EXTRUDER, FACILITY COMPRISING AN EXTRUDER, AND METHOD FOR PRODUCING TARGET POLYMER PRODUCTS CONSISTING OF A PLASTIC-CONTAINING MATERIAL FROM A SOLUTION USING SUCH AN EXTRUDER

Abstract

The invention relates to an extruder (30) comprising a housing (31), a first material inlet (32) for a mixture (46) at least consisting of a solvent and a dissolved medium, a material outlet (33), a screw (35), a screw drive (34), and at least one distillation region (36a-d) between the inlet (32) and the outlet (33), which allows an outflow of solvent, and a discharge line (43-45) for the solvent.

Claims

1. An extruder (30), comprising a housing (31), a first material inlet (32) for a mixture (46) at least consisting of solvent and dissolved medium, a material outlet (33), a screw (35) rotatable in the housing, and a screw drive (34), characterised by at least one distillation region (36a-d) between the inlet (32) and the outlet (33), which allows an outflow of solvent, and a discharge line (43 45) for the solvent.

2. The extruder according to claim 1, characterised in that the distillation region (36a-d) has a widening in the housing (31) to which the outlet is attached.

3. The extruder according to claim 2, characterised in that the screw (35) at the downstream end of the widening has a self-pulling design.

4. The extruder according to claim 2 or 3, characterised in that the configuration is such that in operation the volume (48) of the widening is only partially occupied by the transported mixture (46) and the outlet is attached to the volume not occupied.

5. The extruder according to one of the preceding claims, comprising a second material inlet for the addition of an aggregate.

6. The extruder according to one of the preceding claims, comprising a kneading device (50) for kneading the material in the extruder.

7. The extruder according to one of the preceding claims, comprising two, three, four, five or more distillation regions (36a-d) arranged in succession along the screw (35).

8. The extruder according to claims 5 and 6, in which a kneading device (50) is located between two distillation regions.

9. The extruder according to one of the preceding claims, which is configured to allow evaporation of the solvent in the distillation region, and wherein the outlet has a vapour outlet.

10. The extruder according to one of the preceding claims, characterised in that it is configured for operation at atmospheric pressure or at a pressure higher than atmospheric pressure.

11. The extruder according to one of the preceding claims, characterised by a control system designed to feed it a mixture of solvent, water and dissolved medium, having at the inlet a content of at least 10% or 20% and/or at most 35% or 25% of solvent and water (% by weight).

12. The extruder according to one of the preceding claims, characterised by a control system designed to control the operation so that the mixture of solvent, water and dissolved medium at the outlet of the extruder has a content of at most 2% or 1% and/or at least 0.1% or 0.3% of solvent and water (% by weight).

13. The extruder according one of the preceding claims, characterised by a heater (49) for heating the mixture (46) in the extruder, which heater may be provided in the region of a distillation region or upstream thereof and may act electrically and/or by heat exchange and/or by radiation.

14. The extruder according to one of the preceding claims, with an open-loop or closed-loop control system which is connected to a sensor system on the extruder and/or to an actuator system on the extruder, wherein the sensor system can comprise one or more temperature sensors and/or one or more residual moisture sensors and/or one or more fill level sensors and the actuator system can comprise the heater (49) and/or the kneading device (50) and/or the extruder drive (34) and/or a material feed not shown, wherein the control system can be configured to actuate elements of the actuator system in accordance with signals from the sensor system, in particular to adjust the heating and/or the drive speed in accordance with the residual moisture measured at the extruder output and/or to operate the material feed in accordance with a measured fill level.

15. An installation for separating a solvent from a solution, comprising at least one falling-film evaporator (13, 14) and/or a thin-film evaporator (15), and comprising an extruder (30) connected thereto according to one of the preceding claims.

16. A method for separating a solvent from a solution, in which the solution is fed into an extruder having at least one distillation region where solvent emerges from the surface of the solution and is discharged.

17. The method according to claim 16, in which the solution is guided through an extruder screw successively past a number of distillation regions.

18. The method according to claim 16 or 17 in which the solution is kneaded in front of a distillation region.

19. The method according to one of claims 16 to 18, in which, before being introduced into the extruder, the solution is concentrated in a falling-film evaporator and/or a thin-film evaporator, it being possible here to feed in steam at a temperature below the boiling temperature of the solvent.

Description

[0104] Below, aspects and embodiments of the invention are described with reference to the drawings, in which:

[0105] FIG. 1 shows the pressure-temperature graph of water;

[0106] FIG. 2 shows the overall facility;

[0107] FIG. 3 shows schematically an extruder; and

[0108] FIG. 4 shows schematically a distillation region of an extruder.

[0109] FIG. 3 shows an extruder 30, as it is schematically drawn in FIG. 2 in the lower left corner of the overall facility. The different arrows 37a, 37b, 37c and 37d symbolise material flow directions, namely 37a the direction of the incoming material, 37b the main material flow within the extruder, 37c the outgoing material and 37d distilled solvent or water.

[0110] The extruder 30 has an extruder body 31 with a material inlet 32 at the upstream end of the body 31 and a material outlet 33 at the downstream end. 35 symbolises a screw rotating in the body 31 with a screw core 35a and a screw helix 35b. The enveloping surface of the outer dimension of the rotating screw with a screw core 35b may be, viewed in the radial direction, at least in some areas positively interlocked with the inner circumferential surface of the surrounding recess in the body 31 or may be slightly reduced in relation to it, for example by max. 2 mm or max. 1 mm or max. 0.5 mm in the radial direction. 34 is a drive for the screw, which sets the screw in rotation in such a way that the material flow is effected along the arrow 37b. It should be noted that the core 35a can have a constant or non-constant diameter over its length, and that the pitch can be constant or variable over the length of the screw.

[0111] 36a to 36d denote a plurality of (specifically: four) distillation ranges. Quite generally, at least one of them is provided, but two, three, four, five, six or even more distillation regions may also be provided along the material flow according to arrow 37b and, viewed in the direction of transport 37b, may lie one behind the other and may be separated from each other.

[0112] At the material inlet 32, the extruder 30 receives the mixture of target polymer, solvent and, as applicable, other substances to be treated, including water from previous method steps. In one version, the facility control or design is such that viscous material (such as honey) is fed in at the inlet 32. Expressed in numbers, it may have a content of 10% to 50% solvent (and possibly water) at the inlet, based on the total weight including additives or without additives, the percentage being based on weight. Preferably values between 15% and 35% are used, more preferably values between 20% and 25% at the material inlet. It should be noted here that residual moisture can be between 0.1% and 5% at the outlet, preferably 0.2% to 2%, more preferably 0.5% to 1%. Here too, the percentages are based on weight and relate to the proportion of solvent and, as applicable, water in relation to the total weight with or without additives.

[0113] The design of the screw 35 can be such that the screw is self-pulling at the inlet 32, or the material can be forced in at the inlet 32. The driven screw 35 causes the material to be transported in the extruder body 31 along the arrow 37b, to the right in the drawing of FIG. 3. In this way it passes the distillation region 36a to 36d. One of these regions, 36a, is shown schematically in FIG. 4.

[0114] In the distillation regions 36, moisture (i.e. solvent and/or water) can escape from the mixture, so that the mixture is transported further along the arrow 37b with reduced moisture. In this way, a reduction of the residual moisture takes place in each of the distillation regions 36, so that their relative content decreases and the material accordingly becomes increasingly viscous to solid-like with plastic deformability. Finally, a plastically deformable polymer material with a very low residual moisture content or a residual moisture content of a desired value or within a desired value range can be applied at the extruder outlet, for example to support further processing in other machines or equipment.

[0115] The material can then finally be extruded at the outlet 33, for example as an initially continuous strand of the material with the desired cross-sectional shape. However, further fragmentation can also take place right here at the outlet, so that pellets or short pieces of material are produced. The extruder can have a single opening at the outlet or a number of parallel openings from which parallel strands of material are extruded.

[0116] The inlet of the extruder 30 can receive material from a thin-film evaporator 15 or from a falling-film evaporator 13, 14. The outlet of the extruder 30 can be connected to other equipment, such as a drying screw (not shown) for further drying of the extruded material, or a mill 21 or similar.

[0117] FIG. 4 schematically shows a distillation region 36a. It has an opening 47 in the wall 31 of the extruder body. Preferably, the opening 47 is at the top (with respect to the direction of gravity), so that material does not flow away. An attachment 41 is provided, which leads away from the housing wall 31 radially in relation to the screw rotation and which can be provided with a distal flange 42.

[0118] Generally speaking, the extruder 30 is a closed system without direct access from outside or to the outside. The distillation regions 36 can also be closed regions. For example, an overarching dome or coupling 43 can be attached to the attachment 41 or flange 42, and in turn has a connection piece 44 to which a line 45 can be attached. The dome 43 is used to collect and guide the escaping material (solvent and, as applicable, water, in vapour form or already liquid), and the connection piece 44 and line 45 are used to discharge it.

[0119] Preferably, water and/or solvents are discharged from the material in gaseous/vapour form and are then drained off via the connection piece 44 and line 45. This can be done passively by moving the steam along the arrow 37d via the connection piece 44 to the line 45 according to the pressure conditions. Or it can be actively sucked/extracted.

[0120] 46 symbolises the material present and transported in the extruder. 46a is the surface of the material in the distillation region 36a. It can be seen that the volume 48 defined in the distillation region is not completely occupied by the material 46. Rather, there is free volume that is intended to increase the exposed surface 46a of the material 46 so that the corresponding residual moisture can evaporate from the material 46 similarly to a distillation. A fill level sensor (not shown) may be provided in a distillation region. The system parameters can be subject to open-loop or closed-loop control in such a way that the complete filling of the free volume of the distillation region 36 is avoided or that a set fill level is not exceeded.

[0121] The evaporation or distillation effect can be increased by using a heater 49, only indicated schematically, which heats the material 46 in the distillation region 36 or upstream of it. The heater can work electrically or by means of radiation (microwaves) or via a heat exchanger.

[0122] To ensure that the material is mixed as homogeneously as possible, kneading devices 50 can also be provided to mix the material 46 by kneading. A kneading device 50 may be provided outside a distillation region 36, for example upstream thereof, and/or within a distillation region 36.

[0123] The screw core is symbolised with 35a, and the screw helix with 35b. Their design can be such that at the downstream end of a distillation region 36a the screw is self-pulling and therefore reliably discharges material 46 from the distillation region 36, thus ensuring that the volume 48 in the distillation region 36 is not filled with material 46. The desired transport properties of the screw can be achieved by variable design of the core diameter and/or the outer diameter and/or the pitch of the screw.

[0124] The line 45 can be a rigid pipeline or a hose. For example, it can lead to a condenser in which the discharged vapours are condensed to liquid. However, the line 45 can also lead directly to a store for raw material to be dissolved, so that the raw material is dissolved by solvent vapours right there.

[0125] The extruder, in essence, does not operate at negative pressure or only slightly drops below the atmospheric pressure (not below 500 hPa). Insofar as the vapours escaping in the distillation region 36 are extracted, slight negative pressures (not below 500 hPa) may occur. The extruder places the material under overpressure (compared to atmospheric pressure) in some areas, at least at the outlet, to extrude the remaining material.

[0126] Quite generally, it may be intended that an additive is added in the extruder and mixed with the other material. A separate (not shown) additional inlet can be provided for this purpose, or the additive can be added via the already mentioned inlet 32, just like the main material. The materials are then mixed by means of the screw 35 and, if necessary, the kneading device 50, so that the additive is intimately and homogeneously mixed and blended with the other material at the outlet 33 of the extruder.

[0127] The extruder may have an open-loop or closed-loop control system (not shown). It can be connected on the input side to a sensor system on the extruder or elsewhere in the process and/or on the output side to an actuator system on the extruder. The sensor system can comprise one or more temperature sensors, possibly distributed over the length of the extruder or over the plurality of distillation regions, and/or one or more residual moisture sensors, possibly also distributed over the length of the extruder or over the plurality of distillation regions, and/or one or more fill level sensors approximately at one distillation region 36, possibly also distributed over the length of the extruder or over the plurality of distillation regions. The actuator can be the heater 49 and/or the kneading device 50 and/or the extruder drive 34 and/or a material feed (not shown). Elements of the actuator system can be actuated according to signals from the sensor system. For example, the heating and/or the drive speed can be adjusted according to the residual moisture measured at the extruder output, and/or the material feed can be operated according to a measured fill level. The control system can be provided separately for the extruder or can be part of the overall facility control system.

[0128] The method shown is an extruder used to extrude a solution received on the inlet side towards the outlet and to remove residual moisture from solvent and, as applicable, water in distillation regions. As already mentioned, the material can be heated or kneaded. It is possible to bypass a number of distillation regions. The method comprises feeding in input material of said input composition in terms of water, solvent and target polymer and, as applicable, filler, and operating the extruder so as to produce material with the desired output composition. A filler/additive may be added. In the same way, however, the material fed to the extruder may have additives added earlier (for example, added in the falling-film evaporator or in the thin-film evaporator). Depending on the residual moisture measured at the extruder outlet, heating and/or the drive speed can be adjusted, and/or depending on a measured fill level, the material feed (quantity per time) can be operated or adjusted.

[0129] It may be preferable for the extruder to process material without fillers/additives, i.e.apart from impuritiesa mixture only of solvent and dissolved medium and, as applicable, water. However, the extruder can also receive material already provided with fillers/additives and/or mix in fillers/additives itself. It may then be desirable to have, finally, mixtures with not too large amounts of fillers/additives, for example with a proportion of the total weight above 0.1% or above 1% but below 20% or below 10%.

[0130] In the following, an embodiment for the industrial application of the extruder is described.

EMBODIMENT

[0131] Production of a Masterbatch from Polyethylene and Carbon Black

[0132] The method comprises a first stage in which a polyethylene product is obtained using the method according to the invention from a multilayer film having a polyamide layer and a polyethylene layer, and a second stage in which carbon black can be added to the polyethylene product.

A) Production of Preferably Powdery Polyethylene Product with 3-5% Solvent Content

[0133] The PA-PE multilayer film is destroyed by granulation to make the polyethylene more accessible for the dissolving process. As comparative tests have shown, the granules are dissolved much more easily than snippets from the PA-PE multilayer film. The PA-PE granules are then conveyed by a screw conveyor 5 into the process container 1 in FIG. 2, which is kept at a temperature of 100 C-120 C. by hot steam 19. White spirit type 4 is heated to 120 C. in the solvent storage container 4 and then pumped into the process container 1, where it dissolves the polyethylene from the granules at a temperature of 100-120 C. The temperature is maintained at 100-120 C. by hot steam. The contents of the process container 1 are constantly pumped around. The resulting movement replaces the stirrer and accelerates the dissolving process. After 15 min a solution is obtained which contains 90% of the polyethylene in dissolved form. The polyethylene solution is prepared using 1 part by weight of polyethylene and 8 parts by weight of white spirit. The polyamide insoluble in the white spirit settles quickly with undissolved polyethylene at the bottom of the process container 1. The polyethylene solution forms the supernatant and is pumped into a collection container. In the continuous method, the dissolving process is repeated every 30 min with a new batch of the processed PA-PE multilayer film.

[0134] The suspension of polyamide particles, undissolved polyethylene and polyethylene solution arising at the bottom of the process container 1 is pumped into another process container 2, in which undissolved polyethylene is dissolved out with fresh white spirit at 100-120 C. The container contents are also pumped around here. The ratio of solids to solvent is 1 to 3. The polyethylene solution is combined with the main solution in the collection container.

[0135] The suspension of polyamide particles in white spirit is pumped onto a dewatering screw 20 and again rinsed with white spirit at 100-120 C., resulting in a material consisting of 98% polyamide with a residual polyethylene content. The suspension is centrifuged, the separated polyamide is rinsed with steam at a temperature of 150 C., then removed from the centrifuge and placed in a heated screw conveyor. The heating of the screw conveyor serves to evaporate the solvent, which is intensified by a hot air stream. After leaving the screw conveyor, the polyamide is fed into a vacuum dryer, in which a white spirit adhering to the polyamide for the last time is removed with 150 C. hot steam and then the polyamide is predried in a vacuum at 130 C. After further drying in a solids dryer, the granular polyamide can be filled into bags for further recycling.

[0136] The condensates, which are produced in the various method steps, are conveyed to a sedimentation container. In the sedimentation container, the solvent with a density of 0.7 g/cm3 accumulates as an upper layer. An intermediate layer consists of entrained polymer particles with a density of 0.9 g/cm3, which is separated. The lower layer consists of water with a density of 1.0 g/cm3. All three phases are returned to the production method.

[0137] The polyethylene solution freed from the polyamide in the collection container 6 is kept at a temperature of 90 C. by hot water in an external heater. The polyethylene solution is fed through an inlet pipe 9 into the head region 10 of a falling-film evaporator 7, which comprises 96 pipes which are kept at a temperature of 140 C. by means of hot steam flowing through pipes 13 at an overpressure of 0.9 bar. The head region 10 is filled with the target polymer solution to ensure uniform filling of the 96 tubes. In the head region 10, high-pressure steam at a temperature of 160 C. is introduced into the stream of polyethylene solution through one or more nozzles, which also reduce the pressure, preferably with the stream, if necessary additionally in counter-current. The hot steam heats the polyethylene solution and, when introduced, leads to the formation of steam bubbles and bubbles in the target polymer solution, into which the solvent evaporates. The steam can be introduced mixed with another gas (for example inert gas, nitrogen). The introduction mechanism can be designed to optimise bubble formation, for example by using a large number of nozzles (n>5 or >10 or >20) of relatively small cross-section immersed in the solution. The orientation of the nozzles (i.e. the fluid flow out of them) can be parallel. However, at least in part, they may also be arranged in pairs, not parallel or crossing each other. Vapour injection can, for example, take place in a solution supply line for the solvent/PE solution of an evaporator, approximately shortly upstream of the end of the supply line.

[0138] The heated polyethylene solution mixed with the steam and enriched with steam and possibly gas bubbles reaches the 96 tubes of the falling-film evaporator 7, and flows as a thin film on the heated surface of the tubes 13 in the direction of the sump outlet 11 of the falling-film evaporator 7. Under these conditions, a mixture of white spirit vapours and steam is expelled and water molecules are incorporated into the polyethylene structure. The temperature, caused by the external heating and the hot steam, and the properties of solvent and polymer are such that the solvent quantity is halved up to the sump outlet 11 of the falling-film evaporator 7. The vapour is separated from the liquid by a separator and is fed to the condensation and recovery of water and solvent. The quantity ratio of polyethylene to white spirit is then 1:4.

[0139] The concentrated heated polyethylene solution is fed into a second falling-film evaporator 7, the design of which is identical to the design of the first falling-film evaporator 7. Here, too, the hot steam is introduced into the head region 10 of the falling-film evaporator 8 at a temperature of 140-160 C., which leads to further heating of the target polymer solution and to the accumulation of glass bubbles in the target polymer solution, which increase the evaporation surface. The steam bubbles become enriched with solvent. At the lower end of the second falling-film evaporator 8, the weight ratio of polyethylene to white spirit is 1:1. The vapour is separated from the liquid by a separator and fed to the condensation and recovery of water and solvent. The solution is clearly more viscous, similar to hot honey. When this highly viscous solution is cooled, a waxy solid is obtained which is easily crumbled mechanically.

B) Production of the Carbon Black Masterbatch

[0140] A concentrated slurry of carbon black in white spirit is prepared in an additive container 17. The carbon black can be a type of carbon black for colouring and/or a type of carbon black for obtaining electrical conductivity in polyethylene. Carbon black and white spirit are mixed. The temperature is adjusted to 160-180 C. with hot steam. The polyethylene solution from the second falling-film evaporator 8, with a ratio of 1:1 (target polymer:white spirit) and the carbon black suspension from the additive container 17 are combined and mixed in a mixing device 18 with the addition of hot steam. The viscous polyethylene solution enriched with carbon black is then added to a thin-film evaporator 15. Hot steam at a temperature of 140-160 C. is passed into or over the product stream. The thin-film evaporator 15 itself is heated with hot steam of 140 C. at a slight pressure of 0.9 bar, which flows through a pipe system in the thin-film evaporator 15. In the thin-film evaporator 15, a mixture of steam and test gasoline vapor continues to be expelled until the liquid content of the target polymer is only 10-20% by weight. Under these conditions the polyethylene containing carbon black is present as black crumbly polyethylene with a carbon black content of 60 wt. %.

[0141] Then, the mixture is fed into the described extruder 30 and further processed as described. From the extruder 30, the masterbatch of polyethylene and incorporated carbon black is transported to a mill 21. In the mill 21 the masterbatch is crushed and discharged via a screw 22. In a drying screw the masterbatch is dried at 100 C. to a residual moisture content of solvent and, as applicable, water of 3-5%.

[0142] The masterbatch with a residual solvent moisture of 3-5% is then fed to the final granulation process. The residual moisture increases the melt flow index of the masterbatch in the screw from 5 to 10, which facilitates the incorporation of the carbon black into the polyethylene with optimum distribution of the carbon black and improves granule formation.

[0143] A carbon black masterbatch in granular form with a carbon black content of 60% by weight is obtained. Alternatively, the masterbatch as the target polymer product cannot be dried in granular form but in powder form, which may have advantages when used as a masterbatch.

[0144] In the above description, features should be considered to be combinable with each other even if this is not expressly stated, unless their combination is technically impossible or unfeasible. Descriptions of methods and method steps are also to be understood as descriptions of devices for implementing the particular method or method step, and vice versa.

[0145] Combinations of features C1 ff, which may be related to the extruder, the described facility and the method, can be described as follows:

[0146] C1. A method for producing a solid target polymer product from a target polymer solution, comprising the steps of: a) producing the target polymer solution by dissolving the target polymer in a solvent or dissolving out the target polymer with a solvent from a composite material or a mixture and separating the target polymer solution from the insoluble components, b) concentrating the target polymer solution, which has a temperature of at least the boiling temperature of water, by contacting the target polymer solution with steam at a temperature of at least the boiling temperature of water preferably in at least one falling-film evaporator and/or at least one thin-film evaporator, and then extruding in a described extruder, whereby a solvent-steam mixture is expelled, until the target polymer product has the form of a deformable solid, the temperature of the target polymer solution remaining below the boiling temperature of the target polymer solution when the solvent-steam mixture is expelled.

[0147] C2. The method according to C1, characterised in that the solid obtained in step b) is dried in a further step c) by heating without contacting with steam.

[0148] C3. The method according to C1 or C2, characterised in that the quantity ratio of target polymer to solvent in the method steps is, independently of one another, in the following ranges: before step b) in the range from 1:5 to 1:20 parts by weight; after step b) and before step c) in the range from 7 to 16% by weight of solvent with an additional water content of 2 to 8% by weight; and after step c) in the range from 1 to 7% by weight of solvent.

[0149] C4. The method according to one of the preceding C, characterised in that step b) is carried out in one or more falling-film evaporators (7, 8) and/or one or more thin-film evaporators (15).

[0150] C5. Method according to C4, characterised in that in the falling-film evaporator(s) (7, 8) so much solvent is expelled that the quantity ratio of target polymer to solvent is in the range from 1:0.5 to 1:4 parts by weight, and in that in the thin-film evaporator(s) (15) so much solvent is expelled that the target polymer solution contains 7 to 16% by weight of solvent, based on the total weight of target polymer and solvent.

[0151] C6. The method according to one of the preceding C, characterised in that, when carrying out step b), an additive or a mixture of additives is added, the additive or the mixture of additivesbeing added to the target polymer solution as soon as the quantity ratio of target polymer to solvent has risen to a value in the range from 1:0.5 to 1:4 parts by weight as a result of the evaporation of solvent or being mixed into the target polymer solution before it is introduced into the first thin-film evaporator (15).

[0152] C7. The method according to one of the preceding C, characterised in that a further additive or mixture of additives is added after step b) and before step c) and/or after step c).

[0153] C8. The method according to C6 or C7, characterised in that the additives are solid additives selected from carbon blacks, organic pigments, inorganic pigments, dyes, reinforcing fillers such as talc, glass fibres, carbon fibres, glass balls, metallic particles and mixtures thereof, the additive or mixture of additives being present in solid form, in liquid form, as a suspension or as a solution.

[0154] C9. The method according to one of C6 to C8, characterised in that the additive is a carbon black for colouring the target polymers or a carbon black for electrically conductive target polymers, which is added in a proportion of more than 50% by weight, based on the total weight of target polymer, additive and solvent.

[0155] C10. The method according to any of the preceding C, characterised in that the target polymer is a polyolefin.

[0156] C11. The method according to one of the preceding C, characterised in that the solvent is selected from fatty acid esters, petroleum fractions, gasoline fractions, diesel fuels, aliphatic hydrocarbons, alicyclic hydrocarbons, and aromatic hydrocarbons, individually or in a mixture.

[0157] C12. The method according to one of the preceding C, characterised in that the solvent has a boiling temperature above 100 C., preferably above 110 C.

[0158] C13. The method according to one of C1 to C11, characterised in that the solvent is selected from biodiesel having a boiling range of about 300 to 570 C., rapeseed oil, fuel oil having a boiling range of 170 to 390 C., diesel fuel having a boiling range of 170 to 390 C., white spirit of type 1 (boiling range 130-185 C.), type 2 (boiling range 140-200 C.), type 3 (boiling range 150-190 C.), type 4 (boiling range 180-220 C.) and type 5 (boiling range 130-220 C.), special boiling point gasoline of type 2 (boiling range 80-110 C.), special boiling point gasoline of type 3 (boiling range 100-140 C.), cleaner's solvent with a boiling range of 80 to 110 C., aliphatine with a boiling range of 100 to 160 C., ligroin with a boiling range of 150 to 180 C., kerosene with a boiling range of 180 to 270 C. C7-C20 n-alkane fractions, C7-C20 isoalkanes, isoparaffins, cycloheptane or as a mixture of two or more of these substances, and may have other additives which are less than 20 or less than 10 or less than 5 or less than 2% by weight.

[0159] C14. The method according to one of the preceding C, characterised in that the steam has a temperature in the range of 110 to 250 C.

[0160] C15. The method according to one of the preceding C, characterised in that the target polymer solution in step b) is additionally heated by one or more heating devices (13, 14).

[0161] C16. The method according to C15, characterised in that the evaporation surfaces of the falling-film evaporators (7, 8) and/or the thin-film evaporators (15) are kept at a temperature of 80 to 200 C.

[0162] C17. The method according to one of C4 to C16, characterised in that the hot steam is introduced into the target polymer solution in the feed line (9) to the falling-film evaporator (7, 8) or in the head region (10) of the falling-film evaporator (7, 8) and steam bubbles are formed in the target polymer solution, into which the solvent evaporates, thereby increasing the total evaporation surface area.

[0163] C18. The method according to one of the preceding C, characterised in that the pure target polymer, composite material or mixture used as starting material is converted into granules before being dissolved in step a).

[0164] C19. The method according to one of the preceding C, characterised in that the solvent has a boiling temperature in the range from 180 to 220 C., the target polymer is dissolved in the solvent at 50 to 150 C., the target polymer solution is mixed with high-pressure steam at a temperature of 140 to 180 C. in the one or more falling-film evaporators and/or the one or more thin-film evaporators, in order to expel a solvent-steam mixture, and the one or more falling-film evaporators and/or the one or more thin-film evaporators are additionally heated externally with steam at a temperature of 120 to 140 C.

[0165] C20. An additive-free or additive-containing target polymer product obtainable by the method according to one of C1 to C19.

[0166] C21. A target polymer product as a masterbatch comprising a polymer and carbon black, the carbon black content being at least 51% by weight, based on the total weight of the masterbatch, preferably at least 60% by weight.

[0167] C22. A target polymer product as a masterbatch or compound material comprising a polymer and a carbon black type as an additive for electrically conductive plastic, wherein the carbon black content is at least 40% by weight based on the total weight of the target polymer product.

[0168] C23. A target polymer product as masterbatch comprising a polymer and colour pigments and having a granular or powdery structure

[0169] C24. A target polymer product as a fibre-reinforced compound material comprising a polymer and, in addition to other additives, fibres which have a length of at least 2 mm.

[0170] C25. A polymer product which is additive-free or contains an additive and has a solvent content of 1 to 7% by weight, preferably 3 to 5% by weight, for improving the melt flow index.

[0171] C26. A device for carrying out one of the above processes without mechanical stirrers, comprising: one or more process containers (1, 2) for producing the target polymer solution, in which the solution is circulated by pumping; one or more falling-film evaporators (7, 8) and/or one or more thin-film evaporators (15) which are connected via tubes to the process container(s) (1, 2) in which the solvent is expelled from the target polymer solution by steam or hot-pressure steam, the steam being introduced into the head region (10) of the evaporator (7, 8) with a temperature of at least the boiling temperature for mixing, in order to form steam bubbles in the target polymer solution which increase the evaporation surface of the evaporator (7, 8), wherein, if necessary, steam with a temperature of at least the boiling temperature is introduced additionally in co-current flow at the head (10) of the evaporator(s) (7, 8) and/or in counter-current in the sump outlet (11, 12) of the evaporator(s) (7, 8).

LIST OF REFERENCE SIGNS

[0172] 1 Process container [0173] 2 Process container [0174] 3 Solvent storage container [0175] 4 Heating device [0176] 5 Screw conveyor [0177] 6 Collection container [0178] 7, 8 Falling-film evaporators [0179] 9 Feed tube [0180] 10 Head region [0181] 11, 12 Sump outlet [0182] 13, 14 Tubes [0183] 15 Thin-film evaporator [0184] 16 Screw [0185] 17 Additive preparation unit [0186] 18 Storage container [0187] 19 Steam [0188] 20 Screw conveyor for transporting away [0189] 21 Mill [0190] 22 Screw [0191] 30 Extruder [0192] 31 Housing [0193] 32 Material inlet [0194] 33 Material outlet [0195] 34 Drive [0196] 34 Screw [0197] 35a Screw core [0198] 35b Screw helix [0199] 36a-36d Distillation regions [0200] 37a 37d Directions of movement [0201] 41 Attachment [0202] 42 Flange [0203] 43 Dome [0204] 44 Connection piece [0205] 45 Line [0206] 46 Material [0207] 46a Material surface [0208] 47 Opening [0209] 48 Volume [0210] 49 Heating device [0211] 50 Kneading device