Light source with photoluminescence emitter
11860521 ยท 2024-01-02
Assignee
Inventors
Cpc classification
C09K11/7794
CHEMISTRY; METALLURGY
G03B21/204
PHYSICS
G03B33/12
PHYSICS
International classification
Abstract
A light source is provided that includes a laser operable to emit laser light at a wavelength in a range from 460 nanometers to 470 nanometers and a converter assembly arranged so as to absorb the laser light emitted by the laser and to emit photoluminescent light produced by the laser light and having a longer wavelength than the laser light. The converter assembly has a converter element with a ceramic doped with Eu.sup.3+ such that under irradiation of the laser light the converter assembly emits photoluminescent light in the red spectral range.
Claims
1. A light source, comprising: a laser operable to emit laser light at a wavelength in a range from 460 nanometers to 470 nanometers; a laser light wavelength stabilizer that comprises an active loop control with a loop control circuit that stabilizes the laser at an absorption wavelength of Eu.sup.3+ ions; and a converter assembly arranged to convert the laser light to photoluminescent light having a longer wavelength than the laser light, wherein the converter assembly comprises a converter element doped with Eu.sup.3+ such that under irradiation of the laser light the converter assembly emits photoluminescent light in a red spectral range.
2. The light source of claim 1, wherein the converter element has a red efficacy greater than 35 lm/W.
3. The light source of claim 1, wherein the converter element is made of a material selected from a group consisting of glass, sintered glass powder, phosphor powder embedded in glass, glass ceramic, and ceramic.
4. The light source of claim 1, wherein the converter assembly operates in remission.
5. The light source of claim 1, wherein the converter element comprises a material selected from a group consisting of a host scheelite lattice of Eu.sup.3+ ions, tungstate, Li.sub.3Ba.sub.2La.sub.3(MoO.sub.4)Eu.sup.3+, (Y.sub.1-xEu.sub.x).sup.2Mo.sub.3,O.sub.12, (Y.sub.1-xEu.sub.x).sub.2Mo.sub.4O.sub.15, Li.sub.3Ba.sub.2(La.sub.1-xEu.sub.x).sub.3(MoO.sub.4).sub.8, K(Y.sub.1-xEu.sub.x)(WO.sub.4).sub.2, Li(Y.sub.1-xEu.sub.x)(WO.sub.4).sub.2, Na(Y.sub.1-xEu.sub.x)(WO.sub.4).sub.2, MgY.sub.2-xEu.sub.x(WO.sub.4).sub.4, CaY.sub.2-xEu.sub.x(WO.sub.4).sub.4, Ca.sub.1-2xEu.sub.xLi.sub.xWO.sub.4, molybdate, vanadate, tungstate, tantalate, lanthanum, terbium, gadolinium, yttrium, and lutetium, wherein Eu replaces at least one of element in the material of the converter element in a percentage between 10% and 100%, wherein the material of the converter element further comprises an element selected from a group consisting of molybdate, vanadate, tungstate, tantalate, lithium, sodium, potassium, magnesium, calcium, and strontium.
6. The light source of claim 1, wherein the converter assembly comprises a heat spreader bonded to the converter element.
7. The light source of claim 1, wherein the converter element has a useful-light area with an anti-reflective layer.
8. The light source of claim 1, wherein the converter element has a non-useful-light area that is at least partially mirrored or is surrounded by a diffusely or specularly reflecting reflector.
9. The light source of claim 8, wherein the laser emits laser light at a wavelength in a range of 465 nm2 nm.
10. The light source of claim 1, wherein the laser light wavelength stabilizer comprises a heating element that regulates a temperature of the laser.
11. The light source of claim 1, further comprising a green emitting light emitting element.
12. The light source of claim 11, wherein the green emitting light emitting element emits green light through photoluminescence when irradiated by the laser.
13. The light source of claim 1, wherein the converter element is light-scattering so that scattered laser light combines with the photoluminescent light to emit purple colored light.
14. The light source of claim 1, further comprising: a photoluminescent emitter for emitting green photoluminescent light, wherein the laser and the converter element are matched to one another such that the converter element emits purple light which includes red photoluminescent light and scattered light from the laser; and a ratio of intensities of the red photoluminescent light and of the light from the laser is such that color coordinates of the purple colored light lie on a line emanating from the color coordinates of the photoluminescent light of the photoluminescent emitter and passing through an area around the white point at color coordinates cx=cy=0.33, the area being defined by color coordinate ranges of 0.31cx0.35 and 0.31cy0.35.
15. The light source of claim 1, further comprising a green emitter that, when combined with blue light from the laser and the red photoluminescent light from the converter element, generate white light.
16. The light source of claim 1, further comprising a lens for collimating light emitted by the converter assembly, wherein the laser light is directed to the converter assembly through the lens.
17. The light source of claim 16, wherein the lens has a passage into which an optical fiber is introduced to feed the laser light.
18. A digital projector comprising the light source of claim 1.
19. The digital projector of claim 18, wherein the converter element and the laser are configured so that the converter element emits purple light including a blue component from scattered laser radiation and a red component from photoluminescence excited by the laser, wherein the blue and red components are spatially split into blue and red light beams and each of the light beams is fed to a respective different one of two chips to generate colored sub-images.
Description
BRIEF DESCRIPTION OF THE FIGURES
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DETAILED DESCRIPTION
(13)
(14) The invention avoids this drawback by matching the intrinsically narrow-band laser with the narrow absorption spectrum of the Eu.sup.3+ ions. The surrounding medium has hardly any impact on the spectral position of absorption of the Eu.sup.3+ ions. Typically, absorption occurs at approximately 465 nm, as can also be seen from
(15) Another drawback of a blue LED as an excitation light source is its radiance or radiant flux which is orders of magnitude lower than that of a laser. Accordingly, a drawback of LED-based phosphor-converting light sources is their low luminance which is lower than the luminance that can be achieved with laser-excited ceramic converters by approximately a factor of 10. Accordingly, a phosphor converter light source with high luminance is provided. In this way, high luminous flux can be achieved with the same emitter area as with a phosphor converter LED.
(16) For a highest possible and most consistent possible luminous efficiency, luminance, and luminous flux, it is advantageous to stabilize the wavelength of the laser and to adjust it to the absorption frequency of the Eu.sup.3+ ions.
(17) In fact, it is not at all trivial from a technical standpoint to tune the blue laser the most precisely possible to the absorption wavelength of 465 nm of the Eu.sup.3+ transition .sup.7F.sub.0.fwdarw..sup.5D.sub.2. The emission wavelength of diode lasers which are typically used in applications varies due to the manufacturing process and may also vary as a function of electrical current density and temperature.
(18) Nevertheless, diode lasers with an emission wavelength of 465 nm are commercially available and may be used for the excitation of Eu.sup.3+-doped red emitting photoluminescence converters without further wavelength stabilization. This is in particular true since in practice the diodes are often operated with previously known currents and within a limited temperature range. Optionally, diode lasers with the desired laser wavelength are selected from a production batch in order to meet the absorption wavelength of the Eu.sup.3+ transition .sup.7F.sub.0.fwdarw..sup.5D.sub.2.
(19) Alternatively, according to a further embodiment of the invention, means for stabilizing the laser wavelength are provided.
(20) In order to avoid the laser from shifting or changing its lasing wavelength during operation, it is possible according to one embodiment to use a laser that is stabilized by an external grating.
(21) According to a further embodiment, active loop control of the laser wavelength is suggested, which stabilizes the laser to the absorption wavelength of the Eu.sup.3+ using a loop control circuit of the light source. Loop control may be accomplished by adjusting a parameter which has an impact on the wavelength of the light. One such parameter is the temperature of the laser. By adjusting the laser's temperature, for example, optimization for maximum absorption is achieved.
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(23) More generally, without being limited to the specific illustrated example, it is contemplated according to one embodiment of the invention that the means 9 comprise a heating element 13 for regulating the temperature of the laser 3.
(24) The Eu.sup.3+-doped red emitting converter element 7 which is typically excited at 465 nm can advantageously be used for digital projection, since the color coordinates of its emission are very well suited to define the red vertex of a color space for projection. This is exemplified in
(25) In the arrangements illustrated by examples of
(26) Various red emitting ceramic converter materials have been experimentally investigated. The following table provides an overview of the composition of the examined materials.
(27) TABLE-US-00001 Components Sample Material Detected prior to Sinter # (main phase) secondary phase sintering density ca. 202003 (Y.sub.0.5EU.sub.0.5).sub.2Mo.sub.3O.sub.12) (Y.sub.0.5EU.sub.0.5).sub.2Mo.sub.4O.sub.15) Y.sub.2O.sub.3, Eu.sub.2O.sub.3, MoO.sub.3 93% 202007 (Y.sub.0.5EU.sub.0.5).sub.2Mo.sub.3O.sub.12) (Y.sub.0.5EU.sub.0.5).sub.2Mo.sub.4O.sub.15) Y.sub.2O.sub.3, Eu.sub.2O.sub.3, MoO.sub.3 95% 202009 (Y.sub.0.5EU.sub.0.5).sub.2Mo.sub.3O.sub.12) (Y.sub.0.5EU.sub.0.5).sub.2Mo.sub.4O.sub.15) Y.sub.2O.sub.3, Eu.sub.2O.sub.3, MoO.sub.3 94% 202201 (Y.sub.0.5EU.sub.0.5).sub.2Mo.sub.4O.sub.15) MoO.sub.3 Y.sub.2O.sub.3, Eu.sub.2O.sub.3, MoO.sub.3 95%
(28) In particular, the ceramic materials preferably used for the converter contain Eu.sup.3+ as an active element, and the host lattice of the Eu.sup.3+ is of the scheelite type. Without being limited to the examples in the table, the Eu containing compounds which are suitable for the converter may more generally comprise molybdates, vanadates, tungstates, or tantalates, preferably in ceramic form, and preferably these compounds additionally containing at least one of the following elements: lanthanum, terbium, gadolinium, yttrium, and lutetium. Here, according to one refinement of this embodiment, Eu replaces at least one of the mentioned elements in a percentage between 10% and 100%, preferably between 50% and 100%, more preferably between 70% and 95%.
(29) According to yet another embodiment, the luminescent Eu.sup.3+ containing material may be a molybdate, vanadate, tungstate or tantalate, while this compound additionally contains at least one of the following elements: lithium, sodium, potassium, magnesium, calcium, or strontium.
(30) The converter may be made of a single-phase ceramic. If the converter includes more than one phase, these phases may comprise the compounds mentioned above.
(31) The converter in particular does not contain any residues of MoO.sub.3, VO.sub.3, WO.sub.3, or TaO.sub.3.
(32) From among the above-mentioned samples, sample #202009 listed in the table above was used to experimentally verify the approach of the invention. The measurements were performed on a converter of 200 m thickness made from the sample. The converter was placed on a highly reflective mirror plate. The blue light of a 465 nm laser was irradiated onto the converter at an angle of 30. The emitted light intensity was resolved spectrally. The spectrometer used was a CAS 140+ with a measuring head coupled via a glass fiber bundle.
(33) The color coordinates shown in the table below were determined from the measured spectrum for the specified spectral ranges. These measurement results confirm that a material with purple color coordinates can be achieved.
(34) TABLE-US-00002 cx cy Blue 0.135 0.041 Blue and red 0.287 0.123 Red ( > 600 nm) 0.684 0.316
(35) A spectrum emitted by such a sample is shown in
(36) The lumen equivalent of the red spectrum is 292 lm/W. This means that a radiant flux of 1 W of the red emission corresponds to a photometric flux of 292 lm/W. The conversion efficiency, i.e. the ratio of emitted red light to the input power was estimated to be 33 lumen/W.
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(38) Thus, if the wavelength of the employed laser diodes is not stabilized, the wavelength can be adjusted solely through the temperature of the laser. The temperature of the converter need not be taken into account. For a commercially available 465 nm laser diode, a shift of 0.052 nm/K was measured.
(39) Generally, therefore, a digital projector is provided according to one embodiment of the invention, which comprises a light source 1 according to the invention. According to another embodiment, as in the example explained above, the converter 5 of light source 1 may advantageously furthermore comprise an element which emits green light through photoluminescence when irradiated by the laser 3, in addition to the luminescent inorganic converter element 7 comprising the Eu.sup.3+-doped ceramic. As mentioned before, LuAG, i.e. a lutetium aluminum garnet, is particularly suitable as the luminescent material of such an element. The green emitting element may in particular also be provided in the form of a ceramic material. However, green light, in particular for the projector mentioned, may also be generated in other ways than by photoluminescence. More generally, it is therefore contemplated according to one embodiment of the invention that the light source 1 comprises a green light emitting emitter, preferably in the form of the element as mentioned which emits green light through photoluminescence when irradiated by the laser 3.
(40) In principle, a converter can be operated in transmission or in reflection. In a reflection configuration, it may generally be advantageous to design the phosphor ceramic so as to be highly scattering in order to minimize a lateral enlargement of the emission spot for a given blue excitation spot. However, particularly in the case of materials with limited absorption of the blue light, this is typically also associated with strong backscattering of the blue light and thus with strong diffuse blue reflection. If the Eu.sup.3+-doped phosphor ceramic is design to be highly scattering, e.g. by introducing pores or other scattering centers, the combination of the red emission color coordinates with the blue remission can give purple emission color coordinates for the overall assembly. More generally, according to one embodiment of the invention, a converter assembly 5 is accordingly provided which comprises a luminescent inorganic converter element 7 comprising ceramic that is Eu.sup.3+ -doped such that the converter 5 emits photoluminescent light in the red spectral range when exposed to the laser light, and wherein the luminescent inorganic converter element 7 is designed to be light-scattering so that scattered blue laser light combines with the red photoluminescent light to give emitted purple-colored light.
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(42) TABLE-US-00003 Yellow Green Red efficacy efficacy efficacy [lm/W] [lm/W] [lm/W] Wavelength range 475 nm-780 nm 475 nm-600 nm 600 nm-780 nm Red emitter OC- 57.2 8.5 48.7 202009c Reference sample 317.0 282.9 34.1 Ce:YAG
(43) Thus, with 48.7 lm/W the red sample exhibits a red efficacy that is significantly better than that of a typical cerium-doped YAG converter which has a red efficacy of 34.1 lm/W. More generally, without being limited to particular exemplary embodiments described herein, it is therefore contemplated according to a further embodiment of the invention that the red efficacy of the converter material is greater than 35 lm/W.
(44) Emission of purple light may also arise if the phosphor is excited over an excessively broad band or in a manner not matched in terms of the spectrum. The reason for this may be the use of a large number of blue excitation lasers in order to achieve the laser output power required in high-performance projectors. These lasers usually do not emit exactly identically in terms of their spectrum and, overall, define a rather broadband excitation light source. However, this may even be advantageous, since it allows to dispense with the laser wavelength stabilization described above, but then causes an admixture of blue to the useful light and thus results in a purple light source. Irrespective of whether the lasers are all precisely matched to the Eu.sup.3+ absorption, a light source 1 may be provided comprising a plurality of lasers, in particular such that these lasers simultaneously irradiate the same spot of the converter.
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(46) For the two ceramics, the following color coordinates lying within the red color range are resulting:
(47) TABLE-US-00004 cx cy Curve 19 0.6823 0.3176 Curve 20 0.6843 0.3156
(48) In particular the weighting of the spectral components may vary, which may have an impact on the color coordinates of the emission, without however restricting the suitability of the material for use in projection. Materials are preferred in which the emission at 700 nm is not very pronounced, since the eye's sensitivity for light of this wavelength is only very low and thus it hardly contributes to the perceived brightness of the light.
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(50) In the embodiment according to panel (a), the luminescent inorganic converter element 7 is applied to a heat spreader 21. A reflector 22 may be applied to the heat spreader below the converter element 7, for example in the form of a dielectric or metallic reflection layer. The outwardly facing surface of the luminescent converter element 7 may be provided with an anti-reflective layer 23 in order to improve the emission of the light. The embodiments according to panels (b) and (c) also comprise a reflector 22 arranged between the heat spreader and the luminescent converter element 7. Here, the luminescent converter element 7 is arranged so as to be integrated in the heat spreader 21. For example, the heat spreader 22 may have an appropriate recess for this purpose. In the embodiment according to panel (c), the luminescent converter element 7 is integrated in a through-opening of the heat spreader 21, so that photoluminescent light can be emitted to both sides of the heat spreader and from both mouths of the through opening. In this embodiment, the inner surface of the through-opening may be provided with a reflector 22. In the case of transmissive operation, a dichroic reflector may be applied on the side of the excitation light, which transmits the blue excitation light and reflects the red emitted light.
(51) The purple emission as suggested according to the invention can be used for the projection. The red and blue color channels are generated from the purple phosphor by color wheel filtering.
(52) If emitted light that includes blue and red components, that is to say purple light, is used to produce different colors, in particular for a projector, it is furthermore generally favorable if the purple phosphor or the purple emission is designed such that the color coordinates on the purple line between the blue and red color coordinates are such that a connecting line to the green vertex of the color space passes through the white point. This embodiment is illustrated by
(53) Regardless of the configuration of the converter, that is also regardless of whether the converter comprises a color wheel or not, a light source is provided according to one embodiment of the invention, which comprises, in addition to the luminescent inorganic Eu.sup.3+ ions containing converter element 7, a further photoluminescent emitter for emitting green photoluminescent light, and wherein the laser 3 and the luminescent inorganic converter element 7 are matched to one another such that the ceramic element emits purple light including red photoluminescent light and scattered light from the laser 3, and wherein a ratio of the intensities of the red photoluminescent light and of the light from the laser 3 in the emitted light is such that the color coordinates 26 of the emitted purple light lie on a line 29 which starting from the color coordinates of the photoluminescent light of the further photoluminescent emitter passes through an area 27 around the white point at color coordinates cx=cy=0.33, which area 27 is defined by color coordinate ranges of 0.31cx0.35 and 0.31cy0.35. The area 27 around white point 25 is shown in
(54) In projector applications, the blue light is typically directed onto the converter material through a dichroic beam splitter to separate the blue from the yellow light path.
(55) As a result, the blue light cannot be mixed with the yellow light in such an optical configuration. This is at least the case for light that has the same polarization as the incident laser light. But even when using a polarization-dependent beam splitter, not more than 50% of the incident light can be reused.
(56) For this reason, a tilted beam configuration may be employed in white light applications for mixing yellow and blue light, which allows to laterally irradiate the excitation light from the laser and to collect the generated light including its blue component from the vertical direction. A problem with this approach is that the coupling efficiency is limited since the space required for emission of blue light cannot be used to combine the light beams. For example, if a lens 33 is used to collimate the light, the numerical aperture (NA) of the lens 33 is limited. An exemplary arrangement for this is shown in panel (a) of
(57) In particular if the blue laser beam 30 is directed onto the converter via one or more optical fibers 31, one or more channels or passages 32 for the fibers 31 may be provided in the respective collimation lens 33 in order to approach a fiber 31 as close as possible to the surface of the converter 5. Panel (d) of
(58) The converter assemblies shown in
(59) A light source 1 according to the invention may also be employed with particular advantage in a 3-chip projector. In principle, it is again possible here for the red and blue channels to be fed from the purple phosphor, i.e. the luminescent inorganic converter element 7. However, since the color channels are not superimposed sequentially in time in this case, but spatially, by a dichroic cross prism known as X-cube, the entire luminous flux emitted can be used in the projector, in principle without any filter loss. Such a projector is shown in
(60) As shown in
(61) The invention may also be used generally for lighting purposes. Particularly considered is the use for signaling lights such as for airport lighting, maritime signaling lights, warning lights on wind turbines and radio masts, in the field of special lighting such as stage lighting, effect lighting, architectural lighting.
(62) In order to be able to produce white light for general lighting purposes, the purple light may be combined with green light. The combining with a suitably adapted light source 1 may in particular be made in a way so that color coordinates in the vicinity of the white point are achieved, as can be seen from
(63) The use of the purple light produced by combining blue remission and red emission as described herein does not imply that the converter excited by laser light of 465 nm can only be used in this way. The red efficacy of more than 34 lm/W as already proven shows that a light source comprising a converter assembly which includes such a red emitting inorganic converter element is particularly advantageous also when not using the blue excitation light, depending on the application.
LIST OF REFERENCE NUMERALS
(64) 1 Light source 2 Projector 3 Laser 5 Converter assembly 7,8 Converter element 9 Means for stabilizing laser wavelength 11 Loop control circuit 13 Heating element 15 Light detector 16, 17, 19, 20 Emission spectrum 18 Edge filter 21 Heat spreader 22 Reflector 23 Anti-reflective coating 25 White point 26 Color coordinates of purple light 27 Area around 25 29 Line through 27 30 Laser beam 31 Optical fiber 32 Passage through 33 33 Lens 34 Mirror 35 Dichroic beam splitter 38, 39, 40 Chip 43 Dichroic cross prism 50 Light emitted by converter 5 51 Red sub-beam 52 Blue sub-beam 53 Green sub-beam 54 Image beam 91 Diffraction grating