METHOD AND COMPOSITION FOR MOISTURE INGRESS PROTECTION, AND ELECTRONIC DEVICE COMPRISING SAME
20210217543 ยท 2021-07-15
Inventors
Cpc classification
G01L1/18
PHYSICS
H01C17/00
ELECTRICITY
G01L1/20
PHYSICS
H01C10/106
ELECTRICITY
H01C1/028
ELECTRICITY
International classification
G01L1/20
PHYSICS
Abstract
A method includes coating at least one conductive element of an electronic device with an electrically non-conductive thixotropic liquid. An electronic device includes a first layer including an upper conductive element, a second layer including a lower conductive element, and a spacer positioned between the layers. The first layer, the second layer, and the spacer define a sensing chamber in which the upper and lower conductive elements move to vary the resistance of the electronic device. A non-conductive thixotropic liquid is present within the sensing chamber. Movement of the layers toward each other displaces the thixotropic liquid from an initial state coating at least one of the conductive elements to permit contact between the conductive elements, and movement of the first layer and the second layer away from each other returns the thixotropic liquid to the initial state.
Claims
1. A method for reducing moisture-based damage or interference within an electronic device, the method comprising: coating at least one conductive element of the electronic device with an electrically non-conductive thixotropic liquid.
2. The method as recited in claim 1, wherein the thixotropic liquid includes a thixotropic liquid exhibiting a viscosity ranging from about 140 cP to about 1800 cP at 40 C.
3. The method as recited in claim 1, wherein coating at least one conductive element of the electronic device includes coating the thixotropic liquid to exhibit a thickness ranging from about 10 nm to about 500 m.
4. The method as recited in claim 1, wherein coating at least one conductive element of the electronic device includes coating the thixotropic liquid to exhibit a thickness ranging from about 100 nm to about 10 m.
5. The method as recited in claim 1, wherein coating at least one conductive element of the electronic device includes coating only a single conductive element of the electronic device with thixotropic liquid.
6. The method as recited in claim 1, wherein coating at least one conductive element of the electronic device includes coating two opposing conductive elements of the electronic device with thixotropic liquid.
7. The method as recited in claim 1, wherein coating of the at least one conductive element of the electronic device is performed via screen printing.
8. The method as recited in claim 1, wherein coating of the at least one conductive element of the electronic device is performed via inkjet printing.
9. The method as recited in claim 1, wherein coating of the at least one conductive element of the electronic device is performed via vapor deposition.
10. An electronic device comprising: a first layer including an upper conductive element; a second layer including a lower conductive element facing the upper conductive element; a spacer positioned between the first layer and the second layer, with the first layer, the second layer, and the spacer collectively defining a sensing chamber; and an electrically non-conductive thixotropic liquid within the sensing chamber; wherein, in use, the first layer and the second layer are configured to move toward and away from each other within the sensing chamber to vary the resistance of the electronic device, and wherein movement of the first layer and the second layer toward each other displaces the thixotropic liquid from an initial state coating at least one of the upper conductive element and the lower conductive element to permit contact between the upper conductive element and the lower conductive element, and movement of the first layer and the second layer away from each other returns the thixotropic liquid to the initial state.
11. The electronic device as recited in claim 10, further comprising a vent in fluid communication with a channel defined by the first layer and the second layer.
12. The electronic device as recited in claim 11, wherein the vent is defined by the spacer.
13. The electronic device as recited in claim 10, wherein the thixotropic liquid fills a volume defined by the sensing chamber.
14. The electronic device as recited in claim 13, wherein the electronic device includes a vent through which at least a portion of the thixotropic liquid is expelled as the first layer and the second layer are moved toward each other.
15. The electronic device as recited in claim 10, wherein the thixotropic liquid includes a thixotropic liquid exhibiting a viscosity ranging from about 140 cP to about 1800 cP at 40 C.
16. The electronic device as recited in claim 10, wherein the thixotropic liquid has a thickness ranging from about 10 nm to about 500 m when in the initial state.
17. The electronic device as recited in claim 10, wherein the thixotropic liquid has a thickness ranging from about 100 nm to about 10 m when in the initial state.
18. The electronic device as recited in claim 10, wherein the lower conductive element includes a first electrode and a second electrode spaced apart from the first electrode.
19. The electronic device as recited in claim 18, wherein the upper conductive element is comprised of a force-sensing ink.
Description
BRIEF DESCRIPTION OF THE SEVERAL VIEWS OF THE DRAWINGS
[0019] These and other features, aspects, and advantages of the present invention will become better understood with regard to the following description, appended claims, and accompanying drawings where:
[0020]
[0021]
[0022]
[0023]
[0024]
[0025]
DETAILED DESCRIPTION OF EXEMPLARY EMBODIMENTS OF THE INVENTION
[0026] The details of one or more embodiments of the presently-disclosed subject matter are set forth below. Modifications to embodiments described below, and other embodiments, will be evident to those of ordinary skill in the art after a study of the present disclosure. The specific details of the described exemplary embodiments are provided primarily for clearness of understanding and no unnecessary limitations are to be understood therefrom. In case of conflict, the specification of this document, including definitions, will control.
[0027] While the terms used herein are believed to be well understood by one of ordinary skill in the art, definitions are set forth herein to facilitate explanation of the presently-disclosed subject matter.
[0028] Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which the presently-disclosed subject matter belongs. Although any methods, devices, and materials similar or equivalent to those described herein can be used in the practice or testing of the presently-disclosed subject matter, representative methods, devices, and materials are now described.
[0029] Following long-standing patent law convention, the terms a, an, and the refer to one or more when used in this application, including the claims.
[0030] As used herein, ranges can be expressed as from about one particular value, and/or to about another particular value. It is also understood that there are a number of values disclosed herein, and that each value is also herein disclosed as about that particular value in addition to the value itself. For example, if the value 10 is disclosed, then about 10 is also disclosed. It is also understood that each unit between two particular units are also disclosed. For example, if 10 and 15 are disclosed, then 11, 12, 13, and 14 are also disclosed.
[0031] The terms comprising, including, and having are intended to be inclusive and mean that there may be additional elements other than the listed elements.
[0032] As used herein, the term thixotropic liquid is understood to mean a non-Newtonian liquid whose viscosity decreases when stress, such as a compressive force, is imposed on it. For example, in some embodiments, the thixotropic liquid may comprise a liquid whose viscosity decreases with increased stress, such as shear-thinning liquids, while, in other embodiments, the thixotropic liquid may comprise a liquid whose viscosity decreases as the duration of stress applied increases.
[0033]
[0034] When a compressive force, F, is applied to the first layer 20 and/or the second layer 30, the upper conductive element 22 is moved toward, and ultimately into contact with, the lower conductive element 32, thereby decreasing resistance and increasing the conductivity of the force-sensitive resistor 10. As the compressive force, F, imposed on the force-sensitive resistor 10 is further increased and a greater portion of the upper conductive element 22 is placed in contact with the lower conductive element 32, the resistance of the force-sensitive resistor 10 is further decreased while the conductivity is further increased. Conversely, when the compressive force, F, is removed, the first layer 20 and the second layer 30, and thus the upper conductive element 22 and the lower conductive element 32, move away from each other, thus increasing the resistance and decreasing the conductivity of the force-sensitive resistor 10. In this way, the force-sensitive resistor 10 can thus be transitioned between a compressed configuration (
[0035] Referring still to
[0036] Referring still to
[0037] Referring now to
[0038] Referring still to
[0039] Referring now to
[0040] Referring again to
[0041] Referring still to
[0042] It is appreciated, however, that a variety of alternative thixotropic liquids may be used without departing from the spirit or scope of the present invention. For instance, it has been found that thixotropic liquids exhibiting a viscosity ranging from about 140 cP (centipoise) to about 1800 cP at 40 C. are particularly well suited to respond to the application and removal of compressive force, F, in the above-described manner and enable reliable readings to be acquired from the force-sensitive resistor 10.
[0043] Referring now again to
[0044] Referring still to
[0045]
[0046] As evidenced by viewing
[0047] Referring still to
[0048] Referring now to
[0049] Although discussed herein in the context of the force-sensitive resistors 10, 100 described above with reference to
[0050] The presently-disclosed subject matter is further illustrated by the following specific, but non-limiting, examples. The following examples may include compilations of data that are representative of data gathered at various times during the course of development and experimentation related to the present invention.
EXAMPLES
[0051] The experimental procedure for providing evidence of the innovation is described below. The force sensors with and without coating were connected to devices that can harvest data from the sensor and the contacts were made watertight via either plastic, the ventilation point of the plastic housing was protected by an expanded PTFE membrane. The device can provide a digital output and in the test 16 bits digital signal was used. Thus, ranges from 0 to 65536 for zero to full load capacity of the sensor. In the examples and comparative examples provided below the digital output was provided indicating the signal output according to different loading and environmental conditions. The sensors were first tested using the device that provides a reference point. Then the sensors were subjected to different loading and environmental conditions (represented using digital output in the same manner of the sensor digital output). The sensors were tested repeatedly for a number of cycles. Then the sensors were tested again using the same conditions as during the first step. The result data were presented in Table 1 and Table 2. Table 1 shows the effect with cyclic loading at different load levels, and Table 2 shows the effect of water presence.
[0052] Example 1. With the structure as shown in
[0053] Example 2. This is the same as Example 1, apart from the fact that it was tested under a different load.
[0054] Example 3. This is the same as Example 1, apart from the fact that under the same load the signal output was slightly higher than that of Example 1.
[0055] Example 4. This is the same as Example 2, apart from the fact that under the same load the signal output was slightly lower than that of Example 1.
[0056] Example 5. This is a different force sensor of the same structure as Example 1, apart from 0.125 mm thickness of the spacer, and the use of thixotropic liquid 2, with 140 cPs viscosity at 20 C. and 0.94 g/cm.sup.3 density, that was applied using a dispensing device.
[0057] Example 6. This is the same as Example 5, apart from the fact that under the same load the signal output was slightly lower.
[0058] Example 7. This is the same as Example 6, apart from the fact that a different coating thixotropic liquid was used and the thixotropic liquid used to fill up the entire air gap volume of inside the sensor. The sensor maintain its force sensing function and it was shown in Table 3 the average and the variation of multiple incidences of 6.3% standard deviation.
[0059] Comparative example 1. This is the same structure as Example 1, apart from the fact that there was not any thixotropic liquid coating applied, the sensor material used were different.
[0060] Comparative example 2. This is the same as Example 6, apart from the fact that there was not any thixotropic liquid coating applied.
[0061] Comparative example 3. This is the same as Comparative example 2, apart from the fact that the load level was different during the cyclic testing.
[0062] Comparative example 4. This is the same as Comparative example 3, apart from the fact that the load level was different during the cyclic testing.
[0063] Comparative example 5. This is the same as Comparative example 4, apart from the fact that the load level was different during the cyclic testing.
[0064] Comparative example 6. This is the same as Comparative example 5, apart from the fact that the highly conductive electrode material used in the sensor was different.
[0065] Comparative example 7. This is the same as Comparative example 6, apart from the fact that the cyclic testing was carried out with frequent water contact to sensor and the protected contact housing.
[0066] Comparative example 8. This is the same as Comparative example 1, apart from the fact that the cyclic testing was carried out with frequent water contact to sensor and the protected contact housing.
[0067] Comparative example 9. This is the same as Comparative example 5, apart from the fact that the cyclic testing was carried out with frequent water contact to sensor and the protected contact housing.
[0068] Comparative example 10. This is the same as Comparative example 9, apart from the fact that the load level was different during the cyclic testing.
TABLE-US-00001 TABLE 1 Examples and comparative examples: Digital output before and after cyclic loading under different conditions. Post cyclic Cycle Pre loading and load Example 1 37547 38742 144,000 @ 48888 Example 2 37143 37693 144,000 @ 5441 Comparative 28723 5666 144,000 example 1 @ 38728 Comparative 38338 29039 144,000 example 2 @ 48888 Comparative 38475 5247 144,000 example 3 @ 44272 Comparative 38392 15255 144,000 example 4 @ 38728 Comparative 38729 17924 144,000 example 5 @ 44272 Comparative 41899 45065 144,000 example 6 @ 5441
[0069] Example 1 and Example 2 were tested using different load levels for the cyclic loading. They were tested at a maximum level of 49,000 and 5,500 respectively and 144,000 cycles for each of the examples. When tested prior and post to the cyclic loading with the same reference load, they both return near identical output (3.2% and 1.0% change respectively). There was not any degradation of the sensor, or at least not significant.
[0070] A few comparative examples demonstrated at different cyclic loading levels, as well as difference in sensor construction or material. The number of cycles tested were 144,000.
[0071] One comparative example, Comparative example 1, when tested at cyclic load maximum level of 40,000, the prior and post to the cyclic loading results shown a massive degradation in sensor output, down from 28,723 to 5,666 (down to below 20% of the output level).
[0072] Another comparative example, Comparative example 2, when tested at cyclic load maximum level of 49,000, the prior and post to the cyclic loading results shown a massive degradation in sensor output, down from 38,338 to 29,039 (down to 75.7% of the output level).
[0073] Another comparative example, Comparative example 3, when tested at cyclic load maximum level of 45,000, the prior and post to the cyclic loading results shown a massive degradation in sensor output, down from 38,475 to 5,247 (down to below 15% of the output level).
[0074] Another comparative example, Comparative example 4, when tested at cyclic load maximum level of 39,000, the prior and post to the cyclic loading results shown a massive degradation in sensor output, down from 38,392 to 15,255 (down to below 40% of the output level).
[0075] Another comparative example, Comparative example 5, when tested at cyclic load maximum level of 45,000, the prior and post to the cyclic loading results shown a massive degradation in sensor output, down from 38,729 to 17,924 (down to 46.3% of the output level).
[0076] Another comparative example, Comparative example 6, when tested at cyclic load maximum level of 5,500, the prior and post to the cyclic loading results shown a slight increase in sensor output, up from 41,899 to 45,065 (up to 107.6% of the output level).
TABLE-US-00002 TABLE 2 Examples and comparative examples: Digital output before and after cyclic loading under different conditions. Number of Post cyclic cycles and loading Prior load level with water Example 3 38211 2400 39029 @ 15353 Example 4 37639 16,200 38579 @ 48912 Example 5 31790 2400 31462 @ 42472 Example 6 30845 2400 29684 @ 35468 Comparative 45493 144,000 57505 example 7 @ 48888 Comparative 31076 16,200 24848 example 8 @ 48912 Comparative 39824 144,000 46129 example 9 @ 38728 Comparative 36370 144,000 46696 example 10 @ 5441
[0077] A set of experiments were carried out with present of water in frequent and direct contact with the sensor and its venting area. As demonstrated in Example 3, when cyclic tested at load maximum level of 16,000, 2,400 cycles, the prior and post to the cyclic loading results shown a near identical sensor output (slight increase of 2.1% of the output level).
[0078] Another example, Example 4, when tested at cyclic load maximum level of 49,000, 16,200 cycles, the prior and post to the cyclic loading results shown a near identical output (slight increase of 2.5% of the output level).
[0079] Another example, Example 5, when tested at cyclic load maximum level of 43,000, 2,400 cycles, the prior and post to the cyclic loading results shown a near identical output (slight decrease of 1.1% of the output level).
[0080] Another example, Example 6, when tested at cyclic load maximum level of 36,000, 2,400 cycles, the prior and post to the cyclic loading results shown a near identical output (slight decrease of 3.8% of the output level).
[0081] As shown above, the coated examples shown no water ingress resulted short circuit or adverse degradation due to water damage. A set of comparative examples were tested at different maximum load levels, as well as different sensors.
[0082] One comparative example, Comparative example 7, when tested at cyclic load maximum level of 49,000, 144,000 cycles, the prior and post to the cyclic loading results shown some massive increase of output (increase to 126.4% of the output level).
[0083] Another comparative example, Comparative example 8, when tested at cyclic load maximum level of 49,000, 16,200 cycles, the prior and post to the cyclic loading results shown significant degradation of output (decrease to 80.0% of the output level).
[0084] Another comparative example, Comparative example 9, when tested at cyclic load maximum level of 39,000, 144,000 cycles, the prior and post to the cyclic loading results shown some massive increase of output (increase to 115.8% of the output level).
[0085] Another comparative example, Comparative example 10, when tested at cyclic load maximum level of 5,500, 144,000 cycles, the prior and post to the cyclic loading results shown some massive increase of output (increase to 128.4% of the output level).
[0086] The increase in sensor output levels post to the cyclic loading was caused by water ingress.
TABLE-US-00003 TABLE 3 Example 7: Digital output during loading with average and standard deviation. Average Standard deviation Example 7 34865 6.3%
[0087] Example 7 shows that with multiple sensors tested with the filled liquid, the sensor function was normal or not significantly affected.
[0088] One of ordinary skill in the art will recognize that additional embodiments and implementations are also possible without departing from the teachings of the present invention. This detailed description, and particularly the specific details of the exemplary embodiments and implementations disclosed therein, is given primarily for clarity of understanding, and no unnecessary limitations are to be understood therefrom, for modifications will become obvious to those skilled in the art upon reading this disclosure and may be made without departing from the spirit or scope of the invention.