DISPERSION PAINT

Abstract

Presented and described is a dispersion paint containing, in each case based on the total weight of the dispersion paint, a) 1% to 15% by weight of pigment, b) 30% to 60% by weight of filler, c) 1% to 25% by weight of polymer, d) 0.1% to 3.5% by weight of alkali metal alkyl siliconate, e) 25% to 70% by weight of water, wherein the pH of the dispersion paint is from 10 to 12. Also described is a process for producing the dispersion paint. The dispersion paint is suitable for use in interior and/or exterior applications.

Claims

1. A dispersion paint comprising: (a) 1% to 15% by weight of pigment; (b) 30% to 60% by weight of filler; (c) 1% to 25% by weight of polymer; (d) 0.1% to 3.5% by weight of alkali metal alkyl siliconate; (e) 25% to 70% by weight of water; and (f) 005% to 3% by weight xonotlite and/or ettringite, wherein the pH of the dispersion paint is from 10 to 12 and the % by weight is based on the total weight of the dispersion paint.

2. The dispersion paint of claim 1, wherein the dispersion paint contains 0.1% to 2% by weight alkali metal alkyl siliconate.

3. The dispersion paint of claim 1, wherein the alkali metal alkyl siliconate is potassium methyl siliconate.

4. The dispersion paint of claim 1, wherein the pigment is selected from the group consisting of titanium dioxide, iron oxide yellow, arylide (monoazo), bismuth vanadate, perinone, rutile-tin-zinc, quinacridone, diketopyrrolopyrrole, iron oxide red, phthalocyanine blue, dioxazine, cobalt blue, ultramarine blue, phthalocyanine green, chromium oxide green, cobalt green, color carbon black, iron oxide black, pyrazoloquinazolone, naphthol AS monoazopigment, and mixtures thereof.

5. The dispersion paint of claim 1, wherein the filler is selected from the group consisting of dolomite, barium sulfate, feldspar, quartz, calcium carbonate, mica, kaolin, calcinated kaolin, talc, diatomaceous earth and mixtures thereof.

6. The dispersion paint of claim 5, wherein the filler is a mixture comprising at least calcium carbonate and kaolin.

7. The dispersion paint of claim 1, wherein the pH of the dispersion paint is from 10.5 to 11.5.

8. The dispersion paint of claim 1, wherein the pH of the dispersion paint remains substantially constant over a period of at least 4 weeks.

9. The dispersion paint of claim 1, wherein the dispersion paint comprises 2% to 23% by weight of polymer based on the total weight of the dispersion paint.

10. The dispersion paint of claim 9, wherein the polymer contains at least one polymer and/or copolymer based on at least one monomer selected from the group consisting of acrylic acid, acrylic acid derivatives, acrylic acid esters, methacrylic acid, methacrylic acid derivatives, methacrylic acid esters, styrene, styrene derivatives, N-vinylpyrrolidone, acrylonitrile, vinyl acetate, vinyl propionate, ethylenically unsaturated carboxylic acids, ethylenically unsaturated carboxylic acid esters, ethylenically unsaturated carboxylic acid anhydrides, ethylenically unsaturated carboxylic acid amides and carboxylic acid vinyl esters.

11. The dispersion paint of claim 1, wherein the dispersion paint further comprises at least one additive selected from the group consisting of dispersants, wetting agents, thickeners, stabilizers, defoamers and/or hydrophobizing agents.

12. A process for producing a dispersion paint comprising: (a) providing a composition comprising: (i) 1% to 15% by weight of pigment; (ii) 30% to 60% by weight of filler; (iii) 1% to 25% by weight of polymer; (iv) 0.1% to 3.5% by weight of alkali metal alkyl siliconate; and (v) 25% to 70% by weight of water; (b) dispersing the components recited in step a); and (c) adjusting the pH to a value of 10 to 12. wherein the % by weight is based on the total weight of the dispersion paint.

13. The process of claim 12, wherein: the composition comprises 0.1% to 2% by weight of the composition of alkali metal alkyl siliconate; the pigment is selected from the group consisting of titanium dioxide, iron oxide yellow, arylide (monoazo), bismuth vanadate, perinone, rutile-tin-zinc, quinacridone, diketopyrrolopyrrole, iron oxide red, phthalocyanine blue, dioxazine, cobalt blue, ultramarine blue, phthalocyanine green, chromium oxide green, cobalt green, color carbon black, iron oxide black, pyrazoloquinazolone and mixtures thereof; the pH of the dispersion paint is from 10.5 to 11.5, wherein the pH remains substantially constant over a period of at least 4 weeks; the composition comprises 2% to 23% by weight of the composition of polymer wherein the polymer comprises at least one monomer selected from the group consisting of acrylic acid, acrylic acid derivatives, acrylic acid esters, methacrylic acid, methacrylic acid derivatives, methacrylic acid esters, styrene, styrene derivatives, N-vinylpyrrolidone, acrylonitrile, vinyl acetate, vinyl propionate, ethylenically unsaturated carboxylic acids, ethylenically unsaturated carboxylic acid esters, ethylenically unsaturated carboxylic acid anhydrides, ethylenically unsaturated carboxylic acid amides, and carboxylic acid vinyl esters; and/or the composition further comprises at least one additive selected from the group consisting of dispersants, wetting agents, thickeners, stabilizers, defoamers and/or hydrophobizing agents.

14. A process for coating interior and/or exterior substrates comprising applying the dispersion paint of claim 1 to a substrate.

15. A method of stabilizing a dispersion paint comprising mixing 0.1% to 3.5% by weight of an alkali metal siliconate with the dispersion paint, wherein the % by weight is based on the total weight of the dispersion paint.

16. The dispersion paint of claim 1, wherein the dispersion paint contains 0.5% to 1.5% by weight alkali metal alkyl siliconate.

17. The dispersion paint of claim 1, wherein the pH of the dispersion paint is from 10.5 to 11.4.

18. The dispersion paint of claim 1, wherein the pH of the dispersion paint remains substantially constant over a period of at least 20 weeks.

19. The dispersion paint of claim 1, wherein the dispersion paint comprises 4% to 20% by weight of polymer based on the total weight of the dispersion paint.

Description

EXAMPLES

[0061] Dispersion paints having the following formulations reported in table 1 were produced by mixing the constituents stated in table 1, amounts added being in % by weight in each case.

TABLE-US-00001 TABLE 1 Constituent Formulation A Formulation B Titanium dioxide 6 11 Styrene acrylate (50% by 19 11 weight in water) Potassium methyl siliconate 1 1.5 Calcium carbonate 21.7 32.5 Kaolin 20.8 8 Alkaline compound 0.05 0.5 Defoamer 0.2 0.28 Thickener 0.5 0.75 Wetting agent 0.46 0.3 Water 30.29 34.17 pH 11.3 11.4

[0062] The formulations A and B showed a storage stability of more than 6 months without discolorations and were readily workable. In particular the formulations showed a good workability and after application afforded surfaces having a homogeneous overall impression. After 6 months, formulation A had a pH of 11.3 and formulation B had a pH of 11.4.