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SCRATCH RESISTANT POLYMER COMPOSITION

20210032447 ยท 2021-02-04

    Inventors

    Cpc classification

    International classification

    Abstract

    Scratch resistant polymer composition, in particular for the manufacturing of rigid, scratch resistant and dimensionally stable building bricks, comprising: a) a bio-based HDPE granulate, produced from ethanol or ethylene obtained from biomass; b) an amorphous polymer and/or (semi)crystalline polymer; c) optionally a mineral filler and optionally a colouring pigment; Furthermore, a method for manufacturing an injection moulding article from the scratch resistant polymer composition is disclosed.

    Claims

    1. Scratch resistant building bricks or other pieces of toys obtainable by injection moulding a polymer composition comprising: a) a bio-based HDPE granulate, produced from ethanol or ethylene obtained from biomass; b) an amorphous and/or (semi)crystalline polylactic acid (PLA) based polymer; c) optionally a mineral filler and optionally a colouring pigment.

    2. Scratch resistant building bricks or other pieces of toys according to claim 1, wherein the mineral filler is selected from a group of mineral fillers including: talcum, mica, chalk, and kaolin.

    3.-7. (canceled)

    8. Scratch resistant building bricks or other pieces of toys according to claim 1, wherein the polymer composition further comprises a compatiblizer.

    9. Scratch resistant building bricks or other pieces of toys according to claim 8, wherein the compatiblizer is selected from the group consisting of: one or more of random copolymers, block or graft copolymers, nonreactive polymers containing polar groups, reactive functional polymers, or interfacial agents including SEBS G1650E, OPTIM E-156, ELVALOY PTW, LOTADER AX8900, and PEG2000.

    10. Scratch resistant building bricks or other pieces of toys according to claim 1, wherein the polymer composition further comprises a scratch resistant additive.

    11. Scratch resistant building bricks or other pieces of toys according to claim 10, wherein the scratch-resistant additive is selected from the group consisting of: silicone compounds including Genioplast Pellet S, Tegomer AntiScratch 100, Tegomer H-Si 6441P, polyester modified siloxane including Tegomer AntiScratch L, alkyl-modified siloxane including Cesa-scratch PEABNR12020, PPA0025889, PPA0025913, BYK-TS 3200 3201, Incroslip-G, Incroslip SL, IncoMold IncroMax.

    12. Method for manufacturing an injection moulding article from a polymer composition as defined in claim 1, wherein said method comprises providing said polymer composition and injection moulding said composition into the article.

    13. Articles, in particular building bricks, manufactured according to the method of claim 12.

    14. A method of using an amorphous and/or (semi)crystalline polylactic acid (PLA) based polymer in a polymer composition comprising HDPE to improve the dimensional stability, heat deflection temperature, scratch resistance and rigidity of the polymer composition or an article, in particular building bricks or other pieces of toys, that comprise said polymer composition.

    15. Scratch resistant building bricks or other pieces of toys according to claim 1, wherein the mineral filler has a particle size distribution containing a substantial number of particles between 0 and 100 m.

    16. Scratch resistant building bricks or other pieces of toys according to claim 1, wherein the amount of mineral filler is in the range from about 1 wt % to about 40 wt % based on the total polymer composition.

    17. Scratch resistant building bricks or other pieces of toys according to claim 1, wherein the amount of mineral filler is in the range from about 5 wt % to 25 wt %, based on the total polymer composition.

    18. Scratch resistant building bricks or other pieces of toys according to claim 1, wherein the amount of mineral filler is about 15 wt % based on the total polymer composition.

    19. Scratch resistant building bricks or other pieces of toys according to claim 1, wherein the amount of the amorphous and/or (semi)crystalline polylactic acid (PLA) based polymer is in the range from about 10 wt % to about 50 wt % based on the polymer composition.

    20. Scratch resistant building bricks or other pieces of toys according to claim 1, wherein the amount of the amorphous and/or (semi)crystalline polylactic acid (PLA) based polymer is in the range from about 15 wt % to 40wt %, based on the polymer composition.

    Description

    [0034] The calculated scratch hardness numbers of the prepared compounds are depicted in FIG. 1.

    [0035] FIG. 1 shows a graph of the scratch hardness numbers of bio-based HDPE+talcum and blends with 20/40% POM, CAB and PMMA. ABS is shown as a reference material.

    [0036] From FIG. 1 it can be seen that the scratch hardness numbers increase when a Bio-based HDPE/talc compound is blended with POM, CAB or PMMA thermoplastics.

    [0037] Finally, the following is noted.

    [0038] In the meantime, the Brazilian plastics manufacturer BRASKEM has gained/acquired some fame by producing green polyethylene from sugar cane.

    [0039] The production of ethylene is performed by dehydration of ethanol in the presence of catalysts.

    [0040] During this process, contaminants formed are removed by means of a number of purification steps. The dehydration process produces water as a by-product, which can be utilized in industrial processes or in agricultural applications.