APPARATUS AND METHOD FOR PRODUCING GLASS RIBBONS
20210024400 · 2021-01-28
Assignee
Inventors
- Alexander Glacki (Mainz, DE)
- Christian BREITBACH (Darmstadt, DE)
- Holger Hunnius (Mainz, DE)
- Ulrich Lange (Mainz, DE)
- Wolfgang Munch (Budenheim, DE)
- Gregor Rösel (Ginsheim-Gustavsburg, DE)
- Volker Seibert (Hochheim, DE)
- Holger Wegener (Alfeld, DE)
Cpc classification
Y02P40/57
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
C03B17/068
CHEMISTRY; METALLURGY
C03B17/062
CHEMISTRY; METALLURGY
International classification
Abstract
An apparatus is provided for drawing glass ribbons from molten glass. The apparatus includes a drawing tank for holding the molten glass and a guiding body. The tank has a lower nozzle opening through which the molten glass can exit downwards. The nozzle opening has two nozzle slots defined between the guiding body and edges of the nozzle opening. The guiding body protrudes downward out of the nozzle opening. The guiding body is supported so as to be spaced apart from the edges with the guiding body suspended in a self-supporting manner at least along a central section of the nozzle opening.
Claims
1. An apparatus for drawing glass ribbons from molten glass, the apparatus comprising: a drawing tank having an interior configured to hold the molten glass; a nozzle opening in the drawing tank through which the molten glass can exit downwards, the nozzle opening having edges; a guiding body that protrudes downward out of the nozzle opening, and a mount that supports the guiding body spaced apart from the edges of the nozzle opening to define two nozzle slots between the guiding body and the edges, respectively, wherein the guiding body is suspended, in a self-supporting manner, at least along a central section of the nozzle opening.
2. The apparatus of claim 1, wherein the guiding body is supported outside of the drawing tank and spans into the interior of the drawing tank.
3. The apparatus of claim 1, wherein the drawing tank has portions that define the nozzle opening, wherein the portions are removable while the guiding body remains on the mount.
4. The apparatus of claim 1, wherein the guiding body comprises a fine grain stabilized metal.
5. The apparatus of claim 4, wherein the fine grain stabilized metal is an alloy.
6. The apparatus of claim 4, wherein the fine grain stabilized metal comprises a metal selected from a group consisting of Pt, PtRh, PtAu, PtRhAu, PtIr, and ZrO.sub.2 particles.
7. The apparatus of claim 4, wherein the guiding body is entirely made of the fine grain stabilized metal.
8. The apparatus of claim 1, wherein the guiding body comprises a multi-piece body, wherein at least one component of the multi-piece body is made of fine grain stabilized metal.
9. The apparatus of claim 1, wherein the guiding body is a sandwich structure made of fine grain stabilized metal and a further material.
10. The apparatus of claim 1, wherein the guiding body has an inner portion that is enclosed by a lining.
11. The apparatus of claim 1, wherein the guiding body comprises at least one ceramic component which is coated with a fine grain stabilized metal.
12. The apparatus of claim 1, wherein the guiding body has a feature selected from a group consisting of: protruding out of the nozzle opening by at least 30 mm; protruding out of the nozzle opening by at least 80 mm; has a greater thickness in the interior of the drawing tank than at the nozzle opening, and has a lower end with a tear-off edge defining a cutting edge.
13. The apparatus of claim 1, further comprising a further guiding body arranged in the interior of the drawing tank above the guiding body, the further guiding body protruding out of the nozzle opening and spaced apart from the guiding body.
14. The apparatus of claim 1, wherein the guiding body comprises a resistance body and a blade arranged below the resistance body, wherein the resistance body has a greater width than the blade.
15. A method for producing a glass ribbon, comprising: feeding a molten glass to a drawing tank; causing the molten glass to exit the drawing tank from a lower nozzle opening of the drawing tank in two substreams so that the molten glass runs along a portion of a guiding body protruding out of the nozzle opening; combining the two substreams at a lower end of the guiding body to form a drawing onion; drawing the glass ribbon off the drawing onion, wherein the step of drawing of the glass ribbon exerts a tensile force on the guiding body; and absorbing the tensile force with a mount of the guiding body.
16. The method of claim 15, further comprising suspending the guiding body via the mount so that the guiding body is self-supporting at least along a section of the nozzle opening over which a central area of the glass ribbon is formed, the central area having a uniform thickness that is less than a thickness of two edge-side beads of the glass ribbon.
17. The method of claim 15, wherein the step of drawing the glass ribbon further comprises controlling a temperature of the molten glass to a forming temperature of more than 1100 C.
18. The method of claim 15, further comprising resting supported areas of the guiding body on support elements in the nozzle opening, wherein, between the supported areas, the guiding body is held in a self-supporting manner.
19. The method of claim 15, further comprising supplying electric current through the mounts to directly conductively heat the guiding body.
20. The method of claim 15, further comprising adjusting a temperature of the molten glass in the drawing tank so that for a temperature-dependent viscosity q thereof the following relationship applies:
Description
BRIEF DESCRIPTION OF THE FIGURES
[0021] The invention will now be explained in more detail with reference to the accompanying figures, wherein:
[0022]
[0023]
[0024]
[0025]
[0026]
[0027]
[0028]
[0029]
DETAILED DESCRIPTION
[0030]
[0031] It is generally preferred for the guiding body 11 to protrude from the nozzle opening 9 by at least 30 mm, preferably at least 80 mm. This ensures good distribution of the molten glass on the guiding body 11, so that variations in thickness of the glass ribbon are prevented.
[0032] Without being limited to the example shown, it may be favorable if the guiding body 11 comprises a resistance body 101 which is arranged inside the drawing tank 7 and consists of an thickened portion at the upper end of the guiding body 11, narrowing the flow cross section for the molten glass 5 compared to the downward adjoining portion of the guiding body 11. This lower portion of the guiding body 11 may be referred to as a fin or blade 103. Thus, more generally, it is suggested according to one embodiment of the invention that the guiding body 11 comprises a resistance body 101 and a blade 103 arranged below the resistance body 101, and that the resistance body 101 has a greater width than the blade 103 in order to restrict the flow cross section in the drawing tank 7.
[0033] Preferably, the distance from the nozzle opening 9 to the lower edge of the flow resistance or resistance body 101 will usually be at least 3 mm, preferably at least 8 mm.
[0034] In order to draw off the glass ribbon 3, a drawing device 17 may be provided, which may comprise one or more pairs of driven rollers, for example. The drawing causes a tensile force to be exerted on the glass ribbon 3, which typically acts at least mainly on the guiding body 11. This tensile force acts in the same direction and in addition to the weight force. In order to anchor the guiding body 11 and to absorb the acting forces, the guiding body 11 could be supported in the drawing tank using struts which are surrounded by the molten glass 5. Such support is very stable mechanically. However, it has been found that it might have adverse effects on the quality of the glass ribbon 3. In contrast thereto, the present disclosure generally contemplates that the guiding body 11 is suspended in a self-supporting manner along at least a central section of the nozzle opening 9. According to a further embodiment it may in particular be contemplated that a glass ribbon 3 is formed by the drawing, which has a central area of uniform thickness and two edge-side beads of greater thickness than that of the central area, and that the guiding body 11 is suspended in such a way that it extends in a self-supporting manner at least along the section of the nozzle opening along which the central area of uniform thickness is formed.
[0035]
[0036]
[0037] According to one embodiment of the invention, without being limited to the example shown, it is generally contemplated that the guiding body 11 in the drawing nozzle rests on the support elements 23 and is held on these support elements 23 in a self-supporting manner between the supported areas 21.
[0038] In general, the guiding body 11 is preferably designed such that it does not bend significantly when the glass ribbon is drawn off from the drawing tank 7 with a tensile force of greater than 100 N per 1000 mm glass ribbon width.
[0039]
[0040] This arrangement also has another advantage. The mounts of the guiding body 11 are decoupled from the drawing tank 7 in this way, so that portions of the drawing tank can be replaced without removing the guiding body 11. This applies in particular to the nozzle slot or portions of the drawing tank 7 which define the nozzle slot 9. In the illustrated example, bottom plates 97, 98 can be replaced, or more generally portions of the wall comprising the bottom plates, without removing the guiding body 11. This allows to exchange the bottom plates so as to modify the width of the nozzle opening 9 without having to move the guiding body 11 during that exchange. Without being limited to the specific example of
[0041] However, with self-supporting mounting of the guiding body 11, creep deformation may occur over time, particularly in the case of hot molten glass, under the influence of the weight force and the forces exerted by the drawing device 17. In order to reduce the creep effect the component incurs while being subjected to stress by high temperatures, intrinsic weight and the drawing force and in order to increase processing stability of the blade body and the nozzle material and hence to increase the service life of the apparatus 1, it is contemplated according to a preferred embodiment that the guiding body 11 comprises a fine grain stabilized metal.
[0042] In this regard,
[0043] Examples of fine grain stabilized metals include the materials marketed under the names PtRh10 FKS Rigilit, PtRh10 FKS Saeculit from Umicore, and PtRh10 DPH or DPH-A from Heraeus. In addition to the PtRh alloys on which the measured values of
[0044] Highly creep-resistant precious metals such as pure iridium are not preferred as an alternative, since they are generally less resistant to oxidation. It is generally also possible to coat ceramics with stabilized or partially stabilized alloys in order to increase the creep resistance and to prevent corrosion of the ceramics.
[0045] According to one embodiment, the guiding body 11 is made entirely of fine grain stabilized material. Particularly high creep resistance at high temperatures is achieved in this way. However, this increases material costs. Also, portions made of fine grain stabilized alloys are not easily welded, since the stabilizing particles may float up, which can significantly reduce the stability in the welding zone. Furthermore, these stabilized metals are more brittle than non-stabilized materials, due to the particles contained in the microstructure.
[0046] According to another embodiment, it is therefore contemplated to provide a multi-piece guiding body 11 which comprises at least one component that is made of fine grain stabilized metal. A multi-piece configuration is advantageous with respect to the lower material costs, but service life is somewhat shorter. In this case, the guiding body may in particular comprise a sandwich structure made of fine grain stabilized metal and at least one further material. Creep deformation is particularly relevant in areas subjected to high tensile stress. According to a further embodiment it is therefore contemplated that the guiding body 11 consists of a plurality of pieces and a lower portion of the guiding body 11 is a portion made of fine grain stabilized material. The term lower portion refers to the position of the portion with the guiding body 11 in its installed state.
[0047] In the example of
[0048] Several embodiments of the shape and structure of the guiding body 11 and nozzle opening 9 will now be explained in more detail. Generally, the shape of the tools can be optimized to improve their stability. Also, the pressure profile can be adjusted and the mixing of the molten glass can be improved.
[0049] If, for example, the guiding body 11 is in the form of a simple metal sheet of insufficient thickness inside the nozzle slot, then instabilities may result lengthways and crossways to the drawing direction under high load such as at more than 100 N per 1000 mm glass ribbon width and high temperature of 1200 C. and more. This will cause variations in the width of the nozzle slot and thus instabilities in the drawing process. Stability can be increased sufficiently by adapting the shape of guiding body 11.
[0050]
[0051] Another option is to use a highly creep-resistant metal for the core or inner portion 115, which however is less suitable for contact with the molten glass 5. What comes into consideration here are the highly creep-resistant noble metals already mentioned, such as pure iridium. According to one embodiment, it is therefore suggested that the guiding body comprises an inner portion 115 made of iridium, which is surrounded by a lining 117. The lining 117 may then again comprise a fine grain stabilized metal, at least in areas subject to tensile stress.
[0052] The pressure conditions can be adjusted through the geometry of the system consisting of the nozzle slot and flow resistance inside the drawing tank. Flow resistance and static pressure together cause a desired overpressure at the end of the drawing tank, i.e. at the nozzle opening. This ensures homogeneous glass distribution on the blade body. The geometric design of flow resistance on the guiding body inside the drawing tank and the design of nozzle slot width (spacing between the slot nozzle and the guiding body at the drawing tank outlet) provide means to adjust the pressure drop so that the molten glass at the nozzle outlet barely widens, so that wetting of the underside of the nozzle slot edge is avoided.
[0053]
[0054] The setting of the nozzle slot width also has an influence on the size of the tear-off angle on the lower edge of the nozzle. If this angle is too small, wetting with glass may occur below the edge of the nozzle, which might result in crystallization and glass defects. Without being limited to the exemplary embodiments, it is therefore contemplated according to one embodiment of the invention that the pressure drop of the molten glass 5 in the drawing tank is adjusted such that wetting of areas on the underside of the drawing tank 7 adjacent to the nozzle opening 9 is avoided. In addition to the position and shape of the one or more guiding body/bodies, the pressure drop may also be adjusted through the temperature of the molten glass.
[0055] Another advantage of an internal flow resistance in the form of the guiding body 11, optionally also a further guiding body 12, in the drawing tank 7 is the reduced sensitivity of the glass quality (e.g. with respect to thickness variations) in the case of existing or arising service life-related tool deformations during long-term use (e.g. compensation of drawing tank bulges, lowering of the blade body, inclination of the blade body, etc.), since a kind of compensation volume is created below the internal flow resistance, where the glass mass is allowed to homogenize in terms of its transverse distribution before it flows through the nozzle slot (only for a thickness ratio of blade to flow resistance in the drawing tank of <1).
[0056] With the adjustments presently described, the service life of the tools can be increased by at least one order of magnitude, which translates into a stabilization of product quality and also cost savings. Furthermore, an increase in the width of the ribbon is made possible, since adaptations to the geometry and the use of stabilized alloys translate into less pronounced bending or creep deformation even under the then increased tensile loads. The mechanically stabilizing thickening of the guiding body 11 in the drawing tank 7 as implemented in the exemplary embodiments illustrated so far generally also contributes to the longer service life. Without being limited to the specific exemplary embodiments, it is therefore contemplated according to a further embodiment that the guiding body 11 has a greater thickness inside the drawing tank 7 than at the nozzle opening 9. In the example shown in
[0057] In order to avoid unstable flow patterns at the end of guiding body 11, a sharply tapering tear-off edge 13 at the lower end of guiding body 11 is advantageous, as is the case in the examples of
[0058]
[0059] The thickening is advantageous for mechanical reasons, but is not mandatory.
[0060] Furthermore, it is not necessary in all embodiments of the apparatus that the guiding body 11 extends into the interior of the drawing tank 7. Rather, the upper end thereof may as well be located inside the nozzle opening 9. Such an embodiment is shown in
[0061] As shown in the plan view of
[0062] In the embodiment shown in
[0063] Another possibility for adjusting or controlling the thickness of the glass ribbon is by adjusting the temperature of the molten glass. In this respect, a particular further advantage is obtained by suspending the guiding body 11 in a self-supporting manner across the drawing tank. It is possible in this case to feed an electric current through the mounts 19 of the guiding body or through separate connections so as to conductively heat the guiding body directly. In this case, the current will flow through the guiding body 11 perpendicular to the drawing direction of the glass ribbon and also to the flowing direction of the molten glass 5. In the example shown in
[0064] According to a further embodiment of the invention, the pressure drop in the drawing tank is adjusted in a specific way in order to improve the shape accuracy and dimensional consistency of the glass ribbon. This adjustment prevents a negative pressure from developing in the drawing tank. Such negative pressure might mechanically deform the drawing tank, which may also affect the glass thickness. Moreover, a local negative pressure may cause an unstable flow pattern of the molten glass in the drawing tank, which may also result in an inhomogeneous glass thickness or in glass defects. The adjustment according to this embodiment will now be explained in more detail with reference to the schematic sectional view of the drawing tank 7 in
[0065] Similar to the example in
[0066] In the above relationship, {dot over (v)} is the volume flow of the molten glass, B is the width of the drawing tank 7 in the direction along the nozzle opening or along the glass ribbon perpendicular to the drawing direction, is the viscosity of the molten glass, D.sub.S is the local width of chamber 75, D.sub.L is the local thickness of guiding body 11, is the density of the molten glass, g is the gravitational acceleration, and h is the height of chamber 75. The integration is made over sections H.sub.L and H.sub.S in the vertical direction z. The integration may also be made over two or more sub-sections, in which case the sub-integrals then having to be added. This is the case if a plurality of guiding bodies are provided, which are separated apart from one another in the vertical direction, as in the example of
[0067] The symbol p.sub.u denotes a pressure magnitude of 2000 Pa. This magnitude accounts for a negative pressure that is still tolerable. Thus, the right side of the relationship represents the hydrostatic pressure of the molten glass reduced by the still tolerable negative pressure p.sub.u. This term is a constant. The prefactor {dot over (v)}/B defines the thickness of the glass ribbon which is predetermined so that the prefactor also represents a constant. On the other hand, what can be controlled through the temperature for a given thickness of the glass ribbon is the strongly temperature-dependent viscosity . The temperature may also be controlled differently locally. Also, the temperature in the drawing tank may vary along the vertical direction. Thus, the viscosity may be location-dependent, =(z). This dependency can accordingly also be taken into account in the integration.
[0068] It is thus contemplated according to one embodiment that the drawing tank 7 comprises a chamber 75 in which the guiding body 11 is arranged and which has the nozzle opening 9 at its lower end, and that the temperature of the molten glass 5 in the drawing tank 7 is adjusted such that the relationship given above is fulfilled with the temperature-dependent viscosity thereof.
[0069] It will be apparent to a person skilled in the art that the invention is not limited to the specific exemplary embodiments illustrated in the figures, but may be varied in many ways. Different embodiments may in particular also be combined with one another.
LIST OF REFERENCE NUMERALS
[0070] 1 Apparatus [0071] 3 Glass ribbon [0072] 5 Molten glass [0073] 7 Drawing tank [0074] 9 Nozzle opening [0075] 11, 12 Guiding body [0076] 13 Tear-off edge [0077] 15 Drawing onion [0078] 17 Drawing device [0079] 19 Mount [0080] 21 Supported area [0081] 23 Support element [0082] 25 Cavity [0083] 30 Central area of 3 [0084] 31, 32 Beads of 3 [0085] 50, 52 Substreams of 5 [0086] 70 Bottom of 7 [0087] 71 Lateral end plates [0088] 72 Opening in 71 [0089] 74 Inlet to 7 [0090] 75 Chamber [0091] 76 Manifold pipe [0092] 90, 92 Edges [0093] 94, 96 Nozzle slots [0094] 97, 98 Bottom plates [0095] 100 Protruding portion of guide body [0096] 191 Resistance body [0097] 103 Blade [0098] 110, 111 Cantilever arm [0099] 112 Upper portion [0100] 114 Lower portion [0101] 115 Inner portion [0102] 117 Lining [0103] 118 Thickening [0104] 130, 131 Surfaces converging at tear-off edge