upstream of the collection channel, wherein the distribution gap has a relatively high flow resistance in comparison to a flow resistance of the lateral distribution channel, wherein the controller, upon a transition from the first mode to the second mode, causes the coating fluid supply system to suck coating fluid from at least one outlet of the slot-die coating head that is communicatively coupled to the collection channel, therewith causing excess coating fluid outside the slit-shaped outflow opening to flow via the flow resistive output portion, via the collection channel to said at least one outlet.
2. The slot-die coating apparatus of claim 1, wherein the coating fluid supply system comprises a suction pump for sucking a discrete amount of fluid.
3. The slot-die coating apparatus of claim 2, wherein the suction pump is provided to drain the discrete amount of fluid.
4. The slot-die coating apparatus according to claim 1, wherein the coating fluid supply system comprises a controllable supply pump.
5. The slot-die coating apparatus according to claim 1, wherein the coating fluid supply system comprises a three-way valve for controllably directing a flow of coating fluid provided by a supply pump either to the inlet of the slot-die coating head or bypassing said flow to the slot-die coating head.
6. The slot-die coating apparatus according to claim 3, wherein the suction pump is a membrane pump.
7. The slot-die coating apparatus according to claim 1, wherein the suction pump is configured to suck coating fluid from said outlet a flowrate exceeding the flowrate with which the coating fluid supply system supplies coating fluid to the inlet of the slot-die coating head during said first mode.
8. The slot-die coating apparatus according to claim 1, comprising a positioning actuator to dynamically position the slot-die coating head with respect to the surface of the substrate, and wherein the controller is further provided to control the positioning actuator to position the slot-die coating head with its outflow opening: at a first distance with respect to the surface of the substrate during said first mode, and at a second distance, larger than the first distance., with respect to the surface of the substrate during said second mode.
9. The slot-die coating apparatus according to claim 8, wherein the controller is provided to position the slot-die coating head with its outflow opening at a third distance, smaller than said first distance, with respect to the surface of the substrate during a transition from the first mode to the second mode.
10. The slot-die coating apparatus according to claim 1, wherein the at least one outlet is one of a plurality of outlets that are communicatively coupled to the collection channel at mutually different positions along said slit direction,
11. The slot-die coating apparatus according to claim 1, wherein the outflow opening is provided with one or more shims that locally block a flow of coating fluid.
12. The slot-die coating apparatus according to claim 1, wherein the coating fluid supply system comprises a suction pump for sucking a dynamically controllable amount of fluid.
13. The slot-die coaling apparatus according to claim 12, wherein the controller includes a control module for controlling the dynamically controllable amount of fluid to be sucked by the a suction pump, dependent at least on a detected boundary property of a deposited layer.
14. A slot-die coating method for manufacturing a patterned coating layer on a substrate surface of a substrate, using a slot-die coating head and a substrate carrier for carrying the substrate, wherein: the slot-die coating head comprises an inlet for receiving coating fluid and a slit-shaped outflow opening communicatively coupled to the inlet and having a slit direction, the slot-die coating head defines an internal coating fluid trajectory extending from the inlet to the outflow opening, the internal coating fluid trajectory in a stream-downwards order comprises: a lateral distribution channel, a collection channel extending transverse to the stream-downwards direction, and a flow resistive output portion, the slot-die coating head further comprising at least one outlet that is communicatively coupled to the collection channel, the method comprises: alternately operating in a first mode and a second mode wherein: in said first mode coating fluid is supplied to said inlet, said coating fluid is laterally distributed in the lateral distribution channel and flows via the collection channel and the flow resistive output portion to the outflow opening for deposition on the substrate, and in said second mode a deposition of coating fluid onto the substrate surface is interrupted, the internal coating fluid trajectory further includes a distribution gap stream from a distribution gap, the distribution gap is downstream from the lateral distribution channel and upstream of the collection channel, the distribution gap has a relatively high flow resistance in comparison to a flow resistance of the lateral distribution channel, and in that in said first mode of operation the coating fluid flows via the distribution gap from the lateral distribution channel to the collection channel and wherein upon a transition from the first mode to the second mode a suction is applied to the at least one outlet, causing excess coating fluid outside the slit-shaped outflow opening to flow via the flow resistive output portion, via the collection channel to said at least one outlet.
15. The slot-die coating apparatus according to claim 2 wherein the suction pump is configured to suck coating fluid from said outlet a flowrate exceeding the flowrate with which the coating fluid supply system supplies coating fluid to the inlet of the slot-die coating head during said first mode.
16. The slot-die coating apparatus according to claim 1 wherein the suction pump is configured to suck coating fluid from said outlet a flowrate exceeding the flowrate with which the coating fluid supply system supplies coating fluid to the inlet of the slot-die coating head during said first mode.
17. The slot-die coating apparatus according to claim 2, comprising a positioning actuator to dynamically position the slot-die coating head with respect to the surface of the substrate, and wherein the controller is further provided to control the positioning actuator to position the slot-die coating head with its outflow opening: at a first distance with respect to the surface of the substrate during said first mode, and at a second distance, larger than the first distance, with respect to the surface of the substrate during said second mode.
18. The slot-die coating apparatus according to claim 3, comprising a positioning actuator to dynamically position the slot-die coating head with respect to the surface of the substrate, and wherein the controller is further provided to control the positioning actuator to position the slot-die coating head with its outflow opening: at a first distance with respect to the surface of the substrate during said first mode, and at a second distance, larger than the first distance, with respect to the surface of the substrate during said second mode.
19. The slot-die coating apparatus according to claim 2, wherein the at least one outlet is one of a plurality of outlets that are communicatively coupled to the collection channel at mutually different positions along said slit direction.
20. The slot-die coating apparatus according to claim 3, wherein the at least one outlet is one of a plurality of outlets that are communicatively coupled to the collection channel at mutually different positions along said slit direction.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0012] These and other aspects are described in more detail with reference to the drawing. Therein:
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DETAILED DESCRIPTION OF EMBODIMENTS
[0026] Like reference symbols in the various drawings indicate like elements unless otherwise indicated.
[0027]
[0028] The apparatus comprises a slot-the coating head 2, a coating fluid supply system 7, a controller 9 for controlling the coating fluid supply system, and a substrate carrier 6 for carrying the substrate 1. In an embodiment the substrate carrier 6 may provide for a fixed support of the substrate, and the coating head may be displaced at a velocity v.sub.head as indicated in
[0029] The slot-die coating head 2 comprises an inlet 21 for receiving coating fluid from the coating fluid supply system 7 and a slit-shaped outflow opening 22 that is communicatively coupled to the inlet and that has a slit direction y. In use the controller 9 applies control signal C.sub.7that alternately causes the coating fluid supply system 7 to operate in a first mode M1 and a second mode M2. In the first mode M1 it provides for a flow Vout of coating fluid out of the slit-shaped outflow opening 22 for deposition on the substrate surface 1s. In the second mode M2 a flow of coating fluid out of the slit-shaped outflow opening 22 is interrupted 21. The coating head 2 has an internal coating fluid trajectory extending from the inlet 21 to the slit-shaped outflow opening 22. The coating fluid trajectory comprises in a stream-downwards order a lateral distribution portion 23, a collection channel 24 and a flow resistive output portion 25.
[0030] In operation, the lateral distribution portion 23 distribute a flow of fluid over the slit direction y. In the embodiment shown the lateral distribution portion 23 comprises a comprises a lateral distribution channel 23a and a distribution gap 23b having a relatively high flow resistance in comparison to a flow resistance of the lateral distribution channel 23a.
[0031] The flow resistance R, in Pa.Math.s.Math.m.sup.3, of a trajectory portion may be approximated by the following approximation based on the Poisseuille equation:
[0032] Therein is the dynamic viscosity of the fluid in Pa.Math.s, L.sub.st is the length of the trajectory in the flow direction in m, and W and h are the width the height of the trajectory portion in m.
[0033] In the embodiment shown the distribution gap 23b has a length l.sub.23b and a height h.sub.23b. The flow resistance of the distribution gap is substantially proportional to a ratio length l.sub.23b/h.sub.23b. By way of example the distribution gap may have a height h.sub.23b of 25 to 500 micron and a length l.sub.23b of 10 to 50 mm, wherein the ratio is in the range of 50 to 500. If this ratio is substantially less than 50, e.g. less than 10 than the flow may be insufficiently distributed in the lateral direction, and the ratio is substantially higher than 500, e.g. higher than 1000 than an unnecessary high load of the supply may result, at a relatively modest additional improvement of the lateral distribution.
[0034]
[0035] Stream downwards of the lateral distribution portion 23, a collection channel 24 is provided that extends in a direction transverse to the stream-downwards direction. The collection channel 24 is communicatively coupled to one or more outlets. In the embodiment shown in
[0036] The controller 9 is configured to cause the coating fluid supply system 7 to suck coating fluid from the outlet 26 of the slot-die coating head 2 upon a transition from the first mode M1 to the second mode M2. This suction of coating fluid may proceed during the second mode M2, to compensate for the supply of coating fluid from outlet 71 of the coating fluid supply system 7. Alternatively, this suction may be performed during a suction time interval shorter than the duration of the second mode M2 such that during the suction time interval an excess amount of fluid is sucked from the outflow opening 22 and possibly a portion of the flow resistive output portion 25, while during the remainder of the second mode the supply V.sub.supply of coating fluid provides for a renewed formation of a bead of coating fluid at the outflow opening 22, possibly preceded by a refilling of the flow resistive output portion 25.
[0037] By way of example,
[0038] In a typical example a distance between the coating head and the substrate may be in a range of 25500 m, a viscosity of the coating fluid 1-100 mPa.Math.s, a nozzle cross-section diameter 25-350 m, a relative speed between the coating head and substrate 3-30 metres per minute, a wet coating layer thickness 5-100 m, e.g. 10 to 50 m. Coating parameters may be determined e.g. experimentally and/or by model calculations.
[0039] As shown in
[0040] Whereas in this example the amount Q decreases to 0, also embodiments are conceivable wherein the amount is reduced to a value between 0 and Q.sub.M1. Also embodiments are conceivable wherein the amount Q is reduced to a negative value, implying that also the flow resistive output portion 25 is (partially) discharged.
[0041] As indicated above, during the remainder t1a to t2, for example as illustrated for a point in time tc in
[0042]
[0043] The coating fluid supply system 7 in this embodiment further comprises a suction pump 75 for sucking a discrete amount of coating fluid. Hence, upon each activation the suction pump 75, e.g. by control signal C.sub.75a, the suction pump 75 suck a preset quantity of coating fluid from the outlet 26. In the embodiment shown the suction pump 75 is provided to drain the discrete amount of fluid into the reservoir 73. To that end valves 76, 77 are provided that are controlled by the controller 9 with respective control signals C.sub.76, C.sub.77. In another embodiment the valves 76, 77 may operate autonomously. For example valve 76 may be arranged as a one-way valve that automatically opens if a pressure difference P1-P2 exceeds a threshold value. In this way it is prevented that during operation in mode M1 coating fluid flows away via return channel 27, whereas a flow of coating fluid is enabled in the transition from mode M1 to mode M2. The second valve can also be provided as a one-way valve, but its threshold can be arbitrary low.
[0044]
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[0046] In an embodiment, for example the embodiment of
[0047] In the embodiment shown the controller controls the position of the stopper 755 to automatically regulate an amount of sucked coating fluid.
[0048]
[0049] The ratio between the flow resistance in the lateral distribution portion 23 and in the flow resistive output portion 25 can also be expressed as a ratio of the pressure drops P.sub.1/P.sub.2 occurring in these portions during operation in the first mode. This is schematically indicated in
[0050] Exemplary embodiments of the coating head as illustrated in
TABLE-US-00001 h.sub.23b(m) l.sub.23b(mm) h.sub.25(m) l.sub.25(mm) P1(Pa) P2(Pa) P1/P2 100 2.5 100 1 193 77 2.5 100 2.5 200 2.5 193 24 8.0 100 2.5 200 1 193 10 20.0 100 1 200 2.5 77 24 3.2 100 1 200 1 77 10 8.0 200 2.5 200 1 24 10 2.5
[0051] For comparison the pressure drop in remaining parts of the fluid supply system is substantially lower. For example the pressure drop in the supply line towards the inlet 21 is merely 4 mPa, i.e. its magnitude is at least three orders of magnitude lower than that in the portions 23b, 25 of the coating head 2. Similarly, the pressure drop in the distribution channel 23a and the collection channel 24 is substantially lower, e.g. at least two orders of magnitude lower than those in the portions 23a, 25 respectively.
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[0054] While example embodiments were shown for providing a coating layer on a substrate, also alternative ways may be envisaged by those skilled in the art having the benefit of the present disclosure for achieving a similar function and result. The various elements of the embodiments as discussed and shown offer certain advantages, such as providing homogeneous coating layers. Of course, it is to be appreciated that any one of the above embodiments or processes may be combined with one or more other embodiments or processes to provide even further improvements in finding and matching designs and advantages, e.g. combinations of slot die coating, intermittent coating, shim coating, and/or pre-patterning a substrate. It is appreciated that this disclosure offers particular advantages to the manufacture of solar cell arrays, and in general can be applied for any application of large-scale production of homogeneous patterned layers on a substrate or web.
[0055] Finally, the above-discussion is intended to be merely illustrative of the present system and should not be construed as limiting the appended claims to any particular embodiment or group of embodiments. Thus, while the present system has been described in particular detail with reference to specific exemplary embodiments thereof, it should also be appreciated that numerous modifications and alternative embodiments may be devised by those having ordinary skill in the art without departing from the scope of the present systems and methods as set forth in the claims that follow. The specification and drawings are accordingly to be regarded in an illustrative manner and are not intended to limit the scope of the appended claims.
[0056] In interpreting the appended claims, it should be understood that the word comprising does not exclude the presence of other elements or acts than those listed in a given claim; the word a or an preceding an element does not exclude the presence of a plurality of such elements; any reference signs in the claims do not limit their scope; several means may be represented by the same or different item(s) or implemented structure or function; any of the disclosed devices or portions thereof may be combined together or separated into further portions unless specifically stated otherwise. The mere fact that certain measures are recited in mutually different claims does not indicate that a combination of these measures cannot be used to advantage.