METHOD FOR PRODUCING A COMPOSITE PANE WITH A FUNCTIONAL ELEMENT HAVING ELECTRICALLY CONTROLLABLE OPTICAL PROPERTIES
20210008843 · 2021-01-14
Inventors
Cpc classification
B32B17/10871
PERFORMING OPERATIONS; TRANSPORTING
B32B17/10807
PERFORMING OPERATIONS; TRANSPORTING
B32B17/10036
PERFORMING OPERATIONS; TRANSPORTING
B32B17/10293
PERFORMING OPERATIONS; TRANSPORTING
B32B17/10192
PERFORMING OPERATIONS; TRANSPORTING
B32B17/1088
PERFORMING OPERATIONS; TRANSPORTING
B32B17/10183
PERFORMING OPERATIONS; TRANSPORTING
B32B2605/006
PERFORMING OPERATIONS; TRANSPORTING
B32B38/10
PERFORMING OPERATIONS; TRANSPORTING
G02F1/1334
PHYSICS
International classification
Abstract
A method for producing a composite pane with a functional element having electrically controllable optical properties, includes providing a first pre-composite including a first thermoplastic laminating film and a first barrier film as well as a second pre-composite including a second thermoplastic laminating film and a second barrier layer trimming and the pre-composites substantially to the dimensions of the composite pane, forming a circumferential back cut in the barrier films, arranging the first pane, the first pre-composite, a functional element, the second pre-composite, and a second pane one over another in this order, the barrier films being arranged sheet-wise directly adjacent the functional element, surrounding the circumferential edge of the functional element, and touching one another sheet-wise at least in sections in an overhang u protruding beyond the functional element, and bonding the layer stack.
Claims
1. A method for producing a composite pane with a functional element having electrically controllable optical properties, the method comprising: a) providing a first pre-composite comprising a first thermoplastic laminating film and a first barrier film as well as a second pre-composite comprising a second thermoplastic laminating film and a second barrier layer and trimming the first and second pre-composites substantially to dimensions of the composite pane to be produced, b) forming a circumferential back cut in the first and second barrier films, c) arranging a first pane, the first pre-composite, a functional element, the second pre-composite, and a second pane one over another in this order, wherein the first and second barrier films are arranged sheet-wise directly adjacent the functional element with, at least in sections, a common overhang that is beyond the circumferential edge of the functional element and surrounds the circumferential edge of the functional element, and d) bonding the layer stack comprising, in this order, the first pane, the first thermoplastic laminating film, the first barrier film, the functional element, the second barrier film, the second thermoplastic laminating film, and the second pane by autoclaving to form the composite pane.
2. The method according to claim 1, wherein before step a), the first barrier film is joined to the first thermoplastic laminating film by heating to form a first pre-composite and/or the second barrier film is joined to the second thermoplastic laminating film by heating to form a second pre-composite.
3. The method according to claim 1, wherein in step b), cutouts are made in the barrier films of the pre-composites.
4. The method according to claim 1, wherein in step c), a thermoplastic frame film is arranged between the first pane and the first thermoplastic laminating film and/or between the second pane and the second thermoplastic laminating film, which thermoplastic frame film surrounds the region of the first thermoplastic laminating film and/or the second thermoplastic laminating film into which the functional element is introduced.
5. The method according to claim 1, wherein the first thermoplastic laminating film and/or the second thermoplastic laminating film contain in each case at least one plasticizer.
6. The method according to claim 5, wherein the first and the second thermoplastic laminating film contain at least 3 wt. % of a plasticizer, and the plasticizer contains or is made of aliphatic diesters of tri- or tetraethylene glycol.
7. The method according to claim 1, wherein the thermoplastic laminating films contain at least 60 wt. % of polyvinyl butyral (PVB).
8. The method according to claim 1, wherein the first and the second barrier film are implemented such that the first and the second barrier film prevent the diffusion of plasticizer through the barrier film.
9. The method according to claim 8, wherein the first and the second barrier film are plasticizer-free and contain or are made of polyethylene terephthalate (PET) or polyvinyl fluoride (PVF).
10. The method according to claim 1, wherein the material composition of the first and second barrier films differs in terms of its main constituent by weight from the main constituent by weight of the thermoplastic laminating films.
11. The method according to claim 10, wherein the first and second barrier films contain polyethylene terephthalate (PET) as the main constituent by weight and the thermoplastic laminating films contain polyvinyl butyral (PVB) as the main constituent by weight.
12. A composite pane containing a functional element having electrically controllable optical properties produced in a method according to claim 1, comprising in this order a first pane, a first pre-composite comprising a first thermoplastic laminating film with at least one plasticizer and a first barrier film, wherein the first barrier film is in direct contact with the circumferential edge of the functional element, a functional element, a second pre-composite comprising a second thermoplastic laminating film with at least one plasticizer and a second barrier layer, wherein the second barrier film is in direct contact with the circumferential edge of the functional element, a second pane, wherein the first and second barrier films are arranged sheet-wise directly adjacent the functional element, surround the circumferential edge of the functional element, and touch one another sheet-wise at least in sections in an overhang protruding beyond the functional element.
13. The composite pane according to claim 12, wherein the overhang of the first and the second barrier film protruding beyond the functional element is at least 1 mm, and the overhang of the first and the second barrier film protruding beyond the functional element is at most 50 mm.
14. The composite pane according to claim 12, wherein the functional element is a polymer dispersed liquid crystal film.
15. The composite pane according to claim 12, wherein in the region of the functional element, cutouts are made in the barrier films of the pre-composite, and the first barrier film and/or the second barrier film are implemented in each case in the form of a continuous circumferential frame.
16. The method according to claim 6, wherein the first and the second thermoplastic laminating film contain at least 30 wt.-% of a plasticizer.
17. The method according to claim 6, wherein the plasticizer is triethylene glycol-bis-(2-ethyl hexanoate).
18. The method according to claim 7, wherein the thermoplastic laminating films contain at least 90 wt.-% of polyvinyl butyral (PVB).
19. The composite pane according to claim 13, wherein the overhang of the first and second barrier film protruding beyond the functional element is at least 5 mm.
20. The composite pane according to claim 13, wherein the overhang of the first and the second barrier film protruding beyond the functional element is at most 20 mm.
Description
[0092] The invention is explained in detail with reference to drawings and exemplary embodiments. The drawings are schematic representations and not to scale. The drawings in no way restrict the invention. They depict:
[0093]
[0094]
[0095]
[0096]
[0097]
[0098]
[0099]
[0100]
[0101]
[0102]
[0103]
[0104]
[0105] Accordingly, the use of bilayers is decisive for the ability to automate the process as well as for the variable shaping of the functional element.
[0106]
[0107]
[0108]
[0109] The optical properties of the functional element 5 can be controlled by applying an electrical voltage. For the sake of simplicity, the electrical supply lines are not shown.
[0110] The controllable functional element 5 is, for example, a PDLC multilayer film, consisting of an active layer 11 between two surface electrodes 12, 13 and two carrier films 14, 15. The active layer 11 contains a polymer matrix with liquid crystals dispersed therein, which align themselves as a function of the electrical voltage applied on the surface electrodes, by which means the optical properties can be controlled. The carrier films 14, 15 are made of PET and have a thickness of, for example, 50 m. The carrier films 14, 15 are provided with a coating of ITO facing the active layer 11 and having a thickness of approx. 100 nm, forming the surface electrodes 12, 13. The surface electrodes 12, 13 can be connected to a voltage source via bus bars (not shown) (implemented, for example, by a silver-containing screen print) and connecting cables (not shown).
[0111] The thermoplastic laminating films 3a, 4a comprise in each case a thermoplastic film with a thickness of 0.38 mm and are made, for example, of 78 wt.-% polyvinyl butyral (PVB) and 20 wt.-% triethylene glycol bis(2-ethyl hexanoate) as a plasticizer.
[0112] The barrier films 3b, 4b are made, here, for example, substantially of PET, i.e., at a rate of at least 97 wt.-%. The barrier films 3b, 4b contain less than 0.5 wt.-% plasticizer and are suitable for preventing the diffusion of plasticizer out of the thermoplastic laminating layers 3a, 4a via the circumferential edge 8 into the functional layer 5.
[0113] The barrier films 3b, 4b are in direct contact with the functional element 5, in the present case, in sheet-wise contact with the surfaces of the carrier films 14, 15, as well as, additionally, direct contact with the open cross-section of the functional element 5 along the circumferential edge 8. In the region of the overhang x, the barrier films 3b, 4b are in direct sheet-wise contact with one another. Here, the term in direct contact means that no other components or chemical compounds at all, for example, adhesives, are arranged between the barrier films 3b, 4b and between the barrier films and the functional element 5. According to the prior art, slippage of the barrier films during assembly is prevented by an adhesive connection.
[0114] According to the invention, an adhesive connection is unnecessary and undesirable. Slippage of the adhesive films is achieved through the use of pre-composites 3, 4, comprising in each case a barrier film 3b, 4b and a thermoplastic laminating film 3a, 4a. The embodiment of the invention described in
[0115]
[0116] In this embodiment, a thermoplastic frame film 9 is arranged in sections between the second thermoplastic laminating film 4a and the second pane 2. The thermoplastic frame film 9 is made, for example, of the same material as the thermoplastic laminating films 3a, 4a. The thermoplastic frame film 9 has a cutout, into which the functional element 5 with the barrier films 3b, 4b and the thermoplastic laminating films 3a, 4a is inserted precisely, i.e., flush on all sides. The thermoplastic frame film 9 thus forms a sort of passe-partout for the functional element 5 and the film sections of the laminating film and barrier films surrounding it. By means of the thermoplastic frame film 9, the differences in thickness caused by the material thickness of the functional element 5 can be compensated. The thicknesses of the functional element 5 and of the thermoplastic frame film correspond to the values described in
[0117]
[0118]
[0119] The optical properties of the functional element 5 can be controlled by applying an electrical voltage. For the sake of simplicity, the he electrical supply lines are not shown. The controllable functional element 5 is, for example, a PDLC multilayer film, comprising an active layer 11 between two surface electrodes 12, 13 and two carrier films 14, 15. The further structure of the functional element corresponds to that described in
[0120] The thermoplastic laminating films 3a, 4a and the barrier films 3b, 4b correspond in their chemical composition and their layer thickness to the dimensions described in
[0121] The edge region of the roof panel is concealed by a circumferential black print 10 (circumferential peripheral masking print) that is applied at least on the inner side of the outer pane. The black print is formed by printing an opaque enamel onto the interior-side surface (facing the interior of the vehicle in the installed position) of the pane 1. Optionally, a black print 10 can also be applied on the inner side of the second pane. The circumferential edge 8 of the functional element 5 lies in the region of the black print 10 such that it is not perceptible when viewing the roof panel from the outside. The distance of the functional element 5 from the circumferential edge of the roof panel is thus smaller than the width of the black print 10. The electrical connections (not shown) are also reasonably mounted in the region of the black print 10 and thus hidden.
[0122] The barrier films 3b, 4b are in direct contact with the functional element 5, in the present case, in sheet-wise contact with the surfaces of the carrier films 14, 15, and, additionally, in direct contact with the open cross-section of the functional element 5 along the circumferential edge 8. In the region of the overhang x, the barrier films 3b, 4b are in direct sheet-wise contact with each other. Also, according to the exemplary embodiment of
[0123] The barrier films 3b, 4b according to the invention in the region of the circumferential edge of the functional element 5 are firmly pressed and fixed against one another there by the inner pressure in the finished laminated composite pane 100, as a result of which hermetic sealing occurs even without use of adhesives. This was unexpected and surprising for the person skilled in the art.
[0124]
[0125] The height of the darkened functional element 5 can be adjusted by the segmentation. Thus, depending on the position of the sun, the driver can darken the entire sun visor or even only part of it. The figure indicates that the upper half of the sun visor is darkened and the lower half is transparent.
[0126] In a particularly convenient embodiment, the functional element 5 is controlled by a capacitive switch area arranged in the region of the functional element, wherein the driver determines the degree of darkening by the location at which he touches the pane.
[0127] The windshield per
[0128] The sun visor is formed by a commercially available PDLC multilayer film as the functional element 5 that is embedded in the thermoplastic laminating films. The height of the sun visor is, for example, 21 cm. The first thermoplastic laminating film 3a is bonded to the first pane 1; the second thermoplastic laminating film 4a is bonded to the second pane 2. A thermoplastic frame film 9 situated between the first thermoplastic laminating film 3a and the first pane 1 has a cutout, into which the cut-to-size PDLC multilayer film is inserted precisely, i.e., flush on all sides. The thermoplastic frame film 9 thus forms, so to speak, a sort of passe-partout for the functional element 5, which is thus encapsulated all around in a thermoplastic material and is protected thereby. In the region of the circumferential edge 8 of the functional element 5, a first barrier film 3b and a second barrier film 4b, which surround the edge 8 and seal the functional element 5. The first barrier film 3b is used as a pre-composite 3 with the first thermoplastic laminating film 3a, while the second barrier film 4b is used as a pre-composite 4 with the second thermoplastic laminating film 4a.
[0129] The first thermoplastic laminating film 3a has a tinted region that is arranged between the functional element 5 and the first pane 1 (outer pane). The light transmittance of the windshield is thus additionally reduced in the region of the functional element 5, and the milky appearance of the PDLC functional element 5 in the diffuse state is mitigated. The aesthetics of the windshield are thus significantly more attractive. The first thermoplastic laminating film 3a has, in the tinted region, for example, average light transmittance of 30%, with which good results are achieved. The region can be homogeneously tinted. However, it is often visually more appealing if the tinting decreases in the direction of the lower edge of the functional element 5 such that the tinted and the non-tinted regions merge smoothly.
[0130] The lower edge of the tinted region and the lower edge of the PDLC functional element 5 can be arranged flush with one another and with the barrier films 3b, 4b situated on this edge. This is, however, not necessarily the case. It is also possible for the tinted region to protrude beyond the functional element 5 or, vice versa, for the the functional element 5 to protrude beyond the tinted region. In the latter case, it would not be the entire functional element 5 that would be bonded to the first pane 1 via the tinted region.
[0131] The controllable functional element 5 is a multilayer film, analogous to the structure depicted in
[0132] A so-called high flow PVB, which has stronger flow behavior compared to standard PVB films, can preferably be used for the thermoplastic laminating films 3a, 4a, 9 per
LIST OF REFERENCE CHARACTERS
[0133] 1 first pane [0134] 2 second pane [0135] 3 pre-composite comprising first thermoplastic laminating film 3a and first barrier film 3b [0136] 3a first thermoplastic laminating film [0137] 3b first barrier film [0138] 4 pre-composite comprising second thermoplastic laminating film 4a and second barrier film 4b [0139] 4a second thermoplastic laminating film [0140] 4b second barrier film [0141] 5 functional element having electrically controllable optical properties [0142] 6 cutout (of the barrier films) [0143] 7 back cut (in the edge region of the barrier films) [0144] 8 circumferential edge of the functional element 5 [0145] 9 thermoplastic frame film [0146] 10 black print [0147] 11 active layer of the functional element 5 [0148] 12 first surface electrode of the functional element 5 [0149] 13 second surface electrode of the functional element 5 [0150] 14 first carrier film [0151] 15 second carrier film [0152] 16 isolation lines [0153] 17 cutting tool [0154] 18 cuts [0155] 19 additional thermoplastic laminating film [0156] 20 additional carrier film [0157] 21 infrared reflecting coating [0158] 100 composite pane [0159] u overhang [0160] x overlap [0161] AA, BB section lines [0162] Z enlarged region [0163] C field of vision [0164] M engine edge [0165] D roof edge