Prevent and remove organics from reservoir wells

Abstract

Plating bath and well structures and methods are described to stop the organic compounds present in plating reservoir wells or bath solution from rising, i.e., climbing up the reservoir wall. An electroplating apparatus includes a vessel holding a liquid solution including metal plating material and an organic species, and a method of operating an electroplating apparatus. The apparatus is designed with plating bath and structures and methods to stop the organic compounds present in plating reservoir wells or bath solution from rising, i.e., climbing or wicking up the inner surfaces of reservoir walls, and to wash them back down on a continuous or cyclical basis in order to maintain a concentration of organic compounds in the plating solution within upper and lower specification limits.

Claims

1. A method for operating an electroplating vessel, the vessel having walls configured to hold a liquid solution of a metal plating material and including an organic species, the liquid solution contained within the vessel at a first level below a top rim of the vessel, wherein when a workpiece is immersed in the liquid solution to displace a volume of the liquid solution resulting in the liquid solution level rising within the vessel to a second level above the first level, and wherein a barrier material lining is located on the walls of the vessel and at, or above, the second level, the method comprising: after immersing the workpiece, immersing a removable object in the liquid solution contained in the vessel; the removable object when immersed causing displacement of a volume of the liquid solution resulting in the liquid solution level rising within the vessel to the second level; and removing the removable object from the liquid solution, wherein when the removable object is removed, the liquid level is lowered to the first level while simultaneously washing the organics back into the solution.

2. The method of claim 1, wherein the removable object is a bladder.

3. The method of claim 2, further comprising inputting air into the bladder for expanding the bladder within the solution.

4. The method of claim 1, further comprising: repeating of the immersing and removal of the workpiece in the liquid solution and afterward the immersing and removing the removable object in the liquid solution in alternating fashion.

5. The method of claim 1, further comprising: monitoring a concentration of the organic species in the liquid solution in the vessel; and adding an amount of organic species back in the liquid solution to maintain a concentration of the organic species within an upper and lower limit.

6. The method of claim 1, further comprising a control device configured with the vessel, wherein the control device controls the timing of the immersing.

7. The method of claim 2, further comprising a control device configured with the vessel, wherein the control device controls expansion of the bladder.

8. The method of claim 2, further comprising a control device configured with the vessel, wherein the control device controls the amount of expansion of the bladder when the bladder is immersed in the liquid solution.

9. The method of claim 2, wherein the bladder is a balloon type structure and is composed of a material that is compatible to not compromise the liquid solution of the metal plating material.

10. The method of claim 2, wherein the bladder is solid object structure and is composed of a material that is compatible to not compromise the liquid solution of the metal plating material.

11. The method of claim 1, wherein the volume of the liquid solution resulting in the liquid solution level rising within the vessel to the second level caused by the removable object is less than the volume of the liquid solution resulting in the liquid solution level rising within the vessel to the second level caused by the workpiece.

12. The method of claim 1, wherein the barrier material lining is a glass, glassy carbon, or a ceramic.

13. The method of claim 1, wherein the barrier material lining is embedded in a groove that is cut into the walls of the vessel.

14. The method of claim 13, wherein the barrier material lining has a surface contiguous with the walls of said vessel.

15. The method of claim 1, wherein the metal plating material is nickel.

16. A method for operating an electroplating vessel, the vessel having walls configured to hold a liquid solution of a metal plating material and including an organic species, the liquid solution contained within the vessel at a first level below a top rim of the vessel, wherein when a workpiece is immersed in the liquid solution to displace a volume of the liquid solution resulting in the liquid solution level rising within the vessel to a second level above the first level, and wherein a removable liner is located on the walls of the vessel and at, or above, the second level, the method comprising: after immersing the workpiece, immersing a removable object in the liquid solution contained in the vessel; the removable object when immersed causing displacement of a volume of the liquid solution resulting in the liquid solution level rising within the vessel to the second level; and removing the removable object from the liquid solution, wherein when the removable object is removed, the liquid level is lowered to the first level while simultaneously washing the organics back into the solution.

17. The method of claim 16, wherein the removable liner is configured to be removed, cleaned and reused after the removing of the removable object.

18. The method of claim 16, wherein the removable liner is configured to be removed and discarded after the removing of the removable object.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) These and other objects, features and advantages of the present invention will become apparent from the following detailed description of illustrative embodiments thereof, which is to be read in connection with the accompanying drawings, in which:

(2) FIG. 1 depicts a first embodiment of an electroplating apparatus configured to prevent migration of organic species up inner wall surfaces of a vessel;

(3) FIG. 2 shows a top down view of the top of the electroplating apparatus of FIG. 1 according to the first embodiment;

(4) FIG. 3 depicts a second embodiment of an electroplating apparatus configured to prevent migration of organic species up inner wall surfaces of a vessel;

(5) FIG. 4 shows a top down view of the top of the electroplating apparatus of FIG. 3 according to the second embodiment;

(6) FIG. 5 depicts a third embodiment of an electroplating apparatus configured to prevent migration of organic species up inner wall surfaces of a vessel;

(7) FIG. 6 shows a top down view of the top of the electroplating apparatus of FIG. 5 according to the third embodiment;

(8) FIG. 7 depicts a fourth embodiment of an electroplating apparatus configured to prevent migration of organic species up inner wall surfaces of a vessel; and

(9) FIGS. 8A and 8B depict a wall portion of an electroplating apparatus vessel implementing a barrier material layer configured to prevent migration of organic species up the inner wall surface.

DETAILED DESCRIPTION

(10) FIG. 1 illustrates a diagrammatical cross-sectional view of an example electroplating (or electrodepositing) apparatus 10 according to one embodiment. In the description herein, for electroplating applications, an electroplating bath includes a liquid solution 25 that may be aqueous, and contain one or more chemicals or chemical species. These chemical species exist in certain concentrations in the solution. Some of these species interact or chemically react with a material or object, called a workpiece, which is placed in the bath, e.g., to add a film to a workpiece surface.

(11) For electroplating applications, the apparatus includes a plating vessel 12 (alternately referred to herein as a reservoir, container, or tank), e.g., an open box shape, that contains the bath 25 (liquid plating solution) forming an electroplating cell. A holding fixture 15 may be used to hold the article to be plated. In one embodiment, the article or workpiece is a semiconductor wafer 20. The article to be plated, i.e., the wafer 20, comprises the cathode (e.g., a negative electrode) in the electrolysis cell through which a direct electric current is passed. In another embodiment, the cathode is a separate element. The anode 16 is usually a bar of the metal being plated and is shown in the vessel below and separated from the wafer within the plating bath 25. While the workpiece (e.g., cathode) and the anode are shown in a vertical orientation within the cell in FIG. 1, it is understood that alternative embodiment may be employed where the both workpiece (e.g., cathode) and the anode are situated in a horizontal orientation within the plating vessel 12. Moreover, as shown in FIG. 2, the aqueous solution vessel or container 12 may be a square or rectangular shaped container, or may be round such as a circular or elliptical shaped.

(12) As known, the plating bath solution 25 serves as a conductive medium and utilizes a low direct current (d.c.) voltage. The wafer 20 that is to be plated is submerged into the plating bath 25 and a low voltage d.c. current is applied to the bath. In one embodiment, during electroplating process, via electrolysis, metal becomes deposited on to the workpiece (wafer) and metal from the anode bar 16 dissolves. An external circuit (not shown) consisting of a source of direct current (d.c.), conveys this current to the plating vessel, and associated instruments such as ammeters, voltmeters, and voltage regulators maintain current at the appropriate values. A power source including a rectifier may be used to convert alternating current (a.c.) power to a carefully regulated low voltage d.c. current. Other embodiments for providing electrical energy for the plating process would be known.

(13) In one embodiment, the plating bath well or reservoir wall structure 12 may be a polymer and is used in systems for plating fabricated semiconductor wafers and or wafer substrates 20 with a chemical species that include metals, e.g., Nickel, or alloys thereof such as solder, and other organic compounds (organic species) such as wetting agents. A minimum concentration of the surfactant is required in solution 25, and moreover, it is required that the surfactant concentration be maintained below an upper limit specification. Over time, the organic compounds (surfactant) present in the plating reservoir bath solutions 25 tend to rise, i.e., climb up, the inner surfaces of reservoir walls 17.

(14) In one aspect of the disclosure, for Nickel plating applications, the apparatus 10 includes a control scheme for replenishing one or even several of the depleted or consumed chemical and organic species in the solution. Replenishment, in one embodiment, is used to keep the bath concentration of the escaped organics species from decreasing below a lower concentration limit and increasing beyond an upper concentration limit. In one embodiment, the control scheme is provided to control bath composition variation by preventing organic components in the bath from escaping, i.e., migrating upwards along the inner side walls 17 of the vessel 12.

(15) In the control scheme depicted in the cross-sectional view of the apparatus 10 in FIG. 1, a source tank or reservoir 40 provides the solution 25a (metal plus surfactant in the desired chemistry). In one embodiment, a liquid flow of the solution 25a is provided from the top of the vessel 12 and down each inner side wall 17 of the tank or vessel 12 at times in between workpiece electroplating immersions. In a non-limiting embodiment, a liquid pump 50 and a conveyance or piping apparatus 60 operatively connected to the source tank 40 cooperate under logic control by a programmed processor or equivalent logic controller circuit 99, to feed liquid solution 25a over the top rim 18 of the vessel and down each inner sidewall surface. As further shown in the top down conceptual view of FIG. 2, the conveyance or piping apparatus 60 includes a portion 60 that is configured along the vessel perimeter and aligned with the rim of the vessel. This portion 60 includes the opening 65, e.g., an orifice or slit or series thereof, to generate a cascading flow of the liquid solution 25a that is pumped in apparatus 60. The opening 65 in the conveyance apparatus 60 may be continuous to create a waterfall effect of solution 25a over the top rim or top edge 18 of the container 12 at a force suitable to effect a wash or rinse down of any organics which have migrated up the inner cell wall surface 17 from the top down, along and around the perimeter of the vessel 12 and back into the reservoir solution 25. The piping apparatus 60 may include any liquid feed or conveyance device that is materially compatible with the metal plating solution and organics for conveying the solution above the top rim to produce the cascading waterfall effect via the opening 65 down the inner wall surfaces of the vessel.

(16) In a further embodiment in which liquid flow is provided down the inner side walls of the reservoir, an apparatus 100 is provided as shown in FIGS. 3 and 4, in which a cell 112 (a container) includes an inner wall 17 and outer wall 117 defining a seam or opening 122 there between in which the aqueous solution 25a is pumped. That is, a pumping apparatus including a source tank 40 of aqueous solution (metal plus surfactant in the desired chemistry) and a pump 50 (or 50), connected at 55 to the formed seam or opening 122, under logic control by logic controller circuit 99, pumps the solution 25a within the seam 122 thereby allowing the liquid solution 25a to cascade through an opening 128 in the inner wall 17 provided around the perimeter near the top of the inner wall 17 of cell 112. The solution may be pumped at times in between workpiece electroplating immersions to effect a wash or rinse down of any organics which have migrated up the inner cell wall surface 17 from the top down, along and around the perimeter of the cell 112 and back into the reservoir solution 25. Alternately, the pumped solution 25a within the seam 122 circulates the liquid flow 25a over the top of the inner wall 17 which functions as a weir configured around the perimeter of the container 112.

(17) Similar to the first embodiment, an apparatus 200 is provided in which liquid flow is provided down the inner side walls of the container 12, as shown in FIGS. 5 and 6, by using a nozzle bar 75 provided to direct jets or spray of the liquid solution into the tank to rinse down the inner plating tank walls 17. In this embodiment, a source tank or reservoir 40 provides the liquid plating solution 25a (metal plus surfactant in the desired chemistry). A liquid flow of the solution 25a is provided via piping 70 and a fluid connecting nozzle bar 75 that is configured slightly inwardly offset from the outer perimeter of the top rim above or near the top of the container 12, as shown in FIG. 5. The nozzle bar portion 75 includes orifices such that liquid flow of the solution is provided down each inner side wall 17 of the tank or vessel 12. A liquid pump 50 (or 50), under logic control by logic controller circuit 99, pumps the solution 25a through piping apparatus 70 and nozzle bar 75 configured around the top vessel perimeter as shown in FIG. 6, direct jets of the liquid solution 25a at approximately below the top rim or top edge 18 of the vessel 12 to effect a wash or rinse down of any organics which have migrated up the inner cell wall surface 17 from the top down, along and around the perimeter of the vessel 12 and back into the reservoir solution 25. In this embodiment, the pump and the nozzles of nozzle bar 75 must be maintained and carefully controlled to ensure the correct configuration of the jets of solution 25a to ensure the organics are washed down.

(18) In a slight modification, the piping apparatus 70 and nozzle bar 75 may be incorporated into an opening within the tank wall, e.g., an opening formed by inner and outer wall. The nozzle bar may include a slit type of integral nozzle to release the liquid solution 25a back into the tank to rinse down the plating tank inner wall surfaces 17.

(19) In the embodiments of FIGS. 1-6, a monitoring of the respective concentrations of organic species is performed. In one embodiment, there is a calculated an amount of organics in order to maintain the solution at the particular concentrations of organics species vs. metal plating species as desired. The use of pumps 50 can be operated with minimum control logic, e.g., On/Off logic, to thereby function as valves and ensure that the aqueous solution and concentrations of organic species therein lies between upper and lower limits and is maintained when operating at steady state, i.e., cyclic immersions of a same workpiece type.

(20) As an alternate embodiment, liquid organics may be washed down the sides via an increase in the liquid level in the tank. In this embodiment, as shown in FIG. 7, an apparatus 300 is provided that includes a bladder or physical displacement device 80 (e.g. a solid object) provided within the tank to add volume within the reservoir thereby raising the liquid level of plating chemistry to wash down organics that have climbed up the reservoir. For example, in FIG. 7, a tank 12 is provided with aqueous solution 25 showing a steady state level (L1) of the solution height in the reservoir without a workpiece immersion. As shown in the reservoir or tank 12, a workpiece submerged in the tank solution will displace the solution 25 to a second height level (L2) within the tank. It is understood that the level in which the organic species climb to would be greater than the level L2 within the tank (i.e., beyond the displaced volume level of the workpiece).

(21) In the alternate embodiment of FIG. 7, the expandable bladder 80 is immersed within the solution within the container 12 and a bellows (not shown) is provided to push air into the bladder to increase the volume of the bladder and modulate the displacement volume of the solution. Use of a bellows to expand the bladder 80 to an expanded configuration 80 displaces the liquid and increases the height of the liquid level up the inner side wall equivalent to the height (L2) that an immersed workpiece itself would displace, e.g., level L2, as shown in FIG. 7, under steady state operating conditions. Use of the bladder 80 or like physical displacement device to modulate volume within the reservoir and raise and lower the liquid level of plating chemistry washes down organics that have climbed at least up to level L2 as an immersed workpiece would displace.

(22) In one embodiment, a control or logic device (e.g., including a programmed hardware processor or like controller) 99, in cooperation with the timing of the immersion of the workpiece to be electroplated within the solution, is provided to control the timing of the immersion and/or expansion of the bladder and/or the amount of expansion of the bladder when immersed in the reservoir. That is, under logic device 99 control, in one embodiment, after a workpiece is immersed in the reservoir during electroplating and removed from the reservoir, the bladder 80 is then placed in the reservoir and actuated to modulate the displacement volume, i.e., cause the liquid solution level to rise to the point of liquid displacement, e.g., at level L2, and lower to wash the organics back into the solution. After displacement of the bladder 80 to wash down the organics, the bladder is removed from the reservoir. Under logic control, a steady state cycle is attained including repeated steps of workpiece immersion, electroplating, and removal and subsequent steps of immersion and volume displacement of the bladder. In one example, a steady state operation may include electroplating 300 workpieces, e.g., semiconductor wafers, in a day.

(23) It is understood that the bladder 80 can be a balloon type structure or a solid object structure that can displace (modulate) the liquid solution volume in the tank under logic control in the manner as described. It is understood that the bladder/bellow must be materially compatible to not compromise the liquid metal plating solution and organic species included therein.

(24) As mentioned, the volume that is displaced within the reservoir by the bladder (or object) should not be greater than the volume that a workpiece will displace when immersed in the reservoir in steady state. By controlling the volume to displace the solution to achieve the height L2 in between workpiece immersions, a proper concentration of organics is maintained without variation. However, this does not necessarily eliminate the walking of organics above the L2 height level, nor does it wash all organics back down, but it prevents an increase of organics concentration into the solution. To this end, in this embodiment, the concentration of organics in the liquid solution in the vessel is monitored and that amount of organics species must be increased to obtain the correct concentration of organics in a steady state operation condition due to the climbing. The logic can be used to configure out the correct concentration of organics to add back into the solution in this embodiment.

(25) As mentioned, in the embodiments described with respect to FIGS. 1-7, the vessel 12 is of a material appropriate to the solution it contains. For electroplating metal, the walls of the container 12 are typically plastic, e.g., a polymer, or synthetic polymer such as polymethacrylate.

(26) In a further embodiment for preventing organic species from climbing inner surface wall 20 of a reservoir, as shown in FIG. 8A, there is incorporated a barrier material lining 315, e.g., a glass lining, just at or above the displaced plating solution level height L2 representing the highest level that an immersed workpiece displaces the solution volume in the tank. The barrier material lining 315 prevents organic species in the solution from migrating up plating cell walls above this level. In this embodiment, a notch or groove 310 is cut into each wall 27 of the reservoir, and a barrier material 315 is embedded into the groove 310 to form barrier lining 315 such that the barrier material lining has a surface contiguous with an inner wall surface of the vessel. Barrier materials may include glass, glassy carbon, a ceramic, or any other material that does not allow wetting agent to wet.

(27) In an alternative embodiment, shown in FIG. 8B, a piece of flexible glass 320 may be attached, e.g., glued, or pressed into the notch 310 as the lining on the wall to prevent organics from rising. In this embodiment, a removable liner 320 is used as an assembled part of the tank which can be removed and either cleaned and reused or discarded.

(28) In a further aspect, a combination of one or more the embodiments and structures shown herein with respect to FIGS. 1-8B may be used to eliminate the climbing of organics.

(29) The structures and methods uncover the physical mechanism behind the problem of chemical escape/fluctuation in a plating solution bath. Thus, the structures and methods provided herein reduce workpiece product defects, and reduce any health hazard.

(30) While the invention has been particularly shown and described with respect to illustrative and preformed embodiments thereof, it will be understood by those skilled in the art that the foregoing and other changes in form and details may be made therein without departing from the spirit and scope of the invention which should be limited only by the scope of the appended claims.