Tyre Dressing Composition

Abstract

Disclosed are compositions, and articles containing the composition, where the composition comprises glycerine alkoxylates and/or glyceride esters, obtained by transesterification of seed oil, and their use to enhance the combined gloss index of surfaces. More specifically the compositions are disclosed for the purpose of using a tyre-dressing system to enhance the sidewall aesthetics of tyres without requiring the use of silicone oils.

Claims

1. A tyre dressing composition intended for use in a tyre dressing method, said composition comprising an alcohol alkoxylate polymer corresponding to formula (1): ##STR00003## wherein R.sub.1 represents a hydrogen atom or an acyl moiety (COR) where R is an alkyl or alkenyl group moiety constituted by at least 6, and up to 18 carbons atoms; R.sub.2 represent a hydrogen atom, methyl (CH.sub.3) or ethyl (CH.sub.2CH.sub.3) moiety; and each X independently represents an integer of from 1 to 50 and wherein the sum of all X present is from 1 to 100.

2. The composition of claim 1 wherein the alcohol alkoxylate polymer comprises a glycerine alkoxylate represented by formula (1) wherein R.sub.1 is hydrogen and R.sub.2 is a hydrogen or methyl moiety.

3. The composition of claim 1 wherein the alcohol alkoxylate polymer comprises a glyceride ester represented by formula (1) when at least at least one R.sub.1 is an acyl moiety (COR); and R.sub.2 is a hydrogen or methyl moiety.

4. The composition of claim 1 wherein the alcohol alkoxylate polymer is a mixture comprising (i) a glyceride ester represented by formula (1) when at least at least one R.sub.1 is an acyl moiety (COR); and R.sub.2 is a hydrogen or methyl moiety and (ii) a glycerine alkoxylate represented by formula (1) wherein R.sub.1 is hydrogen and R.sub.2 is a hydrogen or methyl moiety.

5. The composition of claim 4 wherein the glyceride ester component is present in from about 60 to 90 weight percent, and the glycerine alkoxylate component present in from 10 to 40 weight percent, based on total weight of the alcohol alkoxylate polymer present.

6. The composition of claim 4 wherein the glyceride ester is a mixture of mono-, di- or tri-ester glycerides.

7. The composition of claim 6 wherein the weight ratio of said mono-, di- and tri-esters is from 45-90:10-30:1-15 respectively.

8. The composition of claim 4 wherein for the glyceride ester component, the R.sub.2 moiety is hydrogen, and the sum of all X present is an integer of from 10-60.

9. The composition of claim 1 wherein in the sum of all X present in formula (1) is an integer of from 5-80.

10. The composition of claim 3 wherein the glyceride ester is obtained by transesterification of a seed oil with a glycerine alkoxylate represented by formula (1) and where R.sub.1 is hydrogen, R.sub.2 represent a hydrogen atom or methyl moiety.

11. The composition of claim 4 wherein the glyceride ester is obtained by transesterification of a seed oil with a glycerine alkoxylate represented by formula (1) and where R.sub.1 is hydrogen, R.sub.2 represent a hydrogen atom or methyl moiety.

12. The tyre composition of claim 10 wherein the glycerine alkoxylate used in the transesterification is represented by formula (1) where R.sub.1 is hydrogen, R.sub.2 represent a hydrogen atom; and the sum of all X present is from an integer from 10 to 60.

13. The tyre composition of claim 11 wherein the glycerine alkoxylate used in the transesterification is represented by formula (1) where R.sub.1 is hydrogen, R.sub.2 represent a hydrogen atom; and the sum of all X present is from an integer from 10 to 60.

14. The tyre dressing composition of claim 10 wherein the seed oil is sunflower oil, canola oil, soybean oil, coconut oil, corn oil, palm oil, hemp oil, and/or castor oil.

15. The tyre dressing composition of claim 11 wherein the seed oil is sunflower oil, canola oil, soybean oil, coconut oil, corn oil, palm oil, hemp oil, and/or castor oil.

16. The composition of claim 1 further comprising water present in from 40 to 80 weight percent based on total weight of the composition.

17. The composition of claim 1 further comprising an organic liquid present in from 40 to 80 weight percent based on total weight of the composition.

18. The composition of claim 1, wherein the composition is stored in a plastic bottle or in an aerosol disperser unit.

19. A method of dressing a tyre, the method comprising: providing a composition as claimed in claim 1; cleaning a target tyre sidewall; applying a thin film coating of the composition on said tyre sidewall and allowing the surface to dry.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0016] As mentioned, the tyre dressing composition intended for use in a tyre dressing method comprises an alcohol alkoxylate polymer corresponding to formula (I):

##STR00002## [0017] wherein:
each R.sub.1 independently represents a hydrogen atom or an acyl moiety (COR) for which R is an alkyl or alkenyl moiety constituted by at least 6, and up to 18 carbons atoms;
R.sub.2 represent a hydrogen atom, a methyl (CH.sub.3) or an ethyl (CH.sub.2CH.sub.3) moiety; and each X independently represents an integer of from 1 to 50 and wherein the sum of all X present is from 1 to 100.

[0018] The sum of all integers for X of formula (I), in a preferred embodiment is from to 80, and more preferably from 10 to 60.

[0019] In one aspect of the invention, the alcohol alkoxylate polymer comprises one or more glycerine alkoxylates as represented by formula (I) wherein R.sub.1 is hydrogen and R.sub.2 is a hydrogen or methyl moiety; R.sub.2 is preferably hydrogen.

[0020] In another aspect of the invention, the alcohol alkoxylate polymer comprises one or more glyceride esters represented by formula (I) when at least at least one R.sub.1 is an acyl moiety (COR) with R being defined as above; and R.sub.2 is a hydrogen or methyl moiety; R.sub.2 is preferably hydrogen.

[0021] For the presently disclosed invention; preferably, the alcohol alkoxylate is produced by reaction over a narrow range ethoxylation catalyst, more preferably over a calcium-containing ethoxylation catalyst providing for narrow range ethoxylated alcohols. Such catalysts and use thereof to produce ethoxylated alcohols are known to the person skilled in the art and exemplified by the teachings of, for example, U.S. Pat. No. 4,754,075, the disclosure of which is incorporated herein by reference for all purposes. Exemplary of a suitable calcium-containing ethoxylation catalyst is the proprietary catalyst system developed by Sasol (USA) Corporation and as disclosed in U.S. Pat. Nos. 4,775,653; 4,835,321; 5,220,077; 5,626,121; 8,329,609 and 9,802,879, the disclosures of which are all incorporated herein by reference for all purposes.

[0022] In yet another, and preferred, aspect, the alcohol alkoxylate polymer is a mixture comprising (i) a glyceride ester represented by formula (I) when at least one R.sub.1 is an acyl moiety (COR) with R being defined as above; and R.sub.2 is a hydrogen or methyl moiety, preferably hydrogen and (ii) a glycerine alkoxylate represented by formula (I) wherein R.sub.1 is hydrogen and R.sub.2 is a hydrogen or methyl moiety, preferably hydrogen. In this instance, when the alcohol alkoxylate polymer is a mixture, advantageously the glyceride ester component is present in from about 60 to 90 weight percent, preferably 70 to 80 weight percent, and the glycerine alkoxylate component is present in from 10 to 40 weight percent, preferably from 20 to 30 weight percent, based on total weight of the alcohol alkoxylate polymer present.

[0023] When the alcohol alkoxylate polymer comprises the glyceride ester, the ester itself, by virtue of its method of preparation, is generally a blend of mono-, di- and tri-ester glycerides wherein the mole ratio of said mono-, di- and tri-esters is typically 45-90:10-30:1-15 respectively.

[0024] The method of preparing glyceride esters suitable for the present invention is well known to the person skilled in the art and generally consists of the transesterification of fatty acid esters such as present in a seed oil with an alcohol under basic conditions. In the present invention such alcohol is a glycerine alkoxylate as described hereinabove and as represented by formula (I). Preferably the glycerine alkoxylate used to prepare the glyceride ester is represented by formula (I) and wherein R.sub.1 is hydrogen and R.sub.2 is hydrogen. Such preferred glycerine alkoxylate transesterification agents are well known in the art and can be obtained by reaction of glycerine with ethylene oxide and/or propylene oxide under basic conditions.

[0025] The methods for the preparation of glyceride esters are well known to the person skilled in the art and described for example in the publications, U.S. Pat. No. 5,403,509 or U.S. Pat. No. 7,989,411, both incorporated herein by reference for all purposes. In the present disclosure, the inventors have of preference chosen sustainable vegetable seed oils including sunflower oil, canola oil, corn oil, coconut oil, palm oil, soybean oil, hemp oil, and castor oil. Coconut oil and soybean oil are preferred due to an observed ability to impart a gloss result in the end application. Soybean oil is generally recognized as being a fatty acid ester of predominantly linoleic acid (C-18) and minor amounts of oleic acid (C-18) and palmitic acid (C-16); coconut oil being a fatty acid ester of mainly lauric acid (C-12) and a lesser amount of myristic acid (C-14). Full composition details of the various seed oils are well known in the literature, see for example descriptions provided in the Kirk-Othmer Encyclopedia of Chemical Technology, incorporated herein by reference for all purposes.

[0026] Use of the hereinabove defined composition is facilitated if the composition further contains an additional liquid component or solvent to facilitate transfer in the end application. The liquid can be an organic liquid, for example a light hydrocarbon or lower alcohol, for example glycerine, or preferably water. When present the liquid comprises from 40 to 80 weight percent of the total weight of the composition including the alcohol alkoxylate component.

[0027] Of convenience, the composition of the invention as described herein above can be stored, optionally in the presence of the additional liquid component, in a plastic bottle or an aerosol dispenser unit; optionally fitted with a dispensing device.

[0028] As mentioned, one of the primary uses intended for the above-described composition is as a gloss enhancing agent for exposed/visible elastomeric surfaces and notably those of rubber-based elastomers such as found in the sidewall of tyres, especially pneumatic tyres as associated with transportation and particularly automobiles. In this instance, the composition as disclosed hereinabove provides for a method of use, the method comprising: [0029] cleaning a target tyre sidewall; [0030] applying a thin film coating of the composition on said tyre sidewall and allowing the surface to dry, and optionally applying a second coating of the composition to the tyre sidewall.

[0031] To facilitate a better understanding of the present disclosure the following examples of preferred or representative embodiments are given. In no way should the following examples be read to limit, or to define, the scope of the invention.

[0032] The combined gloss index of the various compositions has been determined by projecting a beam of light at a fixed intensity and angle onto a surface and measuring the amount of reflected light at an equal but opposite angle with a 20/60/85 gloss meter for matte to mirror finishes. Test procedure ASTM D523 was followed as a Standard Test Method for Specular Gloss. Haze measurements were taken in accordance with the ASTM E430 procedure.

[0033] Glycine alkoxylate adducts were prepared in a stirred batch reactor to react glycerine with ethylene oxide (EO) in the presence of a catalyst according to the details given in Table 1 below. The reaction was conducted under a nitrogen atmosphere (8 psi, and at a temperature of 175 C.). The catalyst was the Sasol proprietary ethoxylation catalyst system as developed by Sasol (USA) Corporation and as disclosed in U.S. Pat. Nos. 4,775,653; 4,835,321; 5,220,077; 5,626,121; 8,329,609 and 9,802,879, the disclosures of which are all incorporated herein by reference for all purposes.

Examples

[0034]

TABLE-US-00001 TABLE 1 Preparation of Glycerine Alkoxylate Adducts Starter Alkylene G-AO molecule oxide Catalyst Adduct (pbw) (pbw) (pbw) Description 1 Glycerine EO Catalyst Gly-15EO pbw: 612 pbw: 4388 pbw: 7.5 R.sub.1 = hydrogen, R.sub.2 = hydrogen, Sum X = 15 2 Glycerine EO Catalyst Glycerine-50EO pbw: 45 pbw: 965 pbw: 1.5 R.sub.1 = hydrogen, R.sub.2 = hydrogen, Sum X = 50

[0035] Glyceride ester adducts were prepared by transesterification of a seed oil with a glycerine alkoxylate under base conditions, KOH (aq 40%), according to the details given in Table 2. It will be appreciated that the acyl group is derived from the seed oil and thus reflects the compositional make up of the respective seed oil. The reaction was conducted in a stirred batch reactor by first treating the glycerine alkoxylate with the base under a nitrogen purge for approximately 1 hour at 120 C. followed by dropwise addition while stirring, over a period of about 1 hour and at a temperature 100 C. of the seed oil. The resulting glyceride ester was then reduced in temperature to 80 C and neutralized by the addition of formic acid.

TABLE-US-00002 TABLE 2 Preparation of Glyceride Ester Adducts Seed Transesteri- Formic G-Est Oil fication Base Acid Adduct (pbw) alcohol (pbw) (pbw) (pbw) Description 1 Soybean Gly-15EO 5 5 SOE-15 oil pbw: 350 R.sub.1 = acyl, pbw: 150 R.sub.2 = hydrogen, Sum X = 15 2 Coconut Gly-50EO 5 5 CNOE-50 oil pbw: 350 R.sub.1 = acyl, pbw: 150 R.sub.2 = hydrogen, Sum X = 50

[0036] Various compositions/systems were applied onto identical tyre specimens. The tyre composition was applied to a piece of a used lawn mower golf cart tyre size: 18/8.50/8 sidewall rubber. The tyre composition was left to dry and/or adsorb the composition for two (2) hours in well ventilated space. Twenty-degree (20), Sixty-degree (60), and Eighty-five (85) gloss ratings were taken in triplicate with a BYK Handheld Tri-Gloss-Meter. The results were averaged and summed to get a Combined Gloss Index. A higher gloss index value generally equates to a better performance and a more desirable wet look.

[0037] The compositions are detailed in Table 3 along with their observed combined gloss index.

TABLE-US-00003 TABLE 3 Components (pbw) System 1 System 2 System 3 System 4 Gly-15EO 20 Gly-50EO 40 SOE-15 20 CNOE-50 40 Soybean oil 30 Glycerine 30 Linear paraffin solvent 50 Distilled water 50 60 60 Combined Gloss Index 46.5 52.6 57.1 34.4

[0038] By way of comparison, a selection of commercially available tyre-dressing compositions containing between twenty percent (20%) to fifty percent (50%) by weight silicone in solvent mixtures were similarly evaluated and observed as having a combined gloss indices of 18, 42, 98 and 138. The higher the silicone oil content generally the higher the gloss index. The combined gloss index for the compositions/system reported in this disclosure clearly demonstrate that tyre-dressing compositions of acceptable performance can be obtained in the absence of a silicone oil.