BUSHING AND METHOD FOR PRODUCING GLASS FIBER
20230416141 ยท 2023-12-28
Inventors
Cpc classification
C03B37/02
CHEMISTRY; METALLURGY
International classification
Abstract
The present invention addresses the problem of providing a bushing that allows molten glass to be stably drawn out from nozzles provided in a small-sized base plate, and a method for producing glass fiber. A bushing (11) is configured to satisfy the following relations (1) to (6): y1Yy2 (1), y1=4/3X+3 (2), y2=4/3X+8 (3), X=D1.sup.4/Lt (4), Y=A3(A1+A2) (5), and A3=L1L2 (6), where, for first nozzles (N1) and second nozzles (N2) in the bushing (11), D1 is a nozzle hole inner diameter [mm], Lt is a nozzle flow path length [mm], A1 is a nozzle hole cross-sectional area [mm.sup.2], A2 is a nozzle wall cross-sectional area [mm.sup.2], L1 is an interval [mm] between the centers of adjacent first nozzles and an interval [mm] between the centers of adjacent second nozzles, and L2 is an interval [mm] between the centers of adjacent first and second nozzle.
Claims
1. A bushing comprising: a base plate; and a nozzle group provided at a bottom surface of the base plate, wherein the nozzle group includes a first nozzle row in which a plurality of first nozzles are aligned, and a second nozzle row in which a plurality of second nozzles are aligned, the second nozzle row being arranged adjacent to the first nozzle row, and the bushing is configured to satisfy the following relations (1) to (6):
y1Yy2(1)
y1=4/3X+3(2)
y2=4/3X+8(3)
X=D1.sup.4/Lt(4)
Y=A3(A1+A2)(5)
A3=L1L2(6) where, for each of the plurality of first nozzles and the plurality of second nozzles, D1 is a nozzle hole inner diameter [mm], Lt is a nozzle flow path length [mm], A1 is a nozzle hole cross-sectional area [mm.sup.2], and A2 is a nozzle wall cross-sectional area [mm.sup.2], L1 is an interval [mm] between the centers of adjacent first nozzles in the first nozzle row and an interval [mm] between the centers of adjacent second nozzles in the second nozzle row, and L2 is an interval [mm] between the center of the first nozzle row in a row width direction and the center of the second nozzle row in the row width direction.
2. The bushing according to claim 1, wherein the bushing configured to further satisfy the following relation (7):
0.2X3.0.(7)
3. The bushing according to claim 1, wherein a mean value of arithmetic mean roughnesses Ra at an inner surface of a nozzle hole of each of the plurality of first nozzles and the plurality of second nozzles is 2 m or less.
4. A method for producing glass fiber, the method comprising: supplying molten glass to a bushing; drawing out a plurality of glass filaments from the bushing; and then gathering the plurality of glass filaments into a strand, wherein the bushing includes a base plate and a nozzle group provided at a bottom surface of the base plate, the nozzle group includes a first nozzle row in which a plurality of first nozzles are aligned, and a second nozzle row in which a plurality of second nozzles are aligned, the second nozzle row being arranged adjacent to the first nozzle row, and the foregoing relations (1) to (6) are satisfied:
y1Yy2(1)
y1=4/3X+3(2)
y2=4/3X+8(3)
X=D1.sup.4/Lt(4)
Y=A3(A1+A2)(5)
A3=L1L2(6) where, for each of the plurality of first nozzles and the plurality of second nozzles, D1 is a nozzle hole inner diameter [mm], Lt is a nozzle flow path length [mm], A1 is a nozzle hole cross-sectional area [mm.sup.2], and A2 is a nozzle wall cross-sectional area [mm.sup.2], L1 is an interval [mm] between the centers of adjacent first nozzles in the first nozzle row and an interval [mm] between the centers of adjacent second nozzles in the second nozzle row, and L2 is an interval [mm] between the center of the first nozzle row in a row width direction and the center of the second nozzle row in the row width direction.
Description
BRIEF DESCRIPTION OF DRAWINGS
[0013]
[0014]
[0015]
[0016]
DESCRIPTION OF EMBODIMENTS
[0017] An embodiment of a bushing and a method for producing glass fiber will be described below with reference to the accompanying drawings.
[0018] As illustrated in
[0019] The bushing 11 includes a bushing body 11a to which molten glass MG is supplied, and a base plate 11b provided at a bottom of the bushing body 11a. Although not illustrated, the bushing body 11a includes a supply port through which the molten glass MG is supplied, a screen for suppressing deposition of foreign matter on the base plate 11b, and a terminal for resistance heating.
[0020] The bushing 11 includes a nozzle group provided at a bottom surface 11b1 of the base plate 11b. The molten glass MG is supplied to the nozzles N, and glass filaments GF are drawn out from the nozzles N. The number of nozzles is preferably 800 to 10000, and more preferably 2000 to 8000. In the figure, the nozzle group of the bushing 11 is illustrated in a simplified manner.
[0021] As illustrated in
[0022] As illustrated in
[0023] As illustrated in
[0024] The bushing 11 is configured to satisfy the following relations (1) to (6).
y1Yy2(1)
y1=4/3X+3(2)
y2=4/3X+8(3)
X=D1.sup.4/Lt(4)
Y=A3(A1+A2)(5)
A3=L1L2(6)
[0025] Here, L1 represents an interval [mm] between the centers of adjacent first nozzles N1 in the first nozzle row R1 and an interval [mm] between the centers of adjacent second nozzles N2 in the second nozzle row R2. L2 represents an interval [mm] between the center of the first nozzle row R1 in a row width direction and the center of the second nozzle row R2 in the row width direction. In other words, L2 represents an interval [mm] between the center of one of the first nozzles N1 and the center of the second nozzle N2 located closest to this nozzle N1, that is, the interval [mm] between the centers of the first nozzle N1 and the second nozzle N2 adjacent to each other. A straight line passing through the center of the first nozzle row R1 in the row width direction and a straight line passing through the center of the second nozzle row R2 in the row width direction are parallel. The row width direction of the first nozzle row R1 is a direction parallel to the bottom surface 11b1 of the base plate 11b and orthogonal to the alignment direction of the first nozzles N1, and coincides with the X-axis direction, for example, in
[0026] The relation (4) above is an equation for obtaining a numerical value representing the degree of outlet velocity of the molten glass MG flowing out from the nozzle N. The larger the nozzle hole inner diameter D1, the faster the outlet velocity of the molten glass MG. On the other hand, the shorter the nozzle flow path length Lt, the faster the outlet velocity of the molten glass MG.
[0027] The relation (5) above is an equation for obtaining a value representing a size of a space around one nozzle N. Specifically, each nozzle arrangement area A3 indicated by the dotted pattern in
[0028] The nozzle hole inner diameter D1 [mm] is, for example, preferably in a range of 0.5 mm or more and 3.0 mm or less, and more preferably in a range of 0.8 mm or more and 2.0 mm or less. The nozzle flow path length Lt [mm] is preferably in a range of 1.5 mm or more and 8.0 mm or less, and more preferably in a range of 2.5 mm or more and 6.0 mm or less. The nozzle hole cross-sectional area A1 [mm.sup.2] is preferably in a range of 0.2 mm.sup.2 or more and 7.0 mm.sup.2 or less, and more preferably in a range of 0.5 mm.sup.2 or more and 5.0 mm.sup.2 or less. The nozzle wall cross-sectional area A2 [mm.sup.2] is preferably in a range of 0.6 mm.sup.2 or more and 4.9 mm.sup.2 or less, and more preferably in a range of 0.8 mm.sup.2 or more and 3.5 mm.sup.2 or less.
[0029] The bushing 11 is preferably configured to further satisfy the following relation (7), for example, from the viewpoint of more stably drawing out the molten glass MG from the nozzles N.
0.2X3.0(7)
[0030] A mean value of arithmetic mean roughnesses Ra at an inner surface Ns of the nozzle hole of each of the first nozzles N1 and the second nozzles N2 is preferably 2 m or less. This mean value of the arithmetic mean roughnesses Ra is more preferably 0.1 m or more, and still more preferably in a range of 0.3 m or more and 1.5 m or less.
[0031] The mean value of the arithmetic mean roughnesses Ra at the inner surface Ns of the nozzle hole can be adjusted by a shape of a drill used for drilling the nozzle hole or vibration of the drill. The mean value of the arithmetic mean roughnesses Ra at the inner surface Ns of the nozzle hole can also be adjusted by bringing a drill into contact with the inner surface Ns of the nozzle hole or annealing the inner surface Ns of the nozzle hole.
[0032] The mean value of the arithmetic mean roughnesses Ra is a value in an unused state before the molten glass MG is caused to flow. The mean value of the arithmetic mean roughnesses Ra can be measured as follows.
[0033] First, a plurality of nozzles N are manufactured under the same manufacturing conditions, and then a nozzle N to be measured is extracted as a sample from the plurality of nozzles N. Subsequently, the extracted sample is cut along a direction in which a hole axis of the nozzle hole extends (the direction corresponding to the Z-axis direction in the bushing 11). Subsequently, the arithmetic mean roughness Ra of the inner surface Ns of the nozzle hole is measured along the direction in which the hole axis extends in accordance with JIS B 0601:2001.
[0034] For the measurement of the arithmetic mean roughness Ra, Surfcoder (manufactured by Kosaka Laboratory Ltd., product name: ET4000) is used. The measurement distance is 1 mm. The arithmetic mean roughness Ra is measured at six different positions.
[0035] Subsequently, a mean value of the arithmetic mean roughnesses Ra measured at the six positions is taken as the mean value of the arithmetic mean roughnesses Ra of the inner surface Ns. The nozzles N other than the sample for which the arithmetic mean roughnesses Ra were measured are regarded as having the same mean value as the mean value of the arithmetic mean roughnesses Ra in the sample.
[0036] The bushing 11 of the present embodiment further includes a plurality of cooling members 15 provided at the bottom surface 11b1 of the base plate 11b. The cooling members 15 cool the molten glass MG drawn out from the nozzles N. Examples of the cooling member 15 include a cooling fin and a cooling pipe having a flow path through which a cooling medium flows.
[0037] Each cooling member 15 has a longitudinal direction and is arranged extending along the first nozzle row R1 and the second nozzle row R2. The plurality of cooling members 15 are arranged at predetermined intervals. In the bushing 11 of the present embodiment, two nozzle rows, the first nozzle row R1 and the second nozzle row R2, are arranged between the adjacent cooling members 15. But three or more nozzle rows may be arranged between the adjacent cooling members 15.
[0038] Examples of materials for the bushing body 11a, the base plate 11b, the nozzles N, and the cooling members 15 include noble metals and noble metal alloys. The noble metal is gold, silver, platinum, palladium, rhodium, iridium, ruthenium, or osmium. The materials for the bushing body 11a, the base plate 11b, the nozzles N, and the cooling members 15 are preferably platinum or a platinum alloy from the viewpoint of enhancing durability. Examples of the platinum alloy include a platinum-rhodium alloy.
[0039] Next, a method for producing glass fiber will be described.
[0040] In the method for producing glass fiber, the glass strand GS is produced by supplying the molten glass MG to the bushing 11 described above, drawing out the plurality of glass filaments GF from the bushing 11, and then gathering the plurality of glass filaments GF into a strand.
[0041] The viscosity of the molten glass MG at the forming temperature at which the glass filaments GF are formed is preferably in a range of from 10.sup.2.0 to 10.sup.3.5 dPa.Math.s, and more preferably in a range of from 10.sup.2.5 to 10.sup.3.3 dPa.Math.s. Here, the viscosity of the molten glass MG refers to the viscosity of the molten glass at a position where the molten glass flows into the nozzles N.
[0042] Examples of the form of the glass fiber include the cake CA in which the glass strand GS is wound. The glass strand GS can be used as, for example, chopped strands cut to a predetermined length, milled fibers, rovings, yarns, mats, fabrics, tapes, or braided fabrics. Examples of applications of the glass fiber include vehicle applications, electronic material applications, building material applications, civil engineering applications, aircraft-related applications, shipbuilding applications, logistics applications, industrial machinery applications, and daily necessities applications.
[0043] Next, the actions and effects of the present embodiment will be described.
[0044] (1) The faster the outlet velocity of the molten glass MG flowing out from the nozzles N and the smaller the space around the nozzle N, the easier it is for the molten glass MG flowing out from the nozzles N to adhere between the adjacent nozzles N or the like. Here, the bushing 11 of the present embodiment is configured to satisfy the foregoing relations (1) to (6). That is, in the bushing 11 of the present embodiment, since Y is equal to or greater than y1, the space around the nozzle N can be suitably secured in accordance with the outlet velocity of the molten glass MG flowing out from the nozzle N. Thus, adhesion of the molten glass MG, flowing out from the nozzle N, between the adjacent nozzles N or the like can be suppressed. In the bushing 11 of the present embodiment, since Y is equal to or less than y2, the space around the nozzle N does not become excessively large with respect to the outlet velocity of the molten glass MG flowing out from the nozzle N. Thus, an increase in the production cost of the bushing 11 can be prevented. Therefore, the molten glass MG can be stably drawn out from the nozzles N provided in the small-sized base plate 11b. This can, for example, reduce the occurrence of breakage of the glass filament GF.
[0045] (2) The bushing 11 is preferably configured to further satisfy the foregoing relation (7). In this case, the molten glass MG can be more stably drawn out from the nozzles N.
[0046] (3) In the bushing 11, the mean value of the arithmetic mean roughnesses Ra at the inner surface Ns of the nozzle hole of each of the first nozzles N1 and the second nozzles N2 is preferably 2 m or less. In this case, the outlet velocity of the molten glass MG flowing out from the nozzle N can be made further uniform. Thus, adhesion of the molten glass MG, flowing out from the nozzle N, between the adjacent nozzles N or the like can be further suppressed. Therefore, the molten glass MG can be more stably drawn out from the nozzles N provided in the small-sized base plate 11b.
Modifications
[0047] The above embodiment can be implemented with the following modifications. The above embodiment and the following modifications can be implemented in combination within a technically consistent range. [0048] The cooling members 15 of the bushing 11 may be omitted. [0049] In the bushing 11, the nozzle hole inner diameters of the nozzles N, the plurality of first nozzles N1 and the plurality of second nozzles N2, may be the same or different from each other. When the nozzle hole inner diameters of the nozzles N are different from each other, a mean value of the nozzle hole inner diameters can be used as the nozzle hole inner diameter D1 [mm] in the foregoing relation (4). [0050] In the bushing 11, when Y in the relation (1) is equal to or less than y2, Y may further be equal to or less than y2a represented by the following equation (8), or equal to or less than y2b represented by the following equation (9).
y2a=4/3X+7(8)
y2b=4/3X+5(9) [0051] In the bushing 11, the flow path lengths of the nozzles N, the plurality of first nozzles N1 and the plurality of second nozzles N2, may be the same or different from each other. When the flow path lengths of the nozzles N are different from each other, a mean value [mm] of the flow path lengths of the nozzles N can be used as Lt in the foregoing relation (4). [0052] In the bushing 11, the nozzle hole cross-sectional areas of the nozzles N, the plurality of first nozzles N1 and the plurality of second nozzles N2, may be the same or different from each other. When the nozzle hole cross-sectional areas of the nozzles N are different from each other, a mean value of the nozzle hole cross-sectional areas [mm.sup.2] can be used as A1 in the foregoing relation (5). [0053] In the bushing 11, the nozzle wall cross-sectional areas of the nozzles N, the plurality of first nozzles N1 and the plurality of second nozzles N2, may be the same or different from each other. When the nozzle wall cross-sectional areas of the nozzles N are different from each other, a mean value of the nozzle wall cross-sectional areas [mm.sup.2] can be used as A2 in the foregoing relation (5). [0054] the intervals between the centers of the first nozzles N1 may be the same or different from each other. When the intervals between the centers of the first nozzles N1 are different from each other, a mean value calculated from the interval [mm] between the centers of the first nozzles N1 and the interval [mm] between the centers of the second nozzles N2 can be used as L1 in the foregoing relation (6). [0055] the intervals between the centers of the second nozzles N2 may be the same or different from each other. When the intervals between the centers of the second nozzles N2 are different from each other, a mean value calculated from the interval [mm] between the centers of the second nozzles N2 and the interval [mm] between the centers of the first nozzles N1 can be used as L1 in the foregoing relation (6). [0056] A mean value of the intervals between the centers of the first nozzles N1 and a mean value of the intervals between the centers of the second nozzles N2 may be the same or different from each other. When the mean value of the intervals between the centers of the first nozzles N1 and the mean value of the intervals between the centers of the second nozzles N2 are different from each other, a mean value calculated from the intervals [mm] between the centers of the first nozzles N1 and the intervals [mm] between the centers of the second nozzles N2 can be used as L1 in the foregoing relation (6). [0057] In the bushing 11 of the above embodiment, each first nozzle N1 and each second nozzle N2 are arranged such that the center of each first nozzle N1 and the center of each second nozzle N2 are positioned on a straight line orthogonal to the alignment direction of the first nozzles N1 and the second nozzles N2 in the bottom view of the bushing 11. The arrangement of each first nozzle N1 and each second nozzle N2 is not limited to this arrangement. Each first nozzle N1 and each second nozzle N2 may be arranged such that either the center of each first nozzle N1 or the center of each second nozzle N2 is positioned offset from the straight line orthogonal to the alignment direction of the first nozzles N1 and the second nozzles N2 in the bottom view of the bushing 11. [0058] In the first nozzle row R1 of the bushing 11 of the above embodiment, the first nozzles N1 are arranged such that the centers of the first nozzles N1 are positioned on one straight line in the bottom view of the bushing 11. The arrangement of the first nozzles N1 is not limited to this arrangement. When not all the centers of the first nozzles N1 can be positioned on one straight line in the first nozzle row R1, the straight line may be set so that the sum of the intervals between the straight line and the centers of the first nozzles N1 is minimized. [0059] In the second nozzle row R2 of the bushing 11 of the above embodiment, the second nozzles N2 are arranged such that the centers of the second nozzles N2 are positioned on one straight line in the bottom view of the bushing 11. The arrangement of the second nozzles N2 is not limited to this arrangement. When not all the centers of the second nozzles N2 can be positioned on one straight line in the second nozzle row R2, the straight line may be set so that the sum of the intervals between the straight line and the centers of the second nozzles N2 is minimized. [0060] In the bushing 11 of the above embodiment, the straight line passing through the center of the first nozzle row R1 in the row width direction and the straight line passing through the center of the second nozzle row R2 in the row width direction are parallel, but these straight lines do not have to be parallel. However, in the bushing 11, the straight line passing through the center of the first nozzle row R1 in the row width direction should not intersect with the straight line passing through the center of the second nozzle row R2 in the row width direction. In this case, L2 represents an interval [mm] between the line passing through the center of the first nozzle row R1 in the row width direction and the line passing through the center of the second nozzle row R2 in the row width direction.
[0061] Next, examples and comparative examples will be described.
Examples 1 to 50
[0062] In Examples 1 to 50, glass fibers were produced using bushings having the values of X and the values of Y shown in Tables 1 and 2. The number of nozzles of the bushing is 100. The mean value of the arithmetic mean roughnesses Ra at the inner surface of the nozzle hole is 1.5 m. The viscosity of the molten glass at the forming temperature at which the glass filaments are formed is 10.sup.3.0 dPa.Math.s. The velocity at which the glass filaments are formed is in a range of 800 [m/min] or more and 3000 [m/min] or less.
Comparative Examples 1 to 16
[0063] In Comparative Examples 1 to 16, glass fibers were produced in the same manner as in Examples 1 to 50, except that bushings having the values of X and the values of Y shown in Table 3 were used.
Productivity of Glass Fiber
[0064] Glass strands were produced continuously for 30 days using the bushings of Examples 1 to 50 and the bushings of Comparative Examples 1 to 16. For the production of glass fibers for 30 days, the productivity of the glass fiber was evaluated using the following evaluation criteria. The evaluation results are shown in Tables 1 to 3.
[0065] When the average number of times of glass filament breakage is 10 times/day or less: (A) Productivity is high.
[0066] When the average number of times of glass filament breakage is more than 10 times/day but no more than 30 times/day: (B) Productivity is slightly low.
[0067] When the average number of times of glass filament breakage exceeds 30 times/day: (C) Productivity is low.
Effect of Reduced Material Usage
[0068] For the bushings of all examples, the bushings in which Y represented by the relation (1) was equal to or less than y2 were evaluated as having the effect of reducing the amount of the material used for the base plate (Good), and the bushings in which Y represented by the relation (1) exceeded y2 were evaluated as having no effect of reducing the amount of the material used for the base plate (Poor). The results are shown in Tables 1 to 3.
TABLE-US-00001 TABLE 1 Bushing Evaluation result Y = A3 Productivity Reduced X = D1.sup.4/Lt (A1 + A2) of glass fiber material usage Example 1 0.33 5.84 A Good Example 2 0.41 5.79 A Good Example 3 0.38 6.01 A Good Example 4 0.35 5.79 A Good Example 5 0.42 7.09 A Good Example 6 0.42 8.33 A Good Example 7 0.42 5.98 A Good Example 8 0.42 3.96 A Good Example 9 0.42 4.51 A Good Example 10 0.39 7.09 A Good Example 11 0.39 5.98 A Good Example 12 0.33 5.33 A Good Example 13 0.32 5.33 A Good Example 14 0.41 4.98 A Good Example 15 0.39 4.98 A Good Example 16 0.41 5.18 A Good Example 17 0.41 5.45 A Good Example 18 0.41 5.18 A Good Example 19 0.50 5.07 A Good Example 20 0.64 5.89 A Good Example 21 0.68 5.84 A Good Example 22 1.14 5.12 A Good Example 23 1.14 8.84 A Good Example 24 1.14 5.24 A Good Example 25 1.14 9.32 A Good
TABLE-US-00002 TABLE 2 Bushing Evaluation result Y = A3 Productivity Reduced X = D1.sup.4/Lt (A1 + A2) of glass fiber material usage Example 26 1.14 8.93 A Good Example 27 0.91 6.92 A Good Example 28 0.91 7.40 A Good Example 29 1.19 7.40 A Good Example 30 0.98 7.40 A Good Example 31 1.78 9.73 A Good Example 32 1.44 8.00 A Good Example 33 1.33 5.80 A Good Example 34 1.33 8.00 A Good Example 35 1.33 9.05 A Good Example 36 1.33 5.25 A Good Example 37 1.33 9.07 A Good Example 38 1.97 9.56 A Good Example 39 1.48 7.04 A Good Example 40 2.22 9.80 A Good Example 41 1.91 7.40 A Good Example 42 1.79 7.40 A Good Example 43 2.14 8.00 A Good Example 44 2.18 7.79 A Good Example 45 2.66 6.74 A Good Example 46 2.66 8.06 A Good Example 47 2.66 10.28 A Good Example 48 2.66 7.53 A Good Example 49 2.66 9.84 A Good Example 50 2.36 8.06 A Good
TABLE-US-00003 TABLE 3 Bushing Evaluation result Y = A3 Productivity Reduced X = D1.sup.4/Lt (A1 + A2) of glass fiber material usage Comparative 0.42 9.99 A Poor Example 1 Comparative 0.49 2.30 C Good Example 2 Comparative 0.41 2.30 C Good Example 3 Comparative 0.41 10.85 A Poor Example 4 Comparative 1.14 10.24 A Poor Example 5 Comparative 1.14 4.04 C Good Example 6 Comparative 1.14 10.07 A Poor Example 7 Comparative 1.14 3.75 C Good Example 8 Comparative 1.33 10.49 A Poor Example 9 Comparative 1.33 3.05 C Good Example 10 Comparative 1.33 11.01 A Poor Example 11 Comparative 1.33 4.01 C Good Example 12 Comparative 2.66 4.85 C Good Example 13 Comparative 2.66 12.65 A Poor Example 14 Comparative 2.66 5.40 C Good Example 15 Comparative 2.66 12.33 A Poor Example 16
[0069]
[0070] The bushings of Examples 1 to 50 were evaluated to have high productivity of the glass fiber. On the other hand, the bushings of Comparative Examples 2, 3, 6, 8, 10, 12, 13, and 15 were evaluated to have low productivity of the glass fiber. The bushings of Comparative Examples 1, 4, 5, 7, 9, 11, 14, and 16 cannot suitably reduce the amount of the material used for the base plate because the space around the nozzle is excessively large for the outlet velocity of the molten glass flowing out from the nozzle.
REFERENCE SIGNS LIST
[0071] 11 Bushing [0072] 11b Base plate [0073] 11b1 Bottom surface [0074] A1 Nozzle hole cross-sectional area [0075] A2 Nozzle wall cross-sectional area [0076] A3 Nozzle arrangement area [0077] CA Cake [0078] D1 Nozzle hole inner diameter [0079] GF Glass filament [0080] GS Glass strand [0081] Lt Nozzle flow path length [0082] L1 Interval between centers of adjacent nozzles in first nozzle row or second nozzle row [0083] L2 Interval between centers of first nozzle and second nozzle adjacent to each other [0084] MG Molten glass [0085] N Nozzle [0086] N1 First nozzle [0087] N2 Second nozzle [0088] Ns Inner surface [0089] R1 First nozzle row [0090] R2 Second nozzle row