Adhesive sheet

Abstract

The adhesive sheet for bonding an unvulcanized rubber to a metal, including a base cloth layer impregnated with a solvent dispersed type vulcanization adhesive having reactivity with the unvulcanized rubber; and an adhesive layer having reactivity with the metal.

Claims

1. An adhesive sheet for bonding an unvulcanized rubber to a metal, the adhesive sheet comprising: a base adhesive layer including a base cloth whose thickness ranges between 1 micrometer and 100 micrometers, wherein a solvent dispersed type vulcanization adhesive having reactivity with the unvulcanized rubber is completely impregnated in the base cloth; and an adhesive layer having reactivity with the metal, on the base adhesive layer.

2. An adhesive sheet according to claim 1, wherein the base adhesive layer and the adhesive layer are formed so that a surface of the adhesive layer and a surface of the solvent dispersed type vulcanization adhesive of the base adhesive layer are brought into contact with each other.

3. An adhesive sheet according to claim 1, wherein the adhesive layer comprises a layer of a primer.

4. A method of manufacturing an adhesive sheet for bonding an unvulcanized rubber to a metal, the method comprising: forming a base adhesive layer by completely impregnating a base cloth whose thickness ranges between 1 micrometer and 100 micrometers, with a solvent dispersed type vulcanization adhesive having reactivity with the unvulcanized rubber and drying the base cloth; and applying a primer having reactivity with the metal onto the base adhesive layer to form a layer of the primer.

5. The adhesive sheet as claimed in claim 1, wherein the base cloth is processed by a surface modification treatment prior to the impregnation of the base cloth.

6. The adhesive sheet as claimed in claim 5, wherein the surface modification treatment of the base cloth includes a resorcin-formalin-latex treatment.

7. The method as claimed in claim 4, wherein the forming the base adhesive layer including processing by a surface modification treatment prior to the impregnating a base cloth with the solvent dispersed type vulcanization adhesive.

8. The method as claimed in claim 7, wherein the surface modification treatment of the base cloth includes a resorcin-formalin-latex treatment.

Description

BRIEF DESCRIPTION OF DRAWINGS

(1) FIG. 1 is a schematic sectional view of an adhesive sheet according to a first embodiment of the present invention.

(2) FIG. 2 is a manufacturing flow diagram of the adhesive sheet according to the first embodiment of the present invention.

(3) FIG. 3 is a view for illustrating a method of using the adhesive sheet of the first embodiment of the present invention.

(4) FIG. 4 is a schematic sectional view of an adhesive sheet according to a second embodiment of the present invention.

(5) FIG. 5 is a manufacturing flow diagram of the adhesive sheet according to the second embodiment of the present invention.

(6) FIG. 6 is a view for illustrating a method of using the adhesive sheet of the second embodiment of the present invention.

(7) FIG. 7 is a schematic sectional view of an adhesive sheet according to a third embodiment of the present invention.

(8) FIG. 8 is a manufacturing flow diagram of the adhesive sheet according to the third embodiment of the present invention.

(9) FIG. 9 is a view for illustrating a method of using the adhesive sheet of the third embodiment of the present invention.

DESCRIPTION OF EMBODIMENTS

First Embodiment

(10) An adhesive sheet 1 for bonding an unvulcanized rubber to a metal is described as a first embodiment of the present invention with reference to FIG. 1. FIG. 1 is an illustration of a section of the adhesive sheet 1 according to the first embodiment of the present invention. The adhesive sheet 1 of the present invention includes a base cloth 11 and an undercoating adhesive layer 12. In this embodiment, the base cloth 11 and the undercoating adhesive layer 12 are formed so that the surfaces of the undercoating adhesive layer 12 and the layer of the base cloth 11 are brought into contact with each other.

(11) The base cloth 11 is a woven fabric or a nonwoven fabric. Its material is typically, for example, acrylic, acetate, an aramid (meta-type aramid), a high-performance polyethylene (ultrahigh-molecular weight polyethylene), nylon, vinyl, phenol, a polyurethane, a polyester, a polyethylene, a polyethylene terephthalate, a polyvinyl alcohol, a polypropylene, a carbon fiber (a pitch-based carbon fiber or a PAN-based carbon fiber), silicon carbide, an alumina fiber, steel, a ceramic fiber, a glass fiber, cotton, hemp, silk, or rayon. The thickness of the base cloth 11 is typically from 1 m to 100 m.

(12) The base cloth 11 is formed by impregnating a solvent dispersed type vulcanization adhesive having reactivity with the unvulcanized rubber. The solvent dispersed type vulcanization adhesive is typically an adhesive containing as a component at least one selected from, for example, a chlorosulfonated polyethylene, a chlorinated natural rubber, a maleimide-based compound, a nitroso-based compound, an acid scavenger, a cross-linking agent and cross-linking accelerator for a CSM rubber, carbon black, and a silica filler.

(13) The undercoating adhesive layer 12 is formed of an adhesive having reactivity with the metal. The adhesive is typically a primer. The layer is obtained by drying the primer. The undercoating adhesive layer 12 contains as a component at least one selected from, for example, phenol, a phenol-based derivative resin, resorcinol, a bisphenol-based epoxy resin, a polyfunctional aromatic epoxy resin, a chlorinated natural rubber, a chlorinated polyethylene, a chlorinated polypropylene, a chlorinated polyolefin, an acid scavenger, an amine-based curing agent, a silica-based filler, and carbon black.

(14) A method of manufacturing the adhesive sheet 1 of the first embodiment of the present invention is described with reference to FIG. 2. In the method of manufacturing the adhesive sheet 1 of the first embodiment of the present invention, first, the base cloth 11 is impregnated with the solvent dispersed type vulcanization adhesive having reactivity with the unvulcanized rubber (S101). Then, the layer is dried to form the layer of the base cloth 11 (S102). Subsequently, an undercoating adhesive having reactivity with the metal is applied onto the layer of the base cloth 11 (S103). The undercoating adhesive is dried to form the undercoating adhesive layer 12 having reactivity with the metal (S104).

(15) Subsequently, a method of bonding an unvulcanized rubber 22 to a metal 21 with the adhesive sheet 1 of the first embodiment is described with reference to FIG. 3. The adhesive sheet 1 is mounted on the metal 21 so that the undercoating adhesive layer 12 is brought into contact with the surface of the metal. Meanwhile, the adhesive sheet is arranged so that the base cloth 11 is brought into contact with the unvulcanized rubber 22. Then, in this state, the unvulcanized rubber 22 is pressed against the metal 21 to be bonded thereto. The metal 21 and the unvulcanized rubber 22 to each of which the adhesive sheet 1 is attached are loaded into a die together with, for example, a natural rubber, and then molded under heat.

(16) The surface of the base cloth 11 on a side to be bonded to the unvulcanized rubber 22 is subjected to a surface modification treatment. The surface modification treatment is typically, for example, surface modification based on the application of a surface treatment agent that reacts with the vulcanization adhesive well. Examples thereof include treatments, such as a resorcin-formalin-latex treatment (RFL treatment), a resorcin-hexamethylenetetramine-silica treatment, a resorcin-hexamethylenetetramine-epoxy resin treatment, an isocyanate treatment, an epoxy adhesive treatment, and a silane coupling treatment. In addition, plasma, a plasma polymerization treatment, a graft polymerization treatment, CVD, a PVD treatment, or an ion implantation treatment is available as surface modification based on a physical or chemical treatment. In addition, when the base cloth 11 is formed of an aramid fiber, a polyfunctional aziridine compound treatment, a plasma treatment, a treatment with a sulfonyl azide, an epoxy-based resin treatment, a treatment involving introducing a carboxymethyl group, a methacryloyl chloride treatment, a sizing treatment, a hot water treatment, or the like is typically available.

(17) The adhesive sheet 1 according to the first embodiment of the present invention is used as, for example, an adhesive for bonding a seismic isolation rubber for a building, a seismic isolation rubber for a bridge, or any other seismic isolation rubber for civil engineering and construction to be used in, for example, a site where the vulcanization bonding of a rubber and a metal is needed in civil engineering and construction to a metal. Alternatively, the adhesive sheet is used in, for example, an anti-vibration rubber for an automobile, such as an engine mount, a strut mount, a urethane damper, a PR bush, or an FR bush, or any other rubber part for an automobile. In addition, the adhesive sheet is used in, for example, an industrial rubber part, such as an oil seal for a construction machine or a crawler for a construction machine.

Second Embodiment

(18) Subsequently, an adhesive sheet 2 for bonding an unvulcanized rubber to a metal is described as a second embodiment of the present invention with reference to FIG. 4. FIG. 4 is an illustration of a section of the adhesive sheet 2 of the second embodiment of the present invention. The adhesive sheet 2 of the present invention includes a base cloth 11, an undercoating adhesive layer 12, and a top coating adhesive layer 13. The base cloth 11 and undercoating adhesive layer 12 of the adhesive sheet 2 are the same as those of the first embodiment. In this embodiment, in the base cloth 11 and the undercoating adhesive layer 12, the surfaces of the undercoating adhesive layer 12 and the layer of the base cloth 11 contact with each other. This embodiment differs from the first embodiment in that this embodiment includes the top coating adhesive layer 13 between the base cloth 11 and the undercoating adhesive layer 12. That is, the top coating adhesive layer 13 is the layer of a solvent dispersed type vulcanization adhesive having reactivity with the unvulcanized rubber, and the top coating adhesive layer 13 of the solvent dispersed type vulcanization adhesive having reactivity with the unvulcanized rubber is formed between the interface of the undercoating adhesive layer 12 and the interface of the layer of the base cloth 11. As in the first embodiment, the base cloth 11 is a woven fabric or a nonwoven fabric. A material for the base cloth 11 is as described in the first embodiment. The undercoating adhesive of the undercoating adhesive layer 12 is also the same as that of the first embodiment.

(19) The top coating adhesive layer 13 includes the same adhesive as the adhesive with which the base cloth 11 is impregnated. The top coating adhesive layer 13 exhibits an effect of compensating for the lack of the adhesive with which the base cloth 11 is impregnated. The thickness (amount) of the top coating adhesive layer 13 is selected in accordance with the base cloth 11. When the fiber density of the base cloth 11 is small and the content of the adhesive in the base cloth 11 is large, the thickness (amount) of the top coating adhesive layer 13 can be reduced. Meanwhile, when the fiber density of the base cloth 11 is large and the content of the adhesive in the base cloth 11 is small, the thickness (amount) of the top coating adhesive layer 13 is preferably increased.

(20) A method of manufacturing the adhesive sheet 2 of the second embodiment of the present invention is described with reference to FIG. 5. In the method of manufacturing the adhesive sheet 2 of this embodiment, first, the base cloth 11 is impregnated with the solvent dispersed type vulcanization adhesive having reactivity with the unvulcanized rubber (S201). Then, the layer is dried to form the layer of the base cloth 11 (S202). Subsequently, a top coating adhesive that is the solvent dispersed type vulcanization adhesive having reactivity with the unvulcanized rubber, the adhesive serving as the same component as the adhesive with which the base cloth 11 is impregnated, is applied onto the layer of the base cloth 11 (S203). The top coating adhesive is dried to form the top coating adhesive layer 13 (S204). Then, after the formation of the top coating adhesive layer 13, the undercoating adhesive having reactivity with the metal is applied (S205). Then, the undercoating adhesive is dried to form the undercoating adhesive layer 12 having reactivity with the metal (S206).

(21) Subsequently, a method of bonding the unvulcanized rubber 22 to the metal 21 with the adhesive sheet 2 of the second embodiment is described with reference to FIG. 6. The adhesive sheet 2 is mounted on the metal 21 so that the undercoating adhesive layer 12 is brought into contact with the surface of the metal 21. Meanwhile, the adhesive sheet is arranged so that the base cloth 11 is brought into contact with the unvulcanized rubber 22. Then, in this state, the unvulcanized rubber 22 is pressed against the metal 21 to be bonded thereto. The metal 21 and the unvulcanized rubber 22 to each of which the adhesive sheet 2 is attached are loaded into a die together with, for example, a natural rubber, followed by molding under heat.

(22) As compared to the first embodiment, this embodiment exhibits, in particular, the following effect: the top coating adhesive layer 13 compensates for the lack of the amount of the adhesive with which the base cloth 11 is impregnated in accordance with the material for the base cloth 11 to further strengthen the bonding of the unvulcanized rubber to the metal.

Third Embodiment

(23) Subsequently, an adhesive sheet 3 for bonding an unvulcanized rubber to a metal is described as a third embodiment of the present invention with reference to FIG. 7. FIG. 7 is an illustration of a section of the adhesive sheet 3 according to the third embodiment of the present invention. The adhesive sheet 3 of the present invention includes a base cloth 11, an undercoating adhesive layer 12, and a top coating adhesive layer 13. The base cloth 11 and undercoating adhesive layer 12 of the adhesive sheet 2 are the same as those of the first embodiment, and the surfaces of the undercoating adhesive layer 12 and the layer of the base cloth 11 are in contact with each other. This embodiment differs from the first and second embodiments in that the top coating adhesive layer 13 is formed on the surface of the base cloth 11 opposite to the surface in the base cloth 11 on which the undercoating adhesive layer 12 is formed. As in the second embodiment, the top coating adhesive layer 13 is the layer of a solvent dispersed type vulcanization adhesive having reactivity with the unvulcanized rubber. As in the first embodiment, the base cloth 11 is a woven fabric or a nonwoven fabric. A material for the base cloth 11 is as described in the first embodiment. The adhesive of each of the undercoating adhesive layer 12 and the top coating adhesive layer 13 is also the same as that of the first embodiment.

(24) The top coating adhesive layer 13 is the same as that of the second embodiment in that the layer includes the same adhesive as the adhesive with which the base cloth 11 is impregnated. The top coating adhesive layer 13 exhibits an effect of compensating for the lack of the adhesive with which the base cloth 11 is impregnated. The thickness (amount) of the top coating adhesive layer 13 is selected in accordance with the base cloth 11. When the fiber density of the base cloth 11 is small and the content of the adhesive in the base cloth 11 is large, the thickness (amount) of the top coating adhesive layer 13 can be reduced. Meanwhile, when the fiber density of the base cloth 11 is large and the content of the adhesive in the base cloth 11 is small, the thickness (amount) of the top coating adhesive layer 13 is preferably increased.

(25) A method of manufacturing the adhesive sheet 3 of the third embodiment of the present invention is described with reference to FIG. 8. In the method of manufacturing the adhesive sheet 3 of this embodiment, first, the layer of the base cloth 11 is impregnated with the solvent dispersed type vulcanization adhesive having reactivity with the unvulcanized rubber (S301). Then, the layer of the base cloth 11 is dried to form the layer of the base cloth 11 (S302). Subsequently, the undercoating adhesive having reactivity with the metal is applied onto the layer of the base cloth 11 (S303). Then, the undercoating adhesive is dried to form the undercoating adhesive layer 12 of the adhesive having reactivity with the metal (S304). Subsequently, the top coating adhesive that is the solvent dispersed type vulcanization adhesive having reactivity with the unvulcanized rubber, the adhesive serving as the same component as the adhesive with which the base cloth 11 is impregnated, is applied onto the surface of the base cloth 11 opposite to the surface of the base cloth 11 on which the undercoating adhesive layer 12 is formed (S305). The top coating adhesive is dried to form the top coating adhesive layer 13 (S306).

(26) Subsequently, a method of bonding the unvulcanized rubber 22 to the metal 21 with the adhesive sheet 3 of the third embodiment is described with reference to FIG. 9. The adhesive sheet 3 is mounted on the metal 21 so that the undercoating adhesive layer 12 is brought into contact with the surface of the metal 21. Meanwhile, the adhesive sheet is arranged so that the top coating adhesive layer 13 is brought into contact with the unvulcanized rubber 22. Then, in this state, the unvulcanized rubber 22 is pressed against the metal 21 to be bonded thereto. The metal 21 and the unvulcanized rubber 22 to each of which the adhesive sheet 3 is attached are loaded into a die together with, for example, a natural rubber, followed by molding under heat.

(27) As in the second embodiment, this embodiment also exhibits, in particular, the following effect: the top coating adhesive layer 13 compensates for the lack of the amount of the adhesive with which the base cloth 11 is impregnated in accordance with the material for the base cloth 11 to further strengthen the bonding of the unvulcanized rubber to the metal. The third embodiment has, in particular, an effect of improving adhesiveness with the unvulcanized rubber because the top coating adhesive layer 13 is formed outside the base cloth 11.

REFERENCE SIGNS LIST

(28) 1, 2, 3 adhesive sheet 11 base cloth 12 undercoating adhesive layer 13 top coating adhesive layer 21 metal 22 unvulcanized rubber