COMPOSITE PANE WITH A FUNCTIONAL ELEMENT HAVING ELECTRICALLY CONTROLLABLE OPTICAL PROPERTIES WITH IMPROVED EDGE SEALING
20210008842 · 2021-01-14
Inventors
Cpc classification
B32B2605/006
PERFORMING OPERATIONS; TRANSPORTING
B32B17/10036
PERFORMING OPERATIONS; TRANSPORTING
B32B17/10293
PERFORMING OPERATIONS; TRANSPORTING
B32B17/10119
PERFORMING OPERATIONS; TRANSPORTING
B32B17/10174
PERFORMING OPERATIONS; TRANSPORTING
B32B2367/00
PERFORMING OPERATIONS; TRANSPORTING
B32B17/10192
PERFORMING OPERATIONS; TRANSPORTING
B32B17/1088
PERFORMING OPERATIONS; TRANSPORTING
International classification
Abstract
A composite pane containing a functional element having electrically controllable optical properties includes, in this order, a first pane, a first thermoplastic composite film having at least one plasticizer, a functional element having a peripheral edge, a barrier film having a cutout, into which the functional element is inserted, a second thermoplastic composite film having at least one plasticizer, a second pane, wherein the barrier film surrounds the functional element in a frame-like manner and is in direct contact with the peripheral edge of the functional element, and the barrier film contains at most 0.5 wt.-% plasticizer and prevents the diffusion of plasticizer through the barrier film.
Claims
1. A composite pane containing a functional element having electrically controllable optical properties comprising, in this order a first pane, a first thermoplastic composite film having at least one plasticizer, a functional element having a peripheral edge, a barrier film having a cutout, into which the functional element is inserted, a second thermoplastic composite film having at least one plasticizer, a second pane, wherein the barrier film surrounds the functional element in a frame-like manner and is in direct contact with the peripheral edge of the functional element, and the barrier film contains at most 0.5 wt.-% plasticizer and prevents the diffusion of plasticizer through the barrier film.
2. The composite pane according to claim 1, wherein the functional element is a polymer dispersed liquid crystal (PDLC) film.
3. The composite pane according to claim 1, wherein a thickness of the barrier film and a thickness of the functional element differ from one another by at most 30%, and the thickness of the barrier film and the thickness of the functional element are substantially the same.
4. The composite pane according to claim 1, wherein the barrier film has a thickness of 0.1 mm to 1.0 mm.
5. The composite pane according to claim 1, wherein the first and/or the second thermoplastic composite film contains at least 3 wt. % of a plasticizer, and the plasticizer contains or is made of aliphatic diesters of tri- or tetraethylene glycol.
6. The composite pane according to claim 1, wherein the thermoplastic composite films contain at least 60 wt. % of polyvinyl butyral (PVB).
7. The composite pane according to claim 1, wherein the barrier film contains or is made of polyethylene terephthalate PET) or polyvinyl fluoride (PVF) and is plasticizer free.
8. The composite pane according to claim 1, wherein the material composition of the barrier film differs in terms of its main constituent by weight from the main constituent by weight of the thermoplastic composite films.
9. The composite pane according to claim 8, wherein the barrier film contains polyethylene terephthalate (PET) as the main constituent by weight and the thermoplastic composite films contain polyvinyl butyral (PVB) as the main constituent by weight.
10. The composite pane according to claim 1, wherein the barrier film in the form of a pre-composite comprising a barrier film and a first thermoplastic composite film or in the form of a pre-composite comprising a barrier film and a second thermoplastic composite film is inserted into the layer stack of the composite pane and the barrier film is in direct contact with the thermoplastic composite film of the pre-composite.
11. A method for producing a composite pane with a functional element according to claim 1, the method comprising: arranging a first thermoplastic composite film sheet-wise on a first pane, arranging a functional element and a barrier film surrounding the peripheral edge of the functional element in a frame-like manner on the first thermoplastic composite film, arranging a second thermoplastic composite film on the functional element and the barrier film, placing a second pane placed on the second thermoplastic composite film, and bonding the layer stack by autoclaving to form a composite pane, wherein the barrier film contains at most 0.5 wt.-% plasticizer and prevents the diffusion of plasticizer through the barrier film, and the first thermoplastic composite film and the second thermoplastic composite film contain in each case at least one plasticizer.
12. The method according to claim 11, wherein the barrier film is inserted into the layer stack as a pre-composite together with the first thermoplastic composite film or the second thermoplastic composite film.
13. The method according to claim 12, wherein the barrier film is bonded to the first thermoplastic composite film or the second thermoplastic composite film under the action of heat and pressure to form a pre-composite.
14. The method according to claim 12, wherein a pre-composite is created from a substantially congruently arranged thermoplastic composite film and a barrier film, the barrier film of the pre-composite is removed in at least one cutout, and during assembly of the layer stack, the functional element is inserted into the cutout of the barrier film.
15. A method comprising utilizing a composite pane according to claim 1 as a windshield or roof panel of a vehicle, wherein the electrically controllable functional element serves as a sun visor or as a privacy screen.
16. The composite pane according to claim 3, wherein the thickness of the barrier film and the thickness of the functional element differ from one another by at most 20%.
17. The composite pane according to claim 4, wherein the barrier film has a thickness of 0.3 mm to 0.5 mm.
18. The composite pane according to claim 5, wherein the first and/or the second thermoplastic composite film contains at least 30 wt.-% of a plasticizer.
19. The composite pane according to claim 5, wherein the plasticizer contains or is made of triethylene glycol-bis-(2-ethyl hexanoate).
20. The composite pane according to claim 6, wherein the thermoplastic composite films contain at least 90 wt.-% of polyvinyl butyral (PVB).
Description
[0097] The invention is explained in detail with reference to drawings and exemplary embodiments. The drawings are schematic representations and not to scale. The drawings in no way restrict the invention. They depict:
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[0109] Suitable cutting tools 17 are known to the person skilled in the art. A plotter equipped with a cutting blade has, for example, proved to be quite suitable. However, other methods can also be used, such as laser cutting. The barrier film 6 is removed in the region of the cutout 7. This is possible by lifting the barrier film 6 to be detached at the edge of a cut 18. Starting from such a raised corner, the regions of the barrier film 7 to be removed are peeled off. This is possible with morate expenditure of force and without damaging the films. The inner edge 22 of the barrier film 6 extends, set back inward relative to the outer edge of the subsequent composite pane, in the direction of the center of the barrier film 6. The inner edge 22 runs peripherally and forms a passe-partout, into which a functional element can be inserted. The amount by which the inner edge 22 is set back relative to the subsequent outer edge of the composite pane in the direction of the center of the pane can be variable or constant along the peripheral edge. This variability is made possible above all by the use of a pre-composite, which enables a substantially more precise positioning of the films in the layer stack. A pre-composite 9 is created comprising a continuous thermoplastic composite film 3 or 4 and a frame-like barrier film 6, which is present only at the points of the pre-composite where it is required for the sealing of the functional element (see C) in
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[0111] The barrier film 6 is trimmed per
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[0113] The optical properties of the functional element 5 can be controlled by applying an electrical voltage. For the sake of simplicity, the electrical supply lines are not shown.
[0114] The controllable functional element 5 is, for example, a PDLC multilayer film, consisting of an active layer 11 between two surface electrodes 12, 13 and two carrier films 14, 15. The active layer 11 contains a polymer matrix with liquid crystals dispersed therein, which align themselves as a function of the electrical voltage applied on the surface electrodes, by which means the optical properties can be controlled. The carrier films 14, 15 are made of PET and have a thickness of, for example, 180 m. The carrier films 14, 15 are provided with a coating of ITO facing the active layer 11 and having a thickness of approx. 100 nm, forming the surface electrodes 12, 13. The surface electrodes 12, 13 can be connected to a voltage source via bus bars (not shown) (implemented, for example, by a silver-containing screen print) and connecting cables (not shown).
[0115] The thermoplastic composite films 3, 4 comprise in each case a thermoplastic film with a thickness of 0.38 mm and are made, for example, of 78 wt.-% polyvinyl butyral (PVB) and 20 wt.-% triethylene glycol bis(2-ethyl hexanoate) as a plasticizer.
[0116] The barrier film 6 is made, here, for example, substantially of PET, i.e., at a rate of at least 97 wt.-%. The barrier film 6 contains less than 0.5 wt.-% plasticizer and is suitable for preventing the diffusion of plasticizer out of the thermoplastic composite layers 3, 4 via the peripheral edge 8 into the functional layer 5.
[0117] The barrier film 6 has a thickness of 450 m, whereas the functional element has a thickness of 400 m. Since the thickness of the barrier film 6 exceeds the thickness of the functional element 5, the inner edge 22 of the barrier film completely covers the peripheral edge of the functional element.
[0118] The barrier film 6 is in direct contact with the functional element 5, in the present case by direct contact with the open cross-section of the functional element 5 along the peripheral edge 8. The barrier film 6 has no overlap at all in the form of a contact of the film surfaces, but rather enables deliberate selective edge sealing through direct contact of the side edges. In this context, film surfaces refers to the surfaces of the films running substantially parallel to the panes 1, 2, while the film edges have a course essentially orthogonal to the panes 1, 2. Here, direct contact means that no further components or chemical compounds at all, for example, adhesives, are arranged between the barrier film 6 and the functional element 5. According to the prior art, slippage of the barrier films during assembly is prevented by adhesive connections. According to the invention, an adhesive connection is unnecessary and undesirable. Slippage of the barrier films is achieved through the use of the pre-composite 9, which comprises the barrier film 6 and one of the thermoplastic composite films 3 or 4. The embodiment of the invention described in
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[0120] The optical properties of the functional element 5 can be controlled by applying an electrical voltage. For the sake of simplicity, the electrical supply lines are not shown. The controllable functional element 5 is, for example, a PDLC multilayer film, comprising an active layer 11 between two surface electrodes 12, 13 and two carrier films 14, 15. The further structure of the functional element corresponds to that described in
[0121] The thermoplastic composite films 3, 4 and the barrier film 6 correspond in their chemical composition and their layer thickness to the dimensions described in
[0122] The edge region of the roof panel is concealed by a circumferential black print 10 (circumferential peripheral masking print) that is applied at least on the inner side of the outer pane. The black print is formed by printing an opaque enamel onto the interior-side surface (facing the interior of the vehicle in the installed position) of the second pane 2. Optionally, a black print 10 can also be applied on the inner side of the first pane 1. The peripheral edge 8 of the functional element 5 lies in the region of the black print 10 such that it is not perceptible when viewing the roof panel from the outside. The distance of the functional element 5 from the peripheral edge of the roof panel is thus smaller than the width of the black print 10. The electrical connections (not shown) are also reasonably mounted in the region of the black print 10 and thus hidden.
[0123] The barrier film 6 is in direct contact with the functional element 5, in the present case, in sheet-wise contact with the surfaces of the carrier films 14, 15, and, additionally, in direct contact with the open cross-section of the functional element 5 along the peripheral edge 8. Also, according to the exemplary embodiment of
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[0125] The height of the darkened functional element 5 can be adjusted by the segmentation. Thus, depending on the position of the sun, the driver can darken the entire sun visor or even only part of it. The figure indicates that the upper half of the sun visor is darkened and the lower half is transparent.
[0126] In a particularly convenient embodiment, the functional element 5 is controlled by a capacitive switch area arranged in the region of the functional element, wherein the driver determines the degree of darkening by the location at which he touches the pane.
[0127] The windshield per
[0128] The sun visor is formed by a commercially available PDLC multilayer film as the functional element 5 that is embedded in the plastic composite films. The height of the sun visor b is, for example, 21 cm. The first thermoplastic composite film 3 is bonded to the first pane 1; the second thermoplastic composite film 4 is bonded to the second pane 2. In the region of the peripheral edge 8 of the functional element 5, a barrier film 6 that surrounds the edge 8 and seals the functional element 5 is inserted into the layer stack. The barrier film 6 is used as a pre-composite 9 with the second thermoplastic composite film 4.
[0129] The second thermoplastic composite film 4 has a tinted region that is arranged between the functional element 5 and the second pane 2 (outer pane). The light transmittance of the windshield is thus additionally reduced in the region of the functional element 5, and the milky appearance of the PDLC functional element 5 in the diffuse state is mitigated. The aesthetics of the windshield are thus significantly more attractive. The second thermoplastic composite film 4 has, in the tinted region, for example, average light transmittance of 30%, with which good results are achieved. The region can be homogeneously tinted. However, it is often visually more appealing if the tinting decreases in the direction of the lower edge of the functional element 5 such that the tinted and the non-tinted regions merge smoothly.
[0130] The lower edge of the tinted region and the lower edge of the PDLC functional element 5 can be arranged flush with one another. This is, however, not necessarily the case. It is also possible for the tinted region to protrude beyond the functional element 5 or, vice versa, for the functional element 5 to protrude beyond the tinted region. In the latter case, it would not be the entire functional element 5 that would be bonded to the second pane 2 via the tinted region.
[0131] The controllable functional element 5 is a multilayer film, analogous to the structure depicted in
[0132] A so-called high flow PVB, which has stronger flow behavior compared to standard PVB films, can preferably be used for the thermoplastic composite films 3, 4, 19 per
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[0145] VIa Placing a second thermoplastic composite film 4 on the barrier film 6 and the functional element 5 [0146] or [0147] VIb Placing the pre-composite 9 comprising the second thermoplastic composite film 4 and the barrier film 6 on the functional element 5, wherein the barrier film 6 is applied in the vicinity of the functional element and encloses the peripheral edge 8 of the functional element 5 [0148] VII Placing a second pane 2 on the second thermoplastic composite film 4 [0149] VIII Autoclaving the layer stack to form a composite pane 100
LIST OF REFERENCE CHARACTERS
[0150] 1 first pane [0151] 2 second pane [0152] 3 first thermoplastic composite film [0153] 4 second thermoplastic composite film [0154] 5 functional element having electrically controllable optical properties [0155] 6 barrier film [0156] 7 cutout (of the barrier film) [0157] 8 peripheral edge of the functional element 5 [0158] 9 pre-composite comprising first thermoplastic composite film 3 or second thermoplastic composite film 4 and barrier film 6 [0159] 10 black print [0160] 11 active layer of the functional element 5 [0161] 12 first surface electrode of the functional element 5 [0162] 13 second surface electrode of the functional element 5 [0163] 14 first carrier film [0164] 15 second carrier film [0165] 16 isolation lines [0166] 17 cutting tool [0167] 18 cuts [0168] 19 additional thermoplastic composite films [0169] 20 additional carrier film [0170] 21 infrared reflecting coating [0171] 22 inner edge of the barrier film 6 [0172] 100 composite pane [0173] AA, BB, CC section lines [0174] Z enlarged region [0175] S field of vision B [0176] M engine edge [0177] D roof edge